Khairul - Naim.bin - Ahmad 109213 PDF

June 2015 Simulation of
Ethyl Acetate
Synthesis via
Reactive
Distillation
Bachelor Final Year Project
Student: Khairul Naim Bin Ahmad

Supervisor: Manuel Jos Lis Arias
Simulation of Ethyl Acetate Synthesis via Reactive Distillation | Khairul Naim Bin Ahmad
Abstract
Ethyl acetate (EtAc) is mainly used as solvent in paints, adhesives and coatings, eliminating the use of
aromatic compounds. Reactive distillation is a type of process intensification in which the separation
and reaction is combined in one vessel. In this work, reactive distillation (RD) process for EtAc was
implemented using process simulator Aspen HYSYS by applying the data obtained from the
bibliography. A sensitive analysis was performed to determine the effects of key design and
operating variables on column performance and, subsequently, an optimal column configuration
was obtained.
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Contents
Objectives ............................................................................................................................................... 3
Introduction ............................................................................................................................................ 4
Ethyl acetate ....................................................................................................................................... 4
Synthesis of ethyl acetate ............................................................................................................... 4
Reaction kinetics and parameters .................................................................................................. 5
Reactive Distillation ............................................................................................................................ 5
Principles of Reactive Distillation .................................................................................................... 7
Benefits and limitations of Reactive Distillation ............................................................................. 9
Applications of Reactive Distillation ............................................................................................. 12
Aspen HYSYS process simulator ........................................................................................................ 12
Simulation of Reactive Distillation for synthesis of ethyl acetate .................................................... 13
Methodology......................................................................................................................................... 15
Process Description ........................................................................................................................... 15
Process development........................................................................................................................ 17
Defining the simulation basis ........................................................................................................ 17
Add the feed stream ..................................................................................................................... 18
Add the distillation column ........................................................................................................... 20
Adding the reaction ...................................................................................................................... 22
Adding the reaction to the column ............................................................................................... 22
Results and discussions ......................................................................................................................... 25
Effect of feed temperature, TF. ......................................................................................................... 25
Effect of number of stages, n. ........................................................................................................... 26
Effect of kinetic model ...................................................................................................................... 27
Effect of the molar feed ratio of HAc to EtOH. ................................................................................. 28
Effect of reflux ratio, R ...................................................................................................................... 29
Effect of activity model ..................................................................................................................... 30
Effect of rectifying and stripping stages ........................................................................................... 32
Conclusions ........................................................................................................................................... 33
Nomenclature ....................................................................................................................................... 34
Bibliography .......................................................................................................................................... 34
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Objectives
a) To simulate the reactive distillation of esterification of acetic acid and ethanol using the
Aspen HYSYS process simulator.
b) To perform the sensitive analysis to determine the effects of operating variables on column
performance (kinetic model, reflux ratio, molar feed ratio, number of stages, etc.)
c) To obtain the optimum column configuration.
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Introduction
Ethyl acetate
Ethyl acetate is the organic compound with the formula CH3COOC2H5 and having a molecular weight
of 88.10 gmol-1. This compound liquid is colorless, with a characteristically sweet, pleasant odor.
Ethyl acetate has been largely used as a solvent in paints, coatings, inks and adhesives. It has also
been used as a solvent in many chemical processes as a green alternative, eliminating the use of
aromatic compounds, which generate serious damage to the environment and human beings [1].
Synthesis of ethyl acetate
Ethyl acetate can be produced industrially in three ways: the Fischer esterification process,
Tishchencko reaction and the addition of acetic acid to ethylene.
Fischer esterification (Eq. (2.1)) is a classic process which ethyl acetate is formed by the reaction of
ethanol and acetic acid using acidic catalysts [2] such as sulfuric acid and para-toluene sulfonic acid
(PTSA) [3] [4].
2 5 + 3 3 2 5 + 2 (2.1)
This reaction converts ethyl acetate in about 65% yield at room temperature [5]. In the United
States, this method is used commercially to produce more than 100 million pounds of ethyl acetate
annually, mainly for use as a solvent in the paint industry, but also as a solvent for nail polish and
various glues [6].
The Tishchenko reaction (Eq. (2.2)) between two similar aldehydes (acetaldehyde) gives an ester
(ethyl acetate) by adding alkoxide catalyst to acetaldehyde.
23 3 2 5 (2.2)
The exothermic conversion of acetaldehyde takes place at 0 5 C (with cooling) in this solution.
This reaction gives the selectivity roughly 96% at conversion 95% (based on acetaldehyde) [2].
The addition of acetic acid to ethylene (Eq. (2.3)) is newly commercialized. It uses clay and
heteropoly acids (HPA) as catalysts.
2 = 2 + 3 3 2 5 (2.3)
This new reaction has considerable benefits over conventional technologies since it eliminates the
intermediate step for the production of ethanol and also avoids environmental hazards related with
other processes by using supported heteropoly acid on silica [7].
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Reaction kinetics and parameters
Out of these three processes, we will focus on Fischer esterification as the process to be simulated.
The reversible esterification reaction is shown as below:
k1
2 5 + 3 3 2 5 + 2 (2.4)
k2
Where k1 and k2 are forward and backward rate constants.
The rate model is:
= 1 2 2 (2.5)
The rate constants k1 and k2 can be presented by Arrhenius equation:

1 = ( ) 2 = ( ) (2.6)

Where A is pre-exponential factor and Ea is activation energy. Several authors have calculated the
kinetic parameters by conducting the experiment such as Calvar et al. [8] and Erol [9].
Calvar et al. [8] studied the homogenous reaction (esterification of hydrolysis) catalyzed by acetic
acid by taking into account the activity coefficient. The kinetic parameters were calculated using
ASOG [10] and UNIFAC [11] methods.
Erol [9] carried out experiment of esterification with acidic polymer catalyst and found that
heterogeneous catalyst is very effective from the point of view of activity, selectivity, reuse and non-
corrosiveness compared to homogeneous catalyst.
Reactive Distillation
Most chemical processes comprise two important operations (reaction and separation) that are
typically carried out in different sections of the plant and use different equipment. In the reaction
section, the type of reactors that are used typically are CSTR, tubular or batch with variety of
conditions (catalyzed, adiabatic, cooled or heated, single phase, multiple phase, etc.). The separation
section consists of several types of operation (distillation, extraction, crystallization, adsorption,
etc.). Instead of conducting the reaction and separation in separate units and vessels, it is sometime
possible to combine in a single vessel, in other words, to intensify the process. This integration
concept is called reactive distillation (RD), when heterogeneous catalysts are applied the term
catalytic distillation is always used [12].
There has been growing interest in RD. several hundred papers has been published in recent years.
Fig. 2.1 shows the rate of growth in the literature and patents during the last 4 decades (U.S. only).
In a review of Malone et al. [13], a total of 562 publications from 1970 to 1999 and 571 U.S. patents
from 1971 to 2000 were published. Recently updated survey by Gorak et al. [14], survey shows 1979
publications 278 U.S. patents were published between 2000 and 2011.
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Figure 2.1: Publications or U.S patents including reactive and catalytic distillation for the period of 1970-2010.
Most successful application of RD is the manufacturing of methyl acetate by Eastman Chemical

Company. Only one column is needed instead of nine and a reactor. Jeff Siirola reported that this
single reactive column by Eastman improves by 5 times reduction of energy used and 5 times lower
capital investment [15].
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Figure 2.2: Conventional (left) and intensified (right) methyl acetate synthesis processes. (Source Stankiewicz et al. [16])
Fig. 2.2 shows the conventional and intensified processes of methyl acetate synthesis. The
conventional process consists of one reactor followed by eight distillation columns and one
extraction column. The intensified (Eastman) process uses reactive distillation.
Principles of Reactive Distillation
Typically, a RD column equipment consists of a reactive column with the feed input (Fig. 2.3).
Reactive column can be divided into three different zones: rectifying, reactive and stripping. The
rectifying section and the stripping section serve as the reactant recovery from product. However,
they may not be needed depending on the reaction and desired separation. In the reactive zone,
chemical reaction and distillation occur simultaneously [17]. Reactive zone also is the place where
catalysts, either homogeneous or heterogeneous are packed. The feed input can be either single or
double. Double feed input can improve the contact between the reactants, resulting more uniformly
distributed reaction in the column [18].
Reactive distillation is applied whenever a liquid phase reaction is carried out with a large excess of
one reactant, where conventional process experience high costs due to the recycle of the excess
reactant. In certain cases, RD can normally be carried out closer to stoichiometric feed conditions,
therefore eliminating recycle cost. The continuous separation of products from reactants that occurs
in RD causes the reaction to proceed in forward reaction by Le Chateliers principle [19].
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Figure 2.3: Schematic diagram of a typical reactive distillation configuration. (Source Agirre et al. [20])
Combining reaction with distillation is not always advantageous [21]. The in situ separation in the
reaction zone or vice versa leads to complex interactions between vapor-liquid equilibrium, mass
transfer rates, diffusion and chemical kinetics [22] [23].
In designing a reactive distillation column, the model of the process is required. There are two types
of modelling approaches available in the literature for reactive distillation: the equilibrium stage
model and the non-equilibrium stage model [24].
The EQ stage model assumes that the vapor and liquid leaving on each stage are in equilibrium with
each other. This model is mathematically much simpler and computationally less intensive [25]. On
the other hand, the non-equilibrium one is more consistent with the real world operations [26].
According to Taylor et al. [23], in recent years reactive distillation has been modelled using non-
equilibrium (NEQ) rate-based model rather than equilibrium (EQ) stage model. This NEQ approach
takes into account heat and mass transfer through V-L interface using two film models which require
proper mass and heat transfer coefficient estimation [27].
There are two different types of reactive separation process of NEQ rate-based model: a
homogeneous system in which the reaction (catalyzed or not) takes place only in the liquid phase, or
heterogeneous system in which a solid phase is present to catalyze the reaction.
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Figure 2.4: Transport process for (a) Homogeneous liquid phase reaction, and (b) Heterogeneous catalyzed reaction. (Source
Taylor et al. [23])
Fig. 2.4 shows the various transfer processes in homogeneous and heterogeneous RD. The transport
processes for homogeneous system can be described as follows:
a) Mass transfer through the vapor film

b) Mass transfer with reaction in the liquid film
c) Reaction in the bulk liquid
While for the heterogeneous system:
a) Transport of reactants from the bulk vapor to bulk liquid

b) Transport of reactants from the bulk liquid to the catalyst surface
c) Reaction at the surface
d) Transport of reaction products from the catalyst surface to the bulk liquid
e) Transport of the reaction products from the liquid to the bulk vapor.
Benefits and limitations of Reactive Distillation
The advantages of RD are discussed by Gorak et al. [14].
i. Chemical equilibrium limitation can be overcome.

For chemical equilibrium limited reactions, continuous removal of one of the products
increases conversion as it converts a reversible reaction into an irreversible one. Thus, a
reactant conversion approaching 100% is achievable.
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ii. Higher selectivity can be achieved

Undesired side reactions are suppressed through removal of the target product from the
columns reactive zone. Compared to conventional setup, undesired side reactions results
the formation of byproducts and this will require more than single distillation column to
purify the product.
iii. Heat of reaction can be used in situ for distillation

For exothermic reactions, the heat of reaction can be directly used to provide the heat of
vaporization. This leads to the reduction of reboiler duty and hotspots are avoided due to
the vaporization of liquid phase.
iv. Overcoming of azeotropes

Azeotropes of the product mixture from the reactor can be avoided by reacting the mixture
under specific conditions in the column.
v. Simplified separation of close-boiling components

A reactive entrainer can be used to react with one of the components to form an
intermediate product whose boiling point facilitates the separation. The backward reaction
of intermediate product is performed in a subsequent reactive distillation column. This
method is depicted in Fig. 2.5.
vi. Capital savings

Simplification or elimination of the separation system can lead to a significant reduction in
plant costs. Esterification of methyl acetate by Eastman (Fig. 2.2) presents an industrial
example of such energy savings.
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Figure 2.5: Separation of reactive and inert components with close boiling points, facilitated by reactive distillation. (Source
Stankiewicz et al. [16])
Due to its complexity, several constraints and difficulties limit the successful application of RD. Some
of the constraints described by Towler et al. [28] are the following:
I. Volatility constraints
The reagents and products must have suitable volatility to maintain high concentrations of
reactants and low concentrations of products in the reaction zone.
II. Residence time requirement

If the residence time for the reaction is long, a large column size and large tray hold-ups will
be needed and it may be more economic to use a reactor-separator arrangement.
III. Scale up to large flows

It is difficult to design RD processes for a very large flow rates because of liquid distribution
problems in packed RD columns.
IV. Process conditions mismatch

In some processes the optimum conditions of temperature and pressure for distillation may
be far from optimal for reaction and vice versa.
To overcome these constraints, heuristics, or rules-of thumbs, have been published from time to
time to provide guidance and insight for initial analysis of process feasibility and conceptual design.
But still, the literature specific to reactive distillation heuristics is limited [17].
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Applications of Reactive Distillation
Commercial applications of RD reported by Seader et al. [29]:
I. Esterification of acetic acid with ethanol to produce ethyl acetate and water.
II. Reaction of formaldehyde and methanol to produce methylal and water, using a solid acid
catalyst [30].
III. Esterification of acetic acid with methanol to produce methyl acetate and water, using
sulfuric acid catalyst, as patented by Agreda and Partin [31], and described by Agreda, Partin
and Heise [32].
IV. Reaction of isobutene with methanol to produce methyl-tert-butyl ether (MTBE), using a
solid, strong-acid ion exchange resin catalyst, as patented by Smith [33] [34] [35] and further
developed by DeGarmo et al. [36].
Aspen HYSYS process simulator
HYSYS offers a high degree of flexibility because there are multiple ways to accomplish specific tasks.
This flexibility combined with a consistent and logical approach to how these capabilities are
delivered makes HYSYS an extremely versatile process simulation tool [37]. HYSYS is widely used in
universities and colleges in introductory and advanced courses especially in chemical engineering. In
industry the software is used in research, development, modelling and design [38].
The built-in property packages in HYSYS provide accurate thermodynamic, physical and transport
property predictions for hydrocarbon, non-hydrocarbon, petrochemical and chemical fluids. They
are divided into five basic methods [39]:
I. Equations of state (LKP, PR, SRK and their modifications) for rigorous treatment of
hydrocarbon systems
II. Semi-empirical models (Chao-Seader and Grayson-Streed)
III. Vapour pressure models (Antoine, Braun k10, Esso K) for the heavier hydrocarbon systems
IV. Activity coefficient models (Margules, UNIQUAC, Van Laar, NRTL, Wilson and their
modifications, etc.) for chemical systems.
V. Miscellaneous (special application) models (Amines and steam packages).
The calculation method for distillation in HYSYS is done to a high standard in accordance with the
matrix method. A quick convergence and short simulation time is therefore guaranteed. In most
cases, the user need not be concerned with the details of the internal calculation, this is done
automatically by HYSYS [39].
For this study, we used HYSYS v8.0, the latest version of HYSYS to simulate the reactive distillation.
HYSYS provides many built-in modules for simulating various processes. However for reactive
distillation, it is only possible to simulate RD with reactions taking place in homogeneous phase. It is
not directly suitable for the simulation of the heterogeneous catalytic distillation process.
However, Bumbac et al. [40] managed to develop a model for heterogeneous RD and implement the
model in the Aspen HYSYS simulation environment. Reactive section consists of equal CSTR in series
with same geometry and size. The flow and mixing in the reaction zone is approximated by a
backflow cell model (BCM) with forward flow of the liquid and a back flow of vapour in the reactive
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part of RD zone. Both stripping and rectifying zone are simulated as refluxed absorber and reboiled
absorber respectively. Fig. 2.6 shows the process flowsheet of RD column.
Figure 2.6: Simplified flowsheet for RD column by Cristian et al [40]. (I), (II), (III) and (IV) are stripping section, reactive part,
rectifying section and preliminary reactor respectively,
Simulation of Reactive Distillation for synthesis of ethyl acetate
Esterification of acetic acid with ethanol to produce ethyl acetate is one such process where RD has
been implemented successfully. The studies of RD are usually divided into experimental and
simulations parts.
Singh et al. [4] carried out the simulation of industrial RD column using process simulator Aspen Plus.
The 50-stage RD column was simulated using non-equilibrium (NEQ) rate-based model to predict the
composition profile in column based on the plant scale data in literature. As the available activity
models could not give good prediction, a new set of binary interaction parameters is established for
the NRTL model, which give close prediction of composition profile in the plant scale RD column.
There are some authors who have performed simulation of RD of esterification to obtain the
optimum column configuration. Wiheeb et al. [39] used the Aspen HYSYS process simulator to find
the best operating condition. Kinetic parameters of Calvar et al. [8] have been applied to the
simulation. The activity models (NRTL, UNIFAC, Wilson) have been compared for each analysis
(effect of water content in feed, bottom temperature, reflux ratio). Huang et al. [41], conducted a
pilot plant experiment and simulation of RD using Aspen Plus. By applying equilibrium (EQ) model to
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simulation, the key operating parameters has been analysed such as reflux ratio, feed stage location,
molar feed ratio, etc. Both Wiheeb et al. [39] and Huang et al. [41] concluded that the simulation
results show excellent agreement with experimental data. Giwa et al. [42] carried out the simulation
and optimization of the RD column using Aspen HYSYS optimizer by applying different algorithms
which are Fletcher-Reeves, Quasi-Newton and Successive Quadratic Programming (SQP). The
optimization result shows SQP is better algorithm because of lowest feed ratio and reducing cost.
Tavan et al. [43] [44] proposed two improvised version of RD of esterification using Aspen HYSYS. In
the first study, they combined two serial columns of RD and rectifier are used to produce highly
purity ethyl acetate [43]. They found that keeping the reactants rates near the stoichiometric ratio
leads to significant energy saving for various ethanol flow rates. In the second work, Tavan et al. [44]
eliminated the residue water the in the RD column by adding an auxiliary reaction of hydration of
ethylene oxide (EO) which produces ethylene glycol (EG), which is an industrially relevant product
used mainly as antifreeze in coolers. This results the energy reduction, coproduction of ethyl acetate
with ethylene glycol and the breaking of azeotropes.
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Methodology
Process Description
The reversible reaction of ethanol (EtOH) with acetic acid (HAc) towards ethyl acetate (EtAc) and
water (H2O), occuring in the RD column can be represented as:
k1
+ + 2 (3.1)
k2
The kinetic model was taken from Calvar et al [8].

60500
1 = 4619.43 ( ) (3.2)

53740
2 = 3317.28 ( ) (3.3)

The schematic of RD column to be simulated

in this study is shown in Fig 3.1. The 17-stage
RD column comprises two feed sections, F0
and F1, with condenser at the top and reboiler
at the bottom. Stages are numbered from top.
The feed F0, consists of HAc is introduced at
stage 1 while the feed F1, consists of 96 wt%
ethanol is introduced at stage 17. Acetic acid
is always introduced in the higher section,
because it is less volatile than ethanol. All the
stages are considered as reactive stages. To
account for a highly non-ideal system, Wilson
activity model is adopted. A zero-pressure
drop column and a total condenser are
assumed. The column specification and
process parameters are summarized in Table
3.1.
In the upper section, stream F2 contains

desired product of the reaction, ethyl acetate
and bottom section, F3 consists mainly of
water, H2O.
Figure 3.1: Schematic of RD column for production of
ethyl acetate
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Parameter Value
Reactive distillation column
Total no. of stages 17
Reactive trays 17
Acetic acid feed stage 1
Ethanol feed stage 17
Reflux ratio 2.5
Reboiler pressure (kPa) 100
Condenser pressure (kPa) 100
Acetic acid feed (F0)
Flow rate (mol/h) 3.9
Composition Acetic acid 1.000
Water 0.000
Temperature (C) 20
Pressure (kPa) 120
Ethanol feed (F1)

Flow rate (mol/h) 3.00
Composition Ethanol 0.9036
Water 0.0964
Temperature (C) 20
Pressure (kPa) 120
Distillate (F2)
Distillate rate (mol/h) 3.25
Table 3.1: Column specification and other parameters used for simulation
Assumptions taken in the simulation:
I. Chemical reactions are assumed to occur only in liquid phase.

II. Each stage is a perfectly mixed i.e. liquid composition at each stage is homogeneous and
equal to composition of liquid leaving stage.
III. Vapor molar holdup and vapor-phase chemical reactions are neglected.
IV. The vapor and liquid leaving any stage are in phase equilibrium.
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Process development
Defining the simulation basis

The process simulator Aspen HYSYS v8.0 was used for the simulation. To begin with, we have to
construct a simulation basis for our process. The first step is adding the components (ethanol, acetic
acid, ethyl acetate and water) to the simulation (Fig. 3.2).
Figure 3.2: Adding the components to the simulation
Once we have specified the components present in our simulation, we can set the fluid package for
our simulation. The fluid package is used to calculate the fluid/thermodynamic properties of the
components and mixtures in your simulation. For the initial case, Wilson is chosen as property
package as shown in Fig. 3.3.
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Figure 3.3: Selecting the property package
Add the feed stream

Now we have completed all necessary input to begin our simulation. We will be entering the
simulation environment to start defining the material streams and column. We have define two
input material streams, which are our feed streams F0 and F1. The temperature, flow rate, pressure
and flow rate need to be specified for each feed stream. Fig 3.4 and 3.5 shows how we specify the
stream F0 using the data from Table 3.1. The same step is applied for stream F1.
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Figure 3.4: Specifying the composition
Figure 3.5: Defining the stream's conditions
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Add the distillation column

The main component in our simulation, the distillation column is added with condenser and reboiler.
We set the number of stages, the feeding stage F0 and F1, the output streams F2 and F3 and type of
condenser, as shown in Fig. 3.6. The condenser and reboiler pressures, reflux ratio and distillate rate
are defined in Fig. 3.7 and 3.8. Once we have defined the parameters in the column we need to run
the it to ensure our specified data converges.
Figure 3.6: Defining the column parameters 1.
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Adding the reaction

To add a reaction in HYSYS, we have to create a set of new reaction for our process. We define the
stoichiometric coefficients for each component with the positive sign is the product and negative is
the reactant. The reaction is set as kinetic, therefore we need to specify the kinetic parameters such
as pre-exponential constants and activation energies of forward and backward reactions. Also, we
define ethanol as the base component and reaction occurs in liquid phase. Fig. 3.9 represents the
parameters that have been specified in HYSYS.
Figure 3.9: Adding the kinetic parameters
Adding the reaction to the column

Reaction sets in HYSYS can be attached to any stages in the column including the condenser,
reboiler, and side operations. In this case, the reaction occurs on all stages in the column. We add
the set of reaction that we have created before and we define the reaction stage (Fig. 3.10). The
solver is set to sparse continuation solver, a solver designed to handle three phase and reactive
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distillation, which will be our simulation case. Finally, we run the column once again and we can view
the simulation results on the Performance tab (Fig 3.11).
Figure 3.10: Adding the reaction to the column
Figure 3.11: The streams summary in Performance tab
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The flowchart of the system from HYSYS is shown in Fig. 3.12. The simulation results and column
specifications from simulator HYSYS are listed in Table 3.2 and 3.3 respectively. The main product,
EtAc is obtained at 71.32mol% at the top of the RD column. It is necessary to mention that the
proposed system is not in its optimized state yet. In the next section, the sensitive analysis is
performed in order to determine the optimum configuration of RD column. The effects of six
parameters, feed temperature, number of stage, kinetic model, molar feed ratio, reflux ratio and
activity model, which have important influences in column duties, are examined in the process.
Figure 3.12: Aspen HYSYS reactive distillation process flow diagram (PFD)
Parameter/Stream number F0 F1 F2 F3
Temperature (C) 20 20 74.26 98.32
Flow rate (mol/h) 3.90 3.00 3.25 3.65
Composition mol %
EtAc 0.0000 0.0000 0.7132 0.0086
Water 0.0000 0.0964 0.1543 0.5855
EtOH 0.0000 0.9036 0.0224 0.0791
HAc 1.0000 0.0000 0.1101 0.3268
Table 3.2: Simulation results of the process
Reactive distillation column

Type Sieve
Total no. of stages 17
Diameter (m) 1.5
Tray space (m) 0.55
Reflux ratio 2.5
Reboiler duty, Qr (kJ/h) 379.20
Condenser duty, Qc (kJ/h) 386.41
Table 3.3: Specifications of the RD column from HYSYS
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Results and discussions
Effect of feed temperature, TF.
Effect of Feed temperature

86.80
86.70
86.60
Ethanol conversion (%)
86.50
86.40 Variation TF0

Variation TF1
86.30
TF0 = TF1
86.20
86.10
86.00
0 20 40 60 80 100
Feed temperature (C)
Figure 4.1: Comparison of different method of variation feed temperature
In general, increasing feed temperature will decrease the conversion of reactants and purity of the
product. The temperature in the column is around 80 C. If we feed the reactant with temperature
close to the column temperature, the equilibrium between phases will be affected. At higher
temperature, the phase equilibrium will shift to formation of vapor. Thus the vapor composition
inside the tray will increase. As we assume the reaction will occur only in liquid phase, this will lower
the conversion of ethanol and the yield of ethyl acetate. On the other hand, introducing the feed at
lower temperature will affect the phase equilibrium less inside the column. This viewpoint shows
good agreement with Taylor et al. [23] and Gorak et al [14].
Fig. 4.1 shows the variation of acetic acid feed temperature, TF0, ethanol feed temperature, TF1, and
both feed at same temperature, TF0=TF1. The variations of TF0 and TF0=TF1 affect the conversion as it
decreases with increasing feed temperature. The variation of TF1 is insensitive to ethanol conversion
as the conversion remains constant. From the graph, we can deduce that the temperature for the
both feeds of 20 C would be the best option.
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Effect of number of stages, n.
EtOH conversion vs n
89.00
88.50
Ethanol conversion (%)
88.00
87.50
87.00
86.50
86.00
15 20 25 30 35 40 45 50
Number of stages, n
Figure 4.2: Effect of number of stages to ethanol conversion
EtAc purity vs n
73.50
73.00
Ethyl Acetate purity (%)
72.50
72.00
71.50
71.00
70.50
15 20 25 30 35 40 45 50
Number of stages, n
Figure 4.3: Effect of number of stages to ethyl acetate purity
Fig. 4.2 and Fig. 4.3 represent the effect of number of stages to ethanol conversion and ethyl acetate
purity. As mentioned before, all the stages in the column are considered as reactive stages.
Therefore an increase in number of stages improves the conversion. It can be seen from 15 to 30
stages, the conversion of EtOH increase from 86.1 to 88.0% and purity of EtAc from 70.1 to 72.5%.
However, the increase from 30 to 50 stages is not really effective. The EtOH conversion and EtAc
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purity do not change too much, give more or less the same value. This is because increasing stages
will increase the size of RD column and thus longer residence time. Therefore the optimal number of
stages for this case is 30.
Effect of kinetic model
Kinetic Reference A Ea A' Ea' Conversion Purity

model (kJ/kgmole) (kJ/kgmole) EtOH (%) EtAc (%)
1 Calvar et al. [8] 3317.28 53740 4619.43 60500 86.66 0.7132
2 Calvar et al. [8] 65.75 41430 0.06 30060 88.72 0.7266
3 Venkataraman et al. [45] 8055.5 59445.1 2050 59445.1 81.40 0.6751
4 Lone et al. [46] 0.000476 59774 0.000163 59774 -0.01 0.0000
5 Huang et al. [41] 131137 57960 81389 60550 88.10 0.7061
Table 4.1: Kinetic models and simulation results.
The kinetic models from different references have been applied to the simulation and the results are
summarized in Table 4.1. Depending on kinetic model chosen, we specify the values for pre-
exponential factors, A and A and activation energies, Ea and Ea. Each kinetic model gives certain
values of rate constant k1 and k2 (Eq. 4.1), and these will affect the equation rate of reaction, r (Eq.
4.2) and consequently lead to the changing of concentration of the reaction products.

1 = ( ) 2 = ( ) (4.1)

= 1 2 2 (4.2)
Any change on concentration of reaction products gives different composition and this composition
will affect the phase equilibrium and therefore the final results. Among these models, kinetic model
2 gives the highest conversion of EtOH and purity of EtAc for this process. As the process for this
study is uncatalyzed reaction, it gives lower or no composition of product on catalyzed reactions
kinetic model, as can be seen in kinetic model 3 and 4. Hence, kinetic model 2 is the most favorable
to apply for our case.
27 | P a g e
Effect of the molar feed ratio of HAc to EtOH.
Molar feed ratio influence

Ethanol conversion/Ethyl Acetate purity (%) 100.00
90.00
80.00
70.00
60.00
50.00
EtAc Purity
40.00
EtOH Conversion
30.00
20.00
10.00
0.00
0 2 4 6 8 10
Feed ratio of HAc to EtOH (mol/mol)
Figure 4.4: Effect of molar feed ratio to conversion EtOH and purity EtAc
The effect of feed ratio of HAc to EtOH is shown in Fig. 4.4. As the molar feed ratio increases from
0.2 to 1.3, the conversion of EtOH increases linearly from 20 to 87%. This is due to the fact that when
the molar feed ratio increases, the concentration of HAc in the reaction section increases, shifting
the equilibrium reaction to forward reaction. Apart from that, EtAc purity decreases rapidly when
molar feed ratio raise from 1.3 to 10. As we know, esterification reaction of HAc with EtOH is
equimolar reaction, and excess unreacted HAc may be distillate with EtAc from the top of the
column, resulting in reducing the EtAc purity in the product. Hence, the best molar feed ratio of HAc
to EtOH is equimolar.
28 | P a g e
Effect of reflux ratio, R
Effect of Reflux ratio (R)

100.00
90.00
Ethanol conversion/Ethyl Acetate purity (%)
80.00
70.00
60.00
50.00
EtAc Purity
40.00 EtOH conversion
30.00
20.00
10.00
0.00
0 5 10 15 20 25 30
Reflux ratio, R
Figure 4.5: Effect of reflux ratio to EtOH conversion and EtAc purity
In this section, the effect of reflux ratio is analyzed as shown in Fig. 4.5. The increase of reflux ratio
from 0.5 to 2.5 increases linearly the EtOH conversion and EtAc purity. At low R, the product
separation is low and insufficient, thus limits the conversion. When the R is increased, more
unreacted reactants are recycled back to reaction zone as well as improve the separation efficiency,
thus more forward reaction. It also can be seen that the increase of R from 2.5 to 5, there is a
negative effect on EtOH conversion and EtAc purity. This is because the increase in R increases the
concentration of EtAc in the reaction section. According to equilibrium, the increase of EtAc
concentration at the reaction section shifts the equilibrium of esterification reaction to the backward
direction. As seen from the graph, the optimal reflux ratio is 2.5.
29 | P a g e
Effect of activity model
Fig. 4.6, 4.7, 4.8 and 4.9 show the composition of each component using different activity models. In
this part, each activity model (Wilson, UNIQUAC and NRTL) is changed and their effect on ethyl
acetate concentration is studied. For this case, we decided to extend until 50 stages to see better
behavior of these activity models. Stage 0 and 50 correspond to condenser and reboiler respectively.
In general, each activity model behaves almost similarly at the first 30 stages and after that it starts
to deviate. At this region, NRTL shows more deviation with respect to the other models. When the
vapor phase and the equilibrium between phases are very important, the activity model that
discriminates between vapor and liquid is affected and deviates more compared to the generic
models such as Wilson and UNIQUAC. From the graph of EtAc composition in Fig. 4.6, we can see
that NRTL (Non-Random Two Liquid) is the best activity model as it gives higher composition of EtAc
in the product.
Ethyl Acetate
0.8
0.7
0.6
EtAc (molar fraction)
0.5
0.4 Wilson
UNIQUAC
0.3
NRTL
0.2
0.1
0
0 5 10 15 20 25 30 35 40 45 50
Stage number
Figure 4.6: Ethyl acetate composition profile using various activity models
30 | P a g e
Acetic Acid
0.45
0.4
0.35
0.3
HAc (molar fraction)
0.25
Wilson
0.2 UNIQUAC
0.15 NRTL
0.1
0.05
0
0 5 10 15 20 25 30 35 40 45 50
Stage number
Figure 4.7: Acetic acid composition profile using various activity models
Ethanol
0.2
0.18
0.16
0.14
EtOH (molar fraction)
0.12
0.1 Wilson
0.08 UNIQUAC
NRTL
0.06
0.04
0.02
0
0 5 10 15 20 25 30 35 40 45 50
Stage number
Figure 4.8: Ethanol composition profile using various activity models
31 | P a g e
Water
0.7
0.6
0.5
H2O (molar fraction)
0.4
Wilson
0.3 UNIQUAC
NRTL
0.2
0.1
0
0 5 10 15 20 25 30 35 40 45 50
Stage number
Figure 4.9: Water composition profile using various activity models
Effect of rectifying and stripping stages
s
Figure 4.10: Two types of RD configuration
32 | P a g e
In this section the effect non-reactive stripping and rectifying sections at the top and bottom is
investigated through sensitive analysis. Fig. 4.10 shows two different RD column configurations, the
first one is fully reactive column, which is our initial simulation case and the next one is RD column
with rectifying and stripping sections. The effect of rectifying and stripping stages is presented in the
graph in Fig. 4.11. From the figure we can see by introducing 1 stage for each rectifying and stripping
by maintaining the total stages in the column, the conversion of EtOH and purity of EtAc increase
from 86.6 to 91.4% and 71.3 to 76%. This can be explained by the fact that the rectifying and
stripping sections can enhance the recovery of reactant from the product, thus increasing the purity
of the product and conversion of reactant. However, it is only possible to obtain higher conversion of
EtOH and purity of EtAc compared to our initial case just until 3 stages. Beyond that, the EtOH
conversion of and EtAc purity decrease due to lack of reactive section. Therefore, we can deduce
that the optimal stage for rectifying and stripping for our process is 1.
Effect of rectifying and stripping stages

95.00
90.00
EtOH conversion/EtAc purity (%)
85.00
80.00
Purity EtAc
75.00
Conversion EtOH
70.00
65.00
60.00
0 1 2 3 4 5 6
Rectifying and stripping stage
Figure 4.11: Variation of rectifying and stripping stages
Conclusions
A simulation of reactive distillation of synthesis of ethyl acetate was carried out using process
simulator Aspen HYSYS. We have studied the effects of different operation variables by performing
sensitive analysis. In conclusion, the optimal configuration of the RD column is achieved: the feed
temperature of 20 C, 30 stages column, kinetic model 2, the equimolar feed ratio, reflux ratio 2.5,
NRTL activity model and 1 stage for each rectifying and stripping sections.
33 | P a g e
Nomenclature
HAc Acetic acid

EtOH Ethanol
EtAc Ethyl acetate
H2O Water
F molar flux
X molar fraction
RD Reactive Distillation
T Temperature
R Reflux ratio
n Number of stages
r Reaction rate
C Concentration
k Rate constant
A Pre-exponential factor
Ea Activation energy
EQ Equilibrium model
NEQ Non-equilibrium model
Qc Condenser duty
Qr Reboiler duty
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37 | P a g e
APPENDICES
APPENDICES | Khairul Naim Bin Ahmad
Contents
APPENDIX A: TABLES OF CALCULATION .................................................................................................. 2
A1. EFFECT OF FEED TEMPERATURE ................................................................................................... 2
A2. EFFECT OF NUMBER OF STAGES ................................................................................................... 3
A3. EFFECT OF MOLAR FEED RATIO .................................................................................................... 4
A4. EFFECT OF REFLUX RATIO ............................................................................................................. 4
A5. EFFECT OF ACTIVITY MODEL ......................................................................................................... 5
A6. EFFECT OF RECTIFYING AND STRIPPING STAGES .......................................................................... 7
APPENDIX B: ASPEN HYSYS REPORTS........................................................................................................
B1. INIITIAL CASE ...................................................................................................................................
B2. COLUMN SPECIFICATIONS ..............................................................................................................
B3. EFFECT OF THE FEED TEMPERATURE ..............................................................................................
B4. EFECT OF NUMBER OF STAGES .......................................................................................................
B5. EFFECT OF KINETIC MODEL .............................................................................................................
B6. EFFECT OF MOLAR FEED RATIO ......................................................................................................
B7. EFFECT OF REFLUX RATIO ...............................................................................................................
B8. EFFECT OF ACTIVITY MODEL ...........................................................................................................
B9. EFFECT OF RECTIFYING AND STRIPPING STAGES ............................................................................
1|Page
APPENDIX A: TABLES OF CALCULATION

Please note that the initial case is written in font italic.
A1. EFFECT OF FEED TEMPERATURE
TF0 F0 F1 F2 F3 Conversion
(C) EtOH (%)
kmol/h XHAc kmol/h XEtOH kmol/h XEtOH XHAc XEtAc kmol/h XEtOH XHAc
5 0.0039 1.0000 0.003 0.9036 0.00325 0.0229 0.1081 0.7138 0.00365 0.0782 0.3281 86.73
10 0.0039 1.0000 0.003 0.9036 0.00325 0.0228 0.1088 0.7136 0.00365 0.0785 0.3277 86.70
20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
30 0.0039 1.0000 0.003 0.9036 0.00325 0.0221 0.1115 0.7127 0.00365 0.0797 0.3259 86.62
40 0.0039 1.0000 0.003 0.9036 0.00325 0.0218 0.113 0.7122 0.00365 0.0804 0.325 86.56
50 0.0039 1.0000 0.003 0.9036 0.00325 0.0215 0.1145 0.7116 0.00365 0.0811 0.3241 86.50
60 0.0039 1.0000 0.003 0.9036 0.00325 0.0211 0.1161 0.711 0.00365 0.0819 0.3231 86.44
70 0.0039 1.0000 0.003 0.9036 0.00325 0.0208 0.1178 0.7102 0.00365 0.0827 0.3222 86.37
80 0.0039 1.0000 0.003 0.9036 0.00325 0.0205 0.1195 0.7095 0.00365 0.0836 0.3213 86.29
90 0.0039 1.0000 0.003 0.9036 0.00325 0.0202 0.1213 0.7086 0.00365 0.0846 0.3204 86.19
100 0.0039 1.0000 0.003 0.9036 0.00325 0.0199 0.1231 0.7076 0.00365 0.0857 0.3195 86.07
TF1 F0 F1 F2 F3 Conversion
(C) EtOH (%)
5 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
10 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
30 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
40 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68
50 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68
60 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68
70 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68
80 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7131 0.00365 0.079 0.3267 86.68
90 0.0039 1.0000 0.003 0.9036 0.00325 0.0225 0.1101 0.713 0.00365 0.0787 0.3265 86.71
100 0.0039 1.0000 0.003 0.9036 0.00325 0.0225 0.1101 0.713 0.00365 0.0787 0.3265 86.71
2|Page
TF0 = TF1 F0 F1 F2 F3 Conversion

(C) EtOH (%)
5 0.0039 1.0000 0.003 0.9036 0.00325 0.0229 0.1081 0.7138 0.00365 0.0782 0.3282 86.73
10 0.0039 1.0000 0.003 0.9036 0.00325 0.0228 0.1088 0.7136 0.00365 0.0785 0.3277 86.70
20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66
30 0.0039 1.0000 0.003 0.9036 0.00325 0.0221 0.1115 0.7127 0.00365 0.0797 0.3259 86.62
40 0.0039 1.0000 0.003 0.9036 0.00325 0.0218 0.113 0.7122 0.00365 0.0804 0.325 86.56
50 0.0039 1.0000 0.003 0.9036 0.00325 0.0215 0.1145 0.7116 0.00365 0.0811 0.324 86.50
60 0.0039 1.0000 0.003 0.9036 0.00325 0.0211 0.1161 0.7109 0.00365 0.0819 0.3231 86.44
70 0.0039 1.0000 0.003 0.9036 0.00325 0.0208 0.1178 0.7102 0.00365 0.0827 0.3222 86.37
80 0.0039 1.0000 0.003 0.9036 0.00325 0.0205 0.1195 0.7094 0.00365 0.0836 0.3213 86.29
90 0.0039 1.0000 0.003 0.9036 0.00325 0.0202 0.1212 0.7081 0.00365 0.0843 0.3202 86.23
100 0.0039 1.0000 0.003 0.9036 0.00325 0.0199 0.123 0.707 0.00365 0.0854 0.3194 86.12
A2. EFFECT OF NUMBER OF STAGES
n_stages F0 F1 F2 F3
15 0.0039 1.0000 0.003 0.9036 0.00325 0.0239 0.1093 0.7080 0.00365 0.0816 0.3314
17 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268
20 0.0039 1.0000 0.003 0.9036 0.00325 0.0212 0.111 0.7184 0.00365 0.0763 0.3221
30 0.0039 1.0000 0.003 0.9036 0.00325 0.0195 0.1123 0.7262 0.00365 0.0718 0.315
40 0.0039 1.0000 0.003 0.9036 0.00325 0.019 0.1128 0.7291 0.00365 0.0702 0.3124
50 0.0039 1.0000 0.003 0.9036 0.00325 0.0187 0.113 0.7304 0.00365 0.0694 0.3112
n_stages EtAc purity Conversion

(%) EtOH (%)
15 70.80 86.15
17 71.32 86.66
20 71.84 87.18
30 72.62 87.99
40 72.91 88.27
50 73.04 88.41
3|Page
A3. EFFECT OF MOLAR FEED RATIO
Molar F0 F1 F2 F3
feed ratio
HAc/EtOH
0.2 0.0006 1.0000 0.003 0.9036 0.00167 0.4209 0.0123 0.3470 0.00193 0.7402 0
0.5 0.0015 1.0000 0.003 0.9036 0.002088 0.0782 0.0558 0.6621 0.002412 0.483 0.0004
1 0.003 1.0000 0.003 0.9036 0.002784 0.0261 0.0987 0.7140 0.003216 0.1874 0.2145
1.3 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268
2 0.006 1.0000 0.003 0.9036 0.004176 0.0247 0.1548 0.5736 0.004824 0.0365 0.6057
5 0.015 1.0000 0.003 0.9036 0.008352 0.0079 0.3539 0.3060 0.009648 0.0063 0.9805
10 0.03 1.0000 0.003 0.9036 0.01531 0.0018 0.6444 0.1692 0.01769 0.0041 0.9906
Molar EtAc purity Conversion

feed ratio (%) EtOH (%)
HAc/EtOH
0.2 34.70 21.37
0.5 66.21 51.00
1 71.40 75.09
1.3 71.32 86.66
2 57.36 89.70
5 30.60 95.32
10 16.92 96.31
A4. EFFECT OF REFLUX RATIO
R F0 F1 F2 F3
0.5 0.0039 1.0000 0.003 0.9036 0.00325 0.005 0.4283 0.4241 0.00365 0.2957 0.2446
1 0.0039 1.0000 0.003 0.9036 0.00325 0.0105 0.2715 0.5485 0.00365 0.2055 0.2989
2.5 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268
5 0.0039 1.0000 0.003 0.9036 0.00325 0.0574 0.0521 0.698 0.00365 0.0619 0.3924
7.5 0.0039 1.0000 0.003 0.9036 0.00325 0.0995 0.0318 0.6657 0.00365 0.0537 0.4399
10 0.0039 1.0000 0.003 0.9036 0.00325 0.1355 0.0221 0.6389 0.00365 0.0467 0.4735
12.5 0.0039 1.0000 0.003 0.9036 0.00325 0.1622 0.0168 0.6195 0.00365 0.0414 0.4967
15 0.0039 1.0000 0.003 0.9036 0.00325 0.1813 0.0134 0.6057 0.00365 0.0375 0.5129
20 0.0039 1.0000 0.003 0.9036 0.00325 0.2052 0.0096 0.5887 0.00365 0.0328 0.5328
25 0.0039 1.0000 0.003 0.9036 0.00325 0.2187 0.0074 0.579 0.00365 0.0302 0.5441
30 0.0039 1.0000 0.003 0.9036 0.00325 0.227 0.0061 0.573 0.00365 0.0287 0.5512
4|Page
R EtAc purity Conversion

(%) EtOH (%)
0.5 42.41 59.59
1 54.85 71.07
2.5 71.32 86.66
5 69.80 84.78
7.5 66.57 80.84
10 63.89 77.47
12.5 61.95 74.98
15 60.57 73.21
20 58.87 70.98
25 57.90 69.71
30 57.30 68.92
A5. EFFECT OF ACTIVITY MODEL
Ethyl acetate (EtAc)
Num. Molar composition 16 0.4968 0.4859 0.4996 34 0.4605 0.4498 0.4402

Stage
Wilson UNIQUAC NRTL 17 0.4958 0.4847 0.4979 35 0.4552 0.4453 0.431
0 0.7303 0.7195 0.7533 18 0.4948 0.4835 0.4962 36 0.449 0.44 0.4195
1 0.51 0.5027 0.5257 19 0.4937 0.4823 0.4944 37 0.4415 0.4339 0.405
2 0.5086 0.5013 0.5234 20 0.4926 0.481 0.4925 38 0.4323 0.4266 0.3864
3 0.5076 0.5 0.5213 21 0.4914 0.4797 0.4905 39 0.4209 0.4178 0.3621
4 0.5067 0.4989 0.5193 22 0.4901 0.4783 0.4884 40 0.4063 0.4069 0.3307
5 0.5059 0.4977 0.5175 23 0.4888 0.4768 0.4862 41 0.3872 0.3932 0.2914
6 0.5051 0.4966 0.5157 24 0.4873 0.4753 0.4839 42 0.3618 0.3751 0.2456
7 0.5043 0.4956 0.5141 25 0.4857 0.4736 0.4813 43 0.3275 0.3503 0.197
8 0.5036 0.4945 0.5124 26 0.484 0.4718 0.4786 44 0.2817 0.3146 0.1509
9 0.5028 0.4934 0.5108 27 0.4821 0.4699 0.4756 45 0.2242 0.2625 0.1109
10 0.502 0.4924 0.5092 28 0.48 0.4678 0.4723 46 0.16 0.1914 0.078
11 0.5012 0.4913 0.5076 29 0.4776 0.4656 0.4686 47 0.1002 0.1131 0.0512
12 0.5004 0.4903 0.506 30 0.475 0.4631 0.4644 48 0.0547 0.0533 0.0303
13 0.4995 0.4892 0.5044 31 0.4721 0.4603 0.4597 49 0.0261 0.0219 0.0159
14 0.4987 0.4881 0.5028 32 0.4688 0.4572 0.4542 50 0.0063 0.0043 0.0033
15 0.4978 0.487 0.5012 33 0.4649 0.4537 0.4478
5|Page
Acetic acid (HAc)

Stage 16 0.3795 0.3755 0.3797 34 0.3774 0.3725 0.376
0 0.113 0.1103 0.1178 18 0.3794 0.3754 0.3795 36 0.3764 0.3713 0.3756
1 0.3791 0.3765 0.3813 19 0.3793 0.3753 0.3794 37 0.3755 0.3703 0.3757
2 0.3795 0.3765 0.3813 20 0.3792 0.3752 0.3792 38 0.3744 0.369 0.3763
3 0.3797 0.3765 0.3813 21 0.3792 0.3751 0.3791 39 0.3728 0.3672 0.3775
4 0.3798 0.3765 0.3812 22 0.3791 0.375 0.3789 40 0.3706 0.3647 0.3797
5 0.3798 0.3764 0.381 23 0.3791 0.3749 0.3788 41 0.3676 0.3612 0.3823
6 0.3798 0.3763 0.3809 24 0.379 0.3747 0.3786 42 0.3634 0.3563 0.3838
7 0.3798 0.3762 0.3808 25 0.3789 0.3746 0.3784 43 0.3576 0.3496 0.381
8 0.3798 0.3762 0.3807 26 0.3788 0.3745 0.3783 44 0.3491 0.3408 0.3703
9 0.3797 0.3761 0.3806 27 0.3787 0.3743 0.378 45 0.3357 0.3291 0.349
10 0.3797 0.376 0.3804 28 0.3786 0.3742 0.3778 46 0.3137 0.3118 0.3166
11 0.3797 0.3759 0.3803 29 0.3785 0.374 0.3776 47 0.2801 0.2833 0.2752
12 0.3796 0.3759 0.3802 30 0.3784 0.3738 0.3773 48 0.2385 0.2428 0.2311
13 0.3796 0.3758 0.3801 31 0.3782 0.3735 0.377 49 0.2089 0.2119 0.2028
14 0.3795 0.3757 0.38 32 0.378 0.3732 0.3767 50 0.3113 0.3253 0.2896
Ethanol (EtOH)

Stage 17 0.0195 0.0216 0.0193 35 0.0253 0.027 0.0283
Wilson UNIQUAC NRTL
0 0.0187 0.0248 0.0189 18 0.0196 0.0218 0.0195 36 0.0264 0.0279 0.0297
1 0.0156 0.0184 0.0145 19 0.0198 0.0219 0.0198 37 0.0277 0.029 0.0314
2 0.0168 0.019 0.0152 20 0.0199 0.0221 0.0201 38 0.0295 0.0305 0.0334
3 0.0174 0.0194 0.0157 21 0.0201 0.0223 0.0203 39 0.032 0.0325 0.0359
4 0.0178 0.0196 0.0161 22 0.0203 0.0225 0.0206 40 0.0354 0.0352 0.0387
5 0.018 0.0198 0.0164 23 0.0205 0.0227 0.0209 41 0.0401 0.0392 0.0419
6 0.0182 0.02 0.0167 24 0.0207 0.0229 0.0213 42 0.0467 0.045 0.0457
7 0.0183 0.0201 0.017 25 0.0209 0.0231 0.0216 43 0.056 0.0535 0.0501
8 0.0184 0.0203 0.0172 26 0.0211 0.0233 0.022 44 0.0683 0.0662 0.056
9 0.0186 0.0204 0.0174 27 0.0214 0.0236 0.0224 45 0.0837 0.0843 0.0643
10 0.0187 0.0206 0.0177 28 0.0216 0.0238 0.0228 46 0.1011 0.1079 0.076
11 0.0188 0.0207 0.0179 29 0.022 0.0241 0.0233 47 0.1191 0.1323 0.0915
12 0.0189 0.0209 0.0181 30 0.0223 0.0245 0.0239 48 0.1379 0.1526 0.1112
13 0.019 0.021 0.0184 31 0.0227 0.0248 0.0246 49 0.1657 0.177 0.141
14 0.0191 0.0212 0.0186 32 0.0232 0.0253 0.0253 50 0.0694 0.0756 0.0519
15 0.0192 0.0213 0.0188 33 0.0238 0.0258 0.0261
6|Page
Water (H2O)

Stage
16 0.1044 0.1171 0.1016 34 0.1377 0.1514 0.1566
0 0.138 0.1454 0.11 18 0.1062 0.1193 0.1048 36 0.1483 0.1608 0.1752
1 0.0954 0.1024 0.0785 19 0.1072 0.1205 0.1065 37 0.1552 0.1667 0.1879
2 0.0951 0.1031 0.08 20 0.1082 0.1217 0.1082 38 0.1637 0.1739 0.2039
3 0.0953 0.1041 0.0817 21 0.1093 0.123 0.1101 39 0.1743 0.1825 0.2245
4 0.0957 0.105 0.0834 22 0.1105 0.1243 0.112 40 0.1877 0.1931 0.2509
5 0.0963 0.106 0.085 23 0.1117 0.1257 0.1141 41 0.2051 0.2064 0.2843
6 0.0969 0.1071 0.0866 24 0.1131 0.1271 0.1162 42 0.2281 0.2237 0.325
7 0.0976 0.108 0.0882 25 0.1145 0.1287 0.1186 43 0.259 0.2466 0.3719
8 0.0982 0.109 0.0897 26 0.1161 0.1304 0.1212 44 0.3009 0.2784 0.4228
9 0.0989 0.11 0.0912 27 0.1179 0.1322 0.124 45 0.3564 0.3241 0.4757
10 0.0996 0.111 0.0927 28 0.1198 0.1342 0.1271 46 0.4251 0.3889 0.5294
11 0.1004 0.112 0.0942 29 0.1219 0.1363 0.1305 47 0.5006 0.4713 0.582
12 0.1011 0.113 0.0956 30 0.1243 0.1387 0.1344 48 0.5688 0.5514 0.6273
13 0.1019 0.114 0.0971 31 0.127 0.1413 0.1387 49 0.5994 0.5892 0.6404
14 0.1027 0.115 0.0986 32 0.1301 0.1443 0.1438 50 0.613 0.5947 0.6553
A6. EFFECT OF RECTIFYING AND STRIPPING STAGES
Stage F0 Stage F1 Rectifying and

stripping stage
1 17 0
2 16 1
3 15 2
4 13 3
5 12 4
6 11 5
7 10 6
Rectifying F0 F1 F2 F3
and stripping
stage
0 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268
1 0.0039 1.0000 0.003 0.9036 0.00325 0.0222 0.0363 0.7595 0.00365 0.0442 0.3574
2 0.0039 1.0000 0.003 0.9036 0.00325 0.0239 0.0119 0.7561 0.00365 0.0466 0.3831
3 0.0039 1.0000 0.003 0.9036 0.00325 0.029 0.0037 0.7341 0.00365 0.0619 0.4103
4 0.0039 1.0000 0.003 0.9036 0.00325 0.0401 0.0009 0.7036 0.00365 0.0794 0.4402
5 0.0039 1.0000 0.003 0.9036 0.00325 0.0645 0.0001 0.6727 0.00365 0.0855 0.4687
6 0.0039 1.0000 0.003 0.9036 0.00325 0.1179 0 0.6334 0.00365 0.0734 0.5042
7|Page
Rectifying Purity EtAc Conversion

and stripping (%) EtOH(%)
stage
0 71.32 86.66
1 75.95 91.39
2 75.61 90.86
3 73.41 88.19
4 70.36 84.50
5 67.27 80.75
6 63.34 75.98
8|Page
APPENDIX B:
ASPEN HYSYS REPORTS
APPENDIX B1:
INTIAL CASE
1
Case Name: INITIAL CASE.HSC
2 LEGENDS
3 Burlington, MA Unit Set: SI
4 USA
5
Date/Time: Tue May 26 03:14:57 2015
6
Fluid Package: Basis-1
7 Material Stream: F0 Property Package: Wilson - Ideal
8
9
10
CONDITIONS
11 Overall Liquid Phase
12 Vapour / Phase Fraction 0.0000 1.0000
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
15 Molar Flow (kgmole/h) 3.900e-003 * 3.900e-003
16 Mass Flow (kg/h) 0.2342 0.2342
17 Std Ideal Liq Vol Flow (m3/h) 2.227e-004 2.227e-004
18 Molar Enthalpy (kJ/kgmole) -4.610e+005 -4.610e+005
19 Molar Entropy (kJ/kgmole-C) 69.29 69.29
20 Heat Flow (kJ/h) -1798 -1798
21 Liq Vol Flow @Std Cond (m3/h) 2.185e-004 * 2.185e-004
22
23
COMPOSITION
24
25
Overall Phase Vapour Fraction 0.0000
26 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
27 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
Liquid Phase Phase Fraction 1.000
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
69 Aspen Technology Inc. Aspen HYSYS Version 8 (27.0.0.8138) Page 1 of 9
Licensed to: LEGENDS * Specified by user.
1
2 LEGENDS
4 USA
5
6
7 Material Stream: F1 (continued) Property Package: Wilson - Ideal
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
29 Molar Flow (kgmole/h) 3.250e-003 3.250e-003
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
61 Overall Aqueous Phase
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0791 0.0133 0.1053 0.0000 0.1321
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0243
24 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
Aqueous Phase Phase Fraction 1.000
30 Ethanol 0.0003 0.0791 0.0133 0.1053 0.0000 0.1321
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0243
33 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
36 Material Stream: Reflux @COL1 Property Package: Wilson - Ideal
37
38
39
CONDITIONS
40 Overall Vapour Phase Liquid Phase
41 Vapour / Phase Fraction 0.0000 0.0000 1.0000
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
44 Molar Flow (kgmole/h) 8.125e-003 0.0000 8.125e-003
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
46 Std Ideal Liq Vol Flow (m3/h) 6.485e-004 0.0000 6.485e-004
47 Molar Enthalpy (kJ/kgmole) -4.347e+005 -3.908e+005 -4.347e+005
48 Molar Entropy (kJ/kgmole-C) 140.5 237.3 140.5
49 Heat Flow (kJ/h) -3532 0.0000 -3532
50 Liq Vol Flow @Std Cond (m3/h) 6.450e-004 * 0.0000 6.450e-004
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
Vapour Phase Phase Fraction 0.0000
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
7 Material Stream: Reflux @COL1 (continued) Property Package: Wilson - Ideal
8
9
10
COMPOSITION
11
12
Vapour Phase (continued) Phase Fraction 0.0000
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
27 Energy Stream: Q_C Property Package: Wilson - Ideal
28
29
30
CONDITIONS
31 Duty Type: Direct Q Duty Calculation Operation: Condenser @COL1
32 Duty SP: 386.4 kJ/h Minimum Available Duty: --- Maximum Available Duty: ---
33
34 Energy Stream: Q_R Property Package: Wilson - Ideal
35
36
37
CONDITIONS
38 Duty Type: Direct Q Duty Calculation Operation: Reboiler @COL1
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
45 Component Molecular Weight Stoich Coeff Forward Order Reverse Order
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
51 Balance Error : 0.0000 Reaction Heat (25 C) : -1.492e+004 kJ/kgmole
52
53
BASIS
54 Min. Temp Max. Temp
Basis Base Component Rxn Phase
55 (C) (C)
56 Mole Fraction Ethanol LiquidPhase -273.1 3000
57
58
PARAMETERS
59 Forward Reaction Reverse Reaction
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
63 Distillation: C_1
64
65
CONNECTIONS
66
67 Inlet Stream
68 STREAM NAME Stage FROM UNIT OPERATION
1
2 LEGENDS
4 USA
5
6
7 Distillation: C_1 (continued)
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
13 STREAM NAME Stage TO UNIT OPERATION
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
19 Column Solving Algorithm: Sparse Continuation Solver
20 Solving Options Acceleration Parameters
21 Maximum Iterations: 10000 Accelerate K Value & H Model Parameters: Off
22 Equilibrium Error Tolerance: 1.000e-05
23 Heat/Spec Error Tolerance: 5.000e-004
24 Save Solutions as Initial Estimate: On
25 Super Critical Handling Model: Simple K
26 Trace Level: Low
27 Init from Ideal K's: Off Damping Parameters
28 Initial Estimate Generator Parameters Azeotrope Check: On
29 Iterative IEG (Good for Chemicals): Off Fixed Damping Factor: 1
30
31
32
SUMMARY
33
34 Flow Basis: Molar The composition option is selected
35 Feed Composition
36 F0 F1
37 Flow Rate (kgmole/h) 0.0039 0.0030
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
48 Ethanol (kgmole/h) 0.0000 0.0027
49 H2O (kgmole/h) 0.0000 0.0003
50 E-Acetate (kgmole/h) 0.0000 0.0000
51 AceticAcid (kgmole/h) 0.0039 0.0000
52 Products
54 Product Compositions
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0791
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0086
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
65 Flow Rate (kgmole/h) 0.0032 * 0.0036 *
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
12 E-Acetate (kgmole/h) 0.0023 * 0.0000 *
13 AceticAcid (kgmole/h) 0.0004 * 0.0012 *
15 Product Recoveries
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6913 10.6453
20 H2O (%) 173.3518 738.9603
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1781 30.5842
23
COLUMN PROFILES
24
25 Reflux Ratio: 2.500 Reboil Ratio: 2.739 The Flows Option is Selected Flow Basis: Molar
26 Column Profiles Flows
27 Temp Pres Net Liq Net Vap Net Feed Net Draws Duty
28 (C) (kPa) (kgmole/h) (kgmole/h) (kgmole/h) (kgmole/h) (kJ/h)
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.6 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.7 100 1.365e-002 9.580e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.999e-003 --- 3.650e-003 379 *
48 Column Profiles Energy
49 Temperature Liq Enthalpy Vap Enthalpy Heat Loss
50 (C) (kJ/kgmole) (kJ/kgmole) (kJ/h)
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.796e+005 ---
62 11__Main TS 81.60 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.65 -3.999e+005 -3.657e+005 ---
64 13__Main TS 81.90 -3.873e+005 -3.548e+005 ---
65 14__Main TS 82.48 -3.711e+005 -3.401e+005 ---
66 15__Main TS 83.46 -3.524e+005 -3.210e+005 ---
67 16__Main TS 84.64 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.75 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
16 Flow Basis: Molar
17 Stream Type Duty State Flows Enthalpy Temp
18 (kJ/h) (kgmole/h) (kJ/kgmole) (C)
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
21 1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.6e+005 * 20.00*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
43 Internal Feed Stream External Feed Stream Transfer Basis
44 Q_R Q_R None Req'd
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
47 Internal Prod Stream External Prod Stream Transfer Basis
48 Q_C Q_C None Req'd
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
TRAY by TRAY PROPERTIES PLOTS
10
Temperature vs. Tray Position Pressure

