Penilaian Kognitif

a. Kisi-kisi Soal Penilaian Kognitif

Table 12. Kisi-kisi Soal

Kompetensi Indikator Level Nomor Soal Tipe Soal
Dasar
1.1 Knowing C2 1 Uraian
Recognizing the characteristics of
regularity of galvanic cell.
galvanic cell as a
manifestation of
the greatness God
of Almighty and
the knowledge of
their regularity as
a result of human
creative thinking
as a tentative truth.
3.4 Analyze the Calculate the cell C4 8 Uraian
processes that potential based on
occur and perform the potential data
calculations standard.
substance or
Explain the C2 1 Uraian
electricity
working principle
involved in a
of galvanic cells
galvanic cell and
in life.
its application in
life. Writing down C3 6 dan 7 Uraian
symbol cells based
on potential data
standard.
4.3.a. Knowing the C1 10 Uraian
Determine the sequence of the
order of the power of
strength of oxidizing and
oxidizing and reducing agents
reducing agents based on the
based on the results of the
results of the experiment.
experiment.
4.3.b.Giving Explain the C6 2 dan 4 Uraian
examples and process that
implications in the occurs in
context of the accumulator and
application of relationship on
galvanic cell SETS.
 SETS. C4 3 Uraian

4.4.a Describing the C1 5 Uraian

Designing a galvanic cell
galvanic cell by structure and
using materials explain the function
around. of each part.
4.4.b.Determining Determining C4 9 Uraian
the cell potential reactions that
based on the occur in the
results of the experiment.
experiment

b. Soal Penilaian Kognitif

Jawablah Pertanyaan Berikut Ini dengan Jelas dan Benar!

1. (6 point) Jelaskan prinsip kerja sel volta dan sifatnya!

2. (20 point) The commercially available batteries we use today contain heavy metals such
as mercury, lead, cadmium and nickel. Of these components will have an impact on
environmental pollution, if the battery waste is not addressed properly because the battery
waste including (Hazardous and Toxic) waste that is difficult to decompose by microbes
and very dangerous. Apa yang dapat kita lakukan untuk mengatasi limbah tersebut?
Berikan 2 contoh cara mengatasi limbah tersebut!
3. (10 point) Mengapa sel aki dapat digunakan lagi?
4. (10 point) Bagaimana cara kerja hydrogen fuel cell?
5. (5 point)
2+ 2+
Diketahui Notasi Sel : () |() ||() |()
Gambarkan struktur sel galvani dan beri penjelasan fungsi bagiannya!
6. (15 point) Tuliskan reaksi sel untuk sel volta berikut:
2+ 2+
a. () |() ||() |()
2+
b. () |() ||() |2()
2+ +
c. () |() ||() |()
7. (10 point) Tuliskan notasi sel untuk reaksi berikut:
 2+ 2+
a. () + () () + ()
2+
b. 2 () + () 2() + ()
8. (10 point) Hitunglah potensial electrode Cu uang dihubungkan dengan electrode hidrogen
pada keadaan standar jika voltmeter menunjukkan nilai 0,34 V. Tuliskan reaksi setengah
selnya!
9. (10 Point)Apakah reaksi redoks berikut akan berlangsung spontan jika dilakukan pada
keadaaan standar?
3+ 3+
a. () |() ||() |()
2+ 3+
b. () |() ||() |()
10. (4 point) Urutkan kekuatan zat-zat berikut sebagai oksidator dan sebagai reduktor.
Zn2+, Cu2+, Mg2+, Ag+, Al3+

c. Kunci Jawaban Penilaian Kognitif

Nomer
Jawaban
Soal
1 Prinsip:
Galvanic cell is a device powered by an oxidationreduction reaction where the
oxidizing agent is separated from the reducing agent so that the electrons must travel
through a wire from the reducing agent to the oxidizing agent.
Sifat:
A galvanic cell is a device for converting chemical energy to electrical energy. Sel
galvani ada yang bisa diisi ulang da nada yang tidak bisa diisi ulang.

2 Utilization of used battery can be done by replacing the pasta by using durian leather
waste and banana skin. Durian skin contains potassium, sodium, manganese, high folic
acid which can be used to drain positive and negative ions. Content of this substance
which then creates electricity. With a number of processes, Durian skin is able to
produce a voltage of 1.25 volts. This voltage is sufficient to revive the flow of battery
electricity that has been dead. Banana peels contain carbohydrates and are rich in
minerals such as potassium, magnesium, phosphorus, chloride, calcium, and iron.
3 Sel aki tergolong jenis sel volta sekunder, karena jika zat yang ada di dalam aki habis,
maka dengan mengalirkan arus listrik ke dalam sel aki zat semula akan terbentuk
kembali, sehingga sel aki dapat berfungsi lagi.

