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Authors contributions
This work was carried out in collaboration between both authors. Author KHI designed the study,
performed the statistical analysis, wrote the protocol, and wrote the first draft of the manuscript.
Authors KHI and UIP managed the analyses of the study. Author UIP managed the literature
searches. Both authors read and approved the final manuscript.
Article Information
DOI: 10.9734/ACSJ/2015/20099
Editor(s):
(1) Francisco Jos Hernndez Fernndez , Department of Chemical and Environmental Engineering, Technical University of
Cartagena, Spain.
Reviewers:
(1) Merv Fingas, Spill Science, Edmonton, Alberta, Canada.
(2) Volodymyr Krasnoholovets, National Academy of Sciences, Kyiv, Ukraine.
Complete Peer review History: http://sciencedomain.org/review-history/11581
th
Received 11 July 2015
Original Research Article Accepted 4th August 2015
th
Published 28 September 2015
ABSTRACT
Aims: To determine and compare the equilibrium adsorption capacity and adsorption process of
crude oil onto ground chicken feathers and mixture of crude oil on water onto ground chicken
feathers with that of a conventional synthetic sorbent mat determined under the same experimental
condition as ground chicken feathers.
Study Design: The study was designed to use ground chicken feathers and a conventional
synthetic sorbent mat to mop crude oil and mixture of crude oil on water so as to assess the
effectiveness of ground chicken feathers as an oil spill sorbent by comparing its mopping profile
with that of a standard; a conventional synthetic sorbent mat.
Place and Duration of Study: Department of Chemistry Laboratory, Federal College of Education
(Technical), Asaba, Delta State, Nigeria, between September October, 2010.
Methodology: The adsorption of crude oil onto ground chicken feathers/synthetic sorbent mat was
carried out in two stages. The first stage of the study involves kinetic study of the adsorption
_____________________________________________________________________________________________________
process to determine the equilibrium adsorption capacity (qe) of crude oil onto ground chicken
feathers and the standard, and the equilibration time of the adsorption process. The second stage
of the study involves verification of the adsorption process using adsorption isotherms of Langmuir,
Freundlich, Elovich, Temkin and Dubinin-Radushkevich. To determine the mopping profile of crude
oil on water onto ground chickens and synthetic sorbent, the experiment was repeat with mixture of
crude oil on water. The experiment was carried out at room temperature; 28C.
Results: The equilibrium adsorption capacity of crude oil onto ground chicken feathers/synthetic
sorbent obtained from the kinetic study of the adsorption of crude oil onto ground chicken
feathers/synthetic sorbent are 13.60 g/g at equilibration time of 80 minutes and 11.44 g/g at 60
minutes respectively. The linearized form Ceqe versus Ce of Langmuir isotherm model fitted the
experimental data with a coefficient of determination r2 of 0.999 for both sorbents, indicating that
the Langmuir isotherm can describe the adsorption of crude oil onto ground chicken feathers sand
synthetic sorbent. The moderate (less than 10%) average percentage error value (APE %) of 4.6
and 4.8 obtained for ground chicken feathers and synthetic sorbent in the verification of the validity
of the Langmuir model in describing the experimental data, confirms the validity of the Langmuir
isotherm in describing the experimental data. The adsorption isotherm model shows that one
molecule of crude oil is adsorbed on a layer of ground chicken feathers/synthetic and there is no
interaction between the adsorbed molecules of crude oil. The intensity of adsorption of ground
chickens feather and the conventional synthetic sorbent used as the standard are both 1.00
indicating that ground chicken feathers compared well with the standard in terms of affinity for
crude oil and adsorption of crude oil. 14.70 g/g was obtained as the maximum equilibrium
adsorption capacity qm of the adsorption of crude oil onto ground chicken feathers, while 11.11 g/g
was obtained for the adsorption of crude oil onto conventional synthetic sorbent. The result
suggests that ground chicken feathers has larger surface area than the standard and is a better
sorbent than the standard. The dimensionless separation factor equilibrium parameter KR Of
0.0011 for both sorbents shows that the adsorption of crude oil onto ground chicken feathers and
synthetic sorbent are favourable. About 12.00 g/g and 9.00 g/g of the adsorbed oil can be
recovered from ground chicken feathers and conventional synthetic sorbent respectively. This
make ground chicken feathers a better sorbent when oil recovery is required. The amount of water
adsorbed together with crude oil on water was negligible, which means that both sorbents can be
used to mop crude oil spill on land and on water.
