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CHEMICAL BONDING
INORGANIC CHEMISTRY- XI
Assignment - 06
2. Amongst LiCl, RbCl, BeCl2 and MgCl2 the compounds with greatest and least ionic character
respectively are
(a) RbCl and LiCl (b) RbCl and BeCl2 (c) RbCl and MgCl2 (d) MgCl2 and BeCl2
6. Of the three molecules XeF4, SF4, SiF4 which have tetrahedral structures
(a) all the three (b) only SiF4 (c) both SF4 and XeF4 (d) only SF4 and XeF4
+ 2+ 2
7. If Na ion is larger than Mg ion and S ion is larger than Cl ion, which of the following will be
more covalent.
(a) NaCl (b) Na2S (c) MgCl2 (d) MgS
9. Among HF, CH3OH, N2O4 and CH4 which would have inter molecular hydrogen bonding.
(a) CH3OH, CH4 (b) HF, CH4, CH3OH (c) N2O4, HF (d) HF, CH3OH
13. The molecule which has highest dipole moment amongst the following is
(a) CH4 (b) CHCl3 (c) CCl4 (d) CHI3
3
14. In which of the following the central atom does not use sp hybrid orbitals in its bonding ?
(a) BeF3 (b) OH3+ (c) NH2 (d) NF3
19. The maximum number of 90 angles between bond pair-bond pair of electrons is observed in
3 3 2 3 2
(a) dsp -hybridization (b) sp d-hybridization (c) dsp -hybridization (d) sp d -hybridization
20. The correct increasing bond angle among BF3, PF3 and ClF3 follows the order
(a) BF3 < PF3 < ClF3 (b) PF3 < BF3 < ClF3 (c) ClF3 < PF3 < BF3 (d) BF3=PF3=ClF3
22. In which of the following the central atom has maximum number of lone pair of electrons ?
(a) SF4 (b) XeF4 (c) ClO
3 (d) I3
24. The correct order of hybridization of the central atom in the following species NH 3, PCl5 and BCl3
is
2 2 3 3 3 2 2 3 3 2 2 3
(a) dsp , sp and sp (b) sp , sp d, sp (c) dsp , sp , dsp (d) dsp , sp , sp d
25. The correct order of bond angles (smallest first) in H2S, NH3, BF3 and SiH4 is
(a) H2S < NH3 < SiH4 < BF3 (b) NH3 < H2S < SiH4 < BF3
(c) H2S < NH3 < SiH4 < BF3 (d) H2S < NH3 < BF3 < SiH4
27. Two element have electronegativity of 1.2 and 3.0. Bond formed between them would be
(a) ionic (b) polar covalent (c) Co-ordination (d) metallic
Column- I Column-II
(a) (CH3)3B (p) Square planar
(b) NH4Cl (q) Trigonal bipyramidal
(c) [ICl4] (r) Tetrahedral
(d) PCl5 (s) Trigonal
(t) Ionic
37. Column I lists some of hybridization schemes and Column II lists some of the compounds. Match
each entry of Column I with the compounds mentioned in Column II.
Column I Column II
3
(a) sp (p) Ni(CN)4
2
(b) dsp (q) XeO3
3
(c) dsp (r) SO2
3
2 3
(d) d sp (s) XeF2
(t) XeF4
(u) XeO2F2
40. Assertion (A) : N(SiH3)3 has a planar geometry while N(CH3)3 has a nonplanar geometry.
3
Reason (R) : Nitrogen orbitals undergo sp hybridization in both N(CH3)3 and N(SiH3)3 molecules.