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The profound changes in civil engineering over the last few decades were reflected by structural failures,
unprecedented performance limitations, increased cost of maintenance and a large number of deficient
structures.
Thisguideisdevelopedforstructuralspecialists,whohaveexpertiseintheassessmentfield,withcertain
experienceinreinforcementcorrosionproblems.Ithastobestressedthatacorrectassessingofastructure
sufferingrebarcorrosion,canonlyperformedbyamultidisciplinaryteamformedbycorrosionspecialists
andstructuralengineers.
QuantificationofcorrosiondamagetoR/Cstructuresisusuallyperformedviaanumberofinterdependent
variablescalledCorrosionDamageIndicators(CDIs),seeTablebelow.
CDIsareclassifiedintothreegroups(A,BandC)dependingontheirdirectorindirectconnectionto
reinforcementcorrosion.
GroupAcontainsCDIsbeingdirectlyrelatedtocorrosiondamage.CDIsbelongingintoGroupAare:
Finally,ithastoberememberedthatthisguidepresentsanapproachtotheassessmentofconcretestructures
affectedbyrebarcorrosionbasedintheexperienceandideasofagroupofspecialistsonbothfields,
structuralassessmentandcorrosionprocess,theresultsexpectedusingthisguidehavebeencheckedand
verifiedfortheirdevelopers.Thus,theprocedureheredescribedcanbeadaptedorchangedinordertofit
withintherequirementofassessingcodesineachcountryundertheresponsibilityoftheassessingspecialist.
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TheuseofCorrosionDamageIndicators( )providesaclassificationbetweendifferentlevelsandtypes
ofcorrosiondamage.Theschemeoftypesofdamagesandextensionofthemwillbenecessaryonassessing
theactualstateofthestructure.TheindexofCDIisconstitutedbyapoolofindicatorstobesurveyedand
weighted.Theindicatorsmostlyusedare:
ParameterA1alsoknownas ,representstheprobabilityofcorrosiondamagebeingdue
toconcretecarbonation.Sinceprobabilityofcarbonationisstronglyrelatedtoconcretecoverthickness,the
parameterA1isrepresentedasaratio.ParameterA1islimitedbetweenpH9.58.6.
ConcreteAlkalinitycanbemeasuredaccordingtoASTMF710.Typicalfieldmeasuringmethodsinclude:
digitaldevices,penciltyperainbowindicators,stickertyperainbowindicatorsandtheuseof
phenolphthaleinspaying.
likeallchemicals,phenolphthaleinsolutionshouldbetreatedwithrespect.Bothphenolphthalein
itselfandisopropylalcoholareharmfuland,sinceitcontainsalcohol,theindicatorsolutionisflammable.
Ingestion,orcontactwithskinoreyesshouldbeavoided,asshouldbreathingthevapour.Possibleeffects
onthehumanbodyincludekidneydamageandcancer.MSDS:PhenolphthaleinSolution1%,Catalog
Numbers:S71429,S71976,S76970,SP621,SP62500,SP621,SP62500.
Thephenolphthaleinindicatorsolutionisappliedtoafreshfracturesurfaceofconcrete.Iftheindicator
turnspurple,thepHisabove8.6.Wherethesolutionremainscolourless,thepHoftheconcreteisbelow
8.6,suggestingcarbonation.AfullycarbonatedpastehasapHofabout8.4.
Inpractice,apHof8.6mayonlygiveafaintlydiscernibleslightlypinkcolour.Astrong,immediate,colour
changetopurplesuggestsapHthatisratherhigher,perhapspH9or10.
Normalconcreteporesolutionissaturatedwithcalciumhydroxideandalsocontainssodiumandpotassium
hydroxide;thepHistypically1314.ConcretewithaporesolutionofpH1012islessalkalinethansound
concretebutwouldstillproduceastrongcolourchangewithphenolphthaleinindicator.Itthereforefollows
thattheindicatortestislikelytounderestimatethedepthtowhichcarbonationhasoccurred.
Priortoanymeasurement,itisimportanttoproperlycleantheconcretesamplewithrunningwaterto
preventdustfromthecoringprocesstoaffectthemeasurement.Thecorepriortotestingshallbeallowedto
dryforatleast15minutes.
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Measurementofconcretecoverisperformedviatheuseofcovermeters.Todaythereisalargevarietyof
availabledevices.Accuracyofmeasurementisusually 1mm.Covermetersareclassifiedasa)withrebar
diameterdetectionandb)withoutrebardiameterdetection.
