7.1 MSDS Complete PDF

MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO EC6080A
EMERGENCY TELEPHONE NUMBER(S)

See section 16, for Emergency Telephone Numbers.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : NALCO EC6080A
APPLICATION : SCALE INHIBITOR
COMPANY IDENTIFICATION : NALCO EUROPE B.V.

Postbus 627
2300 AP Leiden, The Netherlands
EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.
Date issued : 03.04.2007

Version Number : 1.12
COMPANY CONTACT TELEPHONE NUMBERS.
NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 CHEMIA BRUGG AG (CH) +41 (0)56 4606260
NALCO DANMARK A/S +45-48195800 OEKOPHIL AG (CH) +41 (0)41 760 2220
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
NALCO ESPAOLA S.A. (E) +34 93-4095555 ZAO Nalco (RU) +7 (0)495 980 72 80
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO STERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 local support: Nalco Czechia s.r.o. +420 (0)2 679 123 50
(CZ)
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Hungary Kft. +36 (0)1 471 91 81
(HU)
NALCO ITALIANA S.R.L.(I) +39 06-542971 Local Support: Nalco sterreich +385 (0)1 377 95 21
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
NALCO LIMITED +44 (0)1606 74488 Local Support: Nalco sterreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation Office
ROMANIA (RO)
NALCO NETHERLANDS B.V. +31 (0)13-5952200
2. COMPOSITION/INFORMATION ON INGREDIENTS
This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any
disclosed substance(s) are present below hazardous concentration levels for the product classification.
Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)

ELINCS NO NOTAS
Ethylene Glycol 203-473-3 107-21-1 Xn R22 1- 5
Sodium Phosphate, Tribasic 231-509-8 7601-54-9 Xi R36/38 10 - 30
Refer to Section 16 for descriptions of relevant risk phrases and Notas.
3. HAZARDS IDENTIFICATION
HAZARD CLASSIFICATION :
NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100
For additional copies of an MSDS visit www.nalco.com and request access
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PRODUCT
NALCO EC6080A

This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any
disclosed substance(s) are present below hazardous concentration levels for the product classification.
HUMAN HEALTH HAZARDS - ACUTE :
INHALATION :
Repeated or prolonged exposure may irritate the respiratory tract.
SKIN CONTACT :
May cause irritation with prolonged contact. Can be absorbed through the skin.
EYE CONTACT :
May cause irritation with prolonged contact.
INGESTION :
Not a likely route of exposure. No adverse effects expected.
4. FIRST AID MEASURES
INHALATION :
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
SKIN CONTACT :
Flush affected area with water. If symptoms develop, seek medical advice.
EYE CONTACT :
Flush affected area with water. If symptoms develop, seek medical advice.
INGESTION :
Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If reflexive
vomiting occurs, rinse mouth and repeat administration of water.
NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.
5. FIRE FIGHTING MEASURES
FLASH POINT : 105 C TCC
EXTINGUISHING MEDIA :
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be
ignitable. Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD :

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions. May evolve oxides of phosphorus (POx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
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PRODUCT
NALCO EC6080A

6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible.
METHODS FOR CLEANING UP :

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of
contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS :
Do not contaminate surface water.
7. HANDLING AND STORAGE
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled.
STORAGE CONDITIONS :
Store in suitable labeled containers. Store the containers tightly closed.
SUITABLE CONSTRUCTION MATERIAL :

Stainless Steel 304, Stainless Steel 316L, EPDM, HDPE (high density polyethylene), Viton, Neoprene, Nitrile,
Perfluoroelastomer, PTFE, MDPE
UNSUITABLE CONSTRUCTION MATERIAL :

Carbon steel
SPECIFIC USE(S) :
SCALE INHIBITOR
For specific dosages and customized applications please contact your representative.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Country/Source Substance(s) Category: ppm mg/m3

__AUSTRIA Ethylene Glycol MAK 10 26
MAK CEIL 20 52
Skin*
BELGIUM Ethylene Glycol (Aerosol.) TWA 20 52
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PRODUCT
NALCO EC6080A

STEL 40 104
Skin*
DENMARK Ethylene Glycol GV 10 26

Ethylene Glycol (Aerosol.) GV 10
Ethylene Glycol Skin*
GV 10
Skin*
FINLAND Ethylene Glycol HTP 8H 20 50

HTP 15MIN 40 100
Skin*
FRANCE Ethylene Glycol (Vapour.) VME 20 52

STEL 40 104
Skin*
GERMANY Ethylene Glycol MAK 10 26

Skin*
IRELAND Ethylene Glycol (Vapour.) TWA 20 52

Ethylene Glycol (Particulate.) TWA 10
Ethylene Glycol (Vapour.) STEL 40 104
Skin*
ITALY Ethylene Glycol TWA 20 52

STEL 40 104
Skin*
NETHERLANDS Ethylene Glycol (Mist.) MAC 10

Ethylene Glycol (Vapour.) MAC 20 52
MAC-TGG 40 104
15
Skin*
NORWAY Ethylene Glycol (Dust) ADM. NORM 10

Ethylene Glycol (Vapour.) CEIL 25
Skin*
Ethylene Glycol (Dust) Skin*
SPAIN Ethylene Glycol VLA-ED 20 52

