EDT 04

01.Kircchoffs first law is based on law of 06. In meter bridge the wire used was
conservation of (A) uniform wire of any length and it was divided
(A) electrons (B) charges Lx
(C) energy (D) momentum into 200 equal parts even now X = R
02. A resistance is measured by meter bridge 100 L x
shows value as R and by multi meter the value is will be valid.
R then (B) uniform wire of one meter then only the
(A) R > R due to resistance of galvanometer Lx
(B) R < R due to coil resistance of galvanometer formula X = R will be valid
(C) R > R due digital nature of multi meter 100 L x
(D) R > R due to internal resistance of cell
03.In adjoining figure the arms ____ and ____
are called as conjugate arms. (C) any wire of one meter then only the formula
(A)AB and CD Lx
X = R will be valid
(B) AC and BD
100 L x
(C)AD and BC
(D) DC and AB
(D) any wire of any length even then the formula
04. While performing the
meter bridge experiment Lx
X = R will be valid
it was observed that null 100 L x
point is obtained at 40cm 07. A voltmeter of resistance 100 was
when the resistances of connected to terminals of cell with internal
left gap and right gap are resistance 20 and e.m.f. 2V. then the reading
interchanged it was found that the null point is on scale of voltmeter will be
at 58cm this will indicate (A) 2V
(A) there is a contact resistance (B) 1.7V
(B) wire is non uniform (C) 2.2V
(C) end points of wire are not at zero and 100cm (D) zero as voltmeter never measures e.m.f.
(D) A or B 08. The expression for internal resistance of a
05. Oke sir told students to measure the cell according to standard notation is
resistance of galvanometer using whetstone (A) R(L1 L2)/L2) (B) R(L1 + L2)/L1)
meter bridge. Chintan used null deflection (C) R(L1 + L2)/L2) (D) R(L1 L2)/(L1 +
method and found answer as 2 when Shruti did L 2)
the experiment using balance point she will get 09. The resistance along every
the answer as branch is 3 then resistance
(A) 2 as both names represent same method across AB is ----ohm.
(B) more than 2 as Shruti was using two (A)12/5 (B)5/12
galvanometers (C)18 (D)36
(C) less than 2 as Shruti is using one 10. In metallic conductor, the
galvanometer motion of free electrons in the absence of
(D) 2 even if shruti is using one galvanometer electric field is
(A) random (B) unidirectional
(C) bi-directional (D) circular
11.The potential difference across the terminals 19.In a balanced meter bridge, the segment of
of the cell in open circuit is called as wire opposite to a resistance of 70 is 70 cm.
(A) current (B) pot. Diff. of cell the unknown resistance is
(C) emf of cell (D) resistance (A) 30 (B) 60 (C) 90 (D)
12.In S.I. system, unit of electromotive force of 15
a cell is 20.A meter bridge is balanced by putting 20
(A) newton (B) dyne resistance in the left gap and 40 in the right
(C) volt (D) ampere gap. If 40 resistance is now shunted with 40
13.The mathematical equation of Kirchhoffs resistance. The shift in the null point towards
current law is right is nearly
(A) I =0 (B) IR = 0 (A) 16.67 cm (B) 50 cm
(C) E + IR = 0 (D) E = 0 (C) 25 cm (D) 70.67 cm
14.Kirchhoffs second law is related to the law 21.With resistance P and Q in the left and the
of conservation of right gap respectively of a meter bridge the null
(A) mass (B) momentum point divides the wire in the ratio 3 : 4, when P
(C) energy (D) all of these and Q are increased by 20 each, the null point