CovermetersarecoveredbyseveralstandardslikeBS1881Part204,DIN1045,SN505262,DGZfPB2,
etc.
Covermeterswithrebardiameterdetectionability
Covermeterswithoutrebardiameterdetectionability
Inordertoobtainstatisticallycorrectmeasurementsitisimperativetoconsiderthatbothcoverthickness
andcarbonationdepthfollowanormalprobabilitydensityfunction.Therecommendedminimumpopulation
ofmeasurementsshallbe6perstructuralmemberpereveryoftotalheight/length.Itisimperativeto
rememberthatcorrosioninitiationwilltakeplacefirstlyatstirrups.
Theredarrowsindicatethecoverthickness.
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AtypicalexampleinevaluatingtheparameterA1isshownbelow
Turningofthedataintocumulativeprobabilityplotsrevealsthatthereisnoprobabilityofcarbonation
exceedingthecoverthickness.
InthiscasewecanclassifyanddeterminetheCarbonationindexviatheratio AverageConcreteDepthwith
pH8.69.5/AverageCoverThickness.InthisexampletheratioA1is .Hence,theseverityclassforthe
memberis andthe Carbonationindexweightis .
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Inseveralcaseshowever,thedeterminationofCarbonationIndexcanbepuzzling.Thefollowingexample
representssuchcase
Turningofthedataintoprobabilitydensityplotsrevealsthatthereisapotentialofcarbonationexceeding
coverthickness.
SuchdiscrepanciesarecoveredbylimitsprovidedbytheCarbonationindexclassification.Herein,thelimit
of>0.7representssuchcase.
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AverageConcreteDepthwithpH<7.08.6/AverageCover
Thickness
ParameterA2alsoknownas representstheprobabilityofcorrosion
damagebeingduetochemicalattack.ChemicalAttackClassIIndexreferstolowandmedium
aggressiveness.RefertoACI201.2R08.ConcreteAlkalinitycanbemeasuredaccordingtoASTMF710.
Typicalfieldmeasuringmethodsinclude:digitaldevices,pencilandstickertyperainbowindicators.
Identificationofthechemicalresponsiblefortheattackitisanimportantparameter,signifyingdamagerate
andpotentialadditionalharmfuleffects,i.e.disintegrationofconcrete,gypsumexpansion,etc.Typical
chemicalsandtheireffectsaredepictedbelow(ACI5151R).
Inallcasesitisimperativethattensiletestonrepresentativereinforcementisperformed
accordingtoASTMA370.Chemicalanalysisofconcreteisalsorecommended.Notethatcertain
chemicalsmightfurtherdecreasepHwithexposuretime.
Priortoanymeasurement,itisimportanttoproperlycleantheconcretesamplewithrunningwaterto
preventdustfromthecoringprocesstoaffectthemeasurement.Thecorepriortotestingshallbeallowedto
dryforatleast15minutes.
Measurementofconcretecoverisperformedviatheuseofcovermetersasshowninprevioussection.In
caseofcrackedconcreteandindependentlytocrackwidth,severityclass4shallbeselected.
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AverageConcreteDepthwithpH<7.0/AverageCover
Thickness
ParameterA3alsoknownas representstheprobabilityofcorrosion
damagebeingduetochemicalattack.ChemicalAttackClassIIIndexreferstomediumandhigh
aggressiveness.RefertoACI201.2R08.ConcreteAlkalinitycanbemeasuredaccordingtoASTMF710.
Typicalfieldmeasuringmethodsinclude:digitaldevices,pencilandstickertyperainbowindicators.
Identificationofthechemicalresponsiblefortheattackitisanimportantparameter,signifyingdamagerate
andpotentialadditionalharmfuleffects,i.e.disintegrationofconcrete,gypsumexpansion,etc.Typical
chemicalsandtheireffectsaredepictedinSection2.2.
Inallcasesitisimperativethattensiletestonrepresentativereinforcementisperformed
accordingtoASTMA370.Chemicalanalysisofconcreteisimperative.Specialattentionshallbegivento
thepotentialdecreaseofconcretestrength.Inmanycasescoringshallnotrevealtheextentofdamagesince
partialdepthdisintegrationmightnotregisteredinfullunless.Whencoringistheonlyavailableoptionpay
particularattentiontothetypeofcorefailure,i.e.crushingandcrumblingaccordingtoACI214.4R03
(seefollowingimage).Concretestrengthdegradationisbetterevaluatedusingsignalprocessingon
UltrasonicPulsingorImpactEchooutputs.Payparticularattentiontoamplitudevstimesignal.Thereisa
largevarietyofsignalprocessingalgorithmsthatcanbeused.
