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D R I L L I N G A N D C O M P L E T I O N F L U I D S

NEW GAS-HYDRATE INHIBITORS FOR


DEEPWATER DRILLING FLUIDS
Numerous technical challenges face oper- lines and valves. Large volumes of gas can side of the equilibrium line. Addition of 20
ators venturing into deep water. Drilling- be released if gas hydrates dissociate near wt% NaCl to fresh water causes the
fluid design must address traditional engi- the surface. hydrate-equilibrium line to move approxi-
neering issues of hole cleaning, hole sta- As drilling operations have entered water mately 28°F to the left. Gas hydrates will
bility, and drill-cuttings stability as well as depths greater than 1,000 ft, seafloor tem- form at 75°F and 2,800 psi in fresh water
possible gas-hydrate formation. In deeper peratures as low as 39°F in the GOM and but will not form in the 20-wt%-NaCl fluid
sections of the Gulf of Mexico (GOM), the 30°F in some sections of the North Sea are at the same pressure until the temperature
pressure differential between pore pres- possible. These conditions are favorable for falls to 47°F. Although 20 wt% NaCl, by
sure and fracture gradient may be gas-hydrate formation. Salts or combina- itself or combined with polyglycerol, pro-
extremely small. Fracture pressures on tions of salts with water-soluble organic vides a high level of hydrate suppression,
land are a function of the overburden pres- compounds are used in drilling fluids to densities less than 10 lbm/gal cannot be
sure exerted by the formation. In offshore decrease the likelihood of gas-hydrate for- achieved in these systems.
applications on the other hand, seawater mation. Sodium chloride (NaCl) concen-
reduces the overburden-pressure gradient. trations of 20 wt% or greater have been NEW FLUID DESIGN FOR
In deepwater drilling, a substantial used for drilling deep offshore GOM wells DEEP WATER
amount of hole must be drilled riserless for several years. More recently, fluids An improved gas-hydrate inhibitor for
with returns to the seafloor before a suit- incorporating NaCl and glycerol or poly- drilling-fluid applications should have the
able casing shoe can be established for the glycerol to inhibit gas-hydrate formation following characteristics.
drilling fluid to be pumped from the bot- have been formulated. This combination of • The lowest density possible with maxi-
tom of the hole to the rig floor approxi- gas-hydrate inhibitors often is used as a mum hydrate suppression.
mately 80 to 100 ft above sea level. As specialized spotting fluid to prevent • Compatibility with most common
operators move into deeper water, drilling gas-hydrate formation in subsea well-con- drilling-fluid components.
fluid must be designed both for these trol equipment during kill procedures. • Compatibility with most salts to bal-
lower fracture gradients and potential gas- ance hydrate suppression and fluid density.
hydrate formation. L ABORATORY TESTING • Provide shale inhibition for adequate
Temperature and pressure conditions for borehole and drill-cuttings stability.
GA S HYDRATES formation of gas hydrates are simulated by Salts or water-soluble organic compounds
Gas hydrates are clathrates that are formed use of a gas-hydrate generator capable of have been used as additives for thermody-
under certain temperature and pressure operating at pressures as great as 11,000 namic gas-hydrate control in water-based
conditions and can exist at temperatures psi and temperatures as low as 16°F. The muds. Organic compounds, such as alco-
greater than the freezing point of water at gas-hydrate generator consists of a high- hols and glycols, have been used in produc-
high pressures. Clathrates are complexes pressure reactor, glycol bath with immer- tion applications for gas-hydrate control.
formed between two chemicals when one sion heaters and cooler to vary system tem- Unacceptable physical properties, such as
type of molecule completely encloses the perature, gas booster system to vary initial low flash point and undesirable environ-
other molecule in a crystal lattice. In the pressure, and a data-acquisition system. At mental or occupational health effects, have
case of gas hydrates, hydrogen-bonded the beginning of a test, a mud sample is prevented the use of organic compounds in
water molecules form a cage-like structure placed in the reactor vessel and pressurized drilling fluids. Although glycerol and polyg-
around gas molecules, forming a solid with simulated Green Canyon gas. The lycerol have acceptable physical and envi-
substance. Agglomeration of these cage reactor vessel is cooled while reactor pres- ronmental characteristics, their high density
structures can plug drilling-equipment sure is monitored. When hydrate forma- prevents their use in the low-density formu-
tion is detected, bath temperature is held las required by deepwater formation-frac-
constant and the hydrate is allowed to ture gradients.
soak. After soaking for several hours, the Two new water-soluble compounds,
bath temperature is raised, resulting in GHP1 and GHP2, were selected that met
This article is a synopsis of paper SPE release of gas from the hydrate and a pres- the design requirements. These additives
39316, “New Gas-Hydrate Inhibitors sure increase. When all the gas is released are compatible with most common
for Deepwater Drilling Fluids,” by from the hydrate and the pressure returns drilling-fluid additives, including NaCl
William Halliday, SPE, Dennis K. to normal, dissociation is achieved. Three and other salts. Fig. 1 shows the results of
Clapper, SPE, and Mark Smalling, SPE, hydrate-generation tests are required to tests on a drilling fluid containing 23 wt%
Baker Hughes Inteq, originally present- generate three dissociation points and NaCl with 10 vol% GHP2 and drilling flu-
ed at the 1998 IADC/SPE Drilling form a gas-hydrate-equilibrium line. ids containing only NaCl. Points to the
Conference, Dallas, 3–6 March. Hydrates will form at conditions to the left right of these lines represent conditions

52 NOVEMBER 1998 •
Pressure, psi
Fresh Water
10 wt% NaCl
20 wt% NaCl
23 wt% NaCl
23 wt% NaCl/10 vol% GHP
2

Temperature, °F

Fig. 1—Gas-hydrate phase-equilibrium plot.

where no gas hydrates would form. No temperature caused by addition of


hydrates formed in tests with a drilling inhibitors and the hydrate-equilibrium
fluid containing 23 wt% NaCl and 30 vol% temperature in deionized water. The well
GHP1. Both these drilling fluids have a was drilled without fluid-related problems,
9.6-lbm/gal density. Table 5 in the full- and drilling-fluid properties remained very
length paper details a recommended fluid stable, with little increase in viscosity
formula containing GHP1 for use when despite decreasing temperature.
low density and high gas-hydrate suppres-
sion are required. Both GHP1 and GHP2 Offshore GOM. The second use of GHP1
meet current environmental regulations in a drilling-fluid system was in the GOM
for the GOM. GHP1 has been approved for for a drillship application in 5,800 ft of
use in the North Sea. Additional testing water with a seafloor temperature of 38°F.
will be required for North Sea approval Approximately 23 wt% NaCl was the pri-
of GHP2. mary gas-hydrate inhibitor, with 10 vol%
These new inhibitors can be used to for- GHP1 providing additional hydrate sup-
mulate gas-hydrate pills, concentrated high- pression. Shale stability and cutting encap-
ly inhibitive formulas that can be placed in sulation were provided by partially
the blowout-preventer stack and the choke hydrolyzed polyacrylamide while polyan-
and kill lines. Pills are used when a gas kick ionic cellulose and derivatized polysac-
is encountered during drilling operations or charide provided fluid-loss control. This
when the drilling location is temporarily formula resulted in a gas-hydrate suppres-
abandoned because of severe weather. A sion of 42°F. The well was drilled with no
common practice in deepwater drilling fluid-related problems, and the fluid prop-
operations is to add 30 vol% GHP1 or GHP2 erties remained stable.
to the base fluid used to drill the well.
CONCLUSIONS
FIELD APPLIC ATIONS 1. A new type of water-soluble, organic
Offshore Norway. The first application of gas-hydrate inhibitor was developed.
GHP1 was in a drilling-fluid system on a 2. The new additives allow the design of
semisubmersible offshore Norway. The relatively-low-density fluids with a high
operator wanted a drilling fluid that would level of gas-hydrate suppression.
inhibit gas-hydrate formation at 32°F in 3. The new additives are compatible
2,900 ft of water. The fluid for this well was with most common water-based drilling-
designed with NaCl and GHP1 as the pri- fluid additives.
mary gas-hydrate inhibitors. A small
amount of potassium chloride and a cloud-
point glycol were used for enhanced shale Please read the full-length paper for
stability. This formula resulted in gas- additional detail, illustrations, and ref-
hydrate suppression of 40°F compared with erences. The paper from which the syn-
fresh water. Gas-hydrate suppression is the opsis has been taken has not been peer
difference between the hydrate-equilibrium reviewed.

