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K.S ACADEMY, SALEM-QUESTION PAPER
PG TRB , POLYTECHNIC TRB & TNSET

COACHING CENTRE FOR PHYSICS
Slip test- Spectroscopy
Time:1Hour Marks: 40
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Answer all the question:
1.The frequency of the Raman stoke equation is represented by the following

equation

a) = 0 + b) = 0 c) 2 = 0 d) = 0

2.In the rotational spectrum of the diatomic molecule
a)frequency lines are not equally spaced
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b)frequency lines are equally spaced
c)energy levels are equally spaced
d)energy difference two consecutive energy levels are equal
3.The lowest energy of vibrational rotational spectra is

1
a) + 1 b) + c) 2 d)
2 2
4.In the case of stokes line observed in Raman effect, the frequency of the line
is
a)less than that of the incident radiation
b)more than that of the incident radiation
c)equal to that of the incident radiation
d) any of these
K.S ACADEMY, SALEM PG TRB, POLYTECHNIC TRB & TNSET COACHING CENTRE FOR
PHYSICS CELL:9042976707 Page 1
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5. Pure rotation spectra lie in the
a)near the infrared region b)far infrared region
c)visible region d)ultraviolet region
6. Which quantum number were used by Sommerfield in order to explain the

fine structure of spectral lines?
a) and b) and c) and d)
7.Which of the following is the selection rule for fundamental band?
a) = 2 b) = 0, 1 c) = 1 d) = 3
8.For rotational spectrum
a)energy levels are not equally spaced but frequency is equally spaced
b)energy and frequency are equally spaced
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c)both the energy and frequency are not equally spaced
d)energy levels are equally spaced but frequency levels are not equally spaced
9.For which of the following can both quantum number and the associated
energy be zero?
a) n for the particle in a 1-D box b) J for the rigid rotator
c) v for harmonic oscillator d) n for hydrogen atom
10. The relation between wavelength and wave number is__________

1
a) = b) = c) = 2 d) all the above
11.The value of 2 corresponding to minimum and maximum wavelength in

Balmer series are respectively
a) 3 b) 3 and 0 c) 0 and3 d) and 3
12.Pure vibrational spectra are observed
a)only in solids b)only in liquids
c)only in gases d)both in liquids & gases
13. A linear molecule of N atoms has ______ vibrational degrees of freedom
a) 3 5 b) 3 6 c) 3 d) 3 4
14.The symmetric stretching mode of vibration of CO2 is
a) Raman active b) Raman inactive c) IR active d) both Raman & IR active
15. A simplest diatomic molecule (e.g. 2 , 2 , , ) may be considered as two

point masses 1 and 2 connected by a spring like force. Such a molecule can
vibrate along the line joining the atoms and may be considered as a two-body
oscillator. The frequency of vibration of this oscillator is given by
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a) =
1
2

b) =
1
2

c) =
1
2
3
2
d) =
1
2
2

16.The possible values of orbital quantum number are_________

a) from 0 to (n-1) b) from 0 to n
c) from 0 to (n+1) d) all
17.In rotational Raman spectrum what is the selection rule for Rayleigh line
a) = 1 b) = 1 c) = +2 d) = 0
18.The convergence limit of the Lyman series is

3 4
a) = b) = c) = d) = 3
4 4
19.The 3 principal moment of inertia of a spherical top is
a) = > b) = < c) = , = 0 d) = =
20.In rotational Raman spectrum the Raman shift of stokes lines are
a)2B, 4B, 6B b) 6B, 10B, 14B,
c) -2B, -4B, -6B, d)2B, 6B, 12B,
21.In which of the following transitions of an electron in hydrogen atom the

