09 04 2014 PDF

PART A PHYSICS A
1. An experiment is performed to obtain the 1. L U U L

value of acceleration due to gravity g by U g
using a simple pendulum of length L. In 100 1 UU
this experiment time for 100 oscillations is U
measured by using a watch of 1 second 90.0 U L 1 mm
least count and the value is 90.0 seconds. UU U
The length L is measured by using a meter 20.0 cm g U U
scale of least count 1 mm and the value is
20.0 cm. The error in the determination
(1) 1.7%
of g would be :
(2) 2.7%
(1) 1.7%
(3) 4.4%
(2) 2.7%
(4) 2.27%
(3) 4.4%
(4) 2.27%
2. t50 U S

2. The position of a projectile launched from t52s U r 5(40 i 1 50 j ) m
the origin at t50 is given by u U
, u (g510 ms22 ).
r 5(40 i 1 50 j ) m at t52s. If the
projectile was launched at an angle u from
the horizontal, then u is (take g510 ms22). (1) tan21 2 3
(1) tan21 2 3 (2) tan21 3 2
(2) tan21 3 2 (3) tan21 7 4
(3) tan21 7 4 (4) tan21 4 5
(4) tan21 4 5
English : 1 Set : 01 Hindi : 1 Set : 01

3. Water is flowing at a speed of 1.5 ms21 3. 1022 m2 S U
through a horizontal tube of 1.5 ms21 U U
cross-sectional area 1022 m2 and you are U U
trying to stop the flow by your palm. U UU
Assuming that the water stops L ,
immediately after hitting the palm, the (
minimum force that you must exert should 5103 kgm23).
be (density of water5103 kgm23).
(1) 15 N (1) 15 N
(2) 22.5 N (2) 22.5 N
(3) 33.7 N (3) 33.7 N
(4) 45 N (4) 45 N
4. A block A of mass 4 kg is placed on 4. 4 kg A U

another block B of mass 5 kg, and the block 5 kg B U U U B
B rests on a smooth horizontal table. If U S U
the minimum force that can be applied on A U ,
A so that both the blocks move together is , 12 N
12 N, the maximum force that can be B U ,
applied on B for the blocks to move ,
together will be :
(1) 30 N (1) 30 N
(2) 25 N (2) 25 N
(3) 27 N (3) 27 N
(4) 48 N (4) 48 N

5. Two bodies of masses 1 kg and 4 kg are 5. 1 kg 4 kg S U
connected to a vertical spring, as shown mU U U U
in the figure. The smaller mass executes 25 rad/s
simple harmonic motion of angular 1.6 cm U U U
frequency 25 rad/s, and amplitude 1.6 cm U SU U mU U
while the bigger mass remains stationary
on the ground. The maximum force (g510 ms22 ).
exerted by the system on the floor is
(take g510 ms22).
(1) 20 N
(2) 10 N
(1) 20 N
(3) 60 N
(2) 10 N
(4) 40 N
(3) 60 N
(4) 40 N

6. A cylinder of mass Mc and sphere of mass 6. Mc Ms
Ms are placed at points A and B of two A B
inclines, respectively. (See Figure). If they U U ( )
roll on the incline without slipping such U U U
that their accelerations are the same, then sin uc
, :
sin uc sin us
the ratio is :
sin us
8
(1)
8 7
(1)
7
15
(2)
15 14
(2)
14
8
(3)
8 7
(3)
7 15
(4)
15 14
(4)
14

7. Indias Mangalyan was sent to the Mars 7. U U
by launching it into a transfer orbit EOM U SU EOM
around the sun. It leaves the earth at E E U U U M
and meets Mars at M. If the semi-major U h-
axis of Earths orbit is ae51.531011 m, ae51.531011 m U h-
that of Mars orbit a m 52.28310 11 m, am52.2831011 m , U
taken Keplers laws give the estimate of U
time for Mangalyan to reach Mars from
Earth to be close to :
(1) 500 days (1) 500

(2) 320 days (2) 320
(3) 260 days (3) 260
(4) 220 days (4) 220

8. In materials like aluminium and copper, 8.
the correct order of magnitude of various S U
elastic modulii is :
(1) Youngs modulii < shear modulii (1) S < M S
< bulk modulii. < S .
(2) Bulk modulii < shear modulii (2) S < M
< Youngs modulii. S < S .
(3) Shear modulii < Youngs modulii (3) M S < S
< bulk modulii. < S .
(4) Bulk modulii < Youngs modulii (4) S < S
< shear modulii. < M S .
9. The amplitude of a simple pendulum, 9. U U U

oscillating in air with a small spherical bob, 40 U 10 cm 8 cm
decreases from 10 cm to 8 cm in 40 seconds. U SU
Assuming that Stokes law is valid, and U U
ratio of the coefficient of viscosity of air to 1.3 , U U
that of carbon dioxide is 1.3, the time in 10 cm 5 cm
which amplitude of this pendulum will U
reduce from 10 cm to 5 cm in (ln 551.601, ln 250.693).
carbondioxide will be close to (ln 551.601,
ln 250.693).
(1) 231 s (1) 231 s
(2) 208 s (2) 208 s
(3) 161 s (3) 161 s
(4) 142 s (4) 142 s