VLA-EC 40 104
Skin*
SWEDEN Ethylene Glycol NGV 10 25

KTV 20 50
Skin*
SWITZERLAND Ethylene Glycol TWA 10 26

STEL 20 52
Skin*
UNITED KINGDOM Ethylene Glycol (Particulate.) TWA 10

Ethylene Glycol (Vapour.) TWA 20 52
STEL 40 104
Ethylene Glycol (Particulate.) Skin*
Ethylene Glycol (Vapour.) Skin*
POLAND Ethylene Glycol MAC-NDS 15

MAC- 50
NDSCh
HUNGARY Ethylene Glycol K 52

CK 104
Skin*
CZECH REPUBLIC Ethylene Glycol PEL 50
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PRODUCT
NALCO EC6080A

NPK-P 100
Skin*
CROATIA Ethylene Glycol MDK 50 125
ROMANIA Ethylene Glycol TWA 52

STEL 104
Skin*
SLOVAKIA Ethylene Glycol TWA 20 52

CEILING 104
Skin*
SLOVENIA Ethylene Glycol TWA 20 52

Skin*
* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.
MONITORING MEASURES :
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be
desorbed or removed and analyzed as referenced below:
Substance(s) Method Analysis Absorbant
Ethylene Glycol US NIOSH: 5523 Gas chromatography XAD-7 / Glass fibre
filter OVS tube
ENGINEERING MEASURES :
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples
should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
PERSONAL PROTECTION
GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields. The applicable European
standard can be found in EN 166.
RESPIRATORY PROTECTION :
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found
in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.
HAND PROTECTION :
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on
work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
SKIN PROTECTION :
Wear standard protective clothing.
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PRODUCT
NALCO EC6080A

EYE PROTECTION :
Wear chemical splash goggles. Wear safety glasses with side-shields.
HYGIENE RECOMMENDATIONS :
Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a
safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product
never eat, drink or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Liquid
APPEARANCE Amber
ODOR Mild
FLASH POINT : 105 C TCC

SPECIFIC GRAVITY 1.42 (20 C)
DENSITY 1.4 g/cm3
SOLUBILITY IN WATER Complete
pH (100 %) 3.8
VISCOSITY 250 cst (20 C)
VISCOSITY 360 SUS (15.5 C)
VAPOR PRESSURE 3.2 kPa (25 C)
Note: These physical properties are typical values for this product and are subject to change.
10. STABILITY AND REACTIVITY
STABILITY :
Stable under normal conditions.
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Freezing temperatures.
MATERIALS TO AVOID :
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium
hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or
boiling and toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS :

Under fire conditions: Oxides of nitrogen, Oxides of phosphorus
11. TOXICOLOGICAL INFORMATION
No toxicity studies have been conducted on this product.
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PRODUCT
NALCO EC6080A

SENSITIZATION :
This product is not expected to be a sensitizer.
CARCINOGENICITY :
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH). Two chronic feeding studies, using rats and mice, have not produced any evidence that
ethylene glycol causes dose-related increases in tumor incidence, or a different pattern of tumors when
compared to untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported
by numerous in vitro genotoxicity studies showing that it does not produce chromosomal breakage or mutagenic
effects.
For additional information on the hazard of the preparation, please consult section 3 and 12.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL EFFECTS :
ACUTE FISH RESULTS :

Species Exposure LC50 NOEC Method Test Descriptor
Bluegill Sunfish 96 hrs > 1,000 mg/l 1,000 mg/l Product
Rainbow Trout 96 hrs > 1,000 mg/l 1,000 mg/l Product
Rainbow Trout 96 hrs > 1,800 mg/l 1,800 mg/l Product
ACUTE INVERTEBRATE RESULTS :

Species Exposure LC50 EC50 Method Test Descriptor
Daphnia magna 48 hrs > 2,000 mg/l Product
MOBILITY :
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models. If released into the environment this material is expected to distribute to the air,
water and soil/sediment in the approximate respective percentages;
Air Water Soil/Sediment

<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
PERSISTENCY AND DEGRADATION :
The organic portion of this preparation is expected to be inherently biodegradable.
BIOACCUMULATION POTENTIAL
This preparation or material is not expected to bioaccumulate.
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PRODUCT
NALCO EC6080A

13. DISPOSAL CONSIDERATIONS
If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.
Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if
burned. It can be burned directly in appropriate equipment. Any chemical waste is a potential environmental
pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
EUROPE WASTE CODE :

16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.
NATIONAL REGULATIONS AUSTRIA :

Waste Code :52725
NATIONAL REGULATIONS FRANCE :

Waste Code :Relevant.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
AIR TRANSPORT (ICAO/IATA)

TRANSPORTATION
MARINE TRANSPORT (IMDG/IMO)

TRANSPORTATION
15. REGULATORY INFORMATION
CLASSIFICATION AND LABELLING :
This preparation is not regulated, however, we recommend the following safety precautions:
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PRODUCT
NALCO EC6080A

SAFETY PHRASES
S24/25 - Avoid contact with skin and eyes.
S37/39 - Wear suitable gloves and eye/face protection.
NATIONAL REGULATIONS AUSTRIA

Danger classification according to VbF: Not Regulated
NATIONAL REGULATIONS DENMARK

MAL CODE Yes
FIRE CLASS Non-regulated.
ORGANIC SOLVENTS/VOCS Yes
SUSPECT CARCINOGENS No
NATIONAL REGULATIONS FRANCE

Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Not-applicable.
Dangerous or Poisonous Substances and Preparations: Not-applicable.
Special medical supervision - Decree of 11 July 1977: Not-applicable.
Work Restrictions:
Fair labor standards act, Article R234-9 and 10 (women): Not-applicable.
Fair labor standards act, Article R234-16, 20 and 21 (young workers): Not-applicable.
Fair labor standards act, Decree of the 8/10/90 (temporary work and contract last given): Not-applicable.
Classified Industrial Sites (ICPE): Not-applicable. Water Discharge: Relevant.
PRODUCT REGISTRATION NUMBER

Denmark 1235347
Norway 019853
INTERNATIONAL CHEMICAL CONTROL LAWS

EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.
UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
CANADA :
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
16. OTHER INFORMATION
LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2
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PRODUCT
NALCO EC6080A

R22 - Harmful if swallowed.