54 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

ANAEROBIC BIODEGRADABILITY
OF OIL-BASED FLUID FOR
INVERT-EMULSION DRILLING FLUIDS
Oil-based muds have practical and economic chemicals on the basis of measurement of Anaerobically digested sludge was col-
advantages over water-based muds for deep the end products of methanogenic fermenta- lected from a wastewater-treatment plant.
and directionally drilled wells where torque- tion, methane (CH4) and CO2. Exposure to oxygen was minimized during
and-drag problems exist. In 1997, the maxi- Anaerobic degradation of organic sub- collection, handling, and storage. Samples
mum allowable oil content on cuttings for stances also can be studied by conversion to were collected in 250-mL penicillin vials
North Sea locations was reduced from 10 to 1 volatile fatty acids (acidogenesis) that is anal- previously flushed with nitrogen. Four dif-
wt%. Nontoxic substitute fluids were designed ogous to methanogenic fermentation. Short- ferent batches of inoculum were used. The
to comply with environmental legislation. chain organic acids ultimately are degraded samples were enclosed in an air-tight con-
Different synthetic-based muds were pro- by different bacterial groups. If a compound tainer and incubated at 30°C for 7 days to
posed. These fluids use low-toxicity mineral is degraded into volatile fatty acids, it should convert the organic carbon. Dissolved inor-
oils, poly- or mono-α-olefins, acetals, or esters be considered as biodegradable because ganic carbon from decomposition of organ-
to replace oil as the base fluid. Controversial volatile fatty acids are easily biodegradable. ic carbon was eliminated by centrifugation.
data exist about the biodegradability of these Monitoring intermediate-fatty-acid produc- These samples were used for Series 3 and 4
fluids under aerobic and anaerobic conditions. tion can be important for determination of tests. For Series 1 and 2 tests, the inoculum
Determination of potential hazards associated fatty-acid oxidation efficiency. Acidogenic was washed before use with an oxygen-free,
with the discharge of chemicals into subter- fermentation has been considered a good salted minimum medium and separated by
ranean or marine environments requires reli- alternative to methanogenic fermentation on centrifugation to eliminate the remaining
able methods for predicting the biodegradabil- the basis of studies applied to polymeric dissolved inorganic carbon further. Series 1
ity of these chemicals. materials, such as polyhydroxybutyrate. and 2 preparation corresponds to ECETOC
While information on toxicity and aerobic Procedures used to determine degradation Technical Report No. 28 specified proce-
biodegradation is obtained easily, anaerobic in other reduction/oxidation (redox) condi- dures. All test phases were performed in an
biodegradation is more difficult to deter- tions (sulfate- and nitrate-reducing condi- anaerobic chamber. Nine mL of anaerobic
mine. The most direct approach for tions) involve consumption of stoichiomet- centrifuged sludge was added to 89 mL of
biodegradability studies consists of measure- ric amounts of sulfate or nitrate from the oxygen-free, salted minimum medium. A
ment of substrate disappearance as a func- same type of incubation conditions as for precise amount of the test component was
tion of time. While this approach requires methanogenesis. These redox conditions are added before the vials were sealed. Controls
analytical techniques, it deals only with pri- found in different anoxic environments. (without inoculum) and reference com-
mary biodegradation. It needs to be associat- Extrapolation of potential biodegradation pound (fructose) were prepared in the same
ed with a method for measuring ultimate from one environment to another has not manner. Sufficient head space was available
biodegradation because contaminants ini- been examined in detail. Because marine for produced gases. Compounds tested were
tially transformed under anaerobic condi- sediment usually contains sulfate, evaluation 15 mg oleic acid ester, 15 mg α-olefin, and
tions may not be metabolized further. Until of biodegradation potential in a marine envi- 20 mg fructose. The vials were shaken gen-
recently, no standard test was available to ronment probably is more reliable when a tly once a week to enhance the contact
determine the ultimate anaerobic biodegrad- method based on sulfate reduction is used. A between flocculent-forming bacteria and
ability of organic compounds. One test study of potential biodegradation of different insoluble substrate. Dried-suspended-solids
method described by the European Center inocula originating from different environ- concentration (flocculent-forming bacteria)
for Ecotoxicology and Toxicology of ments, including marine sediments, suggest- in the test vials was 3.2 g/L. Head-space
Chemicals (ECETOC) was used in several ed that biodegradation potential may be pressure was measured once a week by use
studies.1 This screening test uses an anaero- extrapolated from one environment to of a differential-pressure transducer.
bic inoculum from a sewage-treatment plant another if an active methanogenic microbial
and evaluates the ultimate biodegradation of community is present in the environment. Gas-Phase Analysis. CO2, CH4, and N2 were
quantified by use of a chromatograph
This article is a synopsis of paper SPE EXPERIMENTAL equipped with a thermal-conductivity detector.
39386, “Anaerobic Biodegradability of The test procedure is based on ECETOC’s test
Oil-Base Fluid for Invert-Emulsion method1 and determines the biodegradability Ester Analysis. Residual ester was extract-
Drilling Fluids,” by D. Blanchet, A. of products under aqueous anaerobic condi- ed from the sample by toluene containing
Audibert, SPE, and J-F. Argillier, SPE, tions in batch fermentation. Biogas produc- arachidic acid as an internal standard.
Inst. Français du Pétrole, originally pre- tion resulting from degradation of chemical Fatty-acid composition of the oleic acid
sented at the 1998 IADC/SPE Drilling substrates in anaerobic conditions is quanti- ester or the residual ester was analyzed by
Conference, Dallas, 3–5 March. fied by measuring the pressure increase. use of gas chromatography.

56 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

RESULTS tent of the compound tested. Ultimate the parent molecules. Methyl ester
Head-Space Evolution. Figs. 3 to 6 in the biodegradation percentage for the oleic acid hydrolytic activity can occur in acetogens
full-length paper show evolution of degra- ester on the basis of net CO2 and CH4 pro- such as Acetobacterium woodi and
dation in percentage of conversion to CH4 duction was 45, 100, and 82% for Series 1, Eubacterium limosum.
and CO2. The amount of tested compound 3, and 4, respectively.
transformed into gaseous one-carbon CONCLUSIONS
products was determined from the increase DISCUSSION 1. The inoculum pretreatment strongly
in pressure in the vials. Comparison of CH4 is the main product of biodegradation affects its potential for the final mineralization.
Series 3 and 4 tests with Series 1 and 2 tests of the ester, and complete biodegradation of 2. The gas-composition change for the
shows the effect of the washing step on the the ester was observed. The corresponding oleic acid ester corresponded to an 80 to
potential of the inoculum for mineraliza- fatty acids of the initial esters disappear, 100% biodegradation for the untreated
tion. More degradation of fructose and and no short-chain fatty acids were detect- inoculum. Total primary biodegradation was
oleic acid ester was observed when the ed. This result is consistent with the anaer- achieved with no accumulation of fatty acids.
inoculum was used without washing. obic biodegradability of natural fats and 3. The α-olefin had low pressure evolu-
lipids. The ester bond of those molecules is tion and low CH4 production, confirming
Head-Space Composition. The amount of split easily by hydrolytic enzymes (hydro- the poor anaerobic biodegradability of this
CO2 and CH4 produced by biodegradation lases) during the first step of the anaerobic- type of compound.
of carbon sources tested is determined from degradation process. The resulting primary
pressure and gas-phase composition in degradation products, fatty acids and alco- REFERENCE
both the control and chemical tests. Table 1 hol, correspond to an excellent substrate 1. Evaluation of Anaerobic Biodegradation,
in the full-length paper shows the percent- for the consecutive fermentation by Technical Report No. 28, ECETOC, Brussels,
ages of CO2 and CH4 in the gas phase of the acidogenic and acetogenic microorganisms. Belgium, (June 1988).
test vials at the end of the biodegradation The easy biodegradation of short-chain
test. CH4 is the main degradation product. fatty acids is well documented in the litera-
ture. It has been demonstrated that several Please read the full-length paper for
Carbon Conversion. The maximum CH4 methyl carboxylates were completely min- additional detail, illustrations, and ref-
and CO2 production theoretically obtain- eralized by aquifer microorganisms under erences. The paper from which the syn-
able from an organic chemical can be cal- methanogenic conditions, presumably opsis has been taken has not been peer
culated from the carbon and oxygen con- through the initial hydrolytic cleavage of reviewed.

