Sol - 2

1
AITS-CRT-II-PCM (Sol)-JEE(Main)/16
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ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TEST II

Top 500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
(Main)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. D B B
2. A B C
3. D C B
4. D A A
5. B B A
6. D B A
7. C B A
8. C C B
9. B A B
10. C D C
11. C D D
12. A B D
13. A C A
14. B C B
15. C B B
16. D C B
17. B B C
18. B C B
19. B B C
20. A B C
21. A D D
22. B B D
23. C B D
24. A C A
25. B C C
26. C A C
27. C B B
28. A B B
29. C B D
30. C B A
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2
Physics PART I
SECTION A
1. D
Sol. TB TA = 1.4 30 = 42.
2. A
hc 1
Sol. RhCZ2 1
4
1 1 1 1
: : : =1:1:4:9
1 2 3 4
1 1
1 : 2 : 3 : 4 = 1: 1 : :
4 9
3. D
Sol. Magnetic field is decreasing with time hence induced current will oppose this decrease in
magnetic field and it is independent of presence or absence of the wire.
4. D

Sol. B

= (iA) B
5. B
1 1 1
Sol. r = 4 mm.
r r1 r2
6. D
m T 2m 1 T
Sol. f ; n
2 4
7. C
RT
Sol. v
M
8. C
Sol. P (g a)h
9. B
Sol. Path difference = 10.
10. C
2h
Sol. T Tshm 4
g
11. C
3
n RT n RT
Sol. f1 ; f2
2 M 2( x) M
12. A

Sol. f ande 0.6r (r Radius)
2 L 2e
13. A
4/5

vdt
0
Sol. v avg 4/5
dt
0
14. B
Sol. x 2 sin 3t
y 2 2cos 3t
sin2 3t cos2 3t 1
15. C
1
Sol. Speed of light = .
0 0
16. D
2
ifinel
10
Sol.
di VL
L
dt initial
1
5 3
= seconds.
2 20
2
3
17. B
90
Sol. Total momentum =
90
(dm)v cos
M
dm = Rd
R
M 2Mv
Total momentum = R vRd cos
18. B
Sol. P1 = P 2
di1 di
i1L1 i2L 2 2 (i)
dt dt
4
di
and L (ii)
dt
19. B
Sol. Displacement method
u
2 (I) & D u u = 30 cm ...(II)
Du
3u = 2D (I) & D 2u = 30 cm
1 1 1
And
f Du u
f = 20 cm.
20. A
Sol. Applying momentum conservation in the direction of string
3 3
mu = 2 mv v = (u)
2 4
21. A
10v d
Sol. f = v = .
d 10
d
Maximum path diff. can be . Hence, number of maximum will be 6.
3
22. B
n1D
Sol. y n(red)
d
(n 1) 2D
y nt(blue)
d
Apply yn (red) = yn+1 (blue)
n(r) = (n + 1)b
n(7800) = (n + 1) (5200)
n=2
23. C
10 cm
10 10 15
Sol. Xapp =
3/2 3/2 1 15 cm
40
= 15 = 28.33
3
3/2
24. A
Sol. vI m2 v o
9 1.8 i
= ( 5i)
25
5
25. B
Sol. Field at the x-axis due to both current one same (along + z-axis) which is minimum distance
between them.
26. C
Sol. F = mg
4
F = 2 105 v = (1.5 103 )3 103 10
3
2
v= (2.25) = 4.7 m/s
3
27. C
Sol. Loss in KE = ki kf
1 1 1
= (40) 4 2 (60)(2)2 (100) (2.8)2 = 48 J.
2 2 2
28. A
Sol. I number of electrons incident
K.E. = h .
29. C
V
Sol. E= directed Ir to an equipotential surface.
r
30. C
Sol. For no deviation
(1 1)A1 = (2 1)A2
4o(1.54 1) = (1.72 1)A2
4 0.54
A2 = = 3.
0.72
6
Chemistry PART II
SECTION A
1. B
Sol. O
C CONH2 CONH2
O 2NH3 H

