MAJLIS PENGETUA SEKOLAH MALAYSIA

CAWANGAN PULAU PINANG

_. .., - --~- ----"' - , .. -- . -- - /" ... _ ...... _, __ -.,_ - -- - - .... -

SKEMA JAWAPAN
MODUL LATIHAN BERFOKUS
SPM 2014
KIM lA KERTAS 1
4541/1

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 2

JAWAPAN KIMIA KERTAS 1

1 B 11 B 21 c 31 D 41 D

2 c 12 B 22 A 32 c 42 c
3 c 13 A 23 c 33 A 43 D

4 B 14 B 24 A 34 B 44 B

5 D 15 c 25 D 35 A 45 A

6 D 16 B 26 c 36 A 46 c
7 c 17 A . 27 A 37 c 47 D

8 D 1a D 28 B 38 B 48 D
.. . ~ -- .. . - -. ---/ -- -- -
j;f D 19 A 29 c 39 B 49 D

10 A 20 A 30
..
B 40 c 50 B

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..

MAJLIS PENGETUA SEKOLAH MALAYSIA

CAWANGAN PULAU PINANG

SKEMA JAWAPAN
---- -------/ -- --MODUL-lATIHAN BERFOKUS
__.SPM 2014
KIMIA KERTAS 2
4541/2

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 Bromine vapour consists_of and discrete molecules/particles.
Bromine molecules/psl;tic;;les move randomly from the bottom gas jar
(highly concentrated) to 'tile 'top jar (less concentrated).
to the between the air 1 3
1 (b) (i)

1. Shape of curve 1
2. Mark of the m 1 2

(ii)
~- . .. / ., -. - - .
1 1

(iii) 1
1 2

Total 10

as. 2
2 (b) turns brown
at the end of the combustion tube 2
2 (c)
Cu 0
Mass 3.20 0.80 1
Number of moles (mol) 3.20 0.80
' 64 . -16 -
=0.05 = 0.05 1
1 1
Em irical formula CuO 1 3

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2 (d) (i} CuO + Mg -7 Cu + MgO 1 1
(ii} From the equation,
1 mol CuO react completely with 1 mol Mg.
0.05 mol CuO react completely with 0.05 mol Mg. 1
Total mass Mg needed is= 0.05 x 24
= 1.2 g 1 2

- Total 10

3 (b) 1 1

Group 1 -has one valence electron 1

Period 4 - has four shells filled with electrons. 1 2

Atom X donates one electron 1

Atom Y accepts one electron 1 2
__
. .,..-.. ,..._. ..... -.- ....,.... .... -..- ------ --- -...--------.--
. ..... -- . , ~ .,.,..---~------__.,- - . --

1
1 2
1. Correct electron arrangement with nucleus shown
2. Correct ratio of atoms and charges

(ii) Electrostatic force 1 1

move freely 1 1

: . "J..::'~JHJI" H.;l ; .lw:H.:j, t_;; _ .J( Jt

~lf...

'~:.:. L'J .: rrl' ' l; ':

,.,
4 (a) 2 NaE>H+H2S04 - - . Na2SE>:.' +2Hk0

1. CorreCt formula of reactants and products 1

2. Balanced equation 1 2

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4 (b) 5.00 cm 3 1 1

4 (c) MaYa _ _1_

MbVb - 2

0.5 x5 _j_
Mbx25 - 2 1

Mb = 0.2 mol dm-3 1 2

4 (e) (i) 10 cm3 II Double the volume of sulphuric acid 1

Nitric acid is monoprotic acid II Sulphuric acid is diprotic acid 1 2

(il) Add 2 :cm 3 of dilute sulphuric acid and 2 cm 3 of iron( II) sulphate 1
solution into the test tube and shal<e the mixture.
Carefully add a few drops of concentrated sulphuric acid to the side 1
of the test tube.
Brown ring is formed. 1 3

Total 10

5 (b) NumbeF of moles,of =

0.3/24 0.0125 mol
1 mol Mg produces 1 mol H2 1
So 0.0125 'mOI Mg produces 0.0125 mol H2
Volume of H2 gas at room condition= 0.0125 x24 =0.3 dm 3

1 2

5 (c) (I) Expf:!riment I

=0.3 g /60s
=0.005 g s1 1 1

(ii) Experiment II
=0.3 g /30s
=0.01 g s1 1 1

5 (d) Experiment II has higher rate reaction than 1

[of 1
energyofpartlcleirls 1
Frequency of collision between magnesium atom and hydrogen ion 1
is higher in Experiment II.
Frequency of effective collision also increases In Experiment II. 1 3
max

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5 (e) Volume of gaslcm 3

E
1 1

. .

