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What is this topic about?
To keep it as simple as possible, (K.I.S.S.) this topic involves the study of:
1. POLYMERS FROM PETROCHEMICALS & BIOMASS
2. ALTERNATIVE FUELS - ETHANOL & THE ALKANOLS
3. REDOX CHEMISTRY & BATTERIES
4. RADIOACTIVITY & ITS USES
...all in the context of societys use of energy and materials
alcohols
about the
carbon chemistry
and the importance of petroleum as a fuel source.
and the most important member
This topic begins by taking this idea further. Petroleum not of this group
only provides fuels, but is a source of chemicals for making
plastics. ETHANOL C2H5OH
a possible candidate for
replacing petrol as a fuel.
Cells
&
Photo by
Batteries
Marcel Hol
Radioactivity
phenomenon of
Heat of
Combustion
Polymers Alternative Fuels.
from Petrochemicals Ethanol &
& the Alcohols Assessment of
Biomass Ethanol
as an
Alternative Fuel
REDOX
Chemistry Oxidation
& &
Radioactivity Batteries Reduction
&
its Uses Galvanic
Cells.
Structure
Isotopes
&
Chemistry
Y
that can be made from it.
It readily splits open
leaving a single C-C C
X
Its chemical versatility is due to the
bond, and creating 2
new bond positions for double C=C bond
other atoms/groups to
attach to the molecule
H C C H which is highly reactive
and allows many Addition Reactions
to occur.
H H
HSC Chemistry Topic 1
Copyright 2005-2007 keep it simple science
3 www.keepitsimplescience.com.au
TM
Emmaus Catholic College SL#802440
keep it simple science
Practical Work Before Shaking
Identifying Alkenes with Bromine
You may have done simple experiments to learn how an
alkene can be quickly and easily identified, and Hexene layer
differentiated from an alkane.
H H H H H Br Br H H H H
C C C C C C H + Br2 H C C C C C C H
H H H H H H H H H H H
H
Hexene Bromine 1,2-dibromohexane
Many of the important molecules in living cells are Low Density Polyethylene
polymers, for example: If the monomer ethylene is treated with
high pressure (over 1,000 atmospheres)
starch is a polymer of many glucose molecules. high temperature (300oC)
proteins are polymers of amino acids. an initiator chemical
DNA is a polymer of nucleotides, sugar and phosphate. addition polymerization occurs, with about 2,000
monomers joining to form each super-molecule of
Many common, widely used substances are manufactured polymer. In this case, the initiator chemical also causes the
polymers, including all the different plastics and synthetic polymer molecules to have side-branches.
fibres such as nylon.
These molecules cannot pack
Ethylene is the starting chemical (feedstock) in the together closely, so the plastic
manufacture of many polymers. is low-density, highly
flexible, soft and clear...
Addition Polymerization of Ethylene
Not only can ethylene carry out addition reactions with
bromine, water, etc., but many ethylene molecules can react
with each other.
The example above results in the polymer we call Nylon, When glucose molecules join together, each pair eliminates
widely used in fabrics and clothing. a water molecule... a condensation reaction. To make
cellulose, thousands of glucose molecules join into
interlocking chains.
Condensation Polymers
are formed when monomer molecules
join together
by eliminating a molecule of
WATER
Photo by Maciej Ciupa Conclusion: PHB grown in corn has potential, but is
unlikely to become widely used yet.
The reason for ethylenes great usefulness is the d)................. Polystyrene is made from the monomer af)..........................
carbon-carbon bond. This bond is highly e)........................... for which the correct systematic name is ag)...........................
and readily splits open allowing other atoms/groups to .................................. The side group on this molecule is
join onto the molecule. This is called an f)............................... the ring-shaped ah)................................... group. This
Reaction. increases the molecular mass so that the ai).............................
forces hold the polymer molecules even more strongly so
In the laboratory, compounds containing a double bond the plastic is aj)....................................... and ..............................
can be identified using a solution of g)...................................
