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Introduction:
To meet the energy requirements of advancements introduced in our lives, it
is necessary to utilize the available resources efficiently. It is required to
modify the Power Plants, designed to generate usable energy, so that they
produce maximum energy for a specified input. For this purpose, they are
subjected to thermodynamic analysis in order to determine the effect of
various parameters on their efficiency. Those results are then practically
implemented in order to achieve formerly mentioned target.
Exergy is a concept used in thermodynamic analysis which is defined as the
amount of maximum work that can be extracted from a system until it is
brought to equilibrium with respect to its environment. It is a theoretical
terminology and our target is to convert most of it into our desired form of
work. Exergy efficiency has always been an important consideration in
decision making regarding resource utilization. Efficiency is defined as the
ability to produce a desired effect without waste of, or with minimum use of,
energy, time, resources, etc., or the degree to which the ideal is approached
in performing a task. Ratios of energy are conventionally used to determine
efficiencies of engineering systems whose primary purpose is to analyze the
transformation of energy. These efficiencies are based on the first law of
thermodynamics.
In exergy analysis, the initial state is specified, and thus it is not a variable.
The work output is to be maximized when the process between two specified
states is executed in a reversible manner. All the irreversibilities are
disregarded in determining the work potential. Finally, the system must be in
the equilibrium state at the end of the process to maximize the work output.
A system is said to be in the equilibrium state when it is in thermodynamic
equilibrium with the environment. Exergy is consumed due to irreversibilities.
Exergy consumption is proportional to entropy action.
This type of analysis takes into account first and second laws of
thermodynamics unlike energy analysis which is based on first law of
thermodynamics only. Exergy analysis clearly indicates the locations of
energy degradation in a process and can therefore lead to improved
operation or technology. Exergy analysis can also quantify the quality of heat
in a waste stream. A main aim of exergy analysis is to identify exergy
efficiencies, the causes and true magnitude of exergy lose. In the following
text, exergy analysis of Rankine Cycle and Steam Turbine Power Plant will be
performed.
Rankine Cycle:
Rankine cycle is a thermodynamic cycle in which an operating fluid is
continuously evaporated and condensed. It is the fundamental operating
cycle of all power plants. The fluid we are using is water/steam. . The Block
Diagram of Rankine Cycle is shown below,
In a real power plant cycle, the compression by the pump and the
expansion in the turbine are not isentropic. In other words, these
processes are irreversible and entropy is increased during the two
processes. This somewhat increases the power required by the
pump and decreases the power generated by the turbine.
The P-V and T-s diagrams for a non-ideal cycle is shown below,
T
Wmax X heat QH max QH 1 o
TH
Wsurr P0 V2 V1
Where,
P0 is atmospheric pressure, and V1 and V2 are the initial and final volumes of
the system
Xmass=m
Where,
=Xcv/m (exergy per unit mass)
Xdestroyed
Xdestroyed=I=ToSgen
Ssys=Sin-Sout+Sgen
Entropy Generated, Sgen
S m s m s Qk
gen
out
e e
in
i i T
k
Qk
S gen S 2 S1
Tk
Here Tk is the temperature of the heat source or heat sink
(not the system temperature).
To
T Qk W Po V2 V1 To S gen mi i me e X 2 X 1
1
k
To
1 T Qk W To S gen m i e 0
k
For Rankine Cycle
I To S gen
for a component :
Q
S gen m se si
Tk
S S
gen S
gen, pump gen ,boiler S gen,turbine S gen,cond .
Q pump Qboiler Q Q
m s2 s1 s3 s2 s4 s3 turbine s1 s4 cond .,in
To Tcomb.chamber To Tlake
Qout Qin
I To m T T
k ,out k ,in
We will then put this general equation for exergy destruction for a
rankine cycle in the exergy change equation for control volume to
find out the maximum useful work that can be obtained from a
non-ideal cycle. The efficiency is calculated by the formula,
Working Principle: