Metanol(1)/Agua(2) T=15.

5
P.M Metanol 32.04
P.M Agua 18.015
Base 100 g
% peso Mol A Mol B X1 Densidad (g/ml) P.M mezcla(g/mol)
0 0 5.55092978 0.0000 0.999 18.015000
1 0.03121099 5.49542048 0.0056 0.9973 18.094205
2 0.06242197 5.43991119 0.0113 0.9955 18.174109
3 0.09363296 5.38440189 0.0171 0.9938 18.254721
4 0.12484395 5.32889259 0.0229 0.9921 18.336053
5 0.15605493 5.27338329 0.0287 0.9904 18.418112
6 0.18726592 5.21787399 0.0346 0.9889 18.500909
7 0.2184769 5.1623647 0.0406 0.9872 18.584453
8 0.24968789 5.1068554 0.0466 0.9857 18.668756
9 0.28089888 5.0513461 0.0527 0.9841 18.753827
10 0.31210986 4.9958368 0.0588 0.9826 18.839677
11 0.34332085 4.9403275 0.0650 0.9811 18.926316
12 0.37453184 4.88481821 0.0712 0.9796 19.013756
13 0.40574282 4.82930891 0.0775 0.9781 19.102008
14 0.43695381 4.77379961 0.0839 0.9766 19.191083
15 0.46816479 4.71829031 0.0903 0.9752 19.280992
16 0.49937578 4.66278102 0.0967 0.9738 19.371748
17 0.53058677 4.60727172 0.1033 0.9723 19.463362
18 0.56179775 4.55176242 0.1099 0.9709 19.555847
19 0.59300874 4.49625312 0.1165 0.9695 19.649215
20 0.62421973 4.44074382 0.1232 0.968 19.743479
21 0.65543071 4.38523453 0.1300 0.9666 19.838651
22 0.6866417 4.32972523 0.1369 0.9652 19.934746
23 0.71785268 4.27421593 0.1438 0.9638 20.031776
24 0.74906367 4.21870663 0.1508 0.9624 20.129755
25 0.78027466 4.16319734 0.1578 0.9609 20.228698
26 0.81148564 4.10768804 0.1650 0.9595 20.328617
27 0.84269663 4.05217874 0.1722 0.958 20.429529
28 0.87390762 3.99666944 0.1794 0.9565 20.531448
29 0.9051186 3.94116014 0.1868 0.9550 20.634389
30 0.93632959 3.88565085 0.1942 0.9535 20.738367
31 0.96754057 3.83014155 0.2017 0.9521 20.843398
32 0.99875156 3.77463225 0.2092 0.9505 20.949499
33 1.02996255 3.71912295 0.2169 0.9489 21.056686
34 1.06117353 3.66361366 0.2246 0.9473 21.164974
35 1.09238452 3.60810436 0.2324 0.9456 21.274383
36 1.12359551 3.55259506 0.2403 0.944 21.384928
37 1.15480649 3.49708576 0.2482 0.9422 21.496629
38 1.18601748 3.44157646 0.2563 0.9405 21.609502
39 1.21722846 3.38606717 0.2644 0.9387 21.723567
40 1.24843945 3.33055787 0.2726 0.9369 21.838842
41 1.27965044 3.27504857 0.2810 0.9351 21.955348
42 1.31086142 3.21953927 0.2893 0.9333 22.073103
43 1.34207241 3.16402998 0.2978 0.9315 22.192128
44 1.3732834 3.10852068 0.3064 0.9297 22.312443
45 1.40449438 3.05301138 0.3151 0.9279 22.434071
46 1.43570537 2.99750208 0.3239 0.9261 22.557031
47 1.46691635 2.94199278 0.3327 0.9242 22.681347
48 1.49812734 2.88648349 0.3417 0.9223 22.807041