10. A capillary tube is immersed vertically in 10. U U
water and the height of the water column U S x
is x. When this arrangement is taken into U d
a mine of depth d, the height of the water , S y
column is y. If R is the radius of earth, the R , x
x y
ratio is :
y
d d
(1) 12 (1) 12
R R
2d 2d
(2) 12 (2) 12
R R
R 2d R 2d
(3) R 1d (3) R 1d
R 1d R 1d
(4) R 2d (4) R 2d
11. Water of volume 2 L in a closed container 11. 2 L 1 kW

is heated with a coil of 1 kW. While water U U
is heated, the container loses energy at a , 160 J/s U U U
rate of 160 J/s. In how much time will the 278C
temperature of water rise from 278C to 778C ? ( cU c
778C ? (Specific heat of water is 4.2 kJ/kg U cU c )
4.2 kJ/kg and that of the container is
negligible).
(1) 8 min 20 s (1) 8 U 20 U
(2) 6 min 2 s (2) 6 U 2 UU
(3) 7 min (3) 7 U
(4) 14 min (4) 14 U

12. The equation of state for a gas is given by 12. S U PV5nRT1aV
PV5nRT1aV, where n is the number of , n U a
moles and a is a positive constant. The SU U
initial temperature and pressure of one U To
mole of the gas contained in a cylinder are Po U
To and Po respectively. The work done by , mU
the gas when its temperature doubles
isobarically will be :
Po To R Po To R
(1) (1)
Po 2a Po 2a
Po To R Po To R
(2) (2)
Po 1a Po 1a
(3) Po To R ln 2 (3) Po To R ln 2
(4) P o To R (4) Po To R
13. Modern vacuum pumps can evacuate a 13. U (300 K) U

vessel down to a pressure of 4.0310215 atm. 4.0310215 UUSU
at room temperature (300 K). Taking U R58.3 JK21 21,
R58.3 JK21 mole21, 1 atm5105 Pa and 1 USU5105 S U U
N Avogadro 56310 23 mole 21 , the mean 5631023 21
distance between molecules of gas in an U
evacuated vessel will be of the order of :
(1) 0.2 mm (1) 0.2 mm
(2) 0.2 mm (2) 0.2 mm
(3) 0.2 cm (3) 0.2 cm
(4) 0.2 nm (4) 0.2 nm

14. A particle which is simultaneously 14. , U U
subjected to two perpendicular simple
x5a1 cos vt U y5a2 cos 2vt U
harmonic motions represented by ;
x5a1 cos vt and y5a2 cos 2vt traces a ,
curve given by :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)

15. A transverse wave is represented by : 15. S U
10 2p 2p 10 2p 2p
y5 sin t2 x y5 sin t2 x
p T l p T l
For what value of the wavelength the U U
wave velocity is twice the maximum ?
particle velocity ?
(1) 40 cm (1) 40 cm
(2) 20 cm (2) 20 cm
(3) 10 cm (3) 10 cm
(4) 60 cm (4) 60 cm
16. The magnitude of the average electric field 16. cU U U U U

normally present in the atmosphere just S l U
above the surface of the Earth is about 150 N/C
150 N/C, directed inward towards the U U mU U
center of the Earth. This gives the total cU
net surface charge carried by the Earth to [ e o 58.85310 212 C 2 /N-m 2 ,
be : RE56.373106 m]
[Given e o 58.85310 212 C 2 /N-m 2 ,
RE56.373106 m]
(1) 1670 kC (1) 1670 kC
(2) 2670 kC (2) 2670 kC
(3) 2680 kC (3) 2680 kC
(4) 1680 kC (4) 1680 kC

17. Three capacitances, each of 3 mF, are 17. 3 mF U
provided. These cannot be combined to U
provide the resultant capacitance of : U U ?
(1) 1 mF (1) 1 mF
(2) 2 mF (2) 2 mF
(3) 4.5 mF (3) 4.5 mF
(4) 6 mF (4) 6 mF
18. A d.c. main supply of e.m.f. 220 V is 18. l 220 V cU U

connected across a storage battery of 1 V U mU l
e.m.f. 200 V through a resistance of 1 V. 200 V U U
The battery terminals are connected to an UU U U R
external resistance R. The minimum R , UU
value of R, so that a current passes U U U,
through the battery to charge it is :
(1) 7V (1) 7V
(2) 9V (2) 9V
(3) 11 V (3) 11 V
(4) Zero (4)

19. The mid points of two small magnetic 19. S d m
dipoles of length d in end-on positions, are x U U U (x >>d)
separated by a distance x, (x >> d). The x2n , n :
force between them is proportional to
x2n where n is :
(1) 1
(2) 2
(1) 1
(3) 3
(2) 2
(4) 4
(3) 3
(4) 4
20. U U
431025 T
20. The magnetic field of earth at the equator 6.43106 m m
is approximately 431025 T. The radius U
of earth is 6.43106 m. Then the dipole
moment of the earth will be nearly of the (1) 1023 A m2
order of :
(2) 1020 A m2
(1) 1023 A m2
(3) 1016 A m2
(2) 1020 A m2
(4) 1010 A m2
(3) 1016 A m2
(4) 1010 A m2

21. When the rms voltages VL, VC and VR are 21. U LCR
measured respectively across the inductor U U L U C U U R U
L, the capacitor C and the resistor R in a - - U
series LCR circuit connected to an VL, VC VR ,
AC source, it is found that the ratio VL : VC : VR51 : 2 : 3 U o
VL : VC : VR51 : 2 : 3. If the rms voltage -- U 100 V , VR
of the AC source is 100 V, then VR is close
to :
(1) 50 V (1) 50 V
(2) 70 V (2) 70 V
(3) 90 V (3) 90 V
(4) 100 V (4) 100 V

