Exercise class 6

Part b and part c solution

b.
Since
)*
= & + ( )& (Can be proved by using Maxwell relation)
)+
Then
&
= + ( )&

dS is an exact differential, therefore we have following:
&
( )+ = { }
& &
& 2
( ) = ( 2 )&
+

Given C P and CV are constants,

)34 )5 *
= = 0; (From the above result)
)+ + )+ 5 &
)38 )5 &
( )+ = = 0 (Given)
)* )+ 5 :
Therefore, by doing simple integration, we get the following answer:
)*
= , where a and c are functions of V, and = ( )&
)+
Similarly,
)&
= , where b and d are functions of P, and = ( )*
)+

Combine P and V together, we have:

+ + = 2

From the (a),

= & + ( )
&

: A = =
& :
Therefore, we have
+ +
: A =

c.
Consider the derivative of internal energy U:
)B )B )*
( )& = & and ( ) + = ( )& =
)+ )& )+
Integrating them and compare the terms, we have the following expression:
= & + +

Consider the derivative of entropy S:

)H 34 )H )* ) 3I J3K + 3I J3K
( )& = and ( ) + = ( )& = =
)+ + )& )+ )+ & &LM &LM

Integrating them and compare the terms, we have the following expression:
= ln | 34 ( + ) 3I J34 |+constant