NotethatcertainchemicalsmightfurtherdecreasepHwithexposuretime.
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TypicalUltrasonicPulsingandEchopulsedevicesaredepictedbelow
TypicalUltrasonicPulsingequipmentandsignalanalysis
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TypicalEchoPulseequipment
Alwaysdemandfromthelaboratoryperformingthetensiletestonreinforcementtomakeuse
ofcliptypeLongGaugeLengthExtensometers.Knifetypeextensometersshallnotbeusedoncorroded
specimens.Completelyavoidmeasurementsviagripdisplacement.
TypicalcliptypeLongGaugeLengthExtensometer
Thecorrespondingindexandweightsaregivenbelow.
TheassessmentreportshallclearlyindicatethelimitsprovidedbyNationalregulationson
steelreinforcementproperties.ChemicalattackClassIIisextremelycriticalandinmostcasescallsfor
immediateterminationoftheCDIprocedureforseverityclass>3.Weldingtoexistingrebar,asarecovery
measure,isofcoursenotpermittedapartfromthecaseoftemporaryreplacementduringsteelsampling.
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ConcreteElectricalResistanceIndex
Concreteelectricalresistance(frequentlyreferredasWennerArray)representsaindirectmethodfor
examiningthepotentialofreinforcementcorrosionandmoisturecontent.
Theelectrolyticresistivityofconcreteessentiallydependsonthechemicalcompositionoftheporesolution
andtheporestructure(concretecomposition,compactionandcuring)aswellastheconcretemoistureand
temperature.Thebuildingmaterialconcretecanactaseitheraninsulatororagoodelectricalconductor
withrespecttoitselectricalpropertiesdependingonitsmoisturecontent.Adenseaggregatenormallyacts
asaninsulatoronaccountofitsveryhighresistivity,e.g.quartz10141016Wm.Theconductivityof
hardenedcementpasteisdeterminednotonlybythepropertiesoftheporesolution,butalsotoalarge
extentbytheporestructure.
Figure1.IonicConductionofhardenedcementpaste.
Thehardenedcementpastecanbeclassifiedintocementgel,openpores(e.g.capillarypores),closedpores
anddeadendpores.Theporesolutioncontainsbothpositiveandnegativeions(essentiallyNa+,K+,
Mg++,Ca++,OH,Cl,SO4)thataredistributedevenlywithinthehardenedcementpastewithoutbeing
affectedbyexternalcurrents.Thepositiveions(cations)movetothecathodeandthenegativeions(anions)
totheanodewhenanelectricfieldisappliedoverviatwoelectrodes.Thechargecarriersintheclosed
poresordeadendsareblockedandactascondenserswithoutaffectingtheohmicresistanceoftheconcrete.
Ionicconductiongenerallytakesplaceviatheliquidphaseoftheporesolutionofthecementpasteinwater
saturatedconcrete.Withsemimoistconcretestheionicconductiontakesplaceviathemonomolecular
waterfilmadsorbedontheporewalls.Theconcreteactsasaninsulatorwhenitbecomesverydry,the
conductivitydropstolowervalues.
Apartfromthemoisturecontentoftheconcrete,theresistivityalsodependsontheporestructure,which
dependsontheconcretetechnologyinfluencingparameterse.g.w/cratio,cementtype.Thegrinding
additiveschangethechemicalandphysicalpropertiesofthehardenedcementpastsandthusitselectrolytic
conductivity.
Athighageblastfurnaceslagcementshaveahighercontentofchemicallybondedwaterandahigher
contentofgelporesintheoverallgelporevolumethanPortlandcements.Bothpropertiesleadtoan
increasedresistivity.
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Overthepastfewyears,coalflyashhasincreasinglybeenusedasaconcreteadditiveinconcrete
constructionwork.Coalflyashesareanindustrialbyproductfromthegenerationofelectricalenergyin
coalpowerstationsandareclassifiedassyntheticpozzolans.Theeffectofflyashadditivesonthe
resistivityofhardenedconcreteunderliesinthereductionofthecapillaryporecontentthroughthe
pozzolanicreactionofflyashincementandtheassociatedrestrictionoftheionicconduction.The
resistivityofhardenedcementpastewithflyashis3to4timeshigherthanthatofhardenedcementpaste
withonlyPortlandcementunderthesameconditions.
Around2840%ofthecement'sweightinwaterisneededforacompletehydrationofthecement.Ifthe
cementpastecontainsahighercontentofwater,theexcesswaterisdistributedasfreewaterorcapillary
waterintheconcrete.Forwatersaturatedormoistconcretethecapillaryporosityandcapillarywater
contentincreasesandthustheresistivitydecreases.Atypicalrelationshipbetweenresistivityandwater
contentisshowninFigure2.