R36/38 - Irritating to eyes and skin.
- REVISED INFORMATION: section(s):
-3
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.
Trans-European +32-(0)3-575-5555
Belgium / Luxembourg +32-(0)3-575-0330
Czech Republic +420-602-669421
Denmark +47-22-33-69-99
Finland +358-(0)9-4711
France / French Switzerland +33-(0)6-11-07-32-81
Germany / Austria / German Switzerland +49-(0)6232-130128
Hungary +36-30-9-506-447
Italy / Italian Switzerland +39-333-210-7947
The Netherlands +32-(0)3-575-0330
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
Russia / Belarus +7-812-449-0474
Saudi Arabia +966-(3)847-1515
Slovak Republic +421-(0)905-585-938
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
UK and Republic of Ireland +44-(0)7071-223-738
Nalfleet International +32-(0)3-575-5555
POISON CONTROL CENTER TELEPHONE NUMBERS
Belgium +32-70-245245
Czech Republic +420 224 91 92 93
France +33-(0)145-42-59-59 ORFILA
Slovak Republic +421 (0)2 5477 4166
Prepared By : SHE Department

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth
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PRODUCT
NALCO 780-A

PRODUCT NAME : NALCO 780-A
APPLICATION : OXYGEN SCAVENGER

Postbus 627

NALCO EUROPE B.V. +31 71 5241 100

NALCO AB (SE) +46 (0)8-50074000 NALCO ITALIANA S.R.L.(I) +39 06-542971
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO Kft. (HU) +36 (0)1 471 91 81
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NALCO LIMITED +44 (0)1606 74488
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 NALCO NETHERLANDS B.V. +31 (0)13-5952200
NALCO DANMARK A/S +45-48195800 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 NALCO STERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO ESPAOLA S.A. (E) +34 93-4095555 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO FRANCE SAS +33 (0)3 20 11 70 00 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.
Hazardous Substance(s) EINECS / SYMBOL R-PHRASES / % (w/w)

ELINCS NO NOTAS
Sodium Bisulfite 231-548-0 Xn R22, R31 30 - 60
Harmful if swallowed. Contact with acids liberates toxic gas.
INHALATION :
Not a likely route of exposure. Contains Sulfite. Causes asthmatic signs and symptoms in hyper-reactive
individuals.
NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, , , The Netherlands 0031 71 5241100
1 / 11
PRODUCT
NALCO 780-A

SKIN CONTACT :
EYE CONTACT :
INGESTION :
There may be irritation to the gastro-intestinal tract. Harmful if swallowed. May cause asthmatic-like attack.
HUMAN HEALTH HAZARDS - CHRONIC :

Ingestion of sulfite can cause a severe allergic reaction in asthmatics and some sulfite sensitive individuals. The
resulting symptoms can include difficulty in breathing, flushed skin and a rash. Chronic exposure to sulfites may
cause symptoms of upper respiratory disease and affect sense of taste and smell.
INHALATION :
Remove to fresh air, treat symptomatically. If breathing is difficult, administer oxygen. Get medical attention.
SKIN CONTACT :
Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician.
EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately
flush with plenty of water for at least 15 minutes.
INGESTION :
Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give
water to drink.
NOTE TO PHYSICIAN :
FLASH POINT : None
ignitable. Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding
fire.

May evolve oxides of sulfur (SOx) under fire conditions.

2 / 11
PRODUCT
NALCO 780-A

Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by
trained personnel only. Ensure adequate ventilation. Do not touch spilled material. Stop or reduce any leaks if
it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal
Protection). Notify appropriate government, occupational health and safety and environmental authorities.

or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage
thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material.
Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
HANDLING :
Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency
equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Keep the containers
closed when not in use. Use with adequate ventilation.
Store separately from oxidizers. Store the containers tightly closed. Store in suitable labeled containers. Amine
and sulphite products should not be stored within close proximity or resulting vapors may form visible airborne
particles.
SPECIFIC USE(S) :
OXYGEN SCAVENGER
Exposure limits are listed for sulfur dioxide (SO2) since this product evolves SO2 when open to the atmosphere.
are shown below.

