JEE Advanced March 20 P2 EV1

20 MARCH 2017: MAJOR TEST # 10 : JEE (ADVANCED) :PAPER 2
Name of Student: ____________________________Batch:_______ Contact no: ________________
Max Marks: 240 Time: 3 hours
READ THE INSTRUCTIONS CAREFULLY
QUESTION PAPER FORMAT AND MARKING SCHEME

1. The question paper is divided into three parts each comprising of Physics, Chemistry &
Mathematics. Each part is further divided into three sections.
2. Section 1 contains 8 questions. The answer to each question is a single digit integer ranging
from 0 to 9 (both inclusive)
Marking Scheme: +4 for correct answer and 0 in all other cases
3. Section 2 contains 8 multiple choice questions with one or more than one correct option.
Marking Scheme: +4 for correct answer, 0 if not attempted and in all other cases
4. Section 3 contains 2 paragraph type questions. Based on each paragraph, there are two
questions. Each question may have one or more than one correct option(s)
Marking Scheme: +4 for correct answer, 0 if not attempted and in all other cases
PART I: PHYSICS
SECTION 1 (Maximum Marks: 32)
This section contains EIGHT questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive
For each question darken the bubble corresponding to the correct integer in the ORS
Marking Scheme
+4 If the bubble corresponding to the answer is darkened
0 In all other cases
1. A gas expands according to the process represented by the solid line ST in the following P V
diagram. Find the maximum temperature (in K) attained during the process. The temperature at point
A is 200 K. Fill the answer as sum of digits.
P
S
9PA
3PA T
PA A
VA 3VA V
2. A gas expanding at constant pressure performs 25 J of work. The average degree of freedom per
molecule for the gas is 6. Find the heat absorbed by the gas in Joules and fill the answer as sume of
digits.
3. A mixture of moles of monoatomic gas and moles of diatomic gas has ratio of specific heat
capacities for gases as 1.5. The relation between the can be written as . Fill the
answer as .
____________________________________________________________________________
Space for rough work
4. Two identical containers joined by a small pipe initially contain the same gas at pressure and
absolute temperature T . One container is now maintained at the same temperature while the other
container is heated to T . The common pressure of the gases can be written as where a & b are
natural numbers. Fill the answer as .
5. Two cylinders A & B, fitted with pistons, contain equal amounts of an ideal diatomic gas at 300 K.
the pistons of A is free to move, while that of B is held fixed. The same amount of heat is given to
the gas in each cylinder. If the rise in temperature of the gas in A is 30 K, find the rise in temperature
of the gas in B. Fill the answer as product of digits.
6. One end of a uniform rod of length 1 m is placed in boiling water while its other end is placed in
melting ice. A point P on the rod is maintained at a constant temperature of . The mass of the
steam produced per second is equal to the mass of the ice melting per second. If specific latent heat
of the steam is 7 times the specific latent heat of ice, the distance of b from the steam chamber can be
written as where m and n are integers. Fill the answer as .
7. A long glass capillary tube is dipped in water. It is known that water wets the glass. The water level
rises by h in the tube. The tube is now pushed down so that only a length h/2 is outside the water
surface. Find the angle (in degrees) of contact of the water surface at the upper end of the tube and
fill the answer as first digit.
8. A and B are two points on a uniform metal ring whose centre ic C. The angle A . A and B are
maintained at two different constant temperatures. When , the rate of total heat flow from
A to B is 1.2 . When 9 , find this rate. Fill the digit in the first decimal place
____________________________________________________________________________

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN
ONE of these four option(s) is (are ) correct
For each question darken the bubbles corresponding to all the correct option(s) in the
ORS
Marking Scheme
If the bubble(s) corresponding to all the correct option(s) is(are) darkened
If none of the bubbles is darkened
In all other cases
9. The molar hear capacity for an ideal gas

(A) is zero for an adiabatic process
(B) is infinite for an isothermal process
(C) depends only on the nature of the gas for a process in which either volume or pressure is
constant
(D) is equal to the product of the molecular weight and specific heat capacity for any process.
10. A gas expands such that its initial and final temperatures are equal. Also, the process followed by
the gas traces a straight line on the p V diagram.
(A) The temperature of the gas remains constant throughout.
(B) The temperature of the gas first increases and then decreases.
(C) The temperature of the gas first decreases and then increases.
(D) The straight line has a negative slope
11. The power radiated by a black body is P and it radiates maximum energy around the wavelength
. If the temperature of the black body is now changed so that it radiates maximum energy
around a wavelength 3 , the power radiated by it will increase by a factor of .
(A) 3 (B) 9 (C) (D)
____________________________________________________________________________
12. The temperature of an isolated black body falls from T to T in time t. Let c be a constant.
(A) * + (B) * +
(C) * + (D) * +
13. A gas undergoes a process in which its pressure p and volume V are related as V .
The bulk modulus for the gas in the process is