11
12 from Top vs. Tray Position from Top
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
Flow vs. Tray PositionColumn

34
35 from Top
Properties vs. Tray Position from
36 1.40e-002 940 75.0
Vapour Mol Weight(Light)
37
Liquid 930 Mol Weight(Light) 70.0
38 1.20e-002
39
Net Molar Flow (kgmole/h)
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
Composition vs. Tray Position from

11
12 K-Value
Top vs. Tray Position from Top
13 0.800 5.00
Ethanol (Light) Ethanol
14
H2O (Light) 4.50 H2O
15 0.700
E-Acetate (Light) E-Acetate
16 4.00
AceticAcid (Light) AceticAcid
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
35 Component Ratio vs. Tray Position from Top
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: TF0 = 5.HSC
2 LEGENDS
4 USA
5
Date/Time: Sun May 24 02:09:00 2015
6
8
9
10
CONDITIONS
13 Temperature: (C) 5.000 * 5.000
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1803 -1803
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
APPENDIX B2:
COLUMN SPECIFICATION
1
2 LEGENDS
4 USA
5
Date/Time: Tue Apr 21 17:49:26 2015
6
7 Tray Section: Main TS (continued)
8
9
10
Water Draws Summary
11 Name: Name: Name:
12 Molecular Weight
13 Molar Entropy (kJ/kgmole-C)
14 Mass Entropy (kJ/kg-C)
15 Molar Density (kgmole/m3)
16 Mass Density (kg/m3)
17 Std Liq Mass Den (kg/m3)
18 Molar Heat Cap (kJ/kgmole-C)
19 Mass Heat Cap (kJ/kg-C)
20 Thermal Cond (W/m-K)
21 Viscosity (cP)
22 Surface Tension (dyne/cm)
23 Z Factor
24
User Variables
25
26
RATING
27
28
Sizing
29
30 Weir Height (m) 5.000e-002 *
31 Weir Length (m) 1.200 *
32 Tray Space (m) 0.5500 *
33 Tray Volume (m3) 0.9719
34 DC Volume (m3) 8.836e-002 *
35 Diameter (m) 1.500
36 Active Area (m2) ---
37 Flow Paths 1
38 Internal Type: Sieve
39
Nozzles
40
41 Tray Section Elevation Relative to Ground Level 0.0000 m *
42 HoldupRG VtoAbove (m) Diameter (m) L toBelow (m) Diameter (m)
43 1__Main TS 0.0000 m * --- --- 0.0000 m 3.000e-003 m
44 2__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
45 3__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
46 4__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
47 5__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
48 6__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
49 7__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
50 8__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
51 9__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
52 10__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
53 11__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
54 12__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
55 13__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
56 14__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
57 15__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
58 16__Main TS 0.0000 m * 0.5500 m 3.000e-003 m 0.0000 m 3.000e-003 m
59 17__Main TS 0.0000 m * 0.5500 m 3.000e-003 m --- ---
60 Feed Tray Elevation RH (m) Diameter (m)
61 Reflux 1__Main TS 0.4125 m 5.000e-002 m
62 F0 1__Main TS 0.4125 m 5.000e-002 m
63 F1 17__Main TS 0.4125 m 5.000e-002 m
64 Boilup 17__Main TS 0.0000 m 5.000e-002 m
65 Prod Tray Elevation RH (m) Diameter (m)
66 To Condenser 1__Main TS 0.5500 m 5.000e-002 m
67 To Reboiler 17__Main TS 0.0000 m 3.000e-003 m
68 Heat Loss
APPENDIX B3:
EFFECT OF FEED
TEMPERATURE
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.20 74.20
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2380 0.2380
34 Heat Flow (kJ/h) -1412 -1412
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0229 0.0034 0.0144 0.0000 0.0166
43 H2O 0.0005 0.1552 0.0091 0.0382 0.0000 0.0351
44 E-Acetate 0.0023 0.7138 0.2044 0.8587 0.0002 0.8709
45 AceticAcid 0.0004 0.1081 0.0211 0.0887 0.0000 0.0774
46 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0229 0.0034 0.0144 0.0000 0.0166
52 H2O 0.0005 0.1552 0.0091 0.0382 0.0000 0.0351
53 E-Acetate 0.0023 0.7138 0.2044 0.8587 0.0002 0.8709
54 AceticAcid 0.0004 0.1081 0.0211 0.0887 0.0000 0.0774
55 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.90 93.90
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1263 0.1263
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1232 -1232
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0782 0.0131 0.1041 0.0000 0.1305
22 H2O 0.0021 0.5851 0.0385 0.3046 0.0000 0.3047
23 E-Acetate 0.0000 0.0086 0.0028 0.0218 0.0000 0.0240
24 AceticAcid 0.0012 0.3281 0.0719 0.5695 0.0001 0.5407
25 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0782 0.0131 0.1041 0.0000 0.1305
31 H2O 0.0021 0.5851 0.0385 0.3046 0.0000 0.3047
32 E-Acetate 0.0000 0.0086 0.0028 0.0218 0.0000 0.0240
33 AceticAcid 0.0012 0.3281 0.0719 0.5695 0.0001 0.5407
34 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.20 74.20 74.20
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5950 0.0000 0.5950
49 Heat Flow (kJ/h) -3530 0.0000 -3530
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0229 0.0086 0.0144 0.0000 0.0166
58 H2O 0.0013 0.1552 0.0227 0.0382 0.0000 0.0351
59 E-Acetate 0.0058 0.7138 0.5110 0.8587 0.0006 0.8709
60 AceticAcid 0.0009 0.1081 0.0528 0.0887 0.0001 0.0774
61 Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0265 0.0000 0.0170 0.0000 0.0194
67 H2O 0.0000 0.2082 0.0000 0.0523 0.0000 0.0477
68 E-Acetate 0.0000 0.7420 0.0000 0.9112 0.0000 0.9160
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0233 0.0000 0.0195 0.0000 0.0169
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0229 0.0086 0.0144 0.0000 0.0166
22 H2O 0.0013 0.1552 0.0227 0.0382 0.0000 0.0351
23 E-Acetate 0.0058 0.7138 0.5110 0.8587 0.0006 0.8709
24 AceticAcid 0.0009 0.1081 0.0528 0.0887 0.0001 0.0774
25 Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0229 0.0782
59 H2O 0.1552 0.5851
60 E-Acetate 0.7138 0.0086
61 AceticAcid 0.1081 0.3281
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.7500 10.5251
20 H2O (%) 174.4029 738.4861
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.0094 30.7101
23
COLUMN PROFILES
24
29 Condenser 74.2 100 8.125e-003 --- --- 3.250e-003 387 *
30 1__Main TS 82.0 100 1.318e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.0 100 1.315e-002 1.253e-002 --- --- ---
32 3__Main TS 81.9 100 1.312e-002 1.250e-002 --- --- ---
33 4__Main TS 81.9 100 1.309e-002 1.247e-002 --- --- ---
34 5__Main TS 81.8 100 1.305e-002 1.244e-002 --- --- ---
35 6__Main TS 81.8 100 1.299e-002 1.240e-002 --- --- ---
36 7__Main TS 81.7 100 1.293e-002 1.234e-002 --- --- ---
37 8__Main TS 81.6 100 1.285e-002 1.228e-002 --- --- ---
38 9__Main TS 81.5 100 1.274e-002 1.220e-002 --- --- ---
39 10__Main TS 81.4 100 1.260e-002 1.209e-002 --- --- ---
40 11__Main TS 81.4 100 1.240e-002 1.195e-002 --- --- ---
41 12__Main TS 81.4 100 1.215e-002 1.175e-002 --- --- ---
42 13__Main TS 81.6 100 1.180e-002 1.150e-002 --- --- ---
43 14__Main TS 82.2 100 1.137e-002 1.115e-002 --- --- ---
44 15__Main TS 83.3 100 1.087e-002 1.072e-002 --- --- ---
45 16__Main TS 84.6 100 1.037e-002 1.022e-002 --- --- ---
46 17__Main TS 85.8 100 1.380e-002 9.720e-003 3.000e-003 --- ---
47 Reboiler 93.9 100 --- 1.015e-002 --- 3.650e-003 385 *
51 Condenser 74.20 -4.345e+005 -3.905e+005 ---
52 1__Main TS 82.01 -4.385e+005 -4.005e+005 ---
53 2__Main TS 81.98 -4.373e+005 -3.991e+005 ---
54 3__Main TS 81.94 -4.359e+005 -3.978e+005 ---
55 4__Main TS 81.89 -4.344e+005 -3.963e+005 ---
56 5__Main TS 81.84 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.77 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.70 -4.282e+005 -3.904e+005 ---
59 8__Main TS 81.62 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.53 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.44 -4.162e+005 -3.796e+005 ---
62 11__Main TS 81.38 -4.094e+005 -3.737e+005 ---
63 12__Main TS 81.40 -4.001e+005 -3.658e+005 ---
64 13__Main TS 81.63 -3.875e+005 -3.550e+005 ---
65 14__Main TS 82.21 -3.712e+005 -3.403e+005 ---
66 15__Main TS 83.25 -3.523e+005 -3.211e+005 ---
67 16__Main TS 84.56 -3.341e+005 -2.986e+005 ---
68 17__Main TS 85.81 -3.218e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.90 -3.375e+005 -2.782e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.20*
21 1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.6e+005 * 5.00 *
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.90*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 10.00 * 10.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1801 -1801
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.22 74.22
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2380 0.2380
34 Heat Flow (kJ/h) -1412 -1412
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0228 0.0034 0.0143 0.0000 0.0165
43 H2O 0.0005 0.1549 0.0091 0.0381 0.0000 0.0350
44 E-Acetate 0.0023 0.7136 0.2043 0.8584 0.0002 0.8706
45 AceticAcid 0.0004 0.1088 0.0212 0.0892 0.0000 0.0778
46 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0228 0.0034 0.0143 0.0000 0.0165
52 H2O 0.0005 0.1549 0.0091 0.0381 0.0000 0.0350
53 E-Acetate 0.0023 0.7136 0.2043 0.8584 0.0002 0.8706
54 AceticAcid 0.0004 0.1088 0.0212 0.0892 0.0000 0.0778
55 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.87 93.87
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1263 0.1263
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1232 -1232
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0785 0.0132 0.1045 0.0000 0.1310
22 H2O 0.0021 0.5853 0.0385 0.3048 0.0000 0.3049
23 E-Acetate 0.0000 0.0086 0.0028 0.0219 0.0000 0.0241
24 AceticAcid 0.0012 0.3277 0.0718 0.5689 0.0001 0.5400
25 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0785 0.0132 0.1045 0.0000 0.1310
31 H2O 0.0021 0.5853 0.0385 0.3048 0.0000 0.3049
32 E-Acetate 0.0000 0.0086 0.0028 0.0219 0.0000 0.0241
33 AceticAcid 0.0012 0.3277 0.0718 0.5689 0.0001 0.5400
34 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.22 74.22 74.22
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5951 0.0000 0.5951
49 Heat Flow (kJ/h) -3531 0.0000 -3531
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0228 0.0085 0.0143 0.0000 0.0165
58 H2O 0.0013 0.1549 0.0227 0.0381 0.0000 0.0350
59 E-Acetate 0.0058 0.7136 0.5108 0.8584 0.0006 0.8706
60 AceticAcid 0.0009 0.1088 0.0531 0.0892 0.0001 0.0778
61 Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0263 0.0000 0.0169 0.0000 0.0193
67 H2O 0.0000 0.2080 0.0000 0.0522 0.0000 0.0476
68 E-Acetate 0.0000 0.7423 0.0000 0.9113 0.0000 0.9161
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0235 0.0000 0.0196 0.0000 0.0170
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0228 0.0085 0.0143 0.0000 0.0165
22 H2O 0.0013 0.1549 0.0227 0.0381 0.0000 0.0350
23 E-Acetate 0.0058 0.7136 0.5108 0.8584 0.0006 0.8706
24 AceticAcid 0.0009 0.1088 0.0531 0.0892 0.0001 0.0778
25 Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0228 0.0785
59 H2O 0.1549 0.5853
60 E-Acetate 0.7136 0.0086
61 AceticAcid 0.1088 0.3277
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.7304 10.5639
20 H2O (%) 174.0532 738.6548
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.0646 30.6683
23
COLUMN PROFILES
24
29 Condenser 74.2 100 8.125e-003 --- --- 3.250e-003 387 *
30 1__Main TS 82.1 100 1.312e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.0 100 1.310e-002 1.247e-002 --- --- ---
32 3__Main TS 82.0 100 1.307e-002 1.245e-002 --- --- ---
33 4__Main TS 81.9 100 1.304e-002 1.242e-002 --- --- ---
34 5__Main TS 81.9 100 1.299e-002 1.239e-002 --- --- ---
35 6__Main TS 81.8 100 1.294e-002 1.234e-002 --- --- ---
36 7__Main TS 81.8 100 1.288e-002 1.229e-002 --- --- ---
37 8__Main TS 81.7 100 1.280e-002 1.223e-002 --- --- ---
38 9__Main TS 81.6 100 1.269e-002 1.215e-002 --- --- ---
39 10__Main TS 81.5 100 1.255e-002 1.204e-002 --- --- ---
40 11__Main TS 81.5 100 1.235e-002 1.190e-002 --- --- ---
41 12__Main TS 81.5 100 1.210e-002 1.170e-002 --- --- ---
42 13__Main TS 81.7 100 1.175e-002 1.145e-002 --- --- ---
43 14__Main TS 82.3 100 1.132e-002 1.110e-002 --- --- ---
44 15__Main TS 83.3 100 1.082e-002 1.067e-002 --- --- ---
45 16__Main TS 84.6 100 1.032e-002 1.017e-002 --- --- ---
46 17__Main TS 85.8 100 1.375e-002 9.673e-003 3.000e-003 --- ---
47 Reboiler 93.9 100 --- 1.010e-002 --- 3.650e-003 383 *
51 Condenser 74.22 -4.345e+005 -3.906e+005 ---
52 1__Main TS 82.06 -4.386e+005 -4.005e+005 ---
53 2__Main TS 82.03 -4.373e+005 -3.992e+005 ---
54 3__Main TS 81.99 -4.360e+005 -3.978e+005 ---
55 4__Main TS 81.94 -4.345e+005 -3.963e+005 ---
56 5__Main TS 81.89 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.83 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.76 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.68 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.59 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.51 -4.162e+005 -3.796e+005 ---
62 11__Main TS 81.45 -4.093e+005 -3.737e+005 ---
63 12__Main TS 81.48 -4.000e+005 -3.658e+005 ---
64 13__Main TS 81.72 -3.874e+005 -3.550e+005 ---
65 14__Main TS 82.30 -3.712e+005 -3.402e+005 ---
66 15__Main TS 83.32 -3.524e+005 -3.211e+005 ---
67 16__Main TS 84.59 -3.342e+005 -2.986e+005 ---
68 17__Main TS 85.79 -3.217e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.87 -3.374e+005 -2.781e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.22*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.87*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 30.00 * 30.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1794 -1794
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.30 74.30
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2382 0.2382
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0221 0.0033 0.0139 0.0000 0.0160
43 H2O 0.0005 0.1536 0.0090 0.0378 0.0000 0.0347
44 E-Acetate 0.0023 0.7127 0.2041 0.8569 0.0002 0.8694
45 AceticAcid 0.0004 0.1115 0.0218 0.0914 0.0000 0.0798
46 Total 0.0033 1.0000 0.2382 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0221 0.0033 0.0139 0.0000 0.0160
52 H2O 0.0005 0.1536 0.0090 0.0378 0.0000 0.0347
53 E-Acetate 0.0023 0.7127 0.2041 0.8569 0.0002 0.8694
54 AceticAcid 0.0004 0.1115 0.0218 0.0914 0.0000 0.0798
55 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.77 93.77
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1261 0.1261
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1230 -1230
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0797 0.0134 0.1063 0.0000 0.1332
22 H2O 0.0021 0.5857 0.0385 0.3053 0.0000 0.3052
23 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0244
24 AceticAcid 0.0012 0.3259 0.0714 0.5663 0.0001 0.5372
25 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0797 0.0134 0.1063 0.0000 0.1332
31 H2O 0.0021 0.5857 0.0385 0.3053 0.0000 0.3052
32 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0244
33 AceticAcid 0.0012 0.3259 0.0714 0.5663 0.0001 0.5372
34 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.30 74.30 74.30
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5954 0.0000 0.5954
49 Heat Flow (kJ/h) -3533 0.0000 -3533
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0221 0.0083 0.0139 0.0000 0.0160
58 H2O 0.0012 0.1536 0.0225 0.0378 0.0000 0.0347
59 E-Acetate 0.0058 0.7127 0.5102 0.8569 0.0006 0.8694
60 AceticAcid 0.0009 0.1115 0.0544 0.0914 0.0001 0.0798
61 Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0255 0.0000 0.0164 0.0000 0.0187
67 H2O 0.0000 0.2069 0.0000 0.0519 0.0000 0.0473
68 E-Acetate 0.0000 0.7434 0.0000 0.9116 0.0000 0.9165
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0242 0.0000 0.0202 0.0000 0.0175
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0221 0.0083 0.0139 0.0000 0.0160
22 H2O 0.0012 0.1536 0.0225 0.0378 0.0000 0.0347
23 E-Acetate 0.0058 0.7127 0.5102 0.8569 0.0006 0.8694
24 AceticAcid 0.0009 0.1115 0.0544 0.0914 0.0001 0.0798
25 Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0221 0.0797
59 H2O 0.1536 0.5857
60 E-Acetate 0.7127 0.0087
61 AceticAcid 0.1115 0.3259
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6521 10.7319
20 H2O (%) 172.6495 739.2177
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.2958 30.4994
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.3 100 1.292e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.2 100 1.289e-002 1.227e-002 --- --- ---
32 3__Main TS 82.2 100 1.286e-002 1.224e-002 --- --- ---
33 4__Main TS 82.2 100 1.283e-002 1.221e-002 --- --- ---
34 5__Main TS 82.1 100 1.279e-002 1.218e-002 --- --- ---
35 6__Main TS 82.1 100 1.273e-002 1.214e-002 --- --- ---
36 7__Main TS 82.0 100 1.267e-002 1.208e-002 --- --- ---
37 8__Main TS 81.9 100 1.259e-002 1.202e-002 --- --- ---
38 9__Main TS 81.9 100 1.248e-002 1.194e-002 --- --- ---
39 10__Main TS 81.8 100 1.234e-002 1.183e-002 --- --- ---
40 11__Main TS 81.8 100 1.215e-002 1.169e-002 --- --- ---
41 12__Main TS 81.8 100 1.190e-002 1.150e-002 --- --- ---
42 13__Main TS 82.1 100 1.156e-002 1.125e-002 --- --- ---
43 14__Main TS 82.7 100 1.113e-002 1.091e-002 --- --- ---
44 15__Main TS 83.6 100 1.063e-002 1.048e-002 --- --- ---
45 16__Main TS 84.7 100 1.013e-002 9.985e-003 --- --- ---
46 17__Main TS 85.7 100 1.355e-002 9.485e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.898e-003 --- 3.650e-003 375 *
51 Condenser 74.30 -4.348e+005 -3.910e+005 ---
52 1__Main TS 82.27 -4.388e+005 -4.009e+005 ---
53 2__Main TS 82.24 -4.375e+005 -3.995e+005 ---
54 3__Main TS 82.20 -4.361e+005 -3.981e+005 ---
55 4__Main TS 82.16 -4.346e+005 -3.965e+005 ---
56 5__Main TS 82.11 -4.328e+005 -3.948e+005 ---
57 6__Main TS 82.05 -4.308e+005 -3.928e+005 ---
58 7__Main TS 81.99 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.92 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.85 -4.212e+005 -3.840e+005 ---
61 10__Main TS 81.79 -4.160e+005 -3.795e+005 ---
62 11__Main TS 81.77 -4.091e+005 -3.735e+005 ---
63 12__Main TS 81.83 -3.997e+005 -3.655e+005 ---
64 13__Main TS 82.10 -3.872e+005 -3.546e+005 ---
65 14__Main TS 82.67 -3.711e+005 -3.399e+005 ---
66 15__Main TS 83.60 -3.525e+005 -3.209e+005 ---
67 16__Main TS 84.70 -3.344e+005 -2.986e+005 ---
68 17__Main TS 85.70 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.77 -3.371e+005 -2.779e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.30*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.77*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 from vs. Tray Position from Top
13 94.0 105
Top 14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26
78.0 97.0
27
28 76.0 96.0
29
30
74.0 95.0
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
35 from Top
36 1.40e-002 940 75.0
37 Vapour Mol Weight(Light)
38 Liquid 930 Mol Weight(Light) 70.0

