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N de prctica 7
Ttulo PERMANGANOMETRA PARTE I: Preparacin y valoracin de una
solucin de Permanganato de Potasio.
Fecha Realizado:19-06-2017 Entregado:26-06-2017
Autores/Grupo Herrera J.; Ushia A./ Grupo 4
Horario Lunes:09H00/ 11H00
RESUMEN
ABSTRACT
In the present practice a solution of potassium permanganate was prepared, in addition to the
standardization and determination of the percentage of H2O2. These types of titrations are
known as redox, being an oxidation-reduction reaction between the analyte and the titrant; The
KMnO4 acts as a self-indicator. An amount of KMnO4 was weighed, taking the precaution that
it is photosensitive, allowing it to boil for a set time, therefore being allowed to stand for one
day, filtering with glass wool, transferring it to an amber flask. For the standardization Na2C2O4
was used, besides adding distilled water and sulfuric acid, making it boil to titrate with KMnO4
until a pink hue. For the determination of the percentage of hydrogen peroxide, we proceeded
with the relevant calculations to know the aliquot to be taken from the commercial 10 volume
flask, from the calculated aliquot to a certain volume, again an aliquot was taken and acid
FACULTAD DE CIENCIAS QUMICAS
PROCESO PLAN CURRICULAR
INFORME DE LABORATORIO
Cdigo: FCQ-P05-F06; Versin: 01; Fecha: 16 de enero de 2017
Sulfuric acid, finally titrating with KMnO4 to a pink hue. Thus obtaining an average
concentration of KMnO4 from 0.0111 With a confidence limit of 0.0111 2.05x104. For the
commercial sample of H2O2 % w / v was obtained 2.78 % With a confidence limit of 2.780.084
and an error of 8.40%
OBJETIVOS
Especie Q. Formula
Conocer el fundamento bsico de las M. Concentracin
valoraciones o titulaciones de xido Permanganato
reduccin. de Potasio KMnO4 0,0111 M
Entender el manejo de las relaciones Agua destilada H2O ____
estequiomtricas en reacciones qumicas
Agua
de xido-reduccin.
oxigenada H2O2 10 v
Preparar una solucin de Permanganato
de Potasio 0,01 M. Oxalato de
Determinar el %p/v del H2O2 y su % de Sodio Na2C2O4 98%
error del frasco comercial de 10 cido sulfurico H2SO4 10%
volumenes. Elaborado por: Herrera J y otros
= 0.053% =8,40%
3,18 0.053
. = = DISCUSIONES
2
CONCLUSIONES
5
=
2
5
H2O2 =
2
FACULTAD DE CIENCIAS QUMICAS
PROCESO PLAN CURRICULAR
INFORME DE LABORATORIO
Cdigo: FCQ-P05-F06; Versin: 01; Fecha: 16 de enero de 2017
%P/V=masa 5 4 4
M H2O2= ( )
2 22
5 0,04 20
100 M H2O2= ( )
2 25
Cfinal= M H2O2=0,08M
Cini*Vini=Cfin*Vfin
0,08500
Vini= 4,46
CUESTIONARIO Vini=8,968 ml H2O2
1
H2O2H2O+2 O2
VO2=nV H2O2
VO2=50V H2O2
nH2O2 =2 nO2
M H2O2*V H2O2=2 nO2
PV=nO2RT
2(5022)
M H2O2*V H2O2=
2150
Cinicial=MH2O2=
0,082 273,15
Cinicial=MH2O2=4,4646 mol/L
M=
0,2
M= 5 =0,04 M KMnO4
Ecuacin
5 H2O2+6H++2MnO4-2Mn2++8H2O+5 O2
5
M H2O2*VH2O2=2 ( 4 4 )
FACULTAD DE CIENCIAS QUMICAS
PROCESO PLAN CURRICULAR
INFORME DE LABORATORIO
Cdigo: FCQ-P05-F06; Versin: 01; Fecha: 16 de enero de 2017