9.

DERIVADA DE WAGNER PARA OBTENER H

1.5 3 6
d P Ax+ B x + C x + D x
ln = .(1)
dx Pc 1x

X=1-Tr

dx T
=1 (2)
dT Tc

x
1


1.5 3 6 (2.1)
d
ln
P
=
( 1 x ) (
dAx +B x +C x + D x
dx )
Ax+ B x1.5 +C x3 + D x 6 (
d 1x
dx
)

dx Pc

x
1

2

0.5 2 5 1.5 3 6
P ( 1x ) ( A+1.5 B x +3 C x +6 D x ) ( Ax+ B x +C x + D x )(1) (2.2)
=
Pc
d
ln
dx

( A+1.5 B x 0.5 +3 C x 2 +6 D x5 ) Ax1.5 B x1.5 3 C x 36 D x6 + Ax+ B x 1.5 +C x 3+ D x 6

x
1

2

P
=
d Pc
ln
dx

(2.3)
( A+1.5 B x 0.5 +3 C x 2 +6 D x5 ) 0.5 B x 1.52C x 35 D x 6
x
1

2 (2.4)

P
=
d Pc
ln
dx

1.5 x 0.50.5 x 1.5

A + B()+C ( 3 x 22 x3 ) + D (6 x5 5 x6 )

x
1

2 (3)


P
=
Pc
d
ln
dx

1 0.5 1 0.5
1.5( ) 0.5( )
Tc Tc
1 2 1 3 1 5 1 6
A + B()+C 3(( Tc
) 2( ) + D(6(
Tc ) Tc
) 5(
Tc
))

x
1
(3.1)
2


P
=
Pc
d
ln
dx

dx T
=1
dT Tc
 dx 1
= (4)
dT Tc

1
Tc
1

2
dx
0.5 1.5

2 3 5 6 * dT (5)
A+ B( 0.5
0.5 ) +C ( 3 2 )+ D( 6 5 )
P Tc Tc Tc Tc Tc Tc
=
Pc
d
ln
dx

0.5 1.5 2 3 5 6
A + B( 0.5 0.5 ) +C( 3 2 )+ D( 6 5 )=
Tc Tc Tc Tc Tc Tc

1 P
P d
dlnPT dln P Pc
[ Pc = ](6)
dT Pc
dT
Pc

2
P
P 1
d (1+ ) (7)
Pc Tc
=
dT Pc

TR
2
P
vap 1
H = (1+ Tc ) .(8)
Pc

g l
V= V V

TP
V= P
 dP H
=
dT T V

dP
TR
vap dT
V =
P

TR
P
1 2
(1+ )
Tc
TR
Pc
V vap =
P

0.5 1.5 2 3 5 6
A + B( 0.5
0.5
) + C( 3 2 )+ D( 6 5 )
Tc Tc Tc Tc Tc Tc
2
P
1
(1+ )
Tc
TR
Pc
V vap =
P

5 6
6
5 TR
Tc Tc
vap
H = .(8)
0.5 1.5 2 3
A + B( 0.5 0.5 ) +C( 3 2 )+ D
Tc Tc Tc Tc

Tc= 508.3k

Pc= 47.6 bar

P= 585 mmHg______ 0.7799 bar

 vap
H =

5 6
325.158.314 x 105
508.3 k 508.3 k 5
6

47.6

0.5 1.5 2 3
8.16927 9.43213 x 102
(
508.3 k
0.5

508.3 k )
0.5
8.10040 ( 3

508.3 k 508.3 k
2
)+7.85

H vap=

CONSTANTES

A -8.16927

B -9.43213x 10-2

C -8.10040

D 7.85

8.- H a diferentes temperaturas

H 1
Ln P= R
( )
T

H
1
Ln (97)= J
8.314 K * 325.15 K
mol

J
H= 12366.8 molK

H
1
Ln (584)= J
8.314 K * 366.15 K
mol
 J
H= 19391.1 molK