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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology kaimao-chem.com

Jiangsu Kaimao Chemical Technology Co., Ltd The world's largest silver contact formaldehyde plant supplier Sales

Jiangsu Kaimao Chemical Technology Co., Ltd

The world's largest silver contact formaldehyde plant supplier

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology

 

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology

         

Product Details:

   
 

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Place of Origin:

Wuxi, Jiangsu

           

Brand Name:

Kaimao

 
                   
         

Payment & Shipping Terms:

 
             

Minimum Order

   
         

Quantity:

1 set

 
 

Contact Us

             
 

Mr. Allen Wang

                 
 

Tel:86-180-18350556

                 
 

Address:

                 
 

Building NO.50, Henghua Science Park NO.58 Xiuxi Road, Binhu District, Wuxi City, Jiangsu Province, China

               
 

Email:

                 
 

allen.wang@js-yimao.com;

       
 

wjw@kmshkj.com

         
                 
 

Certifications

 

Description

Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology

     

Formaldehyde (HCHO)is basic chemical raw material, widely applied in resin, plastic, leather, paper and fiber production, plays very

     

important role in human’s production and life.

       
     

Relying on a group of well-known senior engineers’ continuous exploration and innovation in formaldehyde industry, based on the traditional

     

production process, Jiangsu Kaimao Chemical Technology Co., Ltd. has developed a series of formaldehyde processes such as off-gas

 

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circulation process, low conversion alcohol free process, flue gas circulation process and the newest formaldehyde process (Kaimao

     

Process).; Created a new route for Chinese formaldehyde industry, and taken leading position in Chinese formaldehyde industry.

           

Section A. Formaldehyde Production Process

 
 

Mr. Allen Wang(General Manager)

               
     

1.Tail gas circulation process

       
     

The formaldehyde traditional production process is that through methanol evaporation, mixing gas heating, filtration and after fire retardant,

     

the methanol is oxidized, and the reaction product is absorbed to produce formaldehyde. The formaldehyde concentration can reach 37% in

     

this production process. Along with formaldehyde down stream products development, and energy saving, emission reduction requirement,

     

more and more formaldehyde producing enterprises wish to increase formaldehyde concentration. Therefore, tail gas circulation process

     

was developed to meet this requirement. The purpose of using tail gas instead of steam vapor is to reduce steam feed. Because the water

     

content in the system is reduced, the formaldehyde concentration can be increased a lot and reaches to around 45%, furthermore, the

     

byproduct steam is also increased.

       

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology kaimao-chem.com

2.Low Conversion, Methanol Free Process In traditional methanol oxidation process, the methanol oxidation temperature is

2.Low Conversion, Methanol Free Process In traditional methanol oxidation process, the methanol oxidation temperature is about 650. Also there are side reactions to form CO2,CO. Meanwhile, the formaldehyde final product contains 1% of methanol residue. This will increase methanol consumption. Low conversion, methanol free process is to lower reaction temperature, decrease side reactions occurrence, and the non-reacted methanol is recovered by distillation. Through this process, the methanol consumption is decreased, and the methanol concentration is increased.

3.Flue Gas Circulation Process Besides CO2,CO,CH4,CH2OH,CH2O, the tail gas also contains 18-20% hydrogen. Hydrogen will

3.Flue Gas Circulation Process Besides CO2,CO,CH4,CH2OH,CH2O, the tail gas also contains 18-20% hydrogen. Hydrogen will cause reduction in the oxidation process, also will consume methanol to form CH4 (side reactions). The existing of hydrogen will inhibit de-hydrogen reaction, also increase methanol consumption. So, we developed Flue Gas Circulation Process. N2 , CO2 and other inert gases are the main compositions in the flue gas. These gases do not participate in the reaction, furthermore, and can play the role of inhibiting the formation of CO2,CO, CH4,HCOOH. The byproduct can be reduced to CO2 2.2-2.8%,CO 0.1-0.3%,CH4 0.1-0.2%, saved methanol 8-10kg/t in total. Meanwhile, the flue gas contains 5-10% excess oxygen, as a result, output can be increased 10-20%, Steam is generated in this process as byproduct, and the steam output can be increased 10%, and power consumption will be decreased 4-6KWh/t The comparison of flue gas circulation process with other processes