• NOVEMBER 1998 57
D R I L L I N G A N D C O M P L E T I O N F L U I D S

INVESTIGATION OF
FORMATION-DAMAGE CONTROL
OF METHYLGLUCOSIDE FLUIDS
Invasion of mud solids and filtrate into the the MEG monomers in the base fluid are all three other drilling fluids. These cores were
formation during drilling can impair rock dissolved in the water. MEG is nontoxic 2.54 cm in diameter and 5 cm long.
permeability around the wellbore. Control and readily biodegradable. Thermographic
of formation damage caused by drilling flu- analysis showed that a 70-wt% solution of Fluids. Clear brine (CB), mixed-metal
ids is recognized as good drilling practice. MEG is stable at 177° C. hydroxide (MMH), and amphionic poly-
Use of muds with improved filtration-con- mer (AP) fluids were used for comparison.
trol characteristics provides an efficient EXPERIMENTAL One kind of bridging material was used.
method of limiting the extent of damage. Core-flow tests were conducted with an Both the MEG fluid and CB are clay-free,
Drilling muds should form an impermeable improved apparatus manufactured at Beijing and their rheological properties were con-
mudcake quickly to reduce spurt loss and U. of Petroleum that can measure the trolled by use of xanthan gum. Both the
cake thickness. If the filtrate is compatible amount of fluids that invade the core as well MMH and AP fluids contain 40 g of ben-
with formation rocks and fluids, the filtrate as measuring permeability. Other experi- tonite in 1 L of water. Table 2 in the full-
is backflushed easily and the extent of for- mental equipment included the following. length paper gives the composition of the
mation damage is reduced effectively. • Rotational viscometer. four drilling fluids, while Table 4 in the full-
Methylglucoside (MEG) fluid is a recently • American Petroleum Inst. (API) filter length paper shows their rheological and
developed, environmentally acceptable press. filtration-control properties.
water-based mud (WBM) whose perfor- • NP-01 swellmeter.
mance approaches that of oil-based muds. • Coulter LS130 particle-size-distribu- Permeability-Recovery Tests. High-
Previous investigations have shown that tion analyzer. Permeability Cores. Permeability-recovery
fluids containing MEG stabilize shale and • Scanning electron microscope (SEM). tests for high-permeability cores were per-
have superior lubrication and filtration- • Surface and interfacial tensionmeters. formed according to conventional core-flow-
control properties. test procedures. Core samples were dried in
Core Samples. High- and low-permeability an oven at 66°C for 24 hours, then their per-
PHYSIC AL AND CHEMIC AL sandstone cores cut from two sandstone meability to nitrogen was measured. Core
PROPERTIES blocks with approximately the same clay samples with approximately the same perme-
MEG is a chemical derivative of glucose content were used to evaluate formation- ability were selected for further tests. After the
and is manufactured from corn starch. damage characteristics of MEG fluids and cores were vacuum saturated with brine for
MEG has a two-tiered cyclic structure con- 24 hours, permeability to brine was deter-
taining four hydroxyl groups and one mined. The brine in the cores was displaced
methyl unit (Fig. 1). The presence of the with 10 pore volumes of kerosene, and their
methyl unit imparts temperature stability, initial effective permeability to kerosene was
low viscosity, and resistance to bacteria. measured. The cores were exposed to mud
The hydroxyl groups may account for the under a differential pressure of 3.5 MPa for 4
unique ability to form a semipermeable hours. During the contamination process, fil-
membrane on shale surfaces. MEG fluid trate displaced from the cores was measured
used in this study is an aqueous solution by use of an electronic mass balance, which
containing 60 to 70 wt% MEG. It includes allowed the depth of filtrate invasion to be cal-
approximately equal portions of the alpha culated. To determine return permeability, the
and beta forms of MEG monomers. The cores were removed from the Hassler holder
specific gravity of the base fluid is 1.2, and and the mudcake removed and then they
were backflushed with kerosene until the per-
This article is a synopsis of paper SPE meability did not change. Approximately 1
39442, “Investigation on Formation- cm was cut from the contaminated sides, and
Damage Control of the Methylglucoside sectional return permeability of the core
Fluids,” by Yan Zhang, SPE, Zhu Chen, remainders was determined.
and Jienian Yan, SPE, U. of Petroleum, Low-Permeability Cores. After the cores
Beijing, originally presented at the were vacuum saturated with brine for 24
1998 SPE International Symposium on hours, the nitrogen permeability of the
Formation Damage Control, Lafayette, Fig. 1—MEG structures.
cores was measured. The cores were
Louisiana, 18–19 February. exposed to mud under a 3.5-MPa differen-

58 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

High-permeability core
Percentage of return permeability (%)

High-permeability core

Percentage of return permeability (%)


Low-permeability core
Low-permeability core

Fig. 2—Permeability-recovery-test results. Fig. 3—Filtrate-immersion-test results.

tial pressure for 4 hours. The return perme- then the cuttings were recovered on a 40- third of the median pore size of the forma-
ability as well as segment return permeabil- mesh screen. tion. Because of its particle-size distribu-
ity of core remainders was measured with tion, MEG can function as a bridging
nitrogen. Procedures for the low-perme- RESULTS AND DISCUSSION material for most formations. Because of
ability cores were designed to simulate gas- Permeability Recovery. Fig. 2 shows the the presence of the hydroxyl groups, the
reservoir conditions. results of the permeability-recovery tests particles can be adsorbed onto the bore-
for high- and low-permeability cores. MEG hole surfaces and seal the pore so that a
Mechanism Investigation. Filtrate fluid caused less formation damage with an tight mudcake can build up on the bore-
Immersion Tests. Filtrate immersion tests 88.7% permeability recovery. Results indi- hole surfaces.
were performed on both high- and low-per- cate that mudcake formed by MEG fluid is Cake-Texture Imaging. MEG fluid has
meability cores with four fluid filtrates to tight and has a very low permeability, excellent filtration control as indicated by
determine whether the filtrate that invades enabling it to resist filtrate invasion effec- the lowest API filtration rate and spurt
the formation can be backflushed easily tively. The sectional-return-permeability loss. A study of cake textures confirms
from formation pores. Filtrate retention in results showed that the depth of invasion of that a less permeable filter cake is formed
pores is a potential source of formation solid particles into the core is less than 1 cm quickly by MEG fluids. SEM imaging of
damage, especially in a low-permeability for MEG fluid. Fig. 2 also shows that return the surface and cross-sectional area of
formation with a low pore pressure. The permeability of low-permeability cores was mudcakes demonstrates its unique mud-
cores were immersed for 10 minutes, then generally lower than that for high-perme- cake structure. The images show a tight
backflushed with nitrogen until the return ability cores, indicating that damage caused mudcake, possibly attributable to the
permeability changed very little. by filtrate retention is more serious for low- strong linkage between the cyclic struc-
Differential pressure was 0.05 MPa for permeability cores. ture of MEG caused by the hydrogen-
high-permeability cores and 1.5 MPa for bond attraction.
low-permeability cores during backflush. Mechanism of Formation-Damage
Surface- and Interfacial-Tension Measure- Control. Filtrate Immersion Tests. Fig. 3 CONCLUSIONS
ments. Interfacial tension between kerosene shows the results of filtrate immersion tests 1. MEG fluid is superior in formation-
and fluid filtrates was measured by use of the for high- and low-permeability cores. damage control for both high- and low-per-
drop-weight method. All measurements were Damage caused by filtrate retention in meability cores and has better filtration-
performed at ambient temperature. pores is much greater in low-permeability control properties compared with conven-
Particle-Size Distribution. A laser-scat- cores. MEG fluid caused the least filtrate- tional WBM’s.
tering particle-size-distribution analyzer retention damage. Damage caused by 2. MEG fluid forms a low-permeability,
was used to determine particle-size distrib- MEG-fluid filtrate is minimized because of consolidated filter cake rapidly without
ution. The MEG base fluid was diluted, agi- its molecular structure. The hydrated MEG addition of a bridging agent.
tated, and circulated continuously through monomer seems to penetrate the exposed 3. Particle-size-distribution analysis on
the measuring cell until the particle-size pore spaces where the hydroxyls adsorb MEG base fluid shows that insoluble parti-
distribution was measured. Sample volume onto the clay surfaces. In the process of cles in MEG fluid can function as a bridg-
was approximately 1 to 2 L. adsorption, water is displaced from the sur- ing material.
Cake-Texture Imaging. Cake texture of face and ordered structures of MEG are 4. MEG fluid’s low surface and interfacial
the muds was studied by use of an SEM. formed while the water solvent remains free tension reduces damage caused by filtrate
Surface and cross-sectional area of the to move. The adsorption of hydroxyls not retention in formation pores.
mudcake were imaged with the pretreated only reduces filtrate retention in formation 5. MEG fluid is an excellent shale
cake samples. pores but also prevents wetting and clay- inhibitor.
Shale Rolling Tests. Shale inhibitive particle migration.
properties of MEG fluid were evaluated Particle-Size Distribution. Particle Please read the full-length paper for
by hot-rolling dispersion tests with diameters range from 0.1 to 40 µm. Mean additional detail, illustrations, and ref-
shales. Tests began by adding 50 g of dried particle diameter is 9.3 µm, and median erences. The paper from which the syn-
shale cuttings to the four fluids. Samples diameter is 7.4 µm. According to common opsis has been taken has not been peer
then were hot-rolled at 66°C for 16 hours, practice, bridging material should be one- reviewed.