15.Sign conventions used to apply Kirchhoffs divides the wire in the ratio 5 : 6 the value of P
current law are and Q are
(A) entering and leaving currents are positive (A) 30 , 40 (B) 20, 40
(B) entering and leaving currents are negative (C) 30, 80 (D) 20, 20
(C) entering currents are positive and leaving 22.In a potentiometer, potential difference
currents are negative across the potentiometer wire is directly
(D) all of these proportional to its
16. The Wheatstones bridge is most sensitive (A) length (B) area
when the arm ratio is equal to (C) resistance (D) all of these
(A) 0 (B) 1 (C) 10 (D) 23.If the length of potentiometer wire is
infinity increased, then the accuracy in the
17.Four resistances 10, 10, 10 and 15 are determination of null point
connected so as to form Whetstones bridge. The (A) decreases
resistance connected across 15 resistance to (B) increases
balance the bridge is (C) remains unaffected
(A) 10 (B) 20 (D) increases up to 1 meter then decreases
(C) 30 (D) 40 24.The best instrument for the accurate
18. In adjoining figure, the key was open and measurement of the emf of a cell is
balancing length was L1 the key was closed and (A) Voltmeter (B) ammeter
balancing length was L2 then the internal (C) potentiometer (D) Wheatstones bridge
resistance of cell E1 will be given by 25.With a potentiometer null points were
(A) This circuit will give internal resistance of E2 obtained at 140 cm and 180 cm with cell of emf
not of E1 1.1V and one of unknown emf respectively. The
L1 unknown emf is
(B) R(1- ) E2 (A) 0.1 V (B) 1.21V
L2 (C) 1.414 V (D) 1.8 V
L1 26.The potential gradient along the length of a
(C) R( -1) E1 uniform wire is 5 V/m. there are two points on
L2 G the same wire at a distance of 20 cm and 40 cm
L R from initial end of the wire. The potential
(D) R( 2 -1)
L1 difference between these points is
(A) 1 V (B) 2V (C) 3V (D) 4V
27.In a potentiometer experiment the balancing 32.A meter bridge is balanced by putting R
length is 8 m, when the two cells E1 and E2 are resistance in the left gap and 3R in the right
joined in series. When the two cells are gap. If 1.5R resistance is shunted with 3R
connected in opposition the balancing length is 4 resistance, the shift in the null point towards
m. the ratio of the emf of two cells (E1/E2) is right is
(A) 1 : 2 (B) 2 : 1 (A) 20 cm (B) 50 cm
(C) 1 : 3 (D) 3 : 1 (C) 25 cm (D) 80 cm
28. Resistance across A, B if every resistance is 33.The value of I in given network is
of 15 is (A)7A 10A 1A
(A) 5 (B) 8A
6A
(B) 45V A B (C) 13A 3A
(C) 15 (D)17A I
(D)1 34.A potentiometer
29. In potentiometer experiment students were wire has a length
expected to compare unknown emf of cells. The of 4m and resistance 10 ohm. The wire is
base emf provided was of 3.6V. Teacher was connected to battery of emf 4V and internal
knowing that the unknown emfs are 1.5V and 2.5V resistance 2ohm. The potential per meter of
the students wire is
(A)used the cells, calculated balancing length and (A) 5V/m (B)1V/m
L1 (C) 5/6V/m (D) 0.8V/m
took ratio as to compare 35.Twelve wires each of resistance 12 ohm form
L2
a cubical skeleton then resistance between
(B)used combination method calculated balancing consecutive corners of same edge is
L1 L 2 (A)9ohm (B)10ohm
lengths and used to compare
L1 L 2 (C) 7 ohm (D) 120ohm
(C)potentiometer can not compare emf it is done 36.Every resistance is of 10 ohm then resistance
by meter bridge across A and D is
((D) either A or B A C

