Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
PVP2008-61627
1
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
Natural gas vapor conversion to a liquid cryogenic and non-cryogenic heat transfer
is handled via numerous liquefaction applications including the above mentioned LNG
technologies present on the market today. These as well as industrial gas production,
include open art technologies such as an petrochemical and hydrocarbon processing, and
expander process or patented process hydrogen and helium liquefaction. Due to their
technologies such as through a mixed refrigerant inherently high surface area compactness and
process like the PRICO technology. In these superior heat transfer capabilities, they can be a
processes, natural gas is transitioned to its liquid cost effective solution for processing of non-
state allowing it then become known as LNG. corrosive liquids and gases when compared to
LNG is then able to be stored in tanks or other traditional heat transfer technology.
transported worldwide via ships to LNG loading BAHX are manufactured as an all
terminals, for example, in order to provide brazed and welded pressure vessel with no
additional make-up supply when the demand mechanical joints. The BAHX core matrix
increases. Then when the demand increases, the consists of three main components: fins, bars,
LNG is vaporized to its gaseous state to provide and parting sheets. The core block is configured
the additional supply desired. in alternating layers of corrugated fins which act
Brazed Aluminum Heat Exchangers as flow paths for individual streams. The layers
(BAHX) are commonly used exchangers for heat are separated by a parting sheet which acts as the
transfer equipment in these liquefied natural gas primary heat transfer surface. Each layer is
(LNG) services. These exchangers are designed sealed around the edges with a solid bar. An
in accordance with major pressure vessel codes exploded view of a layer is seen in Figure 1.
throughout the world. ASME Code stamped
BAHX meet the mechanical design, materials,
fabrication, testing, and inspection requirements
of various ASME Codes [1-4]. Further details
and requirements can be found by referencing
these documents.
Liquefaction of natural gas is a
cryogenic operation in order to condense the
methane gas to a liquid state. Operating in
cryogenic applications is just one instance of
added value for utilization of BAHX to provide
the heat transfer in these plant facilities. BAHX
are an ideal fit for this use and have many
advantages for their use as a result of being able
to be designed for minimal approach Figure 1 - Illustration of Typical BAHX Layer
temperatures as well as lower log mean
temperature differences (LMTD) than other A wide range of fin patterns (plain,
exchanger types. These parameters are key to perforated, herringbone, and serrated)
the LNG plants refrigeration capacity which accommodate different thermal and hydraulic
translates into energy loads. Details follow process requirements enabling the exchanger to
regarding the background on BAHX and their be custom designed for an infinite number of
components as well as design considerations, processes. Several fin designs are shown in
materials of construction, maintenance, and other Figure 2. Following design and stacking of the
mechanical aspects will be illustrated that core block, the matrix is vacuum brazed in a
ultimately result in a safe and reliable means for large vacuum furnace, resulting in an integral,
transferring heat through these types of rigid heat exchanger block. Heat exchanger
exchangers. block sizes can be manufactured in excess of
4W x 5D x 25H. Header assemblies and
DISCUSSION BAHX Definition and supports welded to the brazed matrix complete
Components the unit as shown in Figure 3. Design variations
Brazed aluminum heat exchangers in the configuration of the heat exchanger matrix
(BAHX) are highly efficient, custom designed can accommodate an almost unlimited range of
compact heat transfer devices that offer distinct flow options, including counter flow, cross flow,
advantages over alternative heat exchange parallel flow, multi-pass, and multi-stream
methods. They are used for a variety of
2
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
formats. Detail design aspects are discussed
later.
3
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
exchanger to the external piping which may be
stainless or carbon steel for example. Refer to
the Manufacturing section below for additional
details.
4
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
Condensers, Feed Gas Exchangers and Product Additionally, fluids must not be
Coolers for example. corrosive to aluminum. Such corrosive fluids are
Brazed aluminum plate fin heat mercury and caustic. There are exceptions,
exchangers offer optimized heat transfer fin however, for trace amounts of mercury. Brazed
designs, advanced brazing technologies, quality aluminum equipment from a recognized industry
ensured manufacturing processes and a leader in technology innovation is often designed
continuous improvement program. Additional with mercury tolerance in mind. Although
benefits and design consideration advantages of mercury is highly corrosive to some alloys of
BAHX include close temperature approaches aluminum, design options are available that are
(1C / 2F) and lower MTD capabilities mercury-tolerant whereby the exchanger can
compared to other exchanger types [5]. BAHX operate with mercury present in the process fluid
also offer a design capable of various flow while the equipment is able to resist corrosion.