22. Match List I (Wavelength range of 22. I (l SU U U)
electromagnetic spectrum) with List II. II ( U )
(Method of production of these waves) U
and select the correct option from the
options given below the lists.
I II
List I List II 700 nm U
(a) (i)
(a)
700 nm to
(i)
Vibration of atoms 1 mm
1 mm and molecules.
U U
Inner shell electrons 1 nm
(b) (ii) U SU
1 nm to in atoms moving from 400 nm
(b) (ii) SU
400 nm one energy level to a
lower level.
UU
(c) < 1023 nm (iii)
(c) < 10 23 nm (iii)
Radioactive decay of
the nucleus.
1 mm
(d) (iv) U

1 mm to 0.1 m
(d) (iv) Magnetron valve.
0.1 m
(1) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(1) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i) (2) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
(2) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii) (3) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
(3) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i) (4) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(4) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

23. A diver looking up through the water sees 23. U U U
the outside world contained in a circular
horizon. The refractive index of water is 4 U U
4 3
3
, and the divers eyes are 15 cm below cU 15 cm
the surface of water. Then the radius of
the circle is :
(1) 15333 5 cm (1) 15333 5 cm
(2) 1533 7 cm (2) 1533 7 cm
153 7 153 7
(3) cm (3) cm
3 3
153 3 153 3
(4) cm (4) cm
7 7

24. Using monochromatic light of wavelength 24. U l
l, an experimentalist sets up the Youngs mU U
double slit experiment in three ways as S U
shown. y5b9,
If she observes that y5b9, the wavelength U
of light used is :

(1) 520 nm (1) 520 nm
(2) 540 nm (2) 540 nm
(3) 560 nm (3) 560 nm
(4) 580 nm (4) 580 nm
25. The focal lengths of objective lens and eye

lens of a Gallelian Telescope are 25. U
respectively 30 cm and 3.0 cm. Telescope $ 30 cm
produces virtual, erect image of an object 3.0 cm U ScU
situated far away from it at least distance U U U S
of distinct vision from the eye lens. In this , S ,
condition, the Magnifying Power of the U
Gallelian Telescope should be :
(1) 111.2
(2) 211.2 (1) 111.2
(3) 28.8 (2) 211.2
(4) 18.8 (3) 28.8
(4) 18.8
26. For which of the following particles will it
be most difficult to experimentally verify 26.
the de-Broglie relationship ? U-
(1) an electron ?
(2) a proton (1) U$
(3) an a-particle (2) U
(4) a dust particle (3) a-
(4)

27. If the binding energy of the electron in a 27. U U U
hydrogen atom is 13.6 eV, the energy 13.6 eV , Li11 S
required to remove the electron from the U U
first excited state of Li11 is :
(1) 122.4 eV (1) 122.4 eV
(2) 30.6 eV (2) 30.6 eV
(3) 13.6 eV (3) 13.6 eV
(4) 3.4 eV (4) 3.4 eV
28. Identify the gate and match A, B, Y in

bracket to check. 28. U U cU A, B, Y
U
(1) AND (A51, B51, Y51)

(2) OR (A51, B51, Y50) (1) AND (A51, B51, Y51)
(3) NOT (A51, B51, Y51) (2) OR (A51, B51, Y50)
(4) XOR (A50, B50, Y50) (3) NOT (A51, B51, Y51)
(4) XOR (A50, B50, Y50)
29. A transmitting antenna at the top of a
tower has a height 32 m and the height of
the receiving antenna is 50 m. What is the
29. U U U 32 m
maximum distance between them for U U 50 m
satisfactory communication in line of sight cUU (LOS) U U
(LOS) mode ? U U ?
(1) 55.4 km (1) 55.4 km
(2) 45.5 km (2) 45.5 km
(3) 54.5 km (3) 54.5 km
(4) 455 km (4) 455 km

30. An n-p-n transistor has three leads 30. n-p-n U SUU U
A, B and C. Connecting B and C by moist A, B C B C
fingers, A to the positive lead of an U, U U
ammeter, and C to the negative lead of the A U U U
ammeter, one finds large deflection. Then, U C U
A, B and C refer respectively to : A, B C

(1) Emitter, base and collector (1) , U
(2) Base, emitter and collector (2) U,
(3) Base, collector and emitter (3) U,
(4) Collector, emitter and base. (4) , U

PART B CHEMISTRY B U
31. In a face centered cubic lattice atoms A 31. U A U
are at the corner points and atoms B at U U B U
the face centered points. If atom B is U B U U
missing from one of the face centered
points, the formula of the ionic compound
is : (1) AB2
(1) AB 2 (2) A 5B 2
(2) A 5B2 (3) A 2B 3
(3) A 2B3 (4) A 2B 5
(4) A 2B5
32. UU U
32. Van der Waals equation for a gas is stated 2
nRT n
as, p5 2a .
V 2 nb V
2
nRT n U U
p5 2a .
V 2 nb V
nRT
This equation reduces to the perfect gas
M, p5
V
U U
nRT
equation, p 5 when ,
V
(1) U
(1) temperature is sufficiently high and
pressure is low.
(2) U
(2) temperature is sufficiently low and
pressure is high.
(3) U
(3) both temperature and pressure are
very high.
(4) U
(4) both temperature and pressure are
very low.