Figure2.Experimentaldataontherelationshipbetweenwatercontentandresistivity.
Carbonationleadstoareductionincapillaryporesystembecausethevolumeofthereactionproduct(CaC03)exceeds
thatoftheoriginalreactants.Assuchresistivitywillincrease.Valuesashighas150KOhmcmhavebeenreportedin
dullycarbonatedconcrete. Fornoncarbonatedconcrete,theeffectofthepenetrationofchlorideions
ontheresistivityisrelativelysmall.Temperatureisinverselyproportionaltoresistivity,Figure3.
Itisimperativepriortomeasurementtoknowthemoisturecontentandtemperatureofthe
surface.Theinspectionengineershallthendecidewhethermoisturecontentispermanentorseasonal.In
generalavoidmeasuringunderdirectsunexposure.
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Figure3.Concreteresistivityandtemperature
Measurementsareusuallyperformedusingthefourelectrodesetup(WennerArray).Fourequallyspaced
pointelectrodesthatarepressedontotheconcretesurface.Thetwoouterpointelectrodesinducethe
measuringcurrent(usuallyACwithafrequencybetween50and1000Hz,normallysinusoidal)andthetwo
innerelectrodesmeasuretheresultingpotentialdropintheelectricfield.
Theresistance,R,measuredisconvertedtoresistivity,,usingacellconstantbasedontheoretical
considerationsby:
=2aRwhereatheelectrodespacing.
Figure4.WennerArray
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Thecorrosioncurrentdensity,Icorrisapproximatelyinverselyproportionaltotheelectrolyteresistanceand
theresistivityrespectivelyordirectlyproportionaltotheconductivityaccordingtothefollowingequation:
Figure5showssuchpotentialconnection.
Figure5.Connectionbetweencorrosioncurrentdensityandconcreteresistivity.
However,concreteresistivityandIcorrshouldnotbeusedforquantification(seeASTM176012).
Standardscoveringresistivityare AASHTOT259,ASTMC1202.Classificationbetweenresistivityand
corrosionriskisshownbelow
or
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ThecorrespondingConcreteElectricalResistivityindexandweightsaregivenbelow.
TypicalWennerarraydevicesaredepictedbelow
Followtheprewettingprocedurewithparticularcare.Excessivewateringcouldaffect
measurements.Avoidplacingtheprobesoverrebar.Insomecasesstabilisationofthereadingcanbe
problematic.Allowsufficienttime.
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SaturatedCalomelElectrodeSCEHALFCELLIndex
Whenthereisactivecorrosion,currentflow(intheformofionmigration)throughtheconcretebetween
anodicandcathodicsitesisaccompaniedbyanelectricpotentialfieldsurroundingthecorrodingbar,Figure
1.Theequipotentiallinesintersectthesurfaceoftheconcreteandthepotentialatanypointcanbe
measuredusingthe Bymappingequipotentialcontoursonthesurface,those
portionsofthestructurewherethereisahighlikelihoodofcorrosionactivityareidentifiedbytheirhigh
negativepotentials
ApparatusforhalfcellpotentialmethoddescribedinASTMC87621tomeasuresurface
potentialassociatedwithcorrosioncurrent.
ThestandardtestmethodisgiveninASTMC876.Theapparatusincludesacoppercoppersulfatehalf
cell,connectingwires,andahighimpedancevoltmeter.Thishalfcelliscomposedofacopperbar
immersedinasaturatedcoppersulfatesolution.Itisoneofmanyhalfcellsthatcanbeusedasareferenceto
measuretheelectricalpotentialofembeddedbars.Themeasuredvoltagedependsonthetypeofhalfcell,
andconversionfactorsareavailabletoconvertreadingsobtainedwithotherreferencescellstothecopper
coppersulfatehalfcell.Thepositiveterminalofthevoltmeterisattachedtothereinforcementandthe
negativeterminalisattachedtothecoppercoppersulfatehalfcell.Ahighimpedancevoltmeter(normally
greaterthan10M)isusedsothatthereisverylittlecurrentthroughthecircuit.
hecoppercoppersulfatehalfcellmakeselectricalcontactwiththeconcretebymeansofaporousplug
andaspongethatismoistenedwithawettingsolution(suchasliquiddetergent).Ifthebarwerecorroding,
theexcesselectronsinthebarwouldtendtoflowfromthebartothehalfcell.Becauseofthewaythe
terminalsofthevoltmeterareconnectedintheelectricalcircuitshowninFigure1,thevoltmeterindicatesa
negativevoltage.
