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DOI: 10.1002/ange.201002889
Phosphorus Mononitride
6066 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Angew. Chem. 2010, 122, 6066 6069
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Angew. Chem. 2010, 122, 6066 6069 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.angewandte.de 6067
Zuschriften
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THF/hexane (1:1) solution at room temperature. M.p.: 216 8C; [9] The solid-state structure of three-dimensional polymeric P3N5
1
H NMR (500 MHz, C6D6): d = 7.047.00 (m, 4 H, CH), 6.966.91 has also been reported; see: a) S. Horstmann, E. Irran, W.
(m, 5 H, CH), 3.22 (br, 4 H, CH2 2), 3.13 (sept, J = 7.0 Hz, 2 H, Schnick, Angew. Chem. 1997, 109, 1938 1940; Angew. Chem.
CH(CH3)2), 2.79 (sept, J = 7.0 Hz, 2 H, CH(CH3)2), 2.49 (sept, J =
Int. Ed. Engl. 1997, 36, 1873 1875; b) K. Landskron, H.
7.0 Hz, 2 H, CH(CH3)2), 1.70 (s, 2 H, CH2), 1.271.13 (m, 10 H, CH2),
Huppertz, J. Senker, W. Schnick, Angew. Chem. 2001, 113,
1.10 (d, J = 7.0 Hz, 12 H, CH(CH3)2 2), 1.07 (d, J = 7.0 Hz, 12 H,
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CH(CH3)2 2), 1.02 (d, J = 7.0 Hz, 12 H, CH(CH3)2 2), 0.85 ppm (s,
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6 H, CH3); 13C NMR (125 MHz, C6D6): d = 199.2 (d, 1JP-C = 50.0 Hz,
32918645, 1966; b) X. Zeng, W. Wang, F. Liu, M. Ge, Z. Sun, D.
NPC), 152.4 (d, 2JP-C = 21.3 Hz, CNP), 149.3 (o), 148.5 (o 2), 138.9
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(br, ipso), 135.3 (ipso), 128.5 (p 2), 128.3 (p), 125.2 (m), 124.7 (m
Schmidt, Z. Anorg. Allg. Chem. 1976, 425, 189 192.
2), 66.4 (Cq), 53.5 (d, 2JP-C = 9.1 Hz, PCCq), 51.2 (CH2), 49.0 (br, CH2
2), 36.8 (CH2), 30.1 (CH3), 29.1 (CH 2), 28.9 (CH), 28.4 (CH3), 28.3 [11] For Reviews, see: a) E. A. MacLachlan, M. D. Fryzuk, Organo-
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Keywords: carbenes phosphorus mononitride radical cations Chem. Soc. 2007, 129, 14180 14181; d) J. D. Masuda, W. W.
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6068 www.angewandte.de 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Angew. Chem. 2010, 122, 6066 6069
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