C
COONH4 COOH
O (P) (Q)
NH2
OBr
Q
COOH
2. B
Sol. P = CaO, Q = Ca3N2, R = Ca(OH)2, S = NH3, T = CaCO3, U = NH2CONH2
3. C
Sol. Tf0 - Tf = i Kf m = i Kf w 1000
M W
342 1000
0 (10.936) = 5 1.86
342 W
On solving, W = 850.4 850 g
Water taken = 1000 g
Water left = 850 g
Ice formed = 1000 850 = 150 g
4. A
Sol. No. of radial nodes = (n l 1)
For 4s orbital, it is 3
For 4p orbital, it is 2
For 4d orbital, it is 1
For 4f orbital, it is 0
5. B
Sol. Small size atomic orbitals undergo better overlap than larger atomic orbitals.
6. B
Sol. It attains a half filled electron configuration by gaining one electron. For identical outermost
electron configuration, smaller atoms are more electronegative than larger atoms.
7. B
2
2 2
Sol. Reaction quotient(Q) = 2
2
2
Since Q > KC(0.4), the reaction will proceed towards backward direction.
8. C
7
Sol. en = NH2CH2CH2NH2 is a bidentate ligand. 3 en molecules form six bonds with the metal or
metal ion. Hence the coordination number is six.
9. A
1 10
Sol. Cu [Ar]184s 3d
10
Cu(I) 3d
Since no unpaired d-electron is present it does not show colour in +1 oxidation state.
10. D
Sol. CH3 CH3 CH3
Cl
P, Q, R = , ,
Cl
CH2Cl
Cl
S=
CH3 COOH
MnO 4 ,OH

Cl Cl
11. D
Sol. CN HCl HCN Cl forward shift
Weak acid
2
Be KOH Be OH2 forward shift
PPt.
2
Ag Ag CN2

2CN forward shift
Complex
12. B
Sol.

Fe OH2 H2SO4
FeSO4 H2O
To prevent the hydrolysis of FeSO4 to Fe(OH)2, H2SO4 is added. It makes the reaction proceed
towards backward direction.
13. C
Sol. (C) produces the most stable 2o-allylic carbocation.
14. C
Sol. It is SHE which potential is zero volt.
15. B

Sol. 2NaHCO3 Na 2CO3 CO2 H2O
16. C
Conc.H2SO4
Sol. C12H22O11 12 C 11 H2O
17. B
8
Sol. H OH H
2 NH OH
CH3CHO

C N + C N
H
CH3 CH3 OH
Products display geometrical isomerism and the geometrical isomers are called diastereomers.
18. C
H2O
Sol. Al4 C3 Al OH3 CH4
19. B
+
Sol. Na ions are present at octahedral voids which are found at edge centres as well as body centre.
20. B
Sol. Electron withdrawing groups, like NO2, activates benzene ring for nucleophilic substitution
reaction, when they are ortho and para w.r.t to the leaving group.
21. D
Sol. Due to its strong interparticle force as compared to other given gases. van der Waals force
operates, which depends on atomic mass of monoatomic gases.
22. B
Sol. Inorganic benzene is B3N3H6.
23. B

Sol. Ca CH3COO 2 CH3 COCH3 CaCO3
24. C
Sol. The n-factor of compound in(C) is 8, higher than others.
25. C
Sol. Al(OH)3 does not form salt with NH4OH as it provides less OH.
26. A
Sol. Lindlars catalyst forms cis-alkene.
27. B
Sol. In exothermic process, heat is transferred from system to surrounding. The entropy of
surrounding increases.
28. B

Sol. Ni impure 4 CO
Ni CO 4 Ni pure 4CO
29. B
Sol. (B) contains benzylic hydrogen atom.
30. B
Sol. This is a square planar complex, so, Cu2+ undergoes dsp2 hybridization.
9
Mathematics PART III
SECTION A
1. B
1 R
Sol. Let the slopes of PQ and PR be m and respectively. Since
m
PQR is an isosceles triangle PQR PRQ
1
2
m2
m 2x + y = 3
1 2m 2
1
m
slope of QR 2
1
m 2 1 2m m 3 or P (2, 1) Q
3
So the equation of PQ and PR are
1
y 1 3 x 2 and y 1 x 2
3
Thus, joint equation representing PQ and PR is
3 x 2 y 1 x 2 3 y 1 0
2 2
3 x 2 3 y 1 8 x 2 y 1 0
3x 2 3y 2 8xy 20x 10y 25 0
2. C
15 15
Sol. Im z 2m 1
Im z 2m 1

m 1 m1

Im

z 1 z2

15

1 z2

1 z30
Im
zz
1
Im 1 cos 30 i sin 30
2i sin
1 1

2sin 2sin 3o
3. B
1
Sol. Let p = probability of getting a tail in a single trial
2
n = number of trials = 100 and X = number of tails in 100 trials.
r 100 r 100
100 1 1 100 1
We have P X r Cr Cr
2 2 2
10
Now, P x 1 P x 3 ....... P X 49
100 100 100
1 1 1
100 C1 100 C3 ...... 100 C49
2 2 2
100
1
100 100
C1 C3 ......... C49
2
100