• NOVEMBER 1998 59
D R I L L I N G A N D C O M P L E T I O N F L U I D S

PREVENTING FORMATION
DAMAGE CAUSED BY HIGH-DENSITY
COMPLETION-FLUID/CRUDE-OIL EMULSIONS
Recent laboratory work and field case his- • Efficiently removed from the brine by out of others. Some solvent/surfactant com-
tories identified emulsions that reduced the reclamation process. binations were miscible at ambient tempera-
well productivity after gravel packing cer- • Effective at low concentration and with ture but precipitated out at elevated temper-
tain oil-producing wells in the Gulf of minimal need for mutual solvent. atures. Through trial and error, solvent/sur-
Mexico (GOM). Laboratory investigation • Easily handled on the rig without envi- factant combinations were identified as solu-
identified the emulsifying agent as the cal- ronmental or health and safety concerns. ble or highly dispersible in all brines tested.
cium chloride (CaCl2)/calcium bromide As these formulas were identified, these sim-
(CaBr2) completion fluid used in the grav- DEVELOPMENT OF ple ingredients were blended into more com-
el-pack pumping procedure. Remedial pro- SURFACTANT FORMUL A plex combinations and tested as emulsion
cedures were performed to remove the A nonemulsifier effective in preventing emul- preventers on various GOM crude oils.
damage. Succeeding oil wells were evaluat- sions in a wide variety of oils is necessarily a Several compounds were found to be effec-
ed for completion-fluid/crude-oil compati- heterogeneous mixture comprising nonionic tive in preventing emulsions in some oils but
bility before performing a gravel pack. A and ionic, oil- and water-soluble surface- were only partially effective or completely
nonemulsifier surfactant from the pumping active agents. Combining surfactants with dif- ineffective in others. After a series of labora-
company’s acid-additive product line was ferent solubility characteristics requires tory tests, compounds were formulated that
effective in preventing emulsions when blending them in a hydrotropic solvent or were highly soluble in all brines and effective
added at high concentrations in combina- cosolvent base. Development of a nonemulsi- in preventing emulsions in most oils tested.
tion with a mutual solvent. The recom- fier for high-density completion fluids is com- Brines treated with these compounds then
mended additive package was used in a plicated by the salt saturation of the brines were filtered through a sandpack and tested
gravel-pack operation in the Eugene Island and the highly structured nature of the diva- for emulsion tendency. Several of the com-
field, but because of the high concentration lent-cation/water-hydration complex. Many pounds adsorbed onto the surface of the
of surfactant and mutual solvent in the surface-active agents normally used in non- sandpack material and were not effective in
CaCl2/CaBr2 completion fluid, the fluid emulsifier or demulsifier formulas are insolu- emulsion prevention after filtering. The
could not be reused. Disposal was neces- ble in saturated salt brines and precipitate out ingredients in the compounds that did not
sary because the completion-fluid company immediately after addition. If the nonemulsi- adsorb were recombined into new formulas
believed that the treated brine could not be fier is not highly soluble in the brine, it will be and tested until finished products were pro-
reconditioned economically. In addition, unable to prevent emulsion at every point of duced. Two different formulas were required.
rig personnel reported that the fluid was contact between the brine and the crude oil. If One combination of solvents/surfactants was
difficult to handle on the platform because it is only minimally soluble or dispersible, it is effective in CaCl2 and CaCl2/CaBr2 brines,
of strong fumes from the return pits. These likely to adsorb onto the surface of the forma- and a different combination was required for
issues led to a search for an additive system tion and be unable to prevent emulsions from brines containing ZnBr2.
that met the following performance criteria. forming as the brine is recovered.
• Effective in preventing crude-oil/com- Typical surface-active products are more TESTING
pletion-fluid emulsions in the wellbore soluble in lower-density and noncalcium- Surfactant Solubility. During nonemulsion
and formation. based brines. Very few are miscible in high- testing, it became apparent that the surfactants
• Effective in high-density brines. density two- and three-salt brines. A number must be formulated for solubility in the brines
of solvent and cosolvent packages thought as well as for nonemulsion effectiveness. To
This article is a synopsis of paper SPE suitable as a carrying base for the complete determine solubility of the surfactant blends,
39444, “Eliminate Formation Damage nonemulsifier package were screened. After the surfactants were added to the brine at
Caused by High-Density Completion- identifying several brine-soluble solvent/ room temperature, allowed to stand overnight,
Fluid/Crude-Oil Emulsion,” by William E. cosolvent base fluids, surface-active agents and then heated to 150 to 190°F for an addi-
Foxenberg, SPE, Osca Inc.; Syed A. Ali, were added to the solvent packages and tional 24 hours. The solutions were inspected
SPE, Chevron U.S.A. Production Co.; screened for solubility in high-density brine. for homogeneity after the 24-hour period. In
Minglie Ke, SPE, Osca Inc.; David C. The high-density brines included saturated some cases, the effect of surfactant on surface
Shelby, SPE, Chevron U.S.A. Production or nearly saturated solutions of pure CaCl2; tension of the brine was tested before and after
Co.; and J.W. Burman, SPE, Newfield mixtures of CaCl2 and CaBr2; pure CaBr2; filtration through the sandpack (Fig. 1).
Exploration Co., originally presented at and a mixture of CaCl2, CaBr2, and zinc bro-
the 1998 SPE International Symposium mide (ZnBr2). A number of solvent/surfac- Fluid Compatibility. Representative sam-
on Formation Damage Control, tant combinations were found to be miscible ples of crude oil were collected from pro-
Lafayette, Louisiana, 18–19 February. in some high-density brines but precipitated ducing wells in the GOM. Brines composed

60 NOVEMBER 1998 •
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lbm/gal completion fluid was treated with 1


vol% of Surfactant F. After perforating the
well, the 16.2-lbm/gal fluid was unable to
control formation pressure. During the next 3
days, the well was circulated and the inflow of
oil into the wellbore continued. The fluid
density was increased to 16.4 lbm/gal, and the
wellbore was circulated clean and contami-
nated returns were isolated. A total of 800 bbl
of completion fluid was commingled with
crude oil under high-shear conditions down-
hole and was emulsified when it reached the
surface. After addition of a small amount of
Fig. 1—Effect of sandpack filtration on surface tension, 15.6-lbm/gal surfactant, approximately 70% of the brine
CaCl2/CaBr2/ZnBr2.
broke out of the emulsion and was recovered
and returned to the active system.
of simple salts, such as KCl, NaCl, and samples indicated a tight water-in-oil emul-
potassium formate (KHCO2), were tested in sion. Timing of the operation precluded use DISCUSSION
addition to the high-density brines of CaCl2, of a surfactant blend specifically designed for Solubility of the solvent/surfactant blend in
CaBr2, and ZnBr2. Standard nonemulsion the calcium-based high-density brine. On brine was a critical factor for ensuring that it
tests were performed first with a procedure the basis of previous laboratory work and is still in solution after the brine is slurried
used routinely to test compatibility between field application, a combination of mutual with the sandpack material and then fil-
acidizing solutions and crude oils. Equal vol- solvent, ethylene glycol monobutylether tered. Some surfactant blends that separated
umes of crude oil and high-density brine are (EGMBE), and Surfactant B was tested in the out of solution with time or temperature
mixed under low-shear conditions in a glass laboratory. A mixture of 1 vol% EGMBE and would redisperse on stirring. Other surfac-
jar and allowed to stand at bottomhole tem- 1 vol% Surfactant B was required to pass the tant blends were soluble and effective in the
perature. Compatibility between crude oil sandpack filtration test. Although this high brine before filtration but were completely
and completion fluid is defined by a 95% concentration of solvent and surfactant or partially stripped from solution by filtra-
phase separation within 30 minutes. In addi- might preclude reclamation of the brine and tion. Surfactants that were soluble and effec-
tion, wettability of the brine was evaluated. require disposal, the decision was made that tive in CaCl2 and CaBr2 were not soluble or
compatibility of the oil and brine was the effective in zinc-based brine. Surfactant sys-
Filtration Test. The standard nonemulsion most important consideration. The 13.8- tems effective in ZnBr2 brines were not
test was followed by a sandpack filtration lbm/gal completion fluid was treated with effective in calcium-based brines. Solubility
test in which brine containing surfactant the surfactant and mutual solvent, and the characteristics of typical nonemulsifiers
was filtered through a sand/clay filter pack, job was performed successfully. No indica- were found to be quite different when these
then tested for compatibility with the crude tion of emulsion damage was observed dur- surfactants were added to a high-density
oil. This filtration procedure was designed ing the operation or on flowing the well. brine. Although surfactants can prevent
to simulate the stripping of the surfactant as After the successful gravel-pack opera- crude-oil/brine emulsions, solubility in the
the brine penetrates the formation. Brine tion, a new solvent/surfactant package was brine is required for the surfactant to be
was added to the pack material in a beaker formulated that was much more effective effective after the brine has penetrated some
and mixed with a stirring rod for 1 minute. than the one with 2 vol% additives. In labo- distance into the formation.
The brine system was filtered under vacuum ratory tests, the new system produced short-
and the filtrate collected. The filtrate then er emulsion breakout times and better phase CONCLUSIONS
was tested for compatibility with crude oil. distinction. The next high-density brine 1. Surfactant systems are available that
gravel pack was treated with this new sys- prevent crude oil and brines from forming
Results. Several GOM crude oils are incom- tem, and results indicated that the new sys- emulsions.
patible with completion fluids with densi- tem was as effective as the earlier system, 2. Surfactants must be formulated specif-
ties greater than approximately 12 lbm/gal. and returned fluid was reclaimed easily. ically for solubility and efficacy in the brine
Brines containing Na or K salts did not system for which they are intended.
show significant evidence of emulsification Vermilion Block 398. An oil-producing well 3. High-density brines should be tested by
potential, nor did the low-density CaCl2 in Vermilion Block 398 was scheduled for a use of the slurry/sandpack filtration method
brines. The test results indicate that not all gravel-pack completion. A 16.2-lbm/gal for compatibility with formation crude oils
brines or crude oils are susceptible to emul- CaCl2/CaBr2 fluid was required to control for- before application in the field.
sion formation and that compatibility test- mation pressure. The completion fluid was
ing should be performed whenever possible. tested for compatibility with the formation
oil. The Vermilion oil produced an emulsion
C A SE HISTORIES that brokeout from surfactant-treated comple-
South Timbalier. A 13.8-lbm/gal tion fluid very slowly even before filtration Please read the full-length paper for
CaCl2/CaBr2 brine was scheduled as the through the sandpack. The emulsion never additional detail, illustrations, and ref-
completion fluid for a gravel-pack operation. completely broke out after filtration with as erences. The paper from which the syn-
Laboratory compatibility tests with repre- much as 1.5 vol% Surfactant F and 1.25 vol% opsis has been taken has not been peer
sentative crude-oil and completion-fluid EGMBE. During the completion, the 16.2- reviewed.

