Aiits 1416 PT III Jeem Jeea/main/solutions/solutions

1
AIITS-PT-III-PCM(Sol)-JEE(Main)/16
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ANSWERS, HINTS & SOLUTIONS
PART TEST-III
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. D A A
4551 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
2. D C C
3. A C A
4. B A D
5. B A B
6. A B A
7. A B B
8. C D A
9. C C B
10. A C B
11. C A A
12. B D C
13. C D A
14. A C D
15. C A C
16. D A C
17. D A B
18. A B A
19. A A B
20. A A A
21. A C C
22. A A C
23. B A B
24. C C C
25. B C C
26. D C B
27. D B C
28. B C C
29. A B B
30. D A D
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2
Physics PART I
SECTION A
0I 1 1
1. 4 . sin 450 sin 450
4 R 2R
0I 0I
2 1

2R 2R
10
2. V1 4 volts = 5 volt
44
100 4
10
V2 100 4
100 4
4
100 4
= 4.9 volts V1 V2 0.1 volt
3. Equivalent circuit,
8R
Rnet = A
11 B
4. VP V0 10 10 10 10
= - 200 volts.
5.
R C1+ C2
R
E i
i
10 10V 2
6. I1 +2I 10 = 0 5 + I I1 + 2I 10 = 0
3 I 1F
After solving we get, I1 = 0, Q = 0
I1
10/3
I I1
5V 1
1 q q q q 1 q
7. V= q ... =
40 1 2 4 8 40 1 1 2 20
3
8. Field at any internal point of the cavity.

4
E G C2 C1
3

Since C1 and C 2 are fixed (cavity being concentric with C 2 all the time), field remains constant
both in magnitude and direction.
9. If the fifth point P has identical charges the field at the centre of symmetry O would be zero.

Hence the field due to one single such charge at P would produce a field E , such that ( E + E ) =
0

E = E = ( 3i 4 j 2k )

this field will be four times E due to this rearrangement, hence the required field at O is

4 E = ( 12i 16j 8k ) units
10. If IG 0 then it becomes a balanced whetstone bridge

2 2 200
1 1m 100 cm
3 3 3
Q d d
12. E1 + +
0 2A 0 + +
Q/2
Qd + +
V E1d
2A 0 + +
+ +
13. Apply gaus theorem

qin q 1

E 4r 2 0
E
4 0 r 2
E 2 field depends only on r.
r
R V I
14.
R V I
R V I
100 100 100
R V I
3%
17. Magnetic field is zero at the centre due to symmetrical current distribution.
18. A
2 2
2
2 2
B
2 0 I/ 4 a
2 0 I / 4 2 2
19. B at O 0
4 a / 2 5 4 a 5 5 a a
20I 0I 30I

4 5a 4a 5 4 5a
4
20. Due to electrostatic shielding, the ratio will be 1.
21. When key is open

q1 = CE
when key is closed
E
q2 C R2
R1 R2
q CE R2 R1 5
1 R1 R2
q2 CER2 R2 3
22. If I1 is current in ACDB then

0 i1 0 i2
. .
4 r 4 4r
i1 1

i2 4
1 i
i1 i
5 5
23. From symmetry the currents in segment gh is zero. Thus, the equivalent resistance R is given by
1 1 1 1 1 3 2
R
R 4 4 2 2 2 3
10
Current in eh = 2.5A
4
Potential difference across eh = 5V
24. It is a balanced Wheatstone bridge for capacitor. Consequently the potentials of points a and b
are equal. Thus energy stored in the capacitor is zero.
25. Let after steady state the charges on the capacitor be q1 and q2
q1 = CV, q2 = CV where v is the potential difference between the plates.
Also from charge conservation
q1 + q2 = 0
V=0
1 1
Thus, final energy stored in the capacitors = CV2 + CV2 = 0
2 2
q2 q2 q2
Initial energy stored =
2C 2C C
Thus, heat developed in the resistor = q2/C
26. Initial capacitor is charged to Q/2

2
1Q 1 1 Q2 1
Energy stored in capacitor = = CE2 = Ui
2 2 C 8 C 8
1
Finally energy stored in the capacitor, Uf = CE2
2
5
3 3
Work done by the battery = CE E CE 2
2 2
3 3 1 1
Heat energy lost = CE2 (Uf Ui) = CE2 CE2 CE2
2 2 2 8
3 1 1 9
= CE 2 CE 2
2 2 8 8
27. The equivalent circuit is P

2 2
Q 0.5 A 2
P I2 2 Q
Current flowing through 3 resistance 2
= 3/3 = 1 Amp 3 1A 0.5 A 2
B
Current flowing through P to Q is also A I1 3
1 amp. 1A
From the figure current flowing through
3V 3V
AB is 1 + 0.5 = 1.5 Amp
28. By using the relation