1.20e-002
39
920 65.0
40
41 1.00e-002
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45
6.00e-003 890 50.0
46
47 880 45.0
48 4.00e-003
49 870 40.0
50
2.00e-003
51 860 35.0
52
53 0.000 850 30.0
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
Aspen Technology Inc. Aspen HYSYS Version 8 (27.0.0.8138) Page 8 of 9
1
2 LEGENDS
4 USA
5
6
8
9
10
11
12
Composition vs. Tray Position from Top K-Value vs. Tray Position from Top
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 40.00 * 40.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1791 -1791
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.35 74.35
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2382 0.2382
34 Heat Flow (kJ/h) -1414 -1414
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0218 0.0033 0.0137 0.0000 0.0158
43 H2O 0.0005 0.1530 0.0090 0.0376 0.0000 0.0346
44 E-Acetate 0.0023 0.7122 0.2039 0.8561 0.0002 0.8687
45 AceticAcid 0.0004 0.1130 0.0221 0.0926 0.0000 0.0809
46 Total 0.0033 1.0000 0.2382 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0218 0.0033 0.0137 0.0000 0.0158
52 H2O 0.0005 0.1530 0.0090 0.0376 0.0000 0.0346
53 E-Acetate 0.0023 0.7122 0.2039 0.8561 0.0002 0.8687
54 AceticAcid 0.0004 0.1130 0.0221 0.0926 0.0000 0.0809
55 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.72 93.72
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1261 0.1261
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1230 -1230
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0804 0.0135 0.1072 0.0000 0.1343
22 H2O 0.0021 0.5859 0.0385 0.3055 0.0000 0.3053
23 E-Acetate 0.0000 0.0088 0.0028 0.0223 0.0000 0.0246
24 AceticAcid 0.0012 0.3250 0.0712 0.5649 0.0001 0.5358
25 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0804 0.0135 0.1072 0.0000 0.1343
31 H2O 0.0021 0.5859 0.0385 0.3055 0.0000 0.3053
32 E-Acetate 0.0000 0.0088 0.0028 0.0223 0.0000 0.0246
33 AceticAcid 0.0012 0.3250 0.0712 0.5649 0.0001 0.5358
34 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.35 74.35 74.35
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5955 0.0000 0.5955
49 Heat Flow (kJ/h) -3534 0.0000 -3534
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0218 0.0082 0.0137 0.0000 0.0158
58 H2O 0.0012 0.1530 0.0224 0.0376 0.0000 0.0346
59 E-Acetate 0.0058 0.7122 0.5098 0.8561 0.0006 0.8687
60 AceticAcid 0.0009 0.1130 0.0551 0.0926 0.0001 0.0809
61 Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0251 0.0000 0.0161 0.0000 0.0184
67 H2O 0.0000 0.2063 0.0000 0.0517 0.0000 0.0471
68 E-Acetate 0.0000 0.7440 0.0000 0.9117 0.0000 0.9167
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0246 0.0000 0.0205 0.0000 0.0178
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0218 0.0082 0.0137 0.0000 0.0158
22 H2O 0.0012 0.1530 0.0224 0.0376 0.0000 0.0346
23 E-Acetate 0.0058 0.7122 0.5098 0.8561 0.0006 0.8687
24 AceticAcid 0.0009 0.1130 0.0551 0.0926 0.0001 0.0809
25 Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0218 0.0804
59 H2O 0.1530 0.5859
60 E-Acetate 0.7122 0.0088
61 AceticAcid 0.1130 0.3250
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6129 10.8243
20 H2O (%) 171.9487 739.4200
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.4180 30.4142
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.4 100 1.281e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.4 100 1.279e-002 1.216e-002 --- --- ---
32 3__Main TS 82.3 100 1.276e-002 1.214e-002 --- --- ---
33 4__Main TS 82.3 100 1.272e-002 1.211e-002 --- --- ---
34 5__Main TS 82.2 100 1.268e-002 1.207e-002 --- --- ---
35 6__Main TS 82.2 100 1.263e-002 1.203e-002 --- --- ---
36 7__Main TS 82.1 100 1.256e-002 1.198e-002 --- --- ---
37 8__Main TS 82.1 100 1.248e-002 1.191e-002 --- --- ---
38 9__Main TS 82.0 100 1.238e-002 1.183e-002 --- --- ---
39 10__Main TS 81.9 100 1.224e-002 1.173e-002 --- --- ---
40 11__Main TS 81.9 100 1.205e-002 1.159e-002 --- --- ---
41 12__Main TS 82.0 100 1.180e-002 1.140e-002 --- --- ---
42 13__Main TS 82.3 100 1.146e-002 1.115e-002 --- --- ---
43 14__Main TS 82.9 100 1.103e-002 1.081e-002 --- --- ---
44 15__Main TS 83.8 100 1.054e-002 1.038e-002 --- --- ---
45 16__Main TS 84.8 100 1.004e-002 9.889e-003 --- --- ---
46 17__Main TS 85.7 100 1.345e-002 9.388e-003 3.000e-003 --- ---
47 Reboiler 93.7 100 --- 9.797e-003 --- 3.650e-003 372 *
51 Condenser 74.35 -4.350e+005 -3.912e+005 ---
52 1__Main TS 82.38 -4.389e+005 -4.011e+005 ---
53 2__Main TS 82.35 -4.376e+005 -3.997e+005 ---
54 3__Main TS 82.32 -4.362e+005 -3.982e+005 ---
55 4__Main TS 82.27 -4.347e+005 -3.966e+005 ---
56 5__Main TS 82.22 -4.329e+005 -3.948e+005 ---
57 6__Main TS 82.17 -4.308e+005 -3.928e+005 ---
58 7__Main TS 82.11 -4.283e+005 -3.904e+005 ---
59 8__Main TS 82.05 -4.251e+005 -3.876e+005 ---
60 9__Main TS 81.99 -4.212e+005 -3.840e+005 ---
61 10__Main TS 81.94 -4.159e+005 -3.794e+005 ---
62 11__Main TS 81.94 -4.090e+005 -3.734e+005 ---
63 12__Main TS 82.02 -3.996e+005 -3.654e+005 ---
64 13__Main TS 82.30 -3.870e+005 -3.544e+005 ---
65 14__Main TS 82.87 -3.711e+005 -3.397e+005 ---
66 15__Main TS 83.75 -3.526e+005 -3.208e+005 ---
67 16__Main TS 84.76 -3.345e+005 -2.986e+005 ---
68 17__Main TS 85.66 -3.215e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.72 -3.370e+005 -2.778e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.35*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.72*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 50.00 * 50.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1787 -1787
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.39 74.39
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1414 -1414
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0215 0.0032 0.0135 0.0000 0.0156
43 H2O 0.0005 0.1524 0.0089 0.0374 0.0000 0.0345
44 E-Acetate 0.0023 0.7116 0.2038 0.8552 0.0002 0.8680
45 AceticAcid 0.0004 0.1145 0.0224 0.0938 0.0000 0.0819
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0215 0.0032 0.0135 0.0000 0.0156
52 H2O 0.0005 0.1524 0.0089 0.0374 0.0000 0.0345
53 E-Acetate 0.0023 0.7116 0.2038 0.8552 0.0002 0.8680
54 AceticAcid 0.0004 0.1145 0.0224 0.0938 0.0000 0.0819
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.66 93.66
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1229 -1229
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0811 0.0136 0.1082 0.0000 0.1355
22 H2O 0.0021 0.5860 0.0385 0.3057 0.0000 0.3054
23 E-Acetate 0.0000 0.0088 0.0028 0.0225 0.0000 0.0248
24 AceticAcid 0.0012 0.3241 0.0710 0.5636 0.0001 0.5343
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0811 0.0136 0.1082 0.0000 0.1355
31 H2O 0.0021 0.5860 0.0385 0.3057 0.0000 0.3054
32 E-Acetate 0.0000 0.0088 0.0028 0.0225 0.0000 0.0248
33 AceticAcid 0.0012 0.3241 0.0710 0.5636 0.0001 0.5343
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.39 74.39 74.39
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5956 0.0000 0.5956
49 Heat Flow (kJ/h) -3536 0.0000 -3536
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0215 0.0080 0.0135 0.0000 0.0156
58 H2O 0.0012 0.1524 0.0223 0.0374 0.0000 0.0345
59 E-Acetate 0.0058 0.7116 0.5094 0.8552 0.0006 0.8680
60 AceticAcid 0.0009 0.1145 0.0559 0.0938 0.0001 0.0819
61 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0247 0.0000 0.0158 0.0000 0.0181
67 H2O 0.0000 0.2057 0.0000 0.0515 0.0000 0.0470
68 E-Acetate 0.0000 0.7446 0.0000 0.9118 0.0000 0.9169
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0250 0.0000 0.0208 0.0000 0.0180
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0215 0.0080 0.0135 0.0000 0.0156
22 H2O 0.0012 0.1524 0.0223 0.0374 0.0000 0.0345
23 E-Acetate 0.0058 0.7116 0.5094 0.8552 0.0006 0.8680
24 AceticAcid 0.0009 0.1145 0.0559 0.0938 0.0001 0.0819
25 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0215 0.0811
59 H2O 0.1524 0.5860
60 E-Acetate 0.7116 0.0088
61 AceticAcid 0.1145 0.3241
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.5737 10.9230
20 H2O (%) 171.2521 739.5592
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.5449 30.3286
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.5 100 1.270e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.5 100 1.268e-002 1.205e-002 --- --- ---
32 3__Main TS 82.4 100 1.265e-002 1.203e-002 --- --- ---
33 4__Main TS 82.4 100 1.261e-002 1.200e-002 --- --- ---
34 5__Main TS 82.3 100 1.257e-002 1.196e-002 --- --- ---
35 6__Main TS 82.3 100 1.252e-002 1.192e-002 --- --- ---
36 7__Main TS 82.2 100 1.246e-002 1.187e-002 --- --- ---
37 8__Main TS 82.2 100 1.238e-002 1.181e-002 --- --- ---
38 9__Main TS 82.1 100 1.227e-002 1.173e-002 --- --- ---
39 10__Main TS 82.1 100 1.213e-002 1.162e-002 --- --- ---
40 11__Main TS 82.1 100 1.195e-002 1.148e-002 --- --- ---
41 12__Main TS 82.2 100 1.169e-002 1.130e-002 --- --- ---
42 13__Main TS 82.5 100 1.136e-002 1.104e-002 --- --- ---
43 14__Main TS 83.1 100 1.093e-002 1.071e-002 --- --- ---
44 15__Main TS 83.9 100 1.044e-002 1.028e-002 --- --- ---
45 16__Main TS 84.8 100 9.941e-003 9.792e-003 --- --- ---
46 17__Main TS 85.6 100 1.334e-002 9.291e-003 3.000e-003 --- ---
47 Reboiler 93.7 100 --- 9.694e-003 --- 3.650e-003 368 *
51 Condenser 74.39 -4.352e+005 -3.914e+005 ---
52 1__Main TS 82.49 -4.391e+005 -4.012e+005 ---
53 2__Main TS 82.47 -4.377e+005 -3.998e+005 ---
54 3__Main TS 82.43 -4.363e+005 -3.983e+005 ---
55 4__Main TS 82.39 -4.347e+005 -3.967e+005 ---
56 5__Main TS 82.34 -4.329e+005 -3.949e+005 ---
57 6__Main TS 82.29 -4.308e+005 -3.928e+005 ---
58 7__Main TS 82.24 -4.282e+005 -3.904e+005 ---
59 8__Main TS 82.19 -4.251e+005 -3.875e+005 ---
60 9__Main TS 82.14 -4.211e+005 -3.839e+005 ---
61 10__Main TS 82.11 -4.158e+005 -3.793e+005 ---
62 11__Main TS 82.12 -4.088e+005 -3.733e+005 ---
63 12__Main TS 82.23 -3.994e+005 -3.652e+005 ---
64 13__Main TS 82.52 -3.869e+005 -3.542e+005 ---
65 14__Main TS 83.08 -3.710e+005 -3.395e+005 ---
66 15__Main TS 83.90 -3.527e+005 -3.207e+005 ---
67 16__Main TS 84.81 -3.346e+005 -2.986e+005 ---
68 17__Main TS 85.60 -3.214e+005 -2.763e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.66 -3.368e+005 -2.776e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.39*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.66*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 60.00 * 60.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1783 -1783
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.44 74.44
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1415 -1415
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0211 0.0032 0.0133 0.0000 0.0153
43 H2O 0.0005 0.1518 0.0089 0.0373 0.0000 0.0343
44 E-Acetate 0.0023 0.7110 0.2036 0.8543 0.0002 0.8673
45 AceticAcid 0.0004 0.1161 0.0227 0.0951 0.0000 0.0831
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0211 0.0032 0.0133 0.0000 0.0153
52 H2O 0.0005 0.1518 0.0089 0.0373 0.0000 0.0343
53 E-Acetate 0.0023 0.7110 0.2036 0.8543 0.0002 0.8673
54 AceticAcid 0.0004 0.1161 0.0227 0.0951 0.0000 0.0831
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.60 93.60
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1229 -1229
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0819 0.0138 0.1093 0.0000 0.1368
22 H2O 0.0021 0.5860 0.0385 0.3058 0.0000 0.3054
23 E-Acetate 0.0000 0.0089 0.0029 0.0227 0.0000 0.0250
24 AceticAcid 0.0012 0.3231 0.0708 0.5621 0.0001 0.5327
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0819 0.0138 0.1093 0.0000 0.1368
31 H2O 0.0021 0.5860 0.0385 0.3058 0.0000 0.3054
32 E-Acetate 0.0000 0.0089 0.0029 0.0227 0.0000 0.0250
33 AceticAcid 0.0012 0.3231 0.0708 0.5621 0.0001 0.5327
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.44 74.44 74.44
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5957 0.0000 0.5957
49 Heat Flow (kJ/h) -3537 0.0000 -3537
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0211 0.0079 0.0133 0.0000 0.0153
58 H2O 0.0012 0.1518 0.0222 0.0373 0.0000 0.0343
59 E-Acetate 0.0058 0.7110 0.5090 0.8543 0.0006 0.8673
60 AceticAcid 0.0009 0.1161 0.0567 0.0951 0.0001 0.0831
61 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0243 0.0000 0.0156 0.0000 0.0178
67 H2O 0.0000 0.2051 0.0000 0.0513 0.0000 0.0468
68 E-Acetate 0.0000 0.7451 0.0000 0.9119 0.0000 0.9171
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0254 0.0000 0.0212 0.0000 0.0183
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0211 0.0079 0.0133 0.0000 0.0153
22 H2O 0.0012 0.1518 0.0222 0.0373 0.0000 0.0343
23 E-Acetate 0.0058 0.7110 0.5090 0.8543 0.0006 0.8673
24 AceticAcid 0.0009 0.1161 0.0567 0.0951 0.0001 0.0831
25 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0211 0.0819
59 H2O 0.1518 0.5860
60 E-Acetate 0.7110 0.0089
61 AceticAcid 0.1161 0.3231
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.5346 11.0285
20 H2O (%) 170.5631 739.6260
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.6767 30.2430
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.6 100 1.259e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.6 100 1.257e-002 1.194e-002 --- --- ---
32 3__Main TS 82.6 100 1.254e-002 1.192e-002 --- --- ---
33 4__Main TS 82.5 100 1.250e-002 1.189e-002 --- --- ---
34 5__Main TS 82.5 100 1.246e-002 1.185e-002 --- --- ---
35 6__Main TS 82.4 100 1.241e-002 1.181e-002 --- --- ---
36 7__Main TS 82.4 100 1.235e-002 1.176e-002 --- --- ---
37 8__Main TS 82.3 100 1.227e-002 1.170e-002 --- --- ---
38 9__Main TS 82.3 100 1.216e-002 1.162e-002 --- --- ---
39 10__Main TS 82.3 100 1.203e-002 1.151e-002 --- --- ---
40 11__Main TS 82.3 100 1.184e-002 1.138e-002 --- --- ---
41 12__Main TS 82.4 100 1.159e-002 1.119e-002 --- --- ---
42 13__Main TS 82.7 100 1.125e-002 1.094e-002 --- --- ---
43 14__Main TS 83.3 100 1.083e-002 1.060e-002 --- --- ---
44 15__Main TS 84.1 100 1.034e-002 1.018e-002 --- --- ---
45 16__Main TS 84.9 100 9.842e-003 9.694e-003 --- --- ---
46 17__Main TS 85.6 100 1.324e-002 9.192e-003 3.000e-003 --- ---
47 Reboiler 93.6 100 --- 9.590e-003 --- 3.650e-003 364 *
51 Condenser 74.44 -4.353e+005 -3.915e+005 ---
52 1__Main TS 82.61 -4.392e+005 -4.014e+005 ---
53 2__Main TS 82.59 -4.378e+005 -3.999e+005 ---
54 3__Main TS 82.55 -4.364e+005 -3.984e+005 ---
55 4__Main TS 82.51 -4.347e+005 -3.968e+005 ---
56 5__Main TS 82.47 -4.329e+005 -3.949e+005 ---
57 6__Main TS 82.42 -4.308e+005 -3.929e+005 ---
58 7__Main TS 82.38 -4.282e+005 -3.904e+005 ---
59 8__Main TS 82.33 -4.250e+005 -3.875e+005 ---
60 9__Main TS 82.30 -4.210e+005 -3.839e+005 ---
61 10__Main TS 82.28 -4.157e+005 -3.792e+005 ---
62 11__Main TS 82.31 -4.087e+005 -3.731e+005 ---
63 12__Main TS 82.44 -3.992e+005 -3.650e+005 ---
64 13__Main TS 82.75 -3.868e+005 -3.540e+005 ---
65 14__Main TS 83.29 -3.710e+005 -3.393e+005 ---
66 15__Main TS 84.06 -3.528e+005 -3.206e+005 ---
67 16__Main TS 84.87 -3.347e+005 -2.987e+005 ---
68 17__Main TS 85.55 -3.213e+005 -2.763e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.60 -3.367e+005 -2.775e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.44*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.60*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 70.00 * 70.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1780 -1780
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.49 74.49
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1415 -1415
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0208 0.0031 0.0131 0.0000 0.0151
43 H2O 0.0005 0.1512 0.0089 0.0371 0.0000 0.0342
44 E-Acetate 0.0023 0.7102 0.2034 0.8533 0.0002 0.8665
45 AceticAcid 0.0004 0.1178 0.0230 0.0964 0.0000 0.0843
46 Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0208 0.0031 0.0131 0.0000 0.0151
52 H2O 0.0005 0.1512 0.0089 0.0371 0.0000 0.0342
53 E-Acetate 0.0023 0.7102 0.2034 0.8533 0.0002 0.8665
54 AceticAcid 0.0004 0.1178 0.0230 0.0964 0.0000 0.0843
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.53 93.53
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0827 0.0139 0.1105 0.0000 0.1382
22 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3053
23 E-Acetate 0.0000 0.0090 0.0029 0.0230 0.0000 0.0253
24 AceticAcid 0.0012 0.3222 0.0706 0.5607 0.0001 0.5312
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0827 0.0139 0.1105 0.0000 0.1382
31 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3053
32 E-Acetate 0.0000 0.0090 0.0029 0.0230 0.0000 0.0253
33 AceticAcid 0.0012 0.3222 0.0706 0.5607 0.0001 0.5312
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.49 74.49 74.49
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5958 0.0000 0.5958
49 Heat Flow (kJ/h) -3538 0.0000 -3538
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0208 0.0078 0.0131 0.0000 0.0151
58 H2O 0.0012 0.1512 0.0221 0.0371 0.0000 0.0342
59 E-Acetate 0.0058 0.7102 0.5084 0.8533 0.0006 0.8665
60 AceticAcid 0.0010 0.1178 0.0575 0.0964 0.0001 0.0843
61 Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0240 0.0000 0.0153 0.0000 0.0175
67 H2O 0.0000 0.2046 0.0000 0.0512 0.0000 0.0466
68 E-Acetate 0.0000 0.7457 0.0000 0.9120 0.0000 0.9172
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0258 0.0000 0.0215 0.0000 0.0186
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0208 0.0078 0.0131 0.0000 0.0151
22 H2O 0.0012 0.1512 0.0221 0.0371 0.0000 0.0342
23 E-Acetate 0.0058 0.7102 0.5084 0.8533 0.0006 0.8665
24 AceticAcid 0.0010 0.1178 0.0575 0.0964 0.0001 0.0843
25 Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0208 0.0827
59 H2O 0.1512 0.5860
60 E-Acetate 0.7102 0.0090
61 AceticAcid 0.1178 0.3222
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4956 11.1415
20 H2O (%) 169.8855 739.6100
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.8137 30.1574
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.7 100 1.248e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.7 100 1.246e-002 1.183e-002 --- --- ---
32 3__Main TS 82.7 100 1.243e-002 1.181e-002 --- --- ---
33 4__Main TS 82.6 100 1.239e-002 1.178e-002 --- --- ---
34 5__Main TS 82.6 100 1.235e-002 1.174e-002 --- --- ---
35 6__Main TS 82.6 100 1.230e-002 1.170e-002 --- --- ---
36 7__Main TS 82.5 100 1.223e-002 1.165e-002 --- --- ---
37 8__Main TS 82.5 100 1.216e-002 1.158e-002 --- --- ---
38 9__Main TS 82.5 100 1.205e-002 1.151e-002 --- --- ---
39 10__Main TS 82.5 100 1.192e-002 1.140e-002 --- --- ---
40 11__Main TS 82.5 100 1.173e-002 1.127e-002 --- --- ---
41 12__Main TS 82.7 100 1.148e-002 1.108e-002 --- --- ---
42 13__Main TS 83.0 100 1.115e-002 1.083e-002 --- --- ---
43 14__Main TS 83.5 100 1.073e-002 1.050e-002 --- --- ---
44 15__Main TS 84.2 100 1.025e-002 1.008e-002 --- --- ---
45 16__Main TS 84.9 100 9.742e-003 9.595e-003 --- --- ---
46 17__Main TS 85.5 100 1.314e-002 9.093e-003 3.000e-003 --- ---
47 Reboiler 93.5 100 --- 9.485e-003 --- 3.650e-003 360 *
51 Condenser 74.49 -4.355e+005 -3.917e+005 ---
52 1__Main TS 82.74 -4.393e+005 -4.016e+005 ---
53 2__Main TS 82.71 -4.379e+005 -4.000e+005 ---
54 3__Main TS 82.68 -4.364e+005 -3.985e+005 ---
55 4__Main TS 82.64 -4.348e+005 -3.968e+005 ---
56 5__Main TS 82.60 -4.329e+005 -3.950e+005 ---
57 6__Main TS 82.56 -4.308e+005 -3.929e+005 ---
58 7__Main TS 82.52 -4.282e+005 -3.904e+005 ---
59 8__Main TS 82.48 -4.249e+005 -3.874e+005 ---
60 9__Main TS 82.46 -4.209e+005 -3.838e+005 ---
61 10__Main TS 82.46 -4.155e+005 -3.791e+005 ---
62 11__Main TS 82.52 -4.085e+005 -3.729e+005 ---
63 12__Main TS 82.67 -3.990e+005 -3.648e+005 ---
64 13__Main TS 82.99 -3.866e+005 -3.537e+005 ---
65 14__Main TS 83.52 -3.710e+005 -3.391e+005 ---
66 15__Main TS 84.22 -3.529e+005 -3.205e+005 ---
67 16__Main TS 84.93 -3.349e+005 -2.987e+005 ---
68 17__Main TS 85.49 -3.213e+005 -2.763e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.53 -3.365e+005 -2.774e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.49*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.53*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 80.00 * 80.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1776 -1776
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.54 74.54
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2384 0.2384
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0205 0.0031 0.0129 0.0000 0.0149
43 H2O 0.0005 0.1506 0.0088 0.0370 0.0000 0.0341
44 E-Acetate 0.0023 0.7095 0.2031 0.8523 0.0002 0.8656
45 AceticAcid 0.0004 0.1195 0.0233 0.0978 0.0000 0.0855
46 Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0205 0.0031 0.0129 0.0000 0.0149
52 H2O 0.0005 0.1506 0.0088 0.0370 0.0000 0.0341
53 E-Acetate 0.0023 0.7095 0.2031 0.8523 0.0002 0.8656
54 AceticAcid 0.0004 0.1195 0.0233 0.0978 0.0000 0.0855
55 Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.46 93.46
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1259 0.1259
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0836 0.0141 0.1117 0.0000 0.1397
22 H2O 0.0021 0.5859 0.0385 0.3059 0.0000 0.3052
23 E-Acetate 0.0000 0.0091 0.0029 0.0232 0.0000 0.0255
24 AceticAcid 0.0012 0.3213 0.0704 0.5592 0.0001 0.5295
25 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0836 0.0141 0.1117 0.0000 0.1397
31 H2O 0.0021 0.5859 0.0385 0.3059 0.0000 0.3052
32 E-Acetate 0.0000 0.0091 0.0029 0.0232 0.0000 0.0255
33 AceticAcid 0.0012 0.3213 0.0704 0.5592 0.0001 0.5295
34 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.54 74.54 74.54
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5959 0.0000 0.5959
49 Heat Flow (kJ/h) -3539 0.0000 -3539
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0205 0.0077 0.0129 0.0000 0.0149
58 H2O 0.0012 0.1506 0.0220 0.0370 0.0000 0.0341
59 E-Acetate 0.0058 0.7095 0.5079 0.8523 0.0006 0.8656
60 AceticAcid 0.0010 0.1195 0.0583 0.0978 0.0001 0.0855
61 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0236 0.0000 0.0151 0.0000 0.0172
67 H2O 0.0000 0.2040 0.0000 0.0510 0.0000 0.0465
68 E-Acetate 0.0000 0.7462 0.0000 0.9121 0.0000 0.9174
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0262 0.0000 0.0219 0.0000 0.0189
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0205 0.0077 0.0129 0.0000 0.0149
22 H2O 0.0012 0.1506 0.0220 0.0370 0.0000 0.0341
23 E-Acetate 0.0058 0.7095 0.5079 0.8523 0.0006 0.8656
24 AceticAcid 0.0010 0.1195 0.0583 0.0978 0.0001 0.0855
25 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0205 0.0836
59 H2O 0.1506 0.5859
60 E-Acetate 0.7095 0.0091
61 AceticAcid 0.1195 0.3213
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4568 11.2627
20 H2O (%) 169.2240 739.4988
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.9562 30.0722
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 82.9 100 1.237e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.8 100 1.234e-002 1.172e-002 --- --- ---
32 3__Main TS 82.8 100 1.231e-002 1.169e-002 --- --- ---
33 4__Main TS 82.8 100 1.228e-002 1.166e-002 --- --- ---
34 5__Main TS 82.7 100 1.223e-002 1.163e-002 --- --- ---
35 6__Main TS 82.7 100 1.218e-002 1.158e-002 --- --- ---
36 7__Main TS 82.7 100 1.212e-002 1.153e-002 --- --- ---
37 8__Main TS 82.6 100 1.204e-002 1.147e-002 --- --- ---
38 9__Main TS 82.6 100 1.194e-002 1.139e-002 --- --- ---
39 10__Main TS 82.7 100 1.181e-002 1.129e-002 --- --- ---
40 11__Main TS 82.7 100 1.162e-002 1.116e-002 --- --- ---
41 12__Main TS 82.9 100 1.138e-002 1.097e-002 --- --- ---
42 13__Main TS 83.2 100 1.105e-002 1.073e-002 --- --- ---
43 14__Main TS 83.8 100 1.063e-002 1.040e-002 --- --- ---
44 15__Main TS 84.4 100 1.015e-002 9.981e-003 --- --- ---
45 16__Main TS 85.0 100 9.642e-003 9.495e-003 --- --- ---
46 17__Main TS 85.4 100 1.303e-002 8.992e-003 3.000e-003 --- ---
47 Reboiler 93.5 100 --- 9.379e-003 --- 3.650e-003 356 *
51 Condenser 74.54 -4.356e+005 -3.919e+005 ---
52 1__Main TS 82.86 -4.394e+005 -4.017e+005 ---
53 2__Main TS 82.84 -4.380e+005 -4.002e+005 ---
54 3__Main TS 82.80 -4.365e+005 -3.986e+005 ---
55 4__Main TS 82.77 -4.348e+005 -3.969e+005 ---
56 5__Main TS 82.73 -4.329e+005 -3.950e+005 ---
57 6__Main TS 82.70 -4.307e+005 -3.928e+005 ---
58 7__Main TS 82.67 -4.281e+005 -3.903e+005 ---
59 8__Main TS 82.64 -4.248e+005 -3.873e+005 ---
60 9__Main TS 82.63 -4.207e+005 -3.836e+005 ---
61 10__Main TS 82.66 -4.153e+005 -3.789e+005 ---
62 11__Main TS 82.74 -4.083e+005 -3.727e+005 ---
63 12__Main TS 82.91 -3.988e+005 -3.645e+005 ---
64 13__Main TS 83.24 -3.864e+005 -3.535e+005 ---
65 14__Main TS 83.75 -3.709e+005 -3.389e+005 ---
66 15__Main TS 84.38 -3.531e+005 -3.204e+005 ---
67 16__Main TS 84.98 -3.350e+005 -2.987e+005 ---
68 17__Main TS 85.43 -3.212e+005 -2.763e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.46 -3.364e+005 -2.773e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.54*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.46*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 90.00 * 90.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1772 -1772
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.59 74.59
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2384 0.2384
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0202 0.0030 0.0127 0.0000 0.0146
43 H2O 0.0005 0.1500 0.0088 0.0368 0.0000 0.0339
44 E-Acetate 0.0023 0.7086 0.2029 0.8512 0.0002 0.8646
45 AceticAcid 0.0004 0.1213 0.0237 0.0993 0.0000 0.0868
46 Total 0.0033 1.0000 0.2384 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0202 0.0030 0.0127 0.0000 0.0146
52 H2O 0.0005 0.1500 0.0088 0.0368 0.0000 0.0339
53 E-Acetate 0.0023 0.7086 0.2029 0.8512 0.0002 0.8646
54 AceticAcid 0.0004 0.1213 0.0237 0.0993 0.0000 0.0868
55 Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.39 93.39
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1259 0.1259
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1227 -1227
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0846 0.0142 0.1130 0.0000 0.1413
22 H2O 0.0021 0.5858 0.0385 0.3058 0.0000 0.3050
23 E-Acetate 0.0000 0.0092 0.0030 0.0235 0.0000 0.0258
24 AceticAcid 0.0012 0.3204 0.0702 0.5577 0.0001 0.5279
25 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0846 0.0142 0.1130 0.0000 0.1413
31 H2O 0.0021 0.5858 0.0385 0.3058 0.0000 0.3050
32 E-Acetate 0.0000 0.0092 0.0030 0.0235 0.0000 0.0258
33 AceticAcid 0.0012 0.3204 0.0702 0.5577 0.0001 0.5279
34 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.59 74.59 74.59
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5959 0.0000 0.5959
49 Heat Flow (kJ/h) -3540 0.0000 -3540
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0202 0.0075 0.0127 0.0000 0.0146
58 H2O 0.0012 0.1500 0.0220 0.0368 0.0000 0.0339
59 E-Acetate 0.0058 0.7086 0.5072 0.8512 0.0006 0.8646
60 AceticAcid 0.0010 0.1213 0.0592 0.0993 0.0001 0.0868
61 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0232 0.0000 0.0148 0.0000 0.0169
67 H2O 0.0000 0.2034 0.0000 0.0508 0.0000 0.0463
68 E-Acetate 0.0000 0.7467 0.0000 0.9122 0.0000 0.9175
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0267 0.0000 0.0222 0.0000 0.0192
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0202 0.0075 0.0127 0.0000 0.0146
22 H2O 0.0012 0.1500 0.0220 0.0368 0.0000 0.0339
23 E-Acetate 0.0058 0.7086 0.5072 0.8512 0.0006 0.8646
24 AceticAcid 0.0010 0.1213 0.0592 0.0993 0.0001 0.0868
25 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0202 0.0846
59 H2O 0.1500 0.5858
60 E-Acetate 0.7086 0.0092
61 AceticAcid 0.1213 0.3204
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4182 11.3931
20 H2O (%) 168.5841 739.2782
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 10.1045 29.9877
23
COLUMN PROFILES
24
29 Condenser 74.6 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 83.0 100 1.226e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 83.0 100 1.223e-002 1.161e-002 --- --- ---
32 3__Main TS 82.9 100 1.220e-002 1.158e-002 --- --- ---
33 4__Main TS 82.9 100 1.216e-002 1.155e-002 --- --- ---
34 5__Main TS 82.9 100 1.212e-002 1.151e-002 --- --- ---
35 6__Main TS 82.8 100 1.207e-002 1.147e-002 --- --- ---
36 7__Main TS 82.8 100 1.201e-002 1.142e-002 --- --- ---
37 8__Main TS 82.8 100 1.193e-002 1.136e-002 --- --- ---
38 9__Main TS 82.8 100 1.183e-002 1.128e-002 --- --- ---
39 10__Main TS 82.9 100 1.169e-002 1.118e-002 --- --- ---
40 11__Main TS 83.0 100 1.151e-002 1.104e-002 --- --- ---
41 12__Main TS 83.2 100 1.127e-002 1.086e-002 --- --- ---
42 13__Main TS 83.5 100 1.094e-002 1.062e-002 --- --- ---
43 14__Main TS 84.0 100 1.053e-002 1.029e-002 --- --- ---
44 15__Main TS 84.6 100 1.004e-002 9.878e-003 --- --- ---
45 16__Main TS 85.0 100 9.540e-003 9.394e-003 --- --- ---
46 17__Main TS 85.4 100 1.292e-002 8.890e-003 3.000e-003 --- ---
47 Reboiler 93.4 100 --- 9.271e-003 --- 3.650e-003 352 *
51 Condenser 74.59 -4.357e+005 -3.921e+005 ---
52 1__Main TS 83.00 -4.395e+005 -4.019e+005 ---
53 2__Main TS 82.97 -4.380e+005 -4.003e+005 ---
54 3__Main TS 82.94 -4.365e+005 -3.986e+005 ---
55 4__Main TS 82.90 -4.348e+005 -3.969e+005 ---
56 5__Main TS 82.87 -4.329e+005 -3.950e+005 ---
57 6__Main TS 82.84 -4.307e+005 -3.928e+005 ---
58 7__Main TS 82.82 -4.280e+005 -3.903e+005 ---
59 8__Main TS 82.81 -4.247e+005 -3.872e+005 ---
60 9__Main TS 82.82 -4.205e+005 -3.835e+005 ---
61 10__Main TS 82.86 -4.151e+005 -3.787e+005 ---
62 11__Main TS 82.97 -4.080e+005 -3.725e+005 ---
63 12__Main TS 83.17 -3.986e+005 -3.642e+005 ---
64 13__Main TS 83.51 -3.863e+005 -3.532e+005 ---
65 14__Main TS 83.99 -3.709e+005 -3.387e+005 ---
66 15__Main TS 84.55 -3.532e+005 -3.203e+005 ---
67 16__Main TS 85.04 -3.352e+005 -2.988e+005 ---
68 17__Main TS 85.37 -3.211e+005 -2.763e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.39 -3.362e+005 -2.772e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.59*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.39*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 100.0 * 100.0
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1768 -1768
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.64 74.64
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2384 0.2384
34 Heat Flow (kJ/h) -1417 -1417
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0199 0.0030 0.0125 0.0000 0.0144
43 H2O 0.0005 0.1495 0.0088 0.0367 0.0000 0.0338
44 E-Acetate 0.0023 0.7076 0.2026 0.8500 0.0002 0.8636
45 AceticAcid 0.0004 0.1231 0.0240 0.1008 0.0000 0.0881
46 Total 0.0033 1.0000 0.2384 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0199 0.0030 0.0125 0.0000 0.0144
52 H2O 0.0005 0.1495 0.0088 0.0367 0.0000 0.0338
53 E-Acetate 0.0023 0.7076 0.2026 0.8500 0.0002 0.8636
54 AceticAcid 0.0004 0.1231 0.0240 0.1008 0.0000 0.0881
55 Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.32 93.32
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1259 0.1259
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1227 -1227
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0857 0.0144 0.1144 0.0000 0.1429
22 H2O 0.0021 0.5855 0.0385 0.3057 0.0000 0.3047
23 E-Acetate 0.0000 0.0093 0.0030 0.0238 0.0000 0.0262
24 AceticAcid 0.0012 0.3195 0.0700 0.5561 0.0001 0.5262
25 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0857 0.0144 0.1144 0.0000 0.1429
31 H2O 0.0021 0.5855 0.0385 0.3057 0.0000 0.3047
32 E-Acetate 0.0000 0.0093 0.0030 0.0238 0.0000 0.0262
33 AceticAcid 0.0012 0.3195 0.0700 0.5561 0.0001 0.5262
34 Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.64 74.64 74.64
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5959 0.0000 0.5959
49 Heat Flow (kJ/h) -3541 0.0000 -3541
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0199 0.0074 0.0125 0.0000 0.0144
58 H2O 0.0012 0.1495 0.0219 0.0367 0.0000 0.0338
59 E-Acetate 0.0057 0.7076 0.5065 0.8500 0.0006 0.8636
60 AceticAcid 0.0010 0.1231 0.0601 0.1008 0.0001 0.0881
61 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0228 0.0000 0.0145 0.0000 0.0166
67 H2O 0.0000 0.2028 0.0000 0.0506 0.0000 0.0462
68 E-Acetate 0.0000 0.7472 0.0000 0.9122 0.0000 0.9176
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0272 0.0000 0.0226 0.0000 0.0196
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0199 0.0074 0.0125 0.0000 0.0144
22 H2O 0.0012 0.1495 0.0219 0.0367 0.0000 0.0338
23 E-Acetate 0.0057 0.7076 0.5065 0.8500 0.0006 0.8636
24 AceticAcid 0.0010 0.1231 0.0601 0.1008 0.0001 0.0881
25 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0199 0.0857
59 H2O 0.1495 0.5855
60 E-Acetate 0.7076 0.0093
61 AceticAcid 0.1231 0.3195
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.3799 11.5336
20 H2O (%) 167.9724 738.9315
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 10.2589 29.9044
23
COLUMN PROFILES
24
29 Condenser 74.6 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 83.1 100 1.214e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 83.1 100 1.211e-002 1.149e-002 --- --- ---
32 3__Main TS 83.1 100 1.208e-002 1.146e-002 --- --- ---
33 4__Main TS 83.0 100 1.204e-002 1.143e-002 --- --- ---
34 5__Main TS 83.0 100 1.200e-002 1.139e-002 --- --- ---
35 6__Main TS 83.0 100 1.195e-002 1.135e-002 --- --- ---
36 7__Main TS 83.0 100 1.189e-002 1.130e-002 --- --- ---
37 8__Main TS 83.0 100 1.181e-002 1.124e-002 --- --- ---
38 9__Main TS 83.0 100 1.171e-002 1.116e-002 --- --- ---
39 10__Main TS 83.1 100 1.158e-002 1.106e-002 --- --- ---
40 11__Main TS 83.2 100 1.140e-002 1.093e-002 --- --- ---
41 12__Main TS 83.5 100 1.116e-002 1.075e-002 --- --- ---
42 13__Main TS 83.8 100 1.084e-002 1.051e-002 --- --- ---
43 14__Main TS 84.2 100 1.042e-002 1.019e-002 --- --- ---
44 15__Main TS 84.7 100 9.942e-003 9.775e-003 --- --- ---
45 16__Main TS 85.1 100 9.437e-003 9.292e-003 --- --- ---
46 17__Main TS 85.3 100 1.281e-002 8.787e-003 3.000e-003 --- ---
47 Reboiler 93.3 100 --- 9.162e-003 --- 3.650e-003 348 *
51 Condenser 74.64 -4.359e+005 -3.923e+005 ---
52 1__Main TS 83.13 -4.396e+005 -4.020e+005 ---
53 2__Main TS 83.11 -4.381e+005 -4.004e+005 ---
54 3__Main TS 83.08 -4.365e+005 -3.987e+005 ---
55 4__Main TS 83.05 -4.348e+005 -3.969e+005 ---
56 5__Main TS 83.02 -4.328e+005 -3.950e+005 ---
57 6__Main TS 83.00 -4.306e+005 -3.927e+005 ---
58 7__Main TS 82.99 -4.279e+005 -3.902e+005 ---
59 8__Main TS 82.99 -4.245e+005 -3.871e+005 ---
60 9__Main TS 83.02 -4.203e+005 -3.833e+005 ---
61 10__Main TS 83.09 -4.149e+005 -3.784e+005 ---
62 11__Main TS 83.22 -4.077e+005 -3.722e+005 ---
63 12__Main TS 83.45 -3.983e+005 -3.639e+005 ---
64 13__Main TS 83.80 -3.861e+005 -3.529e+005 ---
65 14__Main TS 84.25 -3.709e+005 -3.384e+005 ---
66 15__Main TS 84.72 -3.534e+005 -3.203e+005 ---
67 16__Main TS 85.09 -3.354e+005 -2.989e+005 ---
68 17__Main TS 85.30 -3.210e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.32 -3.361e+005 -2.770e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.8e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.64*
21 1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.5e+005 * *
100.00
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.32*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 5.000 * 5.000
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
55 Molar Entropy (kJ/kgmole-C) -3.350 -3.350
56 Heat Flow (kJ/h) -845.0 -845.0
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.83 93.83
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0791 0.0133 0.1054 0.0000 0.1321
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0242
24 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5387
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0791 0.0133 0.1054 0.0000 0.1321
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0242
33 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5387
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0791
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0086
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6913 10.6471
20 H2O (%) 173.3495 738.9463
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1781 30.5854
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.6 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.4 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.6 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.7 100 1.382e-002 9.578e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 1.017e-002 --- 3.650e-003 386 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.64 -4.161e+005 -3.796e+005 ---
62 11__Main TS 81.60 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.65 -3.999e+005 -3.657e+005 ---
64 13__Main TS 81.89 -3.873e+005 -3.548e+005 ---
65 14__Main TS 82.47 -3.712e+005 -3.401e+005 ---
66 15__Main TS 83.43 -3.525e+005 -3.210e+005 ---
67 16__Main TS 84.62 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.72 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.83 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.9e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.83*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 10.00 * 10.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -842.8 -842.8
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0791 0.0133 0.1054 0.0000 0.1321
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0242
24 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5387
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0791 0.0133 0.1054 0.0000 0.1321
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0242
33 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5387
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0791
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0086
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6913 10.6465
20 H2O (%) 173.3502 738.9509
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1781 30.5850
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.6 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.4 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.6 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.7 100 1.376e-002 9.579e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 1.011e-002 --- 3.650e-003 383 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.64 -4.161e+005 -3.796e+005 ---
62 11__Main TS 81.60 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.65 -3.999e+005 -3.657e+005 ---
64 13__Main TS 81.89 -3.873e+005 -3.548e+005 ---
65 14__Main TS 82.47 -3.712e+005 -3.401e+005 ---
66 15__Main TS 83.44 -3.525e+005 -3.210e+005 ---
67 16__Main TS 84.63 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.73 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 30.00 * 30.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -834.2 -834.2
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0791 0.0133 0.1053 0.0000 0.1321
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0243
24 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0791 0.0133 0.1053 0.0000 0.1321
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0086 0.0028 0.0220 0.0000 0.0243
33 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0791
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0086
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6913 10.6441
20 H2O (%) 173.3534 738.9698
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1781 30.5834
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.7 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.8 100 1.353e-002 9.580e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.884e-003 --- 3.650e-003 375 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.796e+005 ---
62 11__Main TS 81.61 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.66 -3.999e+005 -3.657e+005 ---
64 13__Main TS 81.91 -3.873e+005 -3.548e+005 ---
65 14__Main TS 82.50 -3.711e+005 -3.400e+005 ---
66 15__Main TS 83.48 -3.524e+005 -3.210e+005 ---
67 16__Main TS 84.66 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.77 -3.217e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 40.00 * 40.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -829.8 -829.8
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0087 0.0028 0.0220 0.0000 0.0243
24 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0087 0.0028 0.0220 0.0000 0.0243
33 AceticAcid 0.0012 0.3268 0.0716 0.5676 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0790
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0087
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6914 10.6428
20 H2O (%) 173.3551 738.9795
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1780 30.5825
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.7 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.8 100 1.342e-002 9.581e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.768e-003 --- 3.650e-003 370 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.795e+005 ---
62 11__Main TS 81.61 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.66 -3.999e+005 -3.656e+005 ---
64 13__Main TS 81.92 -3.873e+005 -3.548e+005 ---
65 14__Main TS 82.51 -3.711e+005 -3.400e+005 ---
66 15__Main TS 83.49 -3.524e+005 -3.209e+005 ---
67 16__Main TS 84.68 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.79 -3.217e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 50.00 * 50.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -825.4 -825.4
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0243
24 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0243
33 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0790
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0087
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6914 10.6415
20 H2O (%) 173.3570 738.9894
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1780 30.5817
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.6 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.7 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.8 100 1.330e-002 9.582e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.651e-003 --- 3.650e-003 366 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.980e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.212e+005 -3.841e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.795e+005 ---
62 11__Main TS 81.61 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.67 -3.998e+005 -3.656e+005 ---
64 13__Main TS 81.93 -3.872e+005 -3.547e+005 ---
65 14__Main TS 82.52 -3.711e+005 -3.400e+005 ---
66 15__Main TS 83.51 -3.524e+005 -3.209e+005 ---
67 16__Main TS 84.70 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.81 -3.218e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 60.00 * 60.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -820.9 -820.9
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
23 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0244
24 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3050
32 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0244
33 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0790
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0087
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6914 10.6402
20 H2O (%) 173.3589 738.9994
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1780 30.5808
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.7 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.5 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.7 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.8 100 1.318e-002 9.583e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.532e-003 --- 3.650e-003 361 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.979e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.212e+005 -3.841e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.795e+005 ---
62 11__Main TS 81.61 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.67 -3.998e+005 -3.656e+005 ---
64 13__Main TS 81.93 -3.872e+005 -3.547e+005 ---
65 14__Main TS 82.54 -3.710e+005 -3.400e+005 ---
66 15__Main TS 83.53 -3.524e+005 -3.209e+005 ---
67 16__Main TS 84.72 -3.343e+005 -2.986e+005 ---
68 17__Main TS 85.83 -3.219e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.780e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 70.00 * 70.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -816.3 -816.3
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7132 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
22 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3051
23 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0244
24 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
31 H2O 0.0021 0.5855 0.0385 0.3051 0.0000 0.3051
32 E-Acetate 0.0000 0.0087 0.0028 0.0221 0.0000 0.0244
33 AceticAcid 0.0012 0.3268 0.0716 0.5675 0.0001 0.5386
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7132 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0790
59 H2O 0.1543 0.5855
60 E-Acetate 0.7132 0.0087
61 AceticAcid 0.1101 0.3268
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6915 10.6389
20 H2O (%) 173.3609 739.0097
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1780 30.5799
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.7 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 81.9 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.6 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.5 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.7 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.8 100 1.306e-002 9.584e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.411e-003 --- 3.650e-003 357 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.979e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.212e+005 -3.840e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.795e+005 ---
62 11__Main TS 81.62 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.68 -3.998e+005 -3.656e+005 ---
64 13__Main TS 81.94 -3.872e+005 -3.547e+005 ---
65 14__Main TS 82.55 -3.710e+005 -3.399e+005 ---
66 15__Main TS 83.55 -3.524e+005 -3.209e+005 ---
67 16__Main TS 84.74 -3.344e+005 -2.986e+005 ---
68 17__Main TS 85.85 -3.219e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.781e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 80.00 * 80.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -811.7 -811.7
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
44 E-Acetate 0.0023 0.7131 0.2042 0.8577 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0224 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1543 0.0090 0.0379 0.0000 0.0349
53 E-Acetate 0.0023 0.7131 0.2042 0.8577 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.82 93.82
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
22 H2O 0.0021 0.5856 0.0385 0.3051 0.0000 0.3051
23 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0244
24 AceticAcid 0.0012 0.3267 0.0716 0.5675 0.0001 0.5385
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0790 0.0133 0.1053 0.0000 0.1320
31 H2O 0.0021 0.5856 0.0385 0.3051 0.0000 0.3051
32 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0244
33 AceticAcid 0.0012 0.3267 0.0716 0.5675 0.0001 0.5385
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
59 E-Acetate 0.0058 0.7131 0.5105 0.8577 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2074 0.0000 0.0520 0.0000 0.0474
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0224 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1543 0.0226 0.0379 0.0000 0.0349
23 E-Acetate 0.0058 0.7131 0.5105 0.8577 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0224 0.0790
59 H2O 0.1543 0.5856
60 E-Acetate 0.7131 0.0087
61 AceticAcid 0.1101 0.3267
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6915 10.6375
20 H2O (%) 173.3631 739.0202
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1780 30.5790
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.7 100 1.259e-002 1.204e-002 --- --- ---
39 10__Main TS 81.7 100 1.245e-002 1.194e-002 --- --- ---
40 11__Main TS 81.6 100 1.225e-002 1.180e-002 --- --- ---
41 12__Main TS 81.7 100 1.200e-002 1.160e-002 --- --- ---
42 13__Main TS 82.0 100 1.166e-002 1.135e-002 --- --- ---
43 14__Main TS 82.6 100 1.123e-002 1.101e-002 --- --- ---
44 15__Main TS 83.6 100 1.073e-002 1.058e-002 --- --- ---
45 16__Main TS 84.8 100 1.023e-002 1.008e-002 --- --- ---
46 17__Main TS 85.9 100 1.294e-002 9.585e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.289e-003 --- 3.650e-003 352 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.994e+005 ---
54 3__Main TS 82.10 -4.360e+005 -3.979e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.328e+005 -3.947e+005 ---
57 6__Main TS 81.94 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.87 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.80 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.72 -4.212e+005 -3.840e+005 ---
61 10__Main TS 81.65 -4.161e+005 -3.795e+005 ---
62 11__Main TS 81.62 -4.092e+005 -3.736e+005 ---
63 12__Main TS 81.68 -3.998e+005 -3.656e+005 ---
64 13__Main TS 81.95 -3.872e+005 -3.547e+005 ---
65 14__Main TS 82.57 -3.710e+005 -3.399e+005 ---
66 15__Main TS 83.57 -3.524e+005 -3.208e+005 ---
67 16__Main TS 84.77 -3.344e+005 -2.986e+005 ---
68 17__Main TS 85.87 -3.220e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.82 -3.373e+005 -2.781e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.82*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
47 Overall Vapour Phase
49 Temperature: (C) 90.00 * 90.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -693.6 -693.6
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0225 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1544 0.0090 0.0380 0.0000 0.0349
44 E-Acetate 0.0023 0.7130 0.2042 0.8576 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0225 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1544 0.0090 0.0380 0.0000 0.0349
53 E-Acetate 0.0023 0.7130 0.2042 0.8576 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.79 93.79
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0787 0.0132 0.1048 0.0000 0.1314
22 H2O 0.0021 0.5858 0.0385 0.3051 0.0000 0.3051
23 E-Acetate 0.0000 0.0091 0.0029 0.0231 0.0000 0.0255
24 AceticAcid 0.0012 0.3265 0.0716 0.5669 0.0001 0.5380
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0787 0.0132 0.1048 0.0000 0.1314
31 H2O 0.0021 0.5858 0.0385 0.3051 0.0000 0.3051
32 E-Acetate 0.0000 0.0091 0.0029 0.0231 0.0000 0.0255
33 AceticAcid 0.0012 0.3265 0.0716 0.5669 0.0001 0.5380
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0225 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1544 0.0226 0.0380 0.0000 0.0349
59 E-Acetate 0.0058 0.7130 0.5104 0.8576 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2075 0.0000 0.0521 0.0000 0.0475
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0225 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1544 0.0226 0.0380 0.0000 0.0349
23 E-Acetate 0.0058 0.7130 0.5104 0.8576 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0225 0.0787
59 H2O 0.1544 0.5858
60 E-Acetate 0.7130 0.0091
61 AceticAcid 0.1101 0.3265
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6939 10.5957
20 H2O (%) 173.4768 739.2755
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1768 30.5528
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.8 100 1.258e-002 1.204e-002 --- --- ---
39 10__Main TS 81.7 100 1.244e-002 1.193e-002 --- --- ---
40 11__Main TS 81.7 100 1.225e-002 1.179e-002 --- --- ---
41 12__Main TS 81.9 100 1.199e-002 1.160e-002 --- --- ---
42 13__Main TS 82.3 100 1.165e-002 1.134e-002 --- --- ---
43 14__Main TS 83.2 100 1.123e-002 1.100e-002 --- --- ---
44 15__Main TS 84.3 100 1.075e-002 1.058e-002 --- --- ---
45 16__Main TS 85.6 100 1.027e-002 1.010e-002 --- --- ---
46 17__Main TS 86.7 100 9.823e-003 9.616e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 6.173e-003 --- 3.650e-003 234 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.993e+005 ---
54 3__Main TS 82.09 -4.360e+005 -3.979e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.94 -4.306e+005 -3.926e+005 ---
58 7__Main TS 81.88 -4.281e+005 -3.903e+005 ---
59 8__Main TS 81.82 -4.250e+005 -3.874e+005 ---
60 9__Main TS 81.76 -4.210e+005 -3.838e+005 ---
61 10__Main TS 81.72 -4.157e+005 -3.792e+005 ---
62 11__Main TS 81.75 -4.085e+005 -3.731e+005 ---
63 12__Main TS 81.91 -3.989e+005 -3.649e+005 ---
64 13__Main TS 82.35 -3.860e+005 -3.537e+005 ---
65 14__Main TS 83.17 -3.698e+005 -3.386e+005 ---
66 15__Main TS 84.34 -3.517e+005 -3.196e+005 ---
67 16__Main TS 85.59 -3.349e+005 -2.979e+005 ---
68 17__Main TS 86.66 -3.241e+005 -2.773e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.79 -3.373e+005 -2.784e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS F1 Feed --- Vapour 3.00e-003 * -2.3e+005 * 90.00*
38 Q_R Energy 2.3e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.79*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 100.0 * 100.0
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -691.4 -691.4
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.26 74.26
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2381 0.2381
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0225 0.0034 0.0141 0.0000 0.0163
43 H2O 0.0005 0.1544 0.0090 0.0380 0.0000 0.0349
44 E-Acetate 0.0023 0.7130 0.2042 0.8576 0.0002 0.8700
45 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
46 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0225 0.0034 0.0141 0.0000 0.0163
52 H2O 0.0005 0.1544 0.0090 0.0380 0.0000 0.0349
53 E-Acetate 0.0023 0.7130 0.2042 0.8576 0.0002 0.8700
54 AceticAcid 0.0004 0.1101 0.0215 0.0903 0.0000 0.0788
55 Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.78 93.78
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1262 0.1262
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0787 0.0132 0.1048 0.0000 0.1314
22 H2O 0.0021 0.5858 0.0385 0.3051 0.0000 0.3051
23 E-Acetate 0.0000 0.0091 0.0029 0.0232 0.0000 0.0256
24 AceticAcid 0.0012 0.3265 0.0716 0.5669 0.0001 0.5379
25 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0787 0.0132 0.1048 0.0000 0.1314
31 H2O 0.0021 0.5858 0.0385 0.3051 0.0000 0.3051
32 E-Acetate 0.0000 0.0091 0.0029 0.0232 0.0000 0.0256
33 AceticAcid 0.0012 0.3265 0.0716 0.5669 0.0001 0.5379
34 Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.26 74.26 74.26
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5952 0.0000 0.5952
49 Heat Flow (kJ/h) -3532 0.0000 -3532
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0225 0.0084 0.0141 0.0000 0.0163
58 H2O 0.0013 0.1544 0.0226 0.0380 0.0000 0.0349
59 E-Acetate 0.0058 0.7130 0.5104 0.8576 0.0006 0.8700
60 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
61 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0259 0.0000 0.0166 0.0000 0.0190
67 H2O 0.0000 0.2075 0.0000 0.0521 0.0000 0.0475
68 E-Acetate 0.0000 0.7428 0.0000 0.9114 0.0000 0.9163
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0225 0.0084 0.0141 0.0000 0.0163
22 H2O 0.0013 0.1544 0.0226 0.0380 0.0000 0.0349
23 E-Acetate 0.0058 0.7130 0.5104 0.8576 0.0006 0.8700
24 AceticAcid 0.0009 0.1101 0.0537 0.0903 0.0001 0.0788
25 Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0225 0.0787
59 H2O 0.1544 0.5858
60 E-Acetate 0.7130 0.0091
61 AceticAcid 0.1101 0.3265
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6940 10.5949
20 H2O (%) 173.4808 739.2790
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1767 30.5523
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.300e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.297e-002 1.235e-002 --- --- ---
33 4__Main TS 82.0 100 1.293e-002 1.232e-002 --- --- ---
34 5__Main TS 82.0 100 1.289e-002 1.228e-002 --- --- ---
35 6__Main TS 81.9 100 1.284e-002 1.224e-002 --- --- ---
36 7__Main TS 81.9 100 1.277e-002 1.219e-002 --- --- ---
37 8__Main TS 81.8 100 1.269e-002 1.212e-002 --- --- ---
38 9__Main TS 81.8 100 1.258e-002 1.204e-002 --- --- ---
39 10__Main TS 81.7 100 1.244e-002 1.193e-002 --- --- ---
40 11__Main TS 81.7 100 1.225e-002 1.179e-002 --- --- ---
41 12__Main TS 81.9 100 1.199e-002 1.160e-002 --- --- ---
42 13__Main TS 82.4 100 1.165e-002 1.134e-002 --- --- ---
43 14__Main TS 83.2 100 1.123e-002 1.100e-002 --- --- ---
44 15__Main TS 84.4 100 1.075e-002 1.058e-002 --- --- ---
45 16__Main TS 85.6 100 1.027e-002 1.010e-002 --- --- ---
46 17__Main TS 86.7 100 9.766e-003 9.617e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 6.116e-003 --- 3.650e-003 232 *
51 Condenser 74.26 -4.347e+005 -3.908e+005 ---
52 1__Main TS 82.16 -4.387e+005 -4.007e+005 ---
53 2__Main TS 82.13 -4.374e+005 -3.993e+005 ---
54 3__Main TS 82.09 -4.360e+005 -3.979e+005 ---
55 4__Main TS 82.05 -4.345e+005 -3.964e+005 ---
56 5__Main TS 82.00 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.94 -4.306e+005 -3.926e+005 ---
58 7__Main TS 81.88 -4.281e+005 -3.903e+005 ---
59 8__Main TS 81.82 -4.250e+005 -3.874e+005 ---
60 9__Main TS 81.76 -4.210e+005 -3.838e+005 ---
61 10__Main TS 81.72 -4.157e+005 -3.792e+005 ---
62 11__Main TS 81.75 -4.085e+005 -3.731e+005 ---
63 12__Main TS 81.92 -3.989e+005 -3.649e+005 ---
64 13__Main TS 82.36 -3.859e+005 -3.537e+005 ---
65 14__Main TS 83.18 -3.698e+005 -3.386e+005 ---
66 15__Main TS 84.36 -3.517e+005 -3.195e+005 ---
67 16__Main TS 85.61 -3.349e+005 -2.979e+005 ---
68 17__Main TS 86.68 -3.242e+005 -2.773e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.78 -3.373e+005 -2.784e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.26*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS F1 Feed --- Vapour 3.00e-003 * -2.3e+005 * *
100.00
38 Q_R Energy 2.3e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.78*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: TF0 = TF1 = 5.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 5.000 * 5.000
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1803 -1803
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 5.000 * 5.000
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
55 Molar Entropy (kJ/kgmole-C) -3.350 -3.350
56 Heat Flow (kJ/h) -845.0 -845.0
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.20 74.20
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2380 0.2380
34 Heat Flow (kJ/h) -1412 -1412
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0229 0.0034 0.0144 0.0000 0.0166
43 H2O 0.0005 0.1552 0.0091 0.0382 0.0000 0.0351
44 E-Acetate 0.0023 0.7138 0.2044 0.8587 0.0002 0.8709
45 AceticAcid 0.0004 0.1081 0.0211 0.0887 0.0000 0.0774
46 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0229 0.0034 0.0144 0.0000 0.0166
52 H2O 0.0005 0.1552 0.0091 0.0382 0.0000 0.0351
53 E-Acetate 0.0023 0.7138 0.2044 0.8587 0.0002 0.8709
54 AceticAcid 0.0004 0.1081 0.0211 0.0887 0.0000 0.0774
55 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.90 93.90
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1263 0.1263
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1232 -1232
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0782 0.0131 0.1041 0.0000 0.1306
22 H2O 0.0021 0.5851 0.0385 0.3046 0.0000 0.3047
23 E-Acetate 0.0000 0.0085 0.0027 0.0217 0.0000 0.0240
24 AceticAcid 0.0012 0.3282 0.0719 0.5695 0.0001 0.5407
25 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0782 0.0131 0.1041 0.0000 0.1306
31 H2O 0.0021 0.5851 0.0385 0.3046 0.0000 0.3047
32 E-Acetate 0.0000 0.0085 0.0027 0.0217 0.0000 0.0240
33 AceticAcid 0.0012 0.3282 0.0719 0.5695 0.0001 0.5407
34 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.20 74.20 74.20
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5950 0.0000 0.5950
49 Heat Flow (kJ/h) -3530 0.0000 -3530
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0229 0.0086 0.0144 0.0000 0.0166
58 H2O 0.0013 0.1552 0.0227 0.0382 0.0000 0.0351
59 E-Acetate 0.0058 0.7138 0.5110 0.8587 0.0006 0.8709
60 AceticAcid 0.0009 0.1081 0.0528 0.0887 0.0001 0.0774
61 Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0265 0.0000 0.0170 0.0000 0.0194
67 H2O 0.0000 0.2082 0.0000 0.0523 0.0000 0.0477
68 E-Acetate 0.0000 0.7420 0.0000 0.9112 0.0000 0.9160
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0233 0.0000 0.0195 0.0000 0.0169
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0229 0.0086 0.0144 0.0000 0.0166
22 H2O 0.0013 0.1552 0.0227 0.0382 0.0000 0.0351
23 E-Acetate 0.0058 0.7138 0.5110 0.8587 0.0006 0.8709
24 AceticAcid 0.0009 0.1081 0.0528 0.0887 0.0001 0.0774
25 Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0229 0.0782
59 H2O 0.1552 0.5851
60 E-Acetate 0.7138 0.0085
61 AceticAcid 0.1081 0.3282
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.7499 10.5268
20 H2O (%) 174.4013 738.4714
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.0094 30.7113
23
COLUMN PROFILES
24
29 Condenser 74.2 100 8.125e-003 --- --- 3.250e-003 387 *
30 1__Main TS 82.0 100 1.318e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.0 100 1.315e-002 1.253e-002 --- --- ---
32 3__Main TS 81.9 100 1.312e-002 1.250e-002 --- --- ---
33 4__Main TS 81.9 100 1.309e-002 1.247e-002 --- --- ---
34 5__Main TS 81.8 100 1.305e-002 1.244e-002 --- --- ---
35 6__Main TS 81.8 100 1.299e-002 1.240e-002 --- --- ---
36 7__Main TS 81.7 100 1.293e-002 1.234e-002 --- --- ---
37 8__Main TS 81.6 100 1.285e-002 1.228e-002 --- --- ---
38 9__Main TS 81.5 100 1.274e-002 1.220e-002 --- --- ---
39 10__Main TS 81.4 100 1.260e-002 1.209e-002 --- --- ---
40 11__Main TS 81.4 100 1.240e-002 1.195e-002 --- --- ---
41 12__Main TS 81.4 100 1.215e-002 1.175e-002 --- --- ---
42 13__Main TS 81.6 100 1.180e-002 1.150e-002 --- --- ---
43 14__Main TS 82.2 100 1.137e-002 1.115e-002 --- --- ---
44 15__Main TS 83.2 100 1.087e-002 1.072e-002 --- --- ---
45 16__Main TS 84.5 100 1.037e-002 1.022e-002 --- --- ---
46 17__Main TS 85.8 100 1.397e-002 9.719e-003 3.000e-003 --- ---
47 Reboiler 93.9 100 --- 1.032e-002 --- 3.650e-003 391 *
51 Condenser 74.20 -4.345e+005 -3.905e+005 ---
52 1__Main TS 82.01 -4.385e+005 -4.005e+005 ---
53 2__Main TS 81.98 -4.373e+005 -3.991e+005 ---
54 3__Main TS 81.94 -4.359e+005 -3.978e+005 ---
55 4__Main TS 81.89 -4.344e+005 -3.963e+005 ---
56 5__Main TS 81.84 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.77 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.70 -4.282e+005 -3.904e+005 ---
59 8__Main TS 81.62 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.53 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.44 -4.162e+005 -3.796e+005 ---
62 11__Main TS 81.37 -4.094e+005 -3.737e+005 ---
63 12__Main TS 81.39 -4.001e+005 -3.658e+005 ---
64 13__Main TS 81.62 -3.875e+005 -3.550e+005 ---
65 14__Main TS 82.20 -3.712e+005 -3.403e+005 ---
66 15__Main TS 83.23 -3.524e+005 -3.212e+005 ---
67 16__Main TS 84.53 -3.341e+005 -2.987e+005 ---
68 17__Main TS 85.78 -3.217e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.90 -3.375e+005 -2.782e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.20*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.9e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.90*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 10.00 * 10.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1801 -1801
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 10.00 * 10.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -842.8 -842.8
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.22 74.22
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2380 0.2380
34 Heat Flow (kJ/h) -1412 -1412
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0228 0.0034 0.0143 0.0000 0.0165
43 H2O 0.0005 0.1549 0.0091 0.0381 0.0000 0.0350
44 E-Acetate 0.0023 0.7136 0.2043 0.8584 0.0002 0.8706
45 AceticAcid 0.0004 0.1088 0.0212 0.0892 0.0000 0.0778
46 Total 0.0033 1.0000 0.2380 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0228 0.0034 0.0143 0.0000 0.0165
52 H2O 0.0005 0.1549 0.0091 0.0381 0.0000 0.0350
53 E-Acetate 0.0023 0.7136 0.2043 0.8584 0.0002 0.8706
54 AceticAcid 0.0004 0.1088 0.0212 0.0892 0.0000 0.0778
55 Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.87 93.87
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1263 0.1263
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1232 -1232
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0785 0.0132 0.1045 0.0000 0.1310
22 H2O 0.0021 0.5853 0.0385 0.3048 0.0000 0.3048
23 E-Acetate 0.0000 0.0086 0.0028 0.0218 0.0000 0.0241
24 AceticAcid 0.0012 0.3277 0.0718 0.5689 0.0001 0.5400
25 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0785 0.0132 0.1045 0.0000 0.1310
31 H2O 0.0021 0.5853 0.0385 0.3048 0.0000 0.3048
32 E-Acetate 0.0000 0.0086 0.0028 0.0218 0.0000 0.0241
33 AceticAcid 0.0012 0.3277 0.0718 0.5689 0.0001 0.5400
34 Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.22 74.22 74.22
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5951 0.0000 0.5951
49 Heat Flow (kJ/h) -3531 0.0000 -3531
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0228 0.0085 0.0143 0.0000 0.0165
58 H2O 0.0013 0.1549 0.0227 0.0381 0.0000 0.0350
59 E-Acetate 0.0058 0.7136 0.5108 0.8584 0.0006 0.8706
60 AceticAcid 0.0009 0.1088 0.0531 0.0892 0.0001 0.0778
61 Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0263 0.0000 0.0169 0.0000 0.0193
67 H2O 0.0000 0.2080 0.0000 0.0522 0.0000 0.0476
68 E-Acetate 0.0000 0.7423 0.0000 0.9113 0.0000 0.9161
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0235 0.0000 0.0196 0.0000 0.0170
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0228 0.0085 0.0143 0.0000 0.0165
22 H2O 0.0013 0.1549 0.0227 0.0381 0.0000 0.0350
23 E-Acetate 0.0058 0.7136 0.5108 0.8584 0.0006 0.8706
24 AceticAcid 0.0009 0.1088 0.0531 0.0892 0.0001 0.0778
25 Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0228 0.0785
59 H2O 0.1549 0.5853
60 E-Acetate 0.7136 0.0086
61 AceticAcid 0.1088 0.3277
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.7304 10.5651
20 H2O (%) 174.0520 738.6451
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.0646 30.6691
23
COLUMN PROFILES
24
29 Condenser 74.2 100 8.125e-003 --- --- 3.250e-003 387 *
30 1__Main TS 82.1 100 1.312e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.0 100 1.310e-002 1.247e-002 --- --- ---
32 3__Main TS 82.0 100 1.307e-002 1.245e-002 --- --- ---
33 4__Main TS 81.9 100 1.304e-002 1.242e-002 --- --- ---
34 5__Main TS 81.9 100 1.299e-002 1.239e-002 --- --- ---
35 6__Main TS 81.8 100 1.294e-002 1.234e-002 --- --- ---
36 7__Main TS 81.8 100 1.288e-002 1.229e-002 --- --- ---
37 8__Main TS 81.7 100 1.280e-002 1.223e-002 --- --- ---
38 9__Main TS 81.6 100 1.269e-002 1.215e-002 --- --- ---
39 10__Main TS 81.5 100 1.255e-002 1.204e-002 --- --- ---
40 11__Main TS 81.4 100 1.235e-002 1.190e-002 --- --- ---
41 12__Main TS 81.5 100 1.210e-002 1.170e-002 --- --- ---
42 13__Main TS 81.7 100 1.175e-002 1.145e-002 --- --- ---
43 14__Main TS 82.3 100 1.132e-002 1.110e-002 --- --- ---
44 15__Main TS 83.3 100 1.082e-002 1.067e-002 --- --- ---
45 16__Main TS 84.6 100 1.032e-002 1.017e-002 --- --- ---
46 17__Main TS 85.8 100 1.386e-002 9.673e-003 3.000e-003 --- ---
47 Reboiler 93.9 100 --- 1.021e-002 --- 3.650e-003 387 *
51 Condenser 74.22 -4.345e+005 -3.906e+005 ---
52 1__Main TS 82.06 -4.386e+005 -4.005e+005 ---
53 2__Main TS 82.03 -4.373e+005 -3.992e+005 ---
54 3__Main TS 81.99 -4.360e+005 -3.978e+005 ---
55 4__Main TS 81.94 -4.345e+005 -3.963e+005 ---
56 5__Main TS 81.89 -4.327e+005 -3.946e+005 ---
57 6__Main TS 81.83 -4.307e+005 -3.927e+005 ---
58 7__Main TS 81.76 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.68 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.59 -4.213e+005 -3.841e+005 ---
61 10__Main TS 81.51 -4.162e+005 -3.796e+005 ---
62 11__Main TS 81.45 -4.093e+005 -3.737e+005 ---
63 12__Main TS 81.48 -4.000e+005 -3.658e+005 ---
64 13__Main TS 81.71 -3.874e+005 -3.550e+005 ---
65 14__Main TS 82.29 -3.712e+005 -3.403e+005 ---
66 15__Main TS 83.30 -3.524e+005 -3.211e+005 ---
67 16__Main TS 84.57 -3.342e+005 -2.986e+005 ---
68 17__Main TS 85.77 -3.217e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.87 -3.374e+005 -2.781e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.22*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.9e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.87*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 30.00 * 30.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1794 -1794
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 30.00 * 30.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -834.2 -834.2
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.30 74.30
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2382 0.2382
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0221 0.0033 0.0139 0.0000 0.0160
43 H2O 0.0005 0.1536 0.0090 0.0378 0.0000 0.0347
44 E-Acetate 0.0023 0.7127 0.2041 0.8569 0.0002 0.8694
45 AceticAcid 0.0004 0.1115 0.0218 0.0914 0.0000 0.0798
46 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0221 0.0033 0.0139 0.0000 0.0160
52 H2O 0.0005 0.1536 0.0090 0.0378 0.0000 0.0347
53 E-Acetate 0.0023 0.7127 0.2041 0.8569 0.0002 0.8694
54 AceticAcid 0.0004 0.1115 0.0218 0.0914 0.0000 0.0798
55 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.77 93.77
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1261 0.1261
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1230 -1230
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0797 0.0134 0.1062 0.0000 0.1331
22 H2O 0.0021 0.5857 0.0385 0.3053 0.0000 0.3052
23 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0245
24 AceticAcid 0.0012 0.3259 0.0714 0.5663 0.0001 0.5372
25 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0797 0.0134 0.1062 0.0000 0.1331
31 H2O 0.0021 0.5857 0.0385 0.3053 0.0000 0.3052
32 E-Acetate 0.0000 0.0087 0.0028 0.0222 0.0000 0.0245
33 AceticAcid 0.0012 0.3259 0.0714 0.5663 0.0001 0.5372
34 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.30 74.30 74.30
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5954 0.0000 0.5954
49 Heat Flow (kJ/h) -3533 0.0000 -3533
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0221 0.0083 0.0139 0.0000 0.0160
58 H2O 0.0012 0.1536 0.0225 0.0378 0.0000 0.0347
59 E-Acetate 0.0058 0.7127 0.5102 0.8569 0.0006 0.8694
60 AceticAcid 0.0009 0.1115 0.0544 0.0914 0.0001 0.0798
61 Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0255 0.0000 0.0164 0.0000 0.0187
67 H2O 0.0000 0.2069 0.0000 0.0519 0.0000 0.0473
68 E-Acetate 0.0000 0.7434 0.0000 0.9116 0.0000 0.9165
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0242 0.0000 0.0202 0.0000 0.0175
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0221 0.0083 0.0139 0.0000 0.0160
22 H2O 0.0012 0.1536 0.0225 0.0378 0.0000 0.0347
23 E-Acetate 0.0058 0.7127 0.5102 0.8569 0.0006 0.8694
24 AceticAcid 0.0009 0.1115 0.0544 0.0914 0.0001 0.0798
25 Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0221 0.0797
59 H2O 0.1536 0.5857
60 E-Acetate 0.7127 0.0087
61 AceticAcid 0.1115 0.3259
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6522 10.7307
20 H2O (%) 172.6515 739.2267
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.2958 30.4986
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.3 100 1.292e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.2 100 1.289e-002 1.227e-002 --- --- ---
32 3__Main TS 82.2 100 1.286e-002 1.224e-002 --- --- ---
33 4__Main TS 82.2 100 1.283e-002 1.221e-002 --- --- ---
34 5__Main TS 82.1 100 1.279e-002 1.218e-002 --- --- ---
35 6__Main TS 82.1 100 1.273e-002 1.214e-002 --- --- ---
36 7__Main TS 82.0 100 1.267e-002 1.208e-002 --- --- ---
37 8__Main TS 81.9 100 1.259e-002 1.202e-002 --- --- ---
38 9__Main TS 81.9 100 1.248e-002 1.194e-002 --- --- ---
39 10__Main TS 81.8 100 1.234e-002 1.183e-002 --- --- ---
40 11__Main TS 81.8 100 1.215e-002 1.169e-002 --- --- ---
41 12__Main TS 81.8 100 1.190e-002 1.150e-002 --- --- ---
42 13__Main TS 82.1 100 1.156e-002 1.125e-002 --- --- ---
43 14__Main TS 82.7 100 1.113e-002 1.091e-002 --- --- ---
44 15__Main TS 83.6 100 1.064e-002 1.048e-002 --- --- ---
45 16__Main TS 84.7 100 1.014e-002 9.985e-003 --- --- ---
46 17__Main TS 85.7 100 1.343e-002 9.485e-003 3.000e-003 --- ---
47 Reboiler 93.8 100 --- 9.784e-003 --- 3.650e-003 371 *
51 Condenser 74.30 -4.348e+005 -3.910e+005 ---
52 1__Main TS 82.27 -4.388e+005 -4.009e+005 ---
53 2__Main TS 82.24 -4.375e+005 -3.995e+005 ---
54 3__Main TS 82.20 -4.361e+005 -3.981e+005 ---
55 4__Main TS 82.16 -4.346e+005 -3.965e+005 ---
56 5__Main TS 82.11 -4.328e+005 -3.948e+005 ---
57 6__Main TS 82.05 -4.308e+005 -3.928e+005 ---
58 7__Main TS 81.99 -4.283e+005 -3.904e+005 ---
59 8__Main TS 81.92 -4.252e+005 -3.876e+005 ---
60 9__Main TS 81.85 -4.212e+005 -3.840e+005 ---
61 10__Main TS 81.79 -4.160e+005 -3.795e+005 ---
62 11__Main TS 81.77 -4.091e+005 -3.735e+005 ---
63 12__Main TS 81.84 -3.997e+005 -3.655e+005 ---
64 13__Main TS 82.10 -3.872e+005 -3.546e+005 ---
65 14__Main TS 82.69 -3.711e+005 -3.399e+005 ---
66 15__Main TS 83.62 -3.525e+005 -3.209e+005 ---
67 16__Main TS 84.72 -3.344e+005 -2.986e+005 ---
68 17__Main TS 85.72 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.77 -3.371e+005 -2.779e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.30*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.77*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 40.00 * 40.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1791 -1791
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 40.00 * 40.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -829.8 -829.8
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.35 74.35
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2382 0.2382
34 Heat Flow (kJ/h) -1414 -1414
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0218 0.0033 0.0137 0.0000 0.0158
43 H2O 0.0005 0.1530 0.0090 0.0376 0.0000 0.0346
44 E-Acetate 0.0023 0.7122 0.2039 0.8561 0.0002 0.8687
45 AceticAcid 0.0004 0.1130 0.0221 0.0926 0.0000 0.0809
46 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0218 0.0033 0.0137 0.0000 0.0158
52 H2O 0.0005 0.1530 0.0090 0.0376 0.0000 0.0346
53 E-Acetate 0.0023 0.7122 0.2039 0.8561 0.0002 0.8687
54 AceticAcid 0.0004 0.1130 0.0221 0.0926 0.0000 0.0809
55 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.71 93.71
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1261 0.1261
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1230 -1230
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0804 0.0135 0.1072 0.0000 0.1343
22 H2O 0.0021 0.5859 0.0385 0.3055 0.0000 0.3053
23 E-Acetate 0.0000 0.0088 0.0028 0.0224 0.0000 0.0247
24 AceticAcid 0.0012 0.3250 0.0712 0.5649 0.0001 0.5357
25 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0804 0.0135 0.1072 0.0000 0.1343
31 H2O 0.0021 0.5859 0.0385 0.3055 0.0000 0.3053
32 E-Acetate 0.0000 0.0088 0.0028 0.0224 0.0000 0.0247
33 AceticAcid 0.0012 0.3250 0.0712 0.5649 0.0001 0.5357
34 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.35 74.35 74.35
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5955 0.0000 0.5955
49 Heat Flow (kJ/h) -3534 0.0000 -3534
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0218 0.0082 0.0137 0.0000 0.0158
58 H2O 0.0012 0.1530 0.0224 0.0376 0.0000 0.0346
59 E-Acetate 0.0058 0.7122 0.5098 0.8561 0.0006 0.8687
60 AceticAcid 0.0009 0.1130 0.0551 0.0926 0.0001 0.0809
61 Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0251 0.0000 0.0161 0.0000 0.0184
67 H2O 0.0000 0.2063 0.0000 0.0517 0.0000 0.0471
68 E-Acetate 0.0000 0.7440 0.0000 0.9117 0.0000 0.9167
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0246 0.0000 0.0205 0.0000 0.0178
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0218 0.0082 0.0137 0.0000 0.0158
22 H2O 0.0012 0.1530 0.0224 0.0376 0.0000 0.0346
23 E-Acetate 0.0058 0.7122 0.5098 0.8561 0.0006 0.8687
24 AceticAcid 0.0009 0.1130 0.0551 0.0926 0.0001 0.0809
25 Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0218 0.0804
59 H2O 0.1530 0.5859
60 E-Acetate 0.7122 0.0088
61 AceticAcid 0.1130 0.3250
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6130 10.8218
20 H2O (%) 171.9539 739.4371
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.4180 30.4126
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.4 100 1.281e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.4 100 1.279e-002 1.216e-002 --- --- ---
32 3__Main TS 82.3 100 1.276e-002 1.214e-002 --- --- ---
33 4__Main TS 82.3 100 1.272e-002 1.211e-002 --- --- ---
34 5__Main TS 82.2 100 1.268e-002 1.207e-002 --- --- ---
35 6__Main TS 82.2 100 1.263e-002 1.203e-002 --- --- ---
36 7__Main TS 82.1 100 1.256e-002 1.198e-002 --- --- ---
37 8__Main TS 82.1 100 1.248e-002 1.191e-002 --- --- ---
38 9__Main TS 82.0 100 1.238e-002 1.183e-002 --- --- ---
39 10__Main TS 81.9 100 1.224e-002 1.173e-002 --- --- ---
40 11__Main TS 81.9 100 1.205e-002 1.159e-002 --- --- ---
41 12__Main TS 82.0 100 1.180e-002 1.140e-002 --- --- ---
42 13__Main TS 82.3 100 1.146e-002 1.115e-002 --- --- ---
43 14__Main TS 82.9 100 1.103e-002 1.081e-002 --- --- ---
44 15__Main TS 83.8 100 1.054e-002 1.038e-002 --- --- ---
45 16__Main TS 84.8 100 1.004e-002 9.890e-003 --- --- ---
46 17__Main TS 85.7 100 1.322e-002 9.390e-003 3.000e-003 --- ---
47 Reboiler 93.7 100 --- 9.567e-003 --- 3.650e-003 363 *
51 Condenser 74.35 -4.350e+005 -3.912e+005 ---
52 1__Main TS 82.38 -4.389e+005 -4.011e+005 ---
53 2__Main TS 82.35 -4.376e+005 -3.996e+005 ---
54 3__Main TS 82.32 -4.362e+005 -3.982e+005 ---
55 4__Main TS 82.27 -4.346e+005 -3.966e+005 ---
56 5__Main TS 82.22 -4.329e+005 -3.948e+005 ---
57 6__Main TS 82.17 -4.308e+005 -3.928e+005 ---
58 7__Main TS 82.11 -4.283e+005 -3.904e+005 ---
59 8__Main TS 82.05 -4.251e+005 -3.876e+005 ---
60 9__Main TS 81.99 -4.211e+005 -3.840e+005 ---
61 10__Main TS 81.95 -4.159e+005 -3.794e+005 ---
62 11__Main TS 81.94 -4.090e+005 -3.734e+005 ---
63 12__Main TS 82.04 -3.996e+005 -3.653e+005 ---
64 13__Main TS 82.32 -3.870e+005 -3.544e+005 ---
65 14__Main TS 82.90 -3.710e+005 -3.397e+005 ---
66 15__Main TS 83.79 -3.526e+005 -3.207e+005 ---
67 16__Main TS 84.80 -3.345e+005 -2.986e+005 ---
68 17__Main TS 85.69 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.71 -3.370e+005 -2.778e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.35*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.71*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 50.00 * 50.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1787 -1787
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 50.00 * 50.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -825.4 -825.4
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.39 74.39
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1414 -1414
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0215 0.0032 0.0135 0.0000 0.0156
43 H2O 0.0005 0.1524 0.0089 0.0375 0.0000 0.0345
44 E-Acetate 0.0023 0.7116 0.2038 0.8552 0.0002 0.8680
45 AceticAcid 0.0004 0.1145 0.0224 0.0938 0.0000 0.0819
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0215 0.0032 0.0135 0.0000 0.0156
52 H2O 0.0005 0.1524 0.0089 0.0375 0.0000 0.0345
53 E-Acetate 0.0023 0.7116 0.2038 0.8552 0.0002 0.8680
54 AceticAcid 0.0004 0.1145 0.0224 0.0938 0.0000 0.0819
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.65 93.65
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1229 -1229
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0811 0.0136 0.1082 0.0000 0.1355
22 H2O 0.0021 0.5860 0.0385 0.3057 0.0000 0.3054
23 E-Acetate 0.0000 0.0089 0.0028 0.0226 0.0000 0.0249
24 AceticAcid 0.0012 0.3240 0.0710 0.5635 0.0001 0.5342
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0811 0.0136 0.1082 0.0000 0.1355
31 H2O 0.0021 0.5860 0.0385 0.3057 0.0000 0.3054
32 E-Acetate 0.0000 0.0089 0.0028 0.0226 0.0000 0.0249
33 AceticAcid 0.0012 0.3240 0.0710 0.5635 0.0001 0.5342
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.39 74.39 74.39
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5956 0.0000 0.5956
49 Heat Flow (kJ/h) -3536 0.0000 -3536
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0215 0.0080 0.0135 0.0000 0.0156
58 H2O 0.0012 0.1524 0.0223 0.0375 0.0000 0.0345
59 E-Acetate 0.0058 0.7116 0.5094 0.8552 0.0006 0.8680
60 AceticAcid 0.0009 0.1145 0.0559 0.0938 0.0001 0.0819
61 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0247 0.0000 0.0158 0.0000 0.0181
67 H2O 0.0000 0.2057 0.0000 0.0515 0.0000 0.0470
68 E-Acetate 0.0000 0.7446 0.0000 0.9118 0.0000 0.9169
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0250 0.0000 0.0208 0.0000 0.0180
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0215 0.0080 0.0135 0.0000 0.0156
22 H2O 0.0012 0.1524 0.0223 0.0375 0.0000 0.0345
23 E-Acetate 0.0058 0.7116 0.5094 0.8552 0.0006 0.8680
24 AceticAcid 0.0009 0.1145 0.0559 0.0938 0.0001 0.0819
25 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0215 0.0811
59 H2O 0.1524 0.5860
60 E-Acetate 0.7116 0.0089
61 AceticAcid 0.1145 0.3240
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.5739 10.9192
20 H2O (%) 171.2618 739.5829
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.5448 30.3263
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.5 100 1.270e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.5 100 1.268e-002 1.205e-002 --- --- ---
32 3__Main TS 82.4 100 1.265e-002 1.203e-002 --- --- ---
33 4__Main TS 82.4 100 1.261e-002 1.200e-002 --- --- ---
34 5__Main TS 82.3 100 1.257e-002 1.196e-002 --- --- ---
35 6__Main TS 82.3 100 1.252e-002 1.192e-002 --- --- ---
36 7__Main TS 82.2 100 1.246e-002 1.187e-002 --- --- ---
37 8__Main TS 82.2 100 1.238e-002 1.181e-002 --- --- ---
38 9__Main TS 82.1 100 1.227e-002 1.173e-002 --- --- ---
39 10__Main TS 82.1 100 1.213e-002 1.162e-002 --- --- ---
40 11__Main TS 82.1 100 1.195e-002 1.148e-002 --- --- ---
41 12__Main TS 82.2 100 1.169e-002 1.130e-002 --- --- ---
42 13__Main TS 82.5 100 1.136e-002 1.104e-002 --- --- ---
43 14__Main TS 83.1 100 1.093e-002 1.071e-002 --- --- ---
44 15__Main TS 84.0 100 1.044e-002 1.028e-002 --- --- ---
45 16__Main TS 84.9 100 9.943e-003 9.794e-003 --- --- ---
46 17__Main TS 85.7 100 1.300e-002 9.293e-003 3.000e-003 --- ---
47 Reboiler 93.7 100 --- 9.347e-003 --- 3.650e-003 355 *
51 Condenser 74.39 -4.352e+005 -3.914e+005 ---
52 1__Main TS 82.49 -4.391e+005 -4.012e+005 ---
53 2__Main TS 82.47 -4.377e+005 -3.998e+005 ---
54 3__Main TS 82.43 -4.363e+005 -3.983e+005 ---
55 4__Main TS 82.39 -4.347e+005 -3.967e+005 ---
56 5__Main TS 82.34 -4.329e+005 -3.949e+005 ---
57 6__Main TS 82.29 -4.308e+005 -3.928e+005 ---
58 7__Main TS 82.24 -4.282e+005 -3.904e+005 ---
59 8__Main TS 82.19 -4.251e+005 -3.875e+005 ---
60 9__Main TS 82.14 -4.211e+005 -3.839e+005 ---
61 10__Main TS 82.11 -4.158e+005 -3.793e+005 ---
62 11__Main TS 82.13 -4.088e+005 -3.733e+005 ---
63 12__Main TS 82.24 -3.994e+005 -3.651e+005 ---
64 13__Main TS 82.55 -3.868e+005 -3.542e+005 ---
65 14__Main TS 83.12 -3.709e+005 -3.394e+005 ---
66 15__Main TS 83.96 -3.527e+005 -3.206e+005 ---
67 16__Main TS 84.88 -3.347e+005 -2.986e+005 ---
68 17__Main TS 85.67 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.65 -3.368e+005 -2.777e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.39*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.65*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 60.00 * 60.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1783 -1783
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 60.00 * 60.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -820.9 -820.9
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.44 74.44
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1415 -1415
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0211 0.0032 0.0133 0.0000 0.0153
43 H2O 0.0005 0.1518 0.0089 0.0373 0.0000 0.0343
44 E-Acetate 0.0023 0.7109 0.2036 0.8543 0.0002 0.8673
45 AceticAcid 0.0004 0.1161 0.0227 0.0951 0.0000 0.0831
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0211 0.0032 0.0133 0.0000 0.0153
52 H2O 0.0005 0.1518 0.0089 0.0373 0.0000 0.0343
53 E-Acetate 0.0023 0.7109 0.2036 0.8543 0.0002 0.8673
54 AceticAcid 0.0004 0.1161 0.0227 0.0951 0.0000 0.0831
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.59 93.59
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1229 -1229
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0819 0.0138 0.1093 0.0000 0.1368
22 H2O 0.0021 0.5861 0.0385 0.3058 0.0000 0.3054
23 E-Acetate 0.0000 0.0090 0.0029 0.0228 0.0000 0.0252
24 AceticAcid 0.0012 0.3231 0.0708 0.5621 0.0001 0.5327
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0819 0.0138 0.1093 0.0000 0.1368
31 H2O 0.0021 0.5861 0.0385 0.3058 0.0000 0.3054
32 E-Acetate 0.0000 0.0090 0.0029 0.0228 0.0000 0.0252
33 AceticAcid 0.0012 0.3231 0.0708 0.5621 0.0001 0.5327
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.44 74.44 74.44
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5957 0.0000 0.5957
49 Heat Flow (kJ/h) -3537 0.0000 -3537
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0211 0.0079 0.0133 0.0000 0.0153
58 H2O 0.0012 0.1518 0.0222 0.0373 0.0000 0.0343
59 E-Acetate 0.0058 0.7109 0.5089 0.8543 0.0006 0.8673
60 AceticAcid 0.0009 0.1161 0.0567 0.0951 0.0001 0.0831
61 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0243 0.0000 0.0156 0.0000 0.0178
67 H2O 0.0000 0.2051 0.0000 0.0513 0.0000 0.0468
68 E-Acetate 0.0000 0.7451 0.0000 0.9119 0.0000 0.9171
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0254 0.0000 0.0212 0.0000 0.0183
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0211 0.0079 0.0133 0.0000 0.0153
22 H2O 0.0012 0.1518 0.0222 0.0373 0.0000 0.0343
23 E-Acetate 0.0058 0.7109 0.5089 0.8543 0.0006 0.8673
24 AceticAcid 0.0009 0.1161 0.0567 0.0951 0.0001 0.0831
25 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0211 0.0819
59 H2O 0.1518 0.5861
60 E-Acetate 0.7109 0.0090
61 AceticAcid 0.1161 0.3231
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.5349 11.0234
20 H2O (%) 170.5793 739.6541
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.6766 30.2399
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.6 100 1.259e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.6 100 1.257e-002 1.194e-002 --- --- ---
32 3__Main TS 82.6 100 1.254e-002 1.192e-002 --- --- ---
33 4__Main TS 82.5 100 1.250e-002 1.189e-002 --- --- ---
34 5__Main TS 82.5 100 1.246e-002 1.185e-002 --- --- ---
35 6__Main TS 82.4 100 1.241e-002 1.181e-002 --- --- ---
36 7__Main TS 82.4 100 1.235e-002 1.176e-002 --- --- ---
37 8__Main TS 82.3 100 1.227e-002 1.170e-002 --- --- ---
38 9__Main TS 82.3 100 1.216e-002 1.162e-002 --- --- ---
39 10__Main TS 82.3 100 1.202e-002 1.151e-002 --- --- ---
40 11__Main TS 82.3 100 1.184e-002 1.137e-002 --- --- ---
41 12__Main TS 82.5 100 1.159e-002 1.119e-002 --- --- ---
42 13__Main TS 82.8 100 1.125e-002 1.094e-002 --- --- ---
43 14__Main TS 83.4 100 1.083e-002 1.060e-002 --- --- ---
44 15__Main TS 84.1 100 1.035e-002 1.018e-002 --- --- ---
45 16__Main TS 85.0 100 9.846e-003 9.696e-003 --- --- ---
46 17__Main TS 85.6 100 1.277e-002 9.196e-003 3.000e-003 --- ---
47 Reboiler 93.6 100 --- 9.124e-003 --- 3.650e-003 346 *
51 Condenser 74.44 -4.353e+005 -3.915e+005 ---
52 1__Main TS 82.61 -4.392e+005 -4.014e+005 ---
53 2__Main TS 82.59 -4.378e+005 -3.999e+005 ---
54 3__Main TS 82.55 -4.363e+005 -3.984e+005 ---
55 4__Main TS 82.51 -4.347e+005 -3.967e+005 ---
56 5__Main TS 82.47 -4.329e+005 -3.949e+005 ---
57 6__Main TS 82.42 -4.308e+005 -3.929e+005 ---
58 7__Main TS 82.38 -4.282e+005 -3.904e+005 ---
59 8__Main TS 82.34 -4.250e+005 -3.875e+005 ---
60 9__Main TS 82.30 -4.209e+005 -3.838e+005 ---
61 10__Main TS 82.29 -4.156e+005 -3.792e+005 ---
62 11__Main TS 82.33 -4.086e+005 -3.731e+005 ---
63 12__Main TS 82.47 -3.991e+005 -3.649e+005 ---
64 13__Main TS 82.79 -3.866e+005 -3.539e+005 ---
65 14__Main TS 83.36 -3.709e+005 -3.392e+005 ---
66 15__Main TS 84.14 -3.528e+005 -3.205e+005 ---
67 16__Main TS 84.96 -3.348e+005 -2.986e+005 ---
68 17__Main TS 85.64 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.59 -3.367e+005 -2.776e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.44*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.59*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 70.00 * 70.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1780 -1780
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 70.00 * 70.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -816.3 -816.3
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.49 74.49
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1415 -1415
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0208 0.0031 0.0131 0.0000 0.0151
43 H2O 0.0005 0.1512 0.0089 0.0371 0.0000 0.0342
44 E-Acetate 0.0023 0.7102 0.2034 0.8533 0.0002 0.8664
45 AceticAcid 0.0004 0.1178 0.0230 0.0964 0.0000 0.0843
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0208 0.0031 0.0131 0.0000 0.0151
52 H2O 0.0005 0.1512 0.0089 0.0371 0.0000 0.0342
53 E-Acetate 0.0023 0.7102 0.2034 0.8533 0.0002 0.8664
54 AceticAcid 0.0004 0.1178 0.0230 0.0964 0.0000 0.0843
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.53 93.53
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0827 0.0139 0.1104 0.0000 0.1381
22 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3053
23 E-Acetate 0.0000 0.0091 0.0029 0.0231 0.0000 0.0255
24 AceticAcid 0.0012 0.3222 0.0706 0.5606 0.0001 0.5311
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0827 0.0139 0.1104 0.0000 0.1381
31 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3053
32 E-Acetate 0.0000 0.0091 0.0029 0.0231 0.0000 0.0255
33 AceticAcid 0.0012 0.3222 0.0706 0.5606 0.0001 0.5311
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.49 74.49 74.49
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5958 0.0000 0.5958
49 Heat Flow (kJ/h) -3538 0.0000 -3538
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0208 0.0078 0.0131 0.0000 0.0151
58 H2O 0.0012 0.1512 0.0221 0.0371 0.0000 0.0342
59 E-Acetate 0.0058 0.7102 0.5084 0.8533 0.0006 0.8664
60 AceticAcid 0.0010 0.1178 0.0575 0.0964 0.0001 0.0843
61 Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0240 0.0000 0.0153 0.0000 0.0175
67 H2O 0.0000 0.2046 0.0000 0.0512 0.0000 0.0466
68 E-Acetate 0.0000 0.7457 0.0000 0.9120 0.0000 0.9172
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0258 0.0000 0.0215 0.0000 0.0186
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0208 0.0078 0.0131 0.0000 0.0151
22 H2O 0.0012 0.1512 0.0221 0.0371 0.0000 0.0342
23 E-Acetate 0.0058 0.7102 0.5084 0.8533 0.0006 0.8664
24 AceticAcid 0.0010 0.1178 0.0575 0.0964 0.0001 0.0843
25 Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0208 0.0827
59 H2O 0.1512 0.5860
60 E-Acetate 0.7102 0.0091
61 AceticAcid 0.1178 0.3222
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4961 11.1352
20 H2O (%) 169.9106 739.6394
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.8135 30.1536
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.7 100 1.248e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.7 100 1.246e-002 1.183e-002 --- --- ---
32 3__Main TS 82.7 100 1.243e-002 1.181e-002 --- --- ---
33 4__Main TS 82.6 100 1.239e-002 1.178e-002 --- --- ---
34 5__Main TS 82.6 100 1.235e-002 1.174e-002 --- --- ---
35 6__Main TS 82.6 100 1.230e-002 1.170e-002 --- --- ---
36 7__Main TS 82.5 100 1.223e-002 1.165e-002 --- --- ---
37 8__Main TS 82.5 100 1.216e-002 1.158e-002 --- --- ---
38 9__Main TS 82.5 100 1.205e-002 1.151e-002 --- --- ---
39 10__Main TS 82.5 100 1.192e-002 1.140e-002 --- --- ---
40 11__Main TS 82.5 100 1.173e-002 1.127e-002 --- --- ---
41 12__Main TS 82.7 100 1.148e-002 1.108e-002 --- --- ---
42 13__Main TS 83.0 100 1.115e-002 1.083e-002 --- --- ---
43 14__Main TS 83.6 100 1.073e-002 1.050e-002 --- --- ---
44 15__Main TS 84.3 100 1.025e-002 1.008e-002 --- --- ---
45 16__Main TS 85.0 100 9.747e-003 9.598e-003 --- --- ---
46 17__Main TS 85.6 100 1.255e-002 9.097e-003 3.000e-003 --- ---
47 Reboiler 93.5 100 --- 8.899e-003 --- 3.650e-003 338 *
51 Condenser 74.49 -4.355e+005 -3.917e+005 ---
52 1__Main TS 82.74 -4.393e+005 -4.016e+005 ---
53 2__Main TS 82.71 -4.379e+005 -4.000e+005 ---
54 3__Main TS 82.67 -4.364e+005 -3.985e+005 ---
55 4__Main TS 82.64 -4.348e+005 -3.968e+005 ---
56 5__Main TS 82.60 -4.329e+005 -3.950e+005 ---
57 6__Main TS 82.56 -4.307e+005 -3.928e+005 ---
58 7__Main TS 82.52 -4.281e+005 -3.904e+005 ---
59 8__Main TS 82.49 -4.249e+005 -3.874e+005 ---
60 9__Main TS 82.47 -4.208e+005 -3.837e+005 ---
61 10__Main TS 82.47 -4.155e+005 -3.790e+005 ---
62 11__Main TS 82.54 -4.084e+005 -3.729e+005 ---
63 12__Main TS 82.71 -3.989e+005 -3.646e+005 ---
64 13__Main TS 83.05 -3.864e+005 -3.536e+005 ---
65 14__Main TS 83.60 -3.708e+005 -3.389e+005 ---
66 15__Main TS 84.32 -3.529e+005 -3.203e+005 ---
67 16__Main TS 85.04 -3.350e+005 -2.986e+005 ---
68 17__Main TS 85.60 -3.216e+005 -2.764e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.53 -3.365e+005 -2.774e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.49*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.4e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.53*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 80.00 * 80.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1776 -1776
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 80.00 * 80.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -811.7 -811.7
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.54 74.54
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0205 0.0031 0.0129 0.0000 0.0149
43 H2O 0.0005 0.1506 0.0088 0.0370 0.0000 0.0341
44 E-Acetate 0.0023 0.7094 0.2031 0.8523 0.0002 0.8656
45 AceticAcid 0.0004 0.1195 0.0233 0.0978 0.0000 0.0855
46 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0205 0.0031 0.0129 0.0000 0.0149
52 H2O 0.0005 0.1506 0.0088 0.0370 0.0000 0.0341
53 E-Acetate 0.0023 0.7094 0.2031 0.8523 0.0002 0.8656
54 AceticAcid 0.0004 0.1195 0.0233 0.0978 0.0000 0.0855
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.46 93.46
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0836 0.0141 0.1116 0.0000 0.1396
22 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3052
23 E-Acetate 0.0000 0.0092 0.0029 0.0234 0.0000 0.0258
24 AceticAcid 0.0012 0.3213 0.0704 0.5591 0.0001 0.5294
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0836 0.0141 0.1116 0.0000 0.1396
31 H2O 0.0021 0.5860 0.0385 0.3059 0.0000 0.3052
32 E-Acetate 0.0000 0.0092 0.0029 0.0234 0.0000 0.0258
33 AceticAcid 0.0012 0.3213 0.0704 0.5591 0.0001 0.5294
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.54 74.54 74.54
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5959 0.0000 0.5959
49 Heat Flow (kJ/h) -3539 0.0000 -3539
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0205 0.0077 0.0129 0.0000 0.0149
58 H2O 0.0012 0.1506 0.0220 0.0370 0.0000 0.0341
59 E-Acetate 0.0058 0.7094 0.5078 0.8523 0.0006 0.8656
60 AceticAcid 0.0010 0.1195 0.0583 0.0978 0.0001 0.0855
61 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0236 0.0000 0.0151 0.0000 0.0172
67 H2O 0.0000 0.2040 0.0000 0.0510 0.0000 0.0465
68 E-Acetate 0.0000 0.7462 0.0000 0.9121 0.0000 0.9174
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0262 0.0000 0.0219 0.0000 0.0189
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0205 0.0077 0.0129 0.0000 0.0149
22 H2O 0.0012 0.1506 0.0220 0.0370 0.0000 0.0341
23 E-Acetate 0.0058 0.7094 0.5078 0.8523 0.0006 0.8656
24 AceticAcid 0.0010 0.1195 0.0583 0.0978 0.0001 0.0855
25 Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0205 0.0836
59 H2O 0.1506 0.5860
60 E-Acetate 0.7094 0.0092
61 AceticAcid 0.1195 0.3213
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4575 11.2552
20 H2O (%) 169.2612 739.5253
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.9558 30.0679
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 82.9 100 1.237e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.8 100 1.234e-002 1.172e-002 --- --- ---
32 3__Main TS 82.8 100 1.231e-002 1.169e-002 --- --- ---
33 4__Main TS 82.8 100 1.228e-002 1.166e-002 --- --- ---
34 5__Main TS 82.7 100 1.223e-002 1.163e-002 --- --- ---
35 6__Main TS 82.7 100 1.218e-002 1.158e-002 --- --- ---
36 7__Main TS 82.7 100 1.212e-002 1.153e-002 --- --- ---
37 8__Main TS 82.6 100 1.204e-002 1.147e-002 --- --- ---
38 9__Main TS 82.6 100 1.194e-002 1.139e-002 --- --- ---
39 10__Main TS 82.7 100 1.180e-002 1.129e-002 --- --- ---
40 11__Main TS 82.8 100 1.162e-002 1.115e-002 --- --- ---
41 12__Main TS 83.0 100 1.137e-002 1.097e-002 --- --- ---
42 13__Main TS 83.3 100 1.105e-002 1.072e-002 --- --- ---
43 14__Main TS 83.9 100 1.063e-002 1.040e-002 --- --- ---
44 15__Main TS 84.5 100 1.015e-002 9.982e-003 --- --- ---
45 16__Main TS 85.1 100 9.647e-003 9.498e-003 --- --- ---
46 17__Main TS 85.6 100 1.232e-002 8.997e-003 3.000e-003 --- ---
47 Reboiler 93.5 100 --- 8.671e-003 --- 3.650e-003 329 *
51 Condenser 74.54 -4.356e+005 -3.919e+005 ---
52 1__Main TS 82.86 -4.394e+005 -4.017e+005 ---
53 2__Main TS 82.84 -4.380e+005 -4.002e+005 ---
54 3__Main TS 82.80 -4.364e+005 -3.986e+005 ---
55 4__Main TS 82.77 -4.348e+005 -3.968e+005 ---
56 5__Main TS 82.73 -4.329e+005 -3.950e+005 ---
57 6__Main TS 82.70 -4.307e+005 -3.928e+005 ---
58 7__Main TS 82.67 -4.280e+005 -3.903e+005 ---
59 8__Main TS 82.65 -4.248e+005 -3.873e+005 ---
60 9__Main TS 82.64 -4.206e+005 -3.836e+005 ---
61 10__Main TS 82.67 -4.152e+005 -3.788e+005 ---
62 11__Main TS 82.77 -4.081e+005 -3.726e+005 ---
63 12__Main TS 82.97 -3.986e+005 -3.643e+005 ---
64 13__Main TS 83.32 -3.862e+005 -3.533e+005 ---
65 14__Main TS 83.86 -3.708e+005 -3.387e+005 ---
66 15__Main TS 84.51 -3.530e+005 -3.202e+005 ---
67 16__Main TS 85.12 -3.351e+005 -2.987e+005 ---
68 17__Main TS 85.57 -3.216e+005 -2.765e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.46 -3.364e+005 -2.773e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.54*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.3e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.46*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 90.00 * 90.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1772 -1772
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 90.00 * 90.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -693.6 -693.6
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.59 74.59
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0202 0.0030 0.0127 0.0000 0.0147
43 H2O 0.0005 0.1504 0.0088 0.0370 0.0000 0.0340
44 E-Acetate 0.0023 0.7081 0.2028 0.8510 0.0002 0.8645
45 AceticAcid 0.0004 0.1212 0.0237 0.0993 0.0000 0.0868
46 Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0202 0.0030 0.0127 0.0000 0.0147
52 H2O 0.0005 0.1504 0.0088 0.0370 0.0000 0.0340
53 E-Acetate 0.0023 0.7081 0.2028 0.8510 0.0002 0.8645
54 AceticAcid 0.0004 0.1212 0.0237 0.0993 0.0000 0.0868
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.34 93.34
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0843 0.0142 0.1125 0.0000 0.1407
22 H2O 0.0021 0.5856 0.0385 0.3055 0.0000 0.3047
23 E-Acetate 0.0000 0.0098 0.0032 0.0250 0.0000 0.0275
24 AceticAcid 0.0012 0.3202 0.0702 0.5569 0.0001 0.5271
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0843 0.0142 0.1125 0.0000 0.1407
31 H2O 0.0021 0.5856 0.0385 0.3055 0.0000 0.3047
32 E-Acetate 0.0000 0.0098 0.0032 0.0250 0.0000 0.0275
33 AceticAcid 0.0012 0.3202 0.0702 0.5569 0.0001 0.5271
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.59 74.59 74.59
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5957 0.0000 0.5957
49 Heat Flow (kJ/h) -3540 0.0000 -3540
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0202 0.0076 0.0127 0.0000 0.0147
58 H2O 0.0012 0.1504 0.0220 0.0370 0.0000 0.0340
59 E-Acetate 0.0058 0.7081 0.5069 0.8510 0.0006 0.8645
60 AceticAcid 0.0010 0.1212 0.0591 0.0993 0.0001 0.0868
61 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0233 0.0000 0.0149 0.0000 0.0170
67 H2O 0.0000 0.2036 0.0000 0.0509 0.0000 0.0464
68 E-Acetate 0.0000 0.7464 0.0000 0.9120 0.0000 0.9174
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0267 0.0000 0.0222 0.0000 0.0192
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0202 0.0076 0.0127 0.0000 0.0147
22 H2O 0.0012 0.1504 0.0220 0.0370 0.0000 0.0340
23 E-Acetate 0.0058 0.7081 0.5069 0.8510 0.0006 0.8645
24 AceticAcid 0.0010 0.1212 0.0591 0.0993 0.0001 0.0868
25 Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0202 0.0843
59 H2O 0.1504 0.5856
60 E-Acetate 0.7081 0.0098
61 AceticAcid 0.1212 0.3202
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4274 11.3531
20 H2O (%) 169.0464 739.1045
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 10.0996 29.9712
23
COLUMN PROFILES
24
29 Condenser 74.6 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 83.0 100 1.226e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 83.0 100 1.223e-002 1.161e-002 --- --- ---
32 3__Main TS 82.9 100 1.220e-002 1.158e-002 --- --- ---
33 4__Main TS 82.9 100 1.216e-002 1.155e-002 --- --- ---
34 5__Main TS 82.9 100 1.212e-002 1.151e-002 --- --- ---
35 6__Main TS 82.9 100 1.206e-002 1.147e-002 --- --- ---
36 7__Main TS 82.9 100 1.200e-002 1.141e-002 --- --- ---
37 8__Main TS 82.9 100 1.192e-002 1.135e-002 --- --- ---
38 9__Main TS 82.9 100 1.182e-002 1.127e-002 --- --- ---
39 10__Main TS 83.1 100 1.168e-002 1.117e-002 --- --- ---
40 11__Main TS 83.3 100 1.150e-002 1.103e-002 --- --- ---
41 12__Main TS 83.7 100 1.126e-002 1.085e-002 --- --- ---
42 13__Main TS 84.3 100 1.094e-002 1.061e-002 --- --- ---
43 14__Main TS 85.0 100 1.053e-002 1.029e-002 --- --- ---
44 15__Main TS 85.7 100 1.007e-002 9.883e-003 --- --- ---
45 16__Main TS 86.1 100 9.581e-003 9.416e-003 --- --- ---
46 17__Main TS 86.4 100 9.106e-003 8.931e-003 3.000e-003 --- ---
47 Reboiler 93.3 100 --- 5.456e-003 --- 3.650e-003 207 *
51 Condenser 74.59 -4.356e+005 -3.920e+005 ---
52 1__Main TS 82.99 -4.394e+005 -4.018e+005 ---
53 2__Main TS 82.97 -4.379e+005 -4.002e+005 ---
54 3__Main TS 82.94 -4.363e+005 -3.985e+005 ---
55 4__Main TS 82.90 -4.346e+005 -3.967e+005 ---
56 5__Main TS 82.88 -4.326e+005 -3.947e+005 ---
57 6__Main TS 82.86 -4.303e+005 -3.925e+005 ---
58 7__Main TS 82.85 -4.275e+005 -3.899e+005 ---
59 8__Main TS 82.87 -4.241e+005 -3.867e+005 ---
60 9__Main TS 82.93 -4.197e+005 -3.828e+005 ---
61 10__Main TS 83.06 -4.140e+005 -3.777e+005 ---
62 11__Main TS 83.31 -4.065e+005 -3.712e+005 ---
63 12__Main TS 83.72 -3.966e+005 -3.625e+005 ---
64 13__Main TS 84.30 -3.842e+005 -3.511e+005 ---
65 14__Main TS 85.00 -3.691e+005 -3.364e+005 ---
66 15__Main TS 85.66 -3.524e+005 -3.184e+005 ---
67 16__Main TS 86.12 -3.359e+005 -2.980e+005 ---
68 17__Main TS 86.40 -3.239e+005 -2.773e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.34 -3.363e+005 -2.776e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.59*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS F1 Feed --- Vapour 3.00e-003 * -2.3e+005 * 90.00*
38 Q_R Energy 2.1e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.34*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 100.0 * 100.0
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1768 -1768
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 100.0 * 100.0
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -691.4 -691.4
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.64 74.64
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2382 0.2382
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0199 0.0030 0.0125 0.0000 0.0145
43 H2O 0.0005 0.1500 0.0088 0.0369 0.0000 0.0340
44 E-Acetate 0.0023 0.7070 0.2025 0.8498 0.0002 0.8634
45 AceticAcid 0.0004 0.1230 0.0240 0.1008 0.0000 0.0881
46 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0199 0.0030 0.0125 0.0000 0.0145
52 H2O 0.0005 0.1500 0.0088 0.0369 0.0000 0.0340
53 E-Acetate 0.0023 0.7070 0.2025 0.8498 0.0002 0.8634
54 AceticAcid 0.0004 0.1230 0.0240 0.1008 0.0000 0.0881
55 Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.25 93.25
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1261 0.1261
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1227 -1227
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0854 0.0144 0.1139 0.0000 0.1423
22 H2O 0.0021 0.5852 0.0385 0.3053 0.0000 0.3043
23 E-Acetate 0.0000 0.0100 0.0032 0.0255 0.0000 0.0280
24 AceticAcid 0.0012 0.3194 0.0700 0.5554 0.0001 0.5254
25 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0854 0.0144 0.1139 0.0000 0.1423
31 H2O 0.0021 0.5852 0.0385 0.3053 0.0000 0.3043
32 E-Acetate 0.0000 0.0100 0.0032 0.0255 0.0000 0.0280
33 AceticAcid 0.0012 0.3194 0.0700 0.5554 0.0001 0.5254
34 Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.64 74.64 74.64
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5956 0.0000 0.5956
49 Heat Flow (kJ/h) -3541 0.0000 -3541
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0199 0.0075 0.0125 0.0000 0.0145
58 H2O 0.0012 0.1500 0.0220 0.0369 0.0000 0.0340
59 E-Acetate 0.0057 0.7070 0.5061 0.8498 0.0006 0.8634
60 AceticAcid 0.0010 0.1230 0.0600 0.1008 0.0001 0.0881
61 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0229 0.0000 0.0146 0.0000 0.0167
67 H2O 0.0000 0.2031 0.0000 0.0507 0.0000 0.0463
68 E-Acetate 0.0000 0.7468 0.0000 0.9121 0.0000 0.9175
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0271 0.0000 0.0226 0.0000 0.0196
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0199 0.0075 0.0125 0.0000 0.0145
22 H2O 0.0012 0.1500 0.0220 0.0369 0.0000 0.0340
23 E-Acetate 0.0057 0.7070 0.5061 0.8498 0.0006 0.8634
24 AceticAcid 0.0010 0.1230 0.0600 0.1008 0.0001 0.0881
25 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0199 0.0854
59 H2O 0.1500 0.5852
60 E-Acetate 0.7070 0.0100
61 AceticAcid 0.1230 0.3194
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.3912 11.4973
20 H2O (%) 168.5498 738.5893
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 10.2529 29.8929
23
COLUMN PROFILES
24
29 Condenser 74.6 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 83.1 100 1.214e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 83.1 100 1.211e-002 1.149e-002 --- --- ---
32 3__Main TS 83.1 100 1.208e-002 1.146e-002 --- --- ---
33 4__Main TS 83.0 100 1.204e-002 1.143e-002 --- --- ---
34 5__Main TS 83.0 100 1.200e-002 1.139e-002 --- --- ---
35 6__Main TS 83.0 100 1.195e-002 1.135e-002 --- --- ---
36 7__Main TS 83.0 100 1.188e-002 1.130e-002 --- --- ---
37 8__Main TS 83.1 100 1.180e-002 1.123e-002 --- --- ---
38 9__Main TS 83.2 100 1.170e-002 1.115e-002 --- --- ---
39 10__Main TS 83.3 100 1.157e-002 1.105e-002 --- --- ---
40 11__Main TS 83.6 100 1.139e-002 1.092e-002 --- --- ---
41 12__Main TS 84.1 100 1.115e-002 1.074e-002 --- --- ---
42 13__Main TS 84.7 100 1.083e-002 1.050e-002 --- --- ---
43 14__Main TS 85.3 100 1.043e-002 1.018e-002 --- --- ---
44 15__Main TS 85.9 100 9.965e-003 9.781e-003 --- --- ---
45 16__Main TS 86.2 100 9.480e-003 9.315e-003 --- --- ---
46 17__Main TS 86.4 100 8.941e-003 8.830e-003 3.000e-003 --- ---
47 Reboiler 93.3 100 --- 5.291e-003 --- 3.650e-003 201 *
51 Condenser 74.64 -4.358e+005 -3.922e+005 ---
52 1__Main TS 83.13 -4.395e+005 -4.019e+005 ---
53 2__Main TS 83.10 -4.380e+005 -4.002e+005 ---
54 3__Main TS 83.07 -4.363e+005 -3.985e+005 ---
55 4__Main TS 83.05 -4.345e+005 -3.967e+005 ---
56 5__Main TS 83.02 -4.325e+005 -3.946e+005 ---
57 6__Main TS 83.01 -4.302e+005 -3.923e+005 ---
58 7__Main TS 83.02 -4.273e+005 -3.897e+005 ---
59 8__Main TS 83.06 -4.238e+005 -3.864e+005 ---
60 9__Main TS 83.16 -4.193e+005 -3.824e+005 ---
61 10__Main TS 83.33 -4.135e+005 -3.773e+005 ---
62 11__Main TS 83.63 -4.059e+005 -3.706e+005 ---
63 12__Main TS 84.08 -3.961e+005 -3.619e+005 ---
64 13__Main TS 84.68 -3.838e+005 -3.505e+005 ---
65 14__Main TS 85.34 -3.690e+005 -3.359e+005 ---
66 15__Main TS 85.90 -3.526e+005 -3.182e+005 ---
67 16__Main TS 86.22 -3.361e+005 -2.981e+005 ---
68 17__Main TS 86.37 -3.240e+005 -2.774e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.25 -3.362e+005 -2.775e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.64*
21 1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.5e+005 * *
100.00
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS F1 Feed --- Vapour 3.00e-003 * -2.3e+005 * *
100.00
38 Q_R Energy 2.0e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.25*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
65.0
40 910
1.00e-002
41
Density (kg/m3)
60.0
42 900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46
880
47 45.0
48 4.00e-003
870
49 40.0
50 2.00e-003 860 35.0
51
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B4:
EFFECT OF NUMBER
OF STAGES
1
Case Name: N_STAGES = 15.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.20 74.20
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2369 0.2369
34 Heat Flow (kJ/h) -1409 -1409
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0239 0.0036 0.0151 0.0000 0.0174
43 H2O 0.0005 0.1588 0.0093 0.0392 0.0000 0.0361
44 E-Acetate 0.0023 0.7080 0.2027 0.8556 0.0002 0.8679
45 AceticAcid 0.0004 0.1093 0.0213 0.0900 0.0000 0.0786
46 Total 0.0032 1.0000 0.2369 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0239 0.0036 0.0151 0.0000 0.0174
52 H2O 0.0005 0.1588 0.0093 0.0392 0.0000 0.0361
53 E-Acetate 0.0023 0.7080 0.2027 0.8556 0.0002 0.8679
54 AceticAcid 0.0004 0.1093 0.0213 0.0900 0.0000 0.0786
55 Total 0.0032 1.0000 0.2369 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.72 93.72
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1274 0.1274
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1234 -1234
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0816 0.0137 0.1078 0.0000 0.1350
22 H2O 0.0021 0.5776 0.0380 0.2982 0.0000 0.2980
23 E-Acetate 0.0000 0.0094 0.0030 0.0236 0.0000 0.0260
24 AceticAcid 0.0012 0.3314 0.0726 0.5704 0.0001 0.5409
25 Total 0.0036 1.0000 0.1274 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0816 0.0137 0.1078 0.0000 0.1350
31 H2O 0.0021 0.5776 0.0380 0.2982 0.0000 0.2980
32 E-Acetate 0.0000 0.0094 0.0030 0.0236 0.0000 0.0260
33 AceticAcid 0.0012 0.3314 0.0726 0.5704 0.0001 0.5409
34 Total 0.0036 1.0000 0.1274 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.20 74.20 74.20
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5924 0.0000 0.5924
49 Heat Flow (kJ/h) -3523 0.0000 -3523
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0239 0.0089 0.0151 0.0000 0.0174
58 H2O 0.0013 0.1588 0.0232 0.0392 0.0000 0.0361
59 E-Acetate 0.0058 0.7080 0.5068 0.8556 0.0006 0.8679
60 AceticAcid 0.0009 0.1093 0.0533 0.0900 0.0001 0.0786
61 Total 0.0081 1.0000 0.5924 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0275 0.0000 0.0177 0.0000 0.0202
67 H2O 0.0000 0.2101 0.0000 0.0529 0.0000 0.0482
68 E-Acetate 0.0000 0.7390 0.0000 0.9098 0.0000 0.9146
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0234 0.0000 0.0196 0.0000 0.0170
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0239 0.0089 0.0151 0.0000 0.0174
22 H2O 0.0013 0.1588 0.0232 0.0392 0.0000 0.0361
23 E-Acetate 0.0058 0.7080 0.5068 0.8556 0.0006 0.8679
24 AceticAcid 0.0009 0.1093 0.0533 0.0900 0.0001 0.0786
25 Total 0.0081 1.0000 0.5924 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 15__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0239 0.0816
59 H2O 0.1588 0.5776
60 E-Acetate 0.7080 0.0094
61 AceticAcid 0.1093 0.3314
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.8627 10.9923
20 H2O (%) 178.4652 728.9877
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.1080 31.0146
23
COLUMN PROFILES
24
29 Condenser 74.2 100 8.125e-003 --- --- 3.250e-003 387 *
30 1__Main TS 82.1 100 1.301e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.298e-002 1.236e-002 --- --- ---
32 3__Main TS 82.0 100 1.293e-002 1.233e-002 --- --- ---
33 4__Main TS 81.9 100 1.288e-002 1.228e-002 --- --- ---
34 5__Main TS 81.9 100 1.282e-002 1.223e-002 --- --- ---
35 6__Main TS 81.8 100 1.273e-002 1.217e-002 --- --- ---
36 7__Main TS 81.7 100 1.263e-002 1.208e-002 --- --- ---
37 8__Main TS 81.6 100 1.249e-002 1.198e-002 --- --- ---
38 9__Main TS 81.5 100 1.230e-002 1.184e-002 --- --- ---
39 10__Main TS 81.5 100 1.204e-002 1.165e-002 --- --- ---
40 11__Main TS 81.7 100 1.171e-002 1.139e-002 --- --- ---
41 12__Main TS 82.2 100 1.128e-002 1.106e-002 --- --- ---
42 13__Main TS 83.2 100 1.078e-002 1.063e-002 --- --- ---
43 14__Main TS 84.4 100 1.027e-002 1.013e-002 --- --- ---
44 15__Main TS 85.6 100 1.368e-002 9.618e-003 3.000e-003 --- ---
45 Reboiler 93.7 100 --- 1.003e-002 --- 3.650e-003 380 *
49 Condenser 74.20 -4.336e+005 -3.900e+005 ---
50 1__Main TS 82.11 -4.376e+005 -3.995e+005 ---
51 2__Main TS 82.06 -4.359e+005 -3.978e+005 ---
52 3__Main TS 82.01 -4.340e+005 -3.959e+005 ---
53 4__Main TS 81.95 -4.319e+005 -3.938e+005 ---
54 5__Main TS 81.87 -4.294e+005 -3.914e+005 ---
55 6__Main TS 81.79 -4.263e+005 -3.886e+005 ---
56 7__Main TS 81.70 -4.224e+005 -3.850e+005 ---
57 8__Main TS 81.61 -4.173e+005 -3.805e+005 ---
58 9__Main TS 81.54 -4.105e+005 -3.747e+005 ---
59 10__Main TS 81.55 -4.014e+005 -3.668e+005 ---
60 11__Main TS 81.73 -3.890e+005 -3.562e+005 ---
61 12__Main TS 82.24 -3.729e+005 -3.417e+005 ---
62 13__Main TS 83.16 -3.540e+005 -3.227e+005 ---
63 14__Main TS 84.37 -3.354e+005 -3.001e+005 ---
64 15__Main TS 85.56 -3.223e+005 -2.774e+005 ---
65 Reboiler 93.72 -3.382e+005 -2.786e+005 ---
66
FEEDS / PRODUCTS
67
1
2 LEGENDS
4 USA
5
6
8
9
FEEDS / PRODUCTS
10
13 Q_C Energy 3.9e+002 * --- --- ---
Condenser
14 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.20*
16 2__Main TS
17 3__Main TS
18 4__Main TS
19 5__Main TS
20 6__Main TS
21 7__Main TS
22 8__Main TS
23 9__Main TS
24 10__Main TS
25 11__Main TS
26 12__Main TS
27 13__Main TS
28 14__Main TS
30 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
31 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.72*
32
SETUP
33
34 Sub-Flowsheet
37 F0 F0 P-H Flash
38 F1 F1 P-H Flash
41 F2 F2 P-H Flash
42 F3 F3 P-H Flash
43
44
45