• NOVEMBER 1998 61
D R I L L I N G A N D C O M P L E T I O N F L U I D S

EVOLUTIONARY ENVIRONMENTAL
MANAGEMENT OF DRILLING DISCHARGES
In most areas of the North Sea, drilling with technology contributed to better environmen- Mud Volume. Use of biodegradable syn-
invert-emulsion drilling fluids has dramati- tal performance. thetics in drilling fluids was introduced in
cally improved drilling efficiency. Un- the North Sea in an attempt to overcome
fortunately, the discharge of drilled cuttings EVOLUTION problems inherent in the discharge of oil-
coated with invert fluids has had detri- Invert-Emulsion Mud. The introduction contaminated cuttings. The cost of the
mental environmental effects on the seabed. and widespread use of invert-emulsion synthetics was much higher than that of
Over the last 20 years, invert drilling fluids muds in the North Sea was driven by cost. oil, and the unit cost focused attention
have evolved from diesel- to synthetic-based In many applications, available water-based quickly on the volume of mud discharged.
fluids, and discharge of cuttings-associated muds (WBM’s) did not perform satisfactori- Personnel were added to the offshore team
fluids has been reduced significantly. Invert ly, causing higher-than-anticipated drilling to track and identify mud volumes lost at
drilling fluids used today are synthetic- costs and long delays in bringing on pro- different phases of the operation. This led
based fluids that have a very low toxicity in duction. As early as 1977, the spud-to-com- to a better understanding of the impor-
the marine environment, are biodegradable, pletion time of wells on one platform was tance and impact of various equipment on
and provide a good working environment. reduced by more than one-half by intro- the rig. Analysis centered attention on
Cuttings discharged into the sea today aver- duction of invert-emulsion drilling fluid. In reducing the losses attributable to the
age less than 5 g synthetic fluid/100 g dry 1988, a study in Norway indicated that solids-control equipment. Well plans were
cuttings compared with greater than 15 g wells drilled with WBM cost 30% more reviewed and modified to reduce the
diesel-based fluid/100 g dry cuttings in ear- than equivalent wells drilled with invert- volume and amount of hole drilled
lier days. Cuttings piles associated with emulsion fluids. The need for the drilling- while still ensuring technical success.
these earlier discharges contained large performance characteristics of oil-based Modifications to the well plan included
quantities of hydrocarbons. The reduction muds (OBM’s) caused improvements in the the following.
in fluid discharged with cuttings and in tox- environmental performance of discharges • Set the 20-in. shoe deeper than normal.
icity and the absence of cuttings beds were of these fluids. Drilling discharges were • Drill a 16-in. hole instead of a 171/2-in.
accomplished without significant increase reduced not by a revolution of technology hole.
in related costs. or philosophy but by a gradual evolution of • Redesign casing strings so that a
Legislation was a major driver in the reduc- techniques and best practices. 171/2-in. hole is not necessary.
tion in oil-contaminated cuttings discharged • Use sacrificial mud to recover mud
into the sea. When legislation limited oil on Cuttings Injection. One of the earliest suc- that otherwise would have been left
cuttings to 1 g/100 g dry cuttings, alternatives cesses was injection of drilled cuttings at the behind the casing.
to conventional wash and discharge had to be Valhall platform in Norway. To meet the These efforts significantly reduced total
found. Cuttings injection, transportation and strict Norwegian discharge requirements mud consumption and mud cost for syn-
discharge of cuttings, and use of synthetic and an announced ban of OBM, a range of thetic fluid to a level comparable with
drilling fluids all played a role in compliance alternative solutions was investigated, that for OBM’s.
with this requirement. Low-toxicity base oils including alternative mud systems, onboard
replaced diesel and, in turn, were replaced by processing by use of a rotary kiln, and trans- Cuttings Dispersion. On one well drilled
low-toxicity, biodegradable synthetic fluids. portation of cuttings to shore. The method in an environmentally sensitive area in
Improvements in solids-separation equip- selected to meet discharge requirements was West of Shetland field, it was agreed (after
ment decreased oil on cuttings. Innovative slurrification of cuttings and injection into a consulting with appropriate government
new techniques, such as cuttings injection disposal well. This method had the advan- agencies) that synthetic-based drilling flu-
and cuttings processing, reduced the total tages of lowest overall energy consumption; ids would be used and the cuttings slurried
amount of cuttings discharged. Each piece of no sulfur or combustible-gas emissions; before discharge overboard. Slurrying the
lowest cost, liability, and safety hazard; and cuttings promotes their dispersion, pre-
This article is a synopsis of paper SPE best reliability. The cuttings-injection sys- vents formation of a cuttings pile, and pro-
46617, “Evolutionary Environmental tem has been in regular use for cuttings and motes faster degradation of the synthetic
Management of Drilling Discharges: other oil-contaminated wastes since fall fluid. A remotely operated vehicle from the
Results Without Cost Penalty,” by G. 1991. Halting discharges of oil-contaminat- rig and a time-lapse camera placed down-
Hanni, SPE, J. Hartley, R. Munro, and ed cuttings has resulted in significant recov- stream of the rig monitored the seabed
A. Skullerud, Amoco, originally pre- ery of the seabed fauna around the platform. before, during, and after drilling. These
sented at the 1998 SPE International When surveyed in 1996, the area that shows inspections and subsequent seabed sam-
Conference on Health, Safety and even a very minor disturbance of the benth- pling confirmed the absence of cuttings
Environment in Oil and Gas Exploration ic community was reduced to approximate- accumulation at the seabed and no dis-
and Production, Caracas, 7–10 June. ly 25% of the 1991 area. cernible biological effects.

62 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

Mud-Recovery Unit. In 1996, a new con- to have gone into the sea. This approach ties CONCLUSIONS
cept to reduce the amount of oil or syn- discharges to the sea to cost and has result- A multidisciplinary team environment is
thetic fluid retained on the cuttings was ed in an improvement in performance. critical to successful environmental man-
tested. A mud-recovery unit based on agement. Team members included a
equipment from the coal industry was Transportation to Shore. In 1997, a well drilling-operations team leader, a drilling-
installed downstream of the shakers. This was drilled in the environmentally sensitive fluids specialist, and environmental special-
unit was used on a subsea-development Haltenbanken area offshore Norway. ists to provide support and direction to the
project in the central North Sea with a 400- Discharges of drilled cuttings with OBM or drilling group. Drilling-fluids and equip-
ft/hr drilling rate. This resulted in another synthetics were prohibited by the authori- ment suppliers as well as drilling contrac-
incremental improvement in reduction of ties, limiting drilling-fluid options for this tors were involved in the planning process.
mud discharged with cuttings. well to water-based systems or drilling with A formal, balanced decision-making process
an oil-based system and transporting cut- is another key element of success. Costs,
Material Balance/Inventory Control. Oil tings to shore for processing. The decision technical requirements, and environmental
on cuttings is measured as required by law, was made to use an OBM and a system with effects were all considered in mud selection
but experience has shown that this is not a specially made closed containers for cuttings and waste disposal, and the best acceptable
quantitative measurement. Accurate inven- transportation. A supply vessel was kept risk-weighted option was chosen. Suc-
tory control is an essential part of invoicing, alongside the rig to manage the containers cessful environmental performance would
and a balanced material reconciliation is a while drilling the 121/4-in. hole section. not have been achieved without commit-
required part of the audit process. Amoco Cuttings handling caused no restrictions ment to continuous improvement. Environ-
and their fluid alliance partner adopted a on drilling speed, and the entire hole sec- mental management was integrated into the
system of material balance and inventory tion was drilled in 5 days. Approximately overall management system.
control to establish the quantity and final 120 containers, each containing 7 tons,
disposition of various chemicals, including were collected, and no spillage occurred in
synthetic fluids used in drilling operations. either transportation or handling. Please read the full-length paper for
The amount of fluid purchased minus the Although the cuttings transportation and additional detail, illustrations, and ref-
amount returned is equal to the amount disposal costs were high, the cost of erences. The paper from which the syn-
lost; fluid that cannot be accounted for as drilling the well was much less than would opsis has been taken has not been peer
having been disposed elsewhere is assumed have been possible with a WBM. reviewed.