4 The hydrogen fuel cell is a tool designed to alter electrochemical energy into electric
energy directly by using hydrogen fuel. The cell consist of a pair of electrodes (an
anode and cathode) that is separated by electrolyte membrane. The fuel cell works by
using hydrogen gas or other gasses oxidized easily that is put into besides an anode as
an electron source. The electron is separated from hydrogen ion by using electrolyte
membrane that is permeable to a positive load. In the cathode side is entered oxygen
from the air. Oxygen ion, electron, and H+ ion merge to form a water molecule , which
then is taken out from a cathode side as a cell by product.

Salt Bridge
Voltmeter
(-) (+)

Mg Cu

2+
Anoda = elektroda Mg = terjadi oksidasi = () () + 2
2+
Katoda = elektroda Cu = terjadi reduksi = () + 2 ()
Jembatan garam= untuk menetralkan kelebihan anion dan kation pada larutan.
Voltmeter = untuk mengukur tegangan listrik yang dihasilkan.

6 a. Reaksi setengah selnya sebagai berikut:

2+
Anode: () () + 2
2+
Cathode: () + 2 ()
Reaksi sel volta keseluruhan sebagai berikut.
 2+ 2+
() + () () + ()

b. Reaksi setengah selnya sebagai berikut:

2+
Anode: () () + 2

Cathode: 2() + 2 2()
Reaksi sel volta keseluruhan sebagai berikut.
2+
() + 2() () + 2()
c. Reaksi setengah selnya sebagai berikut:
2+
Anode: () () + 2
+
Cathode: () + ()
Reaksi sel volta keseluruhan sebagai berikut.
+ 2+
() + () () + ()

7 a. Reaksi setengah selnya sebagai berikut:

2+
Anode: () () + 2
2+
Cathode: () + 2 ()
Penulisan notasi selnya sebagai berikut.
2+ 2+
() |() ||() |()

b. Reaksi setengah selnya sebagai berikut:

Anode: 2 () 2() + 2
2+
Cathode: () + 2 ()
Penulisan notasi selnya sebagai berikut.
2+
2 () |2() ||() |()

8 Persamaan setengah reaksi sel yang terjadi

2+
Cathode : () + 2 ()
+
Anode: 2() 2()

=

0,34 = 2

0,34 = 0,00

= 0,34
Jadi, potensial reduksi standar untuk elektroda Cu adalah 0,34 V.

9 a. The half-equations with their Eovalues

Al3+(aq) + 3e- Al (s) Eo= -1,662 V
Cr3+(aq) + 3e- Cr(s) Eo= -0, 744 V
Cr3+(aq) will be reduced as it has the higher Eo value, and Al(s) will be oxidized
Eocell = Eohalf-cell where reduction occurs - Eohalf-cell where oxidation occurs
Eocell = EoCr - EoAl = -0, 744 (-1,662)V= +0,918 V.
Jadi, reaksi redoks tersebut dapat berlangsung spontan.

b. The half-equations with their Eovalues

Cu2+(aq) + 2e- Cu (s) Eo= + 0,337 V
Cr3+(aq) + 3e- Cr(s) Eo= -0, 744 V
Dari notasi sel tersebut, Cu2+(aq) will be oxidized and Cr(s) will be reduced.
Eocell = Eohalf-cell where reduction occurs - Eohalf-cell where oxidation occurs
Eocell = EoCr - EoCu = -0, 744 (+ 0,337 )V= -1,081 V.
Jadi, reaksi redoks tersebut tidak dapat berlangsung spontan.

10 Sebagai oksidator: Mg2+ < Al3+ < Zn2+ < Cu2+ < Ag+
Sebagai reduktor: Ag+< Cu2+ < Zn2+ < Al3+ < Mg2+

d. Rubrik Penilaian Kognitif

Nomer
Jawaban
Soal
1 Skor maksimal 6 point, dengan rincian:
Prinsip (4 point):
Galvanic cell is a device powered by an oxidationreduction reaction where the
 oxidizing agent is separated from the reducing agent so that the electrons must travel
through a wire from the reducing agent to the oxidizing agent.
Sifat (2 point)
A galvanic cell is a device for converting chemical energy to electrical energy. Sel
galvani ada yang bisa diisi ulang da nada yang tidak bisa diisi ulang.

2 Skor maksimal 20 point dengan rincian: setiap solusi mendapat 10 point.

Utilization of used battery can be done by replacing the pasta by using durian leather
waste and banana skin. Durian skin contains potassium, sodium, manganese, high folic
acid which can be used to drain positive and negative ions. Content of this substance
which then creates electricity. With a number of processes, Durian skin is able to
produce a voltage of 1.25 volts. This voltage is sufficient to revive the flow of battery
electricity that has been dead. Banana peels contain carbohydrates and are rich in
minerals such as potassium, magnesium, phosphorus, chloride, calcium, and iron.