Conclusion: The result of the study shows that ground chicken feather adsorbed more crude oil
per unit mass than the conventional synthetic sorbent used as the standard in this study. Ground
chicken feathers are an efficient natural sorbent that can be used to mop crude oil spill on land and
water, and it is efficient for oil recovery.
Keywords: Equilibrium adsorption capacity; chicken feather; synthetic sorbent mat and crude oil.
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it produces methane, one of the major green a sorbate adsorbed onto a sorbent can be
house gases contributing to climate change [6]. obtained using kinetics and adsorption isotherms
In most developing countries, open dumping with [11]. The kinetics experiment is done as a
open burning is the norm [7]. Improperly function of time. Then by plotting amount
managed solid waste poses a risk to human adsorbed against time a graph is produced from
health and the environment. In addition, it may which the equilibrium adsorption capacity of the
result in safety hazards from fires or explosions. sorbent, equilibration time of the adsorption
However, through proper solid waste process and the rate of adsorption can be
management such as waste prevention, obtained. Adsorption isotherm is defined as a
recycling, composting, controlled burning, or land graphical representation showing the relationship
filling, these problems can be eliminated (6). between the amount adsorbed by a unit weight of
Recycling makes use of materials that otherwise adsorbent and the amount of adsorbate
would become waste by turning them into remaining in a test medium at equilibrium, and it
valuable resources. Recycling helps to reduce shows the distribution of adsorbable solute
green house gas emissions, in part, by diverting between the liquid and solid phases at various
waste from landfills. equilibrium concentrations [10,12]. The three
well-known isotherms are Freundlich, Langmuir
Chicken feathers are poultry waste and are and BET adsorption isotherms [13]. Adsorption
normally thrown out [8]. It is inexpensive, process is usually described through adsorption
abundant and readily available in all countries isotherms. Usually, to obtain experimental data
that eat poultry. There are over three billion to be fitted into an adsorption model, different
pounds of chicken feathers thrown out just in the initial concentrations of the sorbate and/ or
United States [8]. In Nigeria, chicken feather are different mass of the sorbent is used during the
not properly disposed. They constitute an experiment, so as to produce other values of
environmental menace. Feathers are processed equilibrium adsorption capacity (qe) and
to make animal feed, but, the use of feather is equilibrium concentration (Ce) at the end of the
considered a low grade substitute that could experiment [10].
cause disease in other animals. So they are
thrown out as waste instead, filling landfills and The aim of this study is to determine the efficacy
incinerators [8]. In the European Union, for of chicken feathers in the mopping of crude oil on
example, poultry feather meal has been banned land and water. This is done by comparing the
since 2001 [9]. As an organic waste, chicken adsorption of crude oil, and crude oil on water
feather may be capable of releasing methane onto chicken feathers, determined under the
into the atmosphere during biodegradation, when same experimental condition, with that of one of
buried in the landfill. Instead of allowing this to the conventional synthetic sorbent used in
happen, they could be recycled into more useful mopping oil spill in the oil industry. The result if
products. Again, the use of agricultural products favourable, can project the effectiveness of
as a source of raw materials for the chemical and chicken feathers as an oil spill sorbent mop on
materials industry is growing in importance and land and water. Thereby encouraging its use in
value. Chicken feather is a renewable material the production of oil spill sorbent and invariably
whose supply is reliable and none depleting. It help to solve the solid waste generated by
could serve as a source of raw materials for the chicken feathers and reduce the emission of
chemical industry in the production of oil spill methane gas in the environment.
sorbents.