30.In the diagram below each horizontal wire is B D

of resistance of 12 . The total resistance (A) 30 ohm
between A and B is (B) 50 ohm
(A) 23 (C) 110/4 ohm
A B (D) 70/3 ohm
(B) 24
(C) 8 37.A cell of emf 10V and internal resistance r is
connected to resistance R. A current of (2/3)A
(D) 5
flows through it when pd across it is (20/3)V
31.In adjoining diagram the current in resistance
then internal resistance of the cell is
of 4ohm is
(A) 10ohm (B) 5 ohm
2
(C) (5/3) ohm (D) (2/3)ohm
3 2
38.Twelve wires each of resistance 12 ohm form
9V a cubical skeleton then resistance between
8 8 4 opposite corners of same face is
(A) 9ohm (B)10ohm
2 2 2
(C) 7 ohm (D) 120ohm

(A)2A (B)0.2A (C) 0.25A (D)1A

39.The ratio of resistance of two wires of same 47.If every line represents resistance of one ohm
material one is of length 15m and weigh 0.06kg each then effective resistance when the source is
other is 20m and weigh 0.04kg is connected across points A and
(A) 8:3 (B) 3:4 B is B
(C) 3:8 (D)5:7 (A)5/6 ohm
40.If R is external resistance of a circuit and V is (B) 7/12 ohm
emf then keeping current same if the external (C)4/3 ohm A
resistance is doubled means the V is (D) 2/5 ohm
(A) 2V (B) V/2 48.Two diametrically
(C) less than 2V (D) more than 2V opposite points of an uniform metal ring are
41.To determine the resistance of galvanometer connected to the two terminals of the left gap
by using meter bridge a method was developed of a metre bridge. In the right gap a resistance
using single galvanometer this method is known of 10 ohms is introduced. If the null point is
as obtained at a distance of 0.60 m from left end,
(A) method of equal deflection find the resistance R of the complete metal ring.
(B) Kelvins method (A) 60 (B)50 (C)40 (D)10
(C) Voltas method 49.The loop theorem was based on
(D) A and B both (A) law of conservation of charge
42.The emf of a cell is balanced by the length of (B) Meldes law of loops
1.812 m of a potentiometer wire, in the (C) loops of potentiometer
potentiometer experiment. When a resistor of 5 (D) law of conservation of energy
is connected across the cell, the balancing 50.The Instrument designed by Charles
length is found to be 1.51 m. Find the internal Whetstone to measure resistance was errorless
resistance of the cell. because
(A)1 (B)3 (C) 2 (D)4 (A) it was of one meter length
43.A potentiometer wire is supplied a constant (B) no motion of arm was there
voltage of 3V. A cell of emf 1.08 V is balanced (C)the internal resistance of cell was ineffective
by the voltage drop across 216 cm of the wire. (D)it was balanced
Find the total length of the potentiometer wire.
(A)2m (B)4m (C)6m (D)8m 51.By using chlorobenzene, phenol is prepared
44.A cell of emf E is connected to external by_____.
resistance R and produces PD of V the internal (A) Dows process (B) Raschig process
resistance of cell is (C) Both (A) and (B) (D) None of these
(A) R(E-V)/V (B) (E-V)R/E 52. An unknown organic compound on treatment
(C) VR/(E-V) (D)ER/(E-V) with
45.How many cells of emf 1.5V and internal PCC gives a substance,
which reduces Tollens reagent. The compound is:
resistance 0.5 must be connected in series
(A) CH3CHOH-CH2CH3.
with 20 resistance to give 0.6A current in (B) CH3CH2CHOHCH3.
circuit (C) CH3CH2CH2CH2OH.
(A)10 (B)8 (C)4 (D)2 (D) (CH3)3C-OH
46.The potential gradient along the length of a 53. 2,4,6 trinitrophenol is also called
uniform wire is 5 V/m. there are two points on (A)Anisole (B)Chloropicrin
the same wire at a distance of 20 cm and 40 cm (C)Picric acid (D)Cresol
from initial end of the wire. The potential 54. The first crown ether synthesized __
difference between these points is (A) 15-crown-5 (B) 12-crown-6
(A) 1 V (B) 2V (C) 3V (D) 4V (C) 18-crown-6 (D)8-crown-18
55. Carbolic acid and carbinol are 61. Conversion of phenol to salicylic acid and
(A)HCOOH,CH3OCH3 (B)C2H5OH, COOH salicyaldehyde, these name reactions are
COOH
______respectively.
(A)Reimer-Tiemann reaction and Kolbe reaction
(C)H2CO3 and glycol (D)Phenol and CH3OH
COOH (B)Kolbe reaction and Reimer-Tiemann reaction
(C)both are Reimer-Tiemann
56. Product of following reaction? (D)both are Kolbe reaction.
O 62. Correct decreasing order of b.p. of alcohols is
(A)propanol>ethanol>methanol
(B) methanol>ethanol>propanol
+ MgBr dry ether
(C) methanol>propanol>ethanol
H 3O (D) none
OH
63. Bayers reagent and ethene gives__
(A)ethanol (B)ethylene glycol
OH
(C)ethane (D)Two molecules of
methanol
(A) (B) 64.
HO
O O
OH

