MODELO NRTL - SISTEMA B

ACETONA (1)/ METANO

Parametros de Antoine P(Kpa), T(C)

i A B C R(cal/mol-k)
1 14.3145 2756.22 228.06 1.987
2 16.5785 3638.27 239.5

Parametros de NRTL

i vi(cc/mol) b12(cal/mol) b21(cal/mol) Psati

1 74.05 184.7 222.64 0.3084 158.7453664
2 40.73 124.360546

170
x1 Ganma 1 Ganma 2 P y1 165
0 1.77881225 1 124.360546 0
0.1 1.59085559 1.0058849192 137.8372534 0.1832168 160
0.2 1.44088529 1.0236052742 147.5836613 0.3099718
155
0.3 1.32127143 1.0535959374 154.6417516 0.4068999
0.4 1.22631529 1.0967575356 159.7047677 0.4875794 presion (Kpa) 150
0.5 1.15175484 1.1545040878 163.2052513 0.5601405
145
0.6 1.09441603 1.2288456105 165.3680488 0.630352
0.7 1.05196658 1.3225128584 166.2369 0.7031915 140
0.8 1.02274331 1.439135719 165.67895 0.7839536
135
0.9 1.00563389 1.5834925728 163.3681478 0.87946
1 1 1.7618560085 158.7453664 1 130

125

120
0
Parametros de NRTL
i vi(cc/mol) b12(cal/mol) b21(cal/mol) x1
1 74.05 184.7 222.64 0.3084 1
2 40.73 0

Calculo de la temperatura de burbuja

n 0 1 2 3 4
T (C) 56.2001696 56.200169595 0.065905422 56.20017 56.2001696
T (K) 329.20017 329.2001696 273.0659054 329.20017 329.2001696
12 0.28236377 0.2823637741 0.340409405 0.2823638 0.282363774
21 0.3403653 0.3403652987 0.410334325 0.3403653 0.340365299
G12 0.91660286 0.9166028589 0.900340494 0.9166029 0.916602859
G21 0.90035274 0.9003527409 0.881132642 0.9003527 0.900352741
Ganma 1 1 1 1 1 1
Ganma 2 1.48376785 1.4837678533 1.650647613 1.4837679 1.483767853
Psat1 101.33 101.33 101.33 101.33 101.33
Psat2 71.850255 71.850255025 71.85025503 71.850255 71.85025503
T (C) 56.2001696 56.200169595 56.2001696 56.20017 56.2001696

x1 T (C) Ganma 1 ganma 2 Psat1 Psat2

0 64.7001891 1.7943678517 1 134.27639 101.33
0.1 61.8265717 1.6081962492 1.003605222 122.31189 90.40722621
0.2 59.9004862 1.4561496987 1.014694978 114.77555 83.65066082
0.3 58.5907189 1.3333141114 1.033759244 109.8641 79.30140602
0.4 57.6902464 1.2351307249 1.061456576 106.58513 76.4223003
0.5 57.0673377 1.1577701019 1.098678542 104.36263 74.48226372
0.6 56.6382347 1.098184187 1.146611327 102.85312 73.16995161
0.7 56.3520104 1.0540442613 1.206805128 101.8559 72.30540823
0.8 56.1826287 1.0236521256 1.281257318 101.26939 71.79783006
0.9 56.1258365 1.0058585256 1.3725115113 101.07334 71.62831277
1 56.2001696 1 1.483767853 101.33 71.85025503

66
C)
 66

Temperatura (C) 64

62

60

58

56

54

52

50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-y1
 TEMA BINARIO:
METANOL (2)

T(C) T(K)
70 343

12 21 G12 G21
0.2710035 0.3266715 0.919819815 0.9041631

170

165

160

155

150
presion (Kpa)

145

140

135

130

125

120
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-y1
Tsati (C) x1*Tsati Psati (Kpa) P (Kpa)
56.20017 56.20017 101.33 101.33
64.700189 0 71.85025503
56.20017

5 6 7 8 9
56.20017 56.20017 56.2001696 56.20017 56.20017
329.20017 329.20017 329.2001696 329.20017 329.20017 i y1
0.2823638 0.2823638 0.282363774 0.2823638 0.2823638 1 1
0.3403653 0.3403653 0.340365299 0.3403653 0.3403653 2 0
0.9166029 0.9166029 0.916602859 0.9166029 0.9166029 1
0.9003527 0.9003527 0.900352741 0.9003527 0.9003527
1 1 1 1 1
1.4837679 1.4837679 1.483767853 1.4837679 1.4837679
101.33 101.33 101.33 101.33 101.33
71.850255 71.850255 71.85025503 71.850255 71.850255
56.20017 56.20017 56.2001696 56.20017 56.20017

y1
0
0.1941197
0.3298734
0.4336821
0.5196746
0.5962101
0.6688148
0.7416603
0.8184318
0.9029797
1