energy variation is minimum?
a) from n=5 to n=4 b) from n=3 to n=2
C) from n=2 to n=1 d) from n=4 to n=3
22.The rotational kinetic energy of a rigid diatomic molecule is
2 2
a) = +1 b) = 8 2 + 1
2
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2
c) = 2 2 + 1
2
d) = 8 2 + 1
23. Globar source is
a)IR source b)microwave source c)UV source d)X-ray source
24. Which of the following is/are true?
a)Rotational energy level is ( + 1)
b)The vibrational-rotation spectra fall in the infrared region.
c)various electronic state do not have any systematic separation for a given
molecule
d) all the above
25.In vibrational spectra which of the following transistion most intense
a) " = 0 = 2 b) " = 0 = 1
c) " = 0 = 3 d) " = 0 = 4
26.The change in energy in an electronic transistion is of the order of
a) 0.1 b) 10 100 c) 5 10 d) 20 20
27. Why 2 , 2 , 2 etc does not show a rotational spectrum?
a) no rotation b) no diffraction
c) no permanent dipole moment d) no vibration
PROBLEM FOR POLYTECHNIC TRB( 2 mark question)
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28. In a NMR spectrometer, the resonance transistion is shifted from the
reference (400) by 529 , and then its chemical shift is
a) 5.2 b) 2.0 c) 10.5 d) 1.3
29. A sample was excited by 4358 line of Hg. One Raman line is observed at
4447 then the other associated
a) 4325 b)4269 c)4516 d)4482
30. The ratio of minimum wavelengths of Lyman and Balmer series will be
a) 1.25 b) 0.25 c)0.5 d) 10
31. If the mass of electron is reduced to half, then the Rydberg constant is
a) Remains unchanged b) Becomes half
c) Becomes double d) Becomes one-fourth
32. In symmetric stretching mode of 2
a) both Raman and IR are active b) Raman inactive & IR active
c) both Raman and IR are inactive d) Raman active & IR inactive
33. The force constant of the bond in 187 /. The spacing between its
vibrational energy level is ( 1.14 1026 )
a) 8.44 b) 84.4 c) 844 d) 0.0844
34. The harmonic vibrational frequency of HCl in wavenumbers is 2989.6 1

then the energies of the first vibrational levels in Joules
a) 5.67 1020 b) 8.8 1020 c) 1.8 1020 d) 2.96 1020 J.
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35. The energy gap between the two vibrational levels of a hole molecule is
0.36ev then its zero point energy will be
a)0.18ev b)0.36ev c)0.09ev d)0.72ev
36. The number of normal modes in 2 is
a) 6 b) 4 c) 3 d) 5
37. The no of fundamental vibrational model of 2 molecule is
a)four ;two are Raman active and two are infrared active
b)four ;one is Raman active and three are infrared active
c)three; one is Raman active and two are infrared active
d)three; two are Raman active and one is infrared active
38. The wavelength of Lyman series line due to the transistion from =
2 = 1 is
a) 12nm b) 1.2nm c) 120nm d) 1200nm
39. For HF molecule, = 4050 1 , rotational constant is half and moment of

intertia = 1.38 x 1047 kg-2 the internuclear distance r is
a) 0.94 A b) 0.19 A c) 0.54 A d) 1.94 A
40. In a weak field the sodium D, (5896 ) and 2 (5290) are split into ____
and ___ lines respectively
a) 6, 4 b) 3, 6 c) 4, 6 d) 6, 3
ANSWER KEY GIVEN AT THE LAST PAGE
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&
K .S !
( )
TRB
TRB
.
UNIT SLIP TEST , UNIT TEST .
UNIT 400
.
1/3 rd PORTION TEST , HALF PORTION TEST .
(TEN FULL TEST) .
4000
.
2001 PG TRB
.
2006 , DIET

(Polytechnic , DIET & Engineering TRB )
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.
TNPSC (BT SCHOOL

ASST ) PG TRB SYLLABUS
.
TNSET ,
DIET LECTURER TRB & ENGINEERING ASSISTANT PROFESSOR TRB,
SCIENTIFIC ASSISTANT (TNPSC ), DEO (TNPSC MAINS PAPER -3) , TNPSC
SCHOOL ASSISTANT .
EDUCATION , PSYCHOLOGY & GK