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Petroleum Development Company, Port (sorbent and some sorbate) in the beaker was
Harcourt, Rivers State, Nigeria. passed through Whatman filter paper 185 mm
fitted onto a glass funnel. The glass funnel was
2.2 Sample Preparation inserted into the 2000 ml beaker containing the
previous decanted sorbate. At the end of the
The chicken feathers was thoroughly washed filtration, the weight of the 2000 ml beaker
with distilled water and detergent, rinsed several containing the unadsorbed oil (decanted and
times with copious amount of water and dried filtered oil) was weighed. The weight of the
under the sun for two weeks. The feathers were unadsorbed crude oil was obtained by difference
ground using a mechanical blender, but, the in weight. The weight of the unadsorbed oil was
blender could not blend it into particulate form, used as the final concentration of crude oil.
rather into a fluffy form. The standard which was
in form of a mat was cut into smaller dimension. The amount of crude oil adsorbed onto a unit
mass of chicken feathers/synthetic sorbent was
2.3 Analysis of Sample calculated from:
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q = Initial weight Final weight bowl. Crude oil is immiscible with water; hence it
Mass of sorbent floated on the water. Five grams of ground
chicken feathers/synthetic sorbent was weighed
Average of three (3) determinations was made and added into the crude oil on water. The
for the adsorption and recovery and the standard sorbent sorbate system was left for a contact
deviation calculated. time. The contact time was same as used in the
kinetic study in 2.3.1 above.
The experiment was conducted at room
temperature 29C. It was observed that the ground chicken
feathers/synthetic sorbent remained in the crude
oil (organic) layer. At the end of each contact
The amount of crude oil retained per unit mass of time, the crude oil layer containing the ground
the sorbents was obtained from the expression: chicken feathers/synthetic sorbent was carefully
decanted into another pre-weighed transparent
q = Quantity of oil adsorbed per unit mass of bowl. The remaining sorbate (crude oil)
sorbent Quantity of oil recovered per unit mass containing the sorbent, was carefully passed
of sorbent. through a filter paper fitted onto a glass funnel
which was placed inside the transparent bowl
2.3.3 Verification of adsorption process of containing the previous decanted crude oil. Small
crude oil onto ground chicken amounts of crude oil which formed the boundary
feathers/synthetic sorbent using layer between water and crude oil were not
adsorption isotherm separated from water during the filtration,
because water will be lost. These (crude oil) was
carefully removed using syringe and added to the
The adsorption of crude oil onto five (5) grams of crude oil in the transparent bowl.
chicken feather/synthetic sorbent mat, using five
different initial concentrations of crude oil; 0.5
dm3 (442 g), 0.75 dm3 (651 g), 1.00 dm3 (866 g), The separated crude oil and water were
3 3
1.25 dm (1110 g) and 1.5 dm (1320 g) was weighed, and their weight obtained by difference.
determined at this stage, using the same The experiment was conducted at room
procedure and experimental condition as in 2.3.1 temperature 29C. Two determinations were
above. The sorbate sorbent system was left to performed for each contact time and the average
contact for 2 hours (120 minutes) allowing and standard deviation calculated. The amount
additional time for equilibrium to be achieved. of crude oil adsorbed onto a unit mass of the
Triplicate determination was conducted for each sorbents at each contact time was calculated, the
initial concentration, and the average taken. graph plotted from which the equilibration time of
the adsorption process and the equilibrium
adsorption capacity (qe) were determined for
The experimental data (qe and Ce) obtained were
both materials.
fitted into Freundlich, Langmuir, Elovich, Temkin
and Dubinin-Radushkevich adsorption models.