If this is added to an alkene, the g)................................... will Polymers can also form by a ak)........................................
be h)............................................. because of an addition reaction. This occurs when 2 monomer molecules join
reaction. With an alkane, the colour may change and shift together by elimination of a al)..................................................
from one solvent to the other, but will not be h).................... Examples of condensation polymers are nylon,
am)........................................ and .................................... All
The yield of Ethylene from petroleum is greatly increased biological polymers, such as an)..................................... and
by the process of i)............................................ in which ............................................... are condensation polymers.
long-chain alkanes are broken into smaller fragments by
either j).................................. or ........................................ This One important biological polymer is ao).................................
increases the yield of valuable fuel fractions such as which is a polymer of ap)................................. and is found
k)....................................... and increases the yield of ethylene in large amounts in all plants, where it forms the cell
which is extracted from the l).......................... fraction. aq)................................ which strengthens and protects all
plant tissues. We already use cellulose for fabrics such as
The major use of ethylene is the manufacture of ar)................................... and ................................. and process
m)............................................... Thousands of ethylene it to make as)....................................... When the petroleum
monomers join together by n).................................. reactions supplies run out, cellulose has great potential to supply our
to form o)........................................................... If the reaction needs.
is carried out at high p).......................... and .............................
with an initiator chemical, the result is q)...................- Its monomer at)............................... can easily be turned into
density polyethylene. The long chain molecules have many the alcohol au).................................... which can be used as a
r).......................................... and cannot pack close together, fuel, or chemically converted to av).........................................
so the plastic is soft and s)........................................, ideal for to feed the plastics industry. Unfortunately, we have not yet
soft plastic bags and t)............................................... film. developed a simple, efficient and economical way to
convert cellulose to aw)................................... to begin the
If the reaction is carried out at lower pressure and process.
temperature with a u)................................................., the
polymer molecules lack branches and can v)........................... Research is also progressing in the use of engineered
................................... to form w)......................-density Biopolymers such as ax)...................... (abbreviation). This
polyethylene, used (for example) in crinckly x).................... polymer has properties similar to some petrochemical
.................................. from shops. plastics, but is made naturally by microbes such as the
bacterium ay)........................ ................................ (scientific
name). The Monsanto company has used az)..........................
................................ techniques to transfer the genes for
PHB into ba)................................. plants. After normal
growth and harvesting, PHB can be extracted from the
WHEN COMPLETED, WORKSHEETS waste leaves and stems of the crop.
BECOME SECTION SUMMARIES
Although this is very promising, it is unlikely to be used on
a large scale while cheaper petrochemicals are still available.
To get close to pure ethanol, the fermented liquor must be alkanol + oxygen carbon dioxide + water
distilled. In the making of brandy, whiskey, rum, etc, the
spirit is usually around 40% ethanol. Example: Combustion of Ethanol
Fractional distillation will yield a distillate which is about C2H5OH(g) + 3O2(g) 2CO2(g) + 3H2O(g)
95% ethanol, which is quite suitable as a fuel.
The only tricky part is balancing... be careful balancing the
The Industrial Process Today oxygen atoms, noting that there is already 1 oxygen atom
Due to the cheap availability of petrochemicals, most of on the left side in the alkanol molecule.
the ethanol used as an industrial solvent or for cleaning
(i.e. non-drinking purposes) is made from ethene by the Try the worksheet at the end of this section
addition reaction with water, and NOT from the
fermentation of sugar. Heat of Combustion of a Fuel
How much energy is actually released when a fuel burns?
The only industrial-scale use of fermentation to make
high-purity ethanol is in the sugar industry. A major waste All combustion reactions are exothermic, so the energy
product from sugar refining is molasses which contains a profile is
large amount of sugar. Rather than waste it, molasses is
used as the sugar source for yeast fermentation, and the Ea = Activation
fermented liquor is distilled for the ethanol. Ea Energy
Reactants
In Australia, the sugar industry is based in Queensland, and
Energy Content
Notes:
1. Since the definition is the heat given out, it follows that the
value is expressed as a positive quantity. You must remember that
combustion is exothermic, and technically it has a negative value,
for example when using an equation such as H = -mCT.
2. You learned previously that fuels generally burn only after being
vaporized, and that the water forms in the gas state, as shown in
the equation above. However, the definition demands that all
substances are in their standard states at SLC, so both ethanol
and water must be in the liquid state.