100
But C1 C3 .......... C99 299
100 100
100
Also, C99 100C1,
100
C97 100C3 ,.......100 C51 100C49
Thus, 2 100
C1 100 C3 ......... 100C49 299
100 100 100 98
C1 C3 ...... C49 2
298 1
Probability of required event
2100 4
4. A
1/ x
Sol. Let y 1 x
1 1 x2 x3 x 4
log y log 1 x x .....
x x 2 3 4
2 3
x x x
1 ......
2 3 4
x x2 x x2
1 .... ......
2 3 2 3
ye ee
2
x x2 1 x x2
e 1 ..... ....... ......
2 3 2! 2 3
2
1
2 1 1 1
y e ex ex 0 x 0 x .....
2 3 2 2
(0 (x) in terms containing x)
1
ye ex
2 1 1 11
lim 2
e e
x 0 x 3 8 24
5. A
Sol. Since A.M. G.M., We get
1 2 tan2 tan2
x x x2 x tan
2 x2 x x2 x
6. A
Sol. Let ABO then CBL 90o , CL being perpendicular to x axis. The coordinates of C
are (OL, LC).
OL OB BL 3 5 sin
11
C (7, 3)
4 A (0, 4)
3 5 7
5
3
CL 5 cos 5 3
5 5
So the coordinate of C are (7, 3) and
the equation of the circle having C as
4
centre and touching x axis is 5
2 2 2
x 7 y 3 CL 9
x 2 y 2 14x 6y 49 0 90o
O 3 B (3, 0) L
7. A
2
35a a3 3
Sol. Equation of the parabola is y x whose vertex is
16 3 4a
3 35a 105
x , y xy .
4a 16 64
8. B
1
Sol. We have 5 2 6 .
5 2 6
Therefore, 0 5 2 6 1 .
n
Let F 5 2 6 . Then 0 F 1 . Also.
n n
m f F 52 6 5 2 6
2 4
2 C0 5n C2 5n 2 2 6 C 5 2 6
n4
..... 2k where k is some positive integer.
4
Hence, f F 2k m is a positive integer. Also, 0 f F 2 . Therefore, f F 2k m is a
1 1
positive integer. Also, 0 f F 2 . Therefore, f F 1 . Now, f 1 F
1 f F
1 5 2 6
n n

52 6
n n
5 2 6 5 2 6 1
m f F 1 m
9. B
Sol. All the function in (a), (b), (c) are defined on 1, 1 . Let
g x x 2 x sin x cos x log 1 x . (The choice of g is clear as x 2 ,cos x log 1 x
are even function and x,sin x are odd function). Then

g x x 2 x sin x cos x log 1 x x 2 x sin x cos x log 1 x f x .
12
10. C
Sol. According to the given conditions, c12 c 22 c 32 1, a.c 0, b.c 0 and
3 a1b1 a2b 2 a3b3
cos
2 6 a a22 a32 b12 b22 b32
2
1
Thus a1c1 a2c 2 a3c 3 0, b1c1 b2c 2 b3 c 3 0 and

3 2 1/ 2 1/ 2
2

a1 a22 a32 b 2
1 b 22 b 32 a1b1 a2b2 a3b3
2
a1 b1 c1 a1 a2 a3 a1 b1 c1
Now, a2 b2 c 2 b1 b 2 b3 a2 b2 c2
a3 b3 c3 c1 c 2 c 3 a3 b3 c3
a12 a22 a23 a1b1 a 2b2 a3b3 a1c1 a2c 2 a3 c 3
2 2 2
a1b1 a2b2 a3b3 b b b
1 2 3 b1c1 b 2c 2 b3 c 3
a1c1 a2c 2 a3c 3 b1c1 b2c 2 b3c 3 c12 c 22 c 22
a12 a22 a32 a1b1 a2b 2 a 3b3 0
2 2 2
a1b1 a2b 2 a3b3 b b b
1 2 3 0
0 0 1
2
a a a b b b a b a b
2
1
2
2
2
3
2
1
2
2
2
3 1 1 2 2 a3b3
3
a a a b b b a a
2
1
2
2
2
3
2
1
2
2
2
3
2
1
2
2
a23 b12 b22 b32
4
1 2

4

a1 a22 a23 b12 b22 b23
11. D
1 1/2 t
Sol. Put cos x t, so that sin x dx 2dt and I e 2 sin t 3 cos t 2 dt
2 1/2
t t
As e sin t is an odd function, and e cos t is an even function,
1/ 2 1/ 2 1/ 2
I 12 e t cos t dt 12 e t cos t 0 12 e t sin t dt
0 0
1 1/ 2 1/ 2
I 12 e cos 1 12 e t sin t 0 12 e t cos t dt
2 0
1 1
2I 12 e cos sin 1 .
2 2
12. D
Sol. Suppose the given points lie on the line lx my n 0 then a, b, c are the roots of the equation.