2.4 Fourier Transform Infrared (FTIR)
2.3.4 Determination of adsorption and Spectroscopic Analysis of the
recovery of crude oil on water from Conventional Synthetic Sorbent Mat
ground chicken feathers and synthetic
sorbent mat To obtain the chemical composition of the
synthetic sorbent mat used in this study, as it
The experiment was repeated with crude oil on was not disclosed by the oil company it was
water so as to determine the behavior and obtained from, the functional groups present in
mopping ability of chicken feathers and synthetic the sorbent were determined by FTIR
sorbent when crude oil spill on water. Four (4) spectroscopy. The FTIR analysis was carried out
3 using SHIMADZU FTIR-8400S
dm of water was poured into a pre-weighed
transparent plastic bowl of 10 dm3 capacity and spectrophotometer with a NaCl cell. The sample
weighed. The weight of the water was obtained was ground into fine powder and spread
by difference in weight and recorded. Exactly 2 uniformly in between two NaCl based cells. The
3 cells were fixed into the machine and an incident
dm of crude oil whose initial weight had been
predetermined was added into the water in the ray of light passed through it. The FTIR
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Table 1. Amount of crude oil adsorbed onto ground chicken feathers (q), recovered from
ground chicken feathers and retained by ground chicken feathers
Amount of crude oil Amount of crude oil Amount of crude oil Contact time
adsorbed per unit mass recovered per unit mass retained per unit mass (Min)
(q) (g/g) (g/g) (g/g)
13.650.97 12.900.31 0.75 10
13.670.94 12.930.66 0.74 20
13.721.01 13.100.91 0.62 30
13.640.98 12.810.47 0.83 40
13.800.91 13.100.89 0.70 50
13.621.03 12.690.70 0.93 60
13.640.95 13.000.51 0.64 70
13.601.11 12.780.54 0.82 80
13.610.96 12.640.88 0.97 90
13.660.91 13.020.72 0.64 100
Table 2. Amount of crude oil adsorbed onto synthetic sorbent mat (q), recovered from
synthetic sorbent mat and retained by synthetic sorbent mat
Amount of crude oil Amount of crude oil Amount of crude oil Contact time
adsorbed per unit mass recovered per unit mass retained per unit (Min)
(q) (g/g) (g/g) mass (g/g)
11.480.50 9.880.69 1.60 10
11.450.65 9.550.55 1.90 20
11.460.61 9.610.98 1.85 30
11.450.23 9.650.46 1.80 40
11.450.11 9.600.33 1.85 50
11.440.27 9.570.39 1.87 60
11.460.78 9.661.04 1.80 70
11.470.30 9.650.72 1.82 80
11.450.42 9.580.94 1.87 90
11.440.30 9.640.87 1.80 100
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16
14
12
10
q (g/g) 8
feather
6
synthetic
4
2
0
0 20 40 60 80 100 120
Time(min)
Fig. 1. Amount of crude oil adsorbed onto ground chicken feathers and synthetic
sorbent mat per unit mass against time
The experimental data obtained using five free, all sorption sites are uniform i.e. constant
different initial concentrations of crude oil to heat of adsorption, one sorbate molecule reacts
verify the adsorption process are shown on with one active site, no interaction between
Tables 3 and 4. The adsorption isotherms sorbed species [10]. The Langmuir isotherm
applied to the experimental data to describe the relation is of a hyperbolic form, a plot of qe
adsorption process are Freundlich, Langmuir, versus Ce produces a non linear graph. It can be
Elovich, Temkin and Dubinin-Radushkevich linearized to five different forms, out of which the
adsorption models. The Freundlich equation can forms 1/qe = 1/bqm 1/ce +1/qm (plot 1/qe vs.1/Ce)
I/n
be written as qe = KF Ce [14]. KF is a constant and Ce/qe = 1/qmCe + 1/qmb (plot Ce/qe vs Ce) are
indicative of the relative adsorption capacity of the most frequently used by several researchers
the adsorbent (mg I-(I/n) L I/n g-I and n is a constant because of the minimized deviations from the
indicative of the intensity of the adsorption. The fitted equation resulting in the best error
Freundlich expression is an exponential equation distribution. Accordingly, a plot of Ce/qe against
and therefore, assumes that as the adsorbate Ce produces a linear graph with slope = 1/ qm
concentration increases, the concentration of and intercept 1/ Kaqm and a plot of 1/ qe versus
adsorbate on the adsorbent surface also 1/Ce gives a linear graph with slope =1/ Kaqm and
increases. The Freundlich isotherm can be intercept 1/ qm..
linearized by plotting Log qe against Log Ce or ln
qe against ln Ce. The Langmuir equation may be The equation defining the Elovich [16] model is
written as based on a kinetic principle assuming that the
adsorption sites increase exponentially with
qe = qmbCe adsorption, which implies a multilayer adsorption.
