Sei sulla pagina 1di 4

# Instituto Politcnico Nacional

DIQI

Gpo: 2IM41
Tabla de datos

actico
30 0.5 0.7
40 0.7 1.1
50 0.8 2.2
60 0.83 3.5

## Determinacion de P Determinacion de la masa del

P=P cido Paire cido actico

m=v
P1=580 mmHg578 mmHg=2 mmHg
g
P2=578 mmHg574 mmHg=4 mmHg =1.05 3 v =10 ml=c m 3
cm
P3=577 mmHg563 mmHg=14 mmHg
g
P 4=576.7 mmHg556 mmHg=20.7 mmHg m=1.05 3
10 c m3=10.5 g
cm

Considerando RTwA
Determinacion de
Pi=
0.082 atm V
R=
molk
0.01<
v =10 ml=0.01< 0.082 atm
303.15 K0.175 mol =435.02 atm*
molk
m 10.5 g P1=
n= = =0.175 mol
pm g
60 760mmHg =330615 mmHg
mol
0.01<
de cido actico 0.082 atm
313.15 K0.175 mol =341521mmHg
molk
P2=
0.01<
0.082 atm
323.15 K0.175 mol =352427mmHg
molk
P3=
0.01<
0.082 atm
333.15 K0.175 mol =363333mmHg
molk
P 4=

## Determinacion de K Determinacion Determinacion de

Ka=4 (2 PiP) de y=InK 1
x= T
K 1=4 (23306152) =2644912 InK 1=14.7881
mmHg InK 2=14.8206 1
K 2=4 ( 23415214 ) =2732152 x 1=
InK 3=14.8520 303.15 K =0.
mmHg 003299
K 3=4(235242714 ) =2819360 InK 4=14.8825
1
x 2=
mmHg
313.15 K =0.
K 4=4 (236333320.7) =29065 003193
Y=
1 -317.96x+15.836
80mmHg x 3=
323.15 K =0.
In K =b= 15.836
003095
1 H
x 4= InK= RT
333.15 K =0.

003002

H=Rm=317.968.314=2643.52 J mol/k

G=( InKRT ) = H
Hdisociaci n=
2
8.314 J
G 1= -(15.836*
molk 2643.52 J
Hdis 1= =1321.76 J
2
303.15K)=-39913 J
8.314 J mol/k
G 2= -(15.836*
molk H
S=
T
313.15K)=-41229.6 J
8.314 J 1321.76
G 3= -(15.836* S= =44.033 Jmol
molk 30

323.15K)=-42546.3 J 1321.76
S= =33.025 Jmol
40
8.314 J 1321.76
G 4= -(15.836* S= =26.42 Jmol
molk 50

S= =22.01 Jmol
60