33. The standard electrode potentials 33. U A, B, C U D SUUU ()
(E ) of four metals A, B, C and D are

o
M /M
1 U U (E )o
M /M
1 U
21.2 V , 0.6 V, 0.85 V and 20.76 V, 21.2 V, 0.6 V, 0.85 V U 20.76 V
respectively. The sequence of deposition U U
of metals on applying potential is :
(1) A, C, B, D (1) A, C, B, D
(2) B, D, C, A (2) B, D, C, A
(3) C, B, D, A (3) C, B, D, A
(4) D, A, B, C (4) D, A, B, C
34. At a certain temperature, only 50% HI is 34. U 50% HI, H2 U

dissociated into H2 and I2 at equilibrium. I2 SU
The equilibrium constant is :
(1) 1.0 (1) 1.0
(2) 3.0 (2) 3.0
(3) 0.5 (3) 0.5
(4) 0.25 (4) 0.25
35. Dissolving 120 g of a compound of 35. (U 60) 120

(mol. wt. 60) in 1000 g of water gave a 1000 U
solution of density 1.12 g/mL. The 1.12 UU
molarity of the solution is : UU
(1) 1.00 M (1) 1.00 M
(2) 2.00 M (2) 2.00 M
(3) 2.50 M (3) 2.50 M
(4) 4.00 M (4) 4.00 M

36. The half-life period of a first order reaction 36. U -
is 15 minutes. The amount of substance 15 U U U
left after one hour will be :
(1) 1 U 1
4 of the original amount (1) 4
(2) 1 U 1
(3) 1 U 1
(4) 1 U 1
37. A current of 10.0 A flows for 2.00 h 37. X U UU

through an electrolytic cell containing a 2.00 U 10.0 A l
molten salt of metal X. This results in the U U 0.250 X
decomposition of 0.250 mol of metal X at X S
the cathode. The oxidation state of X in ( F596,500 C)
the molten salt is : (F596,500 C)
(1) 11 (1) 11
(2) 21 (2) 21
(3) 31 (3) 31
(4) 41 (4) 41

38. The energy of an electron in first Bohr orbit 38. H-U U U U
of H - atom is 213.6 eV. The energy value 213.6 eV Li 21 S
of electron in the excited state of Li21 is : U
(1) 227.2 eV (1) 227.2 eV
(2) 30.6 eV (2) 30.6 eV
(3) 230.6 eV (3) 230.6 eV
(4) 27.2 eV (4) 27.2 eV
39. The temperature at which oxygen 39. , U

molecules have the same root mean square SU U
speed as helium atoms have at 300 K is : 300 K U ,
(Atomic masses : He54 u, O516 u) (U He54 , O516 )

(1) 300 K (1) 300 K
(2) 600 K (2) 600 K
(3) 1200 K (3) 1200 K
(4) 2400 K (4) 2400 K
40. The standard enthalpy of formation of 40. NH3 246.0 kJ/

NH3 is 246.0 kJ/mol. If the enthalpy of U H 2
formation of H 2 from its atoms is 2436 kJ/ U N2 2712 kJ/
2436 kJ/mol and that of N 2 is N2H NH3 U
2712 kJ/mol, the average bond enthalpy
of N2H bond in NH3 is :
(1) 21102 kJ/mol (1) 21102 kJ/
(2) 2964 kJ/mol (2) 2964 kJ/
(3) 1352 kJ/mol (3) 1352 kJ/
(4) 11056 kJ/mol (4) 11056 kJ/

41. The amount of oxygen in 3.6 moles of water 41. 3.6
is :
(1) 115.2 g (1) 115.2
(2) 57.6 g (2) 57.6
(3) 28.8 g (3) 28.8
(4) 18.4 g (4) 18.4
42. The gas evolved on heating CaF2 and SiO2 42. CaF2 U SiO2 H2SO4 U
with concentrated H2SO4, on hydrolysis U U U $
gives a white gelatinous precipitate. The
precipitate is :
(1) hydrofluosilicic acid (1) U U
(2) silica gel (2)
(3) silicic acid (3)
(4) calciumfluorosilicate (4) UU
43. Chloro compound of Vanadium has only 43. U U 1.73 BM

spin magnetic moment of 1.73 BM. This S U U U
Vanadium chloride has the formula : (V U 523) U UU
(at. no. of V523)
(1) VCl2 (1) VCl2
(2) VCl4 (2) VCl4
(3) VCl3 (3) VCl3
(4) VCl5 (4) VCl5

44. An octahedral complex of Co 31 is 44. Co31 c U
diamagnetic. The hybridisation involved U U
in the formation of the complex is :
(1) sp3d2 (1) sp3d2
(2) dsp2 (2) dsp2
(3) d2sp3 (3) d2sp3
(4) dsp3d (4) dsp3d
45. Which of the following is not formed when 45. K2Cr2O7 H2S
H 2S reacts with acidic K 2 Cr 2 O 7 U ?
solution ? (1) CrSO 4
(1) CrSO 4 (2) Cr2(SO4)
3
(2) Cr2(SO4) (3) K2SO 4
3
(3) K2SO 4 (4) S
(4) S
46. U
46. Which of the following has unpaired ?
electron(s) ? (1) N2
(1) N2
(2) O2
2
(2) O2
2
(3) N 221
(3) N 221
(4) O 222
(4) O 222