____AUSTRIA Sulfur Dioxide MAK 2 5
MAK CEIL 4 10
BELGIUM Sodium Bisulfite TWA 5
Sulfur Dioxide TWA 2 5.3

STEL 5 13
DENMARK Sodium Bisulfite GV 5
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NALCO 780-A

Sulfur Dioxide GV 0.5 1.3
FINLAND Sulfur Dioxide HTP 8H 1 2.7

HTP 15MIN 4 11
FRANCE Sodium Bisulfite VME 5
Sulfur Dioxide VME 2 5

VLE 5 10
GERMANY Sulfur Dioxide MAK 2 5

MAK 1 2.5
MAK 0.5 1.3
IRELAND Sodium Bisulfite TWA 5
Sulfur Dioxide TWA 2 5

STEL 5 13
ITALY Sodium Bisulfite TWA 5
Sulfur Dioxide TWA 2

STEL 5
NETHERLANDS Sodium Bisulfite MAC TGG 5
Sulfur Dioxide MAC TGG 2 5
NORWAY Sodium Bisulfite ADM. NORM 5
Sulfur Dioxide ADM. NORM 2 5
SPAIN Sodium Bisulfite VLA-ED 5
Sulfur Dioxide VLA-ED 2 5.3

VLA-EC 5 13
SWEDEN Sulfur Dioxide NGV 2 5

TGV 5 13
SWITZERLAND Sodium Bisulfite (Inhalable dust) TWA 5
Sulfur Dioxide TWA 0.5 1.3

STEL 0.5 1.3
UNITED KINGDOM Sodium Bisulfite TWA 5
POLAND Sulfur Dioxide MAC-NDS 2

MAC- 5
NDSCh
HUNGARY Sulfur Dioxide K 5

CK 5
CZECH REPUBLIC Sulfur Dioxide PEL 5

NPK-P 10
CROATIA Sodium Bisulfite MDK 5
Sulfur Dioxide MDK 2 5

KDK 5 10
ROMANIA Sulfur Dioxide TWA 5

STEL 10
SLOVAKIA Sulfur Dioxide TWA 0.5 1.3
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PRODUCT
NALCO 780-A

SLOVENIA Sulfur Dioxide TWA 0.5 1.3
the eyes.
Sodium Bisulfite US OSHA: 121 Ion chromatography Cellulose ester filter
Sulfur Dioxide US NIOSH: 6004 Ion chromatography Cellulose ester filter

treated with Sodium
Bicarbonate
General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are
generated. The use of local exhaust ventilation is recommended to control emissions near the source.
Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
PERSONAL PROTECTION
GENERAL ADVICE :
chemicals being handled. Consider the use of filter type: E The applicable European standard can be found in
EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive
pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
SKIN PROTECTION :
When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended.
A full slicker suit is recommended if gross exposure is possible. The applicable European standard can be found
in EN 345.
EYE PROTECTION :
Wear chemical splash goggles. The applicable European standard can be found in EN 166.
5 / 11
PRODUCT
NALCO 780-A

Use good work and personal hygiene practices to avoid exposure. Always wash thoroughly after handling
chemicals. When handling this product never eat, drink or smoke. If clothing is contaminated, remove clothing
and thoroughly wash the affected area. Launder contaminated clothing before reuse. Keep an eye wash
fountain available. Keep a safety shower available.
APPEARANCE Amber
ODOR Sulfurous
FLASH POINT : None

SPECIFIC GRAVITY 1.31 (25 C)
pH (1 %) 4.2
VISCOSITY 6 cps (20 C)
FREEZING POINT -7 C
BOILING POINT 100 C
VAPOR PRESSURE Same as water 4.26 kPa (28 C)
STABILITY :
Freezing temperatures. Avoid extremes of temperature.
Bases, Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic),
potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat,
splattering or boiling and toxic vapors., Contains Sulfite., SO2 may react with vapors from neutralizing amines
and may produce a visible cloud of amine salt particles.Contact with strong oxidizers (e.g. chlorine, peroxides,
chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions
and/or toxic vapors., Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic)
may generate heat, splattering or boiling and toxic vapors., SO2 may react with vapors from neutralizing amines
and may produce a visible cloud of amine salt particles.

Under fire conditions: Oxides of sulfur
6 / 11
PRODUCT
NALCO 780-A

The following results are for a similar product.
ACUTE ORAL TOXICITY :

Species LD50 Test Descriptor
Rabbit 41,000 mg/kg Similar Product
ACUTE DERMAL TOXICITY :

Rabbit 3,038 mg/kg Similar Product
PRIMARY SKIN IRRITATION :

Draize Score Test Descriptor
1.0 / 8.0 Similar Product
PRIMARY EYE IRRITATION :

Draize Score Test Descriptor
9.4 / 110.0 Similar Product
SENSITIZATION :
This product is not expected to be a sensitizer. Sulfites can cause an allergic reaction in sensitive individuals.
CARCINOGENICITY :
Hygienists (ACGIH).
The following results are for the product.

Species Exposure LC50 Method Test Descriptor
Bluegill Sunfish 96 hrs 100 - 1,000 Product
mg/l
Rainbow Trout 96 hrs 100 - 1,000 Product
mg/l
ADDITIONAL ECOLOGICAL DATA:

Depletes oxygen content in water courses.
MOBILITY :
7 / 11
PRODUCT
NALCO 780-A


<5% 30 - 50% 50 - 70%
Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not
applicable.
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if
burned. It can be burned directly in appropriate equipment. This product is NOT suitable for disposal via
municipal sewers, drains, natural streams or rivers.
contractor.
EUROPE WASTE CODE :

16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing
LAND TRANSPORT
Proper Shipping Name : BISULFITES, AQUEOUS SOLUTION, N.O.S.
Technical Name(s) : Sodium Bisulfite
UN/ID No : UN 2693
Hazard Class - Primary : 8
Packing Group : III
ADR/RID H.I.n. : 80
CLASSIFICATION CODE : C1