0.9
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-y1
MODELO UNIFAC - SISTEMA B
ACETONA (1)/ METANOL
Frecuencia
k Rk Qk vk1 vk2 q1=Gk1q2=Gk2 r1 r2
9 1 CH3CO 1.6724 1.488 1 0 1.488 0 1.6724 0
1 2 CH3 0.9011 0.848 1 1 0.848 0.848 0.9011 0.9011
5 3 OH 1 1.2 0 1 0 1.2 0 1

2.336 2.048 2.5735 1.9011

n 0 1 2 3 4 5
t(C) 59.60018 55.168 55.134 55.134 55.134 55.134
T(K) 332.7502 328.168 328.134 328.134 328.134 328.134
x1 0.9 0.9 0.9 0.9 0.9 0.9
x2 0.1 0.1 0.1 0.1 0.1 0.1
L1 1.0125 1.0125 1.0125 1.0125 1.0125 1.0125
L2 0.8877 0.8877 0.8877 0.8877 0.8877 0.8877
J1 1.0268 1.0268 1.0268 1.0268 1.0268 1.0268
J2 0.7585 0.7585 0.7585 0.7585 0.7585 0.7585
1 1.3392 1.3392 1.3392 1.3392 1.3392 1.3392
2 0.8480 0.8480 0.8480 0.8480 0.8480 0.8480
3 0.1200 0.1200 0.1200 0.1200 0.1200 0.1200

s11 1.6906 1.6866 1.6865 1.6865 1.6865 1.6865

s21 2.2210 2.2195 2.2195 2.2195 2.2195 2.2195
s31 0.9514 0.9433 0.9433 0.9433 0.9433 0.9433

s12 1.1349 1.1276 1.1275 1.1275 1.1275 1.1275

s22 1.5980 1.5931 1.5930 1.5930 1.5930 1.5930
s32 1.2437 1.2420 1.2420 1.2420 1.2420 1.2420

1 1.6350 1.6307 1.6306 1.6306 1.6306 1.6306

2 2.1587 2.1568 2.1568 2.1568 2.1568 2.1568
3 0.9806 0.9732 0.9731 0.9731 0.9731 0.9731

Ganma 1 1.00811 1.00824 1.00824 1.00824 1.00824 1.00824

Ganma 2 2.00978 2.02888 2.02902 2.02903 2.02903 2.02903
Psat1 96.439 96.303 96.302 96.302 96.302 96.302
Psat2 68.818 68.722 68.721 68.721 68.721 68.721
t (C) 55.1677 55.1341 55.1338 55.1338 55.1338 55.1338

P= 101.33 KPa
A B C Tsat T(C) Psati(KPa)
Acetona 14.3145 2756.22 228.06 56.20017 57.05017 104.302
metanol 16.5785 3638.27 239.5 64.70019 74.429

ACETONA (1)/ METANOL (2)

Para P=760 mmHg 66.00
x1 T(x1) Ganma 1 P1(t) y1
0.00 64.70 2.51598 134.276 0.000 64.00
0.10 60.38 2.08897 113.738 0.234
0.20 58.02 1.77254 103.900 0.363 62.00
0.30 56.59 1.53887 98.570 0.449
0.40 55.68 1.36594 95.488 0.515

T(C)
0.50 55.08 1.2381 93.705 0.572 60.00
0.60 54.71 1.14458 92.834 0.629
0.70 54.55 1.07806 92.805 0.691 58.00
0.80 54.66 1.03366 93.798 0.765
0.90 55.13 1.00824 96.302 0.862 56.00
1.00 56.20 1 101.330 1.000

54.00
Para T=70C
0.00 0.10 0.20 0.3
x1 Ganma 1 Ganma2 P y1
0.00 2.483 1.000 124.36 0.000
0.10 2.049 1.010 145.59 0.223
0.20 1.740 1.040 158.66 0.348
0.30 1.514 1.089 166.90 0.432
0.40 1.349 1.159 172.10 0.498
0.50 1.227 1.252 175.22 0.556
0.60 1.138 1.373 176.64 0.613
0.70 1.074 1.527 176.33 0.677
0.80 1.032 1.722 173.88 0.754
0.90 1.008 1.969 168.47 0.855
1.00 1.000 2.283 158.75 1.000

180.00 1.00

0.90
170.00 0.80

0.70
160.00
0.60
(KPa)

150.00 0.50

0.40
 0.90
170.00 0.80

0.70
160.00
0.60
P (KPa) 150.00 0.50

0.40
140.00
0.30

0.20
130.00
0.10

120.00 0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 0.00 0.10 0.20

x1-y1
STEMA BINARIO:
ETANOL (2)
Parmetros de interaccin
ak1 ak2 ak3
0 26.76 164.5
476.4 0 986.5
84 156.4 0
Psati(KPa)

66.00

64.00

62.00

60.00

58.00

56.00

54.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

x1-y1

1.00

0.90

0.80

0.70

0.60

0.50

0.40
0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

x1-y1