47. In the following sets of reactants which 47. U U
two sets best exhibit the amphoteric Al2O3 . xH2O U
character of Al2O3 . xH2O ? ?
2 2
Set 1 : Al2O3 . xH2O (s) and OH (aq) Set 1 : Al2O3 . xH2O (s) U OH ()
Set 2 : Al2O3 . xH2O (s) and H2O (l) Set 2 : Al2O3 . xH2O (s) U H2O ()
1 1
Set 3 : Al2O3 . xH2O (s) and H (aq) Set 3 : Al2O3 . xH2O (s) U H ()
Set 4 : Al2O3 . xH2O (s) and NH3 (aq) Set 4 : Al2O3 . xH2O (s) U NH3 ()
(1) 1 and 2 (1) 1 U 2
(2) 1 and 3 (2) 1 U 3
(3) 2 and 4 (3) 2 U 4
(4) 3 and 4 (4) 3 U 4
48. The number and type of bonds in C 222 ion 48. CaC2 C 222
in CaC2 are : U ?
(1) One s bond and one p2bond (1) s U p2
(2) One s bond and two p2bonds (2) s U p2
(3) Two s bonds and two p2bonds (3) s U p2
(4) Two s bonds and one p2bond (4) s U p2
49. The form of iron obtained from blast 49. ^ M

furnace is :
(1) Steel (1) S (Steel)
(2) Cast Iron (2) U (Cast Iron)
(3) Pig Iron (3) (Pig Iron)
(4) Wrought Iron (4) U (Wrought Iron)

50. The correct statement about the magnetic 50. [Fe(CN)6]32 U [FeF6]32
properties of [Fe(CN)6]32 and [FeF6]32 U (Z526).
is : (Z526).
(1) both are paramagnetic. (1)
(2) both are diamagnetic. (2)
(3) [Fe(CN) 6 ] 32 is diamagnetic, (3) [Fe(CN)6]32 U
[FeF6]32 is paramagnetic. [FeF6]32
(4) [Fe(CN) 6 ] 32 is paramagnetic, (4) [Fe (CN)6]32 U [FeF6]32
[FeF6]32 is diamagnetic.
51. Which one of the following reactions will 51. -

not result in the formation of carbon- ?
carbon bond ?
(1) Reimer-Tieman reaction (1) UU - U
(2) Friedel Crafts acylation (2) U U
(3) Wurtz reaction (3) U$
(4) Cannizzaro reaction (4) $U
52. In the hydroboration - oxidation reaction 52. UU, H2O2 U NaOH

of propene with diborane, H 2 O 2 and UU-U
NaOH, the organic compound formed is :
(1) CH3CH2OH (1) CH3CH2OH
(2) CH3CHOHCH3 (2) CH3CHOHCH3
(3) CH3CH2CH2OH (3) CH3CH2CH2OH
(4) (CH3) COH (4) (CH3) COH
3 3

53. The major product of the reaction 53.
NaNO /H SO NaNO /H SO

2 2 4

2 2 4

is :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
54. For the compounds

CH3Cl, CH3Br, CH3I and CH3F,
54.
the correct order of increasing C-halogen
CH3Cl,CH3Br,CH3I U CH3F
bond length is :
- U U
(1) CH3F < CH3Cl < CH3Br < CH3I

(2) CH3F < CH3Br < CH3Cl < CH3I
(1) CH3F < CH3Cl < CH3Br < CH3I
(3) CH3F < CH3I < CH3Br < CH3Cl
(2) CH3F < CH3Br < CH3Cl < CH3I
(4) CH3Cl < CH3Br < CH3F < CH3I
(3) CH3F < CH3I < CH3Br < CH3Cl
(4) CH3Cl < CH3Br < CH3F < CH3I

55. Allyl phenyl ether can be prepared by 55. U U U
heating :
(1) C6H5Br1CH25CH2CH22ONa (1) C6H5Br1CH25CH2CH22ONa
(2) CH25CH2CH22Br1C6H5ONa (2) CH25CH2CH22Br1C6H5ONa
(3) C6H52CH5CH2Br1CH32ONa (3) C6H52CH5CH2Br1CH32ONa
(4) CH25CH2Br1C6H52CH22ONa (4) CH25CH2Br1C6H52CH22ONa
56. In a nucleophilic substitution reaction : 56. S

DMF DMF
R2Br1Cl2 R_Cl1Br2, R2Br1Cl2 R_Cl1Br2,
which one of the following undergoes Z S U U
complete inversion of configuration ? ?
(1) C6H5CHC6H5Br (1) C6H5CHC6H5Br
(2) C6H5CH2Br (2) C6H5CH2Br
(3) C6H5CH CH3Br (3) C6H5CH CH3Br
(4) C6H5CCH3C6H5Br (4) C6H5CCH3C6H5Br
57. In which of the following pairs A is more 57. A, S B ?

stable than B ?
A B A B
(1) (1)
(2) (2)
(3) (3)

(4) Ph3C , (CH3) C (4) Ph3C , (CH3) C
3 3

58. Structure of some important polymers are 58. U h U
given. Which one represents Buna-S ? -S ?
(1) (1)
(2) (2)
(3) (3)
(4) (4)
59. Which is the major product formed when 59.

acetone is heated with iodine and U U U U UU
potassium hydroxide ? U ?
(1) Iodoacetone (1) UU
(2) Acetic acid (2) U U
(3) Iodoform (3) U$
(4) Acetophenone (4) U
60. Which one of the following class of 60. U U U

compounds is obtained by polymerization ?
of acetylene ?
(1) Poly-yne (1) -
(2) Poly-ene (2) -
(3) Poly-ester (3) -SUU
(4) Poly-amide (4) -U