Proper Shipping Name : BISULPHITES, AQUEOUS SOLUTION, N.O.S.
UN/ID No : UN 2693
8 / 11
PRODUCT
NALCO 780-A


Packing Group : III
IATA Cargo Packing Instructions : 820
IATA Cargo Aircraft Limit : 60 L (Max net quantity per package)
IATA Passenger Packing Instructions :
IATA Passenger Aircraft Limit :

Proper Shipping Name : BISULPHITES, AQUEOUS SOLUTION, N.O.S.
UN/ID No : UN 2693
Packing Group : III
OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE : 80GC1-II+III
EMERGENCY ACTION CODE : 2X
GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations

Directive 1999/45/EC.
HAZARD SYMBOLS
HARMFUL
Contains:..Sodium Bisulfite
RISK PHRASES
R31 - Contact with acids liberates toxic gas.
SAFETY PHRASES
S23 - Do not breathe vapor.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 - After contact with skin, wash immediately with plenty of water.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S46 - If swallowed, seek medical advice immediately and show this container or label.
NATIONAL REGULATIONS FRANCE

Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see
table(s): 66
Classified Industrial Sites (ICPE): Not-applicable.
9 / 11
PRODUCT
NALCO 780-A

NATIONAL REGULATIONS GERMANY

WGK 1 (Annex 4)
NATIONAL REGULATIONS HOLLAND

ABM RESULT
ABM RESULT Substance(s) % (w/w)
11 B
NATIONAL REGULATIONS, USA

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act :
When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR
173.310 Boiler Water Additives
Limitations: no more than required to produce intended technical effect.

Norway 019388
UNITED STATES
CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

R31 - Contact with acids liberates toxic gas.
- REVISED INFORMATION: section(s):
-3
10 / 11
PRODUCT
NALCO 780-A

Denmark +47-22-33-69-99
Finland +358-(0)9-4711
Hungary +36-30-9-506-447
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
Saudi Arabia +966-(3)847-1515
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

11 / 11
PRODUCT
EC9610A

PRODUCT NAME : EC9610A
APPLICATION : CLEANER

Postbus 627

NALCO EUROPE B.V. +31 71 5241 100

NALCO AB (SE) +46 (0)8-50074000 NALCO ITALIANA S.R.L.(I) +39 06-542971
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO Kft. (HU) +36 (0)1 471 91 81
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NALCO LIMITED +44 (0)1606 74488
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 NALCO NETHERLANDS B.V. +31 (0)13-5952200
NALCO DANMARK A/S +45-48195800 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 NALCO STERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO ESPAOLA S.A. (E) +34 93-4095555 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO FRANCE SAS +33 (0)3 20 11 70 00 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
This product is classified as dangerous in accordance with the Substance Directive 1967/548/EEC.

ELINCS NO NOTAS
2-Butoxyethanol 203-905-0 Xn R20/21/22, 60 - 100
R36/38
This product is classified as dangerous in accordance with the Substance Directive 1967/548/EEC.
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes and skin.
INHALATION :
Aerosols or product mist may irritate the upper respiratory tract.
NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, , , The Netherlands +31 71 5241 100
1 / 11
PRODUCT
EC9610A

SKIN CONTACT :
EYE CONTACT :
Can cause moderate to severe irritation.
INGESTION :
Not a likely route of exposure. Large quantities may cause kidney and liver damage.
HUMAN HEALTH HAZARDS - CHRONIC :

Contains ethylene glycol monobutyl ether (butoxyethanol). Prolonged and/or repeated exposure through
inhalation or extensive skin contact with EGBE may result in damage to the blood and kidneys.
PHYSICAL AND CHEMICAL HAZARDS :

Combustible.
INHALATION :
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
SKIN CONTACT :
Immediately wash with plenty of soap and water. If symptoms develop, seek medical advice.
EYE CONTACT :
Get medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
INGESTION :
Get medical attention. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If
conscious, washout mouth and give water to drink.
NOTE TO PHYSICIAN :
FLASH POINT : 71 C PMCC
LOWER EXPLOSION LIMIT : 1.1 V%
UPPER EXPLOSION LIMIT : 10.6 V%
AUTOIGNITION TEMPERATURE : 244 C
Dry powder, Carbon dioxide, Water spray, Foam, Other extinguishing agent suitable for Class B fires, For large
fires, use water spray or fog, thoroughly drenching the burning material.
Keep containers cool by spraying with water.
2 / 11
PRODUCT
EC9610A


Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions.

safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by
trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.)
readily available. Notify appropriate government, occupational health and safety and environmental authorities.

HANDLING :
Avoid eye and skin contact. Do not take internally. Ensure all containers are labelled. Keep the containers
closed when not in use. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Do not use, store,
spill or pour near heat, sparks or open flame.
Store the containers tightly closed. Store in suitable labelled containers. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.

Teflon, Kalrez, Perfluoroelastomer, TFE, HDPE (high density polyethylene), Aluminum, Mild steel, Carbon Steel
C1018, Stainless Steel 304, Stainless Steel 316L, Hastelloy C-276, MDPE (medium density polyethylene)

Copper, Neoprene, Ethylene propylene, Polypropylene, Polyethylene, Nitrile, Plexiglass, EPDM, Alfax, Brass,
Nylon, PVC, Buna-N, Natural rubber, Polyurethane, Hypalon, Viton
SPECIFIC USE(S) :
CLEANER
3 / 11
PRODUCT
EC9610A

are shown below.

