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a
Sango Co. Ltd., 605 Kishine, Kouhoku-ku, Yokohama 222-0034, Japan
b
Department of Geosystem Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
Received 4 April 2006; received in revised form 26 January 2007; accepted 8 February 2007
Available online 23 February 2007
Abstract
We describe a method that can be used to produce concrete-reinforcing PET ber from used PET bottles. Using this method, the
concrete and PET bers are easily mixed at a ber contents as high as 3%. The primary characteristic of the PET ber is that it is easy
to handle. The issue of concern in the development of PET ber is its alkali resistance; however, we encountered no problems when using
the ber in normal concrete. The wetting tension of PET was found to be lower than that of PVA but higher than that of PP. No toxic
gas was generated during a combustion test of the PET ber. We describe two example applications: a gateway support at Hishikari
Mine, Japan, and the pavement of bush roads.
2007 Elsevier Ltd. All rights reserved.
Keywords: Fiber-reinforced concrete; Recycled PET; PET ber; Alkali resistance; Mixing; Strength
0958-9465/$ - see front matter 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.cemconcomp.2007.02.002
T. Ochi et al. / Cement & Concrete Composites 29 (2007) 448455 449
PET-ber-reinforced concrete; the measured JCI (Japan the PET ber, using an extruder, as shown in Fig. 1. Pellets
Concrete Institute) toughness was found to have increased were placed in the extruder and melted; 20100 bers were
greatly relative to that of the same material without rein- then extruded from the nozzle at the tip of the extruder.
forcement. A pull-out resistance test of the PET ber was The nozzle was disk-shaped and had numerous small holes.
also conducted, and the adhesion of the ber per surface Through these small holes, bers with a neness of
area was found to compare favorably with that of PP ber. 60,000 dtex (decitex: grams per 10,000 meter length) were
Following the above-mentioned basic tests of the PET extruded. Temperature control during the extrusion pro-
ber, the PET-ber-reinforced concrete was used to sup- cess is generally very dicult. After some trial and error,
port a mine gateway and pave bush roads. In all cases, the temperature inside the extruder was set at 250280 C
the PET ber was applied without any problems. and the temperature of the nozzle was set at 260280 C.
The extruded ber was pulled to the godet roll and hot-
2. Preparation of PET ber drawn to a neness of 25,000 dtex. The ber was further
drawn in a water bath lled with cold water, and a neness
To minimize costs and contribute to material recycling, of 5000 dtex (diameter of 0.7 mm) was achieved when it
we used pellets recycled from PET bottles as the raw mate- reached the snub roll.
rial for the production of PET ber. The properties of plas- The resulting monolament was a smooth ber with a
tic ber vary widely depending upon the production circular cross-section. Judging from our experience with
method. In the normal process, pellets are melted, extruded steel ber and based on the results of simple preliminary
from a nozzle, and drawn into ber while warm. When tests, we inferred that the ber would be easily pulled out
melted plastic is drawn in this way, the polymer chains from the concrete if there were no indents on the ber.
align along the longitudinal direction of the ber. As a Therefore, we developed a process to produce indents
result, the strength of the ber is increased by more than and incorporated this into a ber-cutting apparatus, as
an order of magnitude. shown in Fig. 2. The rolled monolament is on the bobbin
After various considerations, we decided to produce on the right side of Fig. 2, and it is pulled with the pinch
monolaments, which are used as the raw material for roll #1 and gradually reeled out. We marked indents on
Nozzle
60,000 dtex Water
bath #2
Extruder
Water
bath #1
Cutting
PET fiber
Fig. 2. Apparatus for the indent marking and cutting of PET ber.
450 T. Ochi et al. / Cement & Concrete Composites 29 (2007) 448455
Table 3
Blend of concrete constituents
W/C Mixtures (kg/m3) Volumetric content Fiber length Max. size of Slump
(%) of ber (%) (mm) aggregate (mm) (cm)
Cement Water Fine Coarse
aggregate aggregate
Mixing test Hand 50 681 341 1129 0 0.76 30
mixing
Concrete 69 325 225 992 789 0, 0.5, 30 15 18.5a
mixer 1.0, 1.5
Bending test 65 334 217 973 743 0 30 15 16.5
0.5 16.0
1.0 3.5
1.5 4.0
60 358 215 947 754 0 30 15 9.5
0.5
1.0
1.5
55 389 214 918 761 0 30 15 7.0
0.5
1.0
1.5
Hishikari mine 40 538 215 973 585 0.3 30 10 18.0
Bush road pavement 64 285 182 890 898 0.75 40 20 8.0
a
Plain concrete.
