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19. If change in energy, (E) 3 10 8 J, h 6.64 10 34 J s and c 3 10 8 m / s, then wavelength of the light is
30. Calculate the ratio of rate of effusion of O2 and H2 from a container containing 16gm O2 and 2gm H2 :
(A) 1 : 8 (B) 8 : 1 (C) 1 : 4 (D) 4 : 1
Ans. (A)
31. Temperature at which most probable speed of O2 becomes equal to root mean square speed of N2 is [Given : N2 at 427C]
(A) 732 K (B) 1200 K (C) 927 K (D) 800 K
Ans. (B)
32. The density of gas A is twice that of B at the same temperature the molecular weight of gas B is thrice that of A. The ratio of
pressure of gas A and gas B will be
(A) 1 : 6 (B) 7 : 8 (C) 6 : 1 (D) 1 : 4
Ans. (C)
33. Select the correct option for an ideal gas undergoing a process as shown in diagram.
(A) If 'n' is changing , 'V' must also be changing.
(B) If 'n' is constant , 'V' must be constant.
(C) If 'n' is constant , 'V' must be changing.
(D) If 'n' is changing , 'V' must be constant.
Ans. (AB)
34. The term that corrects for the attractive forces present in a real gas in the Vander Waals equation is
an 2 an 2
(A) nb (B) (C) (D) nb
V2 V2
Ans. (B)
35. Which one can act as oxidising & reducing agent both-
(A) HNO2 (B) H2O2
(C) H2SO3 (D) all [D]
36. If Kp for a reaction ,
A(g) + 2B(g) 3C(g) + D(g)
is 0.05 atm at 1000 K, its Kc in terms of R will be -
(1) 20000 R (2) 0.02 R
5 10 5
(3) 5105 R (4)
R
37.Which mixture of gases at room temperature does not obey Dalton's law of partial pressure- [B]
(A) NO2 and O2 (B) NH3 and HCl
(C) CO and CO2 (D) SO2 and SO3