.
Timels

Total 10

1 1

: NickeVNi II Platinum/Pt 1
Temperature: 180 C 1 2

~~c) C~l:l-4: +. 1-:hQ..-+ . .C..2t!sOH. 1 - 1/

;. '

!...
(ii)
l I I
H-C- C-C-OH
I I I
H H H 1

H H H
I I I
H- C-C-C -H
I I I
H OHH 1 2

6 (d) (i) Polythene I Polyethene 1 1

Make plastic bags I bOttles I chairs I toys 1 1

Produces poisonous I toxic gases which can cause 1 1

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-r.,.;;;;;;.".;;~
: ~jijJ:9)r,, ,
,,- :" ',,[ ; - -- -; .; , _. ,
, -l.-.,;L..:i C' i'
lll.WIL~ ,~o>q(;l;. :1_~..
- '~'.,j;,
~").ill.!
' cc '
:lt,ol~i
.,

, l~.ls1 :. i: J~IDJt:~ 4Mir.~ '

. ._.-~_ . . . . ~ ~~~ I .- -~---- --- ~---- -~-~~: -~
7 (a) (i) Negative terminal : zinc 1
positive terminal : copper 1 2

(ii) 1. Zinc electrode becomes thinner 1

2. Oxidation 1 2
7 (b) 1. Voltmeter reading decreases 1
2. Iron is lower than zinc in the electrochemical series II
Iron is less electropositive than zinc II
Distanqe b~tw~en ir~n anq copper i$ shorter than distance
betWeen zinc and copper in the electrochemical series
1 2

7 (c) 1. S - Concentration of the ions 1

2. R - Position of ions in the electrochemical series 1 2

7 (d) 1. Ions present in solution: Na+ Cf H+ OH- I I I

1
2. Ions attracted to electrode R: Na+ W I
1
3. Ions attracted to electrode s : cr OH- I 1
. 4-. Name oflon diScharged' atelecttoae R: Hydtogen ion 1
5. Name of ion discharged at electr(>de S : Chloride ion 1
6. At electrode R H+ ion is selectively discharged because W ion is
1 1
+ .
placed lower than Na ion in the electrochemicalseries.
7. At electrode Sl cr ion is discharged because concentration of cr 1
ion is higher than OH-ion.
1
8. R : Colourless gas bubbles released
9. S : Greenish yellow gas 1
10&11. R: 2H++ 2e-+ H2 1+1
12&13. S: 2cr-. Cl2 + 2e 1+1
12
max
Total 20

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[:12/~r_;r_.,"Jlrzi" : 1! .. -- - - -- iMhtt.~ .~.&r=1~-il~ - - ' ~.!!12 ';~j91hi;
f l~i~ ' ', !\!L~~i. ll~~Jjj_~
i I . .
l --~ - -- - - - ----- -- -- -- - ~I
8 (a) a
Reaction A - not redox reaction 1
Reaction 8 - redox reaction 1
Reaction A:
No change in oxidation number 1

Reaction 8:
Oxidation number of zinc changes/increases from 0 to +2 II
1
Oxidation number of copper changes/decreases from +2 to 0 4

8 (b) (i) Compound P : + 2 , iron(ll) chloride 1+1

Compound a :
+ 3, iron(lll) chloride 1+1 4

(ii) Bromine water [Any suitable oxidising agent] 1

Green solution turns brown II Brown colour of bromine water is 1
decolourised [Any suitable observation for related oxidising agent 2
used]
8 (c) (i) Substance which releases/ donates electrons //Iron( II) ions release 1 1
electrons
8 (c) (ii) a
Electron flows from electrode to electrode P through .external 1
~i~c_uit/ connectingv~ir~s _ . ___ /' / ~-