options and a unique ability to exchange heat Mechanical design of brazed aluminum
with multiple streams (10 or more process heat exchangers must meet the requirements of
streams are possible) making the design and unit the governing pressure vessel code, such as
extremely flexible from a process vantage point. ASME Section VIII, Division 1. Because of the
The multi-stream capabilities of products like unique configuration of the exchangers,
this simplify multiple shell-and-tube limited straightforward calculations can not be done for
stream configurations into a single compact all of their components. The fins must be
brazed aluminum unit which saves significant designed to resist pressure loadings, but there are
plot space and plant footprint. Brazed no standard design formulae for fins in the
Aluminum Heat Exchangers are typically twenty codes. Manufacturers have calculation methods
percent (20%) the size of comparable for fins, but much of the fin selection is based on
performance carbon or stainless steel shell-and- burst test results, as provided for in UG-101 of
tube exchangers and are ten percent (10%) of the ASME Section VIII, Division 1. Representative
weight. Together, these advantages can result in brazed samples are pressurized up to bursting,
installation and operating cost savings with and a safety factor defined by the code is applied
lower compression horsepower requirements and to determine the maximum design pressure for
increased plant output. These compact heat each fin design. Some components of the
exchangers can also reduce engineering, exchangers can use the standard formulae from
insulation, support systems, testing, the code, such as header and nozzle thicknesses
documentation, transportation and site and opening reinforcement.
arrangements. In addition, BAHX enable plant Each brazed aluminum heat exchanger
managers to reduce on site liquid inventory and is pressure tested, with either a hydrostatic test or
improve plant safety. pneumatic test in accordance with Code
Aluminum plate fin exchangers can be requirements. In addition, a leak test is done to
implemented in a variety of applications. With ensure that there are no leaks from one chamber
design temperature capability for aluminum to another.
ranging from +150 F to -452 F which is near Thermal or pressure cycling is not
absolute zero, and design pressure capability common for BAHX, but if it is expected a
ranging from full vacuum to over 2300 psig, fatigue evaluation should be done. It is best to
combined with multi-stream capability, BAHX is limit the maximum normal stress to be below the
especially well suited for LNG applications endurance limit of the materials, but fatigue life
where liquefaction occurs at cryogenic can be predicted using S-N curves obtained from
temperatures and at various pressures with a experimental data and stresses calculated by
better benefit occurring at higher pressures [5]. finite element analysis [6-10].
Its important to consider application limits for
BAHX. Applications are limited to clean fluids LNG Liquefaction Specific Design
typical of hydrocarbon processing. No heavy Concerns/ Considerations
particulate matter can be present in the fluid due
to the very small passageways inherent to the Several specific design considerations
construction. Fluids should always be filtered discussed above need to be considered carefully
prior to introduction to the exchanger. Industry in the use of Brazed Aluminum Heat Exchangers
standards call for 80 Tyler mesh or equivalent to in LNG liquefaction plants in particular.
120 micron filtration.
5
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
Cool down during start-ups - Brazed already begun its cool down process for instance
aluminum heat exchanger components are rigidly prior to being shut down and therefore be on the
connected to each other. Therefore, rapid cool verge of cooling more quickly. Process
down creates large local temperature differences parameters would then need to be controlled as
with potential for high thermal stresses on the per the operating procedures for the facility to
unit which can then lead to failure of the ensure that the same rate of cooling requirements
exchanger. Thermal induced stress limitations is met. It is not practical to design a BAHX to
are evaluated by methodologies such as finite prevent damage from freezing liquid expansion.
element analysis (FEA) [6-10]. Good start-up The process design and operation must avoid this
procedures are critical to eliminate the potential occurrence.
for excessive thermal stresses on BAHX.
Manufacturers of BAHX typically, for example, Purging Prior to a start-up, brazed
recommend a rate of change in metal aluminum heat exchangers must be purged with
temperature of 1 C per minute maximum as the nitrogen to remove any moisture and heavy
flows are introduced and the flow rates hydrocarbons. If any moisture or heavy
increased. It is imperative that proper operator hydrocarbons remain, they can freeze or form
training is conducted to address this important hydrates at the exchanger operating temperatures
cooling down criteria. As part of the training, in the LNG liquefaction process and cause
operators should become familiar with all the cracking in the exchanger. The purge should run
equipment and instrument devices with respect for 4 to about 24 hours depending on the size,
to their field locations as well. Utilizing hands- configuration, and complexity of the exchanger.
on field training to learn the plant facility is also The moisture content at the end of the purge
a critical step in the educational process. The should be less than 10 ppm.
written procedures must be in place and followed
in the plant operating manual that directs the Water Freezing during Operation During
operation staff with precise actions to take and the LNG liquefaction operation, it is critical to
temperatures to track in order to ensure proper prevent impurities from entering the BAHX that
cool down. To help the operating personnel could freeze or form hydrates at the cryogenic
control the cool down rate, BAHX can be operating temperature in the exchanger.