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Themeasuredhalfcellpotentialiscalledthe ,becauseitismeasuredunderthe
conditionofnocurrentinthemeasuringcircuit.Amorenegativevoltagereadingatthesurfaceis
interpretedtomeanthattheembeddedbarhasmoreexcesselectrons,andthereis,therefore,ahigher
likelihoodthatthebariscorroding.
Thehalfcellpotentialreadingsareindicativeoftheprobabilityofcorrosionactivityofthereinforcing
steellocatedbeneaththecoppercoppersulfatereferencecell.However,thisistrueonlyifthatreinforcing
steeliselectricallyconnectedtothebarattachedtothevoltmeter.Toassurethatthisconditionexists,
electricalresistancemeasurementsbetweenwidelyseparatedreinforcingbarsshouldbecarriedout.
Testingisusuallyperformedatpointsarrangedinagrid.Therequiredspacingbetweentestpointsdepends
ontheparticularstructure.Excessivespacingcanmisspointsofactivityorprovideinsufficientdatafor
properevaluation,whilecloserspacingincreasethecostofthesurvey.Insurveyingbridgedecks,ASTMC
876recommendsaspacingof1.2m.AtypicalhalfcellpotentialmapisshowninFigure2.
Ifthedifferencesinvoltagesbetweenadjacentpointsexceed150mV,acloserspacingis
suggested.Reliabledifferenceinvoltagesbetweenadjacentpointsishighlyrecommendednottoexceed50
mV.
Prewettingisusuallynecessary.Thereshouldbenofreesurfacewaterbetweentestpointsatthetimeof
potentialmeasurement.Theconcreteissufficientlymoistifthemeasuredpotentialatatestpointdoesnot
changebymorethan 20mVwithina5minperiod.
Ifstabilitycannotbeachievedbyprewetting,itmaybebecauseofstrayelectricalcurrentsor
excessiveelectricalresistanceinthecircuit.Ineithercase,thehalfcellpotentialmethodshouldnotbeused.
Equipotentialmapofasection1.5x1.5meters.Spacingbetweenmeasurements0.2meters.
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AccordingtoASTMC876,twotechniquescanbeusedtoevaluatetheresults:(1)the technique
(equipotential)or(2)the etechnique.Inthenumerictechnique,thevalueofthepotential
isusedasanindicatorofthelikelihoodofcorrosionactivity.TheappendixofASTMC876givesthefollowing
guidelines(forthecoppercoppersulfatereferenceelectrode)forthenumerictechnique:
Ifthepotentialismorepositivethan200mV(relativetothecoppercoppersulfatehalfcell),thereisa
highlikelihoodthatnocorrosionisoccurringatthetimeofthemeasurement.
Ifthepotentialismorenegativethan350mV,thereisahighlikelihoodthatthereisactivecorrosion.
Corrosionactivityisuncertainwhenthevoltageisintherangeof200to350mV.
Inthepotentialdifferencetechnique,theareasofactivecorrosionareidentifiedonthebasisofthepotential
gradients.Intheequipotentialcontourplot,theclosespacingofthevoltagecontoursindicatesregionsof
highgradients.Somepractitionersusethechangeinpotentialoveragivensurfaceareaasanindicatorof
activecorrosion( etechnique),suchasachangegreaterthan100mVover5square
meters.Itisgenerallyacceptedthatthepotentialdifferencetechniqueismorereliableforidentifying
regionsofactivecorrosionthanistheuseofnumericallimits.
Ashasbeenstated,validpotentialreadingscanbeobtainedonlyiftheconcreteissufficientlymoist,and
theusermustunderstandhowtorecognizewhenthereisinsufficientmoistureforameaningful
measurement.Inaddition,thereareseveralfactorsthatcanaffectthemagnitudeofthepotentialssothat
theyarenotindicativeofthetruecorrosionconditions.Coverthicknesswillnormallyexhibitalower
potentialvalueasshowninFigure3.
Effectofconcretecoverthicknessonthedepthofpotentialfieldabovealocalanode
Forexample,asurfacelayerwithhighresistanceresultsinlessnegativesurfacepotentials;thiscanmask
underlyingcorrosionactivity.Ontheotherhand,cathodicpolarizationduetothelackofoxygenresultsin
morenegativepotentialswhiletheactualcorrosionrateisreduced.