46
48 94.0 105
49
92.0 104
50
51 90.0 103
52
53 88.0 102
Temperature (C)
Pressure (kPa)
54
86.0 101
55
56 84.0 100
57
58 82.0 99.0
59
80.0 98.0
60
61 78.0 97.0
62
63 76.0 96.0
64
74.0 95.0
65
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 from Top
13 1.40e-002 930 75.0
14
15 1.20e-002
16
65.0
17 910
1.00e-002
18
Density (kg/m3)
60.0
19 900
20 8.00e-003 55.0
21 890
22 50.0
6.00e-003
23
880
24 45.0
25 4.00e-003
870
26 40.0
27 2.00e-003 860 35.0
28
29
0.000 850 30.0
30 0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
31
32
33

34
35 K-Value
36 0.800 5.00
37
38 0.700
39 4.00
40 0.600
41 3.50
Mole Fraction
42 0.500
3.00
K Value
43
44 0.400 2.50
45
46 2.00
0.300
47
1.50
48
0.200
49 1.00
50
1.00e-001
51 0.500
52
0.000 0.000
53
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.33 74.33
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2393 0.2393
34 Heat Flow (kJ/h) -1416 -1416
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0212 0.0032 0.0133 0.0000 0.0153
43 H2O 0.0005 0.1495 0.0088 0.0366 0.0000 0.0336
44 E-Acetate 0.0023 0.7184 0.2057 0.8597 0.0002 0.8721
45 AceticAcid 0.0004 0.1110 0.0217 0.0905 0.0000 0.0790
46 Total 0.0032 1.0000 0.2393 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0212 0.0032 0.0133 0.0000 0.0153
52 H2O 0.0005 0.1495 0.0088 0.0366 0.0000 0.0336
53 E-Acetate 0.0023 0.7184 0.2057 0.8597 0.0002 0.8721
54 AceticAcid 0.0004 0.1110 0.0217 0.0905 0.0000 0.0790
55 Total 0.0032 1.0000 0.2393 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.95 93.95
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1250 0.1250
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1228 -1228
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0763 0.0128 0.1026 0.0000 0.1287
22 H2O 0.0022 0.5937 0.0390 0.3123 0.0000 0.3124
23 E-Acetate 0.0000 0.0079 0.0025 0.0203 0.0000 0.0225
24 AceticAcid 0.0012 0.3221 0.0706 0.5648 0.0001 0.5364
25 Total 0.0036 1.0000 0.1250 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0763 0.0128 0.1026 0.0000 0.1287
31 H2O 0.0022 0.5937 0.0390 0.3123 0.0000 0.3124
32 E-Acetate 0.0000 0.0079 0.0025 0.0203 0.0000 0.0225
33 AceticAcid 0.0012 0.3221 0.0706 0.5648 0.0001 0.5364
34 Total 0.0036 1.0000 0.1250 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.33 74.33 74.33
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5982 0.0000 0.5982
49 Heat Flow (kJ/h) -3541 0.0000 -3541
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0212 0.0079 0.0133 0.0000 0.0153
58 H2O 0.0012 0.1495 0.0219 0.0366 0.0000 0.0336
59 E-Acetate 0.0058 0.7184 0.5143 0.8597 0.0006 0.8721
60 AceticAcid 0.0009 0.1110 0.0541 0.0905 0.0001 0.0790
61 Total 0.0081 1.0000 0.5982 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0245 0.0000 0.0157 0.0000 0.0179
67 H2O 0.0000 0.2045 0.0000 0.0511 0.0000 0.0466
68 E-Acetate 0.0000 0.7467 0.0000 0.9130 0.0000 0.9180
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0243 0.0000 0.0202 0.0000 0.0175
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0212 0.0079 0.0133 0.0000 0.0153
22 H2O 0.0012 0.1495 0.0219 0.0366 0.0000 0.0336
23 E-Acetate 0.0058 0.7184 0.5143 0.8597 0.0006 0.8721
24 AceticAcid 0.0009 0.1110 0.0541 0.0905 0.0001 0.0790
25 Total 0.0081 1.0000 0.5982 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 20__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0212 0.0763
59 H2O 0.1495 0.5937
60 E-Acetate 0.7184 0.0079
61 AceticAcid 0.1110 0.3221
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.5397 10.2708
20 H2O (%) 167.9807 749.2626
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.2484 30.1482
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.2 100 1.303e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.2 100 1.302e-002 1.238e-002 --- --- ---
32 3__Main TS 82.2 100 1.300e-002 1.237e-002 --- --- ---
33 4__Main TS 82.1 100 1.298e-002 1.235e-002 --- --- ---
34 5__Main TS 82.1 100 1.295e-002 1.233e-002 --- --- ---
35 6__Main TS 82.1 100 1.292e-002 1.230e-002 --- --- ---
36 7__Main TS 82.0 100 1.289e-002 1.227e-002 --- --- ---
37 8__Main TS 82.0 100 1.285e-002 1.224e-002 --- --- ---
38 9__Main TS 81.9 100 1.280e-002 1.220e-002 --- --- ---
39 10__Main TS 81.9 100 1.273e-002 1.215e-002 --- --- ---
40 11__Main TS 81.8 100 1.265e-002 1.208e-002 --- --- ---
41 12__Main TS 81.7 100 1.254e-002 1.200e-002 --- --- ---
42 13__Main TS 81.7 100 1.240e-002 1.189e-002 --- --- ---
43 14__Main TS 81.7 100 1.221e-002 1.175e-002 --- --- ---
44 15__Main TS 81.8 100 1.195e-002 1.156e-002 --- --- ---
45 16__Main TS 82.1 100 1.160e-002 1.130e-002 --- --- ---
46 17__Main TS 82.8 100 1.117e-002 1.095e-002 --- --- ---
47 18__Main TS 83.8 100 1.068e-002 1.052e-002 --- --- ---
48 19__Main TS 85.0 100 1.019e-002 1.003e-002 --- --- ---
49 20__Main TS 86.0 100 1.362e-002 9.541e-003 3.000e-003 --- ---
50 Reboiler 93.9 100 --- 9.966e-003 --- 3.650e-003 378 *
54 Condenser 74.33 -4.358e+005 -3.917e+005 ---
55 1__Main TS 82.22 -4.398e+005 -4.019e+005 ---
56 2__Main TS 82.20 -4.389e+005 -4.009e+005 ---
57 3__Main TS 82.18 -4.380e+005 -3.999e+005 ---
58 4__Main TS 82.15 -4.370e+005 -3.989e+005 ---
59 5__Main TS 82.11 -4.359e+005 -3.978e+005 ---
60 6__Main TS 82.08 -4.346e+005 -3.965e+005 ---
61 7__Main TS 82.03 -4.332e+005 -3.951e+005 ---
62 8__Main TS 81.99 -4.316e+005 -3.935e+005 ---
63 9__Main TS 81.94 -4.296e+005 -3.916e+005 ---
64 10__Main TS 81.88 -4.271e+005 -3.894e+005 ---
65 11__Main TS 81.81 -4.240e+005 -3.866e+005 ---
66 12__Main TS 81.75 -4.201e+005 -3.831e+005 ---
67 13__Main TS 81.70 -4.148e+005 -3.785e+005 ---
68 14__Main TS 81.69 -4.078e+005 -3.725e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 15__Main TS 81.79 -3.982e+005 -3.643e+005 ---
14 16__Main TS 82.11 -3.854e+005 -3.532e+005 ---
15 17__Main TS 82.78 -3.692e+005 -3.382e+005 ---
16 18__Main TS 83.81 -3.508e+005 -3.191e+005 ---
17 19__Main TS 84.96 -3.332e+005 -2.970e+005 ---
18 20__Main TS 85.95 -3.210e+005 -2.754e+005 ---
19 Reboiler 93.95 -3.363e+005 -2.774e+005 ---
20
FEEDS / PRODUCTS
21
25 Q_C Energy 3.9e+002 * --- --- ---
Condenser
26 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.33*
28 2__Main TS
29 3__Main TS
30 4__Main TS
31 5__Main TS
32 6__Main TS
33 7__Main TS
34 8__Main TS
35 9__Main TS
36 10__Main TS
37 11__Main TS
38 12__Main TS
39 13__Main TS
40 14__Main TS
41 15__Main TS
42 16__Main TS
43 17__Main TS
44 18__Main TS
45 19__Main TS
47 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
48 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.95*
49
SETUP
50
51 Sub-Flowsheet
54 F0 F0 P-H Flash
55 F1 F1 P-H Flash
58 F2 F2 P-H Flash
59 F3 F3 P-H Flash
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 5 10 15 20 25 0 5 10 15 20 25
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 5 10 15 20 25 0 5 10 15 20 25
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 5 10 15 20 25 0 5 10 15 20 25
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 5 10 15 20 25
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.44 74.44
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2411 0.2411
34 Heat Flow (kJ/h) -1422 -1422
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0195 0.0029 0.0121 0.0000 0.0140
43 H2O 0.0005 0.1420 0.0083 0.0345 0.0000 0.0317
44 E-Acetate 0.0024 0.7262 0.2079 0.8625 0.0002 0.8750
45 AceticAcid 0.0004 0.1123 0.0219 0.0909 0.0000 0.0793
46 Total 0.0033 1.0000 0.2411 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0195 0.0029 0.0121 0.0000 0.0140
52 H2O 0.0005 0.1420 0.0083 0.0345 0.0000 0.0317
53 E-Acetate 0.0024 0.7262 0.2079 0.8625 0.0002 0.8750
54 AceticAcid 0.0004 0.1123 0.0219 0.0909 0.0000 0.0793
55 Total 0.0032 1.0000 0.2411 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 94.15 94.15
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1232 0.1232
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1223 -1223
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0718 0.0121 0.0980 0.0000 0.1231
22 H2O 0.0022 0.6063 0.0399 0.3236 0.0000 0.3242
23 E-Acetate 0.0000 0.0069 0.0022 0.0179 0.0000 0.0198
24 AceticAcid 0.0011 0.3150 0.0691 0.5605 0.0001 0.5329
25 Total 0.0036 1.0000 0.1232 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0718 0.0121 0.0980 0.0000 0.1231
31 H2O 0.0022 0.6063 0.0399 0.3236 0.0000 0.3242
32 E-Acetate 0.0000 0.0069 0.0022 0.0179 0.0000 0.0198
33 AceticAcid 0.0011 0.3150 0.0691 0.5605 0.0001 0.5329
34 Total 0.0036 1.0000 0.1232 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.44 74.44 74.44
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.6027 0.0000 0.6027
49 Heat Flow (kJ/h) -3555 0.0000 -3555
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0195 0.0073 0.0121 0.0000 0.0140
58 H2O 0.0012 0.1420 0.0208 0.0345 0.0000 0.0317
59 E-Acetate 0.0059 0.7262 0.5199 0.8625 0.0006 0.8750
60 AceticAcid 0.0009 0.1123 0.0548 0.0909 0.0001 0.0793
61 Total 0.0081 1.0000 0.6027 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0227 0.0000 0.0144 0.0000 0.0165
67 H2O 0.0000 0.1996 0.0000 0.0496 0.0000 0.0452
68 E-Acetate 0.0000 0.7528 0.0000 0.9152 0.0000 0.9204
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0250 0.0000 0.0207 0.0000 0.0179
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0195 0.0073 0.0121 0.0000 0.0140
22 H2O 0.0012 0.1420 0.0208 0.0345 0.0000 0.0317
23 E-Acetate 0.0059 0.7262 0.5199 0.8625 0.0006 0.8750
24 AceticAcid 0.0009 0.1123 0.0548 0.0909 0.0001 0.0793
25 Total 0.0081 1.0000 0.6027 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 30__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0195 0.0718
59 H2O 0.1420 0.6063
60 E-Acetate 0.7262 0.0069
61 AceticAcid 0.1123 0.3150
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.3399 9.6711
20 H2O (%) 159.5815 765.1556
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.3561 29.4847
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 82.3 100 1.305e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.3 100 1.305e-002 1.240e-002 --- --- ---
32 3__Main TS 82.3 100 1.304e-002 1.240e-002 --- --- ---
33 4__Main TS 82.3 100 1.303e-002 1.239e-002 --- --- ---
34 5__Main TS 82.3 100 1.302e-002 1.238e-002 --- --- ---
35 6__Main TS 82.3 100 1.301e-002 1.237e-002 --- --- ---
36 7__Main TS 82.2 100 1.300e-002 1.236e-002 --- --- ---
37 8__Main TS 82.2 100 1.299e-002 1.235e-002 --- --- ---
38 9__Main TS 82.2 100 1.298e-002 1.234e-002 --- --- ---
39 10__Main TS 82.2 100 1.297e-002 1.233e-002 --- --- ---
40 11__Main TS 82.2 100 1.296e-002 1.232e-002 --- --- ---
41 12__Main TS 82.2 100 1.294e-002 1.231e-002 --- --- ---
42 13__Main TS 82.1 100 1.292e-002 1.229e-002 --- --- ---
43 14__Main TS 82.1 100 1.290e-002 1.227e-002 --- --- ---
44 15__Main TS 82.1 100 1.288e-002 1.225e-002 --- --- ---
45 16__Main TS 82.0 100 1.285e-002 1.223e-002 --- --- ---
46 17__Main TS 82.0 100 1.282e-002 1.220e-002 --- --- ---
47 18__Main TS 82.0 100 1.278e-002 1.217e-002 --- --- ---
48 19__Main TS 81.9 100 1.273e-002 1.213e-002 --- --- ---
49 20__Main TS 81.9 100 1.267e-002 1.208e-002 --- --- ---
50 21__Main TS 81.9 100 1.259e-002 1.202e-002 --- --- ---
51 22__Main TS 81.8 100 1.248e-002 1.194e-002 --- --- ---
52 23__Main TS 81.8 100 1.233e-002 1.183e-002 --- --- ---
53 24__Main TS 81.9 100 1.214e-002 1.168e-002 --- --- ---
54 25__Main TS 82.1 100 1.187e-002 1.149e-002 --- --- ---
55 26__Main TS 82.5 100 1.152e-002 1.122e-002 --- --- ---
56 27__Main TS 83.4 100 1.109e-002 1.087e-002 --- --- ---
57 28__Main TS 84.4 100 1.061e-002 1.044e-002 --- --- ---
58 29__Main TS 85.5 100 1.013e-002 9.958e-003 --- --- ---
59 30__Main TS 86.3 100 1.357e-002 9.482e-003 3.000e-003 --- ---
60 Reboiler 94.2 100 --- 9.917e-003 --- 3.650e-003 377 *
64 Condenser 74.44 -4.375e+005 -3.930e+005 ---
65 1__Main TS 82.31 -4.414e+005 -4.037e+005 ---
66 2__Main TS 82.31 -4.410e+005 -4.032e+005 ---
67 3__Main TS 82.31 -4.406e+005 -4.028e+005 ---
68 4__Main TS 82.30 -4.402e+005 -4.024e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 5__Main TS 82.28 -4.398e+005 -4.019e+005 ---
14 6__Main TS 82.27 -4.394e+005 -4.015e+005 ---
15 7__Main TS 82.25 -4.390e+005 -4.010e+005 ---
16 8__Main TS 82.23 -4.385e+005 -4.005e+005 ---
17 9__Main TS 82.21 -4.380e+005 -4.000e+005 ---
18 10__Main TS 82.19 -4.375e+005 -3.994e+005 ---
19 11__Main TS 82.17 -4.369e+005 -3.988e+005 ---
20 12__Main TS 82.15 -4.362e+005 -3.982e+005 ---
21 13__Main TS 82.13 -4.355e+005 -3.974e+005 ---
22 14__Main TS 82.11 -4.347e+005 -3.966e+005 ---
23 15__Main TS 82.08 -4.337e+005 -3.957e+005 ---
24 16__Main TS 82.05 -4.326e+005 -3.946e+005 ---
25 17__Main TS 82.02 -4.313e+005 -3.933e+005 ---
26 18__Main TS 81.98 -4.297e+005 -3.918e+005 ---
27 19__Main TS 81.94 -4.278e+005 -3.900e+005 ---
28 20__Main TS 81.90 -4.253e+005 -3.878e+005 ---
29 21__Main TS 81.85 -4.222e+005 -3.850e+005 ---
30 22__Main TS 81.81 -4.181e+005 -3.815e+005 ---
31 23__Main TS 81.80 -4.127e+005 -3.768e+005 ---
32 24__Main TS 81.87 -4.053e+005 -3.706e+005 ---
33 25__Main TS 82.08 -3.953e+005 -3.620e+005 ---
34 26__Main TS 82.55 -3.822e+005 -3.505e+005 ---
35 27__Main TS 83.36 -3.659e+005 -3.350e+005 ---
36 28__Main TS 84.44 -3.481e+005 -3.158e+005 ---
37 29__Main TS 85.49 -3.314e+005 -2.944e+005 ---
38 30__Main TS 86.30 -3.201e+005 -2.739e+005 ---
39 Reboiler 94.15 -3.349e+005 -2.766e+005 ---
40
FEEDS / PRODUCTS
41
45 Q_C Energy 3.8e+002 * --- --- ---
Condenser
46 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.44*
48 2__Main TS
49 3__Main TS
50 4__Main TS
51 5__Main TS
52 6__Main TS
53 7__Main TS
54 8__Main TS
55 9__Main TS
56 10__Main TS
57 11__Main TS
58 12__Main TS
59 13__Main TS
60 14__Main TS
61 15__Main TS
62 16__Main TS
63 17__Main TS
64 18__Main TS
65 19__Main TS
66 20__Main TS
67 21__Main TS
68 22__Main TS
1
2 LEGENDS
4 USA
5
6
8
9
FEEDS / PRODUCTS
10
11 23__Main TS
12 24__Main TS
13 25__Main TS
14 26__Main TS
15 27__Main TS
16 28__Main TS
17 29__Main TS
19 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
20 F3 Draw --- Liquid 3.65e-003 * -3.3e+005 * 94.15*
21
SETUP
22
23 Sub-Flowsheet
26 F0 F0 P-H Flash
27 F1 F1 P-H Flash
30 F2 F2 P-H Flash
31 F3 F3 P-H Flash
32
33
34

35
37 95.0 105
38
104
39
40 90.0 103
41
42 102
Temperature (C)
Pressure (kPa)
43
85.0 101
44
45 100
46
47 80.0 99.0
48
98.0
49
50 75.0 97.0
51
52 96.0
53
70.0 95.0
54
0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 from Top
13 1.40e-002 940 75.0
14
15 1.20e-002
16
920 65.0
17
1.00e-002
18
Density (kg/m3)
910 60.0
19
20 8.00e-003 900 55.0
21
22 890 50.0
6.00e-003
23
24 880 45.0
25 4.00e-003
26 870 40.0
27 2.00e-003
28 860 35.0
29
0.000 850 30.0
30 0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35
31
32
33