0 i
B where is in radian
4 r
Here = 180 i.e.
0I
So, Bp =
4r
29. Let x = a potential is zero (region II)

q 2q
k k
a a a
a = a
So, in the region II,
Potential is zero and can be proved.
A solution can also found in region I (x = a/3).
30. In the steady state i i

a
E2 iR1 iR1 E1 iR1iR1 = 0
R1 R1
E2 E1 = 4iR1 E2
R2
E 2 E2 2.1 i
I= = (6.3 2.1)/(41.7) = E1 R1 i
4R1 3.4 E2
R1 C
Solving, we get, Va Vb = iR1 + E2 iR1 b
2.1 i
= 6.3 21.7 = 6.3 2.1 = 4.2 V
3.4
6
Chemistry PART II
SECTION A
1. MnO2 oxidized allylic alcohol.
2. OCH 3 OH O
H3O H 2O

O
CH 3OH
OCH 3 OH
COOCH 3 COOH COOH
3. O
COOH
C O
OH
BrO

NH
CONH 2 NH 2
4. This is Hundsdicker reaction.

O O
Ph C O Ag Ph C O + AgBr Ph + CO2
Br PhBr
5. O O
R C O Ag Br Br
R C O Br AgBr
Hypobromite
O O

R C O Br R C O Br

R CO2
O

R Br O C R
R Br R C O
6. CH3 CH3 CH3 CH3 CH3

CH3 C C CH3 HNO2 CH3 C C CH3 CH3 C C CH3

OH NH2 OH OH CH3
H+
O CH3
CH3 C C CH3
CH3
7
8. LiAlH4 PCl5 KCN
N COOH N CH2OH N CH2Cl N CH2 CN

| H H H
H H3O+
N CH2COOH
H
9.
O O O
CH CH COH
O
H
OH H
CH CH C
H
O O O
IMPE
OH O
O OH

C C O Na

H
O ..
CH2OH
.. CH2OH
10. Compound (c) does not form enol and hence enolate ion with a base as it does not have
hydrogen atom.
11. OH
O O COOH COOH

OH

H

O O O OH
12.
alc. KOH 1. O COOH BaO,
Br 3
O
2. H3 O
COOH
13. O
PhMgBr
H3C
(A)
3

C CH
(B)
H O
H3O

(D)
H O
(C)
2
OH
14. Test of terminal alkynes.
16. In polystyrene the monomeric unit is styrene which is having the formula of H2C=CHC6H5.
8
17. n CH2=CHCH=CH2 + n C6H5CH=CH2 (styrene) [CH2CH=CHCH2CH(C6H5)CH2]n

(1,3-butadiene) (BunaS)
18. NBS Mg CH3CN H3O+

dry ether
Br MgBr C=NMgBr C=O

CH3 CH3
19. O O
O O O O

OH
CH3C(CH2)3CH CH2C(CH2)3CH O H2O
OH
OH
H H
Heat H2O
20. Due to the presence of CS2 , only monobromination takes place as CS2 decrease the
electrophilicity of Br2 and also minimize phenol ionization.
23. HO O

Hg2 H2 O Ph
Ph
tautomerise
Ph C C CH3 Ph C C CH3
Hg2
2 CH3
Hg CH3
more stable
(incipient carbocation)
25. R R
R OH HO R
HIO4
(1)
O O O O
R R
R OH
HIO4
(2)
O R
O OH O
HIO
(4) R CHOH CHOH R
4 R CH O R CH O
26. OH O O
O H O
C COOH
CH3 i KBrO,
O H
COOH
COOH
ii Haloform reduction COOH
(X)
keto acid

CO 2
(Y)
9
28. H
OH
(A) - C N (B) - C
CH3
O
O
(C) - (D) - C
C O Ca
2
29. This is an example of Cross Cannizzaro reaction. The molecule first attacked is converted to
sodium salt of benzoic acid in a Cannizzaro reaction. The presence of NO2 group activates the
benzene ring towards nucleophilic attack. Therefore nitrobenzaldehyde is preferentially attacked.
10
Mathematics PART III

SECTION A
1
3 x
x
1. lim
x 2 x 5 1

x
3
1
lim x 1
.
x 5 2
2
x
2. Here A & B set having 2 elements is common, so A B & B A have 22 i.e. four elements in
common. Here n A B B A 4 .
dr
r cos sin
dy d
3.
dx dr
r sin cos
d

2 2cos cos sin 2sin
2 2 2cos sin cos 2 sin
dy 2

dx
2 2
4
4. f(x) = log 2 2 log 16 sin

2
2

x 1
2
1 16sin x + 1 17
0 log2(16 sin2x + 1) log2 17
2 log2 17 2 log2 (16 sin2x + 1) 2
now consider
0 < 2 log2(16 sin2x + 1) 2

