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  • Step 12: U 0 KJ /mol

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    1) The process occurs at an initial temperature of 150°C and pressure of 8 bar, and a final temperature of 50°C and pressure of 3 bar. 2) For the isothermal (constant temperature) step: Work = -2.502 kJ/mol, Heat = 2.502 kJ/mol, and Change in Internal Energy = 0 kJ/mol. 3) For the isochoric (constant volume) step: Work = 0 kJ/mol, Heat = -2.0785 kJ/mol, and Change in Internal Energy = -2.0785 kJ/mol. 4) For the overall process: Work = -2.502 k

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    1) The process occurs at an initial temperature of 150°C and pressure of 8 bar, and a final temperature of 50°C and pressure of 3 bar. 2) For the isothermal (constant temperature) step: Work = -2.502 kJ/mol, Heat = 2.502 kJ/mol, and Change in Internal Energy = 0 kJ/mol. 3) For the isochoric (constant volume) step: Work = 0 kJ/mol, Heat = -2.0785 kJ/mol, and Change in Internal Energy = -2.0785 kJ/mol. 4) For the overall process: Work = -2.502 k

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    1 visualizzazioni3 pagine

    Step 12: U 0 KJ /mol

    Caricato da

    anjar
    1) The process occurs at an initial temperature of 150°C and pressure of 8 bar, and a final temperature of 50°C and pressure of 3 bar. 2) For the isothermal (constant temperature) step: Work = -2.502 kJ/mol, Heat = 2.502 kJ/mol, and Change in Internal Energy = 0 kJ/mol. 3) For the isochoric (constant volume) step: Work = 0 kJ/mol, Heat = -2.0785 kJ/mol, and Change in Internal Energy = -2.0785 kJ/mol. 4) For the overall process: Work = -2.502 k

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    di 3

    3.20.

    diketahui :

    T1 = 150 C = 423,15 K

    P1 = 8 bar

    Perubahan reversible.

    T2 = 50 C = 323,15 K

    P3 = 3 bar

    Cp = (7/2) R

    Cv= (5/2) R

    Ditanya:

    W?

    Q?

    U =?

    H= ?

    Jawab:

    Step 12

    Secara isotermal ( temperatur konstan)

    H=0 kJ /mol

    U =0 kJ /mol

    V1
    W= RT1 ln
    V3

    P1T 3
    = RT1 ln
    P3T 1

    3 x 323,15 K
    = 8,314 x 10-3 kJ/ K mol (423,15 K) (ln ( ) )
    8 x 423,15 K

    = 3,518 ln (0,491)

    = - 2,502 kJ/ mol


    U =Q+W

    Q= -W

    = 2,502 kJ/ mol

    Step 23

    Secara Isokhorik (Volume Tetap)

    W=0

    Q = U = Cv T

    = Cv (T3 T2 )

    = 5/2 R (323,15 423,15) K

    = 5/2 (8,314 x 10-3 kJ/mol . K (-100 K)

    = -2,0785 kJ/ mol

    H= Cp T

    = Cp (T3 T2)

    = 7/2 R (T3 T2)

    = 7/2 (8,314 x 10 -3 kJ/mol. K (323,15 K 423,15 K)

    = - 291 kJ/mol

    UNTUK PROSES KESELURUHAN :

    W= W12 +W23

    = (-2,502 + 0 ) kJ/ mol

    = - 2,502 kJ/mol

    Q= Q12 + Q23

    = (2,502 2,0785 ) kJ/mol

    = 0,424 kJ/mol

    U = U 12+ U 23
    = (0 2,0785 ) kJ/mol

    = -2,0785 kJ/mol

    H= H 12+ H 23

    = (0 2,91) kJ/mol

    = -2,91 kJ/mol

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