__AUSTRIA 2-Butoxyethanol MAK 20 98
MAK STEL 40 200
Skin*
BELGIUM 2-Butoxyethanol TWA 20 98

STEL 50 246
Skin*
DENMARK 2-Butoxyethanol GV 20 98
Skin*
GV 20
Skin*
FINLAND 2-Butoxyethanol HTP 8H 20 98

HTP 15MIN 50 250
Skin*
GERMANY 2-Butoxyethanol MAK 20 98

Skin*
IRELAND 2-Butoxyethanol TWA 20 98

STEL 50 246
Skin*
ITALY 2-Butoxyethanol TWA 20 98

STEL 50 246
Skin*
NETHERLANDS 2-Butoxyethanol MAC TGG 20 100

MAC-TGG 50 246
15
Skin*
NORWAY 2-Butoxyethanol ADM. NORM 10 50

Skin*
SPAIN 2-Butoxyethanol VLA-ED 20 98

VLA-EC 50 245
Skin*
SWEDEN 2-Butoxyethanol NGV 10 50

KTV 20 100
Skin*
SWITZERLAND 2-Butoxyethanol TWA 20 100

STEL 80 400
Skin*
UNITED KINGDOM 2-Butoxyethanol TWA 25

STEL 50
Skin*
POLAND 2-Butoxyethanol MAC-NDS 98

MAC- 200
NDSCh
4 / 11
PRODUCT
EC9610A

HUNGARY 2-Butoxyethanol K 98
CK 246
Skin*
CZECH REPUBLIC 2-Butoxyethanol PEL 100

NPK-P 200
Skin*
CROATIA 2-Butoxyethanol MDK 5 25

Skin*
ROMANIA 2-Butoxyethanol TWA 98

TWA 150
STEL 246
STEL 250
Skin*
SLOVAKIA 2-Butoxyethanol TWA 20 98

CEILING 246
Skin*
SLOVENIA 2-Butoxyethanol TWA 20 98

Skin*
the eyes.
2-Butoxyethanol US NIOSH: 1403 Gas chromatography Charcoal
BIOLOGICAL EXPOSURE INDICES :

2-Butoxyethanol
A biological index of exposure to 2-butoxyethanol (CAS 111-76-2) is the detection of butoxyacetic acid in the
urine at the end of the work shift (UK, 240mmol/mol creatinine) or at the end of the last shift of the working week
(Germany, 100mg/l).
General ventilation is recommended.
PERSONAL PROTECTION
GENERAL ADVICE :
chemicals being handled. The applicable European standard can be found in EN 141, EN 143 and EN 371.
Consider the use of filter type: A In event of emergency or planned entry into unknown concentrations a
positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
respiratory protection program including selection, fit testing, training, maintenance and inspection.
5 / 11
PRODUCT
EC9610A

HAND PROTECTION :
SKIN PROTECTION :
Wear standard protective clothing. When handling this product, the use of overalls is recommended.
EYE PROTECTION :
Wear chemical splash goggles. The applicable European standard can be found in EN 166.
Use good work and personal hygiene practices to avoid exposure. Always wash thoroughly after handling
chemicals. When handling this product never eat, drink or smoke. Keep an eye wash fountain available. Keep a
safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse.
APPEARANCE Colorless
ODOR Glycol Ether
FLASH POINT : 71 C PMCC
LOWER EXPLOSION LIMIT : 1.1 V%
UPPER EXPLOSION LIMIT : 10.6 V%

SPECIFIC GRAVITY 0.89 - 0.91 (16 C) ASTM D-1298
VISCOSITY 2.53 cst (38 C)
FREEZING POINT -71 C ASTM D-1177
BOILING POINT 171 C ASTM D-86
VAPOR PRESSURE 0.1 kPa (20 C) ASTM D-323 0.06 kPa (20 C)
VAPOR DENSITY 1 (Air = 1)
STABILITY :
6 / 11
PRODUCT
EC9610A

Heat and sources of ignition including static discharges.
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.

Under fire conditions: Oxides of carbon
ACUTE ORAL TOXICITY :

Rat 470 mg/kg Product
ACUTE DERMAL TOXICITY :

Rabbit 222 mg/kg Product
ACUTE INHALATION TOXICITY :

Species LC50 Test Descriptor
Rat 7 mg/l (7 hrs) Product
SENSITIZATION :
This product is not expected to be a sensitizer.
CARCINOGENICITY :
Hygienists (ACGIH).
The following results are for the product.

Species Exposure LC50 Method Test Descriptor
Bluegill Sunfish 96 hrs > 1,000 mg/l Product
Inland Silverside 96 hrs > 1,000 mg/l Product
Mosquito Fish 96 hrs > 1,000 mg/l Product
(Gambusia spp.)
7 / 11
PRODUCT
EC9610A

ACUTE INVERTEBRATE RESULTS :

Species Exposure LC50 EC50 Method Test Descriptor
Acartia tonsa 48 hrs 730 mg/l Product
AQUATIC PLANT RESULTS :

Species Exposure EC50/LC50 Method Test Descriptor
Marine Algae 72 hrs 570 mg/l Product
(Skeletonema (EC50)
costatum)
MOBILITY :