< log 2 2 log2 16 sin2 x 1 log2 2 2

1 x 1
0 x 1

1 1 x 0

5. f g x 0 x0
1 0 x 1

0 x 1

1 x 1
points of discontinuity are x = 1, 0 1.
8. Here f is a differentiable function then f is continuous function so by L.M.V.T. theorem for any a
(0,4)
11
f 4 f 0
f a (i)
40
again from mean value for any b (0, 4)
f 4 f 0
f b (ii)
2
multiply both (i) and (ii) we get
f 2 4 f 2 0
f a .f b .
8
9. f(x) = x3 + ax2 + bx + 5 sin2 x

2
f(x) = 3x + 2ax + b + 10 sinx cos x 0 x R
2
i.e. 3x + 2ax + b + 5 sin 2x 0 x R
2
if 3x + 2ax + b 5 0
4a2 12(b 5) 0
a2 3b + 15 0.
x x
10. Slope of the tangent to curve y 2e x sin cos
4 2 4 2
x
y = e cos x
dy
s e x sin x cos x
dx
ds
ex sin x cos x cos x sin x
dx
= 2ex sinx
ds
0 x = 0, , 2 ( 0 x 2)
dx
value of s at x = 0 is 1, at x = is e at x = 2 is e2 minimum at x = .
5 2
11. 4cos x cos2x cos x dx 2 cos 2x cos cos2x dx
6 6 3
1

2 cos 2x cos2x dx 2cos 2 2dx cos2x dx
2

sin 4x sin2x
1 cos 4x cos 2x dx x c
4 2
13. Let y x y
y2 y x = 0
1 1 4x
y y>1
2
1 1 4x
y
2

sin x
14. I 2 2 dx
0 1 cos2 x

sin x
I 2 2 2
2 tan1 cos x 2
0 1 cos x 0
12

2 tan1 0 tan1 1

2
cos 1
2

1 sin 2
cosa sin x
17. I ln dx
sina cos x
a cosa cos x sina sin x a cos a x
ln dx 0 ln sinacos x dx
0
sinacos x
a a
lncos a a x dx ln sina dx lncos x dx
0 0
n n
nk n k 1
n 1 k k 2
18. lim k 1 k 1
n
k 1 k2 k2
2
n n 1 n n 1 2n 1

2 6 .
n n 1 2n 1
6
1 1
1 x x e eln1 x x e
19. lim lim
x 0 x x 0 x
differentiate two times.
20. y = ex cos x
y1 = ex sinx ex cos x = ex sinx y
y2 = ex cosx + ex sin x y1
y2 = y y1 ex sin x
y2 = 2 (y + y1)
y3 = 2(y1 + y2)
y3 = 2(ex sinx y)
y4 = 2y1 2y 2y 2y1
y4 + 4y = 0
g a h f a g a f a h
25. lim
h 0 h
f a g a h g a g a f a h f a
lim
h 0 h
f(a) . g(a) g(a) . f(a)
1
1 5 n n
26. lim
n

6n n 1
6

13
n
1 5

6
n
n 6
5 n 5

6 lim 1
n
6

0
= 6 . e = 6.
27. For all n it touches the curve.
28. f(x) = x3 3x + k f(x) = 3x2 3

2
f(x) = 3(x 1) < 0 x (0, 1)
Hence f(x) is strictly decreasing
e
log 2
29. y tan1 x tan1 3 2log x

log ex 2

1 6log x

1 2log x 1 3 2log x
tan1 tan
1 2log x 1 3.2log x
tan1 1 tan1 2log x tan1 3 tan1 2log x
= tan1 (1) tan1(3)
= constant function.
30. lim

sin e x 1 1
x 1 log x
lim

sin e x 1 1 e x 1 1

x 1

e x 1 1 log x
ex 1 1 as x 1
1 lim x 1
x 1
log x e 1 0
eh 1 h
lim = 1.
h 0 h log 1 h

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1

Q. No. PHYSICS CHEMISTRY MATHEMATICS

8. Field at any internal point of the cavity.

10. If IG 0 then it becomes a balanced whetstone bridge

13. Apply gaus theorem

20. Due to electrostatic shielding, the ratio will be 1.

21. When key is open

22. If I1 is current in ACDB then

26. Initial capacitor is charged to Q/2

27. The equivalent circuit is P

28. By using the relation

29. Let x = a potential is zero (region II)

30. In the steady state i i

1. MnO2 oxidized allylic alcohol.

COOCH 3 COOH COOH

4. This is Hundsdicker reaction.

6. CH3 CH3 CH3 CH3 CH3

8. LiAlH4 PCl5 KCN

N COOH N CH2OH N CH2Cl N CH2 CN

14. Test of terminal alkynes.

17. n CH2=CHCH=CH2 + n C6H5CH=CH2 (styrene) [CH2CH=CHCH2CH(C6H5)CH2]n

18. NBS Mg CH3CN H3O+

Br MgBr C=NMgBr C=O

Mathematics PART III

4. f(x) = log 2 2 log 16 sin

9. f(x) = x3 + ax2 + bx + 5 sin2 x

27. For all n it touches the curve.

28. f(x) = x3 3x + k f(x) = 3x2 3

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