49 1.52933833 2.83097419 0.3507 0.9204 22.934136
50 1.56054931 2.77546489 0.3599 0.9185 23.062655
51 1.5917603 2.71995559 0.3692 0.9166 23.192623
52 1.62297129 2.66444629 0.3785 0.9146 23.324064
53 1.65418227 2.608937 0.3880 0.9126 23.457003
54 1.68539326 2.5534277 0.3976 0.9106 23.591466
55 1.71660424 2.4979184 0.4073 0.9086 23.727480
56 1.74781523 2.4424091 0.4171 0.9065 23.865071
57 1.77902622 2.38689981 0.4270 0.9045 24.004267
58 1.8102372 2.33139051 0.4371 0.9024 24.145096
59 1.84144819 2.27588121 0.4472 0.9002 24.287588
60 1.87265918 2.22037191 0.4575 0.898 24.431771
61 1.90387016 2.16486261 0.4679 0.8958 24.577677
62 1.93508115 2.10935332 0.4785 0.8936 24.725336
63 1.96629213 2.05384402 0.4891 0.8913 24.874779
64 1.99750312 1.99833472 0.4999 0.889 25.026041
65 2.02871411 1.94282542 0.5108 0.8867 25.179153
66 2.05992509 1.88731613 0.5219 0.8844 25.334150
67 2.09113608 1.83180683 0.5331 0.882 25.491067
68 2.12234707 1.77629753 0.5444 0.8797 25.649940
69 2.15355805 1.72078823 0.5559 0.8771 25.810806
70 2.18476904 1.66527893 0.5675 0.8748 25.973702
71 2.21598002 1.60976964 0.5792 0.8726 26.138668
72 2.24719101 1.55426034 0.5911 0.8702 26.305742
73 2.278402 1.49875104 0.6032 0.8678 26.474966
74 2.30961298 1.44324174 0.6154 0.8653 26.646382
75 2.34082397 1.38773245 0.6278 0.8629 26.820031
 76 2.37203496 1.33222315 0.6404 0.8604 26.995959
77 2.40324594 1.27671385 0.6531 0.8579 27.174210
78 2.43445693 1.22120455 0.6659 0.8554 27.354830
79 2.46566792 1.16569525 0.6790 0.8529 27.537868
80 2.4968789 1.11018596 0.6922 0.8503 27.723372
81 2.52808989 1.05467666 0.7056 0.8478 27.911392
82 2.55930087 0.99916736 0.7192 0.8452 28.101979
83 2.59051186 0.94365806 0.7330 0.8426 28.295187
84 2.62172285 0.88814876 0.7470 0.84 28.491071
85 2.65293383 0.83263947 0.7611 0.8374 28.689685
86 2.68414482 0.77713017 0.7755 0.8347 28.891088
87 2.71535581 0.72162087 0.7900 0.832 29.095339
88 2.74656679 0.66611157 0.8048 0.8294 29.302498
89 2.77777778 0.61060228 0.8198 0.8267 29.512628
90 2.80898876 0.55509298 0.8350 0.8239 29.725794
91 2.84019975 0.49958368 0.8504 0.8212 29.942061
92 2.87141074 0.44407438 0.8661 0.8185 30.161499
93 2.90262172 0.38856508 0.8819 0.8157 30.384176
94 2.93383271 0.33305579 0.8981 0.8129 30.610166
95 2.9650437 0.27754649 0.9144 0.8101 30.839543
96 2.99625468 0.22203719 0.9310 0.8073 31.072384
97 3.02746567 0.16652789 0.9479 0.8045 31.308767
98 3.05867665 0.1110186 0.9650 0.8016 31.548774
99 3.08988764 0.0555093 0.9824 0.7987 31.792490
100 3.12109863 0 1.0000 0.7959 32.040000

