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Section: Senior (SI0,1&2) QUALITATIVE ANALYSIS Date: 29-06-2014

Name of the student: I.D.No: Sec:
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SINGLE ANSWER TYPE
1. Before proceeding for Group III analysis, the filtrate of Group II or original solution is boiled with
HNO3 . HNO3 should be taken in small amount to avoid precipitation of the following
A) Ni (OH )2 B) Mn(OH )3 C) Al (OH )3 D) Mn(OH )2
2. Sulphide ions react with Na2[Fe(NO) (CN)5] to form a purple coloured compound Na4[Fe(CN)5
(NOS)]. In the reaction, the oxidation state of ironis _____.
A)Changes from +2 to +3 C)Changes from +3 to +2 C) Changes from +2 to +4 D) Does not change
3. Which of the following mixtures can be separated by using an NH3 solution?
A)Fe3+ and Al3+ B)Al3+ and Zn2+ C)Sn2+ and Pb2+ D)Cu2+ and Cd2+
4. The FeCl3 solution stored in the laboratory is And is made neutral by adding before use.
A)Alkalines, HCl B) Alkaline, H 2 SO4 C) Acidic, NH 4OH D) Acidic, NaOH
5. Which of the following metal oxides is white incolour but becomes yellow on heating
A) Ag2O B) ZnO C) FeO D) MgO
6. In the precipitation of the iron group in qualitative analysis, ammonium chloride is added before adding
ammonium hydroxide to
A) Decrease concentration of OH ions B) Prevent interference by phosphate ions

C) Increase concentration of Cl ions D) Increase in the concentration of NH 4 ions
7. HgCl2 is reduced to Hg2Cl2 by:
A)CH3COOH B)CCl4 C) HCOOH D)NH3
8. In the fifth group, ( NH 4 )2 CO3 is added to precipitate out the carbonates, we do not add Na2CO3
because
A) CaCO3 is soluble in Na2CO3 B) Na2CO3 increases the solubility of fifth group carbonates
C) MgCO3 will be precipitated out in fifth group D) None of these
9. Which of the following nitrates will leave behind a metal on strong heating?
A) Ferric nitrate B) Copper nitrate C) Manganese nitrate D) Silver nitrate
10. When excess of dilute NH 4OH is added to an aqueous solution of copper sulphate, an intense blue
color is obtained. This is due to the presence of
A) CuSO4 B) Cu(OH )2 C) [Cu ( NH 3 ) 4 ]2 D) ( NH 4 )2 SO4
11. Which compound will not give positive chromyl chloride test?
A)Copper chloride, Cucl2 B) Mercuric chloride, HgCl2
C) Zinc chloride, ZnCl2 D) Sodium chloride, NaCl
12. Zn 2 dissolves in excess of NaOH due to the formation of
A) Soluble Zn(OH )2 B) Soluble Na2 [ Zn(OH )4 ] C) Soluble Na(Zn(OH )3 ] D) ZnO
K Cr O HS
13. The number of moles of 2 2 7 that will be needed to react one mole of 2 in acidic medium
A) 1/ 6 B) 1/ 3 C) 2 / 5 D) 2 / 3
14. Which of the following pairs of cations can be separated by adding NH4Cl, NH4OH and then (NH4)2CO3
to the mixture?
A)Ca2+, Mg2+ B)Ba2+, Sr2+ C)Sr2+, Ca2+ D)Ba2+, Ca2+
15. Identify the correct order of solubility of Na2S, CuS and ZnS:
A)CuS>ZnS> Na2S B)ZnS> Na2S >CuS C)Na2S >CuS>ZnS D)Na2S >ZnS>CuS
16. FeSO4 is used in the brown ring test for a nitrate. What is the oxidation state of Fe in the compound
responsible for the brown colour of the ring?