3 Skor maksimal 10 point.

Sel aki tergolong jenis sel volta sekunder, karena jika zat yang ada di dalam aki habis,
maka dengan mengalirkan arus listrik ke dalam sel aki zat semula akan terbentuk
kembali, sehingga sel aki dapat berfungsi lagi.

4 Skor maksimal 10 point, dengan rincian:

The hydrogen fuel cell is a tool designed to alter electrochemical energy into electric
energy directly by using hydrogen fuel. The cell consist of a pair of electrodes (an
anode and cathode) that is separated by electrolyte membrane. The fuel cell works by
using hydrogen gas or other gasses oxidized easily that is put into besides an anode as
an electron source. (5 point)
The electron is separated from hydrogen ion by using electrolyte membrane that is
permeable to a positive load. In the cathode side is entered oxygen from the air.
Oxygen ion, electron, and H+ ion merge to form a water molecule , which then is taken
out from a cathode side as a cell by product. (5 point)
5 Skor maksimal 5 point, dengan rincian:

Salt Bridge
Voltmeter
(-) (+)

Mg Cu

(1 point)
2+
Anoda = elektroda Mg = terjadi oksidasi = () () + 2 (1 point)
2+
Katoda = elektroda Cu = terjadi reduksi = () + 2 () (1 point)
Jembatan garam = untuk menetralkan kelebihan anion dan kation pada larutan(1 point)
Voltmeter = untuk mengukur tegangan listrik yang dihasilkan (1 point)

6 Skor maksimal 15 pint, dengan rincian:

a. ( 5 point) Reaksi setengah selnya sebagai berikut:
2+
Anode: () () + 2
2+
Cathode: () + 2 ()
Reaksi sel volta keseluruhan sebagai berikut.
2+ 2+
() + () () + ()

b. ( 5 point) Reaksi setengah selnya sebagai berikut:

2+
Anode: () () + 2

Cathode: 2() + 2 2()
Reaksi sel volta keseluruhan sebagai berikut.
2+
() + 2() () + 2()

c. ( 5 point) Reaksi setengah selnya sebagai berikut:

 2+
Anode: () () + 2
+
Cathode: () + ()
Reaksi sel volta keseluruhan sebagai berikut.
+ 2+
() + () () + ()

7 Skor maksimal 10 point, dengan rincian:

a. (5 point)Reaksi setengah selnya sebagai berikut:
2+
Anode: () () + 2
2+
Cathode: () + 2 ()
Penulisan notasi selnya sebagai berikut.
2+ 2+
() |() ||() |()

b. (5 point) Reaksi setengah selnya sebagai berikut:

Anode: 2 () 2() + 2
2+
Cathode: () + 2 ()
Penulisan notasi selnya sebagai berikut.
2+
2 () |2() ||() |()

8 Skor maksimal 10 point, dengan rincian:

Persamaan setengah reaksi sel yang terjadi (5 point)
2+
Cathode : () + 2 ()
+
Anode: 2() 2()

=

0,34 = 2

0,34 = 0,00

= 0,34
Jadi, potensial reduksi standar untuk elektroda Cu adalah 0,34 V. (5 point)

9 Skor maksimal 10 point, dengan rincian:

 a. The half-equations with their Eovalues
Al3+(aq) + 3e- Al (s) Eo= -1,662 V
Cr3+(aq) + 3e- Cr(s) Eo= -0, 744 V
Cr3+(aq) will be reduced as it has the higher Eo value, and Al(s) will be oxidized (2
point)
Eocell = Eohalf-cell where reduction occurs - Eohalf-cell where oxidation occurs
Eocell = EoCr - EoAl = -0, 744 (-1,662)V= +0,918 V (2 point)
Jadi, reaksi redoks tersebut dapat berlangsung spontan. (1 point)

b. The half-equations with their Eovalues

Cu2+(aq) + 2e- Cu (s) Eo= + 0,337 V
Cr3+(aq) + 3e- Cr(s) Eo= -0, 744 V
Dari notasi sel tersebut, Cu2+(aq) will be oxidized and Cr(s) will be reduced (2 point)
Eocell = Eohalf-cell where reduction occurs - Eohalf-cell where oxidation occurs
Eocell = EoCr - EoCu = -0, 744 (+ 0,337 )V= -1,081 V (2 point)
Jadi, reaksi redoks tersebut tidak dapat berlangsung spontan (1 point)

10 Skor Maksimal: 4 point, dengan rincian:

2 point jika menjawab= Sebagai oksidator: Mg2+ < Al3+ < Zn2+ < Cu2+ < Ag+
2 point jika menjawab= Sebagai reduktor: Ag+< Cu2+ < Zn2+ < Al3+ < Mg2+