Your time is limited, so dont waste it.
! !! !!!
13.5.2017
K.S ACADEMY
(STC )
-1
13.5.2017
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Answer key
.
Q.NO ANS Q.NO ANS Q.NO ANS

.........
Q.NO ANS
1 B 11 D 21 A 31 B
2 B 12 B 22 C 32 D
3 D 13 A 23 A 33 D
4 A 14 A 24 D 34 D
5 B 15 A 25 B 35 A
6 A 16 A 26 C 36 C
7 C 17 D 27 C 37 B
8 A 18 A 28 D 38 C
9 B 19 D 29 B 39 A
10 A 20 B 30 B 40 C

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PG TRB , POLYTECHNIC TRB & TNSET

1.The frequency of the Raman stoke equation is represented by the following

2.In the rotational spectrum of the diatomic molecule

a)frequency lines are not equally spaced

c)energy levels are equally spaced

d)energy difference two consecutive energy levels are equal

3.The lowest energy of vibrational rotational spectra is

a)less than that of the incident radiation

b)more than that of the incident radiation

c)equal to that of the incident radiation

5. Pure rotation spectra lie in the

a)near the infrared region b)far infrared region

c)visible region d)ultraviolet region

6. Which quantum number were used by Sommerfield in order to explain the

7.Which of the following is the selection rule for fundamental band?

8.For rotational spectrum

b)energy and frequency are equally spaced

a) n for the particle in a 1-D box b) J for the rigid rotator

c) v for harmonic oscillator d) n for hydrogen atom

10. The relation between wavelength and wave number is__________

11.The value of 2 corresponding to minimum and maximum wavelength in

12.Pure vibrational spectra are observed

a)only in solids b)only in liquids

c)only in gases d)both in liquids & gases

13. A linear molecule of N atoms has ______ vibrational degrees of freedom

14.The symmetric stretching mode of vibration of CO2 is

a) Raman active b) Raman inactive c) IR active d) both Raman & IR active

15. A simplest diatomic molecule (e.g. 2 , 2 , , ) may be considered as two

16.The possible values of orbital quantum number are_________

18.The convergence limit of the Lyman series is

19.The 3 principal moment of inertia of a spherical top is

a)2B, 4B, 6B b) 6B, 10B, 14B,

c) -2B, -4B, -6B, d)2B, 6B, 12B,

21.In which of the following transitions of an electron in hydrogen atom the

22.The rotational kinetic energy of a rigid diatomic molecule is

23. Globar source is

a)IR source b)microwave source c)UV source d)X-ray source

24. Which of the following is/are true?

a)Rotational energy level is ( + 1)

b)The vibrational-rotation spectra fall in the infrared region.

d) all the above

25.In vibrational spectra which of the following transistion most intense

26.The change in energy in an electronic transistion is of the order of

27. Why 2 , 2 , 2 etc does not show a rotational spectrum?

c) no permanent dipole moment d) no vibration

PROBLEM FOR POLYTECHNIC TRB( 2 mark question)

a) 5.2 b) 2.0 c) 10.5 d) 1.3

a) 4325 b)4269 c)4516 d)4482

32. In symmetric stretching mode of 2

a) both Raman and IR are active b) Raman inactive & IR active

c) both Raman and IR are inactive d) Raman active & IR inactive

a) 8.44 b) 84.4 c) 844 d) 0.0844

34. The harmonic vibrational frequency of HCl in wavenumbers is 2989.6 1

a) 5.67 1020 b) 8.8 1020 c) 1.8 1020 d) 2.96 1020 J.

a)0.18ev b)0.36ev c)0.09ev d)0.72ev

36. The number of normal modes in 2 is

37. The no of fundamental vibrational model of 2 molecule is

b)four ;one is Raman active and three are infrared active

c)three; one is Raman active and two are infrared active

d)three; two are Raman active and one is infrared active

a) 12nm b) 1.2nm c) 120nm d) 1200nm