CH1010 Molecularity Page Exam 1, 2017-02-03

Worcester Polytechnic Institute 1 Lecture section 02

Exam 1, CH1010-C17-C02
3 February 2017, 11:00 AM

Please read over this page before beginning this exam:

Please write your name and laboratory section number on page 3 prior to starting this exam.

Grading:
The exam contains x problems worth a total of 75 points. This exam represents 18.75% of the
overall grade for this course.
Your solutions must clearly show all steps employed to obtain an answer. You may receive gen-
erous partial credit on multi-step problems where a calculation error was propagated throughout
the remainder of the problem, but only if the remainder of your work is chemically and mathe-
matically sound, and is presented in a legible, straightforward manner.
Only work within the problem boundary will be considered for partial credit.

Cover page:
This top page is a scratch sheet containing a periodic table, a table of electronegativity values,
some equations, and constants. This page should be detached and employed as a reference
throughout the exam.
No work on this scratch sheet will be graded.

Allowed / forbidden items:

Mobile phones are strictly forbidden at any time during the exam period. Observation of a mo-
bile phone will result in an immediate grade of zero for the exam.
Scientific calculators and rulers are allowed. Calculators and rulers may not be shared between
students during the exam.
Scratch paper is not allowed.
You may bring in one 3 5 index card containing notes of your choice, however this index card
must be stapled to the exam upon submission. No work on this index card will be graded.

Timing:
This portion of the exam must be completed in one sitting during the 50-minute lecture period.
Only students having discussed special accommodations with Prof. Grimm may employ addi-
tional time.
If you leave the exam room at any time during the testing period, your exam will be considered
complete.
CH1010 Molecularity Page Exam 1, 2017-02-03
Worcester Polytechnic Institute 2 Lecture section 02

Periodic Table and Electronegativity

1 2
H He
1.0079 4.0026
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
6.941 9.0122 10.811 12.011 14.007 15.999 18.998 20.180
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
22.990 24.305 26.982 28.086 30.974 32.065 35.453 39.948
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.098 40.078 44.956 47.867 50.942 51.996 54.938 55.845 58.933 58.693 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.468 87.62 88.906 91.224 92.906 95.94 [98] 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29
55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba 57-70 Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 174.97 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 [209] [210] [222]
87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra 89.102 Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
[223] [226] [262] [265] [268] [271] [270] [277] [276] [281] [280] [285] [284] [289] [288] [293] [294] [294]

57 58 59 60 61 62 63 64 65 66 67 68 69 70
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
138.91 140.12 140.91 144.24 [145] 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.04
89 90 91 92 93 94 95 96 97 98 99 100 101 102
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
1.0079 1.0079 1.0079 238.03 [237] [244] [243] [247] [247] [251] [252] [257] [258] [259]
1 2
H He
2.1
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
1.0 1.5 2.0 2.5 3.0 3.5 4.0
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
0.9 1.2 1.5 1.8 2.1 2.5 3.0
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
0.8 1.0 1.3 1.5 1.6 1.6 1.5 1.8 1.8 1.8 1.9 1.6 1.6 1.8 2.0 2.4 2.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
0.8 1.0 1.2 1.4 1.6 1.8 1.9 2.2 2.2 2.2 1.9 1.7 1.7 1.8 1.9 2.1 2.5
55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba 57-70 Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
0.7 0.9 1.3 1.3 1.5 1.7 1.9 2.2 2.2 2.2 2.4 1.9 1.8 1.9 1.9 2.0 2.2
87 88 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra 89.102 Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
0.7 0.9

57 58 59 60 61 62 63 64 65 66 67 68 69 70
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
1.1 1.1 1.1 1.1 1.2 1.2 1.1 1.2 1.2 1.2 1.2 1.2 1.2 1.2
89 90 91 92 93 94 95 96 97 98 99 100 101 102
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
1.3 1.5 1.5 1.7 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.5

Equations
me q4e
13.6 eV Z
2
h R = 2 3
= 1.0974 107 m 1
EBohr = 2 Dx mDv 80 h c
n 4p
hc 34 0 h2 11
h = 6.6261 10 Js a0 = = 5.2918 10 m
E = hn = pme q2e
l
c = 2.998 108 m s 1
31
h 19 melectron = 9.109 10 kg
l= 1 eV = 1.602 10 J
mv mproton = 1.672 10
27
kg