Halfcellreadingscanbepuzzlinginthefollowingcases,
Carbonationextendstothelevelofthereinforcement
Comparisonofcorrosionactivityinoutdoorconcretewithhighlyvariablemoistureoroxygencontent
Toformulateconclusionsaboutchangesincorrosionactivityduetorepairswhichchangedthemoisture
oroxygencontentatthelevelofthesteel.Cementpolymermodifiedrepairgroutshavethetendencyto
hidecorrosionactivity.
TypicaldevicesfortheequipotentialtechniqueareshowninFigure4.
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TypicalcommercialHalfCellequipment.
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CorrosionCurrentDensityLinearPolarisationResistance(A/cm2)Index
Thepolarizationresistancetechniqueisawellestablishedmethodfordeterminingcorrosionrateby
usingelectrolytictestcells(ASTMG59).Thetechniquebasicallyinvolvesmeasuringthechangeinthe
opencircuitpotentialoftheshortcircuitedelectrolyticcellwhenanexternalcurrentisappliedtothecell.
Forasmallperturbationabouttheopencircuitpotential,thereisalinearrelationshipbetweenthechangein
voltage, ,andthechangeinappliedcurrent ofelectrodes, .Thisratioiscalledthe
, :
Becausethecurrentisexpressedperunitareaofelectrodethatispolarized,theunitsof areohmstimes
area.Ithasbeenpointedoutthat isnotatrueresistanceintheusualsenseoftheword,butthetermis
widelyused(ASTMG15). establishedtheunderlyingrelationshipsbetweenthecorrosion
rateoftheanodeandthepolarizationresistanceisknownasSternandGearyequation.Noattemptismade
toexplaintheserelationshipsotherthantostatethattheyarederivedfromtheslopesoftheanodicand
cathodicpolarizationcurves(refertoFigure1). Thecorrosionrate(expressedascorrosioncurrentdensity,
i.e.,currentperunitarea)isinverselyrelatedtothepolarizationresistance(ASTMG59):
Theconstant isacharacteristicofthepolarizationcurvesandavaluebetween2652mViscommonly
usedforsteelthatisactivelycorrodinginconcrete.
Thisbasicconfigurationisoftenreferredtoasa3LPdevice,becauseitinvolvesthreeelectrodes,Figure
2.Oneelectrodeiscomposedofareferencehalfcell,andthereinforcementisasecondelectrodecalledthe
.Thethirdelectrodeiscalledthe ,anditsuppliesthepolarizationcurrent
tothebar.Supplementaryinstrumentationmeasuresthevoltagesandcurrentsduringdifferentstagesofthe
test.Suchadevicecanbeoperatedinthe mode,inwhichthecurrentisvariedtomaintain
constantpotentialoftheworkingelectrode;oritcanbeoperatedinthe mode,inwhichthe
potentialisvariedtomaintainconstantcurrentfromthecounterelectrodetotheworkingelectrode.
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Polarizationcurvesforshortcircuitedelectrolyticcellshowingstablecellpotentialandcorrosion
current.
Asummaryofthemainstepsforusingthe3LPdevicetomeasurepolarizationresistanceinthepotentiostatic
modeisasfollows:
Makeanelectricalconnectiontothereinforcement(theworkingelectrode).
Locatethebarwhosecorrosionrateistobemeasured,wettheconcretesurface,andlocatethe
deviceoverthecenterofthebar.
Measuretheopencircuitpotential, ofthereinforcementrelativetothereferenceelectrode,i.e.,
measurethehalfcellpotential(Figure2A).
Measurethecurrentfromthecounterelectrodetotheworkingelectrodethatisnecessaryto
producea4mVchangeinthepotentialoftheworkingelectrode(Figure2B).
Repeatthepreviousstepfordifferentvaluesofpotential,namely,8,and12mVbeyondthe
corrosionpotential.
Calculatetheareaofbarthatisaffectedbythemeasurement.
Plotthepotentialvs.thecurrentperunitareaofthebar,anddeterminetheslopeofthebestfit
straightline.Thisisthepolarizationresistance.
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Threeelectrode,linearpolarizationmethodtomeasurecorrosioncurrent.