Low Tail Gas Flue Gas Traditional Conversion, The Newest No. Name Unit Circulation Circulation Process
Low
Tail Gas
Flue Gas
Traditional
Conversion,
The Newest
No.
Name
Unit
Circulation
Circulation
Process
Methanol Free
Process
Process
Process
Process
Formaldehyde
%
37
37-45
37-45
37-50
37-50

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology kaimao-chem.com

1

Quality

Methanol

%

1-2

1

0.5

0.5

0.2

 
 

Formic Acid

%

0.02

0.01

0.01

0.01

0.01

Methanol

Kg/t

450

445

440

440

436

2

Consumption Circulation Water Power Oxygen/Methanol Ratio

t/t

70

50

50

50

50

Kwh/t

28

30

27-28

30

30

mol

0.38-0.41

0.38-0.45

0.35-0.38

0.38-0.43

0.38-0.41

Process

Oxidation Tem.

640-660

640-660

600-630

620-640

610-640

3

Spec.

Relatively

 

Convert Ratio

low

Good

Lowest

High

High

Safety

Good

Good

Good

Good

Good

4

Inlet Steam

Kg/t

330-350

400-550

330-450

500-650

500-650

 

Heat Comprehensive

 

Relatively

Relatively

Good

Good

5

Utilization

Poor

Good

Good

 
   
 

Flue Gas Circulation Process is superior to other processes. It is a new process and technology and deserved to be promoted. Jiangsu Hengmao has a group of engineers and technicians, who are specialized in this production know-how and process, they are energetic and creative. We also like to undertake turn-key EPC project to offer engineering design, fabrication, installation, and commissioning.

4.The Newest Formaldehyde Production Process(Kaimao process) Tail Gas Circulation Process and Low Conversion, Methanol Free Process is all developed based on the traditional process. The process route: methanol evaporation——over heat——filtration——oxidation——1# absorption tower——2# absorption tower(3# absorption tower) ——tail gas incineration. It has long process, more equipments, and high energy consumption, and covered big land area. Based on years’ production practice, absorbed original process advantages, Kaimao Company has developed the newest formaldehyde production process with own intellectual property. Three sets of equipment (Evaporation——Oxidation——Absorption) are applied in this know-how to replace traditional equipments in this new process. It has the advantage of shorter process route, less land coverage and low investment ; furthermore, low methanol formaldehyde with high concentration products can be received.

The Newest Formaldehyde Process and Features:

 

This process is equipped with air scrubber, which assures raw material gas cleanness. Clean air will help decrease system resistance and increase electrolytic silver efficiency, which will be in favor of formaldehyde production. The air after scrubbing is sent to the evaporator by blower. The evaporator is multi-functional evaporation equipment, combined with evaporation, mixing, over-heating, and filtration. Methanol, air, steam and tail gas (flue gas) are mixed uniformly in proportion in the evaporator, then, sent to the oxidation reactor. Methanol, the oxygen in the air is reacted to form formaldehyde in the oxidation reactor under silver catalyst; while the steam and tail gas (flue gas) is to take away the generated heat. Set a heat exchanging section in the oxidation reactor. The purpose for this is to:

a. Increase vapor amount to recover more steam.

 

b. Increase outlet temperature of oxidation reactor; produce high concentration formaldehyde with low methanol.

 

An absorption tower is divided into distillation section and absorption section inside to form concentration and temperature gradients. In this way, it will avoid formaldehyde polymerization and help to form high concentration formaldehyde, also recover methanol. The final tail gas is sent to the incinerator for burning. After incineration, the flue gas after cooling can be returned to evaporator as heat transfer medium.

Comprehensive Heat System With High Heat Utilization Rate Salt free water can be replenished into the combination evaporator to reduce feeding steam consumption. The heat in formaldehyde circulation of absorption tower can be used for evaporating methanol so that save steam.