Observation
Galvanometer needle deflects 1
Purple colour of acidified potassium manganate(VII) solution 1
decolourises
The green colour of iron(ll} sulphate solution turns brown
(any two)
Half equation at P:

Mn04" + 8H+ + se ~ Mn2 + 4H20 1

Half equation at a:

Fe 2 + ~ Fe3 + e 1

Ionic equation:

5Fe2 + Mno4 (aq) + aH ~ Mn2 + 4H20 + 5Fe3 1+1

At P : reduction reaction 1

Ara : oxidation reaction 1

9
Total 20

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: ~}_,l~i]!JF1 ) 1 t~1r.,)j~~ ;~ch::Jf'l~- -~,h -~:,:1~l~
,,
:r
: :, C

'
'
i
, ' ..
''r-J ;~ ll'1t:v~ :
~
'

l 'l j

9 (a) Type of food additive X - Preservative 1

Example - salt/ sugar/ vinegar/ sodium nitrate/ sodium nitrite/ 1
benzoic acid/ sodium benzoate
Type of food additive Y - Flavouring 1
Example - monosodium glutamate/ aspartame/ salt/ sugar/ vinegar 1 4
9 (b) (i) Ali - Aspirin 1
Raju - Antidepressant 1 2
(ii) Precaution:
Tak~ ,after food II Swallowed with plenty of water 1
Explanation:
Acidic and can cause stomach irritation II To avoid Internal bleeding 1 2
(iii) 1. Drowsiness
2. Respiratory difficulties
3. Poor coordination
4. Llght-headedness 2 2
[any two]
9 (c) Materials:
Soap solution, detergen solution, 1 mol drn"3 magnesium sulphate
solution/ hard water, cloth with oily stains 1

Apparatus :
..500 em~ beaker, 500.cm3 measuring -cylinder . 1

Procedure:
1. [250-400] cm 3 of magnesium sulphate solution (hard water) Is 1
poJ,Jred Into two beakers labelled X and Y respectively. .
2. [20-50] cm 3 of soap is poured Into beaker X and [20-50] cm 3 1
deterg~nt is poured into beaker Y.
3. A small piece of cloth with oily stains is dipped Into each beaker 1
4. Each cloth is washed with the soap or detergent In each beaker. 1
5. The cleansing action of the soap and detergent Is observed and 1
recorded.

Observations :

Beaker Observation
X Oily stains remain 1
y Oily stains disappear 1

Conclusion :

The cleansing action of a detergent Is more effective than soap In 1

hard-water - -- --- - 10

Total 20

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10 (a) (i) .
1. Correct formula of reactants and products
2. Balanced equation 1
1 2

(ii)

1. Axes with label energy and two levels 1

2: Correct-position of reactants; products and AH 1. 2

(iii) 1. Heat of combustion of butanol is higher than propanol. 1

2. The molecular size/number of carbon atoms per molecule of
butanol is bigger/higher than propanol. 1
3. Butanol produces more carbon dioxide and water molecules than
1 3
propanol/ release more heat energy

10 (b) Diagram:
1. Functional diagram 1
2. Labelled diagram 1

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 Procedure: ---

1. [1 00 - 200] cm 3 of water is measured and poured into a copper 1

can and the copper can is placed on a tripod stand.
2. The initial temperature of the water is measureo and recorded. 1
3. A spirit lamp with butanol is weighed and the mass is recorded. 1
4. The lamp is then placed under the copper can and the wick of the 1
lamp is lighted up immediately.
5. The water in the can is stirred continuously until the temperature 1
of the water increases by about 30 C.
6. The flame is put off and the highest temperature reached by the 1
water is recorded.
7. The lamp and the content is weighed and the mass is recorded. 1
Calculation:

The highest temperature of water = 12

The initial temperature of water = t1 1
Increase in temperature, 6 = t2- t1 = e
Mass of !amp before burning = m1
Mass of lamp after burning = m2 1
Mass of butanol burnt, m = m1-m2 =m
.,
' . ' . '
-- Nt:fmberof moles of' butanol: C4 H90H, n '= m - --
. 74 1

