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CONFIDENTIAL 1 4541/3

Chemistry Name :_________________________________


4541/3
October 2014 I/C No. :_________________________________
1 Hour 30 minutes
Class. :_________________________________

FINAL EXAMINATION

CHEMISTRY
SECONDARY
Paper 3
1 HOUR 30 MINUTES
4

DO NOT OPEN THIS BOOKLET UNTIL INSTRUCTED

1. This question paper consists of two questions: Question Full Mark


Question 1 and Question 2. marks obtained

2. Answer all the questions. You may use 1 33


equations, diagrams, tables, graph, and 2 17
other suitable method to explain your answer.
Total 50
3. The diagrams in the questions are not drawn
to scale unless stated.

4. The marks allocated for each question or subpart of a question is shown in brackets.

5. You may use a non-programmable scientific calculator.

6. You are advised to spend 45 minutes to answer Question 1 and 45 minutes for
Question 2.

Prepared by : Mrs. Wan Nurul Aini Wan Nor Yuhaidi


Checked by : Mr. Tan K. K.
Approved by : Mrs. Hariah Muhi

This question paper consists of 6 printed pages

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Answer all questions.

1 Diagram 1.1 shows the apparatus set up for an experiment to construct the
electrochemical series based on the potential difference between pairs of metals in a
simple voltaic cell.
Copper plate is paired with zinc, lead, iron, aluminium and magnesium metals in
Cell I, Cell II, Cell III, Cell IV and Cell V respectively. In each cell, copper acts as
the positive terminal.

Diagram 1.1

Diagram 1.2 shows the voltmeter readings of each cell.

Cell I: Cu Zn Cell II: Cu Pb

Voltmeter reading: ____________V Voltmeter reading: ____________V

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Cell III: Cu Fe Cell IV: Cu Al

Voltmeter reading: ____________V Voltmeter reading: ____________V


Cell V: Cu - Mg

Voltmeter reading: ______________V

Diagram 1.2

(a) Record the voltmeter readings of each cell in the spaces provided in Diagram
1.2.
[3 marks]

(b) Complete the table to record the cell voltage and negative terminal in each of
these cells.

Cell Pair of metals Negative terminal Cell voltage/V


I Zink Copper
II Lead Copper
III Iron Copper
IV Aluminium Copper
V Magnesium - Copper

[3 marks]

(c) State three observations and the corresponding inferences in Table 1.1. The
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observations should not include the deflection of voltmeter needle.

Observation Inference
Negative terminal

Positive terminal

Colour of the solution

[6 marks]

(d) State one hypothesis for this experiment.


...
[3 marks]

(e) For this experiment, state the:


(i) manipulated variable : ...
(ii) responding variable : ...
(iii) constant variable : ...
[3 marks]

(f)
State the operational definition for the position of metals in the
electrochemical series.

...
[3 marks]

(g) Arrange the six metals in descending order of electropositivity.



[3 marks]

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(h) (i) The experiment is repeated using another copper plate to pair with the
copper plate. Predict the voltmeter reading.

..
[3 marks]

(ii) Explain the answer in 1(h)(i).


..
[3 marks]
(i) Classify the ions present in the electrolyte of copper (II) sulphate in this
experiment by completing Table 1.2.

Anions Cations
(i) (iii)

(ii) (iv)

[3 marks]

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2 Diagram 2 shows the apparatus set up for titration of 25.0 cm3 of 1.0 mol dm-3 of
potassium hydroxide, KOH solution with dilute hydrochloric acid, HCl.
Phenolphthalein is used as an indicator.

Dilute hydrochloric
acid

Potassium hydroxide +
phenolphthalein

Diagram 2

Based on this situation, plan one experiment in the laboratory to determine the
concentration of hydrochloric acid by finding the end point of titration. Your
planning should include the following aspects.

(a) Aim of the experiment


(b) Statement of the hypothesis
(c) All the variables
(d) List of substances and apparatus
(e) Procedure of the experiment
(f) Tabulation of data
[17 marks]

END OF QUESTION PAPER

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ANSWER SCHEME CHEMISTRY FINAL EXAMINATION SECONDARY 4


(PAPER 3)

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