124 Chapter 5 C o u p l i n g b e t w e e n Pairs of Spins

T A B L E 5.1 Typical P r o t o n - P r o t o n Spin C o u p l i n g C o n s t a n t s

Type JHH(HZ) Type JHH(HZ)

HH 280 ^cH
x=c: H
- 1 2 to - 1 5

^CH -1.5
H C C H (free rotation) ;c==c^
H
I ^CH -2
HCCCH
C=C

ax-ax 8-10 C=CC=C 10

ax-eq 2 - 3
H H
eq-eq 2 - 3
H
{cis or trans) 4-5
H
7-17
-H -N=c:
{cis or trans) H

42
{cis) 8-10 o=c:
{trans) 4-6
HCC = CH -2
HCC = CCH 2

HCOH H,,.,^ ^ri 5 mem. 6

''C==C^ 6 mem. 10
12
1f +3
(ring) J 7 "^^"^
HCCH
1 .CH
Oto 2
X=CC^ (X = C, O)
1?
HCCH 8
CH

rj {ortho) 8
H 12 to 19 {meta) 2
{para) -0.5
- 3 to + 2
H
(2-3) 5
H H (3-4) 8
c=c 7 to 11 ' (2-4) 0-3
2 (3-5) 1.5
HC. . C -- H (2-5) 1
/C=CC 1-2 (2-6) ~0

{continues)