Read the So, the Molar Heat of Combustion ( Hc) of ethanol would be
labels the (positive) quantity of heat released when 1 mole of ethanol
(=46.1g) burns as follows: (note the states)
Mass of ethanol burnt = 0.80g Although the values that are typically obtained in a simple
school experiment are well below the accepted text
Mass of water in metal can = 100g values, the trends are the same: the Heat of combustion
of the alkanols increases steadily (on both per gram and per
Starting temperature of water = 16oC mole basis) with increasing molecule size.
Final temperature of water = 42oC
T = 26oC It is notable also, that ethanols Hc is much lower than the
typical value for the compounds found in petrol. This
Analysis of Results: means that ethanol, a candidate to replace petroleum fuels,
Heat absorbed by water in the calorimeter: is a much lower-energy fuel.
H = -mC T (C = Specific Heat Capacity of
= - 100 x 4.18 x 26 water = 4.18 J/oC/g) Ethanol as a Renewable Fuel
= - 10,868 J The use of ethanol as a fuel to eventually replace petrol, as
11 kJ of heat released. the petroleum supplies run out, has been proposed
This is the heat released for 0.80g of ethanol burnt. because:
Heat of Combustion per gram = 11/0.80 = 13.75 kJ/g the technology to make ethanol from the fermentation of
sugar (followed by distillation) is a well known and proven
MM(ethanol) = 46.1g process... we know it can be done.
-1
Molar Heat of Combustion = 13.75 x 46.1 630 kJmol . sugar for ethanol production can be harvested from
plants, so it is a renewable, and sustainable energy source.
Discussion:
The text book value of Hc (ethanol) = 1367 kJmol-1. when ethanol from plants is burnt, the carbon dioxide
Typically, in a school experiment, values of only about half, or released is exactly the same amount that was absorbed by
less, are obtained. Why?
the plants during photosynthesis to make the sugar.
Therefore, the use of plant-derived ethanol does not
The analysis of results assumes that all the heat released by the
burning fuel is absorbed by the water in the calorimeter can. contribute to the Greenhouse Effect.
However, this calorimeter is very primitive and inefficient. A lot
of (most of ?) the heat of the fuel can escape into the There is no doubt that ethanol can be considered as a
surroundings, and therefore does not get measured. renewable fuel.
The set-up can be improved by using a larger can, wind baffles, However, thats not the whole story...
insulation, etc., but will always give results well below text
values.
Assessment
Weighing up advantages and disadvantages, the following
conclusions seem realistic:
Mg Look carefully and you will see that the sulfate ions
Decreasing reactivity
2-
(SO4 ) have not changed at all... they are spectators and
Al can be left out, to form the net ionic equation:
Zn Cu2+(aq) + Zn(s) Zn2+(aq) + Cu(s)
Fe Now you can see what really happened; copper ions turned
into copper atoms, and zinc atoms turned into zinc ions.
Sn This can only happen if:
Pb each copper ion gains 2 electrons
Cu Cu2+(aq) + 2e- Cu(s)
Ag No reaction, Electrons
and each zinc atom loses 2 electrons transferred
Least or very slow
Active Au Zn(s) Zn2+(aq)+ 2e-
One of the best hands-on ways to see the Activity Series This is one of the most common and important
in action is to place a piece of metal into a solution general types of chemical reaction; when electrons are
containing the ions of a less-active metal. This experiment transferred from one chemical species to another.
is not actually specified by the syllabus, but hopefully you
have seen what happens. Loss of Electrons = OXIDATION
The zinc has dissolved, and Note that neither part can occur alone. To lose electrons,
displaced the copper ions from there must be another species to accept them, and to gain
solution. electrons, there must be another species to give them.
Metals lower down the Activity Series have a greater This forms a Galvanic Cell which is the basis of all our
tendency to be reduced (= gain electrons). Their atoms are electric cells and batteries.
less likely to react with acids or oxygen, and their ions are
more likely to be displaced from solution by more active Galvanic is
metals. named for one of
the pioneering
You should recall also, that less active metals are easier to scientists, the
Italian Luigi
extract from their ores, (or may even be found uncombined
Galvani who lived
in nature) while more active metals require more and more 200 years ago. At
energy to extract from their ores. Extracting any metal that time, electron
from its ore involves reducing the metals ions, so this idea transfer and REDOX chemistry was NOT understood.
links to that above.