<5% 50 - 70% 30 - 50%
The portion in water is expected to float on the surface.
The organic portion of this preparation is expected to be readily biodegradable.
This product is suitable for disposal in an approved landfill or by controlled incineration. This product is ashless
and can be burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal
sewers, drains, natural streams or rivers.
contractor.
EUROPE WASTE CODE :

8 / 11
PRODUCT
EC9610A

LAND TRANSPORT
TRANSPORTATION

TRANSPORTATION

TRANSPORTATION

HAZARD SYMBOLS
HARMFUL
Contains:..2-Butoxyethanol
RISK PHRASES
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
SAFETY PHRASES
S36/37 - Wear suitable protective clothing and gloves.
S46 - If swallowed, seek medical advice immediately and show this container or label.
NATIONAL REGULATIONS GERMANY

WGK 1 (Annex 4)
9 / 11
PRODUCT
EC9610A

NATIONAL REGULATIONS HOLLAND

ABM RESULT
ABM RESULT Substance(s) % (w/w)
11
NATIONAL REGULATIONS NORWAY

YL code: 5 (> 3200 M/L)

Norway 019505
UNITED STATES
CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.,
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in
Regulation (EC) No.648/2004 on detergents.
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Ministry of International Trade & industry List (MITI).

R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Denmark +47-22-33-69-99
Finland +358-(0)9-4711
10 / 11
PRODUCT
EC9610A


Hungary +36-30-9-506-447
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
Saudi Arabia +966-(3)847-1515
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand
11 / 11
PRODUCT
NALCO EC6527G

PRODUCT NAME : NALCO EC6527G
APPLICATION : BIOCIDE

Postbus 627

NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 CHEMIA BRUGG AG (CH) +41 (0)56 4606260
NALCO DANMARK A/S +45-48195800 OEKOPHIL AG (CH) +41 (0)41 760 2220
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
NALCO ESPAOLA S.A. (E) +34 93-4095555 ZAO Nalco (RU) +7 (0)495 980 72 80
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO STERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 local support: Nalco Czechia s.r.o. +420 (0)2 679 123 50
(CZ)
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Hungary Kft. +36 (0)1 471 91 81
(HU)
NALCO ITALIANA S.R.L.(I) +39 06-542971 Local Support: Nalco sterreich +385 (0)1 377 95 21
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
NALCO LIMITED +44 (0)1606 74488 Local Support: Nalco sterreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation Office
ROMANIA (RO)
NALCO NETHERLANDS B.V. +31 (0)13-5952200

ELINCS NO NOTAS
Tetrakis(hydroxymethyl) phosphonium sulfate 259-709-0 T, N R23, R22, R41, 30 - 60
R43, R63, R50
Polymer containing phosphonate, sulphonate, and Polymer R52/53 1- 5
carboxyl functional groups, sodium salt
1/9
PRODUCT
NALCO EC6527G

Harmful if swallowed. Toxic by inhalation. Risk of serious damage to eyes. May cause sensitization by skin
contact. Very toxic to aquatic organisms. Possible risk of harm to the unborn child.
INHALATION :
Not a likely route of exposure. Toxic by inhalation.
SKIN CONTACT :
May cause irritation with prolonged contact. Prolonged or frequently repeated skin contact may cause allergic
reactions in some individuals.
EYE CONTACT :
Severely irritating. If not removed promptly, will injure eye tissue and may result in permanent eye damage.
INGESTION :
Not a likely route of exposure. Harmful if swallowed.
ENVIRONMENTAL HAZARDS :
Keep out of waterways. This product may pose a risk to the aquatic ecosystem if released.
INHALATION :
Get immediate medical attention. Remove to fresh air, treat symptomatically.
SKIN CONTACT :
Seek medical advice with urgency. For a large splash, flood body under a shower. Immediately wash with
plenty of soap and water. If symptoms develop, seek medical advice.
EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately
flush eye with water for at least 15 minutes while holding eyelids open.
INGESTION :
Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give
water to drink.
NOTE TO PHYSICIAN :
FLASH POINT : None
ignitable. Use extinguishing media appropriate for surrounding fire.
2/9
PRODUCT
NALCO EC6527G


May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire
conditions. May evolve oxides of phosphorus (POx) under fire conditions.

safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.

Prevent material from entering sewers or waterways. Spilled product may pose a risk to the aquatic ecosystem
if released. If drains, streams, soil or sewers become contaminated, notify local authority.
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled.
Store in suitable labeled containers. Store the containers tightly closed.

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.,
Stainless Steel 304, Stainless Steel 316L, TFE, Nitrile, Neoprene, Viton, EPDM, FEP (encapsulated), PTFE,
MDPE (medium density polyethylene), HDPE (high density polyethylene)

Carbon Steel C1018
SPECIFIC USE(S) :
BIOCIDE
3/9
PRODUCT
NALCO EC6527G

are shown below.

