ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE: 2016 CRASH COURSE (C 7 A 1) DATE:

TOPIC: IUPAC, NOMENCLATURE, GOC

SECTIONI (Single Choice Questions)

This section contains 10 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONLY ONE is correct.

1. How many resonance structure can be drawn for the following molecule?

MeO CH3
(A) 1 (B) 4 (C) 3 (D) 2

2. Arrange the following acids according to their pKa decreasing order.

HClO HClO 2 HClO3 HClO 4
(a) (b) (c) (d)
(A) a > b > c > d (B) b > a > c > d (C) d > c > b > a (D) c > b > d > a

3. Find out the basic strength order of the given following bases
NH2
Cl 3C NH2 Cl 3C F 3C NH2
(a) (b) (c)
(A) a > b > c (B) c > b > a (C) b > c > a (D) b > a > c

4. Find out the acidic strength order (Ka)

H3C H2C OH
OH OH HS S
OH
(a) (b) (c) (d)
(A) a > b > c > d (B) d > c > b > a (C) c > d > b > a (d) a > b > d > c

5. Correct IUPAC name of the given following compound

O O
CH3
HO O

CH3
(A) 2-ethyl-3-methory-3-oxopropanole acid (B) 2-methanoylmethoxy butanoic acid methyl
(C) 2-carboxy butanoate (D) 2-methoxycarbonyl butanoic acid

6. Find out the correct order of Ka acidic strength

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

 O OH O OH O OH O OH

OH

HO OH HO OH
OH OH

I II III IV
(A) I > II > II > IV (B) II > IV > III > I
(C) II > I > III > IV (D) IV > II > III > I

7. K b order of the following given compounds

CH3
CH3 H3C CH3

N N
(a) (b)
(A) a > b (B) a < b (C) a b (D) None of these

8. Order of stability of free radical

CH3
CH3
CH3

H3C CH3

(a) (b) (c) (d) (e)

(A) a > b > d > c > e (B) a > c > b > d > e
(C) a > d > c > b > e (D) a > e > c > b > d

9. Find out the order of resonance energy

N S O
H
(I) (II) (III)
(A) I > II > III (B) II > I > III (C) III > I > II (D) III > II > I

10. IUPAC name of the given following compound is

H3C OH
(A) 6-hydroxyhex-2-en-4-yne (B) 1-hydroxyhex-4-en-2-yne
(C) Hex-2-en-yn-6-ol (D) Hex-4-en-2-ynol

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 SECTION-II (Multiple Choice Questions)
This section contains 3 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONE OR MORE is/are correct.

11. Which of the following statement will be correct?

O O O

H2N Cl

O O O
(A) Total no. of functional group will be your
(B) Double bond unsaturation value will be six
(C) Total no. of substituent is three
(D) Principle functional group is acyl chloride

12. Which of the following name will be correct?

OH OH

(A) cyclopenta-2, 4-dienol (B) 5-Hydroxy cyclopenta 1, 3-diene

Cl

Cl

(C) 5-chlorocyclopenta-1, 3-diene (D) 1-chloricyclopenta-1, 3-diene

13. Which of the following statement is correct?

O

OH

(A) Its common name is cinnamic acid

(B) Its IUPAC name is 3-phenyl propenoic acid
(C) It is a unsaturated hydrocarbon derivative
(D) It is a aromatic compound

14. Find out the correct statement

CH3
HN NH2
CH3

CH3
N

I II III
(A) I is more basic than II & III (B) order of K b is I > II > III
(C) order of K b is I > III > II (D) II is more basic I & II

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3

15. Find out the correct statement:
CH3

CH3 H3C
NH2

N CH3 N CH3 N CH3

(I) (II) (III) (IV)

(A) All have localized lone pair (B) All are equally basic
(C) I is more basic than II & III & IV (D) III is more basic than II & IV

16. Find out the correct statement.

(A) Anhydride is always treated as a principle functional group
(B) Ether always treated as a subtituent
(C) Anhydride is a derivative of carboxylic acid
(D) None of these

17. Which of the following is / are more stable than cis-but-2-ene?

H3C H3C CH3 CH3
CH2

(A) H3C (B) H3C (C) H3C (D) H3C

18. Which of the following compound exist in dipolar form?

O

(A) (B) (C) (D)

19. Which alkene is less stable than But-1-en?

CH3 H3C
CH2
CH2
(A)H3C (B) H3C (C) H2C CH2
(D)

20. Which order is / are correct?

O O

H3C H3C
OH OH
(A)
O O O

O 2N < Me3N < NC (K a )

(B) OH OH OH

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

 HN N
> HN N
(K b )
(C)
(D) Picric acid > formic acid (Ka )

