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Research Article
Amity University, Uttar Pradesh, Lucknow Campus, Viraj Khand -5, Gomti Nagar, Lucknow, 226010,
Abstract: With the rising rate of population, need for clean water and subsequent increase in generation
of wastewater, it has become mandatory to treat wastewater in order to obtain high-quality pure water.
The primary need for wastewater treatment is because less than 1 percent of the worlds water is
suitable for drinking while the remaining is brackish. Nanotechnology could help to solve the problem as it
is generally used in areas where there is a need for attacking at the molecular level of the
substances. The highly active, magnetically re-extractable nanoscale Pd on magnetite catalyst
(Pd/Fe3O4) , novel Titanium dioxide nanocatalyst and nanofilteration membrane are some of the
technologies which have been developed for application in wastewater treatment processes have shown
promise of water purification. This review article aims to provide an insight into the treatment techniques
prevalent for industrial wastewater purification by nanotechnology, which could make heavily polluted
water fit for drinking, sanitation, and irrigation. They can chemically degrade pollutants instead of
simply moving them somewhere else, including pollutants for which existing technologies are
inefficient or prohibitively expensive.
INTRODUCTION:
Water is a scarce resource, and for many countries particularly India, supplies already
fall short of demand. With the pressures of climate change and population growth in the urban
areas, water has become even scarcer. Moreover, in these regions, the water available is often
unsafe to drink. As a result, there is a growing need for fresh and clean water especially for
drinking purposes. This escalates the need for technologies that produce high quality water after
treatment that do not cause any detrimental effect to human beings or the environment.
The principal way nanotechnologies might help alleviate water problems is by solving
the technical challenges by removing water contaminants, including pathogenic bacteria, viruses,
harmful chemicals arsenic, mercury, pesticides, insecticides and salt pose etc., altogether, instead of
dumping from one resource to another, as environmental issues have global impact, destroying every
component of atmosphere at an alarming rate(Han Sheng H.,2001).
The presence in the environment of large quantities of toxic metals such as mercury, lead,
cadmium, zinc or others, poses serious health risks to humans, and this threat puts the scientific
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community under pressure to develop new methods to detect and eliminate toxic contaminants from
wastewaters in efficient and economically viable ways(Tsang Lee,2009). Utilizing nanotechnology
for wastewater treatment would certainly help the human being, our environment as well as
industry too as it has shown amazing results in every fields.
There are various methods for wastewater treatment using nanocatalyst. Some of the
eco-friendly and less expensive methods are:
prominent advantage, especially when high concentrations of organic pollutants in water is their
or by other means difficult to handle. It has the more obvious advantages, unmatched by other
conventional methods, especially in recent years, with the development of highly efficient
photocatalyst, loads and metal-doped nano-particles, optoelectronics, with catalytic methods and
solar technology research and development, so that nano-Titanium dioxide photocatalytic
oxidation used in water treatment can be used as a good promise in the future(Mei Shang,2000).
Growing Interest: The chart below represents the number of the publish reports on
nanostructured metal catalyst .(Fig:2 & 3)
Fig:3 Specific metal catalyst: Interest in specific elements in the preparation of Nanoparticles in the
period 2000-2007
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Palladium catalysts can be used for the selective removal of halogenated organic compounds
from aqueous waste via hydro de halogenation reactions in the presence of other omnipresent
constituents of industrial wastewaters(Yuan G.,2003). This detoxification of the water can prevent
the need for further cost-intensive treatment or discharge into waste incineration plants. Often,
the water can then be released to municipal sewage plants. The catalyst can tolerate various
inorganic and organic substances in relevant concentrations. Wastewaters containing a high
background concentration of organic solvents can also be cleaned from halogenated
pollutants(Kopinke F-D.,2003). However, waters which contain heavy metals such as lead or
mercury or reduced sulphur species such as sulphides need specific pre-treatments prior to Pd-
catalysed hydro de halogenations.(Fig : 4 )
Detoxification means that persistent HOCs are converted into organic compounds which can
easily be removed by biodegradation in a wastewater treatment plant(Kopinke F-D.,2004). A novel
promising trend in environmental research is the application of nano-reagents (such as zero-valent
iron) and nano-catalysts. As known from nano-sized metal particles, nano catalysts have the advantage
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of very high reaction rates due to high specific surface areas and low mass-transfer restrictions(Lowry
G.V.,2000). For special applications in wastewater treatment the researchers generated extremely
active palladium catalysts on the basis of ferromagnetic carrier colloids. The magnetic nano-sized
carriers (such as zero-valent iron or magnetite) were spiked with traces of Pd (0.1 wt.-%). These nano-
catalysts have been successfully tested in different reactor systems at the laboratory scale. Using Pd on
nano-scale supports leads to enormous activity of the catalyst which is several orders of magnitude
higher than reached in conventional fixed-bed reactors. The ferromagnetism of the carriers enables a
separation of the catalysts from the treated water by means of magneto-separation(Liu Y., 2005). This
gives the chance to reuse the catalyst several times. The preferred reduction for the HDH reaction is
molecular hydrogen. For highly contaminated waters, alternative hydrogen donors such as formic acid
have been successfully tested.(Fig: 5)
NANOSTRUCTURED SILICA:
New nanotechnology wastewater treatment system for removing heavy metals :
A new type of nanomaterial called nanostructured silica has been found to fulfil the requisites
necessary for removing heavy metals for these applications(Yang,P.,2001 ).