It 3 m t 2 3 n t 1 0
3 2
or lt mt nt 3m n 0
m
a b c
l
13
n
bc ca ab
l
3m n
abc
l
Eliminating l, m, n, we get abc 3 a b c bc ca ab
bc ca ab abc 3 a b c
13. A
Sol. Let t x x 2 b2
1 1 x 2 b2 x

t x x2 b2 b2
b2 b2
t 2x and t 2 x 2 b2
t t
b2

Thus 2 a x x x 2 b 2 2a t

t
t

2at t 2 b 2 a2 b 2 a2 2at t 2
2
a2 b2 a t
Therefore, y 2 a x x
x 2 b2 a2 b2 .
Hence, the maximum value of y is a 2 b 2 . This value is attained at t a or x

a 2
b2 .
2a
14. B
Sol. We know that 1 3 5 ......... 2k 1 k 2
2 2 2
p 1 q 1 r 1
Thus, the given equation can be written as
2 2 2
2 2 2
p 1 q 1 r 1
Therefore, p 1, q 1, r 1 forms a Pythagorean triplet. As p 6, p 1 7 .
The first Pythagorean triplet containing a number > 7 is (6, 8, 10).
We may take p 1 8, q 1 6, r 1 10
p q r 21
15. B
2
Sol. We divide LHS by 4 and C1 by , C2 by and C3 by on the RHS to obtain.
2 3 4
1 1 1 1
p q r s t

3 1 3
1 1 1

1 2 3
1 2 5 1

3 4
1 2 1 3

14
1 1 1 1 1 1
Taking limit as , we get p 1 5 1 0 4 0 8
1 1 3 0 0 2
[using R2 R 2 R1, R 3 R3 R1 ]
16. B
1 1 1
Sol. If p1,p2 ,p3 are altitudes from A, B, C respectively, then ap1 bp2 cp3
2 2 2
2 2 2
p1 , p2 , p3
a b c
By the law of sines
a b c
k say
sin A sinB sinC
2 2 2
p1 , p2 , p3
k sin A k sinB k sinC
Now, sin A,sinB, sin C, are in A.P.
p1,p2 ,p3 are in H.P.
17. C
1 n 1 n
Sol. tan 1 tan1
1 n n 1 1 n n 1
tan1 n 1 tan1 n
So that L.H.S. of the given equation is
tan1 2 tan1 1 tan1 3 tan 1 2 ...... tan1 n 1 tan1 n .
n 1 1
tan 1 n 1 tan1 1 tan1
1 n 1
n
tan1
n2
n n
So that tan 1 tan1 .
n2 n2
18. B
a b 2c 3
Sol. The given relation can be written as
a c b c a b c
a b 2c a b c 3 a c b c
2

a b 3c a b 2c 2 3 ab ac bc c 2
a 2 b2 c 2 ab
a2 b2 c 2 ab 1
cos C
2ab 2ab 2
C 60o
15
19. C
Sol. Let l, m, n be the direction ratios of the line lying in the three planes, then the line is perpendicular
to the normals to these planes, so that we have
l cm bn 0
cl m an 0
bl am n 0
1 c b
Eliminating l, m, n from these equations we get c 1 a 0
b a 1
2
1 a c c ab b ac b 0
a 2 b2 c 2 2abc 1
20. C
3
Sol. Since 5 2 , we have sin5 0, so sin1 sin 5 5 2 . Therefore, the given inequality
2
can be written as 5 2 x 2 4x or x 2 4x 2 5 0
4 16 4 2 5 4 16 4 2 5
x x 0
2 2

