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Abstract This paper presents the development of a novel CNT-metal, e.g., 0.4eV for CNT(8,0)-Pd [8]. Furthermore,
thermal ink-jet printer head prototype using full carbon- as their phonon spectra are similar due to sp2 bond,
based microbubble generators with carbon nanotubes as the CNT-graphene junction has very low interface thermal
heating elements and graphene as electrodes. Meanwhile, each
microbubble generator is equipped with a carbon nanotube resistance [9].
sensor to real-timely probe the temperature of its surrounding The thermal conductivity of CNT is very high and
micro-environment. With an array of microbubble generators anisotropic, i.e., the tubular is three orders bigger than across
and sensors fabricated on quartz glass, as well as a microfluidic the axis [10], [11]. The one-dimensional tubular structure of
structure constructed by the micromachined silicon, the printer CNTs restricts their heat conduction and it is dominated in
head prototype is formed by an anodic silicon-glass bonding
process with several scattered graphene film flakes as medium. the tubular direction. Its joule heating density can be thus
Droplet ejection with volume as tiny as 0.03 pl corresponding very high and localized when working as a heating element.
to a very high spatial resolution of >2000 dpi driven by two Therefore, we proposed and fabricated a low power and high
microbubble valves is demonstrated by the printing unit in the resolution multiwalled CNT based microbubble generator with
prototype. Increasing the input power cannot only speed up the gold electrode [12], [13], and built a printer head structure with
bubble nucleation and growth, but also improve the utilizing
efficiency of electric heating energy. The experimental detected silicon microfluidic structure micromachined by wet etching
temperature variation in the printing unit reveals its nonlinear method [14].
heat convection property by comparison with the theoretical Graphene has the highest thermal conductivity among
calculation by finite-element analysis. [2017-0048] the existing known materials which is also anisotropic,
Index Terms Thermal ink-jet printing, carbon nanotubes- the in-plane is several hundreds times bigger than the out-of-
graphene hybrid structure, MEMS, microbubble generator, full plane [15]. In this paper, we use graphene to replace the metal
carbon-based device. electrodes of our previous CNTs based microbubble generator.
Combing their excellent electrical and thermal contact,
I. I NTRODUCTION
the joule heating of CNTs-graphene structure is theoretically
XIANG et al.: THERMAL INK-JET PRINTER HEAD PROTOTYPE WITH FULL CARBON BASED MICROBUBBLE GENERATOR 3
XIANG et al.: THERMAL INK-JET PRINTER HEAD PROTOTYPE WITH FULL CARBON BASED MICROBUBBLE GENERATOR 5
still too big and it will be decreased a little bit in our modified
layout design. Meanwhile, increase the input voltage to speed
up the bubble generation might also increase the chance of
bubble merging. The effort to speed up the bubble nucleation,
growth and droplet ejection will be done in the future after
our image capture system is upgraded.
So far, the total power consumption is still compara-
ble to our previous CNT-metal based microbubble genera-
tor, we speculate that the total thermal conductivity of the
fabricated CNT-grpahene hybrid structure is affected by its
inner interface thermal transport, i.e., lateral CNT separation
and interlayer distance between graphene sheets , e.g., very
dense packing of long CNTs and graphene could significantly
increase the out-of-plane thermal conductivity[9], [21]. The
thermal management can be later tuned with widely spaced
short CNTs with single layer graphene in the hybrid structure.
The smallest droplet ejected in our current experimental
has a diameter about 45m, i.e., a volume of 0.03pl at
minimum, indicating a very high spatial/printing resolution of
>2000/4000 dpi, with reference to Tsengs work [20].
D. Detection of Microenvironment
In general, CNT has a negative temperature coefficient
of resistance [22], our CNTs are measured to be -0.14%.
As shown in Fig. 1(b), each microchamber has two CNT
temperature sensors located at the outsider of two bubble
generators. During the microbubble generation and droplet
ejection, our lab-built measurement system collects the real-
time resistances of CNT sensors and the temperature in
microchamber can be figured out.