45.000000000

y = -4.1166x2
40.000000000

35.000000000

30.000000000
30.000000000

25.000000000

y = 4.1166x2

20.000000000

15.000000000

y = -4.1166x
10.000000000

5.000000000

0.000000000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000
1)/Agua(2) T=15.56C

Volumen Molar (cm^3/mol) X2 dV/dX1 V_1 (cm^3/mol) V_2 (cm^3/mol)

18.033033033 1.00000 18.104 36.13703303 18.03303303
18.143191116 0.99435 18.15049601 36.19118438 18.04068837
18.256261712 0.98866 18.19740267 36.24722145 18.04981878
18.368606774 0.98291 18.24472544 36.30148542 18.05675998
18.482060888 0.97711 18.2924699 36.3557896 18.0633197
18.596639502 0.97126 18.34064169 36.41012766 18.06948596
18.708573867 0.96535 18.38924659 36.46070853 18.07146193
18.825418766 0.95940 18.43829047 36.51506415 18.07677368
18.939592233 0.95339 18.48777928 36.56558914 18.07780986
19.056830641 0.94732 18.53771913 36.6179959 18.08027677
19.173292150 0.94120 18.58811619 36.66841801 18.08030182
19.290914593 0.93502 18.63897679 36.71876813 18.07979135
19.409714475 0.92879 18.69030733 36.76903698 18.07872965
19.529708611 0.92249 18.74211438 36.81921493 18.07710054
19.650914130 0.91614 18.79440459 36.869292 18.0748874
19.771320866 0.90973 18.84718476 36.91723025 18.07004549
19.892942992 0.90326 18.9004618 36.96501537 18.06455357
20.017856711 0.89673 18.95424276 37.01469437 18.06045162
20.141978502 0.89014 19.00853483 37.06215379 18.05361897
20.267369675 0.88348 19.06334532 37.10942423 18.04607891
20.396155689 0.87676 19.1186817 37.15859966 18.03991795
20.524158186 0.86997 19.17455158 37.20546941 18.03091783
20.653487251 0.86312 19.2309627 37.25211044 18.02114774
20.784162631 0.85620 19.28792297 37.29850849 18.01058551
20.916204467 0.84922 19.34544045 37.34464881 17.99920836
21.051823910 0.84216 19.40352335 37.39270677 17.98918341
21.186677921 0.83504 19.46218006 37.43830256 17.97612251
21.325187209 0.82784 19.52141911 37.4858192 17.96440009
21.465183570 0.82057 19.58124922 37.53304976 17.95180053
21.606689869 0.81323 19.64167929 37.57997734 17.93829805
21.749729436 0.80582 19.70271838 37.62658448 17.92386609
21.892026493 0.79833 19.76437575 37.67055346 17.90617771
22.040504081 0.79077 19.82666084 37.71876428 17.89210344
22.190626563 0.78312 19.88958328 37.76663708 17.8770538
22.342419956 0.77540 19.9531529 37.81415244 17.86099954
22.498289828 0.76760 20.01737975 37.86366926 17.84628951
22.653525752 0.75972 20.08227406 37.91042913 17.82815506
22.815356173 0.75176 20.14784631 37.9616112 17.8137649
22.976610187 0.74371 20.21410716 38.00999391 17.79588675
23.142182562 0.73557 20.28106752 38.06041991 17.7793524
23.309683237 0.72736 20.34873852 38.11044561 17.76170708
23.479144066 0.71905 20.41713155 38.16004776 17.74291621
23.650597596 0.71065 20.48625821 38.2092023 17.72294408
23.824077081 0.70217 20.55613038 38.2578842 17.70175382
23.999616505 0.69359 20.62676018 38.30606754 17.67930736
24.177250604 0.68491 20.69816 38.35372538 17.65556538
24.357014879 0.67615 20.7703425 38.40082979 17.63048729
24.541600779 0.66728 20.84332062 38.4500069 17.60668628
