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Model answer of first booklet

1) M+ =0.011 pH= 1.9 , there is no right answer on the booklet

2) B

3) C

4) CH3CH2CH(OH)-CH2

5) 2 Butanol "sec"

6)look at your book

7) C2H5OH + HOSO3H 80C C2H5OSO3H + H2O

C2H5OSO3H 180C C2H4 + H2SO4

acts as dehydrating agent

8) Fredel craft alkylation

9) cell diagram

10) Alkenes

11) Catalyst , Temp

12) 2CH4 F.C C2H2 + 3H2

C2H2 C6H6

C6H6 + 3Cl2 C6H6Cl6

13) Substance that is molten or solution completely ionized and so acts as strong conductor

14) Substance that its molten or solution partially ionized and so acts as bad conductor

15) FeCl3 +NH4SCN 3 NH4Cl + Fe(SCN)3 (BLOODY RED COLOR)

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16) Due to their brittleness

17) Fluorspar decreases melting point of bauxite from 2045 to 950 , Cryolite decreases
density of bauxite molten

18) 2KI + H2SO4 K2SO4 + 2HI

2HI + H2SO4 2H2O + SO2 + I2

19) 2CH4 F.C C2H2 + 3H2

C2H2 + H2 NI C2H4
C2H4 +H2O + (O) KMnO4 CH2(OH) - CH2(OH)

20) C6H6 + Cl2 C6H5Cl + HCl

300
C6H5Cl + NaOH 300 C6H5OH + NaCl

21) By adding ( Br2) Soln. red color

C2H6 : No change
C2H2 : Color discharge

22) By FeCl3 pale yellow

H2CO3 : No change
C6H5OH : Violet color

23)CaCl2 + AgNo3 = no change

Ca(NO3)2 + White ppt turns violet on sunlight

24) 130 kj/mole

25) 100 ki/mole
26) exo
27) a
28) b
29) c
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30) Primary galvanic cell used mainly in rockets as its fuel of operating depends on rockets
fuel of bunching

31) Secondary galvanic Cell used mainly in cars as its electrolyte is dil H2SO4 between
network of anode ( Pb ) and other of cathode (PbO2)

32) Electronic series

33) Qualitative chemical Analysis
34) Baeyer's reaction ( oxidation)
ka
35) = = 9.4 * 10-3

36)H+ = = 1.89 * 10-3

37) PH = 2.7
POH = 14-Ph = 11.3
38) Due to markownikoffs rule + equation
39) Because it oxidized sponteneously losing e
40) Because they are non-polar covalent compounds.

41) Allow to blow a balloon via tube of silica gel saturated with acidifid K2Cr2O7 "Orange"
when the balloon is left till the exhalation goes out if the driver was drunk the color change
to green after oxidation

42) Combination between unsat monomers to form polymer via breaking pi bonds and
libration of their e that responsible to bind them by single covalent bonds.
43) n(ethene) =(hight temp) ployethene + (CH2 - CH2)

44) kekule discovered the hexagonal shape of benzene in which and double bonds are
exchanged
45) Law of mass action : rate of reaction is directly proportional with reactants conc raised
to the power of no of moles or molecules in balanced equation.
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46) wohler : He prepared the first organic compound , urea from inorganic compound in lab
, so he destroyed the vital force theory + Equation
50) Al2(SO4)3 (s)
51) CaCl2 (s)
52) Sc " Mercury Vapor lamp"
53) Ferromanganese " Fe -Mn"
54) Fehling solution "Cu+++ "
55) N2 + 3H2 2NH3
56) CH3COOH + H2O CH3COO- + H3O+
57) 2-Bromo , 1-propyne
58) 1,1 dibromo ethane
m1 w1
59) =
m2 2
0.073 63.5/1
=
m2 63.5/2
m2= 0.0365 gm
60) Cu2Cl2
2Cu++ + 2Cl- 2Cu + Cl2
CuCl2
Cu++ + 2Cl- Cu + Cl2