The heat energy released = mass of water x c x e = y J 1

Heat of combustion = ~ J mol"1
n 1

A grecaution steg:
The flame from the burning of alcohol must touch the base of the
copper can
A windshield is used to shield/ protect the flame from air currents
/wind
The water in the copper can must be stirred continuously
throughout the experiment to ensure the temperature of the water 1
Is uniform
The spirit lamp must be weighed immediately because alcohol
evaporates easily
[any one]
.. -- . ... - . . .. -1-3 ---
max
Total 20

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 MAJLIS PENGET~A SEKOLAH MALAYSIA
CAWANGAN PULAU PINANG

SKEMA JAWAPAN
.- - ..
. --- / . . . - ...- -~

-- MODUL LATIHAN-BERFOKUS
SPM 2014
KIMIA KERTAS 3
4541/3

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 2

JAWAPAN KIMIA KERTAS 3

Question Mark Scheme Marks

1(a) Able to record the all the observations and inferences accurately. 6

Samole answer:
Test ObseNation Inference
tube
A Pink spot/ colouration lron(ll) I Fez+ ions are not
formed II
Iron does not rust/ corrode

B High intensity of dark blue - lron(ll) I Fe~+ ions formed

spot/ colouration II More dark quickly// Iron rusted/
blue spot formed corroded quickly
II Iron rusts quickly

c Low intensity of dark blue Jron(ll) I Fez+ ions formed

spot/ colouration II Less dark slowly// Iron rusted/
blue spot formed corroded slowly
II Iron rusts slowly

D Very low intensity of dark blue lron(ll) I Fe~"' ions formed

spot/ colouration II Least dark very slow// Iron rusted/
-- blue spotJormed - - _ "- - .corroded very slow _ - . -
II Iron rusts very slow

Able to record any 5 of the observations or inferences accurately. 5

Able to record any 4 of the observations or inferences accurately. 4

Able to record any 3 of the observations or inferences accurately. 3

Able to record any 2 of the observations or inferences accurately. 2

Able to record any 1 of the observation or inference accurately. 1

No response or wrong response 0

Question Mark Scheme Marks

1(b) - Abie to expiain a difference in observation correctly between test tube 3
A and test tube B

Sample answer:
-
Iron ifftest tube A does not rusv CcirroC:Iel -oxidise oecause iron is In
contact/coiled with zinc which is more electropositive metal than iron,
but iron in test tube B rusts/ corrodes/ oxidises because iron is in
contact/coiled with copper which is Jess electropositive metal than iron.

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 3

Able to explain a difference in observation between test tube A and 2

test tube 8 incompletely.

Sample answer:
In test tube A, zinc is more electropositive than iron and in test tube 8,
copper is less electropositive than iron.

Able to state any idea of difference in observation. 1

Sample answer:
Iron/ Ferum/ Fe/ naiV metal does not rust/ corrode/ oxidise
II Iron/ Ferum /Fe /nail/metal rusts/ corrodes/ oxidizes II Zinc is more
electropositive II Copper is less electropositive

No response or wrong response 0

Question Mark Scheme Marks

1(c) Able to state the relationship between the manipulated variable and 3
the responding variable with direction correctly.

Sample answer:
1. When a more-electropositive metal is in contact/coiled with iron,
- .- the me.tal inhibits_rusting I corrosiortof .iron II vice versa - - - --- ,. - . .-

2. If the metal in contact/coiled with iron is higher than iron in the

electrochemical series, the rusting I corrosion of iron is prevented
II vice versa

Able to state the relationship between the manipulated variable and 2

the responding variable with direction but /ass accurately.