34
35 K-Value
36 0.800 6.00
37
0.700 H2O (Light) H2O
38
E-Acetate (Light) 5.00 E-Acetate
39
40 0.600
41
4.00
Mole Fraction
42 0.500
K Value
43
44 0.400 3.00
45
46
0.300
47 2.00
48
0.200
49
50 1.00
1.00e-001
51
52
0.000 0.000
53
0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.49 74.49
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2418 0.2418
34 Heat Flow (kJ/h) -1424 -1424
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0190 0.0028 0.0117 0.0000 0.0135
43 H2O 0.0005 0.1392 0.0082 0.0337 0.0000 0.0310
44 E-Acetate 0.0024 0.7291 0.2088 0.8635 0.0002 0.8760
45 AceticAcid 0.0004 0.1128 0.0220 0.0910 0.0000 0.0795
46 Total 0.0032 1.0000 0.2418 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0190 0.0028 0.0117 0.0000 0.0135
52 H2O 0.0005 0.1392 0.0082 0.0337 0.0000 0.0310
53 E-Acetate 0.0024 0.7291 0.2088 0.8635 0.0002 0.8760
54 AceticAcid 0.0004 0.1128 0.0220 0.0910 0.0000 0.0795
55 Total 0.0032 1.0000 0.2418 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 94.23 94.23
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1225 0.1225
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1221 -1221
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0702 0.0118 0.0963 0.0000 0.1210
22 H2O 0.0022 0.6109 0.0402 0.3278 0.0000 0.3286
23 E-Acetate 0.0000 0.0065 0.0021 0.0170 0.0000 0.0188
24 AceticAcid 0.0011 0.3124 0.0685 0.5589 0.0001 0.5316
25 Total 0.0036 1.0000 0.1225 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0702 0.0118 0.0963 0.0000 0.1210
31 H2O 0.0022 0.6109 0.0402 0.3278 0.0000 0.3286
32 E-Acetate 0.0000 0.0065 0.0021 0.0170 0.0000 0.0188
33 AceticAcid 0.0011 0.3124 0.0685 0.5589 0.0001 0.5316
34 Total 0.0036 1.0000 0.1225 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.49 74.49 74.49
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.6044 0.0000 0.6044
49 Heat Flow (kJ/h) -3560 0.0000 -3560
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0190 0.0071 0.0117 0.0000 0.0135
58 H2O 0.0011 0.1392 0.0204 0.0337 0.0000 0.0310
59 E-Acetate 0.0059 0.7291 0.5219 0.8635 0.0006 0.8760
60 AceticAcid 0.0009 0.1128 0.0550 0.0910 0.0001 0.0795
61 Total 0.0081 1.0000 0.6044 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0221 0.0000 0.0140 0.0000 0.0160
67 H2O 0.0000 0.1977 0.0000 0.0490 0.0000 0.0447
68 E-Acetate 0.0000 0.7550 0.0000 0.9161 0.0000 0.9212
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0253 0.0000 0.0209 0.0000 0.0181
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0190 0.0071 0.0117 0.0000 0.0135
22 H2O 0.0011 0.1392 0.0204 0.0337 0.0000 0.0310
23 E-Acetate 0.0059 0.7291 0.5219 0.8635 0.0006 0.8760
24 AceticAcid 0.0009 0.1128 0.0550 0.0910 0.0001 0.0795
25 Total 0.0081 1.0000 0.6044 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 40__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0190 0.0702
59 H2O 0.1392 0.6109
60 E-Acetate 0.7291 0.0065
61 AceticAcid 0.1128 0.3124
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.2726 9.4459
20 H2O (%) 156.4671 771.0118
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.3964 29.2412
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 384 *
30 1__Main TS 82.3 100 1.305e-002 1.137e-002 3.900e-003 --- ---
31 2__Main TS 82.4 100 1.305e-002 1.240e-002 --- --- ---
32 3__Main TS 82.4 100 1.305e-002 1.240e-002 --- --- ---
33 4__Main TS 82.4 100 1.305e-002 1.240e-002 --- --- ---
34 5__Main TS 82.3 100 1.305e-002 1.240e-002 --- --- ---
35 6__Main TS 82.3 100 1.304e-002 1.240e-002 --- --- ---
36 7__Main TS 82.3 100 1.304e-002 1.239e-002 --- --- ---
37 8__Main TS 82.3 100 1.303e-002 1.239e-002 --- --- ---
38 9__Main TS 82.3 100 1.302e-002 1.238e-002 --- --- ---
39 10__Main TS 82.3 100 1.302e-002 1.237e-002 --- --- ---
40 11__Main TS 82.3 100 1.301e-002 1.237e-002 --- --- ---
41 12__Main TS 82.3 100 1.301e-002 1.236e-002 --- --- ---
42 13__Main TS 82.3 100 1.300e-002 1.236e-002 --- --- ---
43 14__Main TS 82.3 100 1.299e-002 1.235e-002 --- --- ---
44 15__Main TS 82.2 100 1.299e-002 1.234e-002 --- --- ---
45 16__Main TS 82.2 100 1.298e-002 1.234e-002 --- --- ---
46 17__Main TS 82.2 100 1.297e-002 1.233e-002 --- --- ---
47 18__Main TS 82.2 100 1.296e-002 1.232e-002 --- --- ---
48 19__Main TS 82.2 100 1.295e-002 1.231e-002 --- --- ---
49 20__Main TS 82.2 100 1.294e-002 1.230e-002 --- --- ---
50 21__Main TS 82.2 100 1.293e-002 1.229e-002 --- --- ---
51 22__Main TS 82.1 100 1.291e-002 1.228e-002 --- --- ---
52 23__Main TS 82.1 100 1.290e-002 1.226e-002 --- --- ---
53 24__Main TS 82.1 100 1.288e-002 1.225e-002 --- --- ---
54 25__Main TS 82.1 100 1.285e-002 1.223e-002 --- --- ---
55 26__Main TS 82.0 100 1.283e-002 1.220e-002 --- --- ---
56 27__Main TS 82.0 100 1.280e-002 1.218e-002 --- --- ---
57 28__Main TS 82.0 100 1.276e-002 1.215e-002 --- --- ---
58 29__Main TS 81.9 100 1.271e-002 1.211e-002 --- --- ---
59 30__Main TS 81.9 100 1.265e-002 1.206e-002 --- --- ---
60 31__Main TS 81.9 100 1.256e-002 1.200e-002 --- --- ---
61 32__Main TS 81.8 100 1.246e-002 1.191e-002 --- --- ---
62 33__Main TS 81.9 100 1.231e-002 1.181e-002 --- --- ---
63 34__Main TS 82.0 100 1.211e-002 1.166e-002 --- --- ---
64 35__Main TS 82.2 100 1.184e-002 1.146e-002 --- --- ---
65 36__Main TS 82.7 100 1.149e-002 1.119e-002 --- --- ---
66 37__Main TS 83.6 100 1.106e-002 1.084e-002 --- --- ---
67 38__Main TS 84.7 100 1.058e-002 1.041e-002 --- --- ---
68 39__Main TS 85.7 100 1.011e-002 9.931e-003 --- --- ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 40__Main TS 86.4 100 1.355e-002 9.461e-003 3.000e-003 --- ---
14 Reboiler 94.2 100 --- 9.899e-003 --- 3.650e-003 376 *
18 Condenser 74.49 -4.382e+005 -3.935e+005 ---
19 1__Main TS 82.34 -4.420e+005 -4.044e+005 ---
20 2__Main TS 82.36 -4.418e+005 -4.041e+005 ---
21 3__Main TS 82.36 -4.415e+005 -4.038e+005 ---
22 4__Main TS 82.35 -4.413e+005 -4.035e+005 ---
23 5__Main TS 82.35 -4.411e+005 -4.033e+005 ---
24 6__Main TS 82.34 -4.409e+005 -4.031e+005 ---
25 7__Main TS 82.33 -4.406e+005 -4.028e+005 ---
26 8__Main TS 82.32 -4.404e+005 -4.026e+005 ---
27 9__Main TS 82.31 -4.402e+005 -4.023e+005 ---
28 10__Main TS 82.30 -4.399e+005 -4.020e+005 ---
29 11__Main TS 82.29 -4.397e+005 -4.018e+005 ---
30 12__Main TS 82.28 -4.394e+005 -4.015e+005 ---
31 13__Main TS 82.26 -4.391e+005 -4.012e+005 ---
32 14__Main TS 82.25 -4.388e+005 -4.008e+005 ---
33 15__Main TS 82.24 -4.385e+005 -4.005e+005 ---
34 16__Main TS 82.23 -4.382e+005 -4.002e+005 ---
35 17__Main TS 82.21 -4.378e+005 -3.998e+005 ---
36 18__Main TS 82.20 -4.374e+005 -3.994e+005 ---
37 19__Main TS 82.18 -4.370e+005 -3.989e+005 ---
38 20__Main TS 82.17 -4.365e+005 -3.984e+005 ---
39 21__Main TS 82.15 -4.360e+005 -3.979e+005 ---
40 22__Main TS 82.13 -4.353e+005 -3.973e+005 ---
41 23__Main TS 82.11 -4.347e+005 -3.966e+005 ---
42 24__Main TS 82.09 -4.339e+005 -3.958e+005 ---
43 25__Main TS 82.07 -4.330e+005 -3.949e+005 ---
44 26__Main TS 82.04 -4.319e+005 -3.939e+005 ---
45 27__Main TS 82.02 -4.306e+005 -3.927e+005 ---
46 28__Main TS 81.98 -4.290e+005 -3.912e+005 ---
47 29__Main TS 81.95 -4.271e+005 -3.894e+005 ---
48 30__Main TS 81.91 -4.246e+005 -3.872e+005 ---
49 31__Main TS 81.87 -4.215e+005 -3.845e+005 ---
50 32__Main TS 81.85 -4.174e+005 -3.809e+005 ---
51 33__Main TS 81.86 -4.118e+005 -3.761e+005 ---
52 34__Main TS 81.95 -4.043e+005 -3.698e+005 ---
53 35__Main TS 82.21 -3.942e+005 -3.611e+005 ---
54 36__Main TS 82.75 -3.808e+005 -3.493e+005 ---
55 37__Main TS 83.62 -3.646e+005 -3.337e+005 ---
56 38__Main TS 84.70 -3.471e+005 -3.146e+005 ---
57 39__Main TS 85.71 -3.308e+005 -2.935e+005 ---
58 40__Main TS 86.43 -3.197e+005 -2.734e+005 ---
59 Reboiler 94.23 -3.344e+005 -2.763e+005 ---
60
FEEDS / PRODUCTS
61
65 Q_C Energy 3.8e+002 * --- --- ---
Condenser
66 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.49*
68 2__Main TS
1
2 LEGENDS
4 USA
5
6
8
9
FEEDS / PRODUCTS
10
11 3__Main TS
12 4__Main TS
13 5__Main TS
14 6__Main TS
15 7__Main TS
16 8__Main TS
17 9__Main TS
18 10__Main TS
19 11__Main TS
20 12__Main TS
21 13__Main TS
22 14__Main TS
23 15__Main TS
24 16__Main TS
25 17__Main TS
26 18__Main TS
27 19__Main TS
28 20__Main TS
29 21__Main TS
30 22__Main TS
31 23__Main TS
32 24__Main TS
33 25__Main TS
34 26__Main TS
35 27__Main TS
36 28__Main TS
37 29__Main TS
38 30__Main TS
39 31__Main TS
40 32__Main TS
41 33__Main TS
42 34__Main TS
43 35__Main TS
44 36__Main TS
45 37__Main TS
46 38__Main TS
47 39__Main TS
49 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
50 F3 Draw --- Liquid 3.65e-003 * -3.3e+005 * 94.23*
51
SETUP
52
53 Sub-Flowsheet
56 F0 F0 P-H Flash
57 F1 F1 P-H Flash
60 F2 F2 P-H Flash
61 F3 F3 P-H Flash
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 95.0 105
14
104
15
16 90.0 103
17
18 102
Temperature (C)
Pressure (kPa)
19
85.0 101
20
21 100
22
23 80.0 99.0
24
98.0
25
26 75.0 97.0
27
28 96.0
29
70.0 95.0
30 0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 35 40 45
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 35 40 45
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 6.00
14
15
16
17 0.600
18
4.00
Mole Fraction
19 0.500
K Value
20
21 0.400 3.00
22
23
0.300
24 2.00
25
0.200
26
27 1.00
1.00e-001
28
29
0.000 0.000
30 0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 25 30 35 40 45
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 5 10 15 20 25 30 35 40 45
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.51 74.51
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2421 0.2421
34 Heat Flow (kJ/h) -1425 -1425
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0187 0.0028 0.0116 0.0000 0.0133
43 H2O 0.0004 0.1379 0.0081 0.0334 0.0000 0.0307
44 E-Acetate 0.0024 0.7304 0.2092 0.8640 0.0002 0.8765
45 AceticAcid 0.0004 0.1130 0.0221 0.0911 0.0000 0.0795
46 Total 0.0032 1.0000 0.2421 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0187 0.0028 0.0116 0.0000 0.0133
52 H2O 0.0004 0.1379 0.0081 0.0334 0.0000 0.0307
53 E-Acetate 0.0024 0.7304 0.2092 0.8640 0.0002 0.8765
54 AceticAcid 0.0004 0.1130 0.0221 0.0911 0.0000 0.0795
55 Total 0.0032 1.0000 0.2421 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 94.27 94.27
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1222 0.1222
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1220 -1220
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0694 0.0117 0.0954 0.0000 0.1199
22 H2O 0.0022 0.6131 0.0403 0.3298 0.0000 0.3307
23 E-Acetate 0.0000 0.0063 0.0020 0.0166 0.0000 0.0184
24 AceticAcid 0.0011 0.3112 0.0682 0.5581 0.0001 0.5310
25 Total 0.0036 1.0000 0.1222 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0694 0.0117 0.0954 0.0000 0.1199
31 H2O 0.0022 0.6131 0.0403 0.3298 0.0000 0.3307
32 E-Acetate 0.0000 0.0063 0.0020 0.0166 0.0000 0.0184
33 AceticAcid 0.0011 0.3112 0.0682 0.5581 0.0001 0.5310
34 Total 0.0036 1.0000 0.1222 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.51 74.51 74.51
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.6052 0.0000 0.6052
49 Heat Flow (kJ/h) -3562 0.0000 -3562
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0187 0.0070 0.0116 0.0000 0.0133
58 H2O 0.0011 0.1379 0.0202 0.0334 0.0000 0.0307
59 E-Acetate 0.0059 0.7304 0.5229 0.8640 0.0006 0.8765
60 AceticAcid 0.0009 0.1130 0.0551 0.0911 0.0001 0.0795
61 Total 0.0081 1.0000 0.6052 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0218 0.0000 0.0138 0.0000 0.0158
67 H2O 0.0000 0.1967 0.0000 0.0488 0.0000 0.0445
68 E-Acetate 0.0000 0.7561 0.0000 0.9164 0.0000 0.9216
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0254 0.0000 0.0210 0.0000 0.0182
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0187 0.0070 0.0116 0.0000 0.0133
22 H2O 0.0011 0.1379 0.0202 0.0334 0.0000 0.0307
23 E-Acetate 0.0059 0.7304 0.5229 0.8640 0.0006 0.8765
24 AceticAcid 0.0009 0.1130 0.0551 0.0911 0.0001 0.0795
25 Total 0.0081 1.0000 0.6052 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 50__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0187 0.0694
59 H2O 0.1379 0.6131
60 E-Acetate 0.7304 0.0063
61 AceticAcid 0.1130 0.3112
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0004 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.2413 9.3381
20 H2O (%) 154.9809 773.8018
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.4157 29.1251
23
COLUMN PROFILES
24
29 Condenser 74.5 100 8.125e-003 --- --- 3.250e-003 384 *
30 1__Main TS 82.4 100 1.306e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.4 100 1.306e-002 1.241e-002 --- --- ---
32 3__Main TS 82.4 100 1.306e-002 1.241e-002 --- --- ---
33 4__Main TS 82.4 100 1.306e-002 1.241e-002 --- --- ---
34 5__Main TS 82.4 100 1.305e-002 1.241e-002 --- --- ---
35 6__Main TS 82.4 100 1.305e-002 1.240e-002 --- --- ---
36 7__Main TS 82.4 100 1.305e-002 1.240e-002 --- --- ---
37 8__Main TS 82.4 100 1.304e-002 1.240e-002 --- --- ---
38 9__Main TS 82.4 100 1.304e-002 1.239e-002 --- --- ---
39 10__Main TS 82.3 100 1.304e-002 1.239e-002 --- --- ---
40 11__Main TS 82.3 100 1.303e-002 1.239e-002 --- --- ---
41 12__Main TS 82.3 100 1.303e-002 1.238e-002 --- --- ---
42 13__Main TS 82.3 100 1.303e-002 1.238e-002 --- --- ---
43 14__Main TS 82.3 100 1.302e-002 1.238e-002 --- --- ---
44 15__Main TS 82.3 100 1.302e-002 1.237e-002 --- --- ---
45 16__Main TS 82.3 100 1.302e-002 1.237e-002 --- --- ---
46 17__Main TS 82.3 100 1.301e-002 1.237e-002 --- --- ---
47 18__Main TS 82.3 100 1.301e-002 1.236e-002 --- --- ---
48 19__Main TS 82.3 100 1.300e-002 1.236e-002 --- --- ---
49 20__Main TS 82.3 100 1.300e-002 1.235e-002 --- --- ---
50 21__Main TS 82.3 100 1.299e-002 1.235e-002 --- --- ---
51 22__Main TS 82.3 100 1.299e-002 1.234e-002 --- --- ---
52 23__Main TS 82.2 100 1.298e-002 1.234e-002 --- --- ---
53 24__Main TS 82.2 100 1.297e-002 1.233e-002 --- --- ---
54 25__Main TS 82.2 100 1.297e-002 1.232e-002 --- --- ---
55 26__Main TS 82.2 100 1.296e-002 1.232e-002 --- --- ---
56 27__Main TS 82.2 100 1.295e-002 1.231e-002 --- --- ---
57 28__Main TS 82.2 100 1.294e-002 1.230e-002 --- --- ---
58 29__Main TS 82.2 100 1.293e-002 1.229e-002 --- --- ---
59 30__Main TS 82.2 100 1.292e-002 1.228e-002 --- --- ---
60 31__Main TS 82.1 100 1.291e-002 1.227e-002 --- --- ---
61 32__Main TS 82.1 100 1.290e-002 1.226e-002 --- --- ---
62 33__Main TS 82.1 100 1.288e-002 1.225e-002 --- --- ---
63 34__Main TS 82.1 100 1.286e-002 1.223e-002 --- --- ---
64 35__Main TS 82.1 100 1.284e-002 1.221e-002 --- --- ---
65 36__Main TS 82.0 100 1.282e-002 1.219e-002 --- --- ---
66 37__Main TS 82.0 100 1.279e-002 1.217e-002 --- --- ---
67 38__Main TS 82.0 100 1.275e-002 1.214e-002 --- --- ---
68 39__Main TS 82.0 100 1.270e-002 1.210e-002 --- --- ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 40__Main TS 81.9 100 1.264e-002 1.205e-002 --- --- ---
14 41__Main TS 81.9 100 1.255e-002 1.199e-002 --- --- ---
15 42__Main TS 81.9 100 1.244e-002 1.190e-002 --- --- ---
16 43__Main TS 81.9 100 1.229e-002 1.179e-002 --- --- ---
17 44__Main TS 82.0 100 1.209e-002 1.164e-002 --- --- ---
18 45__Main TS 82.3 100 1.182e-002 1.144e-002 --- --- ---
19 46__Main TS 82.9 100 1.147e-002 1.117e-002 --- --- ---
20 47__Main TS 83.7 100 1.104e-002 1.082e-002 --- --- ---
21 48__Main TS 84.8 100 1.057e-002 1.039e-002 --- --- ---
22 49__Main TS 85.8 100 1.010e-002 9.917e-003 --- --- ---
23 50__Main TS 86.5 100 1.354e-002 9.451e-003 3.000e-003 --- ---
24 Reboiler 94.3 100 --- 9.891e-003 --- 3.650e-003 376 *
28 Condenser 74.51 -4.384e+005 -3.937e+005 ---
29 1__Main TS 82.36 -4.423e+005 -4.047e+005 ---
30 2__Main TS 82.38 -4.421e+005 -4.045e+005 ---
31 3__Main TS 82.38 -4.420e+005 -4.043e+005 ---
32 4__Main TS 82.38 -4.418e+005 -4.041e+005 ---
33 5__Main TS 82.38 -4.417e+005 -4.039e+005 ---
34 6__Main TS 82.37 -4.415e+005 -4.038e+005 ---
35 7__Main TS 82.36 -4.414e+005 -4.036e+005 ---
36 8__Main TS 82.36 -4.412e+005 -4.035e+005 ---
37 9__Main TS 82.35 -4.411e+005 -4.033e+005 ---
38 10__Main TS 82.34 -4.409e+005 -4.031e+005 ---
39 11__Main TS 82.34 -4.408e+005 -4.030e+005 ---
40 12__Main TS 82.33 -4.406e+005 -4.028e+005 ---
41 13__Main TS 82.32 -4.405e+005 -4.026e+005 ---
42 14__Main TS 82.32 -4.403e+005 -4.024e+005 ---
43 15__Main TS 82.31 -4.401e+005 -4.023e+005 ---
44 16__Main TS 82.30 -4.400e+005 -4.021e+005 ---
45 17__Main TS 82.29 -4.398e+005 -4.019e+005 ---
46 18__Main TS 82.29 -4.396e+005 -4.017e+005 ---
47 19__Main TS 82.28 -4.394e+005 -4.015e+005 ---
48 20__Main TS 82.27 -4.392e+005 -4.012e+005 ---
49 21__Main TS 82.26 -4.390e+005 -4.010e+005 ---
50 22__Main TS 82.25 -4.387e+005 -4.008e+005 ---
51 23__Main TS 82.24 -4.385e+005 -4.005e+005 ---
52 24__Main TS 82.23 -4.382e+005 -4.002e+005 ---
53 25__Main TS 82.22 -4.379e+005 -3.999e+005 ---
54 26__Main TS 82.21 -4.376e+005 -3.996e+005 ---
55 27__Main TS 82.20 -4.373e+005 -3.992e+005 ---
56 28__Main TS 82.19 -4.369e+005 -3.988e+005 ---
57 29__Main TS 82.17 -4.365e+005 -3.984e+005 ---
58 30__Main TS 82.16 -4.360e+005 -3.980e+005 ---
59 31__Main TS 82.14 -4.355e+005 -3.974e+005 ---
60 32__Main TS 82.13 -4.349e+005 -3.969e+005 ---
61 33__Main TS 82.11 -4.343e+005 -3.962e+005 ---
62 34__Main TS 82.09 -4.335e+005 -3.955e+005 ---
63 35__Main TS 82.07 -4.326e+005 -3.946e+005 ---
64 36__Main TS 82.04 -4.315e+005 -3.936e+005 ---
65 37__Main TS 82.02 -4.303e+005 -3.924e+005 ---
66 38__Main TS 81.98 -4.287e+005 -3.909e+005 ---
67 39__Main TS 81.95 -4.268e+005 -3.892e+005 ---
68 40__Main TS 81.92 -4.243e+005 -3.870e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 41__Main TS 81.88 -4.212e+005 -3.842e+005 ---
14 42__Main TS 81.86 -4.170e+005 -3.806e+005 ---
15 43__Main TS 81.89 -4.114e+005 -3.758e+005 ---
16 44__Main TS 82.00 -4.038e+005 -3.694e+005 ---
17 45__Main TS 82.28 -3.936e+005 -3.606e+005 ---
18 46__Main TS 82.85 -3.802e+005 -3.487e+005 ---
19 47__Main TS 83.75 -3.640e+005 -3.331e+005 ---
20 48__Main TS 84.84 -3.466e+005 -3.139e+005 ---
21 49__Main TS 85.81 -3.305e+005 -2.930e+005 ---
22 50__Main TS 86.50 -3.196e+005 -2.731e+005 ---
23 Reboiler 94.27 -3.342e+005 -2.762e+005 ---
24
FEEDS / PRODUCTS
25
29 Q_C Energy 3.8e+002 * --- --- ---
Condenser
30 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.51*
32 2__Main TS
33 3__Main TS
34 4__Main TS
35 5__Main TS
36 6__Main TS
37 7__Main TS
38 8__Main TS
39 9__Main TS
40 10__Main TS
41 11__Main TS
42 12__Main TS
43 13__Main TS
44 14__Main TS
45 15__Main TS
46 16__Main TS
47 17__Main TS
48 18__Main TS
49 19__Main TS
50 20__Main TS
51 21__Main TS
52 22__Main TS
53 23__Main TS
54 24__Main TS
55 25__Main TS
56 26__Main TS
57 27__Main TS
58 28__Main TS
59 29__Main TS
60 30__Main TS
61 31__Main TS
62 32__Main TS
63 33__Main TS
64 34__Main TS
65 35__Main TS
66 36__Main TS
67 37__Main TS
68 38__Main TS
1
2 LEGENDS
4 USA
5
6
8
9
FEEDS / PRODUCTS
10
11 39__Main TS
12 40__Main TS
13 41__Main TS
14 42__Main TS
15 43__Main TS
16 44__Main TS
17 45__Main TS
18 46__Main TS
19 47__Main TS
20 48__Main TS
21 49__Main TS
23 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
24 F3 Draw --- Liquid 3.65e-003 * -3.3e+005 * 94.27*
25
SETUP
26
27 Sub-Flowsheet
30 F0 F0 P-H Flash
31 F1 F1 P-H Flash
34 F2 F2 P-H Flash
35 F3 F3 P-H Flash
36
37
38

39
41 95.0 105
42
104
43
44 90.0 103
45
46 102
Temperature (C)
Pressure (kPa)
47
85.0 101
48
49 100
50
51 80.0 99.0
52
98.0
53
54 75.0 97.0
55
56 96.0
57
70.0 95.0
58
0 10 20 30 40 50 60 0 10 20 30 40 50 60
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 from Top
13 1.40e-002 940 75.0
14
15 1.20e-002
16
920 65.0
17
1.00e-002
18
Density (kg/m3)
910 60.0
19
20 8.00e-003 900 55.0
21
22 890 50.0
6.00e-003
23
24 880 45.0
25 4.00e-003
26 870 40.0
27 2.00e-003
28 860 35.0
29
0.000 850 30.0
30 0 10 20 30 40 50 60 0 10 20 30 40 50 60
31
32
33