PART C MATHEMATICS C
61. Let P be the relation defined on the set of 61. P S U U
all real numbers such that
P5{(a, b) : sec2 a2tan2 b51}. Then P is : P5{(a, b) : sec2 a2tan2 b51} , P
(1) reflexive and symmetric but not (1) S U
transitive.
(2) reflexive and transitive but not (2) S U
symmetric.
(3) symmetric and transitive but not (3) U S
reflexive.
(4) an equivalence relation. (4)
62. Let w(Im w 0) be a complex number. 62. w(Im w 0) ,

Then the set of all complex numbers z z , S
satisfying the equation w2 w z5k (12z), k , U w2 w z5k (12z)
for some real number k, is : cU U ,
(1) {z : ?z?51} (1) {z : ?z?51}
(2) {z : z5 z } (2) {z : z5 z }
(3) {z : z 1} (3) {z : z 1}
(4) {z : ?z?51, z 1} (4) {z : ?z?51, z 1}
63. If equations ax 2 1bx1c50, 63. U ax 2 1bx1c50,

(a, b, c R, a 0) and 2x213x1450 have (a, b, c R, a 0) 2x213x1450
a common root, then a : b : c equals : cU , a : b : c UU
(1) 1:2:3 (1) 1:2:3
(2) 2:3:4 (2) 2:3:4
(3) 4:3:2 (3) 4:3:2
(4) 3:2:1 (4) 3:2:1

1 1 1 1
64. If and are the roots of the 64. b U ax21bx1150
a b a
equation, ax21bx1150 (a 0, a, b R), (a 0, a, b R) , U
then the equation, x(x1b3)1(a323abx)50
x(x1b3)1(a323abx)50 has roots :
3 3 3 3
(1) a 2 and b 2 (1) a 2 b 2
1 1 1 1
(2) a b 2 and a 2 b (2) ab 2 a 2 b
(3) a b and a b (3) ab a b

223 223 223 223
(4) a and b (4) a b
65. If a, b, c are non - zero real numbers and if 65. a, b, c U S

the system of equations U
(a21)x5y1z, (a21)x5y1z,
(b21)y5z1x, (b21)y5z1x,
(c21)z5x1y, (c21)z5x1y,
has a non-trivial solution, then U , ab1bc1ca UU
ab1bc1ca equals :
(1) a1b1c (1) a1b1c
(2) abc (2) abc
(3) 1 (3) 1
(4) 21 (4) 21

66. If B is a 333 matrix such that B250, then 66. B
333 B250 ,
det. [(I1B)50250B] is equal to : det. [(I1B)50250B] UU
(1) 1 (1) 1
(2) 2 (2) 2
(3) 3 (3) 3
(4) 50 (4) 50
67. The number of terms in the expansion of 67. (11x)101 (11x22x)100 x U

(11x)101 (11x22x)100 in powers of x is :
(1) 302 (1) 302
(2) 301 (2) 301
(3) 202 (3) 202
(4) 101 (4) 101
68. The sum of the digits in the units place of 68. 3, 4, 5 6 ,

all the 4-digit numbers formed by using the U, U
numbers 3, 4, 5 and 6, without repetition, S U
is :
(1) 432 (1) 432
(2) 108 (2) 108
(3) 36 (3) 36
(4) 18 (4) 18

69. Given an A.P. whose terms are all positive 69. U Z
integers. The sum of its first nine terms is 200
greater than 200 and less than 220. If the 220 U 12 ,
second term in it is 12, then its 4th term
is :
(1) 8 (1) 8
(2) 16 (2) 16
(3) 20 (3) 20
(4) 24 (4) 24
70. If the sum 70.

3 5 7 3 5 7
1 2
2 2
1 2 1.......1 u p t o 1 2 1 2 1.......1 20
1 1 12 1 1 2 2 1 32 1 2
1 12 2
1 1 2 2 1 32
k k
20 terms is equal to , then k is equal to : UU , k UU
21 21
(1) 120 (1) 120
(2) 180 (2) 180
(3) 240 (3) 240
(4) 60 (4) 60
71. ( )
If f(x) is continuous and f 9 2 5 2 9 , then 71. f(x) ( )
f 9 2 52 9 ,
12 cos 3x 12 cos 3x
lim f is equal to : lim f UU
x0 x2 x0 x2
(1) 9/2 (1) 9/2
(2) 2/9 (2) 2/9
(3) 0 (3) 0
(4) 8/9 (4) 8/9

d2 y d2 x d2 y d2 x
72. If y5enx, then 2 2 is equal to : 72. y5enx , 2 2 UU
dx dy dx dy
(1) n enx (1) n enx
(2) n e2nx (2) n e2nx
(3) 1 (3) 1
(4) 2n e2nx (4) 2n e2nx
73. If the Rolles theorem holds for the 73. f(x)52x31ax21bx U

function f(x)52x31ax21bx in the interval 1
[21, 1] c5 U U ,
1 2
[21, 1] for the point c5 , then the value
2 2a1b
of 2a1b is :
(1) 1 (1) 1
(2) 21 (2) 21
(3) 2 (3) 2
(4) 22 (4) 22
3 x 4 x x x
74. If f (x )5 1 2 1 , x R, then the 74.
5 5
f (x )5 3 4
1 2 1 , x R ,
5