Anuncertaintyinobtainingthepolarizationresistancebytheaboveprocedureistheareaofthesteel
barthatisaffectedbythecurrentfromthecounterelectrode.Intheapplicationofthe3LPdevice,itis
assumedthatcurrentflowsinstraightlinesperpendiculartothebar(workingelectrode)andthecounter
electrode.Thus,theaffectedbarareaistakenasthebarcircumferencemultipliedbythelengthofthe
barbelowthecounterelectrode.Numericalsimulationsofcurrentflow,however,showthattheabove
assumptionisincorrectandthatthecurrentlinesarenotconfinedtotheregiondirectlybelowthe
counterelectrode.Inanefforttobettercontrolthecurrentpathfromthecounterelectrodetothe
bar,adevicehasbeendevelopedthatincludesafourthelectrode,calleda or ,
thatsurroundsthecounterelectrode,Figure3.Theguardelectrodeismaintainedatthesamepotentialasthe
counterelectrode.Asaresult,thecurrentflowingfromthecounterelectrodetotheworkingelectrodeis
confinedtotheregionbelowthecounterelectrodeandthenonuniformlateralspreadingofthecurrentis
reduced.
Linearpolarizationtechniqueusingguardelectrodetoconfinethecurrentfromcounterelectrode
toreinforcement.
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ThecorrosionrateCRmeasuredusingpolarizationresistancerepresentstherateatthetimeofthetest.A
simplifiedrelationshipbetweencorrosioncurrentdensity(A/cm 2)andcorrosionrate(m/year)isgiven
by,
CR=11.6Icorr
Thecorrosionrateataparticularpointinastructureisexpectedtodependonseveralfactors,suchasthe
moisturecontentoftheconcrete,theavailabilityofoxygen,andthetemperature,Figure4.Thus,the
corrosionrateatanypointinanexposedstructurewouldbeexpectedtohaveseasonalvariations.Such
variationswereobservedduringmultiplemeasurementsthatextendedoveraperiodofmorethan1year.To
projecttheamountofcorrosionthatwouldoccurafteranextendedperiod,itisnecessarytorepeatthe
corrosionratemeasurementsatdifferenttimesoftheyear.
Severalalternativescouldbeusedtocounteracttheseasonaleffectandpredictthefutureconditionofthe
reinforcement:
Usethemaximummeasuredcorrosionratestoobtainaconservativeestimateofremaininglife.
Usetheyearlyaveragecorrosionrateatatypicalortheworstlocationinthestructure.
Usetheminimumandmaximumcorrosionratestoestimatetherangeofremaininglife.
Effectoftemperatureoncorrosionrate.
Asemiempiricalequation(Figure4)relatingnormalisedcorrosionratetotemperatureis
WhereFisthecorrosionrateinm/year.
Measurethetemperatureofconcreteontheareaperformingpolarisationresistancepriortotesting.
Itisimperativethatallmeasurementsareperformedonareasexhibitingtemperaturedifferenceofnomore
than10 oC.
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Thereareotherlimitationsthatshouldbeconsideredwhenplanningcorrosionratetesting.Someofthese
havebeenoutlinedinaproposedtestmethodandareasfollows:
Theconcretesurfacehastobesmooth(notcracked,scarred,oruneven).
Theconcretesurfacehastobefreeofwaterimpermeablecoatingsoroverlays.
Thecoverdepthhastobelessthan100mm.
Thereinforcingsteelcannotbeepoxycoatedorgalvanized.
Thesteeltobemonitoredhastobeindirectcontactwiththeconcrete.
Thereinforcementisnotcathodically(impressedcurrent)protected.
Thereinforcedconcreteisnotnearareasofstrayelectriccurrentsorstrongmagneticfields.
Theambienttemperatureisbetween5Cand40C.
Theconcretesurfaceatthetestlocationmustbefreeofvisiblemoisture.
Testlocationsmustnotbecloserthan300mmtodiscontinuities,suchasedgesandjoints.
Atypicallimitingclassificationofcurrentdensityare,
Icorr=0.1Acm 2Passivecondition(noncorrodingreinforcement)
Icorr=0.10.5Acm 2Lowtomoderatecorrosion
Icorr=0.51.0Acm 2Moderatetohighcorrosion
Icorr>1.0Acm 2 Hightoveryhighcorrosion
Changesinthefactorsthataffectcorrosionrate,suchastemperature,concreteresistivity,and
oxygenavailability,willchangethecorrosionrate.Thus,itisdifficulttoextrapolateservicelifebasedon
onemeasurement.
Typicalcommercialavailabledevicesforpolarisationresistanceareshownbelow
Typicalcommercialdevicesforpolarisationresistance.
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SeverityClass1 SeverityClass2 SeverityClass3 SeverityClass4
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ConcreteMeanStrengthIndex
ConcreteMeanStrengthdoesnotplayavitalroleincontrollingtherateofactivecorrosion.TheroleofCS
isindirecttocorrosioninitiation.Highstrengthconcretewillgenerallyexhibitlowercarbonationrateand
willprovidehigherresistancetochlorideingress,Figure1.Ingeneralwecanassumethatconcretestrength
willincreasethetimetocorrosioninitiationifnoothermeansforprotection,i.e.coatings,areinplace.