24.728441127 0.65832 20.9171076 38.49862234 17.58151475
24.917574911 0.64926 20.99171694 38.5466459 17.55492896
25.109042003 0.64010 21.06716248 38.59404622 17.52688373
25.302883186 0.63083 21.14345836 38.6407907 17.49733235
25.501928190 0.62146 21.22061902 38.68963353 17.46901451
25.703487455 0.61198 21.29865927 38.73780731 17.43914805
25.907605844 0.60239 21.37759422 38.78527673 17.40768251
26.114329270 0.59269 21.45743935 38.83200505 17.37456571
26.326608607 0.58288 21.53821049 38.88085801 17.34264753
26.538714059 0.57296 21.61992385 38.92601805 17.3060942
26.756534039 0.56292 21.70259601 38.97328307 17.27068706
26.980213252 0.55276 21.78624394 39.02270449 17.23646055
27.206872415 0.54248 21.87088503 39.07130681 17.20042178
27.436567318 0.53207 21.95653706 39.11904657 17.1625095
27.669355117 0.52154 22.04321826 39.16587854 17.12266027
27.908425227 0.51089 22.13094729 39.2148865 17.08393921
28.150776808 0.50010 22.21974327 39.26296059 17.04321732
28.396473019 0.48919 22.30962577 39.31005144 17.00042567
28.645578600 0.47814 22.40061486 39.35610763 16.95549276
28.901436365 0.46695 22.49273111 39.404352 16.9116209
29.157599191 0.45562 22.58599558 39.44821358 16.86221799
29.427438053 0.44415 22.68042989 39.50093536 16.82050546
29.691017751 0.43253 22.77605619 39.54244995 16.76639376
29.954925435 0.42077 22.87289717 39.5792079 16.70631072
30.229536212 0.40886 22.97097614 39.62144311 16.65046697
30.508142958 0.39679 23.07031699 39.66230252 16.59198553
30.794385565 0.38457 23.17094423 39.70527511 16.53433087
31.081274034 0.37219 23.27288301 39.74321481 16.4703318
 31.376056519 0.35965 23.37615914 39.78320835 16.40704921
31.675265124 0.34694 23.4807991 39.82162082 16.34082172
31.978992815 0.33406 23.5868301 39.85837236 16.27154226
32.287335101 0.32101 23.69428005 39.89337958 16.19909953
32.604224107 0.30778 23.80317764 39.93038944 16.12721181
32.922141518 0.29437 23.91355231 39.96169185 16.04813954
33.248910451 0.28079 24.02543433 39.99491132 15.96947699
33.580806222 0.26701 24.13885478 40.02611741 15.88726263
33.917941232 0.25304 24.25384562 40.05520932 15.8013637
34.260431091 0.23888 24.37043968 40.0820817 15.71164202
34.612540936 0.22452 24.48867074 40.11077061 15.62209987
34.970358835 0.20996 24.6085735 40.13712659 15.52855309
35.329753696 0.19519 24.73018369 40.15677219 15.4265885
35.699320172 0.18020 24.85353802 40.17804648 15.32450846
36.079370971 0.16501 24.9786743 40.20099695 15.22232265
36.461350753 0.14959 25.10563141 40.21679298 15.11116157
36.849723479 0.13394 25.2344494 40.22961274 14.99516334
37.249204659 0.11806 25.36516947 40.24387491 14.87870544
37.655512678 0.10195 25.49783407 40.25498958 14.75715551
38.068810243 0.08559 25.63248691 40.2627991 14.6303122
38.489265107 0.06899 25.76917302 40.26713828 14.49796526
38.917050260 0.05214 25.90793882 40.26783397 14.35989515
39.357253354 0.03503 26.04883212 40.26961386 14.22078174
39.805295825 0.01765 26.19190223 40.26752496 14.07562273
40.256313607 0.00000 26.3372 40.25631361 13.91911361