With its large surface area and regular pores, it is an ideal material that after a functionalization
process that links to its surface diverse organic ligands has the capability of being able to extract heavy
metals from wastewaters. This capacity also allows its use as a high sensitivity detection tool for these
toxic metals, and considering that the contamination levels permitted in drinking water are
increasingly restrictive; functionalized silica offers additional benefits over other water treatment
methods.
The design of this nanostructured functionalized silica is based on the emulation on the
material of the reaction that heavy metals have with some biomolecules in living cells(A. Lide, 2001)
Therefore a good understanding of the reaction that bonds such metals to particular functional groups
on living cells is of great use to determine the best functional groups to be used on the surface of the
nanostructured material; for example, it has been detected that heavy metals interact mainly with
functional groups containing oxygen, nitrogen and sulphur.
Following the same line of thinking, the researchers from the URJC, managed by Doctor Isabel Sierra,
have achieved a great improvement in heavy metal absorption by creating new materials using
different types of silica such as MCM-41 and HMS and modified them with 5-mercapto-1-
methylthiazole making them capable of collecting lead and zinc(Mc-Nab W.W.,2000). Their study has
also demonstrated that the prepared materials are capable of several cycles of absorption/desorption.
With the added benefit that the retained materials can be recovered and then reused, and this has
important economical benefits for industry and society.
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Nanofiltration is used to remove pesticides and other organic contaminants from surface
and ground waters to help insure the safety of public drinking water supplies. Sometimes
referred to as "membrane softening," NF is an attractive alternative to lime softening or zeolite
softening technologies and since NF operates on lower pressure than RO, energy costs are
lower than for a comparable RO treatment system(Jin-Bao,2000). As such, nanofiltration is
suited especially to treatment of well water or water from surface supplies such as rivers or
lakes.
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Attapulgite clays: Naturally occurring attapulgite clays and zeolites are also used in nanofilters. These
are locally available in many places around the world and have innate nanometer-size pores. A study
using attapulgite clay membranes to filter wastewater from a milk factory in Algeria has shown they
can economically and effectively reduce whey and other organic matter in wastewater, making it safe
to drink.
Nanofiltration membranes can produce safe drinking water from brackish groundwater:
Researchers are developing new classes of nanoporous materials that are more effective than
conventional filters. For example, a study in South Africa has shown than nanofiltration membranes
can produce safe drinking water from brackish groundwater.
Carbon Nanotube Filters Remove Bacteria And Viruses: A team of Indian and US scientists have
developed carbon nanotube filters that remove bacteria and viruses more effectively than conventional
membrane filters(Kiso Y.,2000).
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Where:
P = External pressure
(J) = Solvent flux
(R) = Rejection
solvent flux is given by:
Cb = Concentration level l
Hydrotalcite: Zeolites can also be fabricated. They can be used to separate harmful organics from
water and to remove heavy metal ions. Researchers at Australia's Commonwealth Scientific and
Research Organization have created a low-cost synthetic clay, hydrotalcite, that attracts arsenic,
removing it from water. They have suggested a novel packaging for this product for low-income
communities a 'teabag' that can be dipped into household water supplies for about 15 minutes
before drinking. And selling the used teabags back to the authorities might increase recycling and help
with waste disposal of concentrated arsenic.
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Nano magnets: Magnetic nanoparticles are other examples of how nanotechnology could make
heavily polluted water fit for drinking, sanitation and irrigation. Researchers at the Indian Institute of
Science, in Bangalore, have used nano titanium dioxide for this very purpose.
Magnetic nanoparticles have large surface areas relative to their volume and can easily bind
with chemicals. In water treatment applications, they can be used to bind with contaminants such as
arsenic or oil and then be removed using a magnet. Several companies are commercialising such
technologies and researchers are frequently publishing new discoveries in this area.For example,
scientists at Rice University in the United States are using magnetic "nanorust" to remove arsenic from
drinking water. Nanorust's large surface area means it can capture one hundred times more arsenic
than larger counterparts. The team projects that 200500 milligrams of nanorust could treat a litre of
water. And it is developing a way of creating nanorust from inexpensive household items. This could
significantly reduce production costs, making it a viable product for communities throughout the
developing world.
CONCLUSION:
Nanotechnologies offer an affordable, effective, efficient and durable ways of achieving the
target of water purification- specifically because using nanoparticles for water treatment will allow
manufacturing that is less polluting than traditional methods and requires less labour, capital, land and
energy.A range of water treatment devices that incorporate nanotechnology are already on the market,
with others either close to market launch or in the process of being developed.
Some location of Lucknow have higly polluted water and is not suitable for drinking purpose
and the quality of water that is obtained after the adoption of nanotechnology is well and purified at
extreme level. It has been determined that these nano-based filters are able to achieve 99.95 percent
efficiency, when compared to conventional technologies. As a result, the water or effluent that is
obtained after the treatment could be reused for various domestic and industrial applications
Nanotechnology is an emerging discipline, its application in water treatment has just begun, but
the emerging trends. It can be predicted, with the deepening of research work and practical to a higher
level, nanotechnology water treatment technology will be developed in the 21st century, and solve
global water shortages and water pollution problems play an important role.
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*Correspondence Author: J. Pandey, Amity University, Uttar Pradesh, Lucknow Campus, Viraj
Khand -5, Gomti Nagar, Lucknow, 226010,
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