5
equation f(x)50 has : U f(x)50 /
(1) no solution (1)
(2) one solution (2)
(3) two solutions (3)
(4) more than two solutions (4)

sin 8 x 2 cos8 x sin 8 x 2 cos8 x
75. dx is equal to : 75. dx UU
(12 2 sin 2 x cos 2 x ) (12 2 sin 2 x cos 2 x )
1 1
(1) sin 2x1c (1) sin 2x1c
2 2
1 1
(2) 2 sin 2x1c (2) 2 sin 2x1c
2 2
1 1
(3) 2 sin x1c (3) 2 sin x1c
2 2
(4) 2sin2 x1c (4) 2sin2 x1c
1 1
2 l n (11 2 x ) 2 l n (11 2 x )
76. The integral 0 2
d x , equals : 76. d x , UU
11 4 x 0 11 4 x 2
p p
(1) ln 2 (1) ln 2
4 4
p p
(2) ln 2 (2) ln 2
8 8
p p
(3) ln 2 (3) ln 2
16 16
p p
(4) ln 2 (4) ln 2
32 32
77. Let A5{(x, y) : y2 [ 4x, y22x/24}. The 77. A5{(x, y) : y2 [ 4x, y22x/24}
area (in square units) of the region A is : A ( )
(1) 8 (1) 8
(2) 9 (2) 9
(3) 10 (3) 10
(4) 11 (4) 11

78. If the differential equation representing the 78. , x-
family of all circles touching x-axis at the U S U , U
dy dy
origin is (x 22y 2) 5g(x) y, then g(x) (x22y2) 5g(x) y, , g(x) UU
dx dx
equals :
1 1
(1) x (1) x
2 2
(2) 2x 2 (2) 2x 2
(3) 2x (3) 2x
1 2 1 2
(4) x (4) x
2 2
79. Let a and b be any two numbers satisfying 1 1 1

79. a U b, 2
1 2 5 cU U
4
1 1 1 a b
1 2 5 . Then, the foot of x y
a2
b 4 , UU, 1 51
a b
perpendicular from the origin on the
x y U , S
variable line, 1 51 , lies on :
a b
(1) U U ,
(1) a hyperbola with each 5 2
semi-axis5 2 .
(2) U U U ,
(2) a hyperbola with each semi-axis52. 52
(3) U, 52
(3) a circle of radius52
(4) U, 5 2
(4) a circle of radius5 2

80. Given three points P, Q, R with P(5, 3) and 80. P, Q, R P(5, 3) R,
R lies on the x-axis. If equation of RQ is
x- U S RQ U
x22y52 and PQ is parallel to the x-axis,
then the centroid of DPQR lies on the x22y52 PQ, x- U ,
line : DPQR U U S ,
(1) 2x1y2950
(2) x22y1150 (1) 2x1y2950
(3) 5x22y50 (2) x22y1150
(4) 2x25y50 (3) 5x22y50
(4) 2x25y50
81. If the point (1, 4) lies inside the circle
x 2 1y 2 26x210y1p50 and the circle 81. (1, 4) x21y226x210y1p50
does not touch or intersect the coordinate S ,
axes, then the set of all possible values of p
is the interval : S U , U U , p
(1) (0, 25) U
(2) (25, 39) (1) (0, 25)
(3) (9, 25) (2) (25, 39)
(4) (25, 29) (3) (9, 25)
(4) (25, 29)
82. If OB is the semi-minor axis of an ellipse,
F1 and F2 are its foci and the angle between
82. OB, , F1
F 1 B and F 2B is a right angle, then the F2 F1B F2B
square of the eccentricity of the ellipse is : ,
1
(1)
2 1
(1)
1 2
(2)
2 1
(2)
1 2
(3)
2 2 1
(3)
1 2 2
(4)
4 1
(4)
4

83. Equation of the plane which passes 83. U, U
through the point of intersection of lines x 21 y 2 2 z2 3
5 5
x 21 y 2 2 z2 3 3 1 2
5 5 and
3 1 2 x 2 3 y 21 z2 2
5 5
x 2 3 y 21 z2 2 1 2 3
5 5
1 2 3 U U ,
and has the largest distance from the origin U U ,
is :
(1) 7x12y14z554 (1) 7x12y14z554
(2) 3x14y15z549 (2) 3x14y15z549
(3) 4x13y15z550 (3) 4x13y15z550
(4) 5x14y13z557 (4) 5x14y13z557
84. A line in the 3-dimensional space makes 84. (space) U x y,

p
an angle u 0 < u [ with both the u 0 < u [ p
,
2
2
x and y axes. Then the set of all values of u U
u is the interval :
p p
(1) 0 , (1) 0 ,
4 4
p p p p
(2) 6 , 3 (2) 6 , 3
p p p p
(3) 4 , 2 (3) 4 , 2
p p p p
(4) , (4) ,
3 2 3 2

85. If ? a ?5 2, ? b ?5 3 and ?2 a 2 b ?5 5 , then 85. ? a ?5 2, ? b ?5 3 ?2 a 2 b ?5 5 ,

?2 a 1 b ? equals : ?2 a 1 b ? UU
(1) 17 (1) 17
(2) 7 (2) 7
(3) 5 (3) 5
(4) 1 (4) 1
86. In a set of 2n distinct observations, each of 86. 2n , ,

the observation below the median of all the , 5
observations is increased by 5 and each of 3
the remaining observations is decreased by U ,
3. Then the mean of the new set of
observations :
(1) increases by 1. (1) 1
(2) decreases by 1. (2) 1 U
(3) decreases by 2. (3) 2 U
(4) increases by 2. (4) 2
87. If A and B are two events such that 87. A B U P(AB)5P(AB)