34
35 K-Value
36 0.800 6.00
37
38
39
40 0.600
41
4.00
Mole Fraction
42 0.500
K Value
43
44 0.400 3.00
45
46
0.300
47 2.00
48
0.200
49
50 1.00
1.00e-001
51
52
0.000 0.000
53
0 10 20 30 40 50 60 0 10 20 30 40 50 60
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B5:
EFFECT OF
KINETIC MODEL
1
Case Name: KINETIC 2.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.38 74.38
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2398 0.2398
34 Heat Flow (kJ/h) -1422 -1422
36
37
COMPOSITION
38
39
42 Ethanol 0.0000 0.0069 0.0010 0.0043 0.0000 0.0050
43 H2O 0.0005 0.1556 0.0091 0.0380 0.0000 0.0350
44 E-Acetate 0.0024 0.7266 0.2081 0.8675 0.0002 0.8812
45 AceticAcid 0.0004 0.1108 0.0216 0.0902 0.0000 0.0788
46 Total 0.0033 1.0000 0.2398 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0000 0.0069 0.0010 0.0043 0.0000 0.0050
52 H2O 0.0005 0.1556 0.0091 0.0380 0.0000 0.0350
53 E-Acetate 0.0024 0.7266 0.2081 0.8675 0.0002 0.8812
54 AceticAcid 0.0004 0.1108 0.0216 0.0902 0.0000 0.0788
55 Total 0.0032 1.0000 0.2398 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 93.23 93.23
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1245 0.1245
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1223 -1223
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0776 0.0131 0.1049 0.0000 0.1312
22 H2O 0.0022 0.5996 0.0394 0.3168 0.0000 0.3162
23 E-Acetate 0.0000 0.0119 0.0038 0.0308 0.0000 0.0339
24 AceticAcid 0.0011 0.3109 0.0681 0.5476 0.0001 0.5187
25 Total 0.0036 1.0000 0.1245 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0776 0.0131 0.1049 0.0000 0.1312
31 H2O 0.0022 0.5996 0.0394 0.3168 0.0000 0.3162
32 E-Acetate 0.0000 0.0119 0.0038 0.0308 0.0000 0.0339
33 AceticAcid 0.0011 0.3109 0.0681 0.5476 0.0001 0.5187
34 Total 0.0036 1.0000 0.1245 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.38 74.38 74.38
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5996 0.0000 0.5996
49 Heat Flow (kJ/h) -3555 0.0000 -3555
51
52
COMPOSITION
53
54
57 Ethanol 0.0001 0.0069 0.0026 0.0043 0.0000 0.0050
58 H2O 0.0013 0.1556 0.0228 0.0380 0.0000 0.0350
59 E-Acetate 0.0059 0.7266 0.5202 0.8675 0.0006 0.8812
60 AceticAcid 0.0009 0.1108 0.0541 0.0902 0.0001 0.0788
61 Total 0.0081 1.0000 0.5996 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0080 0.0000 0.0051 0.0000 0.0058
67 H2O 0.0000 0.2113 0.0000 0.0527 0.0000 0.0481
68 E-Acetate 0.0000 0.7560 0.0000 0.9217 0.0000 0.9283
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0247 0.0000 0.0205 0.0000 0.0178
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0001 0.0069 0.0026 0.0043 0.0000 0.0050
22 H2O 0.0013 0.1556 0.0228 0.0380 0.0000 0.0350
23 E-Acetate 0.0059 0.7266 0.5202 0.8675 0.0006 0.8812
24 AceticAcid 0.0009 0.1108 0.0541 0.0902 0.0001 0.0788
25 Total 0.0081 1.0000 0.5996 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 65.75 * A' : 6.000e-002 *
61 E: 4.143e+004 * E' : 3.006e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0069 0.0776
59 H2O 0.1556 0.5996
60 E-Acetate 0.7266 0.0119
61 AceticAcid 0.1108 0.3109
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0000 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 0.8283 10.4497
20 H2O (%) 174.9135 756.6941
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.2338 29.0976
23
COLUMN PROFILES
24
29 Condenser 74.4 100 8.125e-003 --- --- 3.250e-003 385 *
30 1__Main TS 82.1 100 1.302e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.1 100 1.301e-002 1.237e-002 --- --- ---
32 3__Main TS 82.1 100 1.299e-002 1.236e-002 --- --- ---
33 4__Main TS 82.1 100 1.296e-002 1.234e-002 --- --- ---
34 5__Main TS 82.0 100 1.293e-002 1.231e-002 --- --- ---
35 6__Main TS 82.0 100 1.290e-002 1.228e-002 --- --- ---
36 7__Main TS 81.9 100 1.285e-002 1.225e-002 --- --- ---
37 8__Main TS 81.8 100 1.279e-002 1.220e-002 --- --- ---
38 9__Main TS 81.7 100 1.271e-002 1.214e-002 --- --- ---
39 10__Main TS 81.6 100 1.260e-002 1.206e-002 --- --- ---
40 11__Main TS 81.5 100 1.244e-002 1.195e-002 --- --- ---
41 12__Main TS 81.3 100 1.222e-002 1.179e-002 --- --- ---
42 13__Main TS 81.2 100 1.189e-002 1.157e-002 --- --- ---
43 14__Main TS 81.2 100 1.143e-002 1.124e-002 --- --- ---
44 15__Main TS 81.7 100 1.085e-002 1.078e-002 --- --- ---
45 16__Main TS 82.9 100 1.023e-002 1.020e-002 --- --- ---
46 17__Main TS 84.5 100 1.353e-002 9.584e-003 3.000e-003 --- ---
47 Reboiler 93.2 100 --- 9.885e-003 --- 3.650e-003 376 *
51 Condenser 74.38 -4.375e+005 -3.937e+005 ---
52 1__Main TS 82.15 -4.411e+005 -4.036e+005 ---
53 2__Main TS 82.12 -4.403e+005 -4.028e+005 ---
54 3__Main TS 82.09 -4.394e+005 -4.019e+005 ---
55 4__Main TS 82.06 -4.384e+005 -4.008e+005 ---
56 5__Main TS 82.02 -4.372e+005 -3.997e+005 ---
57 6__Main TS 81.97 -4.357e+005 -3.983e+005 ---
58 7__Main TS 81.91 -4.340e+005 -3.967e+005 ---
59 8__Main TS 81.84 -4.317e+005 -3.947e+005 ---
60 9__Main TS 81.75 -4.288e+005 -3.921e+005 ---
61 10__Main TS 81.63 -4.250e+005 -3.888e+005 ---
62 11__Main TS 81.47 -4.196e+005 -3.844e+005 ---
63 12__Main TS 81.30 -4.120e+005 -3.782e+005 ---
64 13__Main TS 81.15 -4.010e+005 -3.693e+005 ---
65 14__Main TS 81.20 -3.851e+005 -3.564e+005 ---
66 15__Main TS 81.70 -3.638e+005 -3.377e+005 ---
67 16__Main TS 82.90 -3.401e+005 -3.123e+005 ---
68 17__Main TS 84.54 -3.222e+005 -2.837e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 93.23 -3.352e+005 -2.793e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.4e+005 * 74.38*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 93.23*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920 65.0
40
1.00e-002
41
Density (kg/m3)
910 60.0
42
43 8.00e-003 900 55.0
44
45 890 50.0
6.00e-003
46
47 880 45.0
48 4.00e-003
49 870 40.0
50 2.00e-003
51 860 35.0
52
0.000 850 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: KINETIC 3.hsc
2 LEGENDS
4 USA
5
Date/Time: Sun Jun 07 18:47:56 2015
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 73.88 73.88
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2318 0.2318
34 Heat Flow (kJ/h) -1386 -1386
36
37
COMPOSITION
38
39
42 Ethanol 0.0002 0.0546 0.0082 0.0353 0.0000 0.0405
43 H2O 0.0005 0.1644 0.0096 0.0415 0.0000 0.0381
44 E-Acetate 0.0022 0.6751 0.1933 0.8340 0.0002 0.8437
45 AceticAcid 0.0003 0.1059 0.0207 0.0892 0.0000 0.0776
46 Total 0.0032 1.0000 0.2318 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0002 0.0546 0.0082 0.0353 0.0000 0.0405
52 H2O 0.0005 0.1644 0.0096 0.0415 0.0000 0.0381
53 E-Acetate 0.0022 0.6751 0.1933 0.8340 0.0002 0.8437
54 AceticAcid 0.0003 0.1059 0.0207 0.0892 0.0000 0.0776
55 Total 0.0032 1.0000 0.2318 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 94.67 94.67
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1325 0.1325
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1254 -1254
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0895 0.0150 0.1135 0.0000 0.1425
22 H2O 0.0020 0.5374 0.0353 0.2667 0.0000 0.2670
23 E-Acetate 0.0000 0.0035 0.0011 0.0086 0.0000 0.0095
24 AceticAcid 0.0013 0.3696 0.0810 0.6113 0.0001 0.5810
25 Total 0.0036 1.0000 0.1325 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0895 0.0150 0.1135 0.0000 0.1425
31 H2O 0.0020 0.5374 0.0353 0.2667 0.0000 0.2670
32 E-Acetate 0.0000 0.0035 0.0011 0.0086 0.0000 0.0095
33 AceticAcid 0.0013 0.3696 0.0810 0.6113 0.0001 0.5810
34 Total 0.0036 1.0000 0.1325 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 73.88 73.88 73.88
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5794 0.0000 0.5794
49 Heat Flow (kJ/h) -3465 0.0000 -3465
51
52
COMPOSITION
53
54
57 Ethanol 0.0004 0.0546 0.0204 0.0353 0.0000 0.0405
58 H2O 0.0013 0.1644 0.0241 0.0415 0.0000 0.0381
59 E-Acetate 0.0055 0.6751 0.4833 0.8340 0.0005 0.8437
60 AceticAcid 0.0009 0.1059 0.0517 0.0892 0.0000 0.0776
61 Total 0.0081 1.0000 0.5794 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0621 0.0000 0.0407 0.0000 0.0463
67 H2O 0.0000 0.2078 0.0000 0.0532 0.0000 0.0484
68 E-Acetate 0.0000 0.7090 0.0000 0.8881 0.0000 0.8898
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0211 0.0000 0.0180 0.0000 0.0155
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0004 0.0546 0.0204 0.0353 0.0000 0.0405
22 H2O 0.0013 0.1644 0.0241 0.0415 0.0000 0.0381
23 E-Acetate 0.0055 0.6751 0.4833 0.8340 0.0005 0.8437
24 AceticAcid 0.0009 0.1059 0.0517 0.0892 0.0000 0.0776
25 Total 0.0081 1.0000 0.5794 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 8056 * A' : 2050 *
61 E: 5.945e+004 * E' : 5.945e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0546 0.0895
59 H2O 0.1644 0.5374
60 E-Acetate 0.6751 0.0035
61 AceticAcid 0.1059 0.3696
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0002 * 0.0003 *
68 H2O (kgmole/h) 0.0005 * 0.0020 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 6.5436 12.0461
20 H2O (%) 184.7914 678.2823
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 8.8262 34.5874
23
COLUMN PROFILES
24
29 Condenser 73.9 100 8.125e-003 --- --- 3.250e-003 391 *
30 1__Main TS 82.0 100 1.297e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 81.9 100 1.290e-002 1.232e-002 --- --- ---
32 3__Main TS 81.8 100 1.281e-002 1.225e-002 --- --- ---
33 4__Main TS 81.8 100 1.272e-002 1.216e-002 --- --- ---
34 5__Main TS 81.7 100 1.260e-002 1.207e-002 --- --- ---
35 6__Main TS 81.8 100 1.247e-002 1.195e-002 --- --- ---
36 7__Main TS 81.9 100 1.231e-002 1.182e-002 --- --- ---
37 8__Main TS 82.2 100 1.213e-002 1.166e-002 --- --- ---
38 9__Main TS 82.8 100 1.192e-002 1.148e-002 --- --- ---
39 10__Main TS 83.6 100 1.169e-002 1.127e-002 --- --- ---
40 11__Main TS 84.7 100 1.145e-002 1.104e-002 --- --- ---
41 12__Main TS 85.8 100 1.120e-002 1.080e-002 --- --- ---
42 13__Main TS 86.8 100 1.095e-002 1.055e-002 --- --- ---
43 14__Main TS 87.4 100 1.069e-002 1.030e-002 --- --- ---
44 15__Main TS 87.7 100 1.045e-002 1.004e-002 --- --- ---
45 16__Main TS 87.7 100 1.022e-002 9.796e-003 --- --- ---
46 17__Main TS 87.7 100 1.396e-002 9.571e-003 3.000e-003 --- ---
47 Reboiler 94.7 100 --- 1.031e-002 --- 3.650e-003 387 *
51 Condenser 73.88 -4.265e+005 -3.833e+005 ---
52 1__Main TS 81.97 -4.312e+005 -3.922e+005 ---
53 2__Main TS 81.90 -4.280e+005 -3.888e+005 ---
54 3__Main TS 81.83 -4.245e+005 -3.852e+005 ---
55 4__Main TS 81.77 -4.205e+005 -3.812e+005 ---
56 5__Main TS 81.73 -4.159e+005 -3.767e+005 ---
57 6__Main TS 81.76 -4.104e+005 -3.714e+005 ---
58 7__Main TS 81.89 -4.039e+005 -3.651e+005 ---
59 8__Main TS 82.19 -3.961e+005 -3.576e+005 ---
60 9__Main TS 82.75 -3.869e+005 -3.486e+005 ---
61 10__Main TS 83.61 -3.768e+005 -3.381e+005 ---
62 11__Main TS 84.70 -3.665e+005 -3.264e+005 ---
63 12__Main TS 85.85 -3.566e+005 -3.143e+005 ---
64 13__Main TS 86.81 -3.475e+005 -3.025e+005 ---
65 14__Main TS 87.43 -3.393e+005 -2.915e+005 ---
66 15__Main TS 87.69 -3.317e+005 -2.813e+005 ---
67 16__Main TS 87.69 -3.252e+005 -2.718e+005 ---
68 17__Main TS 87.65 -3.221e+005 -2.635e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 94.67 -3.436e+005 -2.770e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 73.88*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.9e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 94.67*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 95.0 105
14
104
15
16 90.0 103
17
18 102
Temperature (C)
Pressure (kPa)
19
85.0 101
20
21 100
22
23 80.0 99.0
24
98.0
25
26 75.0 97.0
27
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 930 75.0
37
38 1.20e-002
39
910 65.0
40
1.00e-002
41
Density (kg/m3)
900 60.0
42
43 8.00e-003 890 55.0
44
45 880 50.0
6.00e-003
46
47 870 45.0
48 4.00e-003
49 860 40.0
50 2.00e-003
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 5.00
14
15 0.600
16 4.00
17
0.500 3.50
18
Mole Fraction
19
3.00
K Value
20 0.400
21 2.50
22
0.300
23 2.00
24
0.200 1.50
25
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 80.51 80.51
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.1485 0.1485
34 Heat Flow (kJ/h) -960.1 -960.1
36
37
COMPOSITION
38
39
42 Ethanol 0.0025 0.7836 0.1173 0.7903 0.0001 0.8316
43 H2O 0.0003 0.0813 0.0048 0.0321 0.0000 0.0269
44 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
45 AceticAcid 0.0004 0.1351 0.0264 0.1776 0.0000 0.1415
46 Total 0.0033 1.0000 0.1485 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0025 0.7836 0.1173 0.7903 0.0001 0.8316
52 H2O 0.0003 0.0813 0.0048 0.0321 0.0000 0.0269
53 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
54 AceticAcid 0.0004 0.1351 0.0264 0.1776 0.0000 0.1415
55 Total 0.0032 1.0000 0.1485 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 113.7 113.7
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.2158 0.2158
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1614 -1614
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0450 0.0076 0.0350 0.0000 0.0457
22 H2O 0.0000 0.0069 0.0005 0.0021 0.0000 0.0022
23 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 AceticAcid 0.0035 0.9482 0.2078 0.9629 0.0002 0.9521
25 Total 0.0036 1.0000 0.2158 1.0000 0.0002 1.0000
26
27
30 Ethanol 0.0002 0.0450 0.0076 0.0350 0.0000 0.0457
31 H2O 0.0000 0.0069 0.0005 0.0021 0.0000 0.0022
32 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 AceticAcid 0.0035 0.9482 0.2078 0.9629 0.0002 0.9521
34 Total 0.0036 1.0000 0.2158 1.0000 0.0002 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 80.51 80.51 80.51
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.3711 0.0000 0.3711
49 Heat Flow (kJ/h) -2400 0.0000 -2400
51
52
COMPOSITION
53
54
57 Ethanol 0.0064 0.7836 0.2933 0.7903 0.0004 0.8316
58 H2O 0.0007 0.0813 0.0119 0.0321 0.0000 0.0269
59 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 AceticAcid 0.0011 0.1351 0.0659 0.1776 0.0001 0.1415
61 Total 0.0081 1.0000 0.3711 1.0000 0.0004 1.0000
62
63
66 Ethanol 0.0000 0.8757 0.0000 0.9174 0.0000 0.9347
67 H2O 0.0000 0.0911 0.0000 0.0373 0.0000 0.0303
68 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0332 0.0000 0.0453 0.0000 0.0350
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0064 0.7836 0.2933 0.7903 0.0004 0.8316
22 H2O 0.0007 0.0813 0.0119 0.0321 0.0000 0.0269
23 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 AceticAcid 0.0011 0.1351 0.0659 0.1776 0.0001 0.1415
25 Total 0.0081 1.0000 0.3711 1.0000 0.0004 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 4.760e-004 * A' : 1.630e-004 *
61 E: 5.977e+004 * E' : 5.977e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.7836 0.0450
59 H2O 0.0813 0.0069
60 E-Acetate 0.0000 0.0000
61 AceticAcid 0.1351 0.9482
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0025 * 0.0002 *
68 H2O (kgmole/h) 0.0003 * 0.0000 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 93.9466 6.0533
20 H2O (%) 91.3451 8.6554
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 11.2596 88.7404
23
COLUMN PROFILES
24
29 Condenser 80.5 100 8.125e-003 --- --- 3.250e-003 423 *
30 1__Main TS 87.6 100 1.295e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 87.6 100 1.295e-002 1.230e-002 --- --- ---
32 3__Main TS 87.6 100 1.295e-002 1.230e-002 --- --- ---
33 4__Main TS 87.6 100 1.295e-002 1.230e-002 --- --- ---
34 5__Main TS 87.6 100 1.295e-002 1.230e-002 --- --- ---
35 6__Main TS 87.7 100 1.295e-002 1.230e-002 --- --- ---
36 7__Main TS 87.7 100 1.296e-002 1.230e-002 --- --- ---
37 8__Main TS 87.9 100 1.297e-002 1.231e-002 --- --- ---
38 9__Main TS 88.1 100 1.302e-002 1.232e-002 --- --- ---
39 10__Main TS 88.6 100 1.311e-002 1.237e-002 --- --- ---
40 11__Main TS 89.7 100 1.329e-002 1.246e-002 --- --- ---
41 12__Main TS 91.7 100 1.364e-002 1.264e-002 --- --- ---
42 13__Main TS 94.9 100 1.420e-002 1.299e-002 --- --- ---
43 14__Main TS 98.9 100 1.492e-002 1.355e-002 --- --- ---
44 15__Main TS 102.9 100 1.565e-002 1.427e-002 --- --- ---
45 16__Main TS 106.0 100 1.622e-002 1.500e-002 --- --- ---
46 17__Main TS 108.1 100 2.222e-002 1.557e-002 3.000e-003 --- ---
47 Reboiler 113.7 100 --- 1.857e-002 --- 3.650e-003 485 *
51 Condenser 80.51 -2.954e+005 -2.385e+005 ---
52 1__Main TS 87.61 -3.427e+005 -2.583e+005 ---
53 2__Main TS 87.61 -3.427e+005 -2.583e+005 ---
54 3__Main TS 87.62 -3.428e+005 -2.583e+005 ---
55 4__Main TS 87.63 -3.428e+005 -2.584e+005 ---
56 5__Main TS 87.65 -3.429e+005 -2.584e+005 ---
57 6__Main TS 87.67 -3.431e+005 -2.585e+005 ---
58 7__Main TS 87.73 -3.434e+005 -2.587e+005 ---
59 8__Main TS 87.85 -3.441e+005 -2.591e+005 ---
60 9__Main TS 88.11 -3.455e+005 -2.600e+005 ---
61 10__Main TS 88.64 -3.485e+005 -2.618e+005 ---
62 11__Main TS 89.72 -3.543e+005 -2.655e+005 ---
63 12__Main TS 91.71 -3.643e+005 -2.728e+005 ---
64 13__Main TS 94.86 -3.789e+005 -2.855e+005 ---
65 14__Main TS 98.88 -3.954e+005 -3.040e+005 ---
66 15__Main TS 102.9 -4.100e+005 -3.251e+005 ---
67 16__Main TS 106.0 -4.203e+005 -3.437e+005 ---
68 17__Main TS 108.1 -4.267e+005 -3.569e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 113.7 -4.423e+005 -3.975e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.2e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -3.0e+005 * 80.51*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 4.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -4.4e+005 * *
113.65
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 115 105
14
104
15 110
16 103
17
105 102
18
Temperature (C)
Pressure (kPa)
19
101
20 100
21 100
22
95.0
23 99.0
24
90.0 98.0
25
26 97.0
27 85.0
28 96.0
29
80.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 2.50e-002 940 60.0
37
38
39
2.00e-002
900
40 56.0
41
Density (kg/m3)
880
42 54.0
1.50e-002
43 860
44 52.0
45 840
46 1.00e-002
50.0
47 820
48
48.0
49 800
5.00e-003
50
780 46.0
51
52
0.000 760 44.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 1.00 4.00
14
15 3.50
16 0.800
17 3.00
18 0.700
Mole Fraction
19 2.50
0.600
K Value
20
21 0.500 2.00
22
23 0.400
1.50
24
0.300
25
1.00
26 0.200
27
0.500
28 1.00e-001
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 74.28 74.28
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2383 0.2383
34 Heat Flow (kJ/h) -1409 -1409
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0396 0.0059 0.0249 0.0000 0.0287
43 H2O 0.0005 0.1427 0.0084 0.0351 0.0000 0.0322
44 E-Acetate 0.0023 0.7061 0.2022 0.8486 0.0002 0.8595
45 AceticAcid 0.0004 0.1116 0.0218 0.0914 0.0000 0.0796
46 Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0396 0.0059 0.0249 0.0000 0.0287
52 H2O 0.0005 0.1427 0.0084 0.0351 0.0000 0.0322
53 E-Acetate 0.0023 0.7061 0.2022 0.8486 0.0002 0.8595
54 AceticAcid 0.0004 0.1116 0.0218 0.0914 0.0000 0.0796
55 Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 92.97 92.97
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1260 0.1260
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1236 -1236
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0531 0.0089 0.0709 0.0000 0.0891
22 H2O 0.0022 0.6064 0.0399 0.3164 0.0000 0.3174
23 E-Acetate 0.0001 0.0255 0.0082 0.0652 0.0000 0.0721
24 AceticAcid 0.0011 0.3149 0.0690 0.5476 0.0001 0.5214
25 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0531 0.0089 0.0709 0.0000 0.0891
31 H2O 0.0022 0.6064 0.0399 0.3164 0.0000 0.3174
32 E-Acetate 0.0001 0.0255 0.0082 0.0652 0.0000 0.0721
33 AceticAcid 0.0011 0.3149 0.0690 0.5476 0.0001 0.5214
34 Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 74.28 74.28 74.28
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5956 0.0000 0.5956
49 Heat Flow (kJ/h) -3522 0.0000 -3522
51
52
COMPOSITION
53
54
57 Ethanol 0.0003 0.0396 0.0148 0.0249 0.0000 0.0287
58 H2O 0.0012 0.1427 0.0209 0.0351 0.0000 0.0322
59 E-Acetate 0.0057 0.7061 0.5055 0.8486 0.0006 0.8595
60 AceticAcid 0.0009 0.1116 0.0544 0.0914 0.0001 0.0796
61 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0458 0.0000 0.0294 0.0000 0.0335
67 H2O 0.0000 0.1961 0.0000 0.0492 0.0000 0.0448
68 E-Acetate 0.0000 0.7343 0.0000 0.9014 0.0000 0.9045
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0238 0.0000 0.0199 0.0000 0.0172
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0003 0.0396 0.0148 0.0249 0.0000 0.0287
22 H2O 0.0012 0.1427 0.0209 0.0351 0.0000 0.0322
23 E-Acetate 0.0057 0.7061 0.5055 0.8486 0.0006 0.8595
24 AceticAcid 0.0009 0.1116 0.0544 0.0914 0.0001 0.0796
25 Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 1.311e+005 * A' : 8.139e+004 *
61 E: 5.796e+004 * E' : 6.055e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0396 0.0531
59 H2O 0.1427 0.6064
60 E-Acetate 0.7061 0.0255
61 AceticAcid 0.1116 0.3149
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0002 *
68 H2O (kgmole/h) 0.0005 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 4.7534 7.1513
20 H2O (%) 160.3542 765.3791
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 9.2966 29.4704
23
COLUMN PROFILES
24
29 Condenser 74.3 100 8.125e-003 --- --- 3.250e-003 386 *
30 1__Main TS 82.3 100 1.306e-002 1.138e-002 3.900e-003 --- ---
31 2__Main TS 82.3 100 1.304e-002 1.241e-002 --- --- ---
32 3__Main TS 82.3 100 1.301e-002 1.239e-002 --- --- ---
33 4__Main TS 82.2 100 1.299e-002 1.236e-002 --- --- ---
34 5__Main TS 82.2 100 1.296e-002 1.234e-002 --- --- ---
35 6__Main TS 82.2 100 1.292e-002 1.231e-002 --- --- ---
36 7__Main TS 82.1 100 1.289e-002 1.227e-002 --- --- ---
37 8__Main TS 82.1 100 1.285e-002 1.224e-002 --- --- ---
38 9__Main TS 82.1 100 1.280e-002 1.220e-002 --- --- ---
39 10__Main TS 82.1 100 1.273e-002 1.215e-002 --- --- ---
40 11__Main TS 82.0 100 1.265e-002 1.208e-002 --- --- ---
41 12__Main TS 82.0 100 1.254e-002 1.200e-002 --- --- ---
42 13__Main TS 82.0 100 1.238e-002 1.189e-002 --- --- ---
43 14__Main TS 81.9 100 1.213e-002 1.173e-002 --- --- ---
44 15__Main TS 81.8 100 1.170e-002 1.148e-002 --- --- ---
45 16__Main TS 81.8 100 1.095e-002 1.105e-002 --- --- ---
46 17__Main TS 82.5 100 1.361e-002 1.030e-002 3.000e-003 --- ---
47 Reboiler 93.0 100 --- 9.962e-003 --- 3.650e-003 378 *
51 Condenser 74.28 -4.334e+005 -3.889e+005 ---
52 1__Main TS 82.33 -4.378e+005 -3.994e+005 ---
53 2__Main TS 82.31 -4.368e+005 -3.983e+005 ---
54 3__Main TS 82.27 -4.357e+005 -3.971e+005 ---
55 4__Main TS 82.23 -4.345e+005 -3.958e+005 ---
56 5__Main TS 82.20 -4.333e+005 -3.945e+005 ---
57 6__Main TS 82.16 -4.319e+005 -3.931e+005 ---
58 7__Main TS 82.13 -4.303e+005 -3.915e+005 ---
59 8__Main TS 82.10 -4.285e+005 -3.898e+005 ---
60 9__Main TS 82.08 -4.263e+005 -3.877e+005 ---
61 10__Main TS 82.06 -4.237e+005 -3.853e+005 ---
62 11__Main TS 82.04 -4.204e+005 -3.823e+005 ---
63 12__Main TS 82.02 -4.161e+005 -3.786e+005 ---
64 13__Main TS 82.00 -4.101e+005 -3.736e+005 ---
65 14__Main TS 81.93 -4.013e+005 -3.667e+005 ---
66 15__Main TS 81.82 -3.875e+005 -3.565e+005 ---
67 16__Main TS 81.78 -3.649e+005 -3.401e+005 ---
68 17__Main TS 82.52 -3.331e+005 -3.126e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 92.97 -3.387e+005 -2.931e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 74.28*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 92.97*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 94.0 105
14
92.0 104
15
16 90.0 103
17
18 88.0 102
Temperature (C)
Pressure (kPa)
19
86.0 101
20
21 84.0 100
22
23 82.0 99.0
24
80.0 98.0
25
26 78.0 97.0
27
28 76.0 96.0
29
74.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920
65.0
40
1.00e-002 910
41
Density (kg/m3)
60.0
42
900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46 880
47 45.0
4.00e-003 870
48
49 40.0
860
50 2.00e-003
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 5.00
14
15 0.700
16 4.00
17 0.600
18 3.50
Mole Fraction
19 0.500
3.00
K Value
20
21 0.400 2.50
22
23 2.00
0.300
24
1.50
25
0.200
26 1.00
27
1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B6:
EFFECT OF MOLAR
FEED RATIO
1
Case Name: MOLAR RATIO 0.2.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 3.603e-002 3.603e-002
20 Heat Flow (kJ/h) -276.6 -276.6
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0006 * 1.0000 * 0.0360 * 1.0000 * 0.0000 * 1.0000 *
32 Total 0.0006 1.0000 0.0360 1.0000 0.0000 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0006 1.0000 0.0360 1.0000 0.0000 1.0000
41 Total 0.0006 1.0000 0.0360 1.0000 0.0000 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.37 71.37
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 9.128e-002 9.128e-002
34 Heat Flow (kJ/h) -575.6 -575.6
36
37
COMPOSITION
38
39
42 Ethanol 0.0007 0.4209 0.0324 0.3547 0.0000 0.3878
43 H2O 0.0004 0.2198 0.0066 0.0725 0.0000 0.0632
44 E-Acetate 0.0006 0.3470 0.0511 0.5593 0.0001 0.5378
45 AceticAcid 0.0000 0.0123 0.0012 0.0135 0.0000 0.0112
46 Total 0.0017 1.0000 0.0913 1.0000 0.0001 1.0000
47
48
51 Ethanol 0.0007 0.4209 0.0324 0.3547 0.0000 0.3878
52 H2O 0.0004 0.2198 0.0066 0.0725 0.0000 0.0632
53 E-Acetate 0.0006 0.3470 0.0511 0.5593 0.0001 0.5378
54 AceticAcid 0.0000 0.0123 0.0012 0.0135 0.0000 0.0112
55 Total 0.0017 1.0000 0.0913 1.0000 0.0001 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 77.87 77.87
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 7.485e-002 7.485e-002
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -526.3 -526.3
15
16
COMPOSITION
17
18
21 Ethanol 0.0014 0.7402 0.0658 0.8793 0.0001 0.9013
22 H2O 0.0005 0.2598 0.0090 0.1207 0.0000 0.0987
23 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
24 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 Total 0.0019 1.0000 0.0748 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0014 0.7402 0.0658 0.8793 0.0001 0.9013
31 H2O 0.0005 0.2598 0.0090 0.1207 0.0000 0.0987
32 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
33 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
34 Total 0.0019 1.0000 0.0748 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.37 71.37 71.37
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.2282 0.0000 0.2282
49 Heat Flow (kJ/h) -1439 0.0000 -1439
51
52
COMPOSITION
53
54
57 Ethanol 0.0018 0.4209 0.0810 0.3547 0.0001 0.3878
58 H2O 0.0009 0.2198 0.0165 0.0725 0.0000 0.0632
59 E-Acetate 0.0014 0.3470 0.1276 0.5593 0.0001 0.5378
60 AceticAcid 0.0001 0.0123 0.0031 0.0135 0.0000 0.0112
61 Total 0.0042 1.0000 0.2282 1.0000 0.0003 1.0000
62
63
66 Ethanol 0.0000 0.3722 0.0000 0.2891 0.0000 0.3178
67 H2O 0.0000 0.1871 0.0000 0.0568 0.0000 0.0498
68 E-Acetate 0.0000 0.4393 0.0000 0.6526 0.0000 0.6312
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0014 0.0000 0.0014 0.0000 0.0012
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0018 0.4209 0.0810 0.3547 0.0001 0.3878
22 H2O 0.0009 0.2198 0.0165 0.0725 0.0000 0.0632
23 E-Acetate 0.0014 0.3470 0.1276 0.5593 0.0001 0.5378
24 AceticAcid 0.0001 0.0123 0.0031 0.0135 0.0000 0.0112
25 Total 0.0042 1.0000 0.2282 1.0000 0.0003 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.4209 0.7402
59 H2O 0.2198 0.2598
60 E-Acetate 0.3470 0.0000
61 AceticAcid 0.0123 0.0000
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0007 * 0.0014 *
68 H2O (kgmole/h) 0.0004 * 0.0005 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 25.9287 52.6968
20 H2O (%) 126.9447 173.4019
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 3.4302 0.0000
23
COLUMN PROFILES
24
29 Condenser 71.4 100 4.175e-003 --- --- 1.670e-003 220 *
30 1__Main TS 74.3 100 4.588e-003 5.845e-003 6.000e-004 --- ---
31 2__Main TS 75.5 100 4.357e-003 5.658e-003 --- --- ---
32 3__Main TS 77.2 100 4.244e-003 5.427e-003 --- --- ---
33 4__Main TS 78.2 100 4.199e-003 5.314e-003 --- --- ---
34 5__Main TS 78.6 100 4.182e-003 5.269e-003 --- --- ---
35 6__Main TS 78.8 100 4.175e-003 5.252e-003 --- --- ---
36 7__Main TS 78.8 100 4.172e-003 5.245e-003 --- --- ---
37 8__Main TS 78.8 100 4.171e-003 5.242e-003 --- --- ---
38 9__Main TS 78.8 100 4.171e-003 5.241e-003 --- --- ---
39 10__Main TS 78.8 100 4.172e-003 5.241e-003 --- --- ---
40 11__Main TS 78.8 100 4.173e-003 5.242e-003 --- --- ---
41 12__Main TS 78.7 100 4.176e-003 5.243e-003 --- --- ---
42 13__Main TS 78.6 100 4.180e-003 5.246e-003 --- --- ---
43 14__Main TS 78.5 100 4.187e-003 5.250e-003 --- --- ---
44 15__Main TS 78.3 100 4.199e-003 5.257e-003 --- --- ---
45 16__Main TS 78.0 100 4.215e-003 5.269e-003 --- --- ---
46 17__Main TS 77.8 100 7.861e-003 5.285e-003 3.000e-003 --- ---
47 Reboiler 77.9 100 --- 5.931e-003 --- 1.930e-003 233 *
51 Condenser 71.37 -3.447e+005 -3.239e+005 ---
52 1__Main TS 74.35 -3.294e+005 -3.071e+005 ---
53 2__Main TS 75.52 -3.012e+005 -2.812e+005 ---
54 3__Main TS 77.22 -2.848e+005 -2.564e+005 ---
55 4__Main TS 78.23 -2.783e+005 -2.424e+005 ---
56 5__Main TS 78.62 -2.759e+005 -2.368e+005 ---
57 6__Main TS 78.75 -2.751e+005 -2.348e+005 ---
58 7__Main TS 78.80 -2.747e+005 -2.341e+005 ---
59 8__Main TS 78.81 -2.746e+005 -2.338e+005 ---
60 9__Main TS 78.81 -2.746e+005 -2.337e+005 ---
61 10__Main TS 78.79 -2.745e+005 -2.337e+005 ---
62 11__Main TS 78.77 -2.745e+005 -2.336e+005 ---
63 12__Main TS 78.72 -2.744e+005 -2.336e+005 ---
64 13__Main TS 78.64 -2.743e+005 -2.336e+005 ---
65 14__Main TS 78.50 -2.740e+005 -2.335e+005 ---
66 15__Main TS 78.30 -2.737e+005 -2.334e+005 ---
67 16__Main TS 78.03 -2.731e+005 -2.332e+005 ---
68 17__Main TS 77.76 -2.724e+005 -2.329e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 77.87 -2.727e+005 -2.330e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 2.2e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 1.67e-003 * -3.4e+005 * 71.37*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 2.3e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 1.93e-003 * -2.7e+005 * 77.87*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 79.0 105
14
104
15 78.0
16 103
17 77.0
18 102
Temperature (C)
Pressure (kPa)
19 76.0
101
20
21 75.0 100
22
23 99.0
74.0
24
98.0
25
73.0
26 97.0
27
72.0
28 96.0
29
71.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 8.00e-003 830 55.0
37
7.00e-003 Liquid Mol Weight(Light)
38
820
39
50.0
40 6.00e-003
41
Density (kg/m3)
810
42 5.00e-003
45.0
43
44 4.00e-003 800
45
46 40.0
3.00e-003
47 790
48
2.00e-003
49 35.0
50 780
1.00e-003
51
52
0.000 770 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 4.50
14
0.700 H2O (Light) 4.00 H2O
15
16
AceticAcid (Light) 3.50 AceticAcid
17 0.600
18
3.00
Mole Fraction
19 0.500
K Value
20 2.50
21 0.400
22 2.00
23
0.300
24 1.50
25
0.200
26 1.00
27
1.00e-001 0.500
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 9.008e-002 9.008e-002
20 Heat Flow (kJ/h) -691.5 -691.5
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0015 * 1.0000 * 0.0901 * 1.0000 * 0.0001 * 1.0000 *
32 Total 0.0015 1.0000 0.0901 1.0000 0.0001 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0015 1.0000 0.0901 1.0000 0.0001 1.0000
41 Total 0.0015 1.0000 0.0901 1.0000 0.0001 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 72.29 72.29
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.1440 0.1440
34 Heat Flow (kJ/h) -867.1 -867.1
36
37
COMPOSITION
38
39
42 Ethanol 0.0002 0.0782 0.0075 0.0523 0.0000 0.0597
43 H2O 0.0004 0.2038 0.0077 0.0532 0.0000 0.0485
44 E-Acetate 0.0014 0.6621 0.1218 0.8459 0.0001 0.8498
45 AceticAcid 0.0001 0.0558 0.0070 0.0486 0.0000 0.0420
46 Total 0.0021 1.0000 0.1440 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0002 0.0782 0.0075 0.0523 0.0000 0.0597
52 H2O 0.0004 0.2038 0.0077 0.0532 0.0000 0.0485
53 E-Acetate 0.0014 0.6621 0.1218 0.8459 0.0001 0.8498
54 AceticAcid 0.0001 0.0558 0.0070 0.0486 0.0000 0.0420
55 Total 0.0021 1.0000 0.1440 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 79.42 79.42
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 7.618e-002 7.618e-002
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -664.3 -664.3
15
16
COMPOSITION
17
18
21 Ethanol 0.0012 0.4830 0.0537 0.7045 0.0001 0.7494
22 H2O 0.0012 0.5166 0.0224 0.2947 0.0000 0.2500
23 E-Acetate 0.0000 0.0000 0.0000 0.0001 0.0000 0.0001
24 AceticAcid 0.0000 0.0004 0.0001 0.0007 0.0000 0.0006
25 Total 0.0024 1.0000 0.0762 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0012 0.4830 0.0537 0.7045 0.0001 0.7494
31 H2O 0.0012 0.5166 0.0224 0.2947 0.0000 0.2500
32 E-Acetate 0.0000 0.0000 0.0000 0.0001 0.0000 0.0001
33 AceticAcid 0.0000 0.0004 0.0001 0.0007 0.0000 0.0006
34 Total 0.0024 1.0000 0.0762 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 72.29 72.29 72.29
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.3600 0.0000 0.3600
49 Heat Flow (kJ/h) -2168 0.0000 -2168
51
52
COMPOSITION
53
54
57 Ethanol 0.0004 0.0782 0.0188 0.0523 0.0000 0.0597
58 H2O 0.0011 0.2038 0.0192 0.0532 0.0000 0.0485
59 E-Acetate 0.0035 0.6621 0.3045 0.8459 0.0003 0.8498
60 AceticAcid 0.0003 0.0558 0.0175 0.0486 0.0000 0.0420
61 Total 0.0052 1.0000 0.3600 1.0000 0.0004 1.0000
62
63
66 Ethanol 0.0000 0.0887 0.0000 0.0601 0.0000 0.0682
67 H2O 0.0000 0.2297 0.0000 0.0608 0.0000 0.0551
68 E-Acetate 0.0000 0.6721 0.0000 0.8706 0.0000 0.8695
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0095 0.0000 0.0084 0.0000 0.0072
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0004 0.0782 0.0188 0.0523 0.0000 0.0597
22 H2O 0.0011 0.2038 0.0192 0.0532 0.0000 0.0485
23 E-Acetate 0.0035 0.6621 0.3045 0.8459 0.0003 0.8498
24 AceticAcid 0.0003 0.0558 0.0175 0.0486 0.0000 0.0420
25 Total 0.0052 1.0000 0.3600 1.0000 0.0004 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0782 0.4830
59 H2O 0.2038 0.5166
60 E-Acetate 0.6621 0.0000
61 AceticAcid 0.0558 0.0004
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0002 * 0.0012 *
68 H2O (kgmole/h) 0.0004 * 0.0012 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 6.0269 42.9735
20 H2O (%) 147.1701 430.8580
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 7.7713 0.0623
23
COLUMN PROFILES
24
29 Condenser 72.3 100 5.220e-003 --- --- 2.088e-003 256 *
30 1__Main TS 77.7 100 7.013e-003 7.308e-003 1.500e-003 --- ---
31 2__Main TS 77.3 100 6.912e-003 7.601e-003 --- --- ---
32 3__Main TS 76.8 100 6.789e-003 7.500e-003 --- --- ---
33 4__Main TS 76.3 100 6.636e-003 7.377e-003 --- --- ---
34 5__Main TS 75.7 100 6.445e-003 7.224e-003 --- --- ---
35 6__Main TS 75.2 100 6.207e-003 7.033e-003 --- --- ---
36 7__Main TS 75.2 100 5.920e-003 6.795e-003 --- --- ---
37 8__Main TS 76.0 100 5.631e-003 6.508e-003 --- --- ---
38 9__Main TS 77.6 100 5.420e-003 6.219e-003 --- --- ---
39 10__Main TS 79.0 100 5.302e-003 6.008e-003 --- --- ---
40 11__Main TS 79.7 100 5.241e-003 5.890e-003 --- --- ---
41 12__Main TS 79.9 100 5.211e-003 5.829e-003 --- --- ---
42 13__Main TS 80.0 100 5.197e-003 5.799e-003 --- --- ---
43 14__Main TS 79.9 100 5.194e-003 5.785e-003 --- --- ---
44 15__Main TS 79.7 100 5.202e-003 5.782e-003 --- --- ---
45 16__Main TS 79.3 100 5.223e-003 5.790e-003 --- --- ---
46 17__Main TS 78.5 100 8.837e-003 5.811e-003 3.000e-003 --- ---
47 Reboiler 79.4 100 --- 6.425e-003 --- 2.412e-003 255 *
51 Condenser 72.29 -4.153e+005 -3.737e+005 ---
52 1__Main TS 77.67 -4.186e+005 -3.802e+005 ---
53 2__Main TS 77.27 -4.129e+005 -3.756e+005 ---
54 3__Main TS 76.81 -4.058e+005 -3.698e+005 ---
55 4__Main TS 76.27 -3.965e+005 -3.625e+005 ---
56 5__Main TS 75.71 -3.841e+005 -3.531e+005 ---
57 6__Main TS 75.25 -3.670e+005 -3.405e+005 ---
58 7__Main TS 75.20 -3.438e+005 -3.234e+005 ---
59 8__Main TS 76.01 -3.174e+005 -3.004e+005 ---
60 9__Main TS 77.59 -2.967e+005 -2.744e+005 ---
61 10__Main TS 78.97 -2.856e+005 -2.542e+005 ---
62 11__Main TS 79.67 -2.806e+005 -2.434e+005 ---
63 12__Main TS 79.94 -2.783e+005 -2.384e+005 ---
64 13__Main TS 80.01 -2.772e+005 -2.362e+005 ---
65 14__Main TS 79.95 -2.765e+005 -2.351e+005 ---
66 15__Main TS 79.74 -2.760e+005 -2.345e+005 ---
67 16__Main TS 79.29 -2.753e+005 -2.341e+005 ---
68 17__Main TS 78.51 -2.741e+005 -2.336e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 79.42 -2.754e+005 -2.339e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 2.6e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 2.09e-003 * -4.2e+005 * 72.29*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 2.5e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 2.41e-003 * -2.8e+005 * 79.42*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 81.0 105
14
80.0 104
15
16 103
79.0
17
18 102
Temperature (C)
78.0
Pressure (kPa)
19
101
20 77.0
21 100
22 76.0
23 99.0
24 75.0
98.0
25
26 74.0
97.0
27
28 73.0 96.0
29
72.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 9.00e-003 870 70.0
37
8.00e-003 Liquid Mol Weight(Light) 65.0
38 860
39
7.00e-003 60.0
40
850
41
Density (kg/m3)
6.00e-003 55.0
42
43 5.00e-003 840 50.0
44
45 4.00e-003 45.0
830
46
47 3.00e-003 40.0
48 820
49 2.00e-003 35.0
50 810
51 1.00e-003 30.0
52
0.000 800 25.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 6.00
14
H2O (Light) H2O
15 0.600
16
17
0.500
18
4.00
Mole Fraction
19
K Value
20 0.400
21 3.00
22
0.300
23
24 2.00
25 0.200
26
27 1.00
1.00e-001
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: MOLAR RATIO 1.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.1802 0.1802
20 Heat Flow (kJ/h) -1383 -1383
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0030 * 1.0000 * 0.1802 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0030 1.0000 0.1802 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0030 1.0000 0.1802 1.0000 0.0002 1.0000
41 Total 0.0030 1.0000 0.1802 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 73.90 73.90
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2031 0.2031
34 Heat Flow (kJ/h) -1205 -1205
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0261 0.0033 0.0165 0.0000 0.0190
43 H2O 0.0004 0.1612 0.0081 0.0398 0.0000 0.0366
44 E-Acetate 0.0020 0.7140 0.1751 0.8624 0.0002 0.8736
45 AceticAcid 0.0003 0.0987 0.0165 0.0813 0.0000 0.0708
46 Total 0.0028 1.0000 0.2031 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0001 0.0261 0.0033 0.0165 0.0000 0.0190
52 H2O 0.0004 0.1612 0.0081 0.0398 0.0000 0.0366
53 E-Acetate 0.0020 0.7140 0.1751 0.8624 0.0002 0.8736
54 AceticAcid 0.0003 0.0987 0.0165 0.0813 0.0000 0.0708
55 Total 0.0028 1.0000 0.2031 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
61 Overall Vapour Phase Aqueous Phase
63 Temperature: (C) 87.06 87.06 87.06
64 Pressure: (kPa) 100.0 100.0 100.0
65 Molar Flow (kgmole/h) 3.216e-003 5.212e-009 3.216e-003
66 Mass Flow (kg/h) 0.1072 1.928e-007 0.1072
67 Std Ideal Liq Vol Flow (m3/h) 1.128e-004 2.190e-010 1.128e-004
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
11 Overall Vapour Phase Aqueous Phase
13 Heat Flow (kJ/h) -1023 -1.376e-003 -1023
14 Liq Vol Flow @Std Cond (m3/h) 1.100e-004 * 2.119e-010 1.100e-004
15
16
COMPOSITION
17
18
21 Ethanol 0.0006 0.1874 0.0278 0.2590 0.0000 0.3093
22 H2O 0.0019 0.5833 0.0338 0.3153 0.0000 0.3002
23 E-Acetate 0.0000 0.0149 0.0042 0.0393 0.0000 0.0413
24 AceticAcid 0.0007 0.2145 0.0414 0.3864 0.0000 0.3493
25 Total 0.0032 1.0000 0.1072 1.0000 0.0001 1.0000
26
27
Vapour Phase Phase Fraction 1.621e-006
30 Ethanol 0.0000 0.3934 0.0000 0.4898 0.0000 0.5419
31 H2O 0.0000 0.4605 0.0000 0.2242 0.0000 0.1979
32 E-Acetate 0.0000 0.0643 0.0000 0.1532 0.0000 0.1491
33 AceticAcid 0.0000 0.0818 0.0000 0.1327 0.0000 0.1112
34 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
35
36
39 Ethanol 0.0006 0.1874 0.0278 0.2590 0.0000 0.3093
40 H2O 0.0019 0.5833 0.0338 0.3153 0.0000 0.3002
41 E-Acetate 0.0000 0.0149 0.0042 0.0393 0.0000 0.0413
42 AceticAcid 0.0007 0.2145 0.0414 0.3864 0.0000 0.3493
43 Total 0.0032 1.0000 0.1072 1.0000 0.0001 1.0000
44
46
47
48
CONDITIONS
51 Temperature: (C) 73.90 73.90 73.90
52 Pressure: (kPa) 100.0 100.0 100.0
54 Mass Flow (kg/h) 0.5077 0.0000 0.5077
58 Heat Flow (kJ/h) -3013 0.0000 -3013
60
61
COMPOSITION
62
63
66 Ethanol 0.0002 0.0261 0.0084 0.0165 0.0000 0.0190
67 H2O 0.0011 0.1612 0.0202 0.0398 0.0000 0.0366
68 E-Acetate 0.0050 0.7140 0.4378 0.8624 0.0005 0.8736
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
Overall Phase (continued) Vapour Fraction 0.0000
15 AceticAcid 0.0007 0.0987 0.0413 0.0813 0.0000 0.0708
16 Total 0.0070 1.0000 0.5077 1.0000 0.0006 1.0000
17
18
21 Ethanol 0.0000 0.0302 0.0000 0.0195 0.0000 0.0223
22 H2O 0.0000 0.2128 0.0000 0.0537 0.0000 0.0490
23 E-Acetate 0.0000 0.7362 0.0000 0.9092 0.0000 0.9136
24 AceticAcid 0.0000 0.0208 0.0000 0.0175 0.0000 0.0151
25 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
26
27
30 Ethanol 0.0002 0.0261 0.0084 0.0165 0.0000 0.0190
31 H2O 0.0011 0.1612 0.0202 0.0398 0.0000 0.0366
32 E-Acetate 0.0050 0.7140 0.4378 0.8624 0.0005 0.8736
33 AceticAcid 0.0007 0.0987 0.0413 0.0813 0.0000 0.0708
34 Total 0.0070 1.0000 0.5077 1.0000 0.0006 1.0000
35
37
38
39
CONDITIONS
42
44
45
46
CONDITIONS
49
50 Kinetic: Rxn-1
51
52
53
STOICHIOMETRY
55 Ethanol 46.07 -1 * 1.000 0.0000
56 AceticAcid 60.05 -1 * 1.000 0.0000
57 E-Acetate 88.11 1* 0.0000 1.000
58 H2O 18.02 1* 0.0000 1.000
59
61
62
BASIS
64 (C) (C)
66
67
68
1
2 LEGENDS
4 USA
5
6
7 Kinetic: Rxn-1 (continued)
8
9
10
PARAMETERS
12 A: 3317 * A' : 4619 *
13 E: 5.374e+004 * E' : 6.050e+004 *
14
16
17
CONNECTIONS
18
19 Inlet Stream
21 Q_R Reboiler
22 F0 1__Main TS
23 F1 17__Main TS
24 Outlet Stream
26 Q_C Condenser
27 F2 Condenser
28 F3 Reboiler
29
SOLVER
30
38 Trace Level: Low
42
43
44
SUMMARY
45
47 Feed Composition
48 F0 F1
50 --- ---
51 Ethanol 0.0000 0.9036
52 H2O 0.0000 0.0964
53 E-Acetate 0.0000 0.0000
54 AceticAcid 1.0000 0.0000
56 Feed Flows
57 F0 F1
59 --- ---
61 H2O (kgmole/h) 0.0000 0.0003
64 Products
67 F2 F3
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
12 --- ---
13 Ethanol 0.0261 0.1874
14 H2O 0.1612 0.5833
15 E-Acetate 0.7140 0.0149
16 AceticAcid 0.0987 0.2145
18 Product Flows
19 F2 F3
21 --- ---
22 Ethanol (kgmole/h) 0.0001 * 0.0006 *
23 H2O (kgmole/h) 0.0004 * 0.0019 *
28 F2 F3
30 --- ---
31 Ethanol (%) 2.6824 22.2314
32 H2O (%) 155.1958 648.6011
33 E-Acetate (%) 0.0000 0.0000
34 AceticAcid (%) 9.1607 22.9914
35
COLUMN PROFILES
36
41 Condenser 73.9 100 6.960e-003 --- --- 2.784e-003 332 *
42 1__Main TS 81.3 100 1.072e-002 9.744e-003 3.000e-003 --- ---
43 2__Main TS 81.2 100 1.071e-002 1.051e-002 --- --- ---
44 3__Main TS 81.2 100 1.068e-002 1.049e-002 --- --- ---
45 4__Main TS 81.1 100 1.065e-002 1.047e-002 --- --- ---
46 5__Main TS 81.1 100 1.062e-002 1.044e-002 --- --- ---
47 6__Main TS 81.0 100 1.058e-002 1.040e-002 --- --- ---
48 7__Main TS 80.9 100 1.052e-002 1.036e-002 --- --- ---
49 8__Main TS 80.8 100 1.045e-002 1.031e-002 --- --- ---
50 9__Main TS 80.6 100 1.036e-002 1.024e-002 --- --- ---
51 10__Main TS 80.4 100 1.024e-002 1.014e-002 --- --- ---
52 11__Main TS 80.1 100 1.007e-002 1.002e-002 --- --- ---
53 12__Main TS 79.7 100 9.854e-003 9.858e-003 --- --- ---
54 13__Main TS 79.3 100 9.563e-003 9.638e-003 --- --- ---
55 14__Main TS 79.0 100 9.189e-003 9.347e-003 --- --- ---
56 15__Main TS 78.9 100 8.740e-003 8.973e-003 --- --- ---
57 16__Main TS 79.3 100 8.273e-003 8.524e-003 --- --- ---
58 17__Main TS 79.9 100 1.157e-002 8.057e-003 3.000e-003 --- ---
59 Reboiler 87.1 100 --- 8.355e-003 --- 3.216e-003 326 *
63 Condenser 73.90 -4.329e+005 -3.889e+005 ---
64 1__Main TS 81.27 -4.371e+005 -3.987e+005 ---
65 2__Main TS 81.25 -4.359e+005 -3.975e+005 ---
66 3__Main TS 81.20 -4.346e+005 -3.962e+005 ---
67 4__Main TS 81.15 -4.331e+005 -3.948e+005 ---
68 5__Main TS 81.08 -4.314e+005 -3.932e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 6__Main TS 81.00 -4.295e+005 -3.913e+005 ---
14 7__Main TS 80.90 -4.270e+005 -3.891e+005 ---
15 8__Main TS 80.77 -4.241e+005 -3.865e+005 ---
16 9__Main TS 80.59 -4.203e+005 -3.832e+005 ---
17 10__Main TS 80.37 -4.154e+005 -3.789e+005 ---
18 11__Main TS 80.07 -4.089e+005 -3.734e+005 ---
19 12__Main TS 79.71 -4.002e+005 -3.661e+005 ---
20 13__Main TS 79.31 -3.883e+005 -3.562e+005 ---
21 14__Main TS 78.98 -3.721e+005 -3.427e+005 ---
22 15__Main TS 78.91 -3.510e+005 -3.241e+005 ---
23 16__Main TS 79.27 -3.273e+005 -3.000e+005 ---
24 17__Main TS 79.93 -3.072e+005 -2.727e+005 ---
25 Reboiler 87.06 -3.182e+005 -2.640e+005 ---
26
FEEDS / PRODUCTS
27
31 Q_C Energy 3.3e+002 * --- --- ---
Condenser
32 F2 Draw --- Liquid 2.78e-003 * -4.3e+005 * 73.90*
34 2__Main TS
35 3__Main TS
36 4__Main TS
37 5__Main TS
38 6__Main TS
39 7__Main TS
40 8__Main TS
41 9__Main TS
42 10__Main TS
43 11__Main TS
44 12__Main TS
45 13__Main TS
46 14__Main TS
47 15__Main TS
48 16__Main TS
50 Q_R Energy 3.3e+002 * --- --- ---
Reboiler
51 F3 Draw --- Liquid 3.22e-003 * -3.2e+005 * 87.06*
52
SETUP
53
54 Sub-Flowsheet
57 F0 F0 P-H Flash
58 F1 F1 P-H Flash
61 F2 F2 P-H Flash
62 F3 F3 P-H Flash
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 88.0 105
14
104
15 86.0
16 103
17 84.0
18 102
Temperature (C)
Pressure (kPa)
19 82.0
101
20
21 80.0 100
22
23 99.0
78.0
24
98.0
25
76.0
26 97.0
27
74.0
28 96.0
29
72.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.20e-002 910 75.0
37
Liquid Mol Weight(Light) 70.0
38 900
1.00e-002
39
65.0
40
890
41
Density (kg/m3)
8.00e-003 60.0
42
43 880 55.0
44 6.00e-003
45 50.0
870
46
47 4.00e-003 45.0
48 860
49 40.0
50 2.00e-003
850
51 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 4.50
14
0.700 H2O (Light) 4.00 H2O
15
16
17 0.600
18
3.00
Mole Fraction
19 0.500
K Value
20 2.50
21 0.400
22 2.00
23
0.300
24 1.50
25
0.200
26 1.00
27
1.00e-001 0.500
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.3603 0.3603
20 Heat Flow (kJ/h) -2766 -2766
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0060 * 1.0000 * 0.3603 * 1.0000 * 0.0003 * 1.0000 *
32 Total 0.0060 1.0000 0.3603 1.0000 0.0003 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0060 1.0000 0.3603 1.0000 0.0003 1.0000
41 Total 0.0060 1.0000 0.3603 1.0000 0.0003 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 75.03 75.03
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2732 0.2732
34 Heat Flow (kJ/h) -1737 -1737
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0247 0.0047 0.0174 0.0000 0.0202
43 H2O 0.0010 0.2470 0.0186 0.0680 0.0000 0.0632
44 E-Acetate 0.0024 0.5736 0.2110 0.7725 0.0002 0.7914
45 AceticAcid 0.0006 0.1548 0.0388 0.1421 0.0000 0.1252
46 Total 0.0042 1.0000 0.2732 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0247 0.0047 0.0174 0.0000 0.0202
52 H2O 0.0010 0.2470 0.0186 0.0680 0.0000 0.0632
53 E-Acetate 0.0024 0.5736 0.2110 0.7725 0.0002 0.7914
54 AceticAcid 0.0006 0.1548 0.0388 0.1421 0.0000 0.1252
55 Total 0.0042 1.0000 0.2732 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 101.0 101.0
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.2172 0.2172
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1860 -1860
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0365 0.0081 0.0373 0.0000 0.0483
22 H2O 0.0017 0.3502 0.0304 0.1401 0.0000 0.1444
23 E-Acetate 0.0000 0.0076 0.0032 0.0149 0.0000 0.0169
24 AceticAcid 0.0029 0.6057 0.1755 0.8077 0.0002 0.7904
25 Total 0.0048 1.0000 0.2172 1.0000 0.0002 1.0000
26
27
30 Ethanol 0.0002 0.0365 0.0081 0.0373 0.0000 0.0483
31 H2O 0.0017 0.3502 0.0304 0.1401 0.0000 0.1444
32 E-Acetate 0.0000 0.0076 0.0032 0.0149 0.0000 0.0169
33 AceticAcid 0.0029 0.6057 0.1755 0.8077 0.0002 0.7904
34 Total 0.0048 1.0000 0.2172 1.0000 0.0002 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 75.03 75.03 75.03
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.6829 0.0000 0.6829
49 Heat Flow (kJ/h) -4343 0.0000 -4343
51
52
COMPOSITION
53
54
57 Ethanol 0.0003 0.0247 0.0119 0.0174 0.0000 0.0202
58 H2O 0.0026 0.2470 0.0465 0.0680 0.0000 0.0632
59 E-Acetate 0.0060 0.5736 0.5276 0.7725 0.0006 0.7914
60 AceticAcid 0.0016 0.1548 0.0970 0.1421 0.0001 0.1252
61 Total 0.0104 1.0000 0.6829 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0276 0.0000 0.0185 0.0000 0.0212
67 H2O 0.0000 0.2478 0.0000 0.0650 0.0000 0.0593
68 E-Acetate 0.0000 0.6936 0.0000 0.8894 0.0000 0.8959
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0311 0.0000 0.0272 0.0000 0.0235
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0003 0.0247 0.0119 0.0174 0.0000 0.0202
22 H2O 0.0026 0.2470 0.0465 0.0680 0.0000 0.0632
23 E-Acetate 0.0060 0.5736 0.5276 0.7725 0.0006 0.7914
24 AceticAcid 0.0016 0.1548 0.0970 0.1421 0.0001 0.1252
25 Total 0.0104 1.0000 0.6829 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0247 0.0365
59 H2O 0.2470 0.3502
60 E-Acetate 0.5736 0.0076
61 AceticAcid 0.1548 0.6057
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0002 *
68 H2O (kgmole/h) 0.0010 * 0.0017 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 3.7980 6.4929
20 H2O (%) 356.6980 584.1620
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 10.7710 48.6984
23
COLUMN PROFILES
24
29 Condenser 75.0 100 1.044e-002 --- --- 4.176e-003 507 *
30 1__Main TS 86.0 100 1.784e-002 1.462e-002 6.000e-003 --- ---
31 2__Main TS 88.7 100 1.779e-002 1.602e-002 --- --- ---
32 3__Main TS 91.8 100 1.780e-002 1.596e-002 --- --- ---
33 4__Main TS 94.2 100 1.782e-002 1.597e-002 --- --- ---
34 5__Main TS 95.7 100 1.783e-002 1.599e-002 --- --- ---
35 6__Main TS 96.5 100 1.782e-002 1.601e-002 --- --- ---
36 7__Main TS 96.8 100 1.780e-002 1.600e-002 --- --- ---
37 8__Main TS 96.9 100 1.775e-002 1.597e-002 --- --- ---
38 9__Main TS 96.9 100 1.768e-002 1.593e-002 --- --- ---
39 10__Main TS 96.7 100 1.758e-002 1.586e-002 --- --- ---
40 11__Main TS 96.5 100 1.743e-002 1.576e-002 --- --- ---
41 12__Main TS 96.2 100 1.723e-002 1.561e-002 --- --- ---
42 13__Main TS 95.9 100 1.696e-002 1.541e-002 --- --- ---
43 14__Main TS 95.4 100 1.662e-002 1.514e-002 --- --- ---
44 15__Main TS 94.9 100 1.620e-002 1.479e-002 --- --- ---
45 16__Main TS 94.4 100 1.575e-002 1.437e-002 --- --- ---
46 17__Main TS 94.4 100 1.971e-002 1.393e-002 3.000e-003 --- ---
47 Reboiler 101.0 100 --- 1.488e-002 --- 4.824e-003 514 *
51 Condenser 75.03 -4.160e+005 -3.823e+005 ---
52 1__Main TS 86.00 -4.186e+005 -3.814e+005 ---
53 2__Main TS 88.71 -4.089e+005 -3.704e+005 ---
54 3__Main TS 91.76 -4.010e+005 -3.594e+005 ---
55 4__Main TS 94.21 -3.960e+005 -3.507e+005 ---
56 5__Main TS 95.72 -3.931e+005 -3.451e+005 ---
57 6__Main TS 96.48 -3.915e+005 -3.420e+005 ---
58 7__Main TS 96.81 -3.905e+005 -3.402e+005 ---
59 8__Main TS 96.90 -3.895e+005 -3.389e+005 ---
60 9__Main TS 96.87 -3.883e+005 -3.376e+005 ---
61 10__Main TS 96.74 -3.867e+005 -3.361e+005 ---
62 11__Main TS 96.53 -3.845e+005 -3.340e+005 ---
63 12__Main TS 96.24 -3.814e+005 -3.310e+005 ---
64 13__Main TS 95.87 -3.773e+005 -3.269e+005 ---
65 14__Main TS 95.41 -3.720e+005 -3.214e+005 ---
66 15__Main TS 94.89 -3.656e+005 -3.141e+005 ---
67 16__Main TS 94.43 -3.594e+005 -3.052e+005 ---
68 17__Main TS 94.41 -3.580e+005 -2.963e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 101.0 -3.855e+005 -3.146e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 5.1e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 4.18e-003 * -4.2e+005 * 75.03*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 5.1e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 4.82e-003 * -3.9e+005 * *
101.05
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 105 105
14
104
15
100
16 103
17
18 102
Temperature (C)
95.0
Pressure (kPa)
19
101
20
21 90.0 100
22
23 99.0
24 85.0
98.0
25
26 97.0
27 80.0
28 96.0
29
75.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 2.00e-002 940 70.0
37
38 930
65.0
39
1.60e-002
40 920
1.40e-002 60.0
41
Density (kg/m3)
42 910
1.20e-002
43 55.0
44 1.00e-002 900
45
50.0
46 8.00e-003
890
47
6.00e-003 45.0
48
880
49 4.00e-003
50 40.0
870
51 2.00e-003
52
0.000 860 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.00
14
15 0.600
16
17 3.00
0.500
18
Mole Fraction
19 2.50
K Value
20 0.400
21 2.00
22
0.300
23
1.50
24
25 0.200
1.00
26
27 1.00e-001 0.500
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.9008 0.9008
20 Heat Flow (kJ/h) -6915 -6915
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0150 * 1.0000 * 0.9008 * 1.0000 * 0.0009 * 1.0000 *
32 Total 0.0150 1.0000 0.9008 1.0000 0.0009 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0150 1.0000 0.9008 1.0000 0.0009 1.0000
41 Total 0.0150 1.0000 0.9008 1.0000 0.0009 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 82.45 82.45
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.4557 0.4557
34 Heat Flow (kJ/h) -3338 -3338
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0079 0.0030 0.0066 0.0000 0.0080
43 H2O 0.0028 0.3323 0.0500 0.1097 0.0001 0.1062
44 E-Acetate 0.0026 0.3060 0.2252 0.4941 0.0002 0.5277
45 AceticAcid 0.0030 0.3539 0.1775 0.3895 0.0002 0.3580
46 Total 0.0084 1.0000 0.4557 1.0000 0.0005 1.0000
47
48
51 Ethanol 0.0001 0.0079 0.0030 0.0066 0.0000 0.0080
52 H2O 0.0028 0.3323 0.0500 0.1097 0.0001 0.1062
53 E-Acetate 0.0026 0.3060 0.2252 0.4941 0.0002 0.5277
54 AceticAcid 0.0030 0.3539 0.1775 0.3895 0.0002 0.3580
55 Total 0.0084 1.0000 0.4557 1.0000 0.0005 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 115.9 115.9
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.5752 0.5752
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -4330 -4330
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0063 0.0028 0.0049 0.0000 0.0064
22 H2O 0.0001 0.0102 0.0018 0.0031 0.0000 0.0032
23 E-Acetate 0.0000 0.0030 0.0025 0.0044 0.0000 0.0051
24 AceticAcid 0.0095 0.9805 0.5681 0.9877 0.0005 0.9852
25 Total 0.0096 1.0000 0.5752 1.0000 0.0005 1.0000
26
27
30 Ethanol 0.0001 0.0063 0.0028 0.0049 0.0000 0.0064
31 H2O 0.0001 0.0102 0.0018 0.0031 0.0000 0.0032
32 E-Acetate 0.0000 0.0030 0.0025 0.0044 0.0000 0.0051
33 AceticAcid 0.0095 0.9805 0.5681 0.9877 0.0005 0.9852
34 Total 0.0096 1.0000 0.5752 1.0000 0.0005 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 82.45 82.45 82.45
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 1.139 0.0000 1.139
49 Heat Flow (kJ/h) -8345 0.0000 -8345
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0079 0.0076 0.0066 0.0000 0.0080
58 H2O 0.0069 0.3323 0.1250 0.1097 0.0001 0.1062
59 E-Acetate 0.0064 0.3060 0.5629 0.4941 0.0006 0.5277
60 AceticAcid 0.0074 0.3539 0.4437 0.3895 0.0004 0.3580
61 Total 0.0209 1.0000 1.1392 1.0000 0.0012 1.0000
62
63
66 Ethanol 0.0000 0.0106 0.0000 0.0077 0.0000 0.0089
67 H2O 0.0000 0.3048 0.0000 0.0865 0.0000 0.0800
68 E-Acetate 0.0000 0.5843 0.0000 0.8109 0.0000 0.8277
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.1003 0.0000 0.0949 0.0000 0.0834
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0079 0.0076 0.0066 0.0000 0.0080
22 H2O 0.0069 0.3323 0.1250 0.1097 0.0001 0.1062
23 E-Acetate 0.0064 0.3060 0.5629 0.4941 0.0006 0.5277
24 AceticAcid 0.0074 0.3539 0.4437 0.3895 0.0004 0.3580
25 Total 0.0209 1.0000 1.1392 1.0000 0.0012 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
39 Duty SP: 1069 kJ/h Minimum Available Duty: --- Maximum Available Duty: ---
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0079 0.0063
59 H2O 0.3323 0.0102
60 E-Acetate 0.3060 0.0030
61 AceticAcid 0.3539 0.9805
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0001 *
68 H2O (kgmole/h) 0.0028 * 0.0001 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.4189 2.2474
20 H2O (%) 959.6081 33.9721
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 19.7039 63.0674
23
COLUMN PROFILES
24
29 Condenser 82.4 100 2.088e-002 --- --- 8.352e-003 983 *
30 1__Main TS 97.9 100 4.088e-002 2.923e-002 1.500e-002 --- ---
31 2__Main TS 102.0 100 4.211e-002 3.423e-002 --- --- ---
32 3__Main TS 104.8 100 4.343e-002 3.547e-002 --- --- ---
33 4__Main TS 106.9 100 4.471e-002 3.678e-002 --- --- ---
34 5__Main TS 108.6 100 4.581e-002 3.806e-002 --- --- ---
35 6__Main TS 109.8 100 4.665e-002 3.916e-002 --- --- ---
36 7__Main TS 110.7 100 4.722e-002 4.000e-002 --- --- ---
37 8__Main TS 111.2 100 4.759e-002 4.057e-002 --- --- ---
38 9__Main TS 111.6 100 4.781e-002 4.094e-002 --- --- ---
39 10__Main TS 111.8 100 4.793e-002 4.116e-002 --- --- ---
40 11__Main TS 112.0 100 4.799e-002 4.128e-002 --- --- ---
41 12__Main TS 112.1 100 4.801e-002 4.134e-002 --- --- ---
42 13__Main TS 112.2 100 4.798e-002 4.136e-002 --- --- ---
43 14__Main TS 112.4 100 4.792e-002 4.134e-002 --- --- ---
44 15__Main TS 112.6 100 4.781e-002 4.128e-002 --- --- ---
45 16__Main TS 112.9 100 4.762e-002 4.117e-002 --- --- ---
46 17__Main TS 113.4 100 5.327e-002 4.098e-002 3.000e-003 --- ---
47 Reboiler 115.9 100 --- 4.362e-002 --- 9.648e-003 1.07e+003 *
51 Condenser 82.45 -3.997e+005 -3.735e+005 ---
52 1__Main TS 97.92 -4.153e+005 -3.660e+005 ---
53 2__Main TS 102.0 -4.174e+005 -3.628e+005 ---
54 3__Main TS 104.8 -4.226e+005 -3.670e+005 ---
55 4__Main TS 106.9 -4.286e+005 -3.751e+005 ---
56 5__Main TS 108.6 -4.337e+005 -3.836e+005 ---
57 6__Main TS 109.8 -4.374e+005 -3.909e+005 ---
58 7__Main TS 110.7 -4.399e+005 -3.961e+005 ---
59 8__Main TS 111.2 -4.415e+005 -3.996e+005 ---
60 9__Main TS 111.6 -4.424e+005 -4.018e+005 ---
61 10__Main TS 111.8 -4.429e+005 -4.030e+005 ---
62 11__Main TS 112.0 -4.433e+005 -4.038e+005 ---
63 12__Main TS 112.1 -4.435e+005 -4.042e+005 ---
64 13__Main TS 112.2 -4.436e+005 -4.045e+005 ---
65 14__Main TS 112.4 -4.437e+005 -4.046e+005 ---
66 15__Main TS 112.6 -4.439e+005 -4.047e+005 ---
67 16__Main TS 112.9 -4.440e+005 -4.048e+005 ---
68 17__Main TS 113.4 -4.443e+005 -4.048e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 115.9 -4.488e+005 -4.188e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 9.8e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 8.35e-003 * -4.0e+005 * 82.45*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.1e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 9.65e-003 * -4.5e+005 * *
115.94
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 120 105
14
104
15 115
16 103
17 110
18 102
Temperature (C)
Pressure (kPa)
19 105
101
20
21 100 100
22
23 99.0
95.0
24
98.0
25
90.0
26 97.0
27
85.0
28 96.0
29
80.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 6.00e-002 945 60.0
37
Liquid 940 Mol Weight(Light)
38 59.0
5.00e-002
39
935
40
58.0
41
Density (kg/m3)
4.00e-002 930
42
43 925 57.0
44 3.00e-002
45 920 56.0
46
47 2.00e-002 915
48 55.0
49 910
50 1.00e-002
54.0
51 905
52
0.000 900 53.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 1.00 4.50
14
0.900 H2O (Light) 4.00 H2O
15
16 0.800
17
18 0.700
3.00
Mole Fraction
19
0.600
K Value
20 2.50
21 0.500
22 2.00
23 0.400
24 1.50
0.300
25
26 1.00
0.200
27
28 1.00e-001 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 1.802 1.802
20 Heat Flow (kJ/h) -1.383e+004 -1.383e+004
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0300 * 1.0000 * 1.8016 * 1.0000 * 0.0017 * 1.0000 *
32 Total 0.0300 1.0000 1.8016 1.0000 0.0017 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0300 1.0000 1.8016 1.0000 0.0017 1.0000
41 Total 0.0300 1.0000 1.8016 1.0000 0.0017 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 94.82 94.82
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.8729 0.8729
34 Heat Flow (kJ/h) -6482 -6482
36
37
COMPOSITION
38
39
42 Ethanol 0.0000 0.0018 0.0013 0.0015 0.0000 0.0019
43 H2O 0.0028 0.1846 0.0509 0.0583 0.0001 0.0588
44 E-Acetate 0.0026 0.1692 0.2282 0.2614 0.0003 0.2905
45 AceticAcid 0.0099 0.6444 0.5925 0.6788 0.0006 0.6489
46 Total 0.0153 1.0000 0.8729 1.0000 0.0009 1.0000
47
48
51 Ethanol 0.0000 0.0018 0.0013 0.0015 0.0000 0.0019
52 H2O 0.0028 0.1846 0.0509 0.0583 0.0001 0.0588
53 E-Acetate 0.0026 0.1692 0.2282 0.2614 0.0003 0.2905
54 AceticAcid 0.0099 0.6444 0.5925 0.6788 0.0006 0.6489
55 Total 0.0153 1.0000 0.8729 1.0000 0.0009 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 116.7 116.7
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 1.059 1.059
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -7964 -7964
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0041 0.0033 0.0031 0.0000 0.0041
22 H2O 0.0001 0.0042 0.0013 0.0013 0.0000 0.0013
23 E-Acetate 0.0000 0.0012 0.0019 0.0018 0.0000 0.0021
24 AceticAcid 0.0175 0.9906 1.0523 0.9938 0.0010 0.9925
25 Total 0.0177 1.0000 1.0588 1.0000 0.0010 1.0000
26
27
30 Ethanol 0.0001 0.0041 0.0033 0.0031 0.0000 0.0041
31 H2O 0.0001 0.0042 0.0013 0.0013 0.0000 0.0013
32 E-Acetate 0.0000 0.0012 0.0019 0.0018 0.0000 0.0021
33 AceticAcid 0.0175 0.9906 1.0523 0.9938 0.0010 0.9925
34 Total 0.0177 1.0000 1.0588 1.0000 0.0010 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 94.82 94.82 94.82
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 2.182 0.0000 2.182
49 Heat Flow (kJ/h) -1.621e+004 0.0000 -1.621e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0001 0.0018 0.0032 0.0015 0.0000 0.0019
58 H2O 0.0071 0.1846 0.1273 0.0583 0.0001 0.0588
59 E-Acetate 0.0065 0.1692 0.5705 0.2614 0.0006 0.2905
60 AceticAcid 0.0247 0.6444 1.4811 0.6788 0.0014 0.6489
61 Total 0.0383 1.0000 2.1821 1.0000 0.0022 1.0000
62
63
66 Ethanol 0.0000 0.0032 0.0000 0.0025 0.0000 0.0029
67 H2O 0.0000 0.2681 0.0000 0.0796 0.0000 0.0758
68 E-Acetate 0.0000 0.4266 0.0000 0.6191 0.0000 0.6509
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.3021 0.0000 0.2988 0.0000 0.2703
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0001 0.0018 0.0032 0.0015 0.0000 0.0019
22 H2O 0.0071 0.1846 0.1273 0.0583 0.0001 0.0588
23 E-Acetate 0.0065 0.1692 0.5705 0.2614 0.0006 0.2905
24 AceticAcid 0.0247 0.6444 1.4811 0.6788 0.0014 0.6489
25 Total 0.0383 1.0000 2.1821 1.0000 0.0022 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0018 0.0041
59 H2O 0.1846 0.0042
60 E-Acetate 0.1692 0.0012
61 AceticAcid 0.6444 0.9906
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0000 * 0.0001 *
68 H2O (kgmole/h) 0.0028 * 0.0001 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 1.0246 2.6434
20 H2O (%) 977.3293 25.6079
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 32.8859 58.4095
23
COLUMN PROFILES
24
29 Condenser 94.8 100 3.828e-002 --- --- 1.531e-002 1.57e+003 *
30 1__Main TS 108.0 100 8.163e-002 5.358e-002 3.000e-002 --- ---
31 2__Main TS 111.3 100 8.430e-002 6.694e-002 --- --- ---
32 3__Main TS 113.0 100 8.581e-002 6.961e-002 --- --- ---
33 4__Main TS 113.8 100 8.660e-002 7.112e-002 --- --- ---
34 5__Main TS 114.2 100 8.700e-002 7.191e-002 --- --- ---
35 6__Main TS 114.3 100 8.719e-002 7.231e-002 --- --- ---
36 7__Main TS 114.4 100 8.728e-002 7.250e-002 --- --- ---
37 8__Main TS 114.5 100 8.731e-002 7.259e-002 --- --- ---
38 9__Main TS 114.5 100 8.732e-002 7.262e-002 --- --- ---
39 10__Main TS 114.6 100 8.731e-002 7.263e-002 --- --- ---
40 11__Main TS 114.6 100 8.729e-002 7.262e-002 --- --- ---
41 12__Main TS 114.7 100 8.725e-002 7.260e-002 --- --- ---
42 13__Main TS 114.7 100 8.719e-002 7.256e-002 --- --- ---
43 14__Main TS 114.8 100 8.711e-002 7.250e-002 --- --- ---
44 15__Main TS 115.0 100 8.700e-002 7.242e-002 --- --- ---
45 16__Main TS 115.1 100 8.685e-002 7.232e-002 --- --- ---
46 17__Main TS 115.4 100 9.274e-002 7.216e-002 3.000e-003 --- ---
47 Reboiler 116.7 100 --- 7.505e-002 --- 1.769e-002 1.79e+003 *
51 Condenser 94.82 -4.234e+005 -3.801e+005 ---
52 1__Main TS 108.0 -4.384e+005 -3.941e+005 ---
53 2__Main TS 111.3 -4.422e+005 -4.014e+005 ---
54 3__Main TS 113.0 -4.447e+005 -4.074e+005 ---
55 4__Main TS 113.8 -4.461e+005 -4.111e+005 ---
56 5__Main TS 114.2 -4.468e+005 -4.132e+005 ---
57 6__Main TS 114.3 -4.472e+005 -4.142e+005 ---
58 7__Main TS 114.4 -4.474e+005 -4.148e+005 ---
59 8__Main TS 114.5 -4.475e+005 -4.150e+005 ---
60 9__Main TS 114.5 -4.475e+005 -4.152e+005 ---
61 10__Main TS 114.6 -4.476e+005 -4.152e+005 ---
62 11__Main TS 114.6 -4.476e+005 -4.153e+005 ---
63 12__Main TS 114.7 -4.476e+005 -4.153e+005 ---
64 13__Main TS 114.7 -4.476e+005 -4.153e+005 ---
65 14__Main TS 114.8 -4.477e+005 -4.153e+005 ---
66 15__Main TS 115.0 -4.477e+005 -4.153e+005 ---
67 16__Main TS 115.1 -4.477e+005 -4.153e+005 ---
68 17__Main TS 115.4 -4.478e+005 -4.153e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 116.7 -4.502e+005 -4.233e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 1.6e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 1.53e-002 * -4.2e+005 * 94.82*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.8e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 1.77e-002 * -4.5e+005 * *
116.66
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 120 105
14
104
15
115
16 103
17
18 102
Temperature (C)
110
Pressure (kPa)
19
101
20
21 105 100
22
23 99.0
24 100
98.0
25
26 97.0
27 95.0
28 96.0
29
90.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 0.100 946 60.0
37
9.00e-002 Liquid 944 Mol Weight(Light)
38
59.5
39
8.00e-002 942
40
41 7.00e-002 940
Density (kg/m3)
59.0
42
6.00e-002 938
43
44 5.00e-002 936 58.5
45
46 4.00e-002 934
47 58.0
3.00e-002 932
48
49 2.00e-002 930
50 57.5
51 1.00e-002 928
52
0.000 926 57.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 1.00 4.50
14
0.900 H2O (Light) 4.00 H2O
15
16 0.800
17
18 0.700
3.00
Mole Fraction
19
0.600
K Value
20 2.50
21 0.500
22 2.00
23 0.400
24 1.50
0.300
25
26 1.00
0.200
27
28 1.00e-001 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B7:
EFFECT OF
REFLUX RATIO
1
Case Name: R = 0.5.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 83.83 83.83
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2141 0.2141
34 Heat Flow (kJ/h) -1413 -1413
36
37
COMPOSITION
38
39
42 Ethanol 0.0000 0.0050 0.0008 0.0035 0.0000 0.0043
43 H2O 0.0005 0.1425 0.0083 0.0390 0.0000 0.0375
44 E-Acetate 0.0014 0.4241 0.1214 0.5671 0.0001 0.6018
45 AceticAcid 0.0014 0.4283 0.0836 0.3904 0.0001 0.3565
46 Total 0.0033 1.0000 0.2141 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0000 0.0050 0.0008 0.0035 0.0000 0.0043
52 H2O 0.0005 0.1425 0.0083 0.0390 0.0000 0.0375
53 E-Acetate 0.0014 0.4241 0.1214 0.5671 0.0001 0.6018
54 AceticAcid 0.0014 0.4283 0.0836 0.3904 0.0001 0.3565
55 Total 0.0032 1.0000 0.2141 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 82.99 82.99
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1502 0.1502
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1212 -1212
15
16
COMPOSITION
17
18
21 Ethanol 0.0011 0.2957 0.0497 0.3312 0.0001 0.3844
22 H2O 0.0014 0.3948 0.0260 0.1729 0.0000 0.1601
23 E-Acetate 0.0002 0.0649 0.0209 0.1389 0.0000 0.1418
24 AceticAcid 0.0009 0.2446 0.0536 0.3571 0.0001 0.3137
25 Total 0.0036 1.0000 0.1502 1.0000 0.0002 1.0000
26
27
30 Ethanol 0.0011 0.2957 0.0497 0.3312 0.0001 0.3844
31 H2O 0.0014 0.3948 0.0260 0.1729 0.0000 0.1601
32 E-Acetate 0.0002 0.0649 0.0209 0.1389 0.0000 0.1418
33 AceticAcid 0.0009 0.2446 0.0536 0.3571 0.0001 0.3137
34 Total 0.0036 1.0000 0.1502 1.0000 0.0002 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 83.83 83.83 83.83
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.1071 0.0000 0.1071
49 Heat Flow (kJ/h) -706.4 0.0000 -706.4
51
52
COMPOSITION
53
54
57 Ethanol 0.0000 0.0050 0.0004 0.0035 0.0000 0.0043
58 H2O 0.0002 0.1425 0.0042 0.0390 0.0000 0.0375
59 E-Acetate 0.0007 0.4241 0.0607 0.5671 0.0001 0.6018
60 AceticAcid 0.0007 0.4283 0.0418 0.3904 0.0000 0.3565
61 Total 0.0016 1.0000 0.1071 1.0000 0.0001 1.0000
62
63
66 Ethanol 0.0000 0.0063 0.0000 0.0041 0.0000 0.0047
67 H2O 0.0000 0.1850 0.0000 0.0468 0.0000 0.0433
68 E-Acetate 0.0000 0.6768 0.0000 0.8378 0.0000 0.8543
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.1320 0.0000 0.1114 0.0000 0.0977
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0000 0.0050 0.0004 0.0035 0.0000 0.0043
22 H2O 0.0002 0.1425 0.0042 0.0390 0.0000 0.0375
23 E-Acetate 0.0007 0.4241 0.0607 0.5671 0.0001 0.6018
24 AceticAcid 0.0007 0.4283 0.0418 0.3904 0.0000 0.3565
25 Total 0.0016 1.0000 0.1071 1.0000 0.0001 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0050 0.2957
59 H2O 0.1425 0.3948
60 E-Acetate 0.4241 0.0649
61 AceticAcid 0.4283 0.2446
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0000 * 0.0011 *
68 H2O (kgmole/h) 0.0005 * 0.0014 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 0.6043 39.8182
20 H2O (%) 160.1572 498.2738
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 35.6957 22.8933
23
COLUMN PROFILES
24
29 Condenser 83.8 100 1.625e-003 --- --- 3.250e-003 153 *
30 1__Main TS 99.8 100 6.616e-003 4.875e-003 3.900e-003 --- ---
31 2__Main TS 99.8 100 6.580e-003 5.966e-003 --- --- ---
32 3__Main TS 99.6 100 6.545e-003 5.930e-003 --- --- ---
33 4__Main TS 99.2 100 6.511e-003 5.895e-003 --- --- ---
34 5__Main TS 98.9 100 6.476e-003 5.861e-003 --- --- ---
35 6__Main TS 98.4 100 6.440e-003 5.826e-003 --- --- ---
36 7__Main TS 97.9 100 6.402e-003 5.790e-003 --- --- ---
37 8__Main TS 97.4 100 6.360e-003 5.752e-003 --- --- ---
38 9__Main TS 96.7 100 6.311e-003 5.710e-003 --- --- ---
39 10__Main TS 96.0 100 6.252e-003 5.661e-003 --- --- ---
40 11__Main TS 95.0 100 6.175e-003 5.602e-003 --- --- ---
41 12__Main TS 93.8 100 6.069e-003 5.525e-003 --- --- ---
42 13__Main TS 92.2 100 5.910e-003 5.419e-003 --- --- ---
43 14__Main TS 90.1 100 5.661e-003 5.260e-003 --- --- ---
44 15__Main TS 87.2 100 5.277e-003 5.011e-003 --- --- ---
45 16__Main TS 83.2 100 4.752e-003 4.627e-003 --- --- ---
46 17__Main TS 77.9 100 7.958e-003 4.103e-003 3.000e-003 --- ---
47 Reboiler 83.0 100 --- 4.308e-003 --- 3.650e-003 165 *
51 Condenser 83.83 -4.347e+005 -3.977e+005 ---
52 1__Main TS 99.84 -4.414e+005 -4.033e+005 ---
53 2__Main TS 99.79 -4.392e+005 -3.993e+005 ---
54 3__Main TS 99.57 -4.375e+005 -3.965e+005 ---
55 4__Main TS 99.24 -4.362e+005 -3.944e+005 ---
56 5__Main TS 98.85 -4.349e+005 -3.927e+005 ---
57 6__Main TS 98.41 -4.338e+005 -3.911e+005 ---
58 7__Main TS 97.91 -4.326e+005 -3.895e+005 ---
59 8__Main TS 97.36 -4.312e+005 -3.878e+005 ---
60 9__Main TS 96.72 -4.296e+005 -3.860e+005 ---
61 10__Main TS 95.96 -4.276e+005 -3.838e+005 ---
62 11__Main TS 95.02 -4.250e+005 -3.811e+005 ---
63 12__Main TS 93.82 -4.214e+005 -3.776e+005 ---
64 13__Main TS 92.23 -4.158e+005 -3.726e+005 ---
65 14__Main TS 90.08 -4.069e+005 -3.649e+005 ---
66 15__Main TS 87.16 -3.920e+005 -3.522e+005 ---
67 16__Main TS 83.22 -3.675e+005 -3.307e+005 ---
68 17__Main TS 77.89 -3.260e+005 -2.945e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 82.99 -3.320e+005 -2.826e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 1.5e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 83.83*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.3e+005 * 82.99*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
16 95.0 103
17
18 102
Temperature (C)
Pressure (kPa)
19
90.0 101
20
21 100
22
23 85.0 99.0
24
98.0
25
26 80.0 97.0
27
28 96.0
29
75.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 8.00e-003 930 70.0
37
7.00e-003 Liquid 920 Mol Weight(Light)
38
65.0
39
910
40 6.00e-003
41
Density (kg/m3)
900 60.0
42 5.00e-003
43 890
44 4.00e-003 55.0
45 880
46
3.00e-003
47 870 50.0
48
2.00e-003
49 860
50 45.0
1.00e-003 850
51
52
0.000 840 40.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 3.00
14
15
16
17 0.600
18
2.00
Mole Fraction
19 0.500
K Value
20
21 0.400 1.50
22
23
0.300
24 1.00
25
0.200
26
27 0.500
1.00e-001
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: R = 1.HSC
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 78.55 78.55
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2215 0.2215
34 Heat Flow (kJ/h) -1402 -1402
36
37
COMPOSITION
38
39
42 Ethanol 0.0000 0.0105 0.0016 0.0071 0.0000 0.0083
43 H2O 0.0006 0.1695 0.0099 0.0448 0.0000 0.0422
44 E-Acetate 0.0018 0.5485 0.1571 0.7089 0.0002 0.7358
45 AceticAcid 0.0009 0.2715 0.0530 0.2392 0.0001 0.2136
46 Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0000 0.0105 0.0016 0.0071 0.0000 0.0083
52 H2O 0.0006 0.1695 0.0099 0.0448 0.0000 0.0422
53 E-Acetate 0.0018 0.5485 0.1571 0.7089 0.0002 0.7358
54 AceticAcid 0.0009 0.2715 0.0530 0.2392 0.0001 0.2136
55 Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 86.95 86.95
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1428 0.1428
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1231 -1231
15
16
COMPOSITION
17
18
21 Ethanol 0.0008 0.2055 0.0346 0.2421 0.0000 0.2898
22 H2O 0.0017 0.4561 0.0300 0.2101 0.0000 0.2006
23 E-Acetate 0.0001 0.0395 0.0127 0.0890 0.0000 0.0937
24 AceticAcid 0.0011 0.2989 0.0655 0.4589 0.0001 0.4159
25 Total 0.0036 1.0000 0.1428 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0008 0.2055 0.0346 0.2421 0.0000 0.2898
31 H2O 0.0017 0.4561 0.0300 0.2101 0.0000 0.2006
32 E-Acetate 0.0001 0.0395 0.0127 0.0890 0.0000 0.0937
33 AceticAcid 0.0011 0.2989 0.0655 0.4589 0.0001 0.4159
34 Total 0.0036 1.0000 0.1428 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 78.55 78.55 78.55
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.2215 0.0000 0.2215
49 Heat Flow (kJ/h) -1402 0.0000 -1402
51
52
COMPOSITION
53
54
57 Ethanol 0.0000 0.0105 0.0016 0.0071 0.0000 0.0083
58 H2O 0.0006 0.1695 0.0099 0.0448 0.0000 0.0422
59 E-Acetate 0.0018 0.5485 0.1571 0.7089 0.0002 0.7358
60 AceticAcid 0.0009 0.2715 0.0530 0.2392 0.0001 0.2136
61 Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000
62
63
66 Ethanol 0.0000 0.0118 0.0000 0.0076 0.0000 0.0087
67 H2O 0.0000 0.2039 0.0000 0.0514 0.0000 0.0472
68 E-Acetate 0.0000 0.7171 0.0000 0.8845 0.0000 0.8949
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0672 0.0000 0.0565 0.0000 0.0492
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0000 0.0105 0.0016 0.0071 0.0000 0.0083
22 H2O 0.0006 0.1695 0.0099 0.0448 0.0000 0.0422
23 E-Acetate 0.0018 0.5485 0.1571 0.7089 0.0002 0.7358
24 AceticAcid 0.0009 0.2715 0.0530 0.2392 0.0001 0.2136
25 Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0105 0.2055
59 H2O 0.1695 0.4561
60 E-Acetate 0.5485 0.0395
61 AceticAcid 0.2715 0.2989
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0000 * 0.0008 *
68 H2O (kgmole/h) 0.0006 * 0.0017 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 1.2540 27.6714
20 H2O (%) 190.5363 575.6589
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 22.6261 27.9716
23
COLUMN PROFILES
24
29 Condenser 78.6 100 3.250e-003 --- --- 3.250e-003 215 *
30 1__Main TS 92.6 100 8.178e-003 6.500e-003 3.900e-003 --- ---
31 2__Main TS 93.3 100 8.158e-003 7.528e-003 --- --- ---
32 3__Main TS 93.8 100 8.142e-003 7.508e-003 --- --- ---
33 4__Main TS 94.3 100 8.128e-003 7.492e-003 --- --- ---
34 5__Main TS 94.5 100 8.112e-003 7.478e-003 --- --- ---
35 6__Main TS 94.7 100 8.092e-003 7.462e-003 --- --- ---
36 7__Main TS 94.6 100 8.067e-003 7.442e-003 --- --- ---
37 8__Main TS 94.5 100 8.034e-003 7.417e-003 --- --- ---
38 9__Main TS 94.2 100 7.989e-003 7.384e-003 --- --- ---
39 10__Main TS 93.7 100 7.926e-003 7.339e-003 --- --- ---
40 11__Main TS 93.1 100 7.835e-003 7.276e-003 --- --- ---
41 12__Main TS 92.2 100 7.699e-003 7.185e-003 --- --- ---
42 13__Main TS 90.9 100 7.493e-003 7.049e-003 --- --- ---
43 14__Main TS 89.1 100 7.181e-003 6.843e-003 --- --- ---
44 15__Main TS 86.8 100 6.736e-003 6.531e-003 --- --- ---
45 16__Main TS 83.8 100 6.171e-003 6.086e-003 --- --- ---
46 17__Main TS 80.1 100 9.354e-003 5.521e-003 3.000e-003 --- ---
47 Reboiler 87.0 100 --- 5.704e-003 --- 3.650e-003 218 *
51 Condenser 78.55 -4.313e+005 -3.937e+005 ---
52 1__Main TS 92.56 -4.369e+005 -3.983e+005 ---
53 2__Main TS 93.25 -4.335e+005 -3.935e+005 ---
54 3__Main TS 93.83 -4.309e+005 -3.897e+005 ---
55 4__Main TS 94.26 -4.289e+005 -3.867e+005 ---
56 5__Main TS 94.53 -4.272e+005 -3.844e+005 ---
57 6__Main TS 94.65 -4.259e+005 -3.826e+005 ---
58 7__Main TS 94.64 -4.246e+005 -3.810e+005 ---
59 8__Main TS 94.49 -4.232e+005 -3.794e+005 ---
60 9__Main TS 94.20 -4.216e+005 -3.777e+005 ---
61 10__Main TS 93.74 -4.196e+005 -3.757e+005 ---
62 11__Main TS 93.08 -4.168e+005 -3.731e+005 ---
63 12__Main TS 92.16 -4.127e+005 -3.695e+005 ---
64 13__Main TS 90.87 -4.064e+005 -3.641e+005 ---
65 14__Main TS 89.12 -3.967e+005 -3.557e+005 ---
66 15__Main TS 86.81 -3.815e+005 -3.426e+005 ---
67 16__Main TS 83.84 -3.588e+005 -3.219e+005 ---
68 17__Main TS 80.09 -3.262e+005 -2.904e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 86.95 -3.373e+005 -2.809e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 2.1e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 78.55*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 2.2e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 86.95*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 96.0 105
14
94.0 104
15
16 103
92.0
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20 88.0
21 100
22 86.0
23 99.0
24 84.0
98.0
25
26 82.0
97.0
27
28 80.0 96.0
29
78.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.00e-002 930 70.0
37
38 920 65.0
39
8.00e-003
40
7.00e-003 910 60.0
41
Density (kg/m3)
42
6.00e-003
43 900 55.0
44 5.00e-003
45
890 50.0
46 4.00e-003
47
3.00e-003 880 45.0
48
49 2.00e-003
50 870 40.0
51 1.00e-003
52
0.000 860 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 3.50
14
H2O (Light) H2O
15 0.600 3.00
16
17
0.500 2.50
18
Mole Fraction
19
K Value
20 0.400 2.00
21
22
0.300 1.50
23
24
25 0.200 1.00
26
27 1.00e-001 0.500
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 72.35 72.35
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2299 0.2299
34 Heat Flow (kJ/h) -1370 -1370
36
37
COMPOSITION
38
39
42 Ethanol 0.0002 0.0574 0.0086 0.0374 0.0000 0.0427
43 H2O 0.0006 0.1925 0.0113 0.0490 0.0000 0.0447
44 E-Acetate 0.0023 0.6980 0.1999 0.8694 0.0002 0.8743
45 AceticAcid 0.0002 0.0521 0.0102 0.0442 0.0000 0.0382
46 Total 0.0032 1.0000 0.2299 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0002 0.0574 0.0086 0.0374 0.0000 0.0427
52 H2O 0.0006 0.1925 0.0113 0.0490 0.0000 0.0447
53 E-Acetate 0.0023 0.6980 0.1999 0.8694 0.0002 0.8743
54 AceticAcid 0.0002 0.0521 0.0102 0.0442 0.0000 0.0382
55 Total 0.0032 1.0000 0.2299 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 95.85 95.85
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1344 0.1344
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1273 -1273
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0619 0.0104 0.0774 0.0000 0.0981
22 H2O 0.0020 0.5375 0.0353 0.2630 0.0000 0.2659
23 E-Acetate 0.0000 0.0082 0.0026 0.0196 0.0000 0.0219
24 AceticAcid 0.0014 0.3924 0.0860 0.6400 0.0001 0.6141
25 Total 0.0036 1.0000 0.1344 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0619 0.0104 0.0774 0.0000 0.0981
31 H2O 0.0020 0.5375 0.0353 0.2630 0.0000 0.2659
32 E-Acetate 0.0000 0.0082 0.0026 0.0196 0.0000 0.0219
33 AceticAcid 0.0014 0.3924 0.0860 0.6400 0.0001 0.6141
34 Total 0.0036 1.0000 0.1344 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 72.35 72.35 72.35
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 1.150 0.0000 1.150
49 Heat Flow (kJ/h) -6851 0.0000 -6851
51
52
COMPOSITION
53
54
57 Ethanol 0.0009 0.0574 0.0430 0.0374 0.0001 0.0427
58 H2O 0.0031 0.1925 0.0564 0.0490 0.0001 0.0447
59 E-Acetate 0.0113 0.6980 0.9994 0.8694 0.0011 0.8743
60 AceticAcid 0.0008 0.0521 0.0508 0.0442 0.0000 0.0382
61 Total 0.0162 1.0000 1.1495 1.0000 0.0013 1.0000
62
63
66 Ethanol 0.0000 0.0666 0.0000 0.0445 0.0000 0.0507
67 H2O 0.0000 0.2299 0.0000 0.0601 0.0000 0.0545
68 E-Acetate 0.0000 0.6940 0.0000 0.8872 0.0000 0.8877
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0094 0.0000 0.0082 0.0000 0.0071
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0009 0.0574 0.0430 0.0374 0.0001 0.0427
22 H2O 0.0031 0.1925 0.0564 0.0490 0.0001 0.0447
23 E-Acetate 0.0113 0.6980 0.9994 0.8694 0.0011 0.8743
24 AceticAcid 0.0008 0.0521 0.0508 0.0442 0.0000 0.0382
25 Total 0.0163 1.0000 1.1495 1.0000 0.0013 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0574 0.0619
59 H2O 0.1925 0.5375
60 E-Acetate 0.6980 0.0082
61 AceticAcid 0.0521 0.3924
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0002 * 0.0002 *
68 H2O (kgmole/h) 0.0006 * 0.0020 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 6.8804 8.3298
20 H2O (%) 216.3590 678.3914
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 4.3383 36.7263
23
COLUMN PROFILES
24
29 Condenser 72.3 100 1.625e-002 --- --- 3.250e-003 679 *
30 1__Main TS 77.2 100 2.112e-002 1.950e-002 3.900e-003 --- ---
31 2__Main TS 77.2 100 2.110e-002 2.047e-002 --- --- ---
32 3__Main TS 77.2 100 2.107e-002 2.045e-002 --- --- ---
33 4__Main TS 77.1 100 2.103e-002 2.042e-002 --- --- ---
34 5__Main TS 77.0 100 2.098e-002 2.038e-002 --- --- ---
35 6__Main TS 76.9 100 2.091e-002 2.033e-002 --- --- ---
36 7__Main TS 76.8 100 2.083e-002 2.026e-002 --- --- ---
37 8__Main TS 76.7 100 2.072e-002 2.018e-002 --- --- ---
38 9__Main TS 76.5 100 2.060e-002 2.007e-002 --- --- ---
39 10__Main TS 76.3 100 2.043e-002 1.995e-002 --- --- ---
40 11__Main TS 76.1 100 2.023e-002 1.978e-002 --- --- ---
41 12__Main TS 75.9 100 1.996e-002 1.958e-002 --- --- ---
42 13__Main TS 75.8 100 1.959e-002 1.931e-002 --- --- ---
43 14__Main TS 76.1 100 1.907e-002 1.894e-002 --- --- ---
44 15__Main TS 77.7 100 1.842e-002 1.842e-002 --- --- ---
45 16__Main TS 81.6 100 1.790e-002 1.777e-002 --- --- ---
46 17__Main TS 87.3 100 2.173e-002 1.725e-002 3.000e-003 --- ---
47 Reboiler 95.9 100 --- 1.808e-002 --- 3.650e-003 672 *
51 Condenser 72.35 -4.216e+005 -3.782e+005 ---
52 1__Main TS 77.22 -4.265e+005 -3.868e+005 ---
53 2__Main TS 77.19 -4.257e+005 -3.860e+005 ---
54 3__Main TS 77.15 -4.247e+005 -3.851e+005 ---
55 4__Main TS 77.10 -4.237e+005 -3.841e+005 ---
56 5__Main TS 77.03 -4.224e+005 -3.829e+005 ---
57 6__Main TS 76.94 -4.208e+005 -3.815e+005 ---
58 7__Main TS 76.83 -4.189e+005 -3.797e+005 ---
59 8__Main TS 76.70 -4.165e+005 -3.776e+005 ---
60 9__Main TS 76.54 -4.135e+005 -3.749e+005 ---
61 10__Main TS 76.35 -4.097e+005 -3.715e+005 ---
62 11__Main TS 76.14 -4.045e+005 -3.672e+005 ---
63 12__Main TS 75.93 -3.975e+005 -3.614e+005 ---
64 13__Main TS 75.82 -3.872e+005 -3.535e+005 ---
65 14__Main TS 76.12 -3.718e+005 -3.421e+005 ---
66 15__Main TS 77.66 -3.507e+005 -3.249e+005 ---
67 16__Main TS 81.64 -3.319e+005 -3.013e+005 ---
68 17__Main TS 87.33 -3.276e+005 -2.803e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 95.85 -3.487e+005 -2.862e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 6.8e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.2e+005 * 72.35*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 6.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.5e+005 * 95.85*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 2.50e-002 940 75.0
37
38
39
2.00e-002 920
65.0
40
41 910
Density (kg/m3)
60.0
42
1.50e-002 900
43 55.0
44 890
45 50.0
46 1.00e-002 880
47 45.0
870
48
49 40.0
5.00e-003 860
50
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 5.00
14
15 0.600
16 4.00
17
0.500 3.50
18
Mole Fraction
19
3.00
K Value
20 0.400
21 2.50
22
0.300
23 2.00
24
0.200 1.50
25
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.58 71.58
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2236 0.2236
34 Heat Flow (kJ/h) -1338 -1338
36
37
COMPOSITION
38
39
42 Ethanol 0.0003 0.0995 0.0149 0.0667 0.0000 0.0757
43 H2O 0.0007 0.2029 0.0119 0.0531 0.0000 0.0482
44 E-Acetate 0.0022 0.6657 0.1906 0.8525 0.0002 0.8522
45 AceticAcid 0.0001 0.0318 0.0062 0.0277 0.0000 0.0239
46 Total 0.0032 1.0000 0.2236 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0003 0.0995 0.0149 0.0667 0.0000 0.0757
52 H2O 0.0007 0.2029 0.0119 0.0531 0.0000 0.0482
53 E-Acetate 0.0022 0.6657 0.1906 0.8525 0.0002 0.8522
54 AceticAcid 0.0001 0.0318 0.0062 0.0277 0.0000 0.0239
55 Total 0.0032 1.0000 0.2236 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 97.13 97.13
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1407 0.1407
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1302 -1302
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0537 0.0090 0.0642 0.0000 0.0819
22 H2O 0.0018 0.4989 0.0328 0.2332 0.0000 0.2372
23 E-Acetate 0.0000 0.0076 0.0024 0.0173 0.0000 0.0194
24 AceticAcid 0.0016 0.4399 0.0964 0.6853 0.0001 0.6616
25 Total 0.0036 1.0000 0.1407 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0537 0.0090 0.0642 0.0000 0.0819
31 H2O 0.0018 0.4989 0.0328 0.2332 0.0000 0.2372
32 E-Acetate 0.0000 0.0076 0.0024 0.0173 0.0000 0.0194
33 AceticAcid 0.0016 0.4399 0.0964 0.6853 0.0001 0.6616
34 Total 0.0036 1.0000 0.1407 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.58 71.58 71.58
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 1.677 0.0000 1.677
49 Heat Flow (kJ/h) -1.003e+004 0.0000 -1.003e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0024 0.0995 0.1118 0.0667 0.0001 0.0757
58 H2O 0.0049 0.2029 0.0891 0.0531 0.0001 0.0482
59 E-Acetate 0.0162 0.6657 1.4297 0.8525 0.0016 0.8522
60 AceticAcid 0.0008 0.0318 0.0465 0.0277 0.0000 0.0239
61 Total 0.0244 1.0000 1.6772 1.0000 0.0019 1.0000
62
63
66 Ethanol 0.0000 0.1124 0.0000 0.0770 0.0000 0.0871
67 H2O 0.0000 0.2278 0.0000 0.0610 0.0000 0.0551
68 E-Acetate 0.0000 0.6547 0.0000 0.8575 0.0000 0.8539
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0050 0.0000 0.0045 0.0000 0.0039
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0024 0.0995 0.1118 0.0667 0.0001 0.0757
22 H2O 0.0049 0.2029 0.0891 0.0531 0.0001 0.0482