Concretestrengthhoweverwillcontrolbondrigidityandconsequentlytheratethatbondisdecreasingwith
corrosionrate,Figure2.
Effectofconcretestrengthoncarbonationrate.
Effectofconcretestrengthonbondrigidity.
Concretestrengthisevaluatedbyeitherdirectorindirectmethods(NDE).Coringbelongstodirectmethods.
Coringhoweverduetoitslimitedsampling,cannotprovidearepresentativestrengthvariation
butaratherindicativeone.ASTMC42,ASTM617,BS1881,ASTMC1231,ACI2144Rand
EN13791provideacomprehensivereviewontheissueofconcretestrengthviacoring.
Page31
Figure3showsatypicalcoringfortheevaluationofinplaceconcrete.
Concretecoring.Thewhitemarkingsrepresentsteelreinforcementlocation.
Nondestructivetesting(NDT)shallbeimplementedintoconcretestrengthevaluationprimarilyasa
parameterindicatingvariabilityandlackofuniformity.ThemainNDTmethodscurrentlyusedare,
SpringandPendulumSchmidtHammeringdevices.
Page32
Readingstakenfromthe SchmidtHammerundercertaincircumstancescanbetransformedintoconcrete
Strengthusingcorrelationtablesordiagrams,Figure5.
TypicalreboundnumberRtoconcretestrengthcorrelationchart.
Ifcarbonationdepthexceeds20mm,springtypeSchmidtHammerisknowntoproduceover
estimationonstrengthofmorethan45%.Carbonationshallbemeasuredasdescribedin
Ifthestructuralelementunderinvestigationshowsevidenceofpoorconstruction,Figure6,
selectconcretestrengthequaltozero.Crackingshallnotbeconsideredinthisindex.
Typicalpoorconstructionexample.
Page33
Whenthesurfaceofasemiinfinitesolidisexcitedbyatimevaryingmechanicalforce,energyisradiated
fromthesourceasthreedistincttypesofelasticwavepropagation.Thefastestofthesewaveshasparticle
displacementsinthedirectionoftravelofthedisturbanceandiscalledthelongitudinal,compressionorP
wave.ThecompressionwavevelocityVpisafunctionofthedynamicYoungsmodulusE,thePoissons
ratiov,andthemassdensitypandisgivenby:
Itisclearfromtheaboveequationthatvelocityisindependentofgeometryofmaterialanddependsonlyon
elasticpropertiesofthematerialthroughwhichitpasses.Hencetheprincipleofassessingqualityof
concreteisthatcomparativelyhighervelocitiesareobtainedwhenthequalityofconcreteintermsof
density,homogeneityanduniformityisgood.Incaseofpoorerquality,lowervelocitiesareobtained(Figure
7).
IndicativeUPVvaluesandconcretequality.
SeveralmodelsexistcorrelatingUPVtoconcretestrength,Figure8.
IndicativecorrelationcurvesbetweenUPVvaluesandconcretestrengthfromvarious
authors.
Page34
TypicalUltrasonicPulsingdevicesaredepictedbelow
Itisimperativetonotethatinconcretestrengthindexwealwaysusethelowestobtainedvalue
permemberindependentlytodeterminationmethodused.
OthermethodslikeWinsdorProbearenotcoveredbyinternationalstandardsandhencearenotexplained
here.
Page35
ConcreteMoistureContentIndex
ConcreteMoistureContentrepresentsacrucialparameterincontrollingtherateofactivecorrosion.
TheroleofCSisindirecttocorrosioninitiation.Highstrengthconcretewillgenerallyexhibitlower
carbonationrateandwillprovidehigherresistancetochlorideingress,Figure1.Ingeneralwecanassume
thatconcretestrengthwillincreasethetimetocorrosioninitiationifnoothermeansforprotection,i.e.
coatings,areinplace.
Concretestrengthhoweverwillcontrolbondrigidityandconsequentlytheratethatbondisdecreasingwith
corrosionrate,Figure2.
Effectofconcretestrengthoncarbonationrate.
Effectofconcretestrengthonbondrigidity.
Concretestrengthisevaluatedbyeitherdirectorindirectmethods(NDE).Coringbelongstodirectmethods.
Coringhoweverduetoitslimitedsampling,cannotprovidearepresentativestrengthvariationbutarather
Page36
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