(A) (B) (C) (D)
14. In the cyclic process shown on the V p diagram, the magnitude of the work done is
V
V
(A) ( ) (B) ( )
(C) V V (D) V V
____________________________________________________________________________

15. A gas may expand either adiabatically or isothermally. A number of p V curves are drawn for the
two processes over different range of pressure and volume. It will be found that
(A) Two adiabatic curves dont intersect
(B) Two isothermal curves dont intersect
(C) An adiabatic curve and an isothermal curve may intersect
(D) The magnitude of the slope of an adiabatic curve is greater than the magnitude of the slope of
an isothermal curve for the same values of pressure and volume.
16. A cyclic process is shown on the p T diagram.
D
T
Which of the following curves show the same process?

(a) A (b) A
V V
D D
T T
(c) (D) V
V
D
D
A
T
A T
____________________________________________________________________________

This section contains TWO paragraphs

Based on each paragraph, there will be TWO questions
Marking Scheme
In all other cases
____________________________________________________________________________

PARAGRAPH 1
Once upon a time, a brilliant student of a reputed Physics Institute started delivering Physics lecture to
his fellow classmates out of generosity (I seriously doubt this) so that they can cope up with the
difficulty of the subject. Out of many, only one cared to join his class. Due to lack of space, he held his
class in the open sky at 8 in the evening every Sunday. During one of his class, he was showing his dear
friend two stars P & S. Using one of his many magical ways (for which he was famous among his batch
mates), he was able to find the ratio of the wavelength of the light corresponding to maximum intensity
emitted from the two stars as
Using one of his another magical ways (he had many), he was able to find that the root mean square
speed of the molecules of both the planets is the same. He again used his magic to find that star P is
made up of molecules similar in structure to that of carbon dioxide and star S is made up of molecules
similar in structure to that of water. Again by his magic, he found that the diameter of star P is 4 times
that of star S After his lecture, he posed two questions to his so called student. His so called
student charmed by the magic answered the questions correctly. Using the information in the paragraph,
guess the answers
17. Choose the correct option(s)

(A) The ratio of the average molar mass of molecules on star P to star S is 4.
(B) The ratio of temperature of the star P to star S is 1/4.
(C) The ratio of the intensity of light emitted by the star P to the star S is 1/256.
(D) The ratio of the intensity of light emitted by the star P to the star S is 1/16.
18. Choose the correct option (s) ( Note that the stars are home to super power nuclear fusion reactions
due to their extremely high temperatures)
(A) The ratio of internal energy per mole of star P to star S is
(B) The ratio of internal energy per mole of star P to star S is 3
(C) The ratio of the power emitted by star P to that emitted by star S is 1/16
(D) The ratio of the power emitted by star P to that emitted by star S is 1/4 .
____________________________________________________________________________

PARAGRAPH 2
A solid floats or sinks in a liquid depending on whether the solid is lighter or denser. The mass of liquid
displaced by the solid is equal to weight of the solid. However, the density of the substance may change
with change in temperature. Hence, the fraction of volume of submerged solid may change depending
upon the coefficient of thermal expansions.
19. A solid whose volume does not change with temperature floats in a liquid. For two different
temperatures of the liquid, fractions of the volume of solid remain submergedin the
liquid. The coefficient of volume expansion of the liquid is equal to
(A) (B) (C) (D)
20. A solid with coefficient of linear expansion just floats in a liquid whose coefficient of volume
expansion is . If the system is heated, the solid will
(A) sink in all cases (B) continue to float in all cases
(C) sink if 3 (D) sink if 3
____________________________________________________________________________