1 + bCe It is expressed by the equation:
Where qe is the amount of solute adsorbed per qe/qm = KECE exp (qe/qm)
unit weight of adsorbent at equilibrium (mg /g),
Ce the equilibrium concentration of the solute in where KE is the Elovich equilibrium constant (L
-1 -1
the bulk solution (mg L ), qm the maximum mg ) and qm is the Elovich maximum adsorption
adsorption capacity (mg/g), and b is the constant capacity (mg-1). If the adsorption obeys Elovich
related to the energy of adsorption and equation, Elovich maximum adsorption capacity
temperature, and affinity between the sorbent and Elovich constant can be calculated from the
and sorbate [10,15]. slopes and the intercepts of the linear plot
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Ijeoma and Prisca; ACSJ, 9(4): 1-19, 2015; Article no.ACSJ.20099
adsorbent-adsorbent interactions, and that the Where, BD is related to the free energy of
adsorption is characterized by a uniform sorption per mole of the sorbate as it migrates to
distribution of the binding energies, up to some the surface of the adsorbent from infinite
maximum binding energy. Temkin model is given distance in the solution and qD is the Dubinin-
by Radushkevich isotherm constant related to the
degree of sorbate sorption by the sorbent
qe = RT ln(ATCe) surface.
b
The linear form of equation is given as:
qe = RT ln AT +(RT/b)lnCe
b
ln qe = ln qD 2BDRTln(1+1/Ce)
B= RT/bT
The plot of ln qe against RT ln (1+Ce) yields
qe = BlnAT + BlnCe straight line. The values of qD and BD can be
calculated from the intercept and slope.
where
AT = Temkin isotherm equilibrium binding Tables 3 and 4 shows the experimental data
constant (L/q) obtained for the adsorption of crude oil onto
bT = Temkin isotherm constant chicken feathers and synthetic sorbent, while
R = universal gas constant (8.314J/mol) Table 5 shows the values used to plot the
T = Temperature at 298k adsorption models. Figs. 2 to 14 shows that the
B= Constant related to heat of sorption(J/mol) linearized form Ce /qe versus Ce of the Langmuir
adsorption isotherm produced the best fitted
From the linear plot qe against lnCe the constants isotherm for the adsorption of crude oil onto
can be determined from the slope and intercept. ground chicken feathers and the synthetic
sorbent. This shows that the adsorption obeys
The Dubinin-Radushkevich isotherm estimates the Langmuir model. This implies that the
the characteristics porosity of the sorbent and interaction of both sorbents with crude oil is
apparent energy of adsorption [18]. The model is monolayer adsorption, that is, one sorbate
represented as: molecule is adsorbed on a layer of adsorbent.
There is no interaction between adsorbed
qe = qD exp (-BD[RT ln(1+1/Ce)]2 molecules.
Table 3. Experimental Data obtained for the adsorption of crude oil onto ground chicken
feathers
Table 4. Experimental Data obtained for the adsorption of crude oil onto synthetic sorbent mat
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0.0725
0.072
0.0715
0.071
1/qe
0.0705
0.07
R = 0.2295
0.0695
0.069
0.0685
0 0.0005 0.001 0.0015 0.002 0.0025 0.003
1/Ce
Fig. 2. Langmuir isotherm 1/qe versus 1/Ce of the adsorption of crude oil onto
chicken feathers
100
90 R = 0.9994
80
70
60
Ce/qe
50
40
30
20
10
0
0 200 400 600 800 1000 1200 1400
Ce
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3.5
3
R = 0.1176
2.5
Log qe
2
1.5
1
0.5
0
1.138 1.14 1.142 1.144 1.146 1.148 1.15 1.152
Log Ce
Fig. 4. Freundlich isotherm Log qe versus Log Ce of the adsorption of crude oil
onto chicken feathers
2.665
2.66
2.655
2.65
2.645
ln qe
2.64
2.635
R = 0.1156
2.63
2.625
2.62
2.615
0 2 4 6 8
ln Ce
120
R = 0.9993
100
80
Ce/qe
60
40
20
0
0 200 400 600 800 1000 1200 1400
Ce
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0.088