P(AB)5P(AB), then the incorrect , ?
statement amongst the following
statements is : (1) A B
(1) A and B are equally likely (2) P(AB9)50
(2) P(AB9)50 (3) P(A9B)50
(3) P(A9B)50 (4) P(A)1P(B)51
(4) P(A)1P(B)51

88. The number of values of a in [0, 2p] for 88. [0, 2p] a
,
which 2 sin3 a27 sin2 a17 sin a52, is : 2 sin3 a27 sin2 a17 sin a52 ,
(1) 6 (1) 6
(2) 4 (2) 4
(3) 3 (3) 3
(4) 1 (4) 1
p1q p1q
89. If cosec u5
p2q
(pq0), then 89. cosec u5 (pq0) ,
p2q
p u p u
cot 1 is equal to :
4 2 cot 1
4 2
UU
p p
(1) (1)
q q
q q
(2) (2)
p p
(3) pq (3) pq
(4) pq (4) pq
90. The contrapositive of the statement I go 90. S

to school if it does not rain is : (Contrapositive)
(1) If it rains, I do not go to school. (1) , S
(2) If I do not go to school, it rains. (2) S ,
(3) If it rains, I go to school. (3) , S
(4) If I go to school, it rains. (4) S ,
-o0o- -o0o-

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PART A PHYSICS A

1. An experiment is performed to obtain the 1. L U U L

(1) tan21 2 3 (2) tan21 3 2

(2) tan21 3 2 (3) tan21 7 4

(3) tan21 7 4 (4) tan21 4 5

English : 1 Set : 01 Hindi : 1 Set : 01

4. A block A of mass 4 kg is placed on 4. 4 kg A U

English : 2 Set : 01 Hindi : 2 Set : 01

English : 3 Set : 01 Hindi : 3 Set : 01

English : 4 Set : 01 Hindi : 4 Set : 01

(1) 500 days (1) 500

English : 5 Set : 01 Hindi : 5 Set : 01

9. The amplitude of a simple pendulum, 9. U U U

English : 6 Set : 01 Hindi : 6 Set : 01

11. Water of volume 2 L in a closed container 11. 2 L 1 kW

English : 7 Set : 01 Hindi : 7 Set : 01

13. Modern vacuum pumps can evacuate a 13. U (300 K) U

English : 8 Set : 01 Hindi : 8 Set : 01

English : 9 Set : 01 Hindi : 9 Set : 01

16. The magnitude of the average electric field 16. cU U U U U

English : 10 Set : 01 Hindi : 10 Set : 01

18. A d.c. main supply of e.m.f. 220 V is 18. l 220 V cU U

English : 11 Set : 01 Hindi : 11 Set : 01

English : 12 Set : 01 Hindi : 12 Set : 01

English : 13 Set : 01 Hindi : 13 Set : 01

English : 14 Set : 01 Hindi : 14 Set : 01

(1) 15333 5 cm (1) 15333 5 cm

(2) 1533 7 cm (2) 1533 7 cm

English : 15 Set : 01 Hindi : 15 Set : 01

English : 16 Set : 01 Hindi : 16 Set : 01

25. The focal lengths of objective lens and eye

English : 17 Set : 01 Hindi : 17 Set : 01

28. Identify the gate and match A, B, Y in

(1) AND (A51, B51, Y51)

English : 18 Set : 01 Hindi : 18 Set : 01

English : 19 Set : 01 Hindi : 19 Set : 01

English : 20 Set : 01 Hindi : 20 Set : 01

(E ) of four metals A, B, C and D are

34. At a certain temperature, only 50% HI is 34. U 50% HI, H2 U

35. Dissolving 120 g of a compound of 35. (U 60) 120

English : 21 Set : 01 Hindi : 21 Set : 01

37. A current of 10.0 A flows for 2.00 h 37. X U UU

English : 22 Set : 01 Hindi : 22 Set : 01

39. The temperature at which oxygen 39. , U

40. The standard enthalpy of formation of 40. NH3 246.0 kJ/

English : 23 Set : 01 Hindi : 23 Set : 01

43. Chloro compound of Vanadium has only 43. U U 1.73 BM

English : 24 Set : 01 Hindi : 24 Set : 01

English : 25 Set : 01 Hindi : 25 Set : 01

49. The form of iron obtained from blast 49. ^ M

English : 26 Set : 01 Hindi : 26 Set : 01

51. Which one of the following reactions will 51. -

52. In the hydroboration - oxidation reaction 52. UU, H2O2 U NaOH

English : 27 Set : 01 Hindi : 27 Set : 01

54. For the compounds

English : 28 Set : 01 Hindi : 28 Set : 01

56. In a nucleophilic substitution reaction : 56. S

57. In which of the following pairs A is more 57. A, S B ?

English : 29 Set : 01 Hindi : 29 Set : 01

59. Which is the major product formed when 59.

60. Which one of the following class of 60. U U U

English : 30 Set : 01 Hindi : 30 Set : 01

62. Let w(Im w 0) be a complex number. 62. w(Im w 0) ,