Sample answers:
1. When a more electropositive metal is used, the metal inhibits
rusting I corrosion of iron II vice versa
2. If the metal is higher in the electrochemical series, the rusting I
corrosion of iron is slower II vice versa
3. The rusting of iron is prevented if a more electropositive metal is
used II vice versa

Able to give an idea of hypothesis. 1

Sample answers: - . ... . - -- - -

-
.,.: -Iron rusts when iii eonlacf with other metals
2. Other metals affect the rusting of iron

No response or wrong response 0

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 4

,. Question Mark Scheme M~uks

1(d) .. Able to state all variables correctly: 3

Samgle answer:
Manipulated variable: Type of metal in contact/coiled with iron
Responding variable: Rusting II Presence of blue spot/colouration
Fixed variable: Type of nail I/ iron If medium in which the iron
nails are kept

. ' .
Able to state any two variables correctly. 2
Able to state any one variable correctly. 1
No response or wrong response 0

Question Mark Scheme Marks

1(e) Able to state the relationship between the intensity of blue colour and 3
the rate ofrusting of iron accurately:

SamQie answer:
The higher the intensity of blue colour, the higher the rate of rusting of
iron II vice versa

Able to state the relationship but Jess accurately: 2

- - ... ~- - ,. , - . SamQie answer: - .. - .._ ..

~
.. - ----- -~ _,.... . -,- -- ......- .

Different intensity of blue colour, different rate of rusting.

Able to state an idea of relationship: 1

'
SamQie answer:
The intensity of blue colour affects the rate of rusting.

No response or wrong response 0

Question Mark Scheme Marks

1(f) Able to name the ion that causes blue spot and write a correct half 3
equation for the fonnation of the ion:

Sample answer:
1. lron(ll)'lon
2
2. Fe - Fe + + 2e

Able to name the ion that causes blue spot and write an almost correct 2
.. - - . .. .. half equation for the.fonnation of the ion: . - - . ... .

SamQie answer:
1. lron(ll) ion
2
2. Fe - Fe + +e

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 5

Able to state the ion that causes blue spot or an idea of writing half 1
equation:

Sample answer:
1. Fe2+
2. Fe2+ + e ~ Fe

No response or wrong response 0

Question Mark Scheme Marks

1 (g) Able to arrange all the 4 metals correctly based on descending order 3
of electropositivity.

Sample answer:
Zinc, Iron, metal X, Copper

Able to arrange only 3 metals corractly based on descending order of 2

electropositivity.

Able to arrange at /east 2 metals correctly based on descending order 1

of electropositivity or able to arrange all the metals correctly but in
ascending order of electropositivity
- --- ' -
~ -... ---
~---- .. .. --- --

No response or wrong response

__, ,- - --- -' - .. -' - -- - _ __,.. -- --
0
J' --.

Question Mark Scheme Marks

1(h) Able to define operationally the rusting of iron accurately containing all 3
these 3 criteria:
1. Rusting of iron is the formation of dark blue spot I colouration
2. When iron nail is coiled I in contact with a less electropositive metal
I meta/located below iron in electrochemical serie_s
3. Immersed I dipped I placed I put in a mixture of jelly solution
containing potassium hexacyanoferrate(/11).

Sample answer:
When iron nail is coiled with a less electropositive metal immersed in
jelly solution containing potassium hexacyanoferrate(lll), dark blue
spot I colouration is formed

Able to define operationally the rusting of iron less accurately 2

containing
.. .-
all these 2 criteria:
. -- . . - . . - --.-. -- . -
-- - . ~ ~

1. Rusting of iron is the formation of blue spot I co/ouration

2. When iron nail is coiled I in contact with a less electropositive metal
I meta/located below iron in electrochemical series.

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 6

Sample answer:
When iron nail is coiled with less electropositive metal, dark blue spot I
colouration is formed.

Able to state an idea of operational definition containing any one of 1

these criteria:
1. Rusting of iiun is the formation of blue spot I colouration
2. When iron nail is coiled I in contact with a less electropositive metal
I meta/located below iron in electrochemical series.

Sample answer:
1. Iron nail coiled with less electropositive metal
2. Rusting occurs wheri dark blue spot I colouration is formed

No response or wrong response 0

Question Mark Scheme Marks

1(i) Able to classify the metals into metal that can provide sacrificial 3
protection and metal that cannot provide sacrificial protection correctly.