0.087
0.086
0.085
1/qe 0.084
0.083 R = 0.4026
0.082
0.081
0 0.0005 0.001 0.0015 0.002 0.0025 0.003
1/Ce
Fig. 7. Langmuir isotherm 1/qe versus 1/Ce of the adsorption of crude oil
on synthetic sorbent mat
1.13
1.12
1.11
1.1
Log qe
1.09
R = 0.0295
1.08
1.07
1.06
1.05
0 0.5 1 1.5 2 2.5 3 3.5
Log Ce
2.58
2.56
2.54
2.52
R = 2E-05
ln qe
2.5
2.48
2.46
2.44
2.42
0 1 2 3 4 5 6 7 8
ln Ce
Fig. 9. Freundlich isotherm ln qe versus ln Ce of adsorption of crude oil onto synthetic sorbent
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0
-0.5 13.7 13.8 13.9 14 14.1 14.2 14.3 14.4 14.5
-1
-1.5
-2
ln qe/Ce
-2.5
-3
-3.5 R = 0.2152
-4
-4.5
-5
qe
0
-0.5 11.4 11.5 11.6 11.7 11.8 11.9 12 12.1 12.2
-1
-1.5
-2
ln qe/Ce
-2.5
-3
-3.5
-4 R = 0.0442
-4.5
-5
qe
Fig. 11. Elovich isotherm lnqe/Ce versus qe of adsorption of crude oil onto synthetic sorbent
15
14.8
14.6
14.4
qe
14.2
14
R = 0.4549
13.8
13.6
5.8 6 6.2 6.4 6.6 6.8 7
ln Ce
Fig. 12. Temkin isotherm qe versus lnCe of adsorption of crude oil onto ground
chicken feathers
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Fig. 13. Temkin isotherm qe versus lnCe of adsorption of crude oil onto synthetic sorbent mat
2.665
2.66
2.655
2.65 R = 0.241
2.645
ln qe
2.64
2.635
2.63
2.625
2.62
2.615
0 1 2 3 4 5 6 7
RT ln(1+1/Ce
2.5
2.49
2.48
2.47
ln qe
R = 0.0401
2.46
2.45
2.44
2.43
0 1 2 3 4 5 6 7
RT ln(1 + 1/Ce
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Sorbents can be compared by their respective (Table 6) shows that the Langmuir model can
maximum adsorption capacity qm and b values describe the equilibrium data.
obtained from the Langmuir equation [10]. The
maximum adsorption capacity qm is obtained The favourable nature of adsorption can be
from the isotherm model while qe is the expressed in terms of dimensionless separation
equilibrium adsorption capacity obtained from factor equilibrium parameter of Hall et al. [22]
experiment [19]. qm can be interpreted as the which is defined by the following relationship, KR
total number of binding sites that are available for = 1/1 + KaCo, where KR is a dimensionless
sorption, and qe as the number of binding sites separation factor, Co is initial concentration (mg
-1 -1
that are in fact occupied by the sorbate at the L ) and Ka is Langmuir constant (L mg ). The
concentration Ce [10]. The constant b and qm are values of KR indicates the type of isotherm to be
obtained from the slope and interception of the irreversible (KR = 0), favourable (0<KR <), linear
plot and are presented in Table 6. The b values (KR = 1) or unfavourable (KR >). The
for both chicken feathers and synthetic sorbent dimensionless separation factors calculated for
are 1.00. This implies that both sorbents have ground chicken feather and synthetic sorbent are
same affinity for crude oil. The qm value of 14.70 0.0011. KR values were less than 1 and greater
g/g for chicken feathers is higher than that of than zero indicating favourable adsorption.
synthetic sorbent, 11.11 g/g. This indicates that
The quality of sorbent material is judged not only
ground chicken feathers has more total number
according to how much sorbate it can attract, but
of binding sites than the synthetic sorbent, which
also on how much sorbate it can retain [10].
implies that, ground chicken feathers has a larger
Tables 1 and 2 shows the amount of crude oil
surface area and higher crude oil uptake/removal
recovered and retained by ground chicken
than the synthetic sorbent. The qm shows that
feathers and synthetic sorbent, the result shows
ground chicken feathers is a better sorbent than
that the synthetic sorbent mat retains more of the
the conventional synthetic sorbent mat. The
adsorbed crude oil than ground chicken feathers.
