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III. Discussions
A. Nature of Reactants
The first part of the experiment is about the factor of the chemical kinetics
regarding the nature of reactants. In this experiment, we were tasked to prepare
two test tubes A and H. Test tube A has a content 1/3 full of 3M of acetic acid
and another 1/3 full of 3M hydrochloric acid on the test tube H. Then, 0.3 grams
of iron filings were placed on each test tube. The iron reacted with the other
reactants, thus, producing a hydrogen gas. For the test tube A, iron (II) acetate was
formed plus hydrogen gas. In the test tube H iron (II) chloride plus hydrogen gas
was formed. The gases was tested in the lighter splinter but nothing happened,
probably, due to timeworn reagents, but theoretically the light in the splinter
should ignite brighter since the produced gas, hydrogen gas, is highly flammable.
Fe(s) + 2CH3COOH(aq) Fe (CH3COO)2(aq) + H2(g) (eq.1)
Fe(s) + 2HCl(aq) FeCl2(aq) + H2(g) (eq.2)
B. Effects of Concentration
The second part of the experiment is about the factor of chemical kinetics
regarding the concentration of the solutions. In this experiment, 5 test tubes were
prepared containing sodium hydroxide and water but with different concentration
on each test tube. The experiment was performed so that we can determine the
rates of the reaction of different concentrations of NaOH to aluminium foil. The
outcome of the experiment showed that the solutions with greater concentration
react faster compared to those solutions having lesser concentration. Based on the
collision theory, if the concentration of one of the reactant is doubled, it will
collide in each second twice as many times with the second reactant as before.
Because the rate of reaction depends on the number of effective collisions per
second, the rate is doubled. Thus, rate increases when the concentration of either
or both reactants is increased.
NaOH(s) + H2O (l) Na+ + OH- + H2O + HEAT (eq.3)
C. Effect of Temperature
Supposedly, bicarbonate and hydrogen ions are produced when Alka
Seltzer dissolves in water.
For this part, two test tubes were prepared having 3M of Hydrochloric acid on
both test tubes that were labelled A and B. On test tube A, mossy zinc was
dropped while on test tube B, zinc powder was dropped. While observing the
reaction of the mossy zinc and the zinc powder, it was observed that zinc powder
reacts faster compared to the mossy zinc due to a wider surface area of the
powdered zinc than the mossy zinc. In that reason, the molecules of HCl could
make more contact to the zinc and react faster. Thus, the greater the exposed
surface area of the reactant, the greater the reaction rate.
Zn(s) + 2HCl (aq) ZnCl2 (aq) + H2 (g) (eq.5)
E. Presence of Catalyst
E. Presence of Catalyst
1. Define and give examples of the following
a. Catalyst
A substance that speeds up a chemical reaction while undergoing no
permanent change itself.
Example:
2SO2 (g) + O2 (g) 2SO3 (g) - Solid V2O5 is the catalyst for this reaction.
CH3CH2OH (g) + HCl (g) CH3CH2Cl + H2O (l) H2SO4 as the catalyst
b. Inhibitor
A catalyst that decreases the rate of reaction.
Example: preservatives and penicillin
c. Poison
It is to destroy or diminish the activity of a catalyst. One example is the
poisoning of palladium and platinum catalysts. Platinum was found to be
less susceptible. Common poisons for these two metals are sulfur and
nitrogen-heterocycles like pyridine and quinoline.
2. Should the concentration of the catalyst be part of the rate equation for a
catalyzed reaction?
No
3. Cite qualitative evidence for your answer based on the experiment conducted
When Manganese oxide is added, oxygen gas evolved faster.