23 E-Acetate 0.0162 0.6657 1.4297 0.8525 0.0016 0.8522
24 AceticAcid 0.0008 0.0318 0.0465 0.0277 0.0000 0.0239
25 Total 0.0244 1.0000 1.6772 1.0000 0.0019 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0995 0.0537
59 H2O 0.2029 0.4989
60 E-Acetate 0.6657 0.0076
61 AceticAcid 0.0318 0.4399
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0003 * 0.0002 *
68 H2O (kgmole/h) 0.0007 * 0.0018 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 11.9348 7.2322
20 H2O (%) 228.0611 629.6018
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 2.6487 41.1661
23
COLUMN PROFILES
24
29 Condenser 71.6 100 2.437e-002 --- --- 3.250e-003 974 *
30 1__Main TS 75.1 100 2.923e-002 2.762e-002 3.900e-003 --- ---
31 2__Main TS 75.1 100 2.920e-002 2.858e-002 --- --- ---
32 3__Main TS 75.0 100 2.916e-002 2.855e-002 --- --- ---
33 4__Main TS 75.0 100 2.911e-002 2.851e-002 --- --- ---
34 5__Main TS 74.9 100 2.906e-002 2.846e-002 --- --- ---
35 6__Main TS 74.9 100 2.899e-002 2.841e-002 --- --- ---
36 7__Main TS 74.8 100 2.891e-002 2.834e-002 --- --- ---
37 8__Main TS 74.7 100 2.881e-002 2.826e-002 --- --- ---
38 9__Main TS 74.6 100 2.868e-002 2.816e-002 --- --- ---
39 10__Main TS 74.5 100 2.853e-002 2.803e-002 --- --- ---
40 11__Main TS 74.3 100 2.833e-002 2.788e-002 --- --- ---
41 12__Main TS 74.2 100 2.806e-002 2.768e-002 --- --- ---
42 13__Main TS 74.2 100 2.766e-002 2.741e-002 --- --- ---
43 14__Main TS 74.5 100 2.705e-002 2.701e-002 --- --- ---
44 15__Main TS 76.2 100 2.623e-002 2.640e-002 --- --- ---
45 16__Main TS 81.2 100 2.575e-002 2.558e-002 --- --- ---
46 17__Main TS 88.7 100 3.013e-002 2.510e-002 3.000e-003 --- ---
47 Reboiler 97.1 100 --- 2.648e-002 --- 3.650e-003 970 *
51 Condenser 71.58 -4.116e+005 -3.693e+005 ---
52 1__Main TS 75.11 -4.164e+005 -3.764e+005 ---
53 2__Main TS 75.08 -4.157e+005 -3.757e+005 ---
54 3__Main TS 75.05 -4.149e+005 -3.749e+005 ---
55 4__Main TS 75.00 -4.140e+005 -3.741e+005 ---
56 5__Main TS 74.94 -4.129e+005 -3.731e+005 ---
57 6__Main TS 74.88 -4.116e+005 -3.719e+005 ---
58 7__Main TS 74.80 -4.100e+005 -3.704e+005 ---
59 8__Main TS 74.71 -4.081e+005 -3.687e+005 ---
60 9__Main TS 74.60 -4.057e+005 -3.666e+005 ---
61 10__Main TS 74.48 -4.025e+005 -3.639e+005 ---
62 11__Main TS 74.34 -3.983e+005 -3.605e+005 ---
63 12__Main TS 74.21 -3.923e+005 -3.559e+005 ---
64 13__Main TS 74.17 -3.832e+005 -3.493e+005 ---
65 14__Main TS 74.49 -3.687e+005 -3.394e+005 ---
66 15__Main TS 76.19 -3.475e+005 -3.234e+005 ---
67 16__Main TS 81.18 -3.305e+005 -3.003e+005 ---
68 17__Main TS 88.66 -3.318e+005 -2.819e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 97.13 -3.568e+005 -2.917e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 9.7e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.1e+005 * 71.58*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 9.7e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.6e+005 * 97.13*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 3.50e-002 940 70.0
37
Liquid Mol Weight(Light)
38 3.00e-002 65.0
920
39
40
2.50e-002 60.0
41
Density (kg/m3)
900
42
43 2.00e-002 55.0
44 880
45
1.50e-002 50.0
46
47 860
48 1.00e-002 45.0
49
50 840
5.00e-003 40.0
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.50
14
15 0.600
16
17
0.500
18
3.00
Mole Fraction
19
K Value
20 0.400 2.50
21
22 2.00
0.300
23
24 1.50
25 0.200
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.20 71.20
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2195 0.2195
34 Heat Flow (kJ/h) -1315 -1315
36
37
COMPOSITION
38
39
42 Ethanol 0.0004 0.1355 0.0203 0.0925 0.0000 0.1046
43 H2O 0.0007 0.2034 0.0119 0.0543 0.0000 0.0490
44 E-Acetate 0.0021 0.6389 0.1830 0.8336 0.0002 0.8296
45 AceticAcid 0.0001 0.0221 0.0043 0.0197 0.0000 0.0169
46 Total 0.0033 1.0000 0.2195 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0004 0.1355 0.0203 0.0925 0.0000 0.1046
52 H2O 0.0007 0.2034 0.0119 0.0543 0.0000 0.0490
53 E-Acetate 0.0021 0.6389 0.1830 0.8336 0.0002 0.8296
54 AceticAcid 0.0001 0.0221 0.0043 0.0197 0.0000 0.0169
55 Total 0.0032 1.0000 0.2195 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 98.16 98.16
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1448 0.1448
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1323 -1323
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0467 0.0079 0.0542 0.0000 0.0695
22 H2O 0.0017 0.4734 0.0311 0.2149 0.0000 0.2196
23 E-Acetate 0.0000 0.0064 0.0021 0.0142 0.0000 0.0160
24 AceticAcid 0.0017 0.4735 0.1038 0.7166 0.0001 0.6949
25 Total 0.0036 1.0000 0.1448 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0467 0.0079 0.0542 0.0000 0.0695
31 H2O 0.0017 0.4734 0.0311 0.2149 0.0000 0.2196
32 E-Acetate 0.0000 0.0064 0.0021 0.0142 0.0000 0.0160
33 AceticAcid 0.0017 0.4735 0.1038 0.7166 0.0001 0.6949
34 Total 0.0036 1.0000 0.1448 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.20 71.20 71.20
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 2.195 0.0000 2.195
49 Heat Flow (kJ/h) -1.315e+004 0.0000 -1.315e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0044 0.1355 0.2029 0.0925 0.0003 0.1046
58 H2O 0.0066 0.2034 0.1191 0.0543 0.0001 0.0490
59 E-Acetate 0.0208 0.6389 1.8295 0.8336 0.0020 0.8296
60 AceticAcid 0.0007 0.0221 0.0432 0.0197 0.0000 0.0169
61 Total 0.0325 1.0000 2.1947 1.0000 0.0024 1.0000
62
63
66 Ethanol 0.0000 0.1483 0.0000 0.1031 0.0000 0.1163
67 H2O 0.0000 0.2214 0.0000 0.0602 0.0000 0.0541
68 E-Acetate 0.0000 0.6271 0.0000 0.8338 0.0000 0.8271
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0032 0.0000 0.0029 0.0000 0.0025
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0044 0.1355 0.2029 0.0925 0.0003 0.1046
22 H2O 0.0066 0.2034 0.1191 0.0543 0.0001 0.0490
23 E-Acetate 0.0208 0.6389 1.8295 0.8336 0.0020 0.8296
24 AceticAcid 0.0007 0.0221 0.0432 0.0197 0.0000 0.0169
25 Total 0.0325 1.0000 2.1947 1.0000 0.0024 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.1355 0.0467
59 H2O 0.2034 0.4734
60 E-Acetate 0.6389 0.0064
61 AceticAcid 0.0221 0.4735
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0004 * 0.0002 *
68 H2O (kgmole/h) 0.0007 * 0.0017 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 16.2494 6.2875
20 H2O (%) 228.5979 597.4772
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 1.8445 44.3128
23
COLUMN PROFILES
24
29 Condenser 71.2 100 3.250e-002 --- --- 3.250e-003 1.27e+003 *
30 1__Main TS 74.0 100 3.734e-002 3.575e-002 3.900e-003 --- ---
31 2__Main TS 73.9 100 3.731e-002 3.669e-002 --- --- ---
32 3__Main TS 73.9 100 3.727e-002 3.666e-002 --- --- ---
33 4__Main TS 73.9 100 3.723e-002 3.662e-002 --- --- ---
34 5__Main TS 73.8 100 3.717e-002 3.658e-002 --- --- ---
35 6__Main TS 73.8 100 3.711e-002 3.652e-002 --- --- ---
36 7__Main TS 73.7 100 3.703e-002 3.646e-002 --- --- ---
37 8__Main TS 73.7 100 3.694e-002 3.638e-002 --- --- ---
38 9__Main TS 73.6 100 3.683e-002 3.629e-002 --- --- ---
39 10__Main TS 73.5 100 3.668e-002 3.618e-002 --- --- ---
40 11__Main TS 73.4 100 3.648e-002 3.603e-002 --- --- ---
41 12__Main TS 73.4 100 3.619e-002 3.583e-002 --- --- ---
42 13__Main TS 73.4 100 3.574e-002 3.554e-002 --- --- ---
43 14__Main TS 73.8 100 3.499e-002 3.509e-002 --- --- ---
44 15__Main TS 75.8 100 3.399e-002 3.434e-002 --- --- ---
45 16__Main TS 81.6 100 3.366e-002 3.334e-002 --- --- ---
46 17__Main TS 90.0 100 3.868e-002 3.301e-002 3.000e-003 --- ---
47 Reboiler 98.2 100 --- 3.503e-002 --- 3.650e-003 1.27e+003 *
51 Condenser 71.20 -4.046e+005 -3.633e+005 ---
52 1__Main TS 73.96 -4.090e+005 -3.691e+005 ---
53 2__Main TS 73.94 -4.085e+005 -3.685e+005 ---
54 3__Main TS 73.91 -4.078e+005 -3.679e+005 ---
55 4__Main TS 73.88 -4.071e+005 -3.672e+005 ---
56 5__Main TS 73.84 -4.062e+005 -3.664e+005 ---
57 6__Main TS 73.79 -4.051e+005 -3.654e+005 ---
58 7__Main TS 73.74 -4.038e+005 -3.643e+005 ---
59 8__Main TS 73.68 -4.022e+005 -3.628e+005 ---
60 9__Main TS 73.61 -4.001e+005 -3.611e+005 ---
61 10__Main TS 73.53 -3.974e+005 -3.589e+005 ---
62 11__Main TS 73.44 -3.937e+005 -3.560e+005 ---
63 12__Main TS 73.37 -3.881e+005 -3.519e+005 ---
64 13__Main TS 73.38 -3.793e+005 -3.459e+005 ---
65 14__Main TS 73.78 -3.646e+005 -3.364e+005 ---
66 15__Main TS 75.76 -3.432e+005 -3.205e+005 ---
67 16__Main TS 81.65 -3.288e+005 -2.974e+005 ---
68 17__Main TS 90.02 -3.348e+005 -2.822e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 98.16 -3.624e+005 -2.958e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 1.3e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.0e+005 * 71.20*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.3e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.6e+005 * 98.16*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 4.00e-002 940 70.0
37
38 65.0
920
39
40 3.00e-002
60.0
41
Density (kg/m3)
900
42 2.50e-002
43 55.0
44 2.00e-002 880
45
50.0
46
1.50e-002
47 860
48 45.0
1.00e-002
49
50 840
5.00e-003 40.0
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.50
14
15 0.600
16
17
0.500
18
3.00
Mole Fraction
19
K Value
20 0.400 2.50
21
22 2.00
0.300
23
24 1.50
25 0.200
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.00 71.00
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2167 0.2167
34 Heat Flow (kJ/h) -1299 -1299
36
37
COMPOSITION
38
39
42 Ethanol 0.0005 0.1622 0.0243 0.1121 0.0000 0.1264
43 H2O 0.0007 0.2015 0.0118 0.0544 0.0000 0.0490
44 E-Acetate 0.0020 0.6195 0.1774 0.8184 0.0002 0.8118
45 AceticAcid 0.0001 0.0168 0.0033 0.0151 0.0000 0.0129
46 Total 0.0032 1.0000 0.2167 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0005 0.1622 0.0243 0.1121 0.0000 0.1264
52 H2O 0.0007 0.2015 0.0118 0.0544 0.0000 0.0490
53 E-Acetate 0.0020 0.6195 0.1774 0.8184 0.0002 0.8118
54 AceticAcid 0.0001 0.0168 0.0033 0.0151 0.0000 0.0129
55 Total 0.0032 1.0000 0.2167 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 98.92 98.92
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1476 0.1476
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1337 -1337
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0414 0.0070 0.0472 0.0000 0.0606
22 H2O 0.0017 0.4566 0.0300 0.2035 0.0000 0.2086
23 E-Acetate 0.0000 0.0053 0.0017 0.0115 0.0000 0.0130
24 AceticAcid 0.0018 0.4967 0.1089 0.7379 0.0001 0.7178
25 Total 0.0036 1.0000 0.1476 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0414 0.0070 0.0472 0.0000 0.0606
31 H2O 0.0017 0.4566 0.0300 0.2035 0.0000 0.2086
32 E-Acetate 0.0000 0.0053 0.0017 0.0115 0.0000 0.0130
33 AceticAcid 0.0018 0.4967 0.1089 0.7379 0.0001 0.7178
34 Total 0.0036 1.0000 0.1476 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.00 71.00 71.00
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 2.709 0.0000 2.709
49 Heat Flow (kJ/h) -1.624e+004 0.0000 -1.624e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0066 0.1622 0.3036 0.1121 0.0004 0.1264
58 H2O 0.0082 0.2015 0.1475 0.0544 0.0001 0.0490
59 E-Acetate 0.0252 0.6195 2.2173 0.8184 0.0025 0.8118
60 AceticAcid 0.0007 0.0168 0.0409 0.0151 0.0000 0.0129
61 Total 0.0406 1.0000 2.7093 1.0000 0.0030 1.0000
62
63
66 Ethanol 0.0000 0.1733 0.0000 0.1217 0.0000 0.1368
67 H2O 0.0000 0.2157 0.0000 0.0592 0.0000 0.0531
68 E-Acetate 0.0000 0.6087 0.0000 0.8170 0.0000 0.8083
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0023 0.0000 0.0021 0.0000 0.0018
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0066 0.1622 0.3036 0.1121 0.0004 0.1264
22 H2O 0.0082 0.2015 0.1475 0.0544 0.0001 0.0490
23 E-Acetate 0.0252 0.6195 2.2173 0.8184 0.0025 0.8118
24 AceticAcid 0.0007 0.0168 0.0409 0.0151 0.0000 0.0129
25 Total 0.0406 1.0000 2.7093 1.0000 0.0030 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.1622 0.0414
59 H2O 0.2015 0.4566
60 E-Acetate 0.6195 0.0053
61 AceticAcid 0.0168 0.4967
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0005 * 0.0002 *
68 H2O (kgmole/h) 0.0007 * 0.0017 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 19.4500 5.5712
20 H2O (%) 226.4829 576.3076
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 1.3972 46.4868
23
COLUMN PROFILES
24
29 Condenser 71.0 100 4.063e-002 --- --- 3.250e-003 1.56e+003 *
30 1__Main TS 73.3 100 4.546e-002 4.388e-002 3.900e-003 --- ---
31 2__Main TS 73.2 100 4.543e-002 4.481e-002 --- --- ---
32 3__Main TS 73.2 100 4.540e-002 4.478e-002 --- --- ---
33 4__Main TS 73.2 100 4.536e-002 4.475e-002 --- --- ---
34 5__Main TS 73.2 100 4.531e-002 4.471e-002 --- --- ---
35 6__Main TS 73.1 100 4.525e-002 4.466e-002 --- --- ---
36 7__Main TS 73.1 100 4.518e-002 4.460e-002 --- --- ---
37 8__Main TS 73.1 100 4.509e-002 4.453e-002 --- --- ---
38 9__Main TS 73.0 100 4.498e-002 4.444e-002 --- --- ---
39 10__Main TS 73.0 100 4.483e-002 4.433e-002 --- --- ---
40 11__Main TS 72.9 100 4.462e-002 4.418e-002 --- --- ---
41 12__Main TS 72.9 100 4.429e-002 4.397e-002 --- --- ---
42 13__Main TS 72.9 100 4.376e-002 4.364e-002 --- --- ---
43 14__Main TS 73.4 100 4.283e-002 4.311e-002 --- --- ---
44 15__Main TS 75.7 100 4.166e-002 4.218e-002 --- --- ---
45 16__Main TS 82.4 100 4.158e-002 4.101e-002 --- --- ---
46 17__Main TS 91.2 100 4.728e-002 4.093e-002 3.000e-003 --- ---
47 Reboiler 98.9 100 --- 4.363e-002 --- 3.650e-003 1.57e+003 *
51 Condenser 71.00 -3.997e+005 -3.593e+005 ---
52 1__Main TS 73.25 -4.038e+005 -3.641e+005 ---
53 2__Main TS 73.24 -4.033e+005 -3.636e+005 ---
54 3__Main TS 73.22 -4.027e+005 -3.631e+005 ---
55 4__Main TS 73.19 -4.021e+005 -3.625e+005 ---
56 5__Main TS 73.17 -4.013e+005 -3.618e+005 ---
57 6__Main TS 73.14 -4.004e+005 -3.609e+005 ---
58 7__Main TS 73.10 -3.993e+005 -3.600e+005 ---
59 8__Main TS 73.06 -3.978e+005 -3.587e+005 ---
60 9__Main TS 73.02 -3.960e+005 -3.572e+005 ---
61 10__Main TS 72.96 -3.935e+005 -3.553e+005 ---
62 11__Main TS 72.91 -3.900e+005 -3.526e+005 ---
63 12__Main TS 72.87 -3.845e+005 -3.488e+005 ---
64 13__Main TS 72.92 -3.754e+005 -3.429e+005 ---
65 14__Main TS 73.41 -3.600e+005 -3.332e+005 ---
66 15__Main TS 75.74 -3.385e+005 -3.167e+005 ---
67 16__Main TS 82.39 -3.272e+005 -2.936e+005 ---
68 17__Main TS 91.18 -3.369e+005 -2.820e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 98.92 -3.663e+005 -2.986e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 1.6e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.0e+005 * 71.00*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.6e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.7e+005 * 98.92*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 5.00e-002 940 70.0
37
38 65.0
920
39
4.00e-002
40
3.50e-002 60.0
41
Density (kg/m3)
900
42
3.00e-002
43 55.0
44 2.50e-002 880
45
50.0
46 2.00e-002
47 860
1.50e-002 45.0
48
49 1.00e-002
50 840
40.0
51 5.00e-003
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.50
14
15 0.600
16
17
0.500
18
3.00
Mole Fraction
19
K Value
20 0.400 2.50
21
22 2.00
0.300
23
24 1.50
25 0.200
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.88 70.88
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2149 0.2149
34 Heat Flow (kJ/h) -1288 -1288
36
37
COMPOSITION
38
39
42 Ethanol 0.0006 0.1813 0.0272 0.1263 0.0000 0.1421
43 H2O 0.0006 0.1995 0.0117 0.0544 0.0000 0.0488
44 E-Acetate 0.0020 0.6057 0.1735 0.8071 0.0002 0.7987
45 AceticAcid 0.0000 0.0134 0.0026 0.0122 0.0000 0.0104
46 Total 0.0032 1.0000 0.2149 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0006 0.1813 0.0272 0.1263 0.0000 0.1421
52 H2O 0.0006 0.1995 0.0117 0.0544 0.0000 0.0488
53 E-Acetate 0.0020 0.6057 0.1735 0.8071 0.0002 0.7987
54 AceticAcid 0.0000 0.0134 0.0026 0.0122 0.0000 0.0104
55 Total 0.0032 1.0000 0.2149 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 99.47 99.47
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1494 0.1494
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1346 -1346
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0375 0.0063 0.0423 0.0000 0.0544
22 H2O 0.0016 0.4453 0.0293 0.1960 0.0000 0.2013
23 E-Acetate 0.0000 0.0043 0.0014 0.0093 0.0000 0.0106
24 AceticAcid 0.0019 0.5129 0.1124 0.7524 0.0001 0.7337
25 Total 0.0036 1.0000 0.1494 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0001 0.0375 0.0063 0.0423 0.0000 0.0544
31 H2O 0.0016 0.4453 0.0293 0.1960 0.0000 0.2013
32 E-Acetate 0.0000 0.0043 0.0014 0.0093 0.0000 0.0106
33 AceticAcid 0.0019 0.5129 0.1124 0.7524 0.0001 0.7337
34 Total 0.0036 1.0000 0.1494 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.88 70.88 70.88
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 3.224 0.0000 3.224
49 Heat Flow (kJ/h) -1.932e+004 0.0000 -1.932e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0088 0.1813 0.4073 0.1263 0.0005 0.1421
58 H2O 0.0097 0.1995 0.1752 0.0544 0.0002 0.0488
59 E-Acetate 0.0295 0.6057 2.6018 0.8071 0.0029 0.7987
60 AceticAcid 0.0007 0.0134 0.0393 0.0122 0.0000 0.0104
61 Total 0.0488 1.0000 3.2236 1.0000 0.0036 1.0000
62
63
66 Ethanol 0.0000 0.1905 0.0000 0.1345 0.0000 0.1510
67 H2O 0.0000 0.2113 0.0000 0.0584 0.0000 0.0523
68 E-Acetate 0.0000 0.5964 0.0000 0.8055 0.0000 0.7954
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0018 0.0000 0.0016 0.0000 0.0014
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0088 0.1813 0.4073 0.1263 0.0005 0.1421
22 H2O 0.0097 0.1995 0.1752 0.0544 0.0002 0.0488
23 E-Acetate 0.0295 0.6057 2.6018 0.8071 0.0029 0.7987
24 AceticAcid 0.0007 0.0134 0.0393 0.0122 0.0000 0.0104
25 Total 0.0488 1.0000 3.2236 1.0000 0.0036 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.1813 0.0375
59 H2O 0.1995 0.4453
60 E-Acetate 0.6057 0.0043
61 AceticAcid 0.0134 0.5129
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0006 * 0.0001 *
68 H2O (kgmole/h) 0.0006 * 0.0016 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 21.7410 5.0544
20 H2O (%) 224.1887 561.9717
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 1.1195 47.9976
23
COLUMN PROFILES
24
29 Condenser 70.9 100 4.875e-002 --- --- 3.250e-003 1.86e+003 *
30 1__Main TS 72.8 100 5.359e-002 5.200e-002 3.900e-003 --- ---
31 2__Main TS 72.8 100 5.356e-002 5.294e-002 --- --- ---
32 3__Main TS 72.8 100 5.353e-002 5.291e-002 --- --- ---
33 4__Main TS 72.7 100 5.349e-002 5.288e-002 --- --- ---
34 5__Main TS 72.7 100 5.345e-002 5.284e-002 --- --- ---
35 6__Main TS 72.7 100 5.339e-002 5.280e-002 --- --- ---
36 7__Main TS 72.7 100 5.333e-002 5.274e-002 --- --- ---
37 8__Main TS 72.7 100 5.324e-002 5.268e-002 --- --- ---
38 9__Main TS 72.6 100 5.313e-002 5.259e-002 --- --- ---
39 10__Main TS 72.6 100 5.297e-002 5.248e-002 --- --- ---
40 11__Main TS 72.6 100 5.274e-002 5.232e-002 --- --- ---
41 12__Main TS 72.5 100 5.236e-002 5.209e-002 --- --- ---
42 13__Main TS 72.6 100 5.172e-002 5.171e-002 --- --- ---
43 14__Main TS 73.2 100 5.058e-002 5.107e-002 --- --- ---
44 15__Main TS 75.9 100 4.928e-002 4.993e-002 --- --- ---
45 16__Main TS 83.2 100 4.952e-002 4.863e-002 --- --- ---
46 17__Main TS 92.1 100 5.590e-002 4.887e-002 3.000e-003 --- ---
47 Reboiler 99.5 100 --- 5.225e-002 --- 3.650e-003 1.86e+003 *
51 Condenser 70.88 -3.964e+005 -3.566e+005 ---
52 1__Main TS 72.78 -4.000e+005 -3.606e+005 ---
53 2__Main TS 72.77 -3.996e+005 -3.602e+005 ---
54 3__Main TS 72.76 -3.990e+005 -3.597e+005 ---
55 4__Main TS 72.74 -3.984e+005 -3.591e+005 ---
56 5__Main TS 72.73 -3.977e+005 -3.585e+005 ---
57 6__Main TS 72.71 -3.969e+005 -3.577e+005 ---
58 7__Main TS 72.68 -3.958e+005 -3.568e+005 ---
59 8__Main TS 72.66 -3.945e+005 -3.557e+005 ---
60 9__Main TS 72.63 -3.928e+005 -3.543e+005 ---
61 10__Main TS 72.59 -3.904e+005 -3.525e+005 ---
62 11__Main TS 72.56 -3.868e+005 -3.499e+005 ---
63 12__Main TS 72.54 -3.811e+005 -3.461e+005 ---
64 13__Main TS 72.63 -3.716e+005 -3.401e+005 ---
65 14__Main TS 73.23 -3.552e+005 -3.299e+005 ---
66 15__Main TS 75.92 -3.338e+005 -3.124e+005 ---
67 16__Main TS 83.17 -3.258e+005 -2.895e+005 ---
68 17__Main TS 92.10 -3.384e+005 -2.816e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 99.47 -3.689e+005 -3.006e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 1.9e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.0e+005 * 70.88*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 1.9e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.7e+005 * 99.47*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 6.00e-002 940 70.0
37
Liquid Mol Weight(Light)
38 65.0
5.00e-002 920
39
40
60.0
41
Density (kg/m3)
4.00e-002 900
42
43 55.0
44 3.00e-002 880
45
50.0
46
47 2.00e-002 860
48 45.0
49
50 1.00e-002 840
40.0
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.50
14
15 0.600
16
17
0.500
18
3.00
Mole Fraction
19
K Value
20 0.400 2.50
21
22 2.00
0.300
23
24 1.50
25 0.200
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.76 70.76
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2127 0.2127
34 Heat Flow (kJ/h) -1275 -1275
36
37
COMPOSITION
38
39
42 Ethanol 0.0007 0.2052 0.0307 0.1445 0.0000 0.1620
43 H2O 0.0006 0.1965 0.0115 0.0541 0.0000 0.0484
44 E-Acetate 0.0019 0.5887 0.1686 0.7926 0.0002 0.7821
45 AceticAcid 0.0000 0.0096 0.0019 0.0088 0.0000 0.0075
46 Total 0.0033 1.0000 0.2127 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0007 0.2052 0.0307 0.1445 0.0000 0.1620
52 H2O 0.0006 0.1965 0.0115 0.0541 0.0000 0.0484
53 E-Acetate 0.0019 0.5887 0.1686 0.7926 0.0002 0.7821
54 AceticAcid 0.0000 0.0096 0.0019 0.0088 0.0000 0.0075
55 Total 0.0032 1.0000 0.2127 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 100.2 100.2
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1516 0.1516
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1358 -1358
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0328 0.0055 0.0364 0.0000 0.0470
22 H2O 0.0016 0.4314 0.0284 0.1871 0.0000 0.1927
23 E-Acetate 0.0000 0.0030 0.0010 0.0064 0.0000 0.0072
24 AceticAcid 0.0019 0.5328 0.1168 0.7702 0.0001 0.7531
25 Total 0.0036 1.0000 0.1516 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0001 0.0328 0.0055 0.0364 0.0000 0.0470
31 H2O 0.0016 0.4314 0.0284 0.1871 0.0000 0.1927
32 E-Acetate 0.0000 0.0030 0.0010 0.0064 0.0000 0.0072
33 AceticAcid 0.0019 0.5328 0.1168 0.7702 0.0001 0.7531
34 Total 0.0036 1.0000 0.1516 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.76 70.76 70.76
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 4.253 0.0000 4.253
49 Heat Flow (kJ/h) -2.549e+004 0.0000 -2.549e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0133 0.2052 0.6145 0.1445 0.0008 0.1620
58 H2O 0.0128 0.1965 0.2301 0.0541 0.0002 0.0484
59 E-Acetate 0.0383 0.5887 3.3714 0.7926 0.0037 0.7821
60 AceticAcid 0.0006 0.0096 0.0374 0.0088 0.0000 0.0075
61 Total 0.0650 1.0000 4.2534 1.0000 0.0048 1.0000
62
63
66 Ethanol 0.0000 0.2110 0.0000 0.1501 0.0000 0.1681
67 H2O 0.0000 0.2059 0.0000 0.0573 0.0000 0.0512
68 E-Acetate 0.0000 0.5818 0.0000 0.7915 0.0000 0.7798
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0012 0.0000 0.0011 0.0000 0.0010
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0133 0.2052 0.6145 0.1445 0.0008 0.1620
22 H2O 0.0128 0.1965 0.2301 0.0541 0.0002 0.0484
23 E-Acetate 0.0383 0.5887 3.3714 0.7926 0.0037 0.7821
24 AceticAcid 0.0006 0.0096 0.0374 0.0088 0.0000 0.0075
25 Total 0.0650 1.0000 4.2534 1.0000 0.0048 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.2052 0.0328
59 H2O 0.1965 0.4314
60 E-Acetate 0.5887 0.0030
61 AceticAcid 0.0096 0.5328
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0007 * 0.0001 *
68 H2O (kgmole/h) 0.0006 * 0.0016 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 24.6016 4.4159
20 H2O (%) 220.8579 544.4740
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.7986 49.8631
23
COLUMN PROFILES
24
29 Condenser 70.8 100 6.500e-002 --- --- 3.250e-003 2.45e+003 *
30 1__Main TS 72.2 100 6.984e-002 6.825e-002 3.900e-003 --- ---
31 2__Main TS 72.2 100 6.982e-002 6.919e-002 --- --- ---
32 3__Main TS 72.2 100 6.979e-002 6.917e-002 --- --- ---
33 4__Main TS 72.2 100 6.976e-002 6.914e-002 --- --- ---
34 5__Main TS 72.2 100 6.972e-002 6.911e-002 --- --- ---
35 6__Main TS 72.2 100 6.967e-002 6.907e-002 --- --- ---
36 7__Main TS 72.2 100 6.961e-002 6.902e-002 --- --- ---
37 8__Main TS 72.2 100 6.952e-002 6.896e-002 --- --- ---
38 9__Main TS 72.1 100 6.939e-002 6.887e-002 --- --- ---
39 10__Main TS 72.1 100 6.920e-002 6.874e-002 --- --- ---
40 11__Main TS 72.1 100 6.890e-002 6.855e-002 --- --- ---
41 12__Main TS 72.2 100 6.838e-002 6.825e-002 --- --- ---
42 13__Main TS 72.3 100 6.744e-002 6.773e-002 --- --- ---
43 14__Main TS 73.2 100 6.583e-002 6.679e-002 --- --- ---
44 15__Main TS 76.5 100 6.439e-002 6.518e-002 --- --- ---
45 16__Main TS 84.5 100 6.538e-002 6.374e-002 --- --- ---
46 17__Main TS 93.4 100 7.309e-002 6.473e-002 3.000e-003 --- ---
47 Reboiler 100.2 100 --- 6.944e-002 --- 3.650e-003 2.45e+003 *
51 Condenser 70.76 -3.922e+005 -3.535e+005 ---
52 1__Main TS 72.20 -3.952e+005 -3.563e+005 ---
53 2__Main TS 72.20 -3.947e+005 -3.559e+005 ---
54 3__Main TS 72.20 -3.942e+005 -3.554e+005 ---
55 4__Main TS 72.19 -3.936e+005 -3.549e+005 ---
56 5__Main TS 72.19 -3.929e+005 -3.543e+005 ---
57 6__Main TS 72.18 -3.921e+005 -3.536e+005 ---
58 7__Main TS 72.17 -3.911e+005 -3.527e+005 ---
59 8__Main TS 72.16 -3.898e+005 -3.517e+005 ---
60 9__Main TS 72.15 -3.881e+005 -3.503e+005 ---
61 10__Main TS 72.14 -3.855e+005 -3.485e+005 ---
62 11__Main TS 72.13 -3.816e+005 -3.458e+005 ---
63 12__Main TS 72.15 -3.751e+005 -3.417e+005 ---
64 13__Main TS 72.32 -3.640e+005 -3.349e+005 ---
65 14__Main TS 73.16 -3.455e+005 -3.231e+005 ---
66 15__Main TS 76.52 -3.254e+005 -3.034e+005 ---
67 16__Main TS 84.52 -3.234e+005 -2.821e+005 ---
68 17__Main TS 93.36 -3.401e+005 -2.807e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 100.2 -3.721e+005 -3.031e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 2.4e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -3.9e+005 * 70.76*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 2.5e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.7e+005 * *
100.18
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 105 105
14
104
15 100
16 103
17
95.0 102
18
Temperature (C)
Pressure (kPa)
19
101
20 90.0
21 100
22
85.0
23 99.0
24
80.0 98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 8.00e-002 960 70.0
37
38 940 65.0
39
40 6.00e-002
920 60.0
41
Density (kg/m3)
42 5.00e-002
43 900 55.0
44 4.00e-002
45
880 50.0
46
3.00e-002
47
48 860 45.0
2.00e-002
49
50 840 40.0
1.00e-002
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.600 5.00
14
15
0.500 E-Acetate (Light) E-Acetate
16 4.00
17
18 3.50
0.400
Mole Fraction
19
3.00
K Value
20
21 0.300 2.50
22
23 2.00
24 0.200
1.50
25
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.70 70.70
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2114 0.2114
34 Heat Flow (kJ/h) -1267 -1267
36
37
COMPOSITION
38
39
42 Ethanol 0.0007 0.2187 0.0327 0.1549 0.0000 0.1734
43 H2O 0.0006 0.1949 0.0114 0.0540 0.0000 0.0482
44 E-Acetate 0.0019 0.5790 0.1658 0.7843 0.0002 0.7726
45 AceticAcid 0.0000 0.0074 0.0015 0.0069 0.0000 0.0058
46 Total 0.0033 1.0000 0.2114 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0007 0.2187 0.0327 0.1549 0.0000 0.1734
52 H2O 0.0006 0.1949 0.0114 0.0540 0.0000 0.0482
53 E-Acetate 0.0019 0.5790 0.1658 0.7843 0.0002 0.7726
54 AceticAcid 0.0000 0.0074 0.0015 0.0069 0.0000 0.0058
55 Total 0.0032 1.0000 0.2114 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 100.6 100.6
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1529 0.1529
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1365 -1365
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0302 0.0051 0.0332 0.0000 0.0430
22 H2O 0.0015 0.4235 0.0278 0.1821 0.0000 0.1879
23 E-Acetate 0.0000 0.0022 0.0007 0.0046 0.0000 0.0053
24 AceticAcid 0.0020 0.5441 0.1193 0.7800 0.0001 0.7638
25 Total 0.0036 1.0000 0.1529 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0001 0.0302 0.0051 0.0332 0.0000 0.0430
31 H2O 0.0015 0.4235 0.0278 0.1821 0.0000 0.1879
32 E-Acetate 0.0000 0.0022 0.0007 0.0046 0.0000 0.0053
33 AceticAcid 0.0020 0.5441 0.1193 0.7800 0.0001 0.7638
34 Total 0.0036 1.0000 0.1529 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.70 70.70 70.70
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 5.285 0.0000 5.285
49 Heat Flow (kJ/h) -3.168e+004 0.0000 -3.168e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0178 0.2187 0.8185 0.1549 0.0010 0.1734
58 H2O 0.0158 0.1949 0.2853 0.0540 0.0003 0.0482
59 E-Acetate 0.0470 0.5790 4.1450 0.7843 0.0046 0.7726
60 AceticAcid 0.0006 0.0074 0.0363 0.0069 0.0000 0.0058
61 Total 0.0813 1.0000 5.2851 1.0000 0.0059 1.0000
62
63
66 Ethanol 0.0000 0.2223 0.0000 0.1587 0.0000 0.1775
67 H2O 0.0000 0.2029 0.0000 0.0567 0.0000 0.0506
68 E-Acetate 0.0000 0.5739 0.0000 0.7837 0.0000 0.7712
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0009 0.0000 0.0009 0.0000 0.0007
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0178 0.2187 0.8185 0.1549 0.0010 0.1734
22 H2O 0.0158 0.1949 0.2853 0.0540 0.0003 0.0482
23 E-Acetate 0.0470 0.5790 4.1450 0.7843 0.0046 0.7726
24 AceticAcid 0.0006 0.0074 0.0363 0.0069 0.0000 0.0058
25 Total 0.0813 1.0000 5.2851 1.0000 0.0059 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.2187 0.0302
59 H2O 0.1949 0.4235
60 E-Acetate 0.5790 0.0022
61 AceticAcid 0.0074 0.5441
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0007 * 0.0001 *
68 H2O (kgmole/h) 0.0006 * 0.0015 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 26.2149 4.0706
20 H2O (%) 219.0078 534.4385
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.6201 50.9230
23
COLUMN PROFILES
24
29 Condenser 70.7 100 8.125e-002 --- --- 3.250e-003 3.04e+003 *
30 1__Main TS 71.9 100 8.609e-002 8.450e-002 3.900e-003 --- ---
31 2__Main TS 71.9 100 8.607e-002 8.544e-002 --- --- ---
32 3__Main TS 71.9 100 8.605e-002 8.542e-002 --- --- ---
33 4__Main TS 71.9 100 8.603e-002 8.540e-002 --- --- ---
34 5__Main TS 71.9 100 8.599e-002 8.538e-002 --- --- ---
35 6__Main TS 71.9 100 8.594e-002 8.534e-002 --- --- ---
36 7__Main TS 71.9 100 8.587e-002 8.529e-002 --- --- ---
37 8__Main TS 71.9 100 8.577e-002 8.522e-002 --- --- ---
38 9__Main TS 71.9 100 8.562e-002 8.512e-002 --- --- ---
39 10__Main TS 71.9 100 8.538e-002 8.497e-002 --- --- ---
40 11__Main TS 71.9 100 8.497e-002 8.473e-002 --- --- ---
41 12__Main TS 71.9 100 8.425e-002 8.432e-002 --- --- ---
42 13__Main TS 72.2 100 8.294e-002 8.360e-002 --- --- ---
43 14__Main TS 73.3 100 8.085e-002 8.229e-002 --- --- ---
44 15__Main TS 77.2 100 7.945e-002 8.020e-002 --- --- ---
45 16__Main TS 85.5 100 8.124e-002 7.880e-002 --- --- ---
46 17__Main TS 94.1 100 9.024e-002 8.059e-002 3.000e-003 --- ---
47 Reboiler 100.6 100 --- 8.659e-002 --- 3.650e-003 3.04e+003 *
51 Condenser 70.70 -3.899e+005 -3.518e+005 ---
52 1__Main TS 71.86 -3.923e+005 -3.539e+005 ---
53 2__Main TS 71.87 -3.918e+005 -3.535e+005 ---
54 3__Main TS 71.87 -3.912e+005 -3.530e+005 ---
55 4__Main TS 71.87 -3.906e+005 -3.524e+005 ---
56 5__Main TS 71.87 -3.899e+005 -3.518e+005 ---
57 6__Main TS 71.87 -3.891e+005 -3.511e+005 ---
58 7__Main TS 71.87 -3.880e+005 -3.502e+005 ---
59 8__Main TS 71.87 -3.867e+005 -3.491e+005 ---
60 9__Main TS 71.87 -3.848e+005 -3.477e+005 ---
61 10__Main TS 71.87 -3.819e+005 -3.457e+005 ---
62 11__Main TS 71.88 -3.774e+005 -3.427e+005 ---
63 12__Main TS 71.94 -3.699e+005 -3.380e+005 ---
64 13__Main TS 72.21 -3.568e+005 -3.300e+005 ---
65 14__Main TS 73.31 -3.365e+005 -3.163e+005 ---
66 15__Main TS 77.22 -3.188e+005 -2.947e+005 ---
67 16__Main TS 85.51 -3.217e+005 -2.762e+005 ---
68 17__Main TS 94.12 -3.411e+005 -2.800e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 100.6 -3.739e+005 -3.045e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.0e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -3.9e+005 * 70.70*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.0e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.7e+005 * *
100.58
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 105 105
14
104
15 100
16 103
17
95.0 102
18
Temperature (C)
Pressure (kPa)
19
101
20 90.0
21 100
22
85.0
23 99.0
24
80.0 98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 0.100 960 70.0
37
38 65.0
940
39
8.00e-002
40 60.0
7.00e-002 920
41
Density (kg/m3)
42 55.0
6.00e-002
43 900
44 5.00e-002 50.0
45
880
46 4.00e-002
45.0
47
3.00e-002 860
48
40.0
49 2.00e-002
50 840 35.0
51 1.00e-002
52
0.000 820 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.600 5.00
14
15
16 4.00
17
18 3.50
0.400
Mole Fraction
19
3.00
K Value
20
21 0.300 2.50
22
23 2.00
24 0.200
1.50
25
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.66 70.66
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2106 0.2106
34 Heat Flow (kJ/h) -1262 -1262
36
37
COMPOSITION
38
39
42 Ethanol 0.0007 0.2270 0.0340 0.1614 0.0000 0.1805
43 H2O 0.0006 0.1940 0.0114 0.0539 0.0000 0.0481
44 E-Acetate 0.0019 0.5730 0.1641 0.7791 0.0002 0.7666
45 AceticAcid 0.0000 0.0061 0.0012 0.0056 0.0000 0.0048
46 Total 0.0032 1.0000 0.2106 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0007 0.2270 0.0340 0.1614 0.0000 0.1805
52 H2O 0.0006 0.1940 0.0114 0.0539 0.0000 0.0481
53 E-Acetate 0.0019 0.5730 0.1641 0.7791 0.0002 0.7666
54 AceticAcid 0.0000 0.0061 0.0012 0.0056 0.0000 0.0048
55 Total 0.0032 1.0000 0.2106 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 100.8 100.8
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1537 0.1537
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1369 -1369
15
16
COMPOSITION
17
18
21 Ethanol 0.0001 0.0287 0.0048 0.0314 0.0000 0.0407
22 H2O 0.0015 0.4183 0.0275 0.1790 0.0000 0.1848
23 E-Acetate 0.0000 0.0017 0.0005 0.0035 0.0000 0.0040
24 AceticAcid 0.0020 0.5512 0.1208 0.7861 0.0001 0.7705
25 Total 0.0036 1.0000 0.1537 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0001 0.0287 0.0048 0.0314 0.0000 0.0407
31 H2O 0.0015 0.4183 0.0275 0.1790 0.0000 0.1848
32 E-Acetate 0.0000 0.0017 0.0005 0.0035 0.0000 0.0040
33 AceticAcid 0.0020 0.5512 0.1208 0.7861 0.0001 0.7705
34 Total 0.0036 1.0000 0.1537 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.66 70.66 70.66
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 6.318 0.0000 6.318
49 Heat Flow (kJ/h) -3.787e+004 0.0000 -3.787e+004
51
52
COMPOSITION
53
54
57 Ethanol 0.0221 0.2270 1.0195 0.1614 0.0013 0.1805
58 H2O 0.0189 0.1940 0.3407 0.0539 0.0003 0.0481
59 E-Acetate 0.0559 0.5730 4.9219 0.7791 0.0054 0.7666
60 AceticAcid 0.0006 0.0061 0.0356 0.0056 0.0000 0.0048
61 Total 0.0975 1.0000 6.3178 1.0000 0.0071 1.0000
62
63
66 Ethanol 0.0000 0.2290 0.0000 0.1639 0.0000 0.1832
67 H2O 0.0000 0.2012 0.0000 0.0563 0.0000 0.0502
68 E-Acetate 0.0000 0.5690 0.0000 0.7790 0.0000 0.7660
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0008 0.0000 0.0007 0.0000 0.0006
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0221 0.2270 1.0195 0.1614 0.0013 0.1805
22 H2O 0.0189 0.1940 0.3407 0.0539 0.0003 0.0481
23 E-Acetate 0.0559 0.5730 4.9219 0.7791 0.0054 0.7666
24 AceticAcid 0.0006 0.0061 0.0356 0.0056 0.0000 0.0048
25 Total 0.0975 1.0000 6.3178 1.0000 0.0071 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 1__Main TS
11 F1 17__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.2270 0.0287
59 H2O 0.1940 0.4183
60 E-Acetate 0.5730 0.0017
61 AceticAcid 0.0061 0.5512
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0007 * 0.0001 *
68 H2O (kgmole/h) 0.0006 * 0.0015 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 27.2122 3.8699
20 H2O (%) 218.0057 527.9739
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.5067 51.5901
23
COLUMN PROFILES
24
29 Condenser 70.7 100 9.750e-002 --- --- 3.250e-003 3.63e+003 *
30 1__Main TS 71.6 100 0.1023 0.1007 3.900e-003 --- ---
31 2__Main TS 71.6 100 0.1023 0.1017 --- --- ---
32 3__Main TS 71.6 100 0.1023 0.1017 --- --- ---
33 4__Main TS 71.7 100 0.1023 0.1017 --- --- ---
34 5__Main TS 71.7 100 0.1022 0.1016 --- --- ---
35 6__Main TS 71.7 100 0.1022 0.1016 --- --- ---
36 7__Main TS 71.7 100 0.1021 0.1015 --- --- ---
37 8__Main TS 71.7 100 0.1020 0.1015 --- --- ---
38 9__Main TS 71.7 100 0.1018 0.1014 --- --- ---
39 10__Main TS 71.7 100 0.1015 0.1012 --- --- ---
40 11__Main TS 71.7 100 0.1010 0.1009 --- --- ---
41 12__Main TS 71.8 100 9.998e-002 0.1003 --- --- ---
42 13__Main TS 72.2 100 9.824e-002 9.933e-002 --- --- ---
43 14__Main TS 73.6 100 9.572e-002 9.759e-002 --- --- ---
44 15__Main TS 77.9 100 9.449e-002 9.507e-002 --- --- ---
45 16__Main TS 86.2 100 9.709e-002 9.384e-002 --- --- ---
46 17__Main TS 94.6 100 0.1073 9.644e-002 3.000e-003 --- ---
47 Reboiler 100.8 100 --- 0.1037 --- 3.650e-003 3.63e+003 *
51 Condenser 70.66 -3.884e+005 -3.507e+005 ---
52 1__Main TS 71.64 -3.904e+005 -3.524e+005 ---
53 2__Main TS 71.64 -3.899e+005 -3.520e+005 ---
54 3__Main TS 71.65 -3.893e+005 -3.514e+005 ---
55 4__Main TS 71.66 -3.887e+005 -3.508e+005 ---
56 5__Main TS 71.66 -3.879e+005 -3.502e+005 ---
57 6__Main TS 71.67 -3.870e+005 -3.494e+005 ---
58 7__Main TS 71.67 -3.859e+005 -3.485e+005 ---
59 8__Main TS 71.68 -3.844e+005 -3.474e+005 ---
60 9__Main TS 71.69 -3.823e+005 -3.458e+005 ---
61 10__Main TS 71.70 -3.791e+005 -3.436e+005 ---
62 11__Main TS 71.73 -3.739e+005 -3.402e+005 ---
63 12__Main TS 71.83 -3.650e+005 -3.348e+005 ---
64 13__Main TS 72.20 -3.501e+005 -3.255e+005 ---
65 14__Main TS 73.58 -3.286e+005 -3.098e+005 ---
66 15__Main TS 77.88 -3.138e+005 -2.870e+005 ---
67 16__Main TS 86.20 -3.205e+005 -2.716e+005 ---
68 17__Main TS 94.60 -3.416e+005 -2.795e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 100.8 -3.751e+005 -3.054e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.6e+003 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -3.9e+005 * 70.66*
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
38 Q_R Energy 3.6e+003 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.8e+005 * *
100.82
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 105 105
14
104
15 100
16 103
17
95.0 102
18
Temperature (C)
Pressure (kPa)
19
101
20 90.0
21 100
22
85.0
23 99.0
24
80.0 98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 0.120 960 65.0
37
38 60.0
0.100
39
40 920
55.0
41
Density (kg/m3)
8.00e-002
42 900
43 50.0
44 6.00e-002 880
45
45.0
46
860
47 4.00e-002
48 40.0
840
49
50 2.00e-002
820 35.0
51
52
0.000 800 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.600 5.00
14
15
16 4.00
17
18 3.50
0.400
Mole Fraction
19
3.00
K Value
20
21 0.300 2.50
22
23 2.00
24 0.200
1.50
25
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B8:
EFFECT OF
ACTIVITY MODEL
1
Case Name: WILSON.HSC
2 LEGENDS
4 USA
5
6
7 HYSYS Column Profiles Specsheet:
8
9 Composition vs. Tray Position from Top
10 0.800
Ethanol (Light)
11
0.700 H2O (Light)
12
E-Acetate (Light)
13
AceticAcid (Light)
14 0.600
15
Mole Fraction
16 0.500
17
18 0.400
19
20
0.300
21
22
0.200
23
24
1.00e-001
25
26
0.000
27
0 5 10 15 20 25 30 35 40 45 50
28
29
30
31
32
33
Column Composition Profile
34
35 Options Selected
36 Fraction is selected as the composition basis Net is selected as flow basis
37 Molar basis is selected
38 Stage Ethanol (Light Liq) H2O (Light Liq) E-Acetate (Light Liq) AceticAcid (Light Liq)
39 Condenser 0.0187 0.1380 0.7303 0.1130
40 1__Main TS 0.0156 0.0954 0.5100 0.3791
41 2__Main TS 0.0168 0.0951 0.5086 0.3795
42 3__Main TS 0.0174 0.0953 0.5076 0.3797
43 4__Main TS 0.0178 0.0957 0.5067 0.3798
44 5__Main TS 0.0180 0.0963 0.5059 0.3798
45 6__Main TS 0.0182 0.0969 0.5051 0.3798
46 7__Main TS 0.0183 0.0976 0.5043 0.3798
47 8__Main TS 0.0184 0.0982 0.5036 0.3798
48 9__Main TS 0.0186 0.0989 0.5028 0.3797
49 10__Main TS 0.0187 0.0996 0.5020 0.3797
50 11__Main TS 0.0188 0.1004 0.5012 0.3797
51 12__Main TS 0.0189 0.1011 0.5004 0.3796
52 13__Main TS 0.0190 0.1019 0.4995 0.3796
53 14__Main TS 0.0191 0.1027 0.4987 0.3795
54 15__Main TS 0.0192 0.1035 0.4978 0.3795
55 16__Main TS 0.0194 0.1044 0.4968 0.3795
56 17__Main TS 0.0195 0.1052 0.4958 0.3794
57 18__Main TS 0.0196 0.1062 0.4948 0.3794
58 19__Main TS 0.0198 0.1072 0.4937 0.3793
59 20__Main TS 0.0199 0.1082 0.4926 0.3792
60 21__Main TS 0.0201 0.1093 0.4914 0.3792
61 22__Main TS 0.0203 0.1105 0.4901 0.3791
62 23__Main TS 0.0205 0.1117 0.4888 0.3791
63 24__Main TS 0.0207 0.1131 0.4873 0.3790
64 25__Main TS 0.0209 0.1145 0.4857 0.3789
65 26__Main TS 0.0211 0.1161 0.4840 0.3788
66 27__Main TS 0.0214 0.1179 0.4821 0.3787
67 28__Main TS 0.0216 0.1198 0.4800 0.3786
68 29__Main TS 0.0220 0.1219 0.4776 0.3785
1
Case Name: WILSON.HSC
2 LEGENDS
4 USA
5
6
8
9
11 30__Main TS 0.0223 0.1243 0.4750 0.3784
12 31__Main TS 0.0227 0.1270 0.4721 0.3782
13 32__Main TS 0.0232 0.1301 0.4688 0.3780
14 33__Main TS 0.0238 0.1336 0.4649 0.3777
15 34__Main TS 0.0245 0.1377 0.4605 0.3774
16 35__Main TS 0.0253 0.1425 0.4552 0.3769
17 36__Main TS 0.0264 0.1483 0.4490 0.3764
18 37__Main TS 0.0277 0.1552 0.4415 0.3755
19 38__Main TS 0.0295 0.1637 0.4323 0.3744
20 39__Main TS 0.0320 0.1743 0.4209 0.3728
21 40__Main TS 0.0354 0.1877 0.4063 0.3706
22 41__Main TS 0.0401 0.2051 0.3872 0.3676
23 42__Main TS 0.0467 0.2281 0.3618 0.3634
24 43__Main TS 0.0560 0.2590 0.3275 0.3576
25 44__Main TS 0.0683 0.3009 0.2817 0.3491
26 45__Main TS 0.0837 0.3564 0.2242 0.3357
27 46__Main TS 0.1011 0.4251 0.1600 0.3137
28 47__Main TS 0.1191 0.5006 0.1002 0.2801
29 48__Main TS 0.1379 0.5688 0.0547 0.2385
30 49__Main TS 0.1657 0.5994 0.0261 0.2089
31 Reboiler 0.0694 0.6130 0.0063 0.3113
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: UNIQUAC.HSC
2 LEGENDS
4 USA
5
6
8
10 0.800
Ethanol (Light)
11
0.700 H2O (Light)
12
E-Acetate (Light)
13
AceticAcid (Light)
14 0.600
15
Mole Fraction
16 0.500
17
18 0.400
19
20
0.300
21
22
0.200
23
24
1.00e-001
25
26
0.000
27
0 5 10 15 20 25 30 35 40 45 50
28
29
30
31
32
33
34
35 Options Selected
39 Condenser 0.0248 0.1454 0.7195 0.1103
40 1__Main TS 0.0184 0.1024 0.5027 0.3765
41 2__Main TS 0.0190 0.1031 0.5013 0.3765
42 3__Main TS 0.0194 0.1041 0.5000 0.3765
43 4__Main TS 0.0196 0.1050 0.4989 0.3765
44 5__Main TS 0.0198 0.1060 0.4977 0.3764
45 6__Main TS 0.0200 0.1071 0.4966 0.3763
46 7__Main TS 0.0201 0.1080 0.4956 0.3762
47 8__Main TS 0.0203 0.1090 0.4945 0.3762
48 9__Main TS 0.0204 0.1100 0.4934 0.3761
49 10__Main TS 0.0206 0.1110 0.4924 0.3760
50 11__Main TS 0.0207 0.1120 0.4913 0.3759
51 12__Main TS 0.0209 0.1130 0.4903 0.3759
52 13__Main TS 0.0210 0.1140 0.4892 0.3758
53 14__Main TS 0.0212 0.1150 0.4881 0.3757
54 15__Main TS 0.0213 0.1161 0.4870 0.3756
55 16__Main TS 0.0215 0.1171 0.4859 0.3755
56 17__Main TS 0.0216 0.1182 0.4847 0.3754
57 18__Main TS 0.0218 0.1193 0.4835 0.3754
58 19__Main TS 0.0219 0.1205 0.4823 0.3753
59 20__Main TS 0.0221 0.1217 0.4810 0.3752
60 21__Main TS 0.0223 0.1230 0.4797 0.3751
61 22__Main TS 0.0225 0.1243 0.4783 0.3750
62 23__Main TS 0.0227 0.1257 0.4768 0.3749
63 24__Main TS 0.0229 0.1271 0.4753 0.3747
64 25__Main TS 0.0231 0.1287 0.4736 0.3746
65 26__Main TS 0.0233 0.1304 0.4718 0.3745
66 27__Main TS 0.0236 0.1322 0.4699 0.3743
67 28__Main TS 0.0238 0.1342 0.4678 0.3742
68 29__Main TS 0.0241 0.1363 0.4656 0.3740
1
Case Name: UNIQUAC.HSC
2 LEGENDS
4 USA
5
6
8
9
11 30__Main TS 0.0245 0.1387 0.4631 0.3738
12 31__Main TS 0.0248 0.1413 0.4603 0.3735
13 32__Main TS 0.0253 0.1443 0.4572 0.3732
14 33__Main TS 0.0258 0.1476 0.4537 0.3729
15 34__Main TS 0.0263 0.1514 0.4498 0.3725
16 35__Main TS 0.0270 0.1557 0.4453 0.3720
17 36__Main TS 0.0279 0.1608 0.4400 0.3713
18 37__Main TS 0.0290 0.1667 0.4339 0.3703
19 38__Main TS 0.0305 0.1739 0.4266 0.3690
20 39__Main TS 0.0325 0.1825 0.4178 0.3672
21 40__Main TS 0.0352 0.1931 0.4069 0.3647
22 41__Main TS 0.0392 0.2064 0.3932 0.3612
23 42__Main TS 0.0450 0.2237 0.3751 0.3563
24 43__Main TS 0.0535 0.2466 0.3503 0.3496
25 44__Main TS 0.0662 0.2784 0.3146 0.3408
26 45__Main TS 0.0843 0.3241 0.2625 0.3291
27 46__Main TS 0.1079 0.3889 0.1914 0.3118
28 47__Main TS 0.1323 0.4713 0.1131 0.2833
29 48__Main TS 0.1526 0.5514 0.0533 0.2428
30 49__Main TS 0.1770 0.5892 0.0219 0.2119
31 Reboiler 0.0756 0.5947 0.0043 0.3253
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
Case Name: NRTL.HSC
2 LEGENDS
4 USA
5
6
8
10 0.800
Ethanol (Light)
11
0.700 H2O (Light)
12
E-Acetate (Light)
13
AceticAcid (Light)
14 0.600
15
Mole Fraction
16 0.500
17
18 0.400
19
20
0.300
21
22
0.200
23
24
1.00e-001
25
26
0.000
27
0 5 10 15 20 25 30 35 40 45 50
28
29
30
31
32
33
34
35 Options Selected
39 Condenser 0.0189 0.1100 0.7533 0.1178
40 1__Main TS 0.0145 0.0785 0.5257 0.3813
41 2__Main TS 0.0152 0.0800 0.5234 0.3813
42 3__Main TS 0.0157 0.0817 0.5213 0.3813
43 4__Main TS 0.0161 0.0834 0.5193 0.3812
44 5__Main TS 0.0164 0.0850 0.5175 0.3810
45 6__Main TS 0.0167 0.0866 0.5157 0.3809
46 7__Main TS 0.0170 0.0882 0.5141 0.3808
47 8__Main TS 0.0172 0.0897 0.5124 0.3807
48 9__Main TS 0.0174 0.0912 0.5108 0.3806
49 10__Main TS 0.0177 0.0927 0.5092 0.3804
50 11__Main TS 0.0179 0.0942 0.5076 0.3803
51 12__Main TS 0.0181 0.0956 0.5060 0.3802
52 13__Main TS 0.0184 0.0971 0.5044 0.3801
53 14__Main TS 0.0186 0.0986 0.5028 0.3800
54 15__Main TS 0.0188 0.1001 0.5012 0.3799
55 16__Main TS 0.0191 0.1016 0.4996 0.3797
56 17__Main TS 0.0193 0.1032 0.4979 0.3796
57 18__Main TS 0.0195 0.1048 0.4962 0.3795
58 19__Main TS 0.0198 0.1065 0.4944 0.3794
59 20__Main TS 0.0201 0.1082 0.4925 0.3792
60 21__Main TS 0.0203 0.1101 0.4905 0.3791
61 22__Main TS 0.0206 0.1120 0.4884 0.3789
62 23__Main TS 0.0209 0.1141 0.4862 0.3788
63 24__Main TS 0.0213 0.1162 0.4839 0.3786
64 25__Main TS 0.0216 0.1186 0.4813 0.3784
65 26__Main TS 0.0220 0.1212 0.4786 0.3783
66 27__Main TS 0.0224 0.1240 0.4756 0.3780
67 28__Main TS 0.0228 0.1271 0.4723 0.3778
68 29__Main TS 0.0233 0.1305 0.4686 0.3776
1
Case Name: NRTL.HSC
2 LEGENDS
4 USA
5
6
8
9
11 30__Main TS 0.0239 0.1344 0.4644 0.3773
12 31__Main TS 0.0246 0.1387 0.4597 0.3770
13 32__Main TS 0.0253 0.1438 0.4542 0.3767
14 33__Main TS 0.0261 0.1497 0.4478 0.3764
15 34__Main TS 0.0271 0.1566 0.4402 0.3760
16 35__Main TS 0.0283 0.1650 0.4310 0.3758
17 36__Main TS 0.0297 0.1752 0.4195 0.3756
18 37__Main TS 0.0314 0.1879 0.4050 0.3757
19 38__Main TS 0.0334 0.2039 0.3864 0.3763
20 39__Main TS 0.0359 0.2245 0.3621 0.3775
21 40__Main TS 0.0387 0.2509 0.3307 0.3797
22 41__Main TS 0.0419 0.2843 0.2914 0.3823
23 42__Main TS 0.0457 0.3250 0.2456 0.3838
24 43__Main TS 0.0501 0.3719 0.1970 0.3810
25 44__Main TS 0.0560 0.4228 0.1509 0.3703
26 45__Main TS 0.0643 0.4757 0.1109 0.3490
27 46__Main TS 0.0760 0.5294 0.0780 0.3166
28 47__Main TS 0.0915 0.5820 0.0512 0.2752
29 48__Main TS 0.1112 0.6273 0.0303 0.2311
30 49__Main TS 0.1410 0.6404 0.0159 0.2028
31 Reboiler 0.0519 0.6553 0.0033 0.2896
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
APPENDIX B9:
EFFECT OF
RECTIFYING AND
STRIPPING STAGE
1
Case Name: F0 = STAGE 2, F1 = STAGE 16.HSC
2 LEGENDS
4 USA
5
Date/Time: Wed Jun 03 22:46:58 2015
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 72.25 72.25
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2385 0.2385
34 Heat Flow (kJ/h) -1400 -1400
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0222 0.0033 0.0139 0.0000 0.0159
43 H2O 0.0006 0.1820 0.0107 0.0447 0.0000 0.0408
44 E-Acetate 0.0025 0.7595 0.2175 0.9117 0.0002 0.9176
45 AceticAcid 0.0001 0.0363 0.0071 0.0297 0.0000 0.0257
46 Total 0.0032 1.0000 0.2385 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0222 0.0033 0.0139 0.0000 0.0159
52 H2O 0.0006 0.1820 0.0107 0.0447 0.0000 0.0408
53 E-Acetate 0.0025 0.7595 0.2175 0.9117 0.0002 0.9176
54 AceticAcid 0.0001 0.0363 0.0071 0.0297 0.0000 0.0257
55 Total 0.0032 1.0000 0.2385 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 96.87 96.87
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1258 0.1258
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1247 -1247
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0442 0.0074 0.0591 0.0000 0.0753
22 H2O 0.0022 0.5959 0.0392 0.3116 0.0000 0.3167
23 E-Acetate 0.0000 0.0025 0.0008 0.0063 0.0000 0.0071
24 AceticAcid 0.0013 0.3574 0.0783 0.6230 0.0001 0.6010
25 Total 0.0036 1.0000 0.1258 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0442 0.0074 0.0591 0.0000 0.0753
31 H2O 0.0022 0.5959 0.0392 0.3116 0.0000 0.3167
32 E-Acetate 0.0000 0.0025 0.0008 0.0063 0.0000 0.0071
33 AceticAcid 0.0013 0.3574 0.0783 0.6230 0.0001 0.6010
34 Total 0.0036 1.0000 0.1258 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 72.25 72.25 72.25
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5964 0.0000 0.5964
49 Heat Flow (kJ/h) -3501 0.0000 -3501
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0222 0.0083 0.0139 0.0000 0.0159
58 H2O 0.0015 0.1820 0.0266 0.0447 0.0000 0.0408
59 E-Acetate 0.0062 0.7595 0.5437 0.9117 0.0006 0.9176
60 AceticAcid 0.0003 0.0363 0.0177 0.0297 0.0000 0.0257
61 Total 0.0081 1.0000 0.5964 1.0000 0.0007 1.0000
62
63
66 Ethanol 0.0000 0.0272 0.0000 0.0178 0.0000 0.0204
67 H2O 0.0000 0.2370 0.0000 0.0609 0.0000 0.0554
68 E-Acetate 0.0000 0.7286 0.0000 0.9151 0.0000 0.9189
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0072 0.0000 0.0062 0.0000 0.0054
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0222 0.0083 0.0139 0.0000 0.0159
22 H2O 0.0015 0.1820 0.0266 0.0447 0.0000 0.0408
23 E-Acetate 0.0062 0.7595 0.5437 0.9117 0.0006 0.9176
24 AceticAcid 0.0003 0.0363 0.0177 0.0297 0.0000 0.0257
25 Total 0.0081 1.0000 0.5964 1.0000 0.0007 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 2__Main TS
11 F1 16__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0222 0.0442
59 H2O 0.1820 0.5959
60 E-Acetate 0.7595 0.0025
61 AceticAcid 0.0363 0.3574
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0002 *
68 H2O (kgmole/h) 0.0006 * 0.0022 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.6614 5.9481
20 H2O (%) 204.5211 752.0991
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 3.0252 33.4513
23
COLUMN PROFILES
24
29 Condenser 72.2 100 8.125e-003 --- --- 3.250e-003 392 *
30 1__Main TS 75.7 100 8.361e-003 1.138e-002 --- --- ---
31 2__Main TS 83.0 100 1.324e-002 1.161e-002 3.900e-003 --- ---
32 3__Main TS 83.0 100 1.319e-002 1.259e-002 --- --- ---
33 4__Main TS 82.9 100 1.313e-002 1.254e-002 --- --- ---
34 5__Main TS 82.8 100 1.306e-002 1.248e-002 --- --- ---
35 6__Main TS 82.8 100 1.299e-002 1.241e-002 --- --- ---
36 7__Main TS 82.7 100 1.290e-002 1.234e-002 --- --- ---
37 8__Main TS 82.6 100 1.278e-002 1.225e-002 --- --- ---
38 9__Main TS 82.6 100 1.262e-002 1.213e-002 --- --- ---
39 10__Main TS 82.5 100 1.242e-002 1.197e-002 --- --- ---
40 11__Main TS 82.5 100 1.215e-002 1.177e-002 --- --- ---
41 12__Main TS 82.5 100 1.179e-002 1.150e-002 --- --- ---
42 13__Main TS 82.7 100 1.134e-002 1.114e-002 --- --- ---
43 14__Main TS 83.0 100 1.080e-002 1.069e-002 --- --- ---
44 15__Main TS 83.4 100 1.024e-002 1.015e-002 --- --- ---
45 16__Main TS 83.7 100 1.351e-002 9.591e-003 3.000e-003 --- ---
46 17__Main TS 90.7 100 1.388e-002 9.860e-003 --- --- ---
47 Reboiler 96.9 100 --- 1.023e-002 --- 3.650e-003 381 *
51 Condenser 72.25 -4.309e+005 -3.850e+005 ---
52 1__Main TS 75.67 -4.396e+005 -3.964e+005 ---
53 2__Main TS 83.04 -4.409e+005 -4.034e+005 ---
54 3__Main TS 82.97 -4.387e+005 -4.009e+005 ---
55 4__Main TS 82.90 -4.363e+005 -3.984e+005 ---
56 5__Main TS 82.83 -4.337e+005 -3.958e+005 ---
57 6__Main TS 82.76 -4.308e+005 -3.928e+005 ---
58 7__Main TS 82.69 -4.273e+005 -3.895e+005 ---
59 8__Main TS 82.62 -4.230e+005 -3.855e+005 ---
60 9__Main TS 82.56 -4.175e+005 -3.805e+005 ---
61 10__Main TS 82.50 -4.104e+005 -3.742e+005 ---
62 11__Main TS 82.48 -4.011e+005 -3.660e+005 ---
63 12__Main TS 82.53 -3.889e+005 -3.551e+005 ---
64 13__Main TS 82.71 -3.733e+005 -3.407e+005 ---
65 14__Main TS 83.04 -3.546e+005 -3.221e+005 ---
66 15__Main TS 83.43 -3.348e+005 -2.995e+005 ---
67 16__Main TS 83.69 -3.173e+005 -2.751e+005 ---
68 17__Main TS 90.75 -3.247e+005 -2.696e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 96.87 -3.416e+005 -2.814e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 3.9e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 72.25*
21 1__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
37 17__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.4e+005 * 96.87*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.40e-002 940 75.0
37
38 1.20e-002
39
920
65.0
40
1.00e-002 910
41
Density (kg/m3)
60.0
42
900
43 8.00e-003 55.0
44 890
45 50.0
6.00e-003
46 880
47 45.0
4.00e-003 870
48
49 40.0
860
50 2.00e-003
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 6.00
14
15
16
17 0.600
18
4.00
Mole Fraction
19 0.500
K Value
20
21 0.400 3.00
22
23
0.300
24 2.00
25
0.200
26
27 1.00
1.00e-001
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.53 71.53
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2346 0.2346
34 Heat Flow (kJ/h) -1385 -1385
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0239 0.0036 0.0153 0.0000 0.0174
43 H2O 0.0007 0.2081 0.0122 0.0519 0.0000 0.0473
44 E-Acetate 0.0025 0.7561 0.2165 0.9229 0.0002 0.9267
45 AceticAcid 0.0000 0.0119 0.0023 0.0099 0.0000 0.0085
46 Total 0.0032 1.0000 0.2346 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0239 0.0036 0.0153 0.0000 0.0174
52 H2O 0.0007 0.2081 0.0122 0.0519 0.0000 0.0473
53 E-Acetate 0.0025 0.7561 0.2165 0.9229 0.0002 0.9267
54 AceticAcid 0.0000 0.0119 0.0023 0.0099 0.0000 0.0085
55 Total 0.0032 1.0000 0.2346 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 97.23 97.23
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1297 0.1297
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1262 -1262
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0466 0.0078 0.0604 0.0000 0.0770
22 H2O 0.0021 0.5688 0.0374 0.2883 0.0000 0.2934
23 E-Acetate 0.0000 0.0016 0.0005 0.0039 0.0000 0.0043
24 AceticAcid 0.0014 0.3831 0.0840 0.6474 0.0001 0.6253
25 Total 0.0036 1.0000 0.1297 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0466 0.0078 0.0604 0.0000 0.0770
31 H2O 0.0021 0.5688 0.0374 0.2883 0.0000 0.2934
32 E-Acetate 0.0000 0.0016 0.0005 0.0039 0.0000 0.0043
33 AceticAcid 0.0014 0.3831 0.0840 0.6474 0.0001 0.6253
34 Total 0.0036 1.0000 0.1297 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.53 71.53 71.53
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5865 0.0000 0.5865
49 Heat Flow (kJ/h) -3462 0.0000 -3462
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0239 0.0090 0.0153 0.0000 0.0174
58 H2O 0.0017 0.2081 0.0305 0.0519 0.0000 0.0473
59 E-Acetate 0.0061 0.7561 0.5413 0.9229 0.0006 0.9267
60 AceticAcid 0.0001 0.0119 0.0058 0.0099 0.0000 0.0085
61 Total 0.0081 1.0000 0.5865 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0300 0.0000 0.0200 0.0000 0.0228
67 H2O 0.0000 0.2533 0.0000 0.0661 0.0000 0.0602
68 E-Acetate 0.0000 0.7145 0.0000 0.9119 0.0000 0.9153
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0022 0.0000 0.0019 0.0000 0.0017
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0239 0.0090 0.0153 0.0000 0.0174
22 H2O 0.0017 0.2081 0.0305 0.0519 0.0000 0.0473
23 E-Acetate 0.0061 0.7561 0.5413 0.9229 0.0006 0.9267
24 AceticAcid 0.0001 0.0119 0.0058 0.0099 0.0000 0.0085
25 Total 0.0081 1.0000 0.5865 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 3__Main TS
11 F1 15__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0239 0.0466
59 H2O 0.2081 0.5688
60 E-Acetate 0.7561 0.0016
61 AceticAcid 0.0119 0.3831
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0002 *
68 H2O (kgmole/h) 0.0007 * 0.0021 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 2.8696 6.2710
20 H2O (%) 233.8319 717.8094
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.9906 35.8552
23
COLUMN PROFILES
24
29 Condenser 71.5 100 8.125e-003 --- --- 3.250e-003 396 *
30 1__Main TS 73.0 100 8.312e-003 1.138e-002 --- --- ---
31 2__Main TS 76.4 100 8.518e-003 1.156e-002 --- --- ---
32 3__Main TS 83.3 100 1.336e-002 1.177e-002 3.900e-003 --- ---
33 4__Main TS 83.2 100 1.328e-002 1.271e-002 --- --- ---
34 5__Main TS 83.0 100 1.319e-002 1.263e-002 --- --- ---
35 6__Main TS 82.9 100 1.309e-002 1.254e-002 --- --- ---
36 7__Main TS 82.7 100 1.296e-002 1.244e-002 --- --- ---
37 8__Main TS 82.6 100 1.280e-002 1.231e-002 --- --- ---
38 9__Main TS 82.4 100 1.260e-002 1.215e-002 --- --- ---
39 10__Main TS 82.1 100 1.233e-002 1.195e-002 --- --- ---
40 11__Main TS 81.8 100 1.198e-002 1.168e-002 --- --- ---
41 12__Main TS 81.4 100 1.153e-002 1.133e-002 --- --- ---
42 13__Main TS 81.1 100 1.098e-002 1.088e-002 --- --- ---
43 14__Main TS 80.8 100 1.036e-002 1.033e-002 --- --- ---
44 15__Main TS 80.2 100 1.351e-002 9.714e-003 3.000e-003 --- ---
45 16__Main TS 85.1 100 1.364e-002 9.856e-003 --- --- ---
46 17__Main TS 91.4 100 1.405e-002 9.989e-003 --- --- ---
47 Reboiler 97.2 100 --- 1.040e-002 --- 3.650e-003 385 *
51 Condenser 71.53 -4.260e+005 -3.813e+005 ---
52 1__Main TS 73.04 -4.395e+005 -3.913e+005 ---
53 2__Main TS 76.38 -4.446e+005 -4.015e+005 ---
54 3__Main TS 83.31 -4.430e+005 -4.059e+005 ---
55 4__Main TS 83.16 -4.397e+005 -4.021e+005 ---
56 5__Main TS 83.02 -4.363e+005 -3.983e+005 ---
57 6__Main TS 82.89 -4.324e+005 -3.944e+005 ---
58 7__Main TS 82.75 -4.280e+005 -3.900e+005 ---
59 8__Main TS 82.58 -4.227e+005 -3.849e+005 ---
60 9__Main TS 82.37 -4.160e+005 -3.788e+005 ---
61 10__Main TS 82.11 -4.075e+005 -3.710e+005 ---
62 11__Main TS 81.80 -3.962e+005 -3.609e+005 ---
63 12__Main TS 81.45 -3.815e+005 -3.476e+005 ---
64 13__Main TS 81.10 -3.628e+005 -3.300e+005 ---
65 14__Main TS 80.75 -3.403e+005 -3.073e+005 ---
66 15__Main TS 80.21 -3.160e+005 -2.799e+005 ---
67 16__Main TS 85.05 -3.165e+005 -2.659e+005 ---
68 17__Main TS 91.43 -3.267e+005 -2.673e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 97.23 -3.459e+005 -2.829e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.0e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.3e+005 * 71.53*
21 1__Main TS
22 2__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
36 16__Main TS
37 17__Main TS
38 Q_R Energy 3.8e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.5e+005 * 97.23*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.60e-002 940 80.0
37
38 1.40e-002
39
920 70.0
40 1.20e-002
41 910 65.0
Density (kg/m3)
42 1.00e-002
900 60.0
43
44 8.00e-003 890 55.0
45
46 880 50.0
6.00e-003
47
870 45.0
48
4.00e-003
49 860 40.0
50
2.00e-003
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 6.00
14
15
16
17 0.600
18
4.00
Mole Fraction
19 0.500
K Value
20
21 0.400 3.00
22
23
0.300
24 2.00
25
0.200
26
27 1.00
1.00e-001
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.23 71.23
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2289 0.2289
34 Heat Flow (kJ/h) -1366 -1366
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0290 0.0043 0.0190 0.0000 0.0216
43 H2O 0.0008 0.2332 0.0137 0.0597 0.0000 0.0543
44 E-Acetate 0.0024 0.7341 0.2102 0.9182 0.0002 0.9214
45 AceticAcid 0.0000 0.0037 0.0007 0.0031 0.0000 0.0027
46 Total 0.0033 1.0000 0.2289 1.0000 0.0003 1.0000
47
48
51 Ethanol 0.0001 0.0290 0.0043 0.0190 0.0000 0.0216
52 H2O 0.0008 0.2332 0.0137 0.0597 0.0000 0.0543
53 E-Acetate 0.0024 0.7341 0.2102 0.9182 0.0002 0.9214
54 AceticAcid 0.0000 0.0037 0.0007 0.0031 0.0000 0.0027
55 Total 0.0032 1.0000 0.2289 1.0000 0.0003 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 96.88 96.88
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1354 0.1354
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1279 -1279
15
16
COMPOSITION
17
18
21 Ethanol 0.0002 0.0619 0.0104 0.0769 0.0000 0.0978
22 H2O 0.0019 0.5264 0.0346 0.2557 0.0000 0.2593
23 E-Acetate 0.0000 0.0013 0.0004 0.0030 0.0000 0.0034
24 AceticAcid 0.0015 0.4103 0.0899 0.6643 0.0001 0.6395
25 Total 0.0036 1.0000 0.1354 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0002 0.0619 0.0104 0.0769 0.0000 0.0978
31 H2O 0.0019 0.5264 0.0346 0.2557 0.0000 0.2593
32 E-Acetate 0.0000 0.0013 0.0004 0.0030 0.0000 0.0034
33 AceticAcid 0.0015 0.4103 0.0899 0.6643 0.0001 0.6395
34 Total 0.0036 1.0000 0.1354 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.23 71.23 71.23
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5723 0.0000 0.5723
49 Heat Flow (kJ/h) -3416 0.0000 -3416
51
52
COMPOSITION
53
54
57 Ethanol 0.0002 0.0290 0.0109 0.0190 0.0000 0.0216
58 H2O 0.0019 0.2332 0.0341 0.0597 0.0000 0.0543
59 E-Acetate 0.0060 0.7341 0.5255 0.9182 0.0006 0.9214
60 AceticAcid 0.0000 0.0037 0.0018 0.0031 0.0000 0.0027
61 Total 0.0081 1.0000 0.5723 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0362 0.0000 0.0245 0.0000 0.0279
67 H2O 0.0000 0.2626 0.0000 0.0694 0.0000 0.0631
68 E-Acetate 0.0000 0.7005 0.0000 0.9055 0.0000 0.9085
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0006 0.0000 0.0006 0.0000 0.0005
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0002 0.0290 0.0109 0.0190 0.0000 0.0216
22 H2O 0.0019 0.2332 0.0341 0.0597 0.0000 0.0543
23 E-Acetate 0.0060 0.7341 0.5255 0.9182 0.0006 0.9214
24 AceticAcid 0.0000 0.0037 0.0018 0.0031 0.0000 0.0027
25 Total 0.0081 1.0000 0.5723 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 4__Main TS
11 F1 14__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0290 0.0619
59 H2O 0.2332 0.5264
60 E-Acetate 0.7341 0.0013
61 AceticAcid 0.0037 0.4103
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0002 *
68 H2O (kgmole/h) 0.0008 * 0.0019 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 3.4784 8.3412
20 H2O (%) 262.1196 664.4119
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.3057 38.4021
23
COLUMN PROFILES
24
29 Condenser 71.2 100 8.125e-003 --- --- 3.250e-003 398 *
30 1__Main TS 71.9 100 8.278e-003 1.138e-002 --- --- ---
31 2__Main TS 73.5 100 8.448e-003 1.153e-002 --- --- ---
32 3__Main TS 76.6 100 8.617e-003 1.170e-002 --- --- ---
33 4__Main TS 83.3 100 1.342e-002 1.187e-002 3.900e-003 --- ---
34 5__Main TS 83.0 100 1.329e-002 1.277e-002 --- --- ---
35 6__Main TS 82.8 100 1.316e-002 1.264e-002 --- --- ---
36 7__Main TS 82.5 100 1.299e-002 1.251e-002 --- --- ---
37 8__Main TS 82.2 100 1.278e-002 1.234e-002 --- --- ---
38 9__Main TS 81.9 100 1.252e-002 1.213e-002 --- --- ---
39 10__Main TS 81.4 100 1.217e-002 1.187e-002 --- --- ---
40 11__Main TS 80.9 100 1.172e-002 1.152e-002 --- --- ---
41 12__Main TS 80.2 100 1.118e-002 1.107e-002 --- --- ---
42 13__Main TS 79.4 100 1.055e-002 1.053e-002 --- --- ---
43 14__Main TS 78.4 100 1.365e-002 9.899e-003 3.000e-003 --- ---
44 15__Main TS 81.1 100 1.363e-002 1.000e-002 --- --- ---
45 16__Main TS 85.0 100 1.377e-002 9.979e-003 --- --- ---
46 17__Main TS 90.8 100 1.421e-002 1.012e-002 --- --- ---
47 Reboiler 96.9 100 --- 1.056e-002 --- 3.650e-003 390 *
51 Condenser 71.23 -4.204e+005 -3.782e+005 ---
52 1__Main TS 71.87 -4.340e+005 -3.854e+005 ---
53 2__Main TS 73.51 -4.445e+005 -3.956e+005 ---
54 3__Main TS 76.62 -4.468e+005 -4.038e+005 ---
55 4__Main TS 83.26 -4.432e+005 -4.060e+005 ---
56 5__Main TS 83.01 -4.386e+005 -4.007e+005 ---
57 6__Main TS 82.78 -4.337e+005 -3.955e+005 ---
58 7__Main TS 82.54 -4.281e+005 -3.899e+005 ---
59 8__Main TS 82.24 -4.215e+005 -3.834e+005 ---
60 9__Main TS 81.88 -4.132e+005 -3.757e+005 ---
61 10__Main TS 81.42 -4.024e+005 -3.658e+005 ---
62 11__Main TS 80.86 -3.884e+005 -3.531e+005 ---
63 12__Main TS 80.20 -3.702e+005 -3.363e+005 ---
64 13__Main TS 79.45 -3.472e+005 -3.142e+005 ---
65 14__Main TS 78.36 -3.189e+005 -2.862e+005 ---
66 15__Main TS 81.12 -3.125e+005 -2.685e+005 ---
67 16__Main TS 85.04 -3.155e+005 -2.596e+005 ---
68 17__Main TS 90.76 -3.279e+005 -2.644e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 96.88 -3.504e+005 -2.833e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.0e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.2e+005 * 71.23*
21 1__Main TS
22 2__Main TS
23 3__Main TS
25 5__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
33 13__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS
38 Q_R Energy 3.9e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.5e+005 * 96.88*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.60e-002 940 80.0
37
38 1.40e-002
39
920 70.0
40 1.20e-002
41 910 65.0
Density (kg/m3)
42 1.00e-002
900 60.0
43
44 8.00e-003 890 55.0
45
46 880 50.0
6.00e-003
47
870 45.0
48
4.00e-003
49 860 40.0
50
2.00e-003
51 850 35.0
52
0.000 840 30.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.900 5.00
14
0.800 H2O (Light) 4.50 H2O
15
16 4.00
0.700 AceticAcid (Light) AceticAcid
17
18 3.50
0.600
Mole Fraction
19
3.00
K Value
20 0.500
21 2.50
22 0.400
23 2.00
24 0.300
1.50
25
26 0.200
1.00
27
28 1.00e-001 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 71.06 71.06
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2226 0.2226
34 Heat Flow (kJ/h) -1346 -1346
36
37
COMPOSITION
38
39
42 Ethanol 0.0001 0.0401 0.0060 0.0270 0.0000 0.0308
43 H2O 0.0008 0.2554 0.0150 0.0672 0.0000 0.0611
44 E-Acetate 0.0023 0.7036 0.2015 0.9051 0.0002 0.9075
45 AceticAcid 0.0000 0.0009 0.0002 0.0008 0.0000 0.0007
46 Total 0.0033 1.0000 0.2226 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0001 0.0401 0.0060 0.0270 0.0000 0.0308
52 H2O 0.0008 0.2554 0.0150 0.0672 0.0000 0.0611
53 E-Acetate 0.0023 0.7036 0.2015 0.9051 0.0002 0.9075
54 AceticAcid 0.0000 0.0009 0.0002 0.0008 0.0000 0.0007
55 Total 0.0032 1.0000 0.2226 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 96.60 96.60
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1417 0.1417
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1297 -1297
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0794 0.0133 0.0942 0.0000 0.1194
22 H2O 0.0017 0.4794 0.0315 0.2224 0.0000 0.2248
23 E-Acetate 0.0000 0.0011 0.0004 0.0025 0.0000 0.0028
24 AceticAcid 0.0016 0.4402 0.0965 0.6809 0.0001 0.6531
25 Total 0.0036 1.0000 0.1417 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0794 0.0133 0.0942 0.0000 0.1194
31 H2O 0.0017 0.4794 0.0315 0.2224 0.0000 0.2248
32 E-Acetate 0.0000 0.0011 0.0004 0.0025 0.0000 0.0028
33 AceticAcid 0.0016 0.4402 0.0965 0.6809 0.0001 0.6531
34 Total 0.0036 1.0000 0.1417 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 71.06 71.06 71.06
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5565 0.0000 0.5565
49 Heat Flow (kJ/h) -3365 0.0000 -3365
51
52
COMPOSITION
53
54
57 Ethanol 0.0003 0.0401 0.0150 0.0270 0.0000 0.0308
58 H2O 0.0021 0.2554 0.0374 0.0672 0.0000 0.0611
59 E-Acetate 0.0057 0.7036 0.5037 0.9051 0.0006 0.9075
60 AceticAcid 0.0000 0.0009 0.0004 0.0008 0.0000 0.0007
61 Total 0.0081 1.0000 0.5565 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0493 0.0000 0.0338 0.0000 0.0384
67 H2O 0.0000 0.2666 0.0000 0.0713 0.0000 0.0648
68 E-Acetate 0.0000 0.6840 0.0000 0.8948 0.0000 0.8967
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0001 0.0000 0.0001 0.0000 0.0001
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0003 0.0401 0.0150 0.0270 0.0000 0.0308
22 H2O 0.0021 0.2554 0.0374 0.0672 0.0000 0.0611
23 E-Acetate 0.0057 0.7036 0.5037 0.9051 0.0006 0.9075
24 AceticAcid 0.0000 0.0009 0.0004 0.0008 0.0000 0.0007
25 Total 0.0081 1.0000 0.5565 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 5__Main TS
11 F1 13__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0401 0.0794
59 H2O 0.2554 0.4794
60 E-Acetate 0.7036 0.0011
61 AceticAcid 0.0009 0.4402
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0001 * 0.0003 *
68 H2O (kgmole/h) 0.0008 * 0.0017 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 4.8133 10.6876
20 H2O (%) 287.0303 604.9949
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.0721 41.1945
23
COLUMN PROFILES
24
29 Condenser 71.1 100 8.125e-003 --- --- 3.250e-003 402 *
30 1__Main TS 71.3 100 8.217e-003 1.138e-002 --- --- ---
31 2__Main TS 71.9 100 8.355e-003 1.147e-002 --- --- ---
32 3__Main TS 73.4 100 8.501e-003 1.160e-002 --- --- ---
33 4__Main TS 76.3 100 8.645e-003 1.175e-002 --- --- ---
34 5__Main TS 83.0 100 1.340e-002 1.189e-002 3.900e-003 --- ---
35 6__Main TS 82.6 100 1.321e-002 1.275e-002 --- --- ---
36 7__Main TS 82.2 100 1.300e-002 1.256e-002 --- --- ---
37 8__Main TS 81.8 100 1.273e-002 1.235e-002 --- --- ---
38 9__Main TS 81.3 100 1.238e-002 1.208e-002 --- --- ---
39 10__Main TS 80.6 100 1.194e-002 1.173e-002 --- --- ---
40 11__Main TS 79.8 100 1.140e-002 1.129e-002 --- --- ---
41 12__Main TS 78.8 100 1.077e-002 1.075e-002 --- --- ---
42 13__Main TS 77.5 100 1.386e-002 1.012e-002 3.000e-003 --- ---
43 14__Main TS 79.4 100 1.378e-002 1.021e-002 --- --- ---
44 15__Main TS 81.7 100 1.378e-002 1.013e-002 --- --- ---
45 16__Main TS 84.9 100 1.393e-002 1.013e-002 --- --- ---
46 17__Main TS 90.2 100 1.440e-002 1.028e-002 --- --- ---
47 Reboiler 96.6 100 --- 1.075e-002 --- 3.650e-003 395 *
51 Condenser 71.06 -4.141e+005 -3.747e+005 ---
52 1__Main TS 71.27 -4.231e+005 -3.788e+005 ---
53 2__Main TS 71.90 -4.349e+005 -3.855e+005 ---
54 3__Main TS 73.40 -4.435e+005 -3.944e+005 ---
55 4__Main TS 76.35 -4.446e+005 -4.012e+005 ---
56 5__Main TS 82.96 -4.403e+005 -4.025e+005 ---
57 6__Main TS 82.60 -4.341e+005 -3.957e+005 ---
58 7__Main TS 82.23 -4.272e+005 -3.886e+005 ---
59 8__Main TS 81.79 -4.189e+005 -3.805e+005 ---
60 9__Main TS 81.26 -4.084e+005 -3.707e+005 ---
61 10__Main TS 80.59 -3.949e+005 -3.583e+005 ---
62 11__Main TS 79.79 -3.773e+005 -3.421e+005 ---
63 12__Main TS 78.84 -3.545e+005 -3.207e+005 ---
64 13__Main TS 77.50 -3.245e+005 -2.929e+005 ---
65 14__Main TS 79.43 -3.146e+005 -2.747e+005 ---
66 15__Main TS 81.70 -3.108e+005 -2.609e+005 ---
67 16__Main TS 84.93 -3.153e+005 -2.557e+005 ---
68 17__Main TS 90.16 -3.295e+005 -2.626e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 96.60 -3.554e+005 -2.840e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.0e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.1e+005 * 71.06*
21 1__Main TS
22 2__Main TS
23 3__Main TS
24 4__Main TS
26 6__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
32 12__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS
38 Q_R Energy 4.0e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.6e+005 * 96.60*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.60e-002 940 80.0
37
38
920
39
70.0
40 1.20e-002
41
Density (kg/m3)
900 65.0
42 1.00e-002
43 60.0
44 8.00e-003 880
45 55.0
46
6.00e-003
47 860 50.0
48
4.00e-003
49 45.0
50 840
2.00e-003 40.0
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.900 4.50
14
0.800 H2O (Light) 4.00 H2O
15
16
0.700 AceticAcid (Light) 3.50 AceticAcid
17
18
0.600 3.00
Mole Fraction
19
K Value
20 0.500 2.50
21
22 0.400 2.00
23
24 0.300 1.50
25
26 0.200 1.00
27
28 1.00e-001 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.90 70.90
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2177 0.2177
34 Heat Flow (kJ/h) -1326 -1326
36
37
COMPOSITION
38
39
42 Ethanol 0.0002 0.0645 0.0097 0.0444 0.0000 0.0505
43 H2O 0.0009 0.2627 0.0154 0.0707 0.0000 0.0641
44 E-Acetate 0.0022 0.6727 0.1926 0.8849 0.0002 0.8853
45 AceticAcid 0.0000 0.0001 0.0000 0.0001 0.0000 0.0001
46 Total 0.0032 1.0000 0.2177 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0002 0.0645 0.0097 0.0444 0.0000 0.0505
52 H2O 0.0009 0.2627 0.0154 0.0707 0.0000 0.0641
53 E-Acetate 0.0022 0.6727 0.1926 0.8849 0.0002 0.8853
54 AceticAcid 0.0000 0.0001 0.0000 0.0001 0.0000 0.0001
55 Total 0.0032 1.0000 0.2177 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 96.89 96.89
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1466 0.1466
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1315 -1315
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0855 0.0144 0.0981 0.0000 0.1243
22 H2O 0.0016 0.4450 0.0293 0.1996 0.0000 0.2017
23 E-Acetate 0.0000 0.0008 0.0002 0.0017 0.0000 0.0018
24 AceticAcid 0.0017 0.4687 0.1027 0.7007 0.0001 0.6721
25 Total 0.0036 1.0000 0.1466 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0855 0.0144 0.0981 0.0000 0.1243
31 H2O 0.0016 0.4450 0.0293 0.1996 0.0000 0.2017
32 E-Acetate 0.0000 0.0008 0.0002 0.0017 0.0000 0.0018
33 AceticAcid 0.0017 0.4687 0.1027 0.7007 0.0001 0.6721
34 Total 0.0036 1.0000 0.1466 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.90 70.90 70.90
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5442 0.0000 0.5442
49 Heat Flow (kJ/h) -3314 0.0000 -3314
51
52
COMPOSITION
53
54
57 Ethanol 0.0005 0.0645 0.0241 0.0444 0.0000 0.0505
58 H2O 0.0021 0.2627 0.0385 0.0707 0.0000 0.0641
59 E-Acetate 0.0055 0.6727 0.4815 0.8849 0.0005 0.8853
60 AceticAcid 0.0000 0.0001 0.0001 0.0001 0.0000 0.0001
61 Total 0.0081 1.0000 0.5442 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.0766 0.0000 0.0531 0.0000 0.0603
67 H2O 0.0000 0.2620 0.0000 0.0710 0.0000 0.0643
68 E-Acetate 0.0000 0.6613 0.0000 0.8759 0.0000 0.8754
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0005 0.0645 0.0241 0.0444 0.0000 0.0505
22 H2O 0.0021 0.2627 0.0385 0.0707 0.0000 0.0641
23 E-Acetate 0.0055 0.6727 0.4815 0.8849 0.0005 0.8853
24 AceticAcid 0.0000 0.0001 0.0001 0.0001 0.0000 0.0001
25 Total 0.0081 1.0000 0.5442 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 6__Main TS
11 F1 12__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.0645 0.0855
59 H2O 0.2627 0.4450
60 E-Acetate 0.6727 0.0008
61 AceticAcid 0.0001 0.4687
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0002 * 0.0003 *
68 H2O (kgmole/h) 0.0009 * 0.0016 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 7.7331 11.5183
20 H2O (%) 295.2289 561.6420
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.0100 43.8636
23
COLUMN PROFILES
24
29 Condenser 70.9 100 8.125e-003 --- --- 3.250e-003 404 *
30 1__Main TS 71.0 100 8.158e-003 1.138e-002 --- --- ---
31 2__Main TS 71.1 100 8.216e-003 1.141e-002 --- --- ---
32 3__Main TS 71.5 100 8.309e-003 1.147e-002 --- --- ---
33 4__Main TS 72.6 100 8.423e-003 1.156e-002 --- --- ---
34 5__Main TS 75.5 100 8.555e-003 1.167e-002 --- --- ---
35 6__Main TS 82.4 100 1.322e-002 1.180e-002 3.900e-003 --- ---
36 7__Main TS 81.9 100 1.294e-002 1.257e-002 --- --- ---
37 8__Main TS 81.3 100 1.259e-002 1.229e-002 --- --- ---
38 9__Main TS 80.6 100 1.215e-002 1.194e-002 --- --- ---
39 10__Main TS 79.7 100 1.160e-002 1.150e-002 --- --- ---
40 11__Main TS 78.7 100 1.096e-002 1.095e-002 --- --- ---
41 12__Main TS 77.1 100 1.405e-002 1.031e-002 3.000e-003 --- ---
42 13__Main TS 78.8 100 1.396e-002 1.040e-002 --- --- ---
43 14__Main TS 80.5 100 1.391e-002 1.031e-002 --- --- ---
44 15__Main TS 82.4 100 1.393e-002 1.026e-002 --- --- ---
45 16__Main TS 85.3 100 1.410e-002 1.028e-002 --- --- ---
46 17__Main TS 90.4 100 1.462e-002 1.045e-002 --- --- ---
47 Reboiler 96.9 100 --- 1.097e-002 --- 3.650e-003 400 *
51 Condenser 70.90 -4.079e+005 -3.700e+005 ---
52 1__Main TS 70.98 -4.116e+005 -3.724e+005 ---
53 2__Main TS 71.11 -4.172e+005 -3.751e+005 ---
54 3__Main TS 71.49 -4.257e+005 -3.793e+005 ---
55 4__Main TS 72.63 -4.335e+005 -3.857e+005 ---
56 5__Main TS 75.51 -4.349e+005 -3.917e+005 ---
57 6__Main TS 82.45 -4.320e+005 -3.932e+005 ---
58 7__Main TS 81.94 -4.235e+005 -3.846e+005 ---
59 8__Main TS 81.34 -4.130e+005 -3.746e+005 ---
60 9__Main TS 80.61 -3.998e+005 -3.621e+005 ---
61 10__Main TS 79.73 -3.825e+005 -3.461e+005 ---
62 11__Main TS 78.65 -3.600e+005 -3.252e+005 ---
63 12__Main TS 77.15 -3.293e+005 -2.977e+005 ---
64 13__Main TS 78.78 -3.183e+005 -2.800e+005 ---
65 14__Main TS 80.51 -3.114e+005 -2.646e+005 ---
66 15__Main TS 82.40 -3.102e+005 -2.551e+005 ---
67 16__Main TS 85.30 -3.163e+005 -2.535e+005 ---
68 17__Main TS 90.35 -3.321e+005 -2.627e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 96.89 -3.602e+005 -2.862e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.0e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.1e+005 * 70.90*
21 1__Main TS
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
27 7__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
31 11__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS
38 Q_R Energy 4.0e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.6e+005 * 96.89*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.60e-002 930 75.0
37
38 1.40e-002 70.0
39
910
40 1.20e-002 65.0
41 900
Density (kg/m3)
42 1.00e-002 60.0
890
43
44 8.00e-003 880 55.0
45
46 870
6.00e-003 50.0
47
860
48
4.00e-003 45.0
49 850
50
2.00e-003 40.0
51 840
52
0.000 830 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.800 4.50
14
0.700 H2O (Light) 4.00 H2O
15
16
17 0.600
18
3.00
Mole Fraction
19 0.500
K Value
20 2.50
21 0.400
22 2.00
23
0.300
24 1.50
25
0.200
26 1.00
27
1.00e-001 0.500
28
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Temperature: (C) 20.00 * 20.00
14 Pressure: (kPa) 120.0 * 120.0
16 Mass Flow (kg/h) 0.2342 0.2342
20 Heat Flow (kJ/h) -1798 -1798
22
23
COMPOSITION
24
25
28 Ethanol 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
29 H2O 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
30 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
31 AceticAcid 0.0039 * 1.0000 * 0.2342 * 1.0000 * 0.0002 * 1.0000 *
32 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
33
34
37 Ethanol 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
38 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
39 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
40 AceticAcid 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
41 Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000
42
44
45
46
CONDITIONS
49 Temperature: (C) 20.00 * 20.00
50 Pressure: (kPa) 120.0 * 120.0
52 Mass Flow (kg/h) 0.1301 0.1301
56 Heat Flow (kJ/h) -838.5 -838.5
58
59
COMPOSITION
60
61
64 Ethanol 0.0027 * 0.9036 * 0.1249 * 0.9600 * 0.0002 * 0.9678 *
65 H2O 0.0003 * 0.0964 * 0.0052 * 0.0400 * 0.0000 * 0.0322 *
66 E-Acetate 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
67 AceticAcid 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 * 0.0000 *
68 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 Ethanol 0.0027 0.9036 0.1249 0.9600 0.0002 0.9678
16 H2O 0.0003 0.0964 0.0052 0.0400 0.0000 0.0322
17 E-Acetate 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
18 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000
20
22
23
24
CONDITIONS
27 Temperature: (C) 70.68 70.68
28 Pressure: (kPa) 100.0 100.0
30 Mass Flow (kg/h) 0.2136 0.2136
34 Heat Flow (kJ/h) -1300 -1300
36
37
COMPOSITION
38
39
42 Ethanol 0.0004 0.1179 0.0176 0.0826 0.0000 0.0935
43 H2O 0.0008 0.2488 0.0146 0.0682 0.0000 0.0615
44 E-Acetate 0.0021 0.6334 0.1814 0.8492 0.0002 0.8450
45 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
46 Total 0.0033 1.0000 0.2136 1.0000 0.0002 1.0000
47
48
51 Ethanol 0.0004 0.1179 0.0176 0.0826 0.0000 0.0935
52 H2O 0.0008 0.2488 0.0146 0.0682 0.0000 0.0615
53 E-Acetate 0.0021 0.6334 0.1814 0.8492 0.0002 0.8450
54 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Total 0.0032 1.0000 0.2136 1.0000 0.0002 1.0000
56
58
59
60
CONDITIONS
63 Temperature: (C) 98.09 98.09
64 Pressure: (kPa) 100.0 100.0
66 Mass Flow (kg/h) 0.1507 0.1507
1
2 LEGENDS
4 USA
5
6
8
9
10
CONDITIONS
13 Heat Flow (kJ/h) -1337 -1337
15
16
COMPOSITION
17
18
21 Ethanol 0.0003 0.0734 0.0123 0.0819 0.0000 0.1044
22 H2O 0.0015 0.4221 0.0278 0.1841 0.0000 0.1872
23 E-Acetate 0.0000 0.0004 0.0001 0.0008 0.0000 0.0009
24 AceticAcid 0.0018 0.5042 0.1105 0.7332 0.0001 0.7075
25 Total 0.0036 1.0000 0.1507 1.0000 0.0001 1.0000
26
27
30 Ethanol 0.0003 0.0734 0.0123 0.0819 0.0000 0.1044
31 H2O 0.0015 0.4221 0.0278 0.1841 0.0000 0.1872
32 E-Acetate 0.0000 0.0004 0.0001 0.0008 0.0000 0.0009
33 AceticAcid 0.0018 0.5042 0.1105 0.7332 0.0001 0.7075
34 Total 0.0036 1.0000 0.1507 1.0000 0.0001 1.0000
35
37
38
39
CONDITIONS
42 Temperature: (C) 70.68 70.68 70.68
43 Pressure: (kPa) 100.0 100.0 100.0
45 Mass Flow (kg/h) 0.5339 0.0000 0.5339
49 Heat Flow (kJ/h) -3249 0.0000 -3249
51
52
COMPOSITION
53
54
57 Ethanol 0.0010 0.1179 0.0441 0.0826 0.0001 0.0935
58 H2O 0.0020 0.2488 0.0364 0.0682 0.0000 0.0615
59 E-Acetate 0.0051 0.6334 0.4534 0.8492 0.0005 0.8450
60 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Total 0.0081 1.0000 0.5339 1.0000 0.0006 1.0000
62
63
66 Ethanol 0.0000 0.1312 0.0000 0.0924 0.0000 0.1044
67 H2O 0.0000 0.2449 0.0000 0.0674 0.0000 0.0607
68 E-Acetate 0.0000 0.6239 0.0000 0.8402 0.0000 0.8349
1
2 LEGENDS
4 USA
5
6
8
9
10
COMPOSITION
11
12
15 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000
17
18
21 Ethanol 0.0010 0.1179 0.0441 0.0826 0.0001 0.0935
22 H2O 0.0020 0.2488 0.0364 0.0682 0.0000 0.0615
23 E-Acetate 0.0051 0.6334 0.4534 0.8492 0.0005 0.8450
24 AceticAcid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
25 Total 0.0081 1.0000 0.5339 1.0000 0.0006 1.0000
26
28
29
30
CONDITIONS
33
35
36
37
CONDITIONS
40
41 Kinetic: Rxn-1
42
43
44
STOICHIOMETRY
46 Ethanol 46.07 -1 * 1.000 0.0000
47 AceticAcid 60.05 -1 * 1.000 0.0000
48 E-Acetate 88.11 1* 0.0000 1.000
49 H2O 18.02 1* 0.0000 1.000
50
52
53
BASIS
55 (C) (C)
57
58
PARAMETERS
60 A: 3317 * A' : 4619 *
61 E: 5.374e+004 * E' : 6.050e+004 *
62
64
65
CONNECTIONS
66
67 Inlet Stream
1
2 LEGENDS
4 USA
5
6
8
9 Q_R Reboiler
10 F0 7__Main TS
11 F1 11__Main TS
12 Outlet Stream
14 Q_C Condenser
15 F2 Condenser
16 F3 Reboiler
17
SOLVER
18
26 Trace Level: Low
30
31
32
SUMMARY
33
35 Feed Composition
36 F0 F1
38 --- ---
39 Ethanol 0.0000 0.9036
40 H2O 0.0000 0.0964
41 E-Acetate 0.0000 0.0000
42 AceticAcid 1.0000 0.0000
44 Feed Flows
45 F0 F1
47 --- ---
49 H2O (kgmole/h) 0.0000 0.0003
52 Products
55 F2 F3
57 --- ---
58 Ethanol 0.1179 0.0734
59 H2O 0.2488 0.4221
60 E-Acetate 0.6334 0.0004
61 AceticAcid 0.0000 0.5042
63 Product Flows
64 F2 F3
66 --- ---
67 Ethanol (kgmole/h) 0.0004 * 0.0003 *
68 H2O (kgmole/h) 0.0008 * 0.0015 *
1
2 LEGENDS
4 USA
5
6
8
9
SUMMARY
10
11 F2 F3
16 F2 F3
18 --- ---
19 Ethanol (%) 14.1325 9.8808
20 H2O (%) 279.5431 532.6938
21 E-Acetate (%) 0.0000 0.0000
22 AceticAcid (%) 0.0009 47.1826
23
COLUMN PROFILES
24
29 Condenser 70.7 100 8.125e-003 --- --- 3.250e-003 407 *
30 1__Main TS 70.7 100 8.141e-003 1.138e-002 --- --- ---
31 2__Main TS 70.8 100 8.160e-003 1.139e-002 --- --- ---
32 3__Main TS 70.8 100 8.190e-003 1.141e-002 --- --- ---
33 4__Main TS 71.1 100 8.236e-003 1.144e-002 --- --- ---
34 5__Main TS 71.8 100 8.291e-003 1.149e-002 --- --- ---
35 6__Main TS 74.5 100 8.379e-003 1.154e-002 --- --- ---
36 7__Main TS 81.8 100 1.288e-002 1.163e-002 3.900e-003 --- ---
37 8__Main TS 81.0 100 1.241e-002 1.223e-002 --- --- ---
38 9__Main TS 80.0 100 1.184e-002 1.176e-002 --- --- ---
39 10__Main TS 78.8 100 1.117e-002 1.119e-002 --- --- ---
40 11__Main TS 77.2 100 1.424e-002 1.052e-002 3.000e-003 --- ---
41 12__Main TS 78.7 100 1.414e-002 1.059e-002 --- --- ---
42 13__Main TS 80.2 100 1.409e-002 1.049e-002 --- --- ---
43 14__Main TS 81.7 100 1.407e-002 1.044e-002 --- --- ---
44 15__Main TS 83.5 100 1.412e-002 1.042e-002 --- --- ---
45 16__Main TS 86.5 100 1.434e-002 1.047e-002 --- --- ---
46 17__Main TS 91.8 100 1.493e-002 1.069e-002 --- --- ---
47 Reboiler 98.1 100 --- 1.128e-002 --- 3.650e-003 406 *
51 Condenser 70.68 -3.999e+005 -3.622e+005 ---
52 1__Main TS 70.73 -4.022e+005 -3.642e+005 ---
53 2__Main TS 70.77 -4.046e+005 -3.658e+005 ---
54 3__Main TS 70.84 -4.077e+005 -3.676e+005 ---
55 4__Main TS 71.05 -4.123e+005 -3.700e+005 ---
56 5__Main TS 71.84 -4.169e+005 -3.734e+005 ---
57 6__Main TS 74.53 -4.169e+005 -3.769e+005 ---
58 7__Main TS 81.83 -4.167e+005 -3.772e+005 ---
59 8__Main TS 81.01 -4.035e+005 -3.648e+005 ---
60 9__Main TS 80.03 -3.865e+005 -3.489e+005 ---
61 10__Main TS 78.84 -3.642e+005 -3.281e+005 ---
62 11__Main TS 77.16 -3.330e+005 -3.007e+005 ---
63 12__Main TS 78.67 -3.216e+005 -2.832e+005 ---
64 13__Main TS 80.24 -3.137e+005 -2.674e+005 ---
65 14__Main TS 81.70 -3.102e+005 -2.564e+005 ---
66 15__Main TS 83.46 -3.116e+005 -2.515e+005 ---
67 16__Main TS 86.54 -3.200e+005 -2.537e+005 ---
68 17__Main TS 91.76 -3.372e+005 -2.661e+005 ---
1
2 LEGENDS
4 USA
5
6
8
9
COLUMN PROFILES
10
13 Reboiler 98.09 -3.663e+005 -2.918e+005 ---
14
FEEDS / PRODUCTS
15
19 Q_C Energy 4.1e+002 * --- --- ---
Condenser
20 F2 Draw --- Liquid 3.25e-003 * -4.0e+005 * 70.68*
21 1__Main TS
22 2__Main TS
23 3__Main TS
24 4__Main TS
25 5__Main TS
26 6__Main TS
28 8__Main TS
29 9__Main TS
30 10__Main TS
32 12__Main TS
33 13__Main TS
34 14__Main TS
35 15__Main TS
36 16__Main TS
37 17__Main TS
38 Q_R Energy 4.1e+002 * --- --- ---
Reboiler
39 F3 Draw --- Liquid 3.65e-003 * -3.7e+005 * 98.09*
40
SETUP
41
42 Sub-Flowsheet
45 F0 F0 P-H Flash
46 F1 F1 P-H Flash
49 F2 F2 P-H Flash
50 F3 F3 P-H Flash
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
13 100 105
14
104
15
95.0
16 103
17
18 102
Temperature (C)
90.0
Pressure (kPa)
19
101
20
21 85.0 100
22
23 99.0
24 80.0
98.0
25
26 97.0
27 75.0
28 96.0
29
70.0 95.0
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33