Voltmeter
ele
w
flo
ct
ro
on
n
tr
re
flo
ec
wi
el
w
in
Salt Bridge
Zn Cu
Typical Anode Reaction Typical Cathode Reaction
+ve
+ve
example example
ve
ve
-v
-v
ANODE CATHODE
Half-c
cell where Half-c
cell where
OXIDATION REDUCTION
occurs occurs
If both electrodes are metals, If both electrodes are metals,
this will be the this will be the
more active metal less active metal
An Electrode
Definitions is a conductor placed in each
& half-ccell to pick up or
Things To Know... An Electrolyte release electrons.
is a substance which will
conduct electricity when Sometimes the electrode is
molten, or in solution. involved in the reaction; in
The Salt Bridge can be just a other cases it can be inert.
filter paper soaked in Generally, it refers to
electrolyte, or a tube of ionic solutions
electrolyte jelly, or even just
the electrolyte solution itself. Spectator Ions
It must allow diffusion of Be aware that there must be
ions from one half-c cell to the Each cell can be described by
other ions in the solutions as
other a short-h
hand. The cell above
well. For example, the
would be described by
Ions migrate through solutions shown contain Cl-
the Salt Bridge to keep and SO42- ions as well as the
the total charge in Zn|Zn2+ || Cu2+|Cu
metal ions. They take no
each half-c cell neutral part, except to migrate
anode salt cathode
through the Salt Bridge.
species bridge species
Mg2+ + 2e- Mg(s) -2.36 3. The overall equation for the reaction can be found by
simply adding together the 2 half-equations, being sure that
Zn2+ + 2e- Zn(s) -0.76 the same number of electrons are on each side and
therefore, cancel-out as follows:
Fe2+ + 2e- Fe(s) -0.44
Zn(s) + Cu2+(aq)+ 2e- Cu(s) + Zn2+(aq)+ 2e-
2H+ + 2e- H2(g) 0.00
Any 2 half-equations can be combined this way, but
2+ - sometimes it may be necessary to multiply one or both by
Cu + 2e Cu(s) +0.34 a factor so that the electrons will cancel.
I2(aq) + 2e- 2I-(aq) +0.62 Example:
-
Cl2(aq) + 2e 2Cl-(aq)
Fe3+ + e- Fe2+(s) +0.77 combined with
Fe2+ Fe3+(s) + e-
O2(g)+ 4H+(aq) + 4e- 2H2O(l) +1.23 You need to multiply everything in the 2nd equation x2
before combining them
Cl2(aq) + 2e- 2Cl-(aq) +1.36
Cl2(aq)+ 2e- + 2Fe2+ 2Fe3+(s)+ 2e- + 2Cl-(aq)
Notice that each half-equation is written as a reduction. If
However, when you do this, the Eo values
you need to write it backwards as an oxidation, then simply
o DO NOT CHANGE
reverse the sign of the E value.
From the table, the half-cell reactions involved must be: If, during a REDOX reaction the oxidation number of a
Eo species decreases, then it has been REDUCED.
2+ -
Cu + 2e Cu(s) +0.34
and Examples of Half-Equations with Oxidation Numbers
I2(aq) + 2e- 2I-(aq) +0.62
Fe(s) Fe2+(aq)
The copper equation is higher up the Standard Potentials oxd no. 0 +2
table, so it must run in reverse as an oxidation. Dont forget Oxd number has increased, Oxidation has occurred.
to reverse the sign of the Eo value too.
2Cl-(aq) Cl2(g)
2+ -
Cu(s) Cu + 2e -0.34 oxd no. -1 0
Oxd number has increased, Oxidation has occurred.
Now combine the half-equations to form the overall
equation, and add the Eos to get the total cell EMF. Fe3+(aq) Fe2+(aq)
oxd no. +3 +2
I2(aq)+ 2e-+ Cu(s) Cu2++ 2e-+ 2I-(aq) +0.62 Oxd number has decreased, Reduction has occurred.
-0.34
Total Cell EMF = +0.28 V 2H+(aq) H2(g)
oxd no. +1 0
In the diagram above, the Copper half-cell is the ANODE Oxd number has decreased, Reduction has occurred.