PART II: CHEMISTRY

inclusive
Marking Scheme
1. Write the maximum number of atoms having same hybridisation in 2, 5-di-N-chloridothioimino-3, 4-

diagonothiophene as shown below:
N N
C C
C=C
C C
N S N
S S
Cl Cl
2. Two moles of a monoatomic gas is mixed with two moles of a diatomic gas. What is the molar heat
capacity at constant volume of the gaseous mixture in calorie?
3. What is the number of compounds having a benzene nucleus can have the molecular formula C7H8O?
____________________________________________________________________________
4. If, X = next nearest neighbor for a simple cubic arrangement
Y = next nearest neighbor for a body centre cubic arrangement
Z = next nearest neighbor for a Face centre cubic arrangement
XY Z
Than what is the value of ?
3
5. The bond order of CN-as well as NO+ has a value of?
6. A reaction, A(g) + 2B(g) 2C(g) + D(g) was studied using an initial concentration of B which
was 1.5 times that of A. But the equilibrium concentrations of A and B were found to be equal. The
value of Kp for the equilibrium is ______.
7. Amongst the following, the total number of physical properties which are extensive are:
(a) Density (b) Viscosity (c) Surface tension (d) Dipole moment
(e) Volume (f) Refractive index (g) G (h) H
(i) U (j) S
8. How many structures have peroxy linkages in following list:
H2SO5,H2S2O7,H2S2O8,CrO5,K3CrO8,KO2,BaO2,SrO2,HNO4,PbO2
____________________________________________________________________________

ORS
Marking Scheme
In all other cases
9. The correct expressions of an adiabatic process

1
1
T2 V1 P2 T1 r

(A) T1 = V2 (B) P1 = T2
(C) P1V1 = P2V2 (D) P1V11 = P2V21
10. 100 mL of 0.06 M Ca(NO3)2 is added to 50 mL of 0.06 M Na2C2O4. After the reaction is complete
(A) 0.003 moles of calcium oxalate will get precipitated.
2
(B) 0.003 M of Ca will remain in excess.
(D) Na2C2O4 is limiting reagent.
(D) Ca(NO3)2 is excess reagent.
11. Select the correct statement about FCC (ABCAB..) structure.

3a
(A) Distance between nearest octahedral void and tetrahedral void is 4
a
(B) Distance between two nearest octahedral void is 2
3a
(C) Distance between two nearest tetrahedral void is 2
2
2r
(D) Distance between layer A and B is 3
____________________________________________________________________________
12. Choose the correct option(s) for ABnL2
A = Central atom L = Lone pair on atom A n = Number of single bond atom B
(A) When n =4, then molecule is planar but non polar
(B) When n =3, then molecule is non planar but polar
(C) When n =2, then molecule is planar but polar
(D) When n =2, then total bond polarity is being equal to polarity of molecule.
13. The standard enthalpy of formation of CO2 will be given by :

(A) standard enthalpy of combustion of diamond
(B) standard enthalpy of combustion of graphite
(C) standard enthalpy of combustion of CO
(D) sum of standard enthalpy of formation and enthalpy of combustion of CO
14. The correct order of the properties as given in the parenthesis from among the following is
(are):
(A) Cl2 Br2 F2 I2 (Bond energy)
(B) CH3Cl CH2Cl2 CHCl3 CCl4 (dipole moment)
(C) BeF2 NO3 I3 BrF5 (s-character of hybrid orbital of central atom)
(D) BaCO3 SrCO3 CaCO3 MgCO3 (thermal stability)
____________________________________________________________________________
15. Study the following data and select the correct alternative(s). Enthalpies of neutralization of NaOH
by HCl and by acetic acid are -13.7 kcal / mol and -13.2 kcal / mol respectively. Enthalpy of
neutralization of acetic acid by NH4OH -12.3 kcal / mol.
(A) Enthalpy of dissociation of acetic acid is 0.5 kcal / mol
(B) Enthalpy of dissociation of acetic acid is 0.9 kcal / mo
(C) Enthalpy of dissociation of NH4OH is 1.4 kcal / mo
(D) Enthalpy of dissociation of NH4OH is 0.9 kcal / mol
16. Which one is correct for a cyclic process as shown in the figure?
(A) dU 0 (B) q w (C) W = -314 J (D) W = 31.4 J
____________________________________________________________________________

Marking Scheme
In all other cases
PARAGRAPH 1
Heat of neutralization is defined as the enthalpy change when 1 mole of acid/base is completely
neutralization by base/acid in dilute solution.
H aq OH H2O l ; r H0 55.84 kJ / mol
Hionization
0
of aqueous solution of strong acid and strong base is zero.
When a dilute solution of a weak acid or base is neutralized, the enthalpy of neutralization is
somewhat less because of the absorption of heat in the ionization of the weak acid base, for
weak acid/base H0neutralisation Hionization
0