 A) 0 B) 1 C) +2 D)+3
17. Which of the following sulphides is white?
A)CdSB)PbSC)ZnS D)SnS
18. The nature of an aqueous solution of FeCl2 is
A)acidic B)basic C)amphoteric D) neutral
19. A black sulphide is formed by the action of H2S on:
A) CuCl2 B)CdCl2 C)ZnCl2 D)NaCl
20. When KMnO4 reacts with acidified FeSO4
A) Only FeSO4 is oxidized B) Only KMnO4 is oxidized
C) FeSO4 is oxidized and KMnO4 is reduced D) KMnO4 and FeSO4 oxidized
21. Which of the following in insoluble in yellow ammonium polysulphide?
A)CuS B)As2S3 C)Sb2S3 D)SnS
22. When SO2 is passed through acidified K 2Cr2O7 solution
A) The solution turns blue B) The solution is decolourised
C) SO2 is reduced D) Green Cr2 ( SO4 )3 is formed
23. Which of the following reagents can beused distinguish between Na2CO3 and Na2 SO3 ?
A) Limewater B)Baryta water C) Acidified K 2Cr2O7 solution D) H 2 SO4 solution
24. An aqueous solution of a substance gives a white precipitate on treatment with dil. HCl which
dissolves on heating, When H2S is passed through the hot acidic solution, black precipitate is
obtained. The substance is:
A) Hg 22 salt B) Hg 2 salt C) Ag salt D) Pb 2 salt
25. N2 ,
X Y
H2 O
Z
CuSO4
T Blue colour Y and T respectively,
Colourless
(A) Mg(NO2)2, [Cu(NH3)4]SO4 (B) Mg3N2, [Cu(NH3)4]SO4
(C) MgO, [Cu(NH3)4]SO4 (D) Mg(NO3)2, [Mg(NH3)4]SO4
26. The only cations present in a slightly acidic solution are Fe3+, Zn2+ and Cu2+. The reagent that when added in
excess to this solution would identify and separate Fe3+ in one step, is
(A) 2 M HCl (B)6 M NH3 (C) 6 M NaOH (D) H2S gas
27. SnCl2 excess NaOH A, then A is
A) Na2 SnO2 B) Na2 SnO3 C) Na2 SnO4 D) NaSnO
28. AuCl3 FeCl2 pale yellow solution, it is
A) Fe B) Sn C) FeCl3 D) SnCl2
29. K 2Cr2O7 (Acidified ) AuCl
The net reaction is not given. Which of the following is present in the final stage.
A) Cr 3 B) AuCl3 C) Cr2 SO4 3 D) Cr2O72
30. KMnO4 (Basic medium ) KI A B C ; B+ Acetaldehyde I 2 yellow ppt, B is
A) KOH B) KIO3 C) MnO2 D) MnO42
31. Which of the following reagent can be used to separate Cu 2 and Ca 2
A) dil HCl B) NH 4OH / NH 4Cl C) dil HCl / H 2 S gas D) NaOH (dil )
32. A salt of potassium gave following acidic radical Test & observations
i) Release pungent gas by adding dil H 2 SO4
ii) The gas turns lime water milky
The salt is
A) KNO3 B) K 2 SO4 C) K2 SO3 D) K 2 S or K 2CO3
33. A salt solution is not effected by dil HCl but on passing H 2 S gas in to the solution black ppt which is
insoluble in yellow Ammonium sulphide is formed. Which of the following basic radical will not
respond to this reaction.
A) Cu 2 B) Bi 3 C) Cd 2 D) As 3
34. Oxidation state of iron in NO. FeSO4
A) +2 and +3 B) only +2 C) only +3 D) only +1
3
35. Fe solu NH 4 SCN solu
slightly
acidic
Deep red colouration is due to
2
A) Fe SCN B) Fe SCN 3 C) Fe SCN 4 D)ALL
36. Cu2 S2O3 Na2 S 2O3 excess Na4 Cu6 S2O3 x here x is
A) 4 B) 5 C) 6 D) 9

37. Al OH 3 OH Al (OH ) 4 . Which of the following should cause the reaction to


proceed from right to left
A) NH 4Cl heating B)By addition of a small amount of acid
C)both A &B D)excess of NaOH.