100 mm and a height of 200 mm. The uidity on this occa- Table 4
sion was good, and uplifting of the PET ber was not The number of bers exposed on the cross-section and the orientation
factor
observed even when the mold was hit with a wooden ham-
mer to create compaction. Samples #1 #2 #3
The three test specimens of the PET-ber-reinforced Cross-sectional area (cm2) 44 44 79
mortar were removed from the molds after hardening. Number of bers counted on a Cross- 31 52 73
cross-section section 6
They were then cut into seven round slices. As the PET
Cross- 20 52 78
bers in the mortar are not visible, the PET bers exposed section 5
on the cross-section were colored and counted. The cross- Cross- 31 60 73
sections of the three test specimens were observed, and section 4
the PET bers were found to be evenly dispersed. The num- Cross- 43 42 91
section 3
ber of bers exposed on the six cross-sections and the ori-
Cross- 51 44 75
entation factors of the test specimens in the direction of section 2
specimen height are shown in Table 4. The orientation fac- Cross- 37 14 67
tor P is dened here as the average length of the projection section 1
on the longitudinal axis of all bers crossing a section, Average 36 44 76
divided by the ber length [8,9]; it can be approximated Average ber densitya (1/cm2) 0.81 1.00 0.96
by the following equation [8,9]: Orientation factorb 0.47 0.58 0.56
a
Average number of bers per unit cross-sectional area.
P aA=V b
(Average ber density)(Cross-sectional area of a ber)/(Volumetric
where a, A, and V indicate the number of bers per unit content of bers) [8,9].
cross-sectional area, the cross-sectional area of an individ-
ual ber, and the volumetric content of bers, respectively. the mixture in this case was ca. 3%; however, no ber balls
The bers were evenly distributed except for cross-sec- were generated. Although the viscosity increased, uidity
tion 1 of test specimen #2. The orientation factors for all was maintained. The ber was easily mixed with concrete
test specimens were lower than 0.64, which is the theoreti- at a ber content as high as 3%.
cal value for two-dimensional random orientations, and Based on the above results, the dispersion of the PET
close to 0.5, which is the theoretical value for three-dimen- bers in mortar following hand mixing is considered to
sional random orientations. Thus, the bers are considered be good.
to be randomly oriented.
After the moulds were cast for the investigation of ber 4.2. Machine-mixing test
orientations, 46.9 g of additional ber was added to the
remaining PET-ber-reinforced mortar (ca. 2 dm3), and The machine-mixing test was conducted for the blend
the mixture was blended together. The ber content of shown in Table 3. Initially, measured amounts of cement
452 T. Ochi et al. / Cement & Concrete Composites 29 (2007) 448455
and ne aggregates were mixed in a 55 dm3 concrete mixer little up to a ber content of 1%; however, the bending
for 15 s. Following this, a predetermined amount of water strength increases signicantly at a ber content of 1.5%.
was added and the mixture was mixed for 30 s. Next, This trend is the same as that observed for steel-ber-rein-
coarse aggregates were added and the mixture was mixed forced concrete [10], in which the length and cross-sectional
for an additional 60 s. The obtained concrete was cast into area of the steel bers are 25 mm and 0.3 mm2, respec-
three molds with dimensions of 100 100 400 mm to pre- tively, and the watercement ratio is 0.6. The bending
pare test specimens (plain concrete with 0% of PET ber) strengths for all conditions are shown in Table 5. The trend
for the bending test. Next, a predetermined amount of of variation in bending strength with changing content of
the PET ber was poured into the concrete mixer, during PET ber was qualitatively similar for all cases with dier-
mixing of the remaining concrete, for a period of 45 sec- ent watercement ratios.
onds. The prepared PET-ber-reinforced concrete was cast The loaddeection curves for the test specimen with a
into a mold to prepare test specimens for the bending test. watercement ratio of 60% are shown in Fig. 4. When the
The mixed state was carefully observed, and neither ber ber content is 0% (plain concrete), the maximum load is
balls nor any abnormalities were recognized; the uidity at a deection of ca. 0.20.3 mm (deection at the load
was also good during the mold casting. point); following this, the load suddenly decreases. When
Based on the above results, the mixability of the rein- the ber content is 1.5%, cracks form at the same deection
forcing PET ber and concrete by machine mixing is con- point at which the maximum load was reached for plain
sidered to be good. concrete; however, since the load is supported with the
18
Load (kN)
5
1.0 %
12
4
0.5 %
6
3 0%
0 0.5 1 1.5 2
Volumetric fiber content (%) 0
0 1 2 3 4 5
Deflection (mm)
Fig. 3. Change in the bending strength with respect to the ber content for
concrete with a watercement ratio of 60%. The vertical line indicates the Fig. 4. Loaddeection curve for concrete with a watercement ratio of
standard deviation. 60%.
T. Ochi et al. / Cement & Concrete Composites 29 (2007) 448455 453
Hishikari Mine is a gold mine located in Kagoshima ing and deviation, and the surface was relatively smooth.
Prefecture, which is one of Japans leading gold-producing One year later, a survey of the sprayed location was con-
areas [13]. In the past, steel-ber-reinforced concrete was ducted. The sprayed surface had no cracks, and an excel-
sprayed onto a gateway with a cross-sectional area of lent supporting ability appeared to have been achieved.