r H0 H OH H2O
17. What is H0 for complete neutralization of strong diacidic base A(OH)2 by HNO3 ?
(A) 55.84 kJ (B) 111.68 kJ (C) 55.84 kJ (D) 111.68 kJ
18. Under the same conditions how many mL of 0.1 M NaOH and 0.05 M H2A (strong diprotic acid)
solution should be mixed for a total volume of 100 mL produce the highest rise in temperature.
(A) 25 : 75 (B) 50 : 50 (C) 75 : 25 (D) 66.66 : 33.33
____________________________________________________________________________
PARAGRAPH 2
Iron melts at 1811 K. Between room temperature and its melting point, iron metal can exist in
different crystalline forms. From room temperature to 1185 K, the crystal structure of iron
exists as a body centered cubic lattice known as -iron. From 1185 K to 1667 K, the structure
becomes face centered cubic and is called -iron. Above 1667 K and upto its melting point, iron
reverts to a bcc structure similar to that of -iron. The later phase is called -iron.
Steel is an alloy of iron and carbon in which some of the interstitial spaces (holes) of the
crystal lattice of iron are occupied by small atoms (carbon). In a blast furnace, the
melting of iron is facilitated when it contains 5.36% of carbon by mass. If this mixture is cooled
too rapidly, the carbon atoms remain dispersed within the -iron phase. This new solid, called
martensite, is extremely hard and brittle. Assume that size of the unit cell of this solid
(martensite) is same as that of -iron (bcc).
19. The density of pure iron metal is 7.8 g/cc at 293 K. The density (in g/cc) of iron at 1250 K would be
(A) 7.8 g/cc (B) 8.84 g/cc (C) 7.24 g/cc (D) 8.48 g/cc
20. Cu exists in FCC unit cell (radius of a Cu atom = 170 pm). When it is mixed with BCC iron at 293
K, an alloy is formed having BCC arrangement where Cu is present at the corners of a unit cell. The
volume of the unit cell of alloy will be
(A) 4.094 1022 cm3 (B) 3.941 1023 cm3 (C) 1.55 1023 cm3 (D) 2.047 1022 cm3
____________________________________________________________________________
PART III: MATHEMATICS

inclusive
Marking Scheme
1 A student is allowed to select at most n books from a collection of (2n + 1) books. If the
total number of ways in which he can select at least one book is 63, find the value of n.
2 If A = ( ) , abc = 1, ATA = I, then find the value of a3 + b3 + c3.
3 The set of values of for which the circles x2 + y2 = 2 and x2 + y2 4x 4y + = 0

have exactly three real common tangents is ?
____________________________________________________________________________
4 Consider the locus of center of circle which touches the circle x2+y2 = 4 and the line
x=4. The distance of the vertex of the locus from the origin is?
5 A tangent drawn to hyperbola the = 1 at P( ) forms a traingle of area 3a2 sq.
units, with the coordinate axes. If the eccentricity of the hyperbola is e, then the value
of e29 is?
6 Find the n in the binomial * + if the ratio of 7th term from beginning to 7th term

from the end is 1/6.

7 The maximum amplitude of z such that |Z 1 i 3 | 1 is, if answer is 'P', give
answer as 6P/ ?
8 How many solutions of '' for equation 4 cos 2 = 7 4x + 4x2, where x R?

____________________________________________________________________________

ORS
Marking Scheme
In all other cases
Q. 9 The number of distinct terms in the expansion, of (x + 2y 3z + 5w 7u)n is

n+4
(A) n + 1 (B) C4
(C) n + 4Cn (D)
Q. 10 The value of the expression

2 ( 1 + ) (1+) + 3(2+ 1) (22 + 1) + 4 (3+1) (32 + 1) +
+ . + (n + 1) (n+ 1) (22 + 1) is
(is the cube root of unity)
(A) (B) ( ) +n
(C) ( ) n (D) None of these
____________________________________________________________________________
Q.11 If the circle x2+y2 = a2 intersects the hyperbola xy=c2 at four points P(x1,y1), Q(x2,y2),
R(x3,y3) and S(x4,y4), then
(A) x1+x2+x3+x4 = 0
(B) y1+y2+y3+y4 = 0
(C) x1x2x3x4 = c4
(D) y1y2y3y4 = c4
Q.12 If the equation of the ellipse is 3x2 + 2y2 + 6x 8y +5 = 0, then which of the following
is/are true?
(A) e = (B) center is (1,2)

(C) Foci is (1,1)&(1,3) (D) Directrices are y=23
Q. 13 In a ABC, C = 90. Then tan A and tan B are the roots of the equation
(A) abx2 c2x + ab = 0 (B) abx2 (a2 + b2)x + ab = 0
(C) c2x2 abx + c2 = 0 (D) ax2 bx + a = 0
____________________________________________________________________________
Q. 14 All points lying on or inside the triangle formed by the points (1, 3) (5, 0) and (1, 2)
satisfy
(A) 3x + 2y 0 (B) 2x + y 13 0
(C) 2x 3y 12 0 (D) 2x + y 0
Q. 15 The line y = mx + c touches the circle