(I) (II)

(B) (D) (I)and (II) are;

57. Maximum number of active hydrogen(s) are (A) metamers (B)tautomers
present in__ (C) chain isomers (D) both (A) and (C)
(A)ethanoic acid (B)ethyl alcohol 65. Epoxide are
(B)ethylene glycol (D)glycerol (A)cyclic ethers (B)aryl-alkyl ethers
58. Dehydrohalogenation is the -------- type of (C)hydroxy ethers (D) they are not ether
reaction. 66. The ether
(A) Dehydration (B) Elimination
(C) Substitution (D) Any of these
59. In cresols, along with hydroxy group, ____ when reacted with cold HI gives
group is present
(A) Ethyl (B) Methyl (C) Cr (D) Cl

60. Dehydration is fastest in

(A) (B)
O
O
(A) mixture of 3 and 4
CH3 (B) mixture of 1 and 2
OH
(C) mixture of 2 and 3
OH (D) mixture of 1 and 4
(C) (D) 67. When excess ethyl alcohol is treated with
O O conc. H2SO4 at 413K gives__
OH (A)ethene (B)diethyl ether
(C)ethyl methyl ether (D)Both
OH
68.Wood spirit is__ 77. KMnO4 acts as oxidizing agent in__
(A)Mixture of ethanol +acetone (A)acidic medium (B)neutral medium
(B)phenol+ether (C)alkaline medium (D)all of the above
(C)Only methanol 78. Cumene is__
(D)ether+methanol (A) o-methyl phenol (B) p-cresol
69. The name of (CH3)2CH-O-CH2-CH2-CH3 is (C) iso-propyl benzene (D) phenyl n-propane
(A)isopropyl propyl ether 79. Which gas is evolved in fermentation reaction ?
(B)dipropyl ether (A)CH4 (B)H2
(C)di-isopropyl ether (C)CO2 (D) N2+CO2
(D)isopropyl-isopropyl ether 80.Williamsons synthesis is used for preparation
70. Which of following are called mercaptans ? of_
(A)thioethers (B)thioalcohols (A) both symmetrical and unsymmetrical ethers
(C)dithionic acids (D)thioaldehydes (B) Only symmetrical ethers
71. Ethers are treated with excess of conc. (C) Only unsymmetrical ethers
hydrogen halide to give alky halides, the order of (D) alcohol + ether
reactivity of hydrogen halides is_____ 81. The compound which gives the most stable
(A)HI>HBr>HCl (B) HCl >HBr> HI Carbonium ion on dehydration is
(C)HBr>HI>HCl (D)HI<HBr<HCl (A) CH3 C H CH2OH
72. LiAlH4 converts acetic acid into |
CH3
(A)Methane (B)acetaldehyde
CH3
(C)ethanal (D)ethanol |
73. Grignard reagent reacts separately with A,B,C (B) CH 3 C OH
Which on acid hydrolysis give 1o, 2o and 3o alcohol
|
CH3
respectively. So A, B,C are
(A)Acetone, acetic acid, acetyl chloride (C) CH3 CH2 CH2 CH2OH
(B)Acetic anhydride, acetone, HCHO
(C)alkyl halide, HCHO, acetone (D) CH 3 CH CH 2 CH 3
(D)HCHO, CH3CHO, acetone |
74. The correct order of relative acidic strength of OH
the following compounds is
(A)phenol > o-nitrophenol > m-nitrophenol > p- 82. Phenol can be distinguished from alcohol
nitrophenol using
(B)p-nitrophenol > m-nitrophenol > o-nitrophenol > (A) Tollens reagent (B) Schiff's base
phenol (C) Neutral FeCl3 (D) HCl
(C)p-nitrophenol >o-nitrophenol >m-nitrophenol > 83. Boiling point of alcohols are __than
phenol thioalcohols
(D)o-nitrophenol > m-nitrophenol >p-nitrophenol > (A)same (B)lower (C)higher (D)none
phenol 84. When an alcohol is oxidized, it converts into__
75. Sodium benzene sulphonate reacts with NaOH (A) Firstly aldehyde and then to carboxylic acid
and Product on acid hydrolysis gives (B) Firstly ketone and then to carboxylic acid
(A) ethanol (B) Diethyl ether (C) Firstly aldehyde with same number of C-atoms
(C)phenol (D) Diphenyl ether and then to carboxylic acid containing one C-atom
76. CH3Cl reacts with___giving methyl t-butyl less
ether. (D) The nature of products formed depends upon
(A) (C2 H5)3CONa (B) (CH3)3C-ONa the nature of original alcohol used and nature of
CH3 oxidizing agent used.
(C) (D) all correct
C2H5-C-ONa
CH3
85. Reaction of phenol with chloroform/sodium 94. Ethoxy benzene on nitration gives which of the
hydroxide to give o-hydroxy benzaldehyde involves following__as main product.
the formation of (A)4-nitroethoxy benzene(B)3-nitroethoxy benzene
(a)dichlorocarbene (b) trichlorocarbene (C)2-nitroethoxy benzene (D)nitrobenzene
(c) chlorine atoms (d) chlorine molecules 95. Chemically ethers are__
86.Phenol+benzenediazonium chloride (A)Condensation product of acid and alcohol