• NOVEMBER 1998 63
D R I L L I N G A N D C O M P L E T I O N F L U I D S

WELLBORE-STABILITY PREDICTIONS
USING A MODIFIED LADE CRITERION
The two most commonly used rock-failure predict the effect of σ2 much more accu- changes, and defining appropriate stress
criteria in wellbore-stability analyses are the rately than either the Mohr-Coulomb or the invariants I1′ and I3′, we obtain the follow-
Mohr-Coulomb criterion and the Drucker- Drucker-Prager criterion. However, it is ing failure criterion.
Prager criterion.1,2 The literature gives usually difficult to apply these complex cri-
many examples that demonstrate the appli- teria to the wellbore-stability problem. This (I1′)3/I3′ =27+η, . . . . . . . . . . . . . . . . . . (4)
cation of these two criteria to wellbore-sta- is especially true when analyzing the gener-
bility computations. These two failure cri- al deviated-well problem (a well not aligned where
teria represent two extreme treatments of with any principal-stress axis) and when
the intermediate principal stress, σ2. The trying to solve for critical mud weight that I1′=(σ1+S1−pp)+(σ2+S1−pp)+(σ3+S1−pp)
Mohr-Coulomb criterion assumes that σ2 will prevent instability.
has zero influence on rock strength. The full-length paper presents a 3D rock- . . . . . . . . . . . . . . . (5)
Conversely, the Drucker-Prager criterion failure criterion that is a modification of a
(sometimes referred to as a linear extended criterion originally developed by Lade.3 and
von Mises criterion) gives as much weight The criterion proposed has the following
to σ2 as it does to the major and minor prin- desirable qualities: (1) it correctly describes I3′=(σ1+S1−pp)(σ2+S1−pp)(σ3+S1−pp),
cipal stresses, σ1 and σ3, respectively. If the the influence of σ2 on rock strength and
criteria are both fit to the same set of triax- therefore on wellbore stability; (2) it can be . . . . . . . . . . . . . . . (6)
ial-compression-strength data (σ1>σ2=σ3), rearranged to give a closed-form solution
the Drucker-Prager criterion predicts for critical mud weight for any wellbore ori- where S1 and η=material constants and
greater rock strength than the Mohr- entation; and (3) only two rock-strength pp=pore pressure. The full-length paper
Coulomb criterion for all stress states other parameters, such as cohesion and friction contains equations for the invariants I1′ and
than triaxial compression. angle, are required. I3′ for a wellbore coordinate system. The
While it is true that σ2 has a strengthen- parameter S1 is related to the cohesion of
ing effect (which is ignored by the Mohr- MODIFIED L ADE CRITERION the rock, while the parameter η represents
Coulomb criterion), it is not as profound as The Lade criterion for failure of frictional the internal friction. Calculations show that
that predicted by the Drucker-Prager crite- materials is given by these parameters can be derived directly
rion. The Mohr-Coulomb criterion under- from the Mohr-Coulomb cohesion, S0, and
estimates rock strength for general stress (I13/I3−27)(I1/pa)m=η1, . . . . . . . . . . . . (1) friction angle, φ, by
situations (σ1≠σ2≠σ3), but the Drucker-
Prager criterion overestimates rock strength where S1=S0/tan φ . . . . . . . . . . . . . . . . . . . . . . (7)
for these general stress states and is in error
especially under triaxial-extension I 1=σ1+σ2+σ3 . . . . . . . . . . . . . . . . . . . (2) and η=4tan2φ(9−7sin φ)/(1−sin φ), . . (8)
(σ1=σ2>σ3) conditions. When applied to
the wellbore situation (a very general stress and I 3=(σ1)(σ2)(σ3). . . . . . . . . . . . . . . (3) where S0 and φ are determined from triaxi-
state), the Mohr-Coulomb criterion is too al-compression tests.
conservative because it neglects the In Eqs. 1 through 3, σ1, σ2, σ3=the three Fig. 1 shows the relationship between
strengthening effect of σ2. The Drucker- principal stresses, pa=atmospheric pres- the modified Lade, Mohr-Coulomb, and
Prager criterion can be unconservative and sure, and η1 and m=material constants. Drucker-Prager criteria under triaxial-com-
can give unreliable stability predictions To obtain a criterion that predicts linear pression and -extension conditions for
because it overestimates the intermediate- shear-strength increase with increasing I1, S0=500 psi and φ=30°. For triaxial-com-
stress effect. m is set equal to 0. In this form, the crite- pression conditions, the three criteria are
Several researchers have proposed three- rion is similar to that originally proposed the same because they are fit to the same
dimensional (3D) rock-failure criteria that for cohesionless sands. To handle materials triaxial-compression test data. However,
with cohesion or a nonzero tensile Fig. 1 shows that the three criteria predict
strength, Lade proposed that the stress different strength under triaxial-extension
This article is a synopsis of paper SPE axes be shifted into the tensile region by a conditions. The Drucker-Prager criterion
47251, “Wellbore-Stability Predictions dimensionless constant multiplied by pa. predicts that shear strength is the same in
Using a Modified Lade Criterion,” by For the author’s purposes, a shift constant triaxial extension as in triaxial compres-
R.T. Ewy, SPE, Chevron Petroleum with units of cohesion is more applicable sion. Both the modified Lade and Mohr-
Technology Co., originally presented at and is defined as S1. In addition, pore pres- Coulomb criteria predict that shear
the 1998 SPE/ISRM Eurock, Trondheim, sure, pp, must be subtracted to handle strength in triaxial extension is less than in
Norway, 8–10 July. effective stresses. Performing these triaxial compression.

64 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

Shear strength, psi

Major stress, psi


Mean Effective Stress, psi
Intermediate Stress, psi
Fig. 1—Strength predictions under triaxial-compression and -ex-
tension conditions. Fig. 2—Predicted strength.

VALIDATION OF CRITERION σ1 at failure decreases and predicts a triaxial- cylinders of rock. Usually, the samples are
Intermediate-Stress-Effect Experiments. extension strength of σ1=σ2=2,150 psi. For jacketed and subjected to a hydrostatic con-
Under general stress conditions, the modi- nonzero values of σ3, the predicted influence fining pressure that acts both on the outside
fied Lade criterion (as well as the original of σ2 on strength is very similar. Fig. 3, which diameter of the sample and axially on the
Lade criterion) has the desirable property compares the three criteria with S0=500 psi ends of the sample. Sometimes a support
that it first predicts a strengthening effect and φ=30°, shows this. In Fig. 3, the mag- pressure is applied in the model hole, but
from increasing σ2, followed by a slight nitude of σ3 is set equal to 866 psi, which is the hole usually is left empty. In either case,
reduction in strength once σ2 becomes “too exactly one-half the unconfined compressive the magnitude of confining pressure that
high.” This is explained best through the strength of this example rock. results in failure at the hole wall inevitably
illustration in Fig. 2. This figure shows the Several researchers conducted laboratory is several times greater than that predicted
predicted value of σ1 at failure as a function experiments to measure the influence of σ2 on by the Mohr-Coulomb criterion (in con-
of σ2 for a constant value of σ3 equal to rock strength directly; they all found that junction with the stress concentration pre-
zero, where S0=500 psi and φ=30°. increasing σ2 increases the value of σ1 at fail- dicted by linear elasticity). When blocks of
All three criteria predict the same uncon- ure, but only up to a point. With further rock are used to apply nonaxisymmetric
fined compressive strength of 1,732 psi. The increase in σ2, the value of σ1 at failure stresses around the hole, similarly high
Mohr-Coulomb criterion predicts that the decreases slightly, especially as one approach- apparent strengths are observed.
rock fails at σ1=1,732 psi regardless of the es triaxial-extension conditions. The observed Many explanations have been proposed
magnitude of σ2. The Drucker-Prager criteri- effect of σ2 on rock strength is matched very for this apparent strengthening around
on predicts that σ1 at failure increases dra- closely by the modified Lade criterion. The model holes, including size effects, nonlin-
matically with increasing σ2, and it predicts a shape illustrated in Figs. 1 and 2 is a very ear rock behavior, plasticity, nonconstant
triaxial-extension strength of σ1=σ2=5,196 good fit to the experimental observations. moduli, and the strengthening effect of the
psi. The modified Lade criterion predicts that intermediate principal stress. While the
σ1 at failure first increases with increasing σ2 Hollow-Cylinder and Block Experiments. intermediate stress cannot account for all the
up to a maximum strength of σ1=2,525 psi. Many researchers have performed hole-fail- apparent strengthening commonly ob-
With further increases in σ2, it predicts that ure experiments using thick-walled hollow served, it is most likely a major contributor
Major stress, psi

(I1′)3/ I3′

Intermediate Stress, psi Mud Weight, lbm/gal

Fig. 3—Predicted strength. Fig. 4—Stability vs. mud weight.