Fig.8(a) plots the real-timely measured resistance and
Fig. 7. CCD image sequences of micro-bubble growth (a)-(c) and the calculated temperature variations of sensor #1 (closer to the
trajectory of the corresponding droplet ejected with nozzle position shifted (d). chamber neck, the other sensor #2 is broken unfortunately)
(e) The bubble growth rate in the tested printing unit. during a printing unit testing. When the first bubble nucleated
on the microbubble generator #1 (near the chamber neck,
initial resistance 65 k) at 4.2s, the sensor resistance
reached 30m and 25m (at 1# and 2#), and a droplet was decreased to 704.3k with a R of 235.7k (under
ejection from the nozzle (see Fig. 7(d)) was captured. It is constant current of 200nA, initial resistance 940k at 25),
found that, under the same conditions, the bubble nucleation corresponding to 204.1 at that moment. When the second
time of #1 and #2 are 2.9s and 3.5s shorter respectively than bubble nucleated on the microbubble generator #2 (initial
they worked separately. Apparently, when two generators resistance 104 k) at 5.1s, the sensor resistance reached its
work at the same time, their efficiency to heat the equivalent lowest value of 692.4k with the R of 247.6 k, accordingly
volume of ink are higher than they work alone, the rates of the temperature was the highest 213.1. Afterwards,
bubble nucleation and bubble growth are accelerated. the resistance and the temperature almost kept constant with
Fig. 7(e) depicts the relationship between the bubble diam- slight fluctuation of 10 k and 10 till the droplet ejection.
eter and the duration time of input voltage. The bubbles grow Compared with the transient simulation of temperature
fast at the beginning, and their rates are decreased due to more at the center of microbubble generator and sensor by finite
convection and higher pressure in microchamber that makes it element analysis (FEA) using ANSYS (the strong and
need more input power to maintain the bubble growth rates. weak convection coefficients are 104 W/m2 K and 103 W/m2 K,
Previous research has shown that the bubble valve structure respectively.) as shown in Fig. 8, we can find that the real time
and bubble merging to cut off the droplet can efficiently temperature curve is very similar to the transient FEA calcu-
eliminate the satellite droplet [19], [20]. In our current exper- lation under strong convection at temperature above 100, and
imental results, a satellite droplet appeared and disappeared it is the converse around 100 or less. Therefore, we can infer
0.01s later because that the merging of two microbubbles did that the heat transfer of the microenvironment in a printing
not happen before droplet ejection although they did in an open unit during microbubble generation and droplet ejection is a
water circumstance testing before bonding to form the closed weak convection before the phase change from water to vapor,
structure. It is conjectured that the distance of two heaters is and strong convection after that and till bubble generation.
This article has been accepted for inclusion in a future issue of this journal. Content is final as presented, with the exception of pagination.
IV. C ONCLUSION
So far, our work demonstrates a successful application
of full-carbon device in MEMS. A novel thermal ink-jet
printer head prototype with carbon nanotubes-graphene hybrid
structure based microbubble generator and carbon nanotubes
based temperature sensor is fabricated and characterized. Very
tiny droplet with volume of 0.03pl corresponding to very
high resolution spatial/printing resolution of >2000/4000 dpi
is obtained by driving two microbubble generators in a printing
unit with nozzle diameter less than 10m. The real-time
temperature probing of microbubble generation and droplet
ejection reveals the dynamic behavior of heat convection in
the printing unit, providing evidence for precise control of
thermal ink-jet printing. Further scaling down the nozzle and
microchamber of printing unit can reduce its power consump-
tion and improve the resolution. We are seeking a feedback
Fig. 8. (a) Experimentally measured resistance and calculated temperature control of the microbubble generator to benefit its application
of the sensor during bubble generation and droplet ejection of a printing unit, in our printer head and other MEMS devices and systems.
with comparison to a transient (a) and steady (b) temperature simulation of
the temperature sensor and nearby microbubble generator (MG) by ANSYS.
The strong and weak convection coefficient underwater is 104 W/m2 K and ACKNOWLEDGMENT
103 W/m2 K, respectively.
The authors would thank Analytical and Testing Center
in Huazhong University of Science & Technology, Micro/
Nanofabrication Platform in Wuhan National Laboratory for
Moreover, there exists a lagging of temperature rising at the Optoelectronics.
beginning, which means the coefficient at lower temperature
is actually smaller than that in the FEA calculation. Overall,
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