(oxidation) and the Iodine half-cell is the CATHODE
(reduction). Electrons would flow from the copper Wherever an oxidation has occurred, electrons have been
electrode towards the graphite (carbon) electrode. lost. If you add electron(s) to the RIGHT side of the half-
equation, the charges will balance.
The Shorthand description for this cell is:
e.g. from above, Fe(s) Fe2+(aq) + 2e-
2+ - Inert electrode
Cu|Cu || I2|I (C)
in brackets
Notes For reductions, add electron(s) to the LEFT side.
1. There would also be spectator ions in each half-cell.
They have been totally ignored above. e.g. from above, 2H+(aq)+ 2e- H2(g)
H in a galvanic cell,
the Ea is very low
The cell is NOT Galvanic. It will NOT run
spontaneously. Instead of producing electricity, you would
have to put electricity INTO the cell (minimum 1.10 Volts)
Energy is released Products to make these reactions run.
by the reaction
The overall reaction is Endothermic.
Energy Content
to the definitions involved, and is not really a contradiction. must be put
H IN, to make
positive
this reaction
Battery
go.
Reactants
To make this cell, you could use exactly the same half-cells,
Cell
but instead of connecting a voltmeter in the circuit, you
would need to place an electrical source, such as a battery
or power pack to provide energy.
Electrical
source
(The difference is explained Electron flow
soon)
Zn Cu
All Dry Cells & Batteries
Environmental Impact
of this technology is minimal, since the chemicals involved
This battery really is a battery. do not cause any significant problems when disposed of
Inside are 4 connected cells, into landfill rubbish dumps.
each 1.5 volts.
The Silver Oxide Button Cell
The entire device gives 6 volts. There is a limit to how small you can make a standard dry
cell and still get a practical amount of electricity from it.
The first dry cell was invented by Leclanche in 1866, and KOH electrolyte paste
developed to commercial standard by Gassner in 1881. The
electrolyte solution is a thick paste, and the entire cell is +ve
Ag2O + water paste
sealed against spillage, and easily transported.
(CATHODE)
Structure of a Dry Cell Positive Terminal Stainless steel casing
The a)....................................... Series of Metals contols The original ak)................... cell allowed the invention and
what happens when a metal reacts with the b).................... development of many small, portable, electrical devices.
al).......................................... cells have allowed even
of another metal in solution. If the metal is
further miniaturization.
c).......................................... the Series, it will
d)......................................... the lower-activity ion from the Part B Practice problems
solution. In this process, the atoms of the higher-activity
metal e)............................... electrons, and become ions in 1. Metal Displacement Reactions
the solution. The process of losing electrons is called For each combination below, firstly use the Activity Series
f).......................................... Meanwhile, the ions of the to decide whether or not a reaction would occur.
less-active metal g)............................. electrons and form If not, write no reaction. If so,
atoms, which form a solid precipitate. The process of write half-equations for the change occurring to each
gaining electrons is called h)................................................. species. Label each half-reaction as oxidn. or reduction
write a balanced, net ionic equation for the overall
reaction.
Neither process can occur alone; each can only happen
with the other, so the entire reaction is called a) Magnesium metal placed in a solution of Pb2+ ions.
i)..................................... - .......................................... or simply b) Lead metal placed in a solution of Mg2+ ions.
j)............................... c) Aluminium metal placed in a solution of Cu2+ ions.
d) Copper metal placed in a solution of Ag+ ions.
2+
Although oxidation and reduction must occur together, e) Iron metal placed in a solution of Ba ions.
they can be separated as long as k)..................................... can f) Calcium metal placed in a solution of Sn2+ ions.
flow from the site of l).......................................... to the site
of m)...................................... through a wire. This is the 2. Galvanic Cells
basis of all electrical n)...................................... and For each cell diagram or description, below:
................................................. i) Write half-equations for each half-cell. Label each as
Anode reaction or Cathode reaction
ii) Find the cell EMF under standard conditions.
A typical electric cell consists of 2 o)........................................ iii) Write an overall, balanced, net ionic equation for the cell
In one, called the p)....................................., oxidation occurs,
a)
while reduction occurs in the q)............................. half-cell. V
The 2 half-cells must be connected by a conducting circuit
so that r).......................... can flow from the s).........................
to the t)...................................... Half-cells must also be
connected by a u)....................... Bridge to allow v).............. Mg Cu
to diffuse between half-cells, so that the total w)....................
