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REACTION MECHANISM

Contents
Topic Page No.

Theory 01 - 10

Exercise - 1 11 - 19

Exercise - 2 20 - 28

Exercise - 3 29 - 33

Exercise - 4 34 - 35

Answer Key 36 - 40

Syllabus
Organic Reagents, Alkyl halides : Nucleophilic substitution reactions, elimination reactions,
Alcohols : dehydration, reaction with sodium, phosphorus halides, ZnCl2/concentrated HCl,
Ethers : Preparation by W illiamson s Synthesis; Nucleophilic substitution reactions.

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REACTION MECHANISM
(Alkyl halides, Alcohols & Ethers)
KEY CONCEPTS

Types of solvents

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Polar protic solvent Polar aprotic solvent

Capable of H-bonding Incapable of H-bonding

even thought polar protic solvents are not the best SN2 and E2, these reactions are often run in these
solvents because nucleophiles and bases are often easily prepared in these solvents.

ETOOS ACADEMY Pvt. Ltd

F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14 -233303 REACTION MECHANISM # 1

Solvents Non Polar Polar Protic Aprotic

1. H2 O ! !

2. CH3OH ! !

3. CH3CH2OH ! !

4. HCOOH ! !

5. CH3COOH ! !

6. NH3 ! !

7. ! !

8. ! !DMSODimethyl sulphoxide

9. ! !DMF Dimethyl formamide

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9. ! !DMF Dimethyl formamide

10. ! !DMA Dimethyl acetamide

11. ! " !

12. ! " !

13. CCCCCC ! " !

ETOOS ACADEMY Pvt. Ltd

F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14 -233303 REACTION MECHANISM # 2

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