Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

TEST - 2 (Paper-I)

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 31. (1) 61. (4)
2. (4) 32. (4) 62. (2)
3. (2) 33. (2) 63. (2)
4. (2) 34. (2) 64. (2)
5. (2) 35. (2) 65. (3)
6. (1) 36. (2) 66. (1)
7. (1) 37. (3) 67. (Deleted)
8. (3) 38. (4) 68. (Deleted)
9. (2) 39. (2) 69. (1)
10. (1) 40. (1) 70. (3)
11. (2) 41. (2) 71. (1)
12. (2) 42. (1) 72. (2)
13. (2) 43. (2) 73. (3)
14. (3) 44. (4) 74. (1)
15. (1) 45. (4) 75. (4)
16. (3) 46. (3) 76. (4)
17. (4) 47. (1) 77. (2)
18. (2) 48. (3) 78. (3)
19. (3) 49. (3) 79. (4)
20. (1) 50. (2) 80. (2)
21. (3) 51. (1) 81. (2)
22. (1) 52. (2) 82. (2)
23. (3) 53. (1) 83. (1)
24. (1