34
35 from Top
36 1.60e-002 940 75.0
37
38
920
39
40 1.20e-002 65.0
41
Density (kg/m3)
900
42 1.00e-002 60.0
43
44 8.00e-003 880 55.0
45
46
6.00e-003 50.0
47 860
48
4.00e-003 45.0
49
50 840
2.00e-003 40.0
51
52
0.000 820 35.0
53
0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
1
2 LEGENDS
4 USA
5
6
8
9
10

11
12 K-Value
13 0.700 4.50
14
15 0.600
16
17
0.500
18
3.00
Mole Fraction
19
K Value
20 0.400 2.50
21
22 2.00
0.300
23
24 1.50
25 0.200
26 1.00
27 1.00e-001
28 0.500
29
0.000 0.000
30 0 2 4 6 8 10 12 14 16 18 0 2 4 6 8 10 12 14 16 18
31
32
33
34
36 10.0
Light
37
9.00
38
39
8.00
40
Mole Fraction Ratio
41
7.00
42
43 6.00
44
45 5.00
46
47 4.00
48
49 3.00
50
51 2.00
52
1.00
53
0 2 4 6 8 10 12 14 16 18
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68

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June 2015 Simulation of

Student: Khairul Naim Bin Ahmad

Synthesis of ethyl acetate

Reaction kinetics and parameters

Where k1 and k2 are forward and backward rate constants.

The rate model is:

The rate constants k1 and k2 can be presented by Arrhenius equation:

Most successful application of RD is the manufacturing of methyl acetate by Eastman Chemical

Principles of Reactive Distillation

a) Mass transfer through the vapor film

While for the heterogeneous system:

a) Transport of reactants from the bulk vapor to bulk liquid

Benefits and limitations of Reactive Distillation

The advantages of RD are discussed by Gorak et al. [14].

i. Chemical equilibrium limitation can be overcome.

ii. Higher selectivity can be achieved

iii. Heat of reaction can be used in situ for distillation

iv. Overcoming of azeotropes

v. Simplified separation of close-boiling components

vi. Capital savings

II. Residence time requirement

III. Scale up to large flows

IV. Process conditions mismatch

Applications of Reactive Distillation

Commercial applications of RD reported by Seader et al. [29]:

Aspen HYSYS process simulator

Simulation of Reactive Distillation for synthesis of ethyl acetate

The kinetic model was taken from Calvar et al [8].

The schematic of RD column to be simulated

In the upper section, stream F2 contains

Ethanol feed (F1)

Assumptions taken in the simulation:

I. Chemical reactions are assumed to occur only in liquid phase.

Defining the simulation basis

Figure 3.2: Adding the components to the simulation

Figure 3.3: Selecting the property package

Add the feed stream

Figure 3.4: Specifying the composition

Figure 3.5: Defining the stream's conditions

Add the distillation column

Figure 3.6: Defining the column parameters 1.

Figure 3.7: Defining the column parameters 2.

Figure 3.8: Defining the column parameters 3.

Adding the reaction

Figure 3.9: Adding the kinetic parameters

Adding the reaction to the column

Figure 3.10: Adding the reaction to the column

Figure 3.11: The streams summary in Performance tab

Reactive distillation column

Results and discussions

Effect of feed temperature, TF.

Effect of Feed temperature

86.40 Variation TF0

Figure 4.1: Comparison of different method of variation feed temperature

Effect of number of stages, n.

Figure 4.2: Effect of number of stages to ethanol conversion

Figure 4.3: Effect of number of stages to ethyl acetate purity

Effect of kinetic model

Kinetic Reference A Ea A' Ea' Conversion Purity

Effect of the molar feed ratio of HAc to EtOH.

Molar feed ratio influence

Effect of reflux ratio, R

Effect of Reflux ratio (R)