21. Find out the correct statement about following cation.

G

(A) It is stabilized by 7 resonating structure

(B) It is stabilized by 8 resonating structure
(C) Benzene ring is present in four resonating structure
(D) Benzene ring is present in five resonating structure

22. Find out the true statement about the given compound is / are:

(A) given compound is aromatic (B) It exist in zwitter ion form

(C) given compound is anti aromatic (D) given compound is non aromatic

23. In which of the following cases second canonical form makes the greater contribution to the
resonance hybrid?
- + - +
(A) H N C O , H N C O
- +
H3C C O H3C C O
(B) ,

O O
(C)
+ +
OH2 OH2

(D)

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5

24. Which of the following order is correct for stability?
OH
H2O
+
+
OH2 H2O
+
> +
OH
+
<H O+ +
OH2
H O 2
(A) O (B) 2 2
+ CH3
+ OH2
OMe OH2

+ OH2
+ > + +
+
+
OH2
H O OH2
H2O
(C) 2 (D) H2O

25. Which of the following compounds is likely to adopt a planar conformation?

H + H
N

(A) (B) (C) (D)

26. Which of the following statements about benzene is correct?

(A) It is unstable than hexatriene
(B) The carbon-carbon bond lengths are all the same
(C) The carbon-carbon bond lengths are longer than ethene
(D) The carbon-carbon bond lengths are shorter than ethene

27. Which of the following reaction does not occurs as shown?

(A) HC CH + NaNH 2 NH 3 + HC CNa

(B) HC CH + NaOH H 2 O + HC C Na
O O O O

+ ++ NaOH H 2O +
+ +
NH3 NH3
H3N +
(C)H3N Na

(D) HClO 4 + HOSO3 Na H 2SO 4 + ClO 4 Na +

28. Which of the following reaction is / are favourable?

(A) (B)

(C) (D)

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29. Find out the correct statement
O O
|| ||
(A) Priority order of functional group in IUPAC system C H > C Cl > OH
(B) (X) All halogen is always treated as a substituent
O O
|| ||
(C) Priority order of functional group C OH > C H > OH
(D) Maleic acid is more acidic than fumaric acid

30. Find out the correct statement.

(A) pKa 2 of Maleic acid is more than fumaric acid
(B) Guanidine is a strongest base than pyridine
(C) Fomic acid is more acidic than benzoic acid
(D) Pyrrole is more basic than aniline

SECTION III (Integer Answer Type)

This section contains 20 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The correct digit below the question number in
the ORS is be bubbled.

31. How many compound is stronger base than NH 3 ?

NH2 H2N

NH NH2

H2N NH2 H2N N

N O
N H2N NH2 N H

32. How many groups shows both effect (M & +M)

R
H3C
NO 2 NO S =O CN
+
CH =
CH 2 COOH COO NH 2 N H3

33. How many compound is aromatic?

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 7

 O
CH2
O

34. How Many compounds will undergo resonance?

CH2
H2C CH2
H2C CH2 CH2

+
H2C NH3 N

35. How many acids is less acidic than acetic acid?

O OH

H O
N
H OH picric acid HClO 4
OH

Cl
H 2SO 4 Maleic acid HOCl = O COOH
O
O
HO N
HOC N HF HOI = O O

36. How many compound will undergo hyperconjugation?

CH3
CH3
CH3

CH3
H3C CH2 H2C
H3C
H3C Cl
CH2 CH2 CH2
Cl
H3C Cl H3C

37. How many compounds loose water upon treatment with HCl?

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 8

 OH O
OH
OH

OH
H2C
OH
OH
O OH
OH
OH
H CH2 H3C CH3

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 9

38. How many types of functional group are present?
O
O CH3 O

H OH
Br CH3
O O O Cl

39. How many structures are possible for the given molecular formula C7 H16 , in which five carbon
present in main chain or in parent chain?

40. How many -Hydrogen present in the given molecule?

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 10

 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
IIT JEE: 2016 CRASH COURSE DATE:
TOPIC: IUPAC, NOMENCLATURE, GOC

ANSWER KEY

1. (C) 2. (A) 3. (D) 4. (B) 5. (D)

6. (B) 7. (A) 8. (C) 9. (B) 10. (D)

11. (ABC) 12. (ACD) 13. (ABCD) 14. (AB) 15. (ACD)

16. (BC) 17. (ABCD) 18. (ABD) 19. (AC) 20. (ACD)

21. (AC) 22. (AB) 23. (BD) 24. (ABCD) 25. (AB)

26. (BC) 27. (BCD) 28. (BCD) 29. (BCD) 30. (ABC)

31. (3) 32. (4) 33. (5) 34. (5) 35. (3)

36. (6) 37. (6) 38. (8) 39. (5) 40. (6)

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 11