4 4 m; however, this was unsatisfactory because the mix- At mines, bedrock can be marked by local weaknesses.
ing of steel ber and concrete was dicult, and the steel- There are also locations, such as a 4-way entry and 3-
ber-reinforced concrete often blocked the sprayer. The way entry, that are very dicult to support and the roof
PET-ber-reinforced concrete was applied on a trial basis is susceptible to collapse. In these cases, there is a long-
from January 2004, and the workability of the concrete standing demand to increase the support by increasing
and its supporting ability were evaluated. the ber content; however, in the case of steel-ber-rein-
The prerequisite condition stipulated by the mining forced concrete, the formation of ber balls has prevented
company was that a loose rock with a weight of 24 kN the use of higher ber contents. When the PET-ber-rein-
should be supported after 2 h of spraying. To satisfy this forced concrete was used, the ber content was increased
requirement, the standard specications of the concrete as necessary. Even when the ber content was more than
(shotcrete) were set as shown in Table 3. 1%, uniform PET-ber-reinforced concrete could be
Actual spraying was conducted at the mine gateway, obtained within the normal mixing time. In addition, pipe
and the operation proceeded smoothly and was completed clogging during concrete pumping or poor concrete adhe-
without any problems. The rebound rate (rebound weight/ sion did not occur. It is a noteworthy characteristic of
sprayed weight) of the PET-ber-reinforced concrete was the PET ber that the ber content can be freely changed
14% by weight. in situ without ber-ball formation and pipe clogging.
Observation of the sprayed surface revealed that the
PET bers were adequately dispersed, there was no uplift- 6.2. Pavement of narrow areas
Table 7
Passages in tunnels under construction, passages
Installation processes and necessary time for bush road paving through underground structures, urban alleyways, and
PET ber-reinforced Wire mesh-reinforced
bush roads are commonly narrow, winding, and steeply.
concrete concrete It is desirable to apply ber-reinforced concrete to the
Area (m2) 41 48
pavement of such narrow sections of road; however, steel
Depth (cm) 13 15 ber can puncture tires, and there are workability concerns
about this conventional ber. Thus, it has not been used
Process Concrete placing Concrete placing #1
Wire mesh placing previously to pave narrow sections of road in Japan. In this
Concrete placing #2 study, we decided to use PET-ber-reinforced concrete to
Finishing Finishing pave bush roads to make use of its easy workability.
Worker-hours 4.4 9.7 PET-ber-reinforced concrete was applied to a bush
Man-hours 0.11 0.20 road between Hayatogawa and Kanazawa, Kanagawa Pre-
(m2) fecture, Japan. On March 26 2004, a road with a length of
Table 8
Example applications of the PET bers
Starting date Prefecture Location Sprayed/ W/CM Fiber length Volumetric Remark
placed (%) (mm) content of
bers (%)
January 2004 Kagoshima Mine Sprayed 50 30 0.3 Replacement of steel ber. First trial to use
gateway PET ber in Japan. Found to be very easy to
handle
March 2004 Kanagawa Bush road Placed 64 40 0.75 Replacement of wire mesh. Considerable
laborsaving
October 2004 Ibaragi Bush road Placed 64 40 1.0 Applied successfully to road with 10%
gradient
March 2004 Ehime Slope Sprayed 50 30 0.3 Replacement of steel ber on the sea front
August 2004 Fukuoka Tunnel Placed 52 40 0.3 Applied to tunnel support for the rst time
February 2005 Tottori Tunnel Placed 52 40 0.3 A new ber content analyzer was developed
and used
September 2005 Kanagawa Bridge pier Placed 50 30 0.3 Crack extension was substantially decreased
October 2005 Shiga Tunnel Placed 52 40 0.3 A new ber injector was developed and used
In the planning Underground Sprayed 50 30 0.75 Replacement of wire mesh to prevent rust for
stage storage for longer service life
LNG
T. Ochi et al. / Cement & Concrete Composites 29 (2007) 448455 455
20 m and a width of 3.64.9 m was paved. The PET ber pared. At present, PET ber is used in Japan for spraying
was gradually added to the agitator of an agitator truck and lining tunnels, including expressway tunnels, and
and combined with the ready-mixed concrete. The mixed future use is expected to increase. Future applications
PET-ber-reinforced concrete (see Table 3) was applied include not only general tunnel support, but also under-
on the bush road to a pavement thickness of 13 cm. For ground structures that are located in harsh environments,
comparison, a conventional composition using welded such as near the coast or under the sea. In addition, its
mesh as reinforcement was also used. For the conventional use as pavement on narrow, winding, and steep roads
composition, plain concrete was installed to a predeter- can be considered.
mined thickness of 15 cm. The processes and necessary
time for installation using the PET ber method and the Acknowledgments
conventional method are listed in Table 7. As seen from
the table, the application of PET-ber-reinforced concrete The authors thank all the involved sta members of
is ecient and laborsaving. A follow-up survey was con- Sumitomo Metal Mining Co. Ltd. and Sango Co. Ltd.
ducted half a year later; aws such as cracking or chipping for various collaborations.
were not observed in the pavements constructed by either
method. References
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