x 2 9 2 x 2 9 2 0

x 2 9 2 , 2 9 2
21. D
2
Sol. h x f 1 x But y f x x 1
x y 1 so f 1 x x 1.g x h x 3
x 3 1
22. D
Sol. Put log x t, or x e t , so that
b 1
I log t 2 e t dt
a
t
where a log ,b log
b 1 1 1
log t 2 et dt
a
t t t
b
1
log t e t [use e x f x f ' x ex f x ]
t a
1 1
logb eb loga ea
b a
1 1
log log log log .
log log
16
23. D
Sol. Note that x 0, x 1
loga x 2
Using a a, we get 1 x 9 x 4, 2
Also x > 0, we get x 4
24. A
Sol. Let the coordinate of A, B, C be t i , 2t i 2
i 1, 2, 3 respectively. The tangents at A and B are
t1y x t12 and t 2 y x t 22 which intersect at x t1 t 2 , y t1 t 2
So the vertices are P t1t 2 , t1 t 2 , Q t 2 t 3 , t 2 t 3 and R t1t 3 , t1 t 3
t1 t 2 t 2 t 3 t 3 t1
t1 t 2 t1 t 2 1
1
' t 2 t3 t2 t3 1
2
t 3 t1 t 3 t1 1
t1 t 3 t 2 t1 t 3 0
1
t 2 t1 t 3 t 2 t1 0
2
t 3 t1 t 3 t1 1
1
t1 t 3 t 2 t1 t 2 t 3 2 '
2
25. C
1
Sol. Let x 0 cos , then x1 1 cos cos , x 2 cos 2 , x 3 cos 3 .... and so on.
2 2 2 2
1 x 20
So that
x1x 2 x3 .......to infinite
sin

cos cos 2 ......cos n ......infinite
2 2 2

2 sin cos
2 2

cos cos 2 .....cos n .....infinite
2 2 2

22 sin 2 cos 2
2 2

cos 2 cos 3 .......cos n .....infinite
2 2 2

2n sin n
lim 2
n
cos n1
2
17

sin 2n 1
lim
n
cos
2n 2n1
1 x2
0
So that cos cos x0
x1 x 2 .....inf
26. C
1 1
Sol. I tan1 dx
0 1 x 1 x

1 1 x x
tan1 dx
0 1 1 x x

1
tan1 1 x tan 1 x dx
0
1 1
tan 1 1 x dx tan1 x dx
0 0
1 1
tan 1 1 1 x dx tan1 x dx
0 0
1
2 tan1 x dx
0
27. B
Sol. Since 3 does not occur in 1000, we have to count the number of times 3 occurs when we list the
integers from 1 to 999. Any number between 1 and 999 if of the form xyz where 0 x, y, z 9 .
Let us first count the numbers in which 3 occurs exactly once. Since 3 can occur at one place in
3
C1 ways, there are 3 C1 9 9 3 92 such numbers. Next, 3 can occur in exactly two places
in 3

C2 9 3 9 such numbers. Lastly, 3 can occur in all three digits in one number only.

Hence, the number of times 3 occurs is 1 3 9 2 2 3 9 3 1 300
28. B
100 100 r 1/8 r
Sol. r 1 th
in the expansion of 51/6 21/8
is t r 1 100 Cr 51/6 2
100 r r
As 5 and 2 are relatively prime, t r 1 will be rational if and are both integers. i.e. if
6 8
100 r is a multiple of 6 and r is a multiple of 8. As 0 r 100, multiples of 8 upto 100 and
corresponding value of 100 r are
r = 0, 8, 16, 24,..88, 96
100 r 100, 92, 84, 76,......12, 4
Out of values of 100 r, multiples of 6 are 84, 60, 36, 12
there are just four rational terms.
number of irrational terms is 101 4 = 97
29. D
2
Sol. We have f x x 2 2bx 2c 2 x b 2c 2 b 2
min f x 2c 2 b2
18
Also g x x 2 2cx b2
2
b2 c 2 x c
so max g x b2 c 2
Since min f x max g x ,
so 2c 2 b2 b2 c 2
c 2 2b 2 c 2 b .
30. A
Sol. Let the equation of the line through (1, 2) be y 2 m x 1
2m 1
If p denotes the length of the perpendicular from (3, 1) on this line, then p
m2 1
4m2 4m 1 4m 3
p2 2
4 2 s (say),
m 1 m 1
then p2 is greatest if and only if s is greatest
Now
ds

m2 1 4 2m 4m 3
2
dm m2 1
2 2m 1m 2
2
m 2
1
ds 1
0m , 2
dm 2
ds 1
Also 0 if m
dm 2
1
0 if m2
2
0 if m 2
So s is greatest for m = 2 and thus equation of the required line is y 2x

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ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST II

Q. No. PHYSICS CHEMISTRY MATHEMATICS

Mathematics PART III

Thus a1c1 a2c 2 a3c 3 0, b1c1 b2c 2 b3 c 3 0 and

Hence, the maximum value of y is a 2 b 2 . This value is attained at t a or x

So s is greatest for m = 2 and thus equation of the required line is y 2x

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