Sample answer:

_, ... M~~! t~a..t ~ar1 PJQYit!_~ _ . .IYI~~I ~~atcarm..ot provide ..

sacrificial protection sacrificial protection
Zinc Metal X
Copper

Able to classify any two metals correctly. 2

Able to classify any one metal correctly. 1

No response or wrong response 0

Question Mark Scheme Marks

1(j) Able to predict the obseNation accurately. 3

Sample answer:
The Intensity of dark blue spot lcolouration is very high II higher than
test tube B.
A.bl~ to predict tht:J Qb..serv~tion/ess accurately. 2

Sample answer:
Blue spot /colouration is formed.

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 7

Able to state an idea of observation. 1

Sample answer:
The test tube/ jelly turns blue.
No response or wrong response 0

Question Mark Scheme Marks

2(a) Able to state the problem statement accurately. 3

Sample answer:
How does the solubility of sodium chloride and naphthalene in water
and in propanone differ?

Able to state the problem statement but less accurately. 2

Sample answer:
How is the solubility of ionic and covalent compounds in water?

Able to give an idea of statement of the problem. 1

Sample answer:
Is ionic I covalent compound soluble in water?

' - ~ . ... ... No response or wrong_ res(:>onse - --' - / - - . - _. , .,. ~

- 0 ---

Question Mark Scheme Marks

2(b) Able to state all the variables correctly. 3
,.
Sample answer:
Manipulated variable: Type of solvent II Water and propanone
Responding variable: Solubility of compound in solvent
Fixed variable: Amount of sodium chloride and naphthalene

Able to state any two variables correctly. 2

Able to state any one variable correctly. 1
Noresponseorwrongresponse 0

Question Mark Scheme Marks

2(c) Able to state the relationship between the manipulated variable and 3
.. the responding variable with direction correctly; -- - - ... -- -

Sample answer:
Sodium chloride is soluble in water but insoluble in propanone
whereas naphthalene is insoluble in water but soluble in propanone.

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 8

Able to state the relationship between the manipulated variable and 2

the responding variable but less accuraiely.

Sample answer:
Ionic compound is soluble in water but insoluble in organic solvent
whereas covalent compound is insoluble in water but soluble in
organic solvent.

Able to state ari idea of hypothesis. 1

Sample answer:
Sodium chloride is soluble in water II Sodium chloride is insoluble in
propanone II Acetamide is insoluble in water II Naphthalene is soluble
in propanone.

No response or wrong response 0

Question Mark Scheme Marks

2(d) Able to give a complete list of materials and apparatus that involves the 3
following:

Sample answer:
Water, propanone, sodium chloride, naphthalene, test tubes, spatula
- - - - - - -
. ---- - ~ ~ ~ - . ........ ---------
.../ " / - - - -- , - . - - ....
... ,... --

Able to give a list of materials and apparatus that if!VOives the following 2
but less accurately.

Sample answer:
Water, propanone, sodium chloride, naphthalene, test tube/ spatula

Able to give an idea of the materials and apparatus that involves the 1
following:

Sample answer:
Water/ Propanone, Sodium chloride/ Naphthalene, Test tube/ Spatula

No response or wrong response 0

Question Mark Scheme Marks

2(e) Able to state all the following 5 steps correctly: 3

Sample answer:
1. Put a [<:Juarter/ half of] sp~t~_la of ~odi~m chlo_ri~~ a~d ~~hthalene ..
ilito two separate test tubes:---- -
3
2. Pour [2-5] cm of distilled water into the test tubes.
3. Stopper the test tubes and shake well.
4. Record the observations.
5. Repeat steps 1 to 4 by using propanone to replace distilled water.

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 9

Steps 1, 2, 4, 5 2

Steps 1, 2, 4 1

No response or wrong response 0

Question Mark Scheme Marks

2(f) Able to exhibit the tabulation of data that includes the following 2
information:

1. Heading for manipulated variable : Type of solvent II Solvent

2. Heading for responding variable : Solubility of compound
3. 3 x 3 table

Sample answer:

Type of solvent Solubility of sodium Solubility of

chloride naphthalene
Distilled water
Propanone

Able to exhibit the tabulation of data that includes the following 1

-infotfiiatiPn - - - - ~ - --

1. Heading for manipulated/ responding variable

2. 2 x 2 table

sa'l hole answer:

ISolvent ISolubility
No response or wrong response 0

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