65 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

to the high strengths observed around model the risk of lost returns. Under certain con- Under general stress states, the Mohr-
holes. For example, when hollow cylinders ditions, there is no solution for a mud Coulomb criterion underestimates strength
are subjected to hydrostatic confining pres- weight that will stabilize the hole complete- while the Drucker-Prager criterion overesti-
sure, the magnitude of stress acting along the ly. This occurs when the minimum point of mates it.
axis of the hole wall is about one-half the the (I1′)3/I3′ vs. mud-weight curve lies above 2. The Lade and modified Lade criteria
magnitude of the stress acting tangentially the value of η+27. The full-length paper correctly account for the influence of σ2
around the hole wall. This is a situation presents example calculations of critical on rock strength and therefore on
where σ2 is approximately one-half σ1. It is mud weight as a function of hole angle, wellbore stability.
apparent from Figs. 2 and 3 that significant rock strength, and in-situ stress. 3. A correct 3D failure criterion, such as
strengthening, relative to the Mohr- the modified Lade criterion, explains some
Coulomb criterion, occurs under such a Application Issues. The closed-form solu- of the apparent strengthening that is com-
stress state. Examination of Figs. 2 and 3 tion for critical mud weight does have limita- monly observed around model holes in
shows that, once σ2 exceeds approximately tions. Similar to the Mohr-Coulomb and the laboratory.
one-half of σ1, any further increase in σ2 will Drucker-Prager criteria, the modified Lade 4. The modified Lade criterion can be
result either in no strength increase or in a criterion predicts linearly increasing shear rearranged to obtain a closed-form solution
small strength decrease. The strengthening strength with increasing mean effective for critical mud weight that is applicable to
effects of the intermediate principal stress stress. The Lade criterion was linearized to all wellbore orientations and in-situ
predicted by the modified Lade criterion are make the equations more tractable for the stress states.
in agreement with observations made on general wellbore problem. The linear nature 5. The modified Lade criterion predicts
model holes. Therefore, this failure criterion of the criterion is not considered to be a prob- critical-mud-weight values that are less
can be applied to wellbore-stability problems lem as long as care is used in its application. conservative than those predicted by the
with confidence. The range of mean effective-stress values that Mohr-Coulomb criterion but not as uncon-
is relevant to a wellbore problem is usually servative as those predicted by the Drucker-
APPLIC ATION TO quite small. Rock-strength data usually can Prager criterion.
WELLBORE STABILITY be fit quite accurately by a straight line over a 6. When the correct influence of σ2 is
Closed-Form Solution for Critical Mud reasonable stress range. The linear form of accounted for, it is found that the required
Weight. The first step in calculating the mud the modified Lade criterion therefore pre- increase in mud weight when going from
weight required to prevent hole instability is sents no loss of accuracy as long as the cohe- low hole angle to high hole angle is not as
to transform the in-situ stresses to the well- sion and friction angle represent the strength great as that predicted by either the Mohr-
bore coordinate system. The equations can over the appropriate stress range. Coulomb or Drucker-Prager criterion.
be found in available references.2 The full- Because it has no tension cutoff, the
length paper presents an equation for critical modified Lade criterion tends to overesti- NOMENCL ATURE
wellbore pressure that can be converted easi- mate tensile strengths and is not accurate I1′= modified first stress invariant,
ly to drilling-fluid density, or mud weight. when tensile stresses are present. This is m/Lt2, psi
These equations use stresses at the wellbore not a problem in wellbore-stability calcula- I3′ = modified third stress invariant,
wall predicted by linear elasticity and can be tions because the locations around the well- m/Lt2, psi
altered to account for nonlinear rock behav- bore that require mud weight for support η= material parameter related to friction
ior. They also assume no communication are not subject to tension. σ3= minor principal stress, m/Lt2, psi
between wellbore pressure and formation The equations are not appropriate for sit-
pore pressure. A derivation is provided in the uations where there is communication REFERENCES
Appendix of the full-length paper. The solu- between wellbore pressure and formation 1. McLean, M.R. and Addis, M.A.: “Wellbore
tion for critical wellbore pressure is the lesser pore pressure, such as underbalanced Stability Analysis: A Review of Current
of the two roots of a quadratic equation. Fig. drilling and overbalanced drilling without Methods of Analysis and Their Field
4 shows the behavior of the dimensionless the presence of a filter cake on the hole Application,” paper SPE 19941 presented at
term (I1′)3/I3′ as a function of mud weight.The wall. Chemical effects in shales also require the 1990 IADC/SPE Drilling Conference,
calculations were performed for a wellbore special mathematical treatment. Houston, 27 February–2 March.
deviated 30° from vertical, and the stresses The critical-mud-weight solution is based 2. McLean, M.R. and Addis, M.A.: “Wellbore
were analyzed at the point of highest tangen- on the stress concentration at the wellbore pre- Stability: The Effect of Strength Criteria on
tial stress around the circumference (the dicted by linear elasticity. In some situations, Mud Weight Recommendations,” paper SPE
sides of the hole). Fig. 4 shows that, for a the wellbore stresses may not be quite as high 20405 presented at the 1990 SPE Annual
mud weight less than approximately 10 as predicted by linear elasticity; this results in Technical Conference and Exhibition,
lbm/gal, (I1′)3/I3′ exceeds the quantity η+27 predicted mud weights that are higher than Houston, 23–26 September.
(the stress is greater than the rock strength) actually necessary. Alternative methods of pre- 3. Lade, P.V.: “Failure Criterion for Frictional
and the hole is unstable. For mud weight dicting the stress concentration at the wellbore Materials,” Mechanics of Engineering Materials,
greater than 10 lbm/gal, the stress is less could be used in conjunction with the modi- C.S. Desai and R.H. Galager (eds.), John Wiley
than the strength and the hole is stable. It is fied Lade criterion to obtain less conservative & Sons, New York City (1984) 385.
apparent from Fig. 4 that a second, higher mud-weight predictions.
mud-weight value exists that satisfies Eq. 4. Please read the full-length paper for
Once mud weight exceeds this upper limit, CONCLUSIONS additional detail, illustrations, and ref-
the wellbore again is theoretically unstable. 1. Neither the Mohr-Coulomb nor erences. The paper from which the syn-
A mud weight greater than 14.4 lbm/gal is Drucker-Prager criterion correctly accounts opsis has been taken has not been peer
not likely to be used in this case because of for the influence of σ2 on rock strength. reviewed.

• NOVEMBER 1998 66
D R I L L I N G A N D C O M P L E T I O N F L U I D S

DENSITY BEHAVIOR OF DRILLING FLUIDS


DURING HP/HT DRILLING
Although a number of high-pressure/high- density with a transient-temperature model process is defined as a constant-volume
temperature (HP/HT) wells have been for circulation-fluid temperatures. This process. Therefore, any pit gains or losses
drilled in Norway in the past 25 years, these enables the model to predict the density are the result of a gain or loss of mass to the
wells still present a drilling challenge. A profile of the well during drilling, mud in the well. The full-length paper con-
considerable amount of time and cost is workover, and well-control operations. tains equations for mud volume, mud-sys-
related to setting the production casing and Appendix A of the full-length paper gives tem mass, and change of mass in surface-
drilling and testing the reservoir. Operating mathematical details of the procedure to volume units.
margins are very small. Borehole stability, evaluate density as a function of pressure
well control, and interpretation of well sig- and temperature. Models that earlier were DENSITY PROFILES
nals are key issues. Measurement-while- considered pure empirical correlations can A field example demonstrates the effect of
drilling tools measure pressure and temper- be derived from this analytical solution by compressibility and transient temperature
ature at bottom and show more variation in expanding the EOS in a Taylor series and on mud density. Assuming a surface densi-
both parameters than thought previously. neglecting second-order and higher terms. ty of 2.04 g/cm3, the EMD at geothermal
Mud temperature is always in a transient conditions is 1.98 g/cm3. Immediately after
state, strongly affected by flow rate. PRESSURE AND circulation starts, EMD increases to 1.99
Determination of effective mud density TEMPERATURE EFFECTS g/cm3 and continues to increase to 2.06
(EMD) is critical to analysis of drilling and As the temperature and pressure of the g/cm3 after 12 hours of circulation. EMD
completion operations. Without knowl- mud column increase with depth, the mud changes more rapidly for high circulation
edge of actual system pressures, preventing experiences two opposing effects. rates and tends to stabilize at a higher
a gas kick or circulation losses in fractured Increases in temperature cause the mud value. EMD usually stabilizes within 12
formations is difficult. EMD is affected density to decrease because of thermal hours’ circulation time
directly by downhole variations in pressure expansion, while increases in pressure Mud density increases as circulation con-
and temperature. cause the mud density to increase because tinues because of continuous cooling of the
of compressibility. For a particular temper- well. For very-high-temperature wells,
COMPARISON WITH ature profile, these two opposing effects changes in EMD caused by temperature
EMPIRIC AL MODELS cancel each other out. This is defined as changes are significant. This effect has been
In the past, models that predicted down- the constant-density temperature profile observed in HP/HT wells that are shut in
hole densities have assumed a linear tem- (CDTP) that results in a constant density after a well-control incident. Changes in
perature distribution. However, during through the depth interval. If the real mud shut-in pressures have been interpreted as a
drilling and completion, this is seldom the temperature is greater than the CDTP, the direct measurement of the reservoir pore
case. In earlier models that present an equa- mud density is less than the surface densi- pressure. In reality, density variation caused
tion of state (EOS) for the downhole densi- ty and thermal expansion is predominant. by temperature changes may change shut-
ty in static drilling fluids, the equations If the temperature is less than the CDTP, in pressure significantly.
were obtained from curve-fitting methods. the mud density would be greater than that
The full-length paper presents the mathe- at surface and the compressibility effect is CONCLUSIONS
matical development and derivation of an predominant. If the CDTP is known, it can 1. This paper describes a mud-density
analytical model for the density/pressure/ be compared with the real temperature model that couples a transient-temperature
temperature dependence of drilling fluids. profile in the well, immediately indicating model with a fluid-density model.
This generalized EOS is valid for oil- and whether thermal expansion or compress- 2. Fluid density calculated by this model
water-based drilling fluids and also for ibility is predominant. includes the effects of compression and
completion fluids. The analytical model thermal expansion.
couples a model for predicting downhole PIT GAINS AND LOSSES 3. Measurement of volume variations in
Return-mud volume varies during drilling, the return mud can provide an estimate of
This article is a synopsis of paper SPE having either a too-low or -high return rate. the effective bottomhole pressure.
47806, “Density Behavior of Drilling This effect often is called ballooning.
Fluids During High-Pressure/High- Because mud density is very temperature
Temperature Drilling,” by Eirik dependent, mud-volume gains or losses
Kårstad, SPE, and Bernt S. Aadnøy, caused by thermal effects may be substan- Please read the full-length paper for
SPE, Stavanger College, originally pre- tial. In contrast to pressure effects, which additional detail, illustrations, and ref-
sented at the 1998 IADC/SPE Asia occur over a short time period, thermal erences. The paper from which the syn-
Pacific Drilling Technology Conference, effects may take hours. Because the volume opsis has been taken has not been peer
Jakarta, 7–9 September. of the well is constant at a given time, the reviewed.