 

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology kaimao-chem.com

“Combination Type Evaporator” can greatly shorten the distance between evaporator and oxidation reactor; therefore, equipment arrangement will be more tight, as a result, decrease heat loss. The emission gas from incinerator can be used to preheat water of boiler or air, byproduct steam can be sent out for other application, and the whole facility heat energy is comprehensively utilized.

the whole facility heat energy is comprehensively utilized. Section B. Use Iron, molybdenum method to produce

Section B. Use Iron, molybdenum method to produce formaldehyde

Iron, molybdenum method is operated below the methanol-air explosion limit, which means it is operated in the air excess condition, so, it is also called “Air Excess Method”. This reaction occurs under ambient pressure at 250-400, so that, can reduce side reaction, increase convert rate and lower consumption.

1.Iron, molybdenum method process Iron, molybdenum method methanol oxidation reactions are as following:

Main Reaction CH3OH + 1/2O2 CH2O + H2O - 159KJ/mol Side Reaction CH3OH + 3/2O2 CO2 + 2H2O CH3OH + O2 CO + 2H2O CH3OH + O2 HCOOH + H2O 2CH3OH CH3OCH3 + H2O Formaldehyde production using iron, molybdenum method consists of air compression, reaction, steam generation, and formaldehyde absorption etc. processes. The air, through silencer, is mixed with the circulation tail gas from the top of No.2 tower, after that, to be sent to the circulation blower, then, compressed and sent to methanol pre-evaporator. Raw material methanol, from tank farm, is pumped to the evaporator to be heated and vaporized, at meantime, mixed with air to form raw material mixing gases. The heat in the evaporator is supplied by the formaldehyde circulation solution which comes from No.2 tower. Raw material mixing gases after over-heated through the evaporator, are reacted each other in the fixed bed reactor under the existing of iron, molybdenum catalyst. The reacting temperature is controlled by heating oil. In the reaction process, the byproduct water steam will be produced when the heating oil is cooled down. The reaction product formaldehyde gas, through methanol evaporator coil, is cooled down by heat exchanging with raw material gas, then, is sent to the absorption tower. The liquid partially received in the circulation process is the final product formaldehyde. The off- gas from the top of No.2 absorption tower is partly returned to the blower inlet, another part is sent to incineration system. Byproduct, steam is sent out for other application.

2.The comparison of iron, molybdenum method and silver method. (1)Investment: Iron, molybdenum method is 50% higher than silver method. (2)Unit methanol consumption: Because use silver method, formaldehyde is received in methanol excess condition, unit methanol consumption in silver method is 5-10kg more than iron, molybdenum method. (3)Energy consumption: Energy consumption of iron, molybdenum method is 2.3 times more than that of silver method, while the steam output (byproduct) is almost same as Kaimao silver method.

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Formaldehyde Plant , Formaldehyde equipment , Formalin plant , Formadehyde technology kaimao-chem.com

(4)The life span of catalyst: The temperature used in the silver method is more than
(4)The life span of catalyst: The temperature used in the silver method is more than 650℃, and the life span of silver catalyst is usually
about 3 months. Iron, molybdenum method has high activity, and this catalyst life span is 6-12 months.
(5)Product quality: Either silver method or iron, molybdenum method, both can receive low methanol, high concentration formaldehyde with
50% formaldehyde concentration and ≤0.5% methanol content.
Iron, molybdenum method consumption rate
No.
Name
Unit
Consumption rate
1
Methanol(99.5%)
Kg/t
430-435
2
Power Consumption
kwh/t
70
3
Salt free water
kg/t
400
4
Steam Consumption
kg/t
600-700
Note: Calculated on on 37% formaldehyde basis
Salt free water kg/t 400 4 Steam Consumption kg/t 600-700 Note: Calculated on on 37% formaldehyde
Salt free water kg/t 400 4 Steam Consumption kg/t 600-700 Note: Calculated on on 37% formaldehyde

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Contact Us

           

Mr. Allen Wang

           

Building NO.50, Henghua Science

District, Wuxi City, Jiangsu

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Park NO.58 Xiuxi Road, Binhu

Send your inquiry directly to us

     

Province, China

 

Tel:86-180-18350556

 

Fax:86-510-85560611

 
         

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