(x a)2 + (y )2 = a2 if
(A) = ma + c + a (B) m = + c + a
(B) + a = m + c (D) c = a
Q.16 If y=2 is directrix and (0,1) is the vertex of the parabola x2+y+=0 , then
(A) = 4 (B) =8 (C) =8 (D) =4
____________________________________________________________________________

Marking Scheme
In all other cases
PARAGRAPH 1
A tangent PT is drawn to the circle x2+y2 = 4 at the point P(3 . A straight line L,
2 2
perpendicular to PT is a tangent to the circle (x3) + y = 1.
Q.17 A possible equation of L is

(A) x3y = 1 (B) x+3y = 1 (C) x3y = 1 (D) x+3y = 5
Q.18 A common tangent of the two circles is

(A) x=2 (B) y=2 (C) x+3y = 4 (D) x +2 y = 6
____________________________________________________________________________
PARAGRAPH 2
Let Vr denotes the sum of 1st r terms of an arthimetic progression (A.P) whose first term
is r and the common difference is 2r1. Let Tr = Vr+1 Vr and Qr = Tr+1 Tr for r =
1,2,3
Q.19 The sum V1 + V2 + V3 Vn is

(A) (n+1)(3 n+1) (B) (n+1)(3 +n+1)
(D) (2 n+1) (D) (2 2n+3)
Q.20 Tr is always a/an

(A) odd number (B) even number (C) prime number (D) composite number
____________________________________________________________________________

JEE Advanced March 20 P2 EV1

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20 MARCH 2017: MAJOR TEST # 10 : JEE (ADVANCED) :PAPER 2

Name of Student: ____________________________Batch:_______ Contact no: ________________

Max Marks: 240 Time: 3 hours

READ THE INSTRUCTIONS CAREFULLY

QUESTION PAPER FORMAT AND MARKING SCHEME

SECTION 1 (Maximum Marks: 32)

This section contains EIGHT questions

This section contains EIGHT questions

9. The molar hear capacity for an ideal gas

Space for rough work

16. A cyclic process is shown on the p T diagram.

Which of the following curves show the same process?

Space for rough work

This section contains TWO paragraphs

Space for rough work

17. Choose the correct option(s)

Space for rough work

Space for rough work

SECTION 1 (Maximum Marks: 32)

This section contains EIGHT questions

1. Write the maximum number of atoms having same hybridisation in 2, 5-di-N-chloridothioimino-3, 4-

5. The bond order of CN-as well as NO+ has a value of?

8. How many structures have peroxy linkages in following list:

This section contains EIGHT questions

9. The correct expressions of an adiabatic process

(C) P1V1 = P2V2 (D) P1V11 = P2V21

11. Select the correct statement about FCC (ABCAB..) structure.

13. The standard enthalpy of formation of CO2 will be given by :

(A) dU 0 (B) q w (C) W = -314 J (D) W = 31.4 J

This section contains TWO paragraphs

H aq OH H2O l ; r H0 55.84 kJ / mol

(A) 55.84 kJ (B) 111.68 kJ (C) 55.84 kJ (D) 111.68 kJ

(A) 25 : 75 (B) 50 : 50 (C) 75 : 25 (D) 66.66 : 33.33

SECTION 1 (Maximum Marks: 32)

This section contains EIGHT questions

2 If A = ( ) , abc = 1, ATA = I, then find the value of a3 + b3 + c3.

3 The set of values of for which the circles x2 + y2 = 2 and x2 + y2 4x 4y + = 0

5 A tangent drawn to hyperbola the = 1 at P( ) forms a traingle of area 3a2 sq.

from the end is 1/6.

8 How many solutions of '' for equation 4 cos 2 = 7 4x + 4x2, where x R?

This section contains EIGHT questions

Q. 9 The number of distinct terms in the expansion, of (x + 2y 3z + 5w 7u)n is

(C) n + 4Cn (D)

Q. 10 The value of the expression

(C) ( ) n (D) None of these

(C) Foci is (1,1)&(1,3) (D) Directrices are y=23

Q. 15 The line y = mx + c touches the circle

This section contains TWO paragraphs

Q.17 A possible equation of L is

Q.18 A common tangent of the two circles is

Q.19 The sum V1 + V2 + V3 Vn is

(D) (2 n+1) (D) (2 2n+3)

Q.20 Tr is always a/an

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Name of Student: ________________________Batch:_ Contact no: ______________