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PHYWE series of publications Laboratory Experiments Chemistry PHYWE SYSTEME GMBH & Co. KG D-37070 Gttingen P3020501 1
LEC
Partial molar volumes
02.05
Calculate the masses of 25 ml of the respective mixtures as the The dependence of it on the composition is described by the
difference of the two weights. relationship
d 1MV2
1VA VB 2 1VA VB 2
m (C2H5OH) / g m (H2O) / g d Vr d Vid
(6)
30.6 1.35 dxA dxA dxA
29.35 2.85
27.90 4.70 under consideration of the Gibbs-Duhem equation.
Analogous correlations can be formulated for xB due to the fact
26.20 6.85 that xA = 1 - xB.
24.15 9.45 After substituting (6) in (5), the following relationships are
obtained:
21.60 12.65
18.35 16.75 d 1MV2
VB MV xA VB (7.1)
14.15 22.10 dxA
8.35 29.40
and
MV Vr Vid
2 P3020501 PHYWE series of publications Laboratory Experiments Chemistry PHYWE SYSTEME GMBH & Co. KG D-37070 Gttingen
LEC
Partial molar volumes
02.05
PHYWE series of publications Laboratory Experiments Chemistry PHYWE SYSTEME GMBH & Co. KG D-37070 Gttingen P3020501 3
LEC
Partial molar volumes
02.05
4 P3020501 PHYWE series of publications Laboratory Experiments Chemistry PHYWE SYSTEME GMBH & Co. KG D-37070 Gttingen