F. Order of Reaction
1. Determine the order w/ respect to iodide ion, bromate ion, and hydrogen ion.
[I-]0= zeroth order; [BrO3-]0=zeroth order; [H]3=third order
2. What is the overall order of reaction?
Rate = k [I-]0 [BrO3-]0 [HCl]3 = 3rd order
V. Conclusion
After the experiment was conducted, we conclude that there are factors that affect
the speed and rates of the chemical reactions. These factors are the nature of the
reactants, concentration of reactants, temperature, surface area and presence of a
catalyst. The concentrations of reactants greatly affect the rates because two
substances cannot possibly react with each other unless their constituent particles
come into contact. If there is no contact, the reaction rate will be zero. Thus, the more
reactant particles that collide per unit time, the more often a reaction between them
can occur. The temperature affects the rate because increasing the temperature of a
system increases the average kinetic energy of its constituent particles. As the average
kinetic energy increases, the particles move faster and collide more frequently per
unit time and possess greater energy when they collide. The reaction rate of all
reactions also increases with increasing temperature. The surface area affects the rate
because the reactants are in two different phases and collisions between them can
occur only at interfaces between phases. The number of collisions between reactants
per unit time is substantially reduced, so is the reaction rate. The presence of the
catalyst affects the rate of reaction because catalyst is a substance that participates in
a chemical reaction and increases the reaction rate without undergoing a net chemical
change itself. Therefore, there are many factors that can affect the rate of the reaction.
VI. References
https://books.google.com.ph
Bartholomew, Calvin H. "Mechanisms of catalyst deactivation". Applied
Catalysis A: General 212 (1-2): 1760
Smooth,Robert,Chemistry ; A Modern Course, Merrill Publishing Co., Columbus,
OH, 1983
VII. Appendices
Calculations
K I BRO 3 H +
-
Concentration: [I ]= K I xM -
; [BRO3 ]= BRO 3 xM +
; [H ]= H + xM
V V V
1 [ A] 1 [B ] 1 [C ]
Initial rates: = = = = =
a T b T c T
INITIAL CONCENTRATIONS
TRIAL [I-] [BRO3-] [H+] INITIAL RATE
1 0.010Mx(0.01/0.05 0.040Mx(0.01/0.05) 0.010Mx(0.01/0.05
) = 8x10-3 M ) 6 (
1 2 x 103 M 0.010 M
112 s0 s )=1.19 x 10
= 2x10-3 M = 0.02 M
2 0.010Mx(0.02/0.05 0.040Mx(0.01/0.05) 0.010Mx(0.01/0.05
) = 8x10-3 M ) 6 (
1 4 x 103 M 0.010 M
64 s0 s )=1.56 x 10
= 4x10-3 M = 0.02 M
3 0.010Mx(0.01/0.05 0.040Mx(0.02/0.05) 0.010Mx(0.01/0.05
) =0.016 M ) 6 (
1 2 x 103 M 0.010 M
22 2 s0 s )=6.01 x 10
= 2x10-3 M =0.02 M
4 0.010Mx(0.01/0.05) 0.040Mx(0.01/0.05) 0.010Mx(0.02/0.05
= 2x10-3 M = 8x10-3 M ) 6 (
1 2 x 103 M 0.010 M
11 s0 s )=1.21 x 10
= 0.04 M
5 0.010Mx(0.01/0.05 0.040Mx(0.005/0.05) 0.010Mx(0.15/0.05
) = 2x10-3 M = 4x10-3 M ) 6 (
1 2 x 103 M 0.010 M
18 s0 s )=7.41 x 10
= 0.03 M
0.763 = 0.5x
x=0
Rate 1 k [2 x 103 M ]x [8 x 103 M ] y [0.02 M ]z
= x y z
Rate 3 k 3
[2 x 10 M ] [0.016 M] [0.02 M ]
5 3 y
1.19 x 10 M /s [ 8 x 10 M ]
6.01 x 106 M /s = [0.016 M]
y
1.98 = 0.5y
y=0
3 x 3 y z
Rate 1 k [2 x 10 M ] [8 x 10 M ] [ 0.02 M ]
= x y z
Rate 4 k 3
[2 x 10 M ]
3
[8 x 10 M ] [ 0.04 M ]
0.0983 = 0.5z
z= 3