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AromaticsProduction
TopsoeCatalysisForum
Munkerupgaard,DenmarkAugust2728,2015
GregMarshall
GAMEngineeringLLC
GAMEngineeringLLC 1
REFINERYCONFIURATION
LPG
GASOLINE BLENDING
ISOMERISATION
NAPHTHA
HYDROTREATING MOTOR
CATALYTIC GASOLINE
REFORMING
ICN
ALKYLATION
CRUDE DISTILLATION (APS/VPS)
DISTILLATE BLENDING
DISTILLATE ADO
HYDROTREATING
LUBES
HEATING
OIL
VGO CATALYTIC
FCCU DISTILLATE
HYDROCRACKING/ CRACKING
HYDROTREATING
GOFINING (FCCU)
GAMEngineeringLLC 5
SimplifiedSemiRegenReformer
GAMEngineeringLLC 6
CyclicReforming
TO/FROM
UPPER REACTION HEADER UPPER REGEN HEADER REGEN
CIRCUIT
REACTORS
A B C D A-S S
Cat Flow #1
#2
#3
Regenerated
Catalyst
Hydrogen
Spent Catalyst
Hydrotreated
Start
Naphtha Charge
GAMEngineeringLLC 8
UnitRevamps
Mostdonetostretchexistingunitcapacity
Heaterpreplacementduetocreep
Loweringpressuretoincreaseyields
Changingfeedeffluentexchangers
Purgefromcompressordischarge
Switchingfrommonometalliccatalysttobimetallic
catalyst
GAMEngineeringLLC 9
Catalyst
DualFunction
Acid:Aluminawithchloride
Metal:Ptwithorwithoutpromotermetals(Re,Ir,Sn)
ReprovidescokestabilityandadditionalrunlengthSulfiding required
Ir additionalactivitySulfiding required
Snpromotesyieldatlowcokelevelsnosulfiding required
Supportedongammaalumina
Highsurfacearea
200m2/gmfreshcatalyst
120m2/gmagedcatalyst
Surfaceareadeclinewithexposuretohightemperatureandsteam
Heartofreformingprocess
Promotesgoodreactions
GAMEngineeringLLC 10
Products
SAMEHYDROCARBONTYPESASFEEDBUTPRIMARILYAROMATIC
ANDC7 PARAFFINS
AROMATICSARETHEPRINCIPALSOURCEOFHIGHOCTANE
NAPHTHENESANDC8+PARAFFINSESSENTIALLYABSENTAT98+ RON
LIGHTERPARAFFINSAREMOREBRANCHEDTHANINFEEDBUTARESTILL
PREDOMINATELYSINGLEMETHYLSUBSTITUTEDWITHLOWRON
100 %AromaticsVsRON
98
96
94
RON
92
90
88
86
84
0,0% 20,0% 40,0% 60,0% 80,0%
GAMEngineeringLLC 11
%Aromatics
UnitOptimization
LowpressureandlowH2/HCratiofavor
Higherliquidyields
Higheraromaticyields
Coke
Hightemperaturesfavor
Dehydrogenation
Dehydrocyclization
Hydrocracking
Coke
GAMEngineeringLLC 12
FeedSelection
Highyield Easyfeed
Naphthenicfeeds
ExampleSleipner Condensate
~70%naphthenes
Requirelargereheatfurnaces highendotherms
Highhydrogenandaromaticsyields
LowerYield Moredifficultfeed
Paraffinicfeeds
ExampleLtArabNaphtha
~70%paraffins
Reactorendothermsdecreased
HigherLtendsyields
GAMEngineeringLLC 13
MogasVsAromaticsOperation
Mogasoperation
TargetsC5+RONneededforgasolineblending
Targetcanandwillchangebasedongasolinegradeblended
TypicalRON92to95withshortexcursionsto98asneeded
Aromaticsoperation
Targetmaximumaromaticsconcentrationinreformate
TypicalRONofreformate>98withsomeunitsoperatingupto102
Feedandunittypedependent
Semiregenunitsrequirefrequentregeneration
CyclicandCCRbettersuitedforaromaticsoperation
MinimizeC9nonaromatics
GAMEngineeringLLC 14
YieldversusSeverity
TypicalyieldwithafeedWatsonKof11.8
88
87
86
85
84
C5+Yield
83
82
81
80
79
90 91 92 93 94 95 96 97 98 99 100
RON
GAMEngineeringLLC 15
ExpectedYields
ReformerTypesandYields
95
90
85
C5+Yield
SemiRegen
Cyclic
80 SemiRegen2
CCR
75
70
0 2 4 6 8 10 12 14
Months
AromaticsRecovery
Removelightends
Depentanize viadistillation
Removeheavyends
C8 overheadindistillationtower
CanseparateA8fromA9bydistillation
CannotseparateA8fromP9bydistillation
Azeotropeformed
Mogasand/oraromaticsolvents
C6toC8streamsenttosolventextraction
Raffinate tomogas orspecialtysolvents
GAMEngineeringLLC 17
BTXRecovery
ClayTreater
Fractionation
BZproductO/H
Towerbottomstoanotherfractionator
Tolueneproductoverhead
Towerbottomstoanotherfractionator
ToweroverheadconcentratedParaXylene
SenttoParex forproductionofpurePx
Parex rejectstreamsenttoParaXyleneIsomerazation
Towerbottomssenttoanotherfractionator
ProducesOrthoXylenefromtoweroverhead
Towerbottomssenttomogas
GAMEngineeringLLC 18
AdditionalPx
ProductTolueneisdividedbetweensalesandSTDP
Flowratesdeterminedbyeconomics
STDPFeedsToluene
Majorproductare
Benzene
Paraxylene
GAMEngineeringLLC 19