.................................. remains balanced.
For Galvanic Cells, when combining any 2 half-equations d) An inert graphite electrode is in contact with an acid
from the table, the one ac).................................... the table (contains H+) in a stream of H2(g). This is connected to a
Zn /Zn2+ half-cell.
must always by written as an ad)...............................................,
and its Eo value ae)................................................... You can e) The same H+/H2 half cell is connected to one
then af)............................. the 2 Eo values to get the total cell containing a graphite electrode in a solution containing Cl-
ag).................................. under standard conditions. ions, and dissolved Cl2(aq)
Br
80
Most elements exist in nature as a mixture of 2 or more
Any atom can be described this way: isotopes. The Atomic Mass shown on the Periodic
35 Table is the weighted average of the mixture of
Atomic Number isotopes that occurs on Earth.
However, on the Periodic Table, elements are described like
Example: Chlorine exists as 2 isotopes:
this:
Atomic Number
35
Cl 37
Cl
18 Equal to the number of electrons
and the number of protons in
17 17
Ar
Argon
Chemical Symbol
Element Name
18 neutrons 20 neutrons
This is best seen if all the known isotopes of all the The largest naturally occuring atoms are isotopes of
elements are plotted on a graph, as follows. uranium (Atomic Number 92), and in early text books you
will see that the Periodic Table ended at uranium. However,
In this zone, over the past 50 years or so, it has become possible to
140
are stable
Most Periodic Tables now list transuranic elements as far as
number of Neutrons
p
Atomic Number 110 or even to No.118, although the
=
n
names for some of these have not been agreed upon, and
re
he
w
in some cases only tiny quantities have ever been made, and
e
lin
80
One of the most important and commonly used In aircraft manufacture, the airplane parts may be welded
radioisotopes produced is Cobalt-60. It is produced when together. It is essential that the welded joints are totally
ordinary, stable Cobalt-59 absorbs a neutron: strong and free of defects. (Having a wing fall off in flight
is not a good look this season!) To see inside the weld,
59 1 60 gamma rays are used like X-rays; they are beamed through
27
Co + 0
n 27
Co the welded joint and an image captured by a gamma-ray
camera. Analysis of the image allows engineers to be sure
Uses of Radioisotopes of the quality of the welding.
Cobalt-60 is unstable and undergoes Beta Decay:
Medical Uses of Cobalt-60
0
Some forms of cancer can be treated by beaming the
60 60
Co Ni + -1
1
e + gamma rays into the tumour. Cancer cells are actively
27 28 growing and this makes their DNA more susceptible to
particle gamma gamma ray damage than healthy cells.
electron ray
By enclosing the radioactive material inside a heavily Why is Cobalt-60 Ideal for These Uses?
shielded container with a narrow aperture, a narrow beam
of gamma rays can be produced. Cobalt-60 has a half-life of 5.3 years, so once a cannister
is prepared, it will have a useful life of about 6-10 years
before it needs to be replaced. This is convenient for
industrial and medical uses.
The energy of the gamma rays emitted by Cobalt-60 is
ideal for the imaging of welded metal joints, and for killing
living cells, whether tumour cells or bacteria on a bandage.
The energy carried by gamma rays can vary considerably.
The radiation from Cobalt-60 is ideal for certain industrial It is relatively cheap and easy to prepare Cobalt-60 by
applications and in the medical treatment of some cancers. inserting ordinary Cobalt-59 into a nuclear reactor and
allowing neutron-bombardment to occur.
Radiation causes electrons to be knocked out of their The benefits to air safety should be obvious.
orbits, so the atom becomes an ion. One alpha paticle can
ionize thousands of atoms, causing a tube of non- Using gamma rays to sterilize bandages is cheaper and
conducting gas (Argon is often used) to become more effective and reliable than the alternatives which
momentarily conductive. include heat treatments and/or chemical antiseptics.
Problems
The problems associated with the use of radioisotopes,
centre mainly around the safety of the people who work
with the radioactive materials.
Geiger All radiations are dangerous to living cells, and even low-
Tube level exposure is known to increase the risk of genetic
mutations and development of cancers.