engineered with a unique design for temperature Therefore, such components as water, carbon
measurement in the exchanger that requires dioxide, benzene, and any heavy hydrocarbons
thermocouples to be installed in thermowells that should be reduced in their concentrations prior to
are embedded in several layers of the brazed entering the appropriate sections of the BAHX to
aluminum exchanger. These thermocouples are acceptable and appropriate levels which will
distributed along the length of the exchanger to prevent the component from freezing.
give an indicative temperature profile for the Customarily, in the liquefaction process, the
exchanger. Operators are then able to watch water and the carbon dioxide are treated
these temperature readings on their HMI (Human upstream of the BAHX and reduced to levels that
Machine Interface) or control system to ensure will not freeze in the unit at operating
that design parameters for cooling down the temperatures. Typically, any heavy
exchanger are satisfied on the appropriate hydrocarbons are extracted from the process in
timeline. These temperatures can be trended in an intermediate step of the liquefaction process.
the forms of a graph on the display screen with A stream exits the cold box from the BAHX and
appropriate timer indications to facilitate the cool separates the heavy hydrocarbons from the gas
down process. This data must be not only before allowing the natural gas to return to the
available but easily accessible. Therefore, it is BAHX and complete the liquefaction process.
customary to have a dedicated screen for the cold Any free water is absolutely critical to prevent
box itself with the appropriate temperature from entering the exchanger. As noted above, it
measurements outlined. Occasionally as start- can damage the core if it enters and freezes. If
ups for plants occur, it is common for trips or there is any breakthrough in the plant
plant shut downs to happen along the way which dehydration or treating systems, the brazed
force operation to stop. It is important to note aluminum heat exchanger must be immediately
that restarts of the BAHX have the same shut down, isolated, and purged.
importance and criteria for cool down as the
initial start-up. This is sometimes difficult and Fluid Distribution Design considerations
requires added attention as the unit may have for LNG liquefaction plants often involve two-
6
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
phase fluids. For flows in critical applications the outer surface of the parting sheet. Its purpose
(tight approach temperatures, small MTDs, large is to form the braze material. During the vacuum
% of the duty being done by the two phase brazing process, the core block is slowly heated
stream, or where the outlet temperatures of each to brazing temperature. When the core block
stream are very important), most exchanger reaches that brazing temperature, the cladding
fabricators recommend external phase separation material melts and diffuses into the base 3003
and distribution of the vapor and liquid material of the parting sheets, fins, and side bars.
separately to ensure proper distribution of the After a sufficient time at brazing temperature,
liquid and vapor to each layer of the exchanger. the block is cooled and the braze material re-
In some cases, two-phase flow can be handled solidifies forming a rigid brazed core matrix.
without separation with the use of perforated Headers and nozzle assemblies are
plates or sparge pipes in the inlet header. typically formed with 5083 alloy aluminum.
Depending on the application, other alloys of
When there are two or more cores within a cold aluminum such as 6061 or 5454 may be used for
box, distribution between the cores must be headers and nozzles, but 5083 is typically
considered to avoid excessive thermal stresses. utilized for LNG applications. Both headers and
To ensure that refrigerant is evenly distributed nozzles can be made from pipe or brake-formed
between cores, the refrigerant flow (both liquid from flat plate to form whatever radius is
and vapor) are controlled and metered to each required for the application. Header/nozzle
core. On the other hand, feed gas is metered to assemblies are welded to the core block during
each cold box and then split with parallel piping final assembly (reference Figure 7). Each stream
inside the cold box to each core. This works is pressure tested to ensure structural integrity.
well because the largest amount of the pressure
drop in the gas flow path is in the exchanger
core. Also, if there are minor variations in the
gas distribution between cores, the refrigerant
can be adjusted to match up with the gas flow to
optimize the operation.
7
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
mechanical connection of dissimilar metals. possibility for damage or failure of the heat
Individual transition joint manufacturers have exchanger, the operator should strongly consider
established designs and manufacturing processes the manufacturers operating guidelines. These
that meet the requirements of ASME B31.3 [11]. include the following:
For most LNG applications, the transition joint o Regulate the pressure and external loads
will be 6061-T6 aluminum on the exchanger and limit temperature differences
side, terminating in 304 or 316 stainless steel on between adjacent streams at any point
the customer interface side. Transition joints are in the heat exchanger to those specified
commonly used when customer preferences by the manufacturer.
dictate that penetrations to the cold box consist o Exercise care in applications where a
of stainless steel piping. The transition joint liquid is totally vaporized within the
allows the customer to utilize a non-mechanical exchanger.
connection inside the cold box between the o Design and operate plant equipment and
exchanger and terminating piping. To reduce the piping connected to the exchanger to
opportunity or points for leaks to occur, prevent flow excursion and instabilities.
connections with flanges are typically all down o Limit frequently repeated temperature
outside of the cold box such that inside the cold fluctuations of any stream to +1 C.
box all the connections with the BAHX are o Limit thermal gradients during transient
welded. conditions such as start-up and
shutdown to those specified by the
manufacturer and repeated in the
operating manual.