45

4.1166x2 + 8.2332x + 36.182

40

35

30
 30

Volumen de mezcla
25
Volumen molar parcial A
4.1166x2 + 18.104x + 18.078 Volumen molar parcial 2
R = 1 Poly. (Volumen de mezcla)
Poly. (Volumen molar parcial A)
20
Poly. (Volumen molar parcial 2)

15

4.1166x2 + 2E-05x + 18.078

10

0
0.6000 0.7000 0.8000 0.9000 1.0000
0.0000
 Metanol(1)/Agua(2) T=20C

Densidad (g/ml) Volumen Molar (cm^3/mol) dV/dX1 V_1 (cm^3/mol) V_2 (cm^3/mol)
0.9982 18.04748547 18.297 36.34448547 18.04748547
0.9965 18.15775665 18.3434102 36.39757461 18.05416445
0.9948 18.2691079 18.3902302 36.45070764 18.06047741
0.9931 18.38155414 18.4374656 36.50387858 18.06641294
0.9914 18.49511056 18.4851219 36.55708123 18.07195929
0.9896 18.61167316 18.5332048 36.61218971 18.0789849
0.988 18.72561609 18.58172 36.66355572 18.08183574
0.9863 18.84259698 18.6306733 36.71681393 18.08614063
0.9847 18.9588261 18.6800708 36.76815108 18.08808033
0.9831 19.07621507 18.7299184 36.81945468 18.08953628
0.9815 19.1947803 18.7802224 36.87071645 18.09049403
0.9799 19.31453853 18.8309891 36.92192783 18.09093871
0.9784 19.43352034 18.8822249 36.97109347 18.08886857
0.9768 19.55570024 18.9339363 37.02216131 18.08822501
0.9754 19.67508995 18.98613 37.06911585 18.08298587
0.974 19.79567978 19.0388127 37.11591946 18.07710676
0.9725 19.9195351 19.0919914 37.16460891 18.07261753
0.971 20.04465714 19.1456731 37.21315608 18.06748303
0.9696 20.16898404 19.1998649 37.25946905 18.05960416
0.9681 20.29667896 19.2545742 37.3076801 18.05310591
0.9666 20.42569699 19.3098084 37.3557127 18.04590428
0.9651 20.55605772 19.3655751 37.40355398 18.03797883
0.9636 20.68778113 19.4218821 37.45119063 18.02930851
0.9622 20.8187237 19.4787372 37.49644499 18.01770775
0.9607 20.95321659 19.5361485 37.54361315 18.00746463
0.9592 21.08913427 19.5941242 37.59053365 17.99640945
0.9576 21.22871498 19.6526726 37.6394078 17.98673519
0.9562 21.36533084 19.7118023 37.68356984 17.97176755
0.9546 21.50790707 19.771522 37.73190613 17.96038417
0.9531 21.6497627 19.8318405 37.77769575 17.9458553
0.9515 21.79544616 19.8927669 37.82544616 17.9326793
0.9499 21.94272915 19.9543104 37.87288696 17.91857657
0.9483 22.09163675 20.0164805 37.91999998 17.90351949
0.9466 22.24454421 20.0792868 37.96911608 17.88982932
0.945 22.39679833 20.142739 38.01553645 17.87279742
0.9433 22.55314625 20.2068473 38.06396134 17.85711404
0.9416 22.71126626 20.2716218 38.11202089 17.84039908
0.9398 22.87362054 20.337073 38.16212778 17.82505479
0.9381 23.03539269 20.4032115 38.20941474 17.80620323
0.9363 23.20150248 20.4700483 38.25874925 17.788701
0.9345 23.36954759 20.5375943 38.30767522 17.7700809
0.9327 23.53956 20.6058611 38.35616935 17.75030827
0.9309 23.71157239 20.6748601 38.40420746 17.72934733
0.929 23.88818924 20.7446033 38.45433555 17.70973226
0.9272 24.06432643 20.8151027 38.50140937 17.68630667
0.9252 24.24780678 20.8863707 38.55318985 17.66681914
0.9234 24.42823422 20.9584199 38.59921722 17.64079728
0.9214 24.61617912 21.0312633 38.64999633 17.618733
0.9196 24.80104529 21.1049141 38.69486355 17.58994947