NaOHsolution (B)Alkyl derivative of fatty acids
dye. This reaction is chemically__ (C)Mono alkyl derivative of water
(A)diazotization (B)diazocoupling (D) alkoxy derivative of alkanes
(C)polymerization (D) hydrolysis
96. Aldehydes and ketones react with Grignard
87. Which of the following is aromatic organic reagent to give alcohols. Which alcohol cannot be
hydroxyl compound? prepared by this method?
(A) Tyrosine (B) Carbohydrate (A) CH3OH
(C) Cyclohexanol (D) All of these (B) CH CH CH CH
3 2 3
88.
OH
Alcohol alkene (C) CH3 CH2 CH2 OH
Conc.H2SO4
CH3
initial step of this reaction is__
(A)Formation of water (D) CH3 C OH
(B)Formation of carbocation
CH3
(C)Formation of ester
(D)protonation of alcohol 97. Which of the following can be used to convert
89. Aromatic electrophilic substitution reaction of ethanol to ethanal without further oxidation to
phenol occurs at, ethanoic acid?
(A)ortho position (A) Cu/573 K (B) PDC
(B) para position (C) PCC (D) All of these
(C) meta position PCl
98. CH3 CH2 OH
5
X
(D)at both ortho and para positions KOHalc . (i)H SO
Y
2


4
Z .
90.Isopropyl alcohol(vapours) X, so here
Cu .300o c
(ii)H2O /
X is Z is :
(A)ethane (B)acetone (A) CH3 OH (B) CH3 CH2 - Cl
(C)ether (D)CH3CHO (C) CH2 = CH2 (D) CH3 CH2 OH
91. Phenol is oxidized by chromic acid to give__ 99. Phenol when distilled with Zn dust gives
(A) a diketone, hydroquinone (A) Phenyl zincate. (B) Carbolic acid.
(B) a diketone, benzoquinone (C) Benzene. (D) Toluene.
(C) 2-hydroxy benzoic acid 100. Which of the following is phloroglucinol?
(D)a mono ketone, benzoquinone
CH3 OH
92. Reaction of alcohol with .explains acidic (A) (B)
Nature of alcohol__
(A)PCl5 (B) Na OH
(C)HBr (D) SOCl2 OH
93. Identify X in the following reaction ,
OH OH
i)C2H5MgBr OH
X 3-ethylpentan-3-ol (C) (D)
ii)H+/H2O
(A)Butanone (B)Propanone OH HO OH
(C)Pentan-3-one (D) Pentan-2-one