8
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use
external to the cold box. Exchanger relieving [2] 2004 ASME Boiler and Pressure Vessel
rates can be designed per recognized consensus Code, Section V, Nondestructive Examination
documents such as API 521 [13].
The cold box itself is typically designed [3] 2004 ASME Boiler and Pressure Vessel
for a low pressure (about 4 inches of water). Code, Section VIII, Rules for Construction of
There are no flanged connections inside the cold Pressure Vessels
box, eliminating potential leak points. To ensure
that hydrocarbon vapors cannot build up in the [4] 2004 ASME Boiler and Pressure Vessel
cold box, a nitrogen purge system is furnished Code, Section IX, Welding and Brazing
within the cold box. The nitrogen purge system Qualifications
is designed to ensure an even distribution of
purge gas. The nitrogen enters the bottom of the [5] GPSA, Gas Processors Suppliers Association,
box and exits through a breather vent at the top Engineering Data Book, Twelfth Edition, 2004,
of the cold box. The nitrogen sweep is Volume I, Chapter 9
monitored with a combustible gas detector
mounted on the breather vent. If combustible [6] Terada, Susumu; Noishiki, Koji; Fukuda,
gas is detected, the exchanger is shut down and Yukihiro; Miura, Shinichi, Fatigue Evaluation of
inspected for leaks. The cold box is also Brazed Aluminum Heat Exchanger for High
furnished with a blow-off hatch to relieve any Pressure Use, PVP-Vol. 418, High Pressure
pressure buildup in the box, preventing the cold Technology at the Dawn of the New Millennium
box from rupturing in the event of an exchanger ASME 2001
leak. In some applications, containment of
leaking cryogenic fluids is provided to avoid [7] Nakaoka, Takehiro; Nakagawa, Tomokazu;
damage to the carbon steel cold box structure. Ueno, Kouichi, Evaluation of Fatigue Strength of
Plate-Fin Heat Exchanger Under Thermal
SUMMARY Loading, International Conference on Pressure
As the demand for natural gas continues Vessel Technology, Volume 1, ASME 1996
to increase, the shortfall in supply must be
addressed. Exploration, drilling, and gas [8] Nakagawa, Tomokazu; Sou, Tadashi, Three-
processing will aid in providing more natural gas Dimensional Structural Analysis of the Plate-Fin
supply as will the increase in LNG facilities. Heat Exchanger, ASME 84-PVP-7
LNG facilities allow for economic storage as
well as means for facilitating the means for [9] Mizoguchi, Takao; Ueno, Kouichi; Okada,
transportation of natural gas. BAHX are an Kazahiko; Nakaoki, Kozo, Fatigue Strength of
excellent application in these LNG and Corrugated Fin Type Heat Exchanger, ASME 82-
cryogenic gas processing facilities. Specific PVP-29
considerations have been outlined in this paper
to aid in the design engineering and operation of [10] Chen, Hu; Geng, Luyang; Gong, Jianming;
this heat transfer equipment to enhance its safety Tu, Shan-Tung, Numerical Analysis of Thermal
and reliability. Deformation and Residual Stress for the Brazed
Plate-Fin Structure, 2006 ASME Pressure
ACKNOWLEDGEMENTS Vessels and Piping Division Conference,
The authors wish to recognize their Vancouver, BC, Canada
employers, Chart Energy & Chemicals, Inc. and
Black & Veatch for their support, contribution, [11] ASME Process Piping, ASME Code for
and courtesy photographs supplied to develop Pressure Piping B31.3, 2004 Edition
this paper. Additionally, we would like to
recognize Praxair, White Martins, Brazil for the [12] ALPEMA, The Standards of the Brazed
use of the installed cold box picture from the Aluminum Plate-Fin Heat Exchanger
recently completed Black & Veatch project. Manufacturers Association, Second Edition,
2000.
REFERENCES
[1] 2004 ASME Boiler and Pressure Vessel [13] API 521, Guide to Pressure-Relieving and
Code, Section II, Materials Depressuring Systems, Fourth Edition, March
1997, Paragraph 3.18
9
Downloaded From: http://proceedings.asmedigitalcollection.asme.org/ on 02/01/2016 Terms of Use: http://www.asme.org/about-asme/terms-of-use