value of the maximum adsorption capacity is
In the light of this, ground chicken feathers with a
higher than the experimental equilibrium
higher crude oil uptake are better than the
adsorption capacity for ground chicken feathers,
synthetic sorbent mat, however, in terms of
while it is lower than the experimental value for
retainability, the synthetic sorbent mat is better.
synthetic sorbent. It implies that the linearized
Tables 1 and 2 and Fig. 1 shows that, substantial
form Ce/qe versus Ce of the Langmuir isotherm
amount of the adsorbed/absorbed crude oil;
provided a better fit to the experimental data for
about 12.00 g and 9.00 g was recovered from
ground chicken feathers than synthetic sorbent.
both chicken feathers and the synthetic sorbent
2 respectively, but more of crude oil was recovered
The coefficient of determination r between the from chicken feathers. Since much crude oil was
experimental data and isotherms was determined recovered from both sorbents, it means that the
using solver add-in with Microsofts spreadsheet, sorbate are attracted and held to the sorbent
Microsoft Excel [20,21]. The results are surfaces, including internal fibre walls by physical
2
presented in Table 6. The r value shows good bonds that becomes easily broken on pressing.
correlation between experimental data and the This also suggest that the adsorption of crude oil
linearized form Ce/qe versus Ce of the Langmuir on the surface is greater than its absorption in
isotherm. This indicates that there is strong the void of chicken feathers than in the void of
positive evidence that the adsorption process synthetic sorbent mat, because, the adsorbed
follows the Langmuir isotherm. In order to check sorbates on the surfaces are easily desorbed
the validity of the Langmuir model, it is than the sorbates absorbed within the voids. This
interesting and essential to recalculate the phenomenon explains why more crude oil was
adsorbed amounts using the equilibrium retained by the synthetic sorbent mat than
concentration values and Langmuir parameter chicken feathers.
qm. to obtain the average percentage errors
(APE) according to the equation: Fig. 17 shows the ftir spectrum of the synthetic
sorbent mat. The prominent peaks are 829.42
APE (%) = Ni =1(qe),exp (qe),cal / (qe ) x 100 cm-1 (s) c-h of alkene, 983.73 cm-1 (s) c-h of
-1
alkene, 1159.26 cm , (s) c-c of alkane, 1369.50
N cm-1 (s) c-h of alkane , 1453.41 cm-1(s) c-h of
alkane, 2925.15 cm-1(s) c-h of alkane. This
The moderately low value of APE obtained for suggest that the synthetic sorbent mat is a
ground chicken feathers and synthetic sorbent polyhydrocarbon.
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Ijeoma and Prisca; ACSJ, 9(4): 1-19, 2015; Article no.ACSJ.20099
Table 6A. Parameters of Langmuir isotherm for the adsorption of crude oil onto ground
chicken feathers and synthetic sorbent mat
14
12
Amount Recovered(g/g)
10
8
6 feather
4 synthetic
2
0
0 20 40 60 80 100 120
Time(min)
Fig. 16. Amount of crude oil recovered from ground chicken feathers and
synthetic sorbent mat per unit mass against time
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Ijeoma and Prisca; ACSJ, 9(4): 1-19, 2015; Article no.ACSJ.20099
Chicken feathers and all feathers are mainly microscope shows that there are lot of empty
composed of 91% protein (keratin) [23]. Keratins space in quill, shaft, rami and barbules of feather
are long chains of amino acids. Based on the [27]. The large surface area makes it possible for
side chain of an amino acid, it can be classified the trapping, entanglement and occlusion of
as hydrophobic, polar or charged. The side crude oil within the feather void. Basically
chains of the hydrophobic amino acids are chicken feathers and the synthetic sorbent have
nonpolar; mainly hydrocarbon. The polar amino similar features, enabling them to sorb much
acids side chains are hydrocarbons containing crude oil.