• NOVEMBER 1998 67
D R I L L I N G A N D C O M P L E T I O N F L U I D S

MODELING EFFECTS OF DRILLING-FLUID


TEMPERATURE ON WELLBORE STABILITY
Stresses, pore pressure, wellbore pressure, If a transient temperature field exists in the hole wall were determined by the model
drilling-fluid design, and formation proper- saturated rock, the difference between the coef- and analytical solutions for different times.
ties are among the primary considerations for ficients of thermal expansion of the pore fluid There was good agreement between the
wellbore-stability assessment and develop- and the rock matrix induces changes in pore numerical and analytical solutions.
ment of recommendations to manage insta- pressure and stresses. This can cause thermal-
bility. Drilling-fluid temperature is often dif- induced pore-fluid flow and deformation of THERMOPOROEL A STICITY-MODEL
ferent from formation temperature, which rock around the borehole. Because of its low VALIDATION
results in heat transfer between the two permeability, when a shale formation is heated, Analytical solutions of coupled, linear
media. Changes in volume of the rock matrix the volume expansion of the pore fluid causes heat/fluid/stress diffusion equations for
and pore fluid induced by changes in tem- an increase in pore pressure. Thermal expan- some specific boundary or initial-value
perature depend on the thermal-expansion sion of the rock matrix under constrained con- problems have been derived by various
properties of the rock matrix and pore fluid. ditions results in generation of thermal stress in researchers. However, analytical solutions
These volume changes result in changes in the tangential direction. The reduction of effec- for general initial-value problems of defor-
effective stresses and pore pressure in low- tive mud support associated with the increase mation of poroelastic materials under non-
permeability formations, such as shales, and in pore pressure combined with the increase in isothermal conditions are unavailable. To
can lead to borehole failure. Thermal effects thermal stress results in a less stable wellbore. validate the model, simple numerical
need to be included in prediction of time- Formation cooling decreases the pore pressure experiments were performed to determine
dependent wellbore instability and in mud and tangential stress and causes a more stable whether the induced changes in effective
programs to prevent wellbore instability. wellbore. However, reduction of the tangential stresses, strains, and pore pressure for fully
A numerical thermoporoelasticity model stress leads to a lower hydraulic-fracture gradi- constrained and completely free unit cubes
has been developed that can model the ent, and, in extreme cases, the tangential stress satisfy the equations.
effects of time-dependent changes in stress- can become tensile and initiate a hydraulic
es and pore-fluid pressure on wellbore sta- fracture. The model was integrated with poro- Model Description. A unit cube composed of
bility in shale formations. The thermoporo- elasticity and drilling-fluid/shale interaction a finite element was used in the analyses. In
elasticity model has been validated by com- models to form the time-dependent wellbore- the fully constrained case, all six faces of the
paring model results with analytical solu- stability-analysis software. cube are fixed. A step change in temperature
tions and by simple numerical experiments was assigned to the cube, and the changes in
that use a single finite element to simulate POROEL ASTIC-MODEL VALIDATION effective stresses and pore pressure were com-
a fully saturated cube. Analytical solutions for the case of instanta- puted. The constraints on all the faces were
neous injection in a cylindrical borehole removed later and the cube allowed to deform
THEORETIC AL BA SIS have been derived. The coupled fluid/stress freely. Changes in stresses, strains, and pore
Governing Equations. Because of the low diffusion equations were uncoupled to solve pressure at equilibrium were computed.
permeability of shales, the coefficient of for pore pressure independently of the dis-
thermal diffusivity is several orders of mag- placement field. Loading conditions were Model Results. For a step change of 50°C,
nitude greater than the coefficient of fluid decomposed into three simple modes, and the induced change in principal stresses
diffusivity; therefore, heat transfer will be solutions to more general cases were was 5.5 MPa (compressive) and the
dominated by diffusion, and convective obtained by superimposing the solutions for induced change in pore pressure was 29.8
transport by pore fluid can be ignored. The the three modes. Comparison of numerical MPa. When the constraints were removed,
full-length paper presents equations for results with analytical solutions validated the the cube expanded and the principal stress-
conductive heat transfer in the shale, effects poroelasticity component of the model. es and pore pressure at the new equilibrium
of temperature change on pore-fluid pres- state were 11.8 MPa (tensile) and 29.7
sure, and changes in effective stresses that Model Description. The outer boundary of MPa, respectively. These values agreed with
result from mechanical deformation and the mesh was set at 10 wellbore diameters those determined by use of equations found
changes in pore pressure and temperature. to minimize any boundary effects. A con- in the full-length paper. For the case of a
stant fluid pressure was defined at the well- step change of −50°C, the induced changes
This article is a synopsis of paper SPE bore wall, with zero initial stress and pore- in stress and pore pressure were of the same
47304, “Modeling of Effects of Drilling- fluid pressure in the formation. Stresses and magnitude as the heating case but opposite
Fluid Temperature on Wellbore pore-fluid pressure calculated are the in sign, as expected.
Stability,” by S.K. Choi, SPE, and C.P. changes from the initial undisturbed state.
Tan, SPE, CSIRO Petroleum, originally PARAMETRIC ANALYSES
presented at the 1998 SPE/ISRM Model Results. Induced changes in pore The formation was assumed to be saturated
Eurock, Trondheim, Norway, 8–10 July. pressure and tangential stress near the bore- initially with pore fluid, and the pore pressure

68 NOVEMBER 1998 •
D R I L L I N G A N D C O M P L E T I O N F L U I D S

and temperature were assumed to be uniform Discussion. As thermal and induced pore- pressure increasing to slightly more than
in the formation. Wellbore diameter was 81/2 fluid diffusion proceeded, effective stress the wellbore pressure. Cooling improves
in., and the mesh boundary was set at 10 well- and pore-pressure distributions changed the stability of the wellbore, while heating
bore diameters from the center. A constant with time. For the permeable-wall condi- reduces the safety factor of plastic yielding
temperature representing the difference in tion, cooling resulted in a sharp decrease in and can induce wellbore instability. Because
temperature between the drilling fluid and the pore pressure near the wellbore wall after a of the boundary condition at the wellbore
formation was defined at the wellbore wall. short time. With time, the peak of the pore- wall, effective radial stresses are very simi-
Drilling fluids 50°C hotter and colder than the pressure decrease moves away from the lar for both cooling and heating. After less
formation were analyzed. Principal horizontal wellbore wall and the shape becomes flat- than 690 seconds, the difference in effective
stresses were isotropic. A fully permeable and ter, indicating that the thermal effect has tangential stress is approximately 6 MPa.
an impermeable wellbore wall were studied. spread out. Heating resulted in the pore Such changes in effective stresses can lead
to shear or tensile failure of the rock,
depending on the stress state in the region
around the wellbore wall. In general,
drilling fluid that is cooler than the forma-
tion tends to improve the stability of the
wellbore while drilling fluid that is warmer
than the formation can induce rock failure
because of thermoporoelasticity effects.
Cooling the drilling fluid can be an effective
option to manage wellbore instability when
the use of high mud weight is not feasible.

Thermal-Diffusivity Effects. A higher


thermal diffusivity implies that heat is
going to diffuse faster into the rock forma-
tion, reducing the time for induced pore
pressure to dissipate. As a result, the mag-
nitude of induced pore-pressure and stress
changes is higher for shales of a given fluid
diffusivity with higher thermal diffusivity. A
higher thermal diffusivity increased the
safety factor for cooling and decreased it
for heating.

CONCLUSIONS
1. A numerical thermoporoelasticity
model that can model time-dependent
changes in stresses and pore-fluid pressure
induced by thermal and fluid diffusion has
been developed.
2. Results of the model-validation analy-
ses agree well with analytical solutions for
instantaneous fluid injection of a poroelas-
tic medium.
3. Results of the simple numerical exper-
iment show that the computed changes in
effective stresses and pore pressure satisfy
the equations for the thermoporoelastic
medium used in the model.
4. Temperature differences between
drilling fluid and the formation can in-
duce significant changes in pore-fluid
pressure and effective stresses around the
wellbore wall.

Please read the full-length paper for


additional detail, illustrations, and ref-
erences. The paper from which the syn-
opsis has been taken has not been peer
reviewed.

70 NOVEMBER 1998 •

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