2
38. Hg is precipitated by
A) dil HCl NH 4OH B) dil HCl H 2 S C) dil HCl D) NH 4OH NH 4Cl
MULTIPLE ANSWER TYPE
39. K4[Fe(CN)6] is used for the detection of
(A) Fe2+ (B)Fe3+ (C) Cu2+ (D) Zn2+
40. Which of the following cations can not be detected by the flame test ?
(A) K+ (B)Ba2+ (C) Sr2+ (D)Mg2+
41. Which of the following will respond positively to the chromyl chloride test ?
(A) CuCl2 (B)ZnCl2 (C) HgCl2 (D)AgCl
1
42. How many given below react with Ag and Reduce it to Ag
A) Glucose B) PH 3 C) Cu D) Zn
43. How many of the salts reacts with conc acid followed by reaction with MnO2 to release
coloured gases on warming
A) NaI B) KBr C) KI D) RbCl
44. How many of the ions give red coloration in Flame Test
A) Ba 2 B) Sr 2 C) Cu 2 D) Ca 2
45. The basic radical(s) for which, group reagent is NH 4OH NH 4Cl
A) Fe 3 B) As 3 C) Cr 3 D) Al 3
46. How many of the reagent(s) react with AgNO3 and give colourless solution or white precipitate
A) Na2 S2O3 excess B) NaCNS C) Na2 S D) K 2CrO4
47. The Reagents used in chromyl chloride Test is/are
A) HCl B) K 2Cr2O7 C) H 2 SO4 D) NaOH
48. How many reagents of following is/are involved in separation of Mn2 , Ag 1, Fe3 , Cu 2 in a given
mixture
A) Dil HCl B) dil HCl H 2 S C) H 2 S NH 4OH D) NH 4OH NH 4Cl
INTEGER ANSWER TYPE
49. Acidified KMnO4 KI I 2 " n " moles of H 2O , here n is ____ moles in product(s) obtained
50. Oxidation state of cobalt in Rinmann green is _________
51. How many of the following sulphides are decomposed by dil H 2 SO4 easily PbS , CdS , Na2 S , CoS , Sb2 S3
52. Cu 2 excess NH 3 Blue color
In Blue color compound Cu 2 is associated with ______ number of NH 3 molecules
53. Acidified K 2Cr2O7 SnCl2
products , oxidation number of Tin in final product is ______
54. In estimation of mixture of Fe2 and Fe 3 using standard K 2Cr2O7 in presence of
diphenylamine indicator. The number of moles of Fe2 reacting with one mole of
acidified K 2Cr2O7 is --------
55. FeSO4 H 2 SO4 K2Cr2O7 H 2O iron salt, the oxidation state of iron in product is
56. How many of the salts of silver are black Ag2 S , AgCNS , AgI , AgBr , AgCl , Ag3 PO4
57. A sodium salt reacts with dil HCl and upon warming gives vinegar like smell. On
adding of FeCl3 it turns deep red-coloration owing to formation of a complex ion. The
number of acetate in coordination sphere of complex ion is ______
58. Out of given sulphide ppt of group II radicals (Hgs, Pbs, Bi2S3, Cus, Cds). the sum total of all the black
and yellow ppt. will be ?
59. Suppose you have given certain reagents like :
K 2 Cr2O7 / H ; H2SO4 Conc. ;H2SO4 dil. AgNO3 solution
How many of them can be used to detect Cl & NO 3 radicals for given sample ?
60. For the given radicals Mg 2 , Mn 2 , Cu 2 , Ni 2 the number of radicals that will give borax bead test ?
MATCHING TYPE
61. Match the following:
Column-I Column-II
A)Brown ring test P) NO3
B)Blue ring test Q) NO2
C)sodium nitro prusside R) S2O32
D) Dilute.H 2 SO4 S) Na2 S
62. Column I (Radicals) Column II (colour of borax bead in hot oxidizing flame)
(A) Co2+ (p) Violet
(B) Fe3+ (q) Blue
3+
(C) Cr (r) Yellow
(D) Mn2+ (s) Yellowish brown
63. Match the ions of column I with the reagent in column II. Which responds to a positive test
Column I (Radicals) Column II (Reagents)
(A) Cl
(p) K 2Cr2O7 , H
(B) SO32 (q) H2SO4 Conc.
(C) S2 (r) H2SO4 dil.
(D) NO 3 (s) AgNO3 solution
KEY
1 B 2 D 3 B 4 C 5 B 6 A 7 C 8 C
9 D 10 C 11 B 12 B 13 B 14 A 15 D 16 B
17 C 18 A 19 A 20 B 21 A 22 D 23 C 24 D
25 B 26 B 27 A 28 C 29 D 30 A 31 C 32 C
33 D 34 D 35 D 36 B 37 C 38 B 39 ABCD 40 D
41 AB 42 ACD 43 ABCD 44 BD 45 ACD 46 AB 47 BC 48 ABCD
49 8 50 2 51 2 52 4 53 4 54 6 55 3 56 1
57 6 58 4 (or) 59 4 60 3 61 A-PQ; B-R; C-S; D-QRS
5
62 A-Q; B-S; C-R; D-P 63 A-PQS; B-PR; C-PRS; D-Q