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PhysicalChemistry 6. Ameasureofdisorderlinessinasystemisgivenby
INSTRUCTION:Selectthecorrectanswerforeachofthefollowing a. Freeenergy
sections.Markonlyoneanswerforeachitembyshadingthebox b. Enthalpy
correspondingtotheletterofyourchoiceontheanswersheet c. Heat
provided.STRICTLYNOERASURESALLOWED.Usepencilno.1only. d. Entropy
1. Chemicalequilibriumreactionsarecharacterizedby 7. Thereisnochangeininternalenergyofanidealgasduring
a. G >0 a. Adiabaticexpansion
b. G <0 b. Adiabaticcompression
c. G =0 c. Isothermalexpansion
d. G = G o d. Noneoftheabove
8. Theefficiencyofaheatengineislimitedby
2. Spontaneousreactionsarecharacterizedby a. Firstlawofthermodynamics
a. G >0 b. Secondlawofthermodynamics
b. G <0 c. Thirdlawofthermodynamics
c. G o =0 d. Noneoftheabove
d. G =0
9. Nonidealgasbehaviorislikelytobeobservedat
3. Capillaryactionisdueto: a. Lowpressureandlowtemperature
a. Cohesion b. Highpressureandhightemperature
b. Viscosity c. Highpressureandlowtemperature
c. Gravity d. Lowpressureandhightemperature
d. Surfacetension 10. Inanequilibriumreaction,KpequalsKcwhen
a. Reactantsandproductsareallgases
4. Anidealgashasacompressibilityfactorof b. Temperatureisconstant
a. 1 c. Reactantsandproductshaveequalnumberofmoles
b. 2 d. Reactantsandproductsareallliquids
c. PV
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20. AsealedisothermalcontainerinitiallycontainsthreemolesofCO 24. A + B C + D
gasandfourmolesofO2gas.Thefollowingreversiblereaction A+C D + E
tookplace: Amultistepreactiontakesplacebytheabovemechanism.
2CO( g ) + O2 ( g ) U 2CO2 ( g ) Whichofthespeciesshownaboveisanintermediateinthe
Atequilibrium,thereweretwomolesofCO2inthecontainer. reaction?
Whatwasthetotalnumberofmolesofgaspresentinthe a. A
containeratequilibrium? b. D
a. 6 c. B
b. 4 d. C
c. 5
d. 7 25. Abulbisfilledwithargongasattheambientpressureandis
foundtocontain7.98gofargonatatemperatureT.Thebulbis
21. At1035oC,twomolesofrutheniumchangesfromthetothe
thenimmersedinabathwhosetemperatureis30oChotterthan
solidstate.The H forthetransitionis142J/mol.The
thefirstone.Thestopcockonthebulbisopenedsothatthe
surroundingcoolingbathisatSTP.Find S inJ/Koftheuniverse.
argongaspressurereturnstotheinitialvalue.Thebulbisnow
a. 1.040
foundtocontain5.33gofargon.Whatisthevalueofthefinal
b. 0.642
temperature?Theatomicmassofargonis39.9.
c. 0.823
a. 242oC
d. 0.217
b. 90.9oC
22. Determinethebarometricdecreaseinatmosphericpressurefrom c. 212oC
sealeveltoanaltitudeof1.8x106cm.Assumeairtobea d. 182oC
uniformgasofmolecularmass29,andauniformtemperatureof
0oC. 26. Ammoniadissolvesinwaterat20oCtogiveasolutioncontaining
a. 0.307 0.040molefractionofammonia.Thetotalvaporpressureofthe
b. 0.998 solutionis6.58x102atmandthevaporpressureforwateris
c. 0.105 17.00torratthesametemperature.ApplyingHenrysand
d. 304.1 Raoultslaws,calculatetheHenrysconstant.
36. Thevalveonacylindercontaininginitially15Lofanidealgasat
25atm,25oCisopenedtotheatmospherewherethepressureis 40. At1482Kand12atm,theequilibriumcompositionofsodium
760torr.Assumingthattheprocessisisothermal,howmuch vaporcontains3.10molesofNamonomerand0.624molesofNa
workisKJisdoneontheatmospherebytheactionofexpanding dimer.CalculatetheKpforthedimerizationofsodiumat1482K.
gas? a. 2.01x102
a. 0.86 b. 3.68x101
b. 3.64 c. 2.47
c. 4.28 d. 2.89x101
47. Whatisthepressureofacolumnofairataheightof10kmanda
temperatureof2oC?Assumethatthepressureatzeroheightis
760mmHgandthemolarmassofairis29.
a. 449
b. 340
c. 219
d. 759
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SITUATIONALPROBLEMS: 55. FindthestandardenergyinkJofthecombustionreactionof
propeneat25oCassumingallreactantsandproductsbehaveas
Situation#01Theactivationenergyforthethermaldecomposition
ofgaseousacetaldehydeis190.37kJ/molandthemolecular idealgases.
diameter,,ofamoleculeofacetaldehydeis5x108cm.This a. 2068
decompositionisasecondorderreaction. b. 2075
c. 2069
51. Determinethenumberofmoleculescollidingpermilliliterper d. 2094
secondat800Kand760torr.