An electronic circuit detects the change and counts the From the workers at the nuclear reactor, to those who
ionization events occurring when radiation is present. handle and transport the isotopes, to the professional end-
users in hospitals or industry, there are risks of dangerous
A Scintillation Counter detects radiation by the flash of exposure to radiation.
light which some chemicals emit when struck by radiation.
Light-sensitive detectors pick up each tiny flash of light The key to safety is effective packaging and shielding of the
and an electronic circuit counts and records the events. material, and constant monitoring for escaped radiation.
For example, all personnel in at-risk jobs and
environments must wear small tell-tale detectors to warn
of radiation exposure.
Iodine-131 is radioactive and emits beta and gamma rays. I-131 has a short half-life and the
radiation disappears rapidly.
HSC Chemistry Topic 1
Copyright 2005-2007 keep it simple science
27 www.keepitsimplescience.com.au
TM
Emmaus Catholic College SL#802440
keep it simple science
Worksheet 4
Isotopes are atoms of the same The largest naturally-occurring atoms are of the
a)........................................ which have the same element q).................................... which has atomic
atomic b)..................................., but different number r)............. Atoms larger than this are
c)............................................... because they have a called s)........................................ Elements and
different number of d).................................. in the are all made artificially by either t)............................
nucleus. Most elements occur in nature as a - bombardment in a nuclear reactor, or by
mixture of 2 or more e)........................................... colliding different nuclei in a
u).................................... .........................................
The Atomic Weight shown on the periodic
table is the weighted f)......................................... Commercial Radioisotopes can also be prepared
of the masses of the mix of isotopes in nature. by neutron- v)........................................ in a
w).............................. .................................... One of
Isotopes of an element show exactly the same the most commonly used radioisotopes is Cobalt-
g)..................................... properties, but some may x)...................., which is unstable and decays by
be unstable and h)..................................................... emitting y)................... and ........................ rays.
There are 3 different radiations that might be
emitted: It is used in industry for
z).......................................... medical bandages and
i).............................. () radiation is a stream of dressings, and for checking the quality of
particles. Each particle is composed of aa)................................................. in aircraft
j)................................... and ........................................ manufacture. In medicine, it is used to treat
Beta radiation (symbol, k).................) is a stream ab)...................................... by killing the tumour
of l)........................................... cells with ac)............................ rays.
m).................................. () radiation is
n)....................-frequency waves. The radiations from radioactive substances can
be detected and measured by
Whether or not any isotope is stable or ad)....................................... film, as well as the
radioactive is mainly determined by the ratio of ae).................................-Counter which
o).............................. to ..................................... in electronically registers the af)....................................
the nucleus, and also how large the nucleus is. All effects of the radiation. Another method of
atoms with more than about p).............. protons detection, called a ag............................. -Counter,
are too big to be stable. detects the ah)..........................................................
which some chemicals emit when struck by
radiations.
PRODUCTION
of
MATERIALS
Practice Questions 6.
These are not intended to be "HSC style" questions, but to Cellulose is:
challenge your basic knowledge and understanding of the A. an addition polymer of ethylene.
topic, and remind you of what you NEED to know at the B. a condensation polymer of glucose.
K.I.S.S. Principle level. C. an addition polymer of glucose.
D. a monomer which can be polymerized.
When you have confidently mastered this level, it is
strongly recommended you work on questions from past
7.
exam papers.
Theoretically, we should be able to use cellulose as a raw
Part A Multiple Choice material to replace petroleum compounds. However, there
is one technology lacking which prevents this becoming an
1. economically viable process. The step missing is a cheap
If propene (C3H6) underwent an addition reaction with efficient way to convert:
water, the correct structural formula for the product would A. cellulose into glucose.
be B. glucose into ethanol.
A. H H H B. H H O-H H C. ethanol into ethylene.
D. ethylene into plastics.
H C C C H H C C C H
H H H H H H 8.
The alkanol with condensed structural formula
C. H H O-H
H D. H H O-H
H CH3(CH2)4CH2OH would be called:
A. butanol B. pentanol C. hexanol D. heptanol
H C C C H H C C C H
H H H H O-H
H 9.
