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PV =0.08206 nT
P ( psig ) +14.696
a) P ( atm )=
14.696
28.317 ft 3
V ( L ) =V ' ( ft 3 )
L
' 453.593 mol
n ( mol ) =n ( Ibmole )
1 Ibmole
T ( )32
T ( K )= + 273.15
1.8
= 0.308Ibmole
T =85
0.3 Ibmole CO
nCO =0.308 Ibmole
P=500 psi Ibmole
PV 0.0924 Ibmole
n ' tot =
10.73 T
28 Ibm
mco=0.0924 Ibmole
Ibmole
2.5872 Ibm
( 3000 psi+14.696 ) 3.5 ft 3=10.73 ( 0.308 Ibmole
c) Temperature
10551.436=3.30484 (T + 459.7)
( P' + 14.696 ) V ' =10.73 n' (T + 459.7)
P=3000 psi
T =2733.02
QUESTION 2
[ ]
()
P 2
q=C A
d 4
1 1
d2
[ ]
L3 T 2 M T 2 2
= L
T L2 M L3 L 4
1 ()
L
2 L
L [ ]
T 2 L2
T2
2
0
[ ( ) ]
2
T 2 L
2 L
L T
[ ]
T L3
L2 T
L
3
L
L ,it is not dimensionally homogenou s QUESTION 3
T
=54.46
M
a)
1 x
=
M M
1 0.25 x (0.75x )
= + +
54.46 44.05 58.08 60.05
x (0.75x)
0.0183621=5.6754 103+ +
58.08 60.05
60.05 x +58.08(0.75x)
0.012687=
3487.704
44.25 = 60.05x +5x +43. 56 58.08x
0.69 = 1.97x
X = 0.35
X = 35wt% acetone
Y= 0.75-0.35=0.4
Y=40wt% acetic acid
mol
nacetaldehyde=25 g
44.05 g
= 0.5675mol
mol
nacetone=35 g
58.08 g
=0.6026mol
mol
nacetic acid=40 g
60.05 g
= 0.666mol
nT= 0.5675+0.6026+0.666
=1.8361mol
0.6026 mol
Yacetone= =0.33
1.8361 mol
0.66 mol
Yacetic acid= =0.3 6
1.8361 mol
Yacetaldehyde = 1-0.33-0.36
=0.30
15.625 lbm
naldehyde= =0.3547 mol
44.05 lbm/lbmol
25 lbm
nacetic acid= =0.4163 mol
60.05 lbm/lbmol
nT= 0.3547+0.3766+0.4163
= 1.476mol
Question 4
30.0 cm3 of oxygen gas (MW 32.00,SG 1.141) is reacted with 30.0 cm 3 of
ammonia(MW 17.03,SG 0.682) to produce nitric oxide(MW 30.01,SG 1.340) and
water(MW 18.02,SG 1.00).The yield of nitroc oxide is found to be 35 %.
5 3
O2 + NH3 NO + H2O
4 2
For oxygen,
SG=
r
1.141=
1.205
kg
=1.375
m3
m
=
V
kg
=(1.375 m3 ) (3
5
10 m3 )
=4.125 105 kg
=0.04125 g
M
n=
MM
(0.04125 g)
= (32.00 g )
mol
For ammonia,
SG= r
0.682=
1.205 kg/m 3
kg
=0.82181
m3
m
=
V
m= V
=2.465 x 10-5 kg
=0.02465 g
M
n= MM
0.02465 g
= 17.03 g/mol
Oxygen,
Ammonia,
1.447 x 103
mol
1
=1.03128 x 10 -3 mol
= 40.31 %
iv.Calculate the mass(in gram) of nitric oxide and water produced from the
reaction
mol product
yield= x 100
mol limiting reactant
n NO
0.35 = 1.03128 x 103
kg
30.0 mol x (3.609 x 10-4 mol ) = 0.01083 g
For water,
100 35 = 65
n water
0.65 = 1.547 x 10
3
g
18 mol x (1.006 x 10-3 mol ) = 0.0181 g
QUESTION 5
i)
1.0 mol H2o /mol 1.0 mol H2o /mol 1.0 mol H2o /mol
total total total
1 2 3
D metric ton/year E metric ton/year F metric ton/year
0.5 mol NaCl/mol 0.65 mol NaCl/mol 0.9 mol NaCl/mol
total total total
0.5 mol H2o /mol 0.35 mol H2o /mol 0.1 mol H2o /mol
total total total NaCl & H2o
kg 1 mol
0.3968 ( 1.0 103 ) =6.837
s kg s
58.04
kmol
E=2.892+7.521
mol
C=0.6837
s
mol
10.41
s
F=0.6837+6.837
Evaporator 1
mol
7.521
s D= A+10.41
0.5 A=1.562
mol
A=3.123
s
D=3.123+10.41
Evaporator 2 mol
13.53
s
E=B+7.521