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These differences result from the fact that palm is not a wax
but a fat and behaves as a fat. The behaviour of a fat is
different to that of a wax.
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The Fatty Acid Content or FAC is the ratio of the different carbon chains in the
material. For palm this is C12 to C20 although C16 and C18 are the major
components.
Palm waxes with similar MP and IV can have different FAC and so will behave
differently in a candle formulation. Consider 2 RBD palm stearines:
Both products have a similar IV and MP but have different FAC profiles. Product
B has a higher C16 content. What affect does this have on performance?
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# Is the FAC suitable for the intended application? A high C16 content will
result in excessive crystallization (foaming). This will limit the amount of palm
in the candle formulation.
SAMPLE A SAMPLE B
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The Solid Fat Content or SFC is the % of the fat that is solid at a given
temperature.
It is important to select a palm with the correct SFC for the intended application.
Consider 2 different RBD palm stearines.
Stearine 200 250 300 350 400 450 500 550 600
# Using a palm in a formulation with the wrong SFC can lead to problems
with sweating in jar candles
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POLYMORPHISM
Unlike paraffin wax which always cools to an orthorhombic crystal whatever the
conditions fats can cool into three different forms alpha, beta and beta prime.
These 3 crystal forms have different structures and where a mix of crystal forms
exists then surface imperfections can be seen.
SUPERCOOLING
Paraffin Palm
Liquid Liquid
1st transition
2nd transition
Solid Solid
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APPLICATIONS
Palm can be used as a replacement for paraffin in most candle applications. The
optimum palm paraffin ratio will depend on a number of factors but there are
some general guidelines
Type of candle Container candles can often use a higher palm content than
pillars and other free standing candles.
Size of candle As the size of the candle increases then the palm content of the
blend may decrease.
Production process A higher palm content is possible for moulding and filling
compared to pressing and extrusion.
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APPLICATIONS
Palm cannot be used as a paraffin wax replacement for certain candle types and
certain processes. They are not recommended for the following
Candle type Any special effect candle such as mottle, rustic, cracked where
the unique properties of paraffin are needed to create the effect.
Process Drawing and dipping which need to wax to be flexible and with
specific cooling characteristics.
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FORMULATION - Pillar
FORMULATION - Pillar
FORMULATION - Pillar
FORMULATION - Extrusion
Extruder Piston
Form Process as beads
Process as pre-blend. Do not feed
Blend
waxes into extruder separately
FORMULATION - Extrusion
Extruder Piston
Form Process as beads
Process as pre-blend. Do not feed
Blend
waxes into extruder separately
FORMULATION - Pressing
Press Piston
Form Process as beads
FORMULATION - Filling
FORMULATION - Filling
FORMULATION - Filling
Conclusions
Palm offers the candle maker an alternative to paraffin wax but the following
points must be taken into account:
Palm is not a wax but a fat and has different performance characteristics
compared to paraffin wax. These differences need to be taken into account when
working with palm especially process conditions. Ensure the right process
conditions for the type and amount of palm added.
Palm with the same apparent melt point and IV can behave very differently. Make
sure you know the source of the palm being used.
In most cases optimum results both product performance and process quality
come from using palm / paraffin blends. Work on the optimum blend for each
application.
For maximum candle performance the changes may also need to be made to the
wick, colour and fragrance when using palm in the formulation. Do not assume
that the same wick and colour combinations that work for 100% paraffin will work
in palm / paraffin blends.