The alkanols have much higher m.p.s & b.ps compared to
the corresponding alkanes, because:
2. A. the mass of the OH group increases dispersion forces.
Alkenes can be identified by their reaction with bromine B. the intra-molecular covalent bonds are stronger.
water, in which the bromine: C. the O-H bond is polar, creating a dipole.
A. moves from one liquid layer to the other.
D. the C=C double bond is much stronger than C-C bonds.
B. changes colour from brown to purple.
C. completely loses its colour.
D. changes from colourless to purple. 10.
As well as a source of carbohydrates and some live yeast,
3. the other necessary conditions for the production of
In the Catalytic Cracking of the alkane C20H42, the ethanol by fermentation are:
molecule happened to break up into 4 pieces; 1 molecule of A. temperature above 40oC and plenty of oxygen.
ethylene, one of octane, 1 of hexene, and another B. anaerobic conditions and temperature below 20oC.
hydrocarbon molecule. The formula for the 4th fragment C. temperature around 25oC and plenty of oxygen.
would be: D. anaerobic conditions and temperatures about 25oC.
A. C4H8 B. C6H12 C. C2H4 D. C3H8
11.
4. Which equation for the combustion of methanol is the one
An addition polymer is formed when: for which the energy released would be equal to Hc ?
A. long-chain alkane molecules combine.
B. C=C double bonds are formed in monomer molecules. A. CH3OH(g) + 2O2(g) CO2(g) + 2H2O(g)
C. molecules join by removing atoms to create bonds.
D. monomers join by splitting C=C double bonds. B. CH3OH(l) + 3O2(g) CO2(g) + 2H2O(l)
2
5. C. 2CH3OH(l) + 3O2(g) 2CO2(g) + 4H2O(l)
In general terms, increasing the size and mass of any side
groups in an ethylene-based plastic, will probably result in D. CH3OH(g) + 3O2(g) CO2(g) + 2H2O(g)
the plastic being 2
A. softer and more flexible.
B. less soluble in water.
C. a better conductor of electricity.
D. harder and more rigid.
20. (4 marks)
Explain, using chemical equation(s) when needed, why
Mg Zn liquid hexene will de-colourize a bromine solution, but
liquid hexane will not.
21. (6 marks)
The main industrial source of ethylene is Cat-Cracking of
certain molecules in petroleum.
Mg2+ Zn2+ a) Outline the general process of Cat-Cracking, including
the meaning of the term.
In the cell shown: b) Outline the process of Addition Polymerization of
A. electrons would flow towards the Mg half-cell. ethylene.
B. zinc would be oxidized by the reaction. c) Draw a structural formula for a section of a polyethylene
C. positive ions would flow out of the Mg half-cell. molecule containing 3 monomer units.
D. the zinc half-cell is the anode.
22. (7 marks)
15. A common plastic is known as P.V.C.
The Galvanic Cell shown in Q14 uses a metal and ions of a) Draw a structural formula for the monomer from which
the same metal in each half-cell. If you built a series of PVC is made, and give both its common name and
similar cells, but used different metal combinations in each systematic chemical name.
case, which of the following would give the highest cell b) Account for the differences in properties and typical
voltage? (Assuming all other variables were kept the same.) uses of PVC compared to polyethylene.
A. iron & zinc B. copper and silver
C. copper and magnesium D. magnesium and zinc 23. (4 marks)
The amino acid Glycine has the following structure:
16. H O-H
H
In the following equation, which species has undergone
H N C C
reduction?
H H O
Cl2(aq) + 2Br-(aq) Br2(aq) + 2Cl-(aq)
The condensation polymer polyglycine can be formed by
A. Cl2(aq) -
B. Br (aq) joining together many glycine molecules.
C. Br2(aq) D. Cl-(aq)
a) Use structural diagrams to show the 2 products formed
17. when two glycine monomers join together.
Isotopes have
A. the same mass number as each other. b) Explain why this is called condensation
B. different atomic numbers. polymerization.
C. different electron configurations.
D. the same chemical properties as each other.
34. (5 marks)
FOR MAXIMUM MARKS SHOW
a) Indentify one use of a named radioisotope in industry.
FORMULAS & WORKING,
APPROPRIATE PRECISION & UNITS b) Identify one use of a named radioisotope in medicine,
IN ALL CHEMICAL PROBLEMS and explain how its use is related to its chemical properties.