CHEMICAL BONDING & BALANCING REDOX REACTIONS(TALENT HUNTER)

1. Which of the following are isoelectronic and isostructural?

(a) NO2+ CO2 (b) NO3- , BF3 (c) NH3,CH3- (d) all of these
2.
(a) N2 N2+ (P) Bond order increases and magnetic property is changed
(b) O2+ O2+2 (Q) Bond order decreases and magnetic property is not changed
(c) B2 B2+ (R) Bond order increases and magnetic property is not changed
(d) NO- NO (S) Bond order decreases and magnetic property is changed

a b c d
(A) S P R Q
(B) S P Q R
(C) R Q S P
(D) P S Q R

3. In the structure of H2CSF4 to decide the plane in which C=S is present the following bond angle values are given. Axial
FSF angle = 1700. Equatorial FSF angle = 970. After deciding the plane of double bond, which of the following statement
is correct?
(a)Two C-H bonds are in the same plane of axial S-F bonds.
(b) Two C-H bonds are in the same plane of equatorial S-F bonds
(c) Total five atoms are in the same plane
(d) Equatorial S-F bonds are perpendicular to the plane of bond

4. Which of the following is true related to structure of KrF 4

(a) It has one lone pair on the central atom (b) Bond angle is more than 1090
(c) It is square planar (d) Molecule is polar

5. The following equations are balanced

(i) Cr2O72- + 8H+ + 3H2O2 2Cr3+ + 7H2O + 3O2
(ii) Cr2O72- + 8H+ + 5H2O2 2Cr3+ + 9H2O + 4O2
(iii) Cr2O72- + 8H+ + 7H2O2 2Cr3+ + 11H2O + 5O2
The precise equation representing the complete oxidation of hydrogen peroxide is
(a) I only (b) ii only (c)iii only (d) all the three
6. In the reaction CrO5 + H2SO4 Cr2(SO4)3 + H2O + O2. One mole of CrO5 will liberate how many moles of O2
(a)5/2 (b)5/4 (c)9/2 (d) none of these

7. Which of the following the correct order of boiling point?

(a) H2O < CCl4<CS2<CO2 (b) CO2< CS2<CCl4<H2O
(c) CO2< CCl4<CS2<H2O (d) CO2< H2O <CS2<CCl4

8. A diatomic molecule has a dipole moment of 1.2 D. if its bond length is equal to 10 -10m, then the fraction of an electronic
charge on each atom will be
(a) 42% (b)52% (c)37% (d)25%

9. According to molecular orbital theory which of the following is incorrect

(a) LUMO level for C2molecule is 2py (b) in C22- molecule two of the bonds are bonds
2-
(c) C2 as well as C2 are diamagnetic (d) in C2 molecule both the bonds are bonds.

10. Which of the following is correct?

(a) (CH3)3COH is less acidic than (CH3)3SiOH
(b) Like CO, its analogue of Si is not stable
(c) In phosgene C-O bond length is longer than expected while C-Cl bond length is shorter
(d) All of these

11. Which of the following pairs of species have identical shapes?

(a) NO2+ and NO2- (b) PCl5 and BrF5 (c)XeF4 and ICl4- (d)TeCl4 and XeO4

12. The strongest P-O bond is found in the molecule

(a) F3PO (b)Cl3PO (c)Br3PO (d)(CH3)3PO
13. O2F2 is an unstable yellow orange solid and H2O2 is a colourless liquid, both have o-o bond and o-o bond length in H 2O2
and O2F2 respectively is
(a) 1.22 Ao, 1.48Ao (b) 1.48Ao, 1.22 Ao (c) 1.22 Ao , 1.22 Ao (d) 1.48Ao1.48Ao
14. The S-O bond length is maximum in
(a)SOCl2 (b)SOBr2
(c)SOF2 (d)all have the same bond length

15. Number of S-S bond in H2SnO6 is

(a) n (b) n-1 (c)n-2 (d)n+1

16. Select pair of compounds in which both have different hybridisation but have same molecular geometry
(a)BF3 BrF3 (b) ICl2- BeCl2 (c)BCl3, PCl3 (d)PCl3,NCl3

17. The correct increasing order of extent of hydrolysis is

(a)CCl4<MgCl2<AlCl3<SiCl4<PCl5 (b) CCl4<MgCl2<AlCl3< PCl5<SiCl4
(c)CCl4<MgCl2< PCl5<AlCl3<SiCl4 (d) CCl4< <AlCl3 <MgCl2<SiCl4<PCl5

18. Which is a polar molecule?

(a) XeF4 (b)BF3 (c)I2Cl6 (d)PCl2F3

19. Which of the following statements is not correct regarding bonding molecular orbitals?
(a) bonding molecular orbitals possess less energy than the atomic orbitals from which they are formed
(b) bonding molecular orbitals have low electron density between the two nuclei
(c) electron in bonding molecular contributes to the attraction between atoms
(d) they are formed when the lobes of the combining atomic orbitals have the same sign

H2C
CH2
20. Nodal planes of bond(s) in are located in
(a) all are in molecular plane
(b) two in molecular plane and one in a plane perpendicular to the molecular plane which contain s C-C sigma
bond
(c) one in molecular plane and two in a plane perpendicular to molecular plane which contains C-C sigma bonds
(d) two in molecular plane and one in a plane perpendicular to molecular plane which bisects C-C sigma bonds at
right angle

NUMERICALS

The bond order of the underlined species in NOHSO4 is

How many hydrogen bonded water molecule(s) are associated in CuSO4.5H2O.

Dichromate ion in acidic medium oxidizes stannous ion as

xSn2+ + y Cr2O72- + zH+aSn4+ + bCr3+ +c H2O. the value of Z-C is

B3N3H6 is converted in to B3N3H4X2 by the replacement of H. how many structures are possible?

How many of the following compounds contain bond(s) between sulphur atoms
S2O32- , S2O42-,S2O52-,S2O72-

How many of the following statements are correct?

(a) It is impossible to satisfy the octet rule for all the atoms in xenon diflouride
(b) The bond in NO+ should be stronger than the bond in NO-
(c)Crystals of hydrated calcium sulphate can be easily cleaved
(d) N2F3+ is planar at each nitrogen atom
(e) SeOCl2 has a lone pair and a double bond

How many of the following species are not isostructural with CO2
 HgCl2, SnCl2,C2H2,NO2,Cyanamide ion, CS2

Stable Lix exists in vapour state. The value of x is

For N2H2 how many isomeric structures are possible(both structural and stereo)

In the molecule SF6, the maximum number of atoms present in one single plane is

ANSWER KEY:

1. D 2. B 3.A 4.C 5.A

6. D 7. B 8. D 9.A 10.D

11. D 12.A 13.B 14.B 15.B

16. B 17A 18.D 19.B 20.B

N1. 3 N2.2 N3.7 N4. 4 N5. 3

N6. 5 N7. 2 N8.2 N9.3 N.10. 5