56. FindWinkJofthecombustionreactionofpropeneat25oC.
a. 2.10x1031
a. 2.0
b. 4.75x1015
b. 1.0
c. 9.17x1021
c. 4.0
d. 2.88x1028
d. 0
52. Calculatethesecondorderrateconstant,k,inL/molsec. Situation#03Akilogramofacetylenewascompressedfrom102L
a. 6.9x102 to103Lataconstanttemperatureof150oC.Calculatetheminimum
b. 7.7x102 workthatmustbeexpendedinthecompressionprocessassuming
c. 8.3x104 thegastobe
d. 6.0x1023
57. IDEAL.
a. 1.09x103J
53. DeterminethepreexponentialfactorAat800K.
b. 3.12x105J
a. 1.10x1013
c. 1.11x105J
b. 2.07x1011
d. 3.08x103J
c. 1.86x1015
59. IfacetylenesatisfiesthevanderWaalsequation,whatwouldbe
54. FindthestandardenthalpyinkJ/molofthecombustionreaction itscriticalpressureinatm?
ofpropaneat25oC. a. 282
a. 2076 b. 197
b. 2068 c. 50.8
c. 2060 d. 1371
d. 2084
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Situation#04Amovingboundaryexperimentwasperformed 64. theadiabaticexpansioninkJwherethefinaltemperaturewas
initiallyat25oCwith0.100MKClonthebottomand0.0700MNaCl 243oC.
ontop.ThetransportnumbersofK+andNa+ionsinthesesolutions a. 16.7
are0.490and0.388,respectively.Theboundarymoveddownward. b. 9.2
Thecrosssectionalareaofthetubewas0.100cm2.Thecharge c. 5.8
passedthroughwas96.5coulombs. d. 23.1
60. Howmanyequivalentsweretransported? 65. FindtheenthalpychangeinJifthefinaltemperaturewas243oC.
a. 1.00x103 a. 24,210
b. 1.43x103 b. 59,164
c. 0.25x103 c. 8,090
d. 0.68x103 d. 32,358
61. Howfar(incentimeters)didtheboundarymove? Situation#06At1atm,120gofbenzeneisvaporizedatitsboiling
a. 65.4 pointof80.2oC.Theheatofvaporizationis94.4cal/g.
b. 79.2
c. 49.0 66. CalculateWinunitsofjoule.
d. 57.6 a. 4522
b. 293.6
62. Whilethecurrentwasflowing,whatwastheconcentrationin c. +293.6
mol/LofNaCljustabovetheboundary? d. +4522
a. 7.92x102
b. 2.18x101 67. Calculateqinjoules.
c. 8.14x104 a. 39497
d. 6.24x105 b. 7480
c. 15627
Situation#05Fourmolesofanidealnitrogengaswasexpanded d. 395
from10Lto25L.Theinitialtemperaturewas35oC.AssumeCv=2.5
R.Calculatethemaximumworkobtainedby: 68. Calculate U injoules.
a. 34975
63. theisothermalexpansioninJ. b. 44019
a. 92.7 c. 0
b. 9385.4 d. 15921
c. 7039.6
d. 2243.0
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Situation#07TwoequimolarsolutionsAandBwithequalvolume 73. S forwaterinJ/K.
ofsolutionsaremixedtogetherandthereaction A + B C occurs. a. 50.40
After60minutes,Ais75%reacted.HowmuchofAwillNOTreact b. 28.16
aftertwohoursif: c. 14.24
Situation#10GiventhedatabelowwhereVeisthevolume
adsorbedatequilibriumandVisthevolumeadsorbedattimet.The
adsorptionratefollowsfirstorderkinetics.
t(sec) 1380 3000 4260 7320
3
VeV(cm ) 0.284 0.179 0.121 0.043
78. DeterminetherateconstantKinpersecond.
a. 3.20x104
b. 1.80x102
c. 1.60x103
d. 2.30x105
79. Determinethevolumeadsorbedat3500secifVeisequalto0.451
cm3.
a. 0.281
b. 0.302
c. 0.325
d. 0.290
80. DetermineVeViftis800seconds.
a. 0.354
b. 0.418
c. 0.166
d. 0.201
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