atom(s) that can form hydrogen bond. The side
chain of the charged amino acids contains Another quality attributed to an ideal sorbent is
hydrocarbons carrying negative or positive that it should be oleophilic (oil attracting) and
charges. Sorption results from a variety of hydrophobic (water repelling) [5]. Tables 6 and 7
different types of attractive forces between the shows that the amount of crude oil on water
sorbate and sorbent [24,25]. Organic sorbates adsorbed, recovered and retained by ground
chemically bond to the sorbent, if the sorbate and chicken feathers and synthetic sorbent mat
sorbent have mutually reactive moieties. Also, compares closely with that obtained with the
the extent of intermolecular attraction depends experiment involving crude oil only. The
on molecular chain length and on surface area. equilibrium adsorption capacity of crude oil on
water for ground chicken feathers and synthetic
The synthetic sorbent mat and crude oil are sorbent are 13.10 g/g at 90 minutes equilibration
composed mainly of hydrocarbons, in order time and 10.86 g/g at 80 minutes respectively.
words they have mutual reactive moieties, During the experiment, the difference in volume
attracting each other by Van der Waal forces, between the initial volume of water added to
London forces and other dispersion forces. This transparent bowl, and final volume of water after
explains why the much crude oil 3
experiment are 0.06 dm and 0.04 dm for
3
adsorption/absorption by the synthetic sorbent. synthetic sorbent and ground chicken feathers
The amino acid content of feather is highly respectively. This suggests the amount of water
hydrophobic; containing side chains that are sorbed by both sorbents is negligible. This is not
mainly hydrocarbon [26]. This hydrocarbon side surprising because the amino acid content of
chains accounts for the intermolecular bonds feather is hydrophobic [23,26]. The synthetic
formed between chicken feathers and crude oil, sorbent mat been a polyhydrocarbon is also
leading to the sorption of the crude oil on chicken hydrophobic. Therefore both sorbents can be
feathers. Also, the conformation of feather conveniently used in mopping crude oil on water.
makes it have large surface area, a look under a
Fig. 18. Amount of crude oil on water adsorbed onto unit mass of ground chicken feathers
and synthetic sorbent mat against time
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Ijeoma and Prisca; ACSJ, 9(4): 1-19, 2015; Article no.ACSJ.20099
Table 6B. Amount of crude oil on water adsorbed onto ground chicken feathers (q), recovered
from chicken feather and retained by chicken feather
Amount of crude oil Amount of crude oil Amount of crude oil Contact time
adsorbed (q) (g/g) recovered (g/g) retained (g/g) (Min)
13.010.98 12.280.62 0.73 10
13.080.13 12.161.06 0.92 20
13.110.57 12.130.86 0.98 30
13.090.42 12.070.11 1.02 40
13.100.73 12.340.02 0.76 50
13.090.94 12.310.34 0.78 60
13.071.14 12.161.04 0.91 70
13.130.23 12.240.32 0.89 80
13.100.21 12.230.22 0.87 90
13.061.43 12.272.32. 0.79 100
Table 7. Amount of crude oil on water adsorbed onto synthetic sorbent mat (q), recovered from
synthetic sorbent mat and retained by synthetic sorbent mat
Amount of crude oil Amount of crude oil Amount of crude oil Contact time
adsorbed (q) (g/g) recovered (g/g) retained (g/g) (Min)
10.980.13 9.180.21 1.80 10
11.010.45 9.200.31 1.81 20
10.960.51 9.130.32 1.83 30
11.000.45 9.200.64 1.80 40
10.940.42 9.070.72 1.87 50
10.960.37 9.100.01 1.86 60
10.970.75 9.070.33 1.90 70
10.860.60 9.040.41 1.82 80
10.900.43 9.040.10 1.86 90
10.950.21 9.071.43 1.88 100
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Ijeoma and Prisca; ACSJ, 9(4): 1-19, 2015; Article no.ACSJ.20099
oil onto ground chicken feathers and synthetic 8. Putting waste materials to work: Plastic
sorbent is favourable. from chicken feathers.
Available:http://www.helium.com/items/216
The amount of water adsorbed together with 3233-putting-waste-materials-to-work-
crude oil on water is negligible which means that plastics-from-chicken-feathers (Accessed
both sorbents; ground chicken feathers and 15 May 2014)
standard can be used in mopping of crude oil 9. European Parliament. Enjoy your meal.
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European Parliament in Action Highlights.
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agricultural by product-based powdered
Authors have declared that no competing activated carbons in a geosmin-water
interests exist. system. Bioresource Technology. 2002;
85:131-135.
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