0.9176 24.99360936 21.1793857 38.74452606 17.56514038
0.9156 25.18857042 21.2546919 38.79361147 17.53891953
0.9135 25.38874957 21.330847 38.84486725 17.51402029
0.9114 25.59146755 21.4078652 38.89553835 17.48767317
0.9094 25.79393298 21.4857613 38.94275527 17.45699393
0.9073 26.00183609 21.5645506 38.99212779 17.42757723
0.9052 26.21241668 21.6442483 39.04081282 17.39656454
0.9032 26.4227975 21.7248703 39.08584768 17.36097737
0.901 26.64180562 21.8064328 39.13597137 17.32953857
0.8988 26.86370307 21.8889523 39.18535515 17.29640281
0.8968 27.0825022 21.9724458 39.22791777 17.25547193
0.8946 27.31027434 22.0569307 39.27563407 17.2187034
0.8924 27.54109929 22.1424246 39.32248425 17.18005968
0.8902 27.77503452 22.2289457 39.36842312 17.13947738
0.8879 28.01529384 22.3165128 39.41655853 17.10004572
0.8856 28.25885341 22.4051448 39.46375728 17.05861243
0.8834 28.50254995 22.4948614 39.50674324 17.01188183
0.8811 28.75286541 22.5856825 39.55188185 16.96619933
0.8787 29.0099771 22.6776287 39.59923013 16.92160143
0.8763 29.27072921 22.770721 39.64550805 16.87478705
0.8738 29.53857395 22.864981 39.69403948 16.82905852
0.8715 29.80344501 22.9604307 39.73462557 16.77419486
0.869 30.07901949 23.0570929 39.78080642 16.72371351
0.8665 30.3586179 23.1549908 39.82576099 16.67077017
0.8641 30.63877614 23.2541483 39.86587881 16.61173055
0.8616 30.92662701 23.3545897 39.90814141 16.55355169
0.8592 31.2151203 23.4563403 39.9453421 16.4890018
 0.8567 31.51156651 23.5594258 39.98462953 16.42520376
0.8542 31.81246775 23.6638725 40.02233837 16.35846584
0.8518 32.11414705 23.7697078 40.05461842 16.28491064
0.8494 32.42037686 23.8769594 40.0850628 16.20810343
0.8469 32.73511838 23.9856559 40.11744706 16.13179115
0.8446 33.04687613 24.0958268 40.14008351 16.0442567
0.842 33.37527211 24.2075023 40.17239507 15.9648928
0.8394 33.70882454 24.3207133 40.20269375 15.88198042
0.8366 34.05578608 24.4354919 40.2390185 15.80352663
0.834 34.40010191 24.5518707 40.26509305 15.71322237
0.8314 34.74992533 24.6698835 40.28884113 15.61895767
0.8286 35.11385295 24.7895649 40.31862129 15.52905642
0.8258 35.48377054 24.9109505 40.34607243 15.4351219
0.823 35.85981529 25.0340771 40.37107561 15.33699848
0.8202 36.24212844 25.1589824 40.39350629 15.23452391
0.8174 36.63085544 25.2857051 40.41323411 15.127529
0.8146 37.02614617 25.4142853 40.43012255 15.01583727
0.8118 37.42815501 25.544764 40.44402861 14.89926459
0.809 37.83704111 25.6771837 40.45480251 14.77761882
0.8062 38.25296847 25.8115879 40.46228731 14.65069938
0.8034 38.6761062 25.9480217 40.46631855 14.51829684
0.8005 39.11151397 26.0865313 40.47160911 14.38507779
0.7976 39.55463176 26.2271645 40.47323835 14.24607385
0.7948 40.00061623 26.3699705 40.46598787 14.09601739
0.7917 40.46987495 26.515 40.46987495 13.95487495

45

40

35

30
30

y = 4.109x2 + 18.297x + 18
25

20

15

10

0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000
 T 18
% peso 30
Vt (cm^3) 1000
 + 18.297x + 18.088

Volumen de mezcla
Poly. (Volumen de mezcla)

0.7000 0.8000 0.9000 1.0000