__ Tetrakis(hydroxymethyl) phosphonium sulfate TWA 2
the eyes.
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples
should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
PERSONAL PROTECTION
GENERAL ADVICE :
chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found
in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.
HAND PROTECTION :
conditions using gloves made from Nitrile . Gloves should be replaced immediately if signs of degradation are
SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The
applicable European standard can be found in EN ISO 20345.
EYE PROTECTION :
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.
4/9
PRODUCT
NALCO EC6527G

ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS :

Consider the provision of containment around storage vessels.
APPEARANCE Clear
ODOR None
FLASH POINT : None

SPECIFIC GRAVITY 1.24 (15.5 C)
pH () 4.0
STABILITY :
Avoid extremes of temperature.
None known

Under fire conditions: Oxides of carbon, Oxides of sulfur, Oxides of phosphorus
SENSITIZATION :
Repeated or prolonged contact may cause skin sensitization.
CARCINOGENICITY :
Hygienists (ACGIH).
5/9
PRODUCT
NALCO EC6527G

MOBILITY :

<5% 10 - 30% 10 - 30%
The organic portion of this preparation is expected to be readily biodegradable.
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be
burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT
suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
contractor.
EUROPE WASTE CODE :

6/9
PRODUCT
NALCO EC6527G

LAND TRANSPORT
Proper Shipping Name : TOXIC LIQUID, ORGANIC, N.O.S.
Technical Name(s) : Tetrakis(hydroxymethyl) phosphonium sulfate
UN/ID No : UN 2810
Hazard Class - Primary : 6.1
Packing Group : III
ADR/RID H.I.n. : 60
CLASSIFICATION CODE : T1

UN/ID No : UN 2810
Packing Group : III
IATA Cargo Packing Instructions : 618
IATA Cargo Aircraft Limit : 220 L (Max net quantity per package)
IATA Passenger Packing Instructions : Y611 / 611
IATA Passenger Aircraft Limit : 2 L / 60 L

UN/ID No : UN 2810
Packing Group : III
OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE : 61GT1-III
EMERGENCY ACTION CODE : 2X

HAZARD SYMBOLS
TOXIC
Contains:..Tetrakis(hydroxymethyl) phosphonium sulfate
RISK PHRASES
R23 - Toxic by inhalation.
7/9
PRODUCT
NALCO EC6527G

R41 - Risk of serious damage to eyes.

R43 - May cause sensitization by skin contact.
R50 - Very toxic to aquatic organisms.
R63 - Possible risk of harm to the unborn child.
SAFETY PHRASES
S23 - Do not breathe .. (gas/fumes/vapor/spray).
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
EUROPE
The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories

R23 - Toxic by inhalation.
R41 - Risk of serious damage to eyes.
R43 - May cause sensitization by skin contact.
R50 - Very toxic to aquatic organisms.
R63 - Possible risk of harm to the unborn child.
Denmark +47-22-33-69-99
Finland +358-(0)9-4711
Hungary +36-30-9-506-447
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
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PRODUCT
NALCO EC6527G


Saudi Arabia +966-(3)847-1515
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

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MATERIAL SAFETY DATA SHEET

EMERGENCY TELEPHONE NUMBER(S)

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : NALCO EC6080A

APPLICATION : SCALE INHIBITOR

COMPANY IDENTIFICATION : NALCO EUROPE B.V.

Date issued : 03.04.2007

COMPANY CONTACT TELEPHONE NUMBERS.

Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

EMERGENCY TELEPHONE NUMBER(S)

HUMAN HEALTH HAZARDS - ACUTE :

4. FIRST AID MEASURES

5. FIRE FIGHTING MEASURES

FLASH POINT : 105 C TCC

FIRE AND EXPLOSION HAZARD :

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :

EMERGENCY TELEPHONE NUMBER(S)

6. ACCIDENTAL RELEASE MEASURES

METHODS FOR CLEANING UP :

7. HANDLING AND STORAGE

SUITABLE CONSTRUCTION MATERIAL :

UNSUITABLE CONSTRUCTION MATERIAL :

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

Country/Source Substance(s) Category: ppm mg/m3

BELGIUM Ethylene Glycol (Aerosol.) TWA 20 52

EMERGENCY TELEPHONE NUMBER(S)

DENMARK Ethylene Glycol GV 10 26

FINLAND Ethylene Glycol HTP 8H 20 50

FRANCE Ethylene Glycol (Vapour.) VME 20 52

GERMANY Ethylene Glycol MAK 10 26

IRELAND Ethylene Glycol (Vapour.) TWA 20 52

ITALY Ethylene Glycol TWA 20 52

NETHERLANDS Ethylene Glycol (Mist.) MAC 10

NORWAY Ethylene Glycol (Dust) ADM. NORM 10

SPAIN Ethylene Glycol VLA-ED 20 52

SWEDEN Ethylene Glycol NGV 10 25

SWITZERLAND Ethylene Glycol TWA 10 26

UNITED KINGDOM Ethylene Glycol (Particulate.) TWA 10

POLAND Ethylene Glycol MAC-NDS 15

HUNGARY Ethylene Glycol K 52

CZECH REPUBLIC Ethylene Glycol PEL 50

EMERGENCY TELEPHONE NUMBER(S)

CROATIA Ethylene Glycol MDK 50 125

ROMANIA Ethylene Glycol TWA 52

SLOVAKIA Ethylene Glycol TWA 20 52

SLOVENIA Ethylene Glycol TWA 20 52

EMERGENCY TELEPHONE NUMBER(S)

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

FLASH POINT : 105 C TCC

10. STABILITY AND REACTIVITY

HAZARDOUS DECOMPOSITION PRODUCTS :

11. TOXICOLOGICAL INFORMATION

No toxicity studies have been conducted on this product.

EMERGENCY TELEPHONE NUMBER(S)

12. ECOLOGICAL INFORMATION

No toxicity studies have been conducted on this product.

ACUTE FISH RESULTS :

ACUTE INVERTEBRATE RESULTS :

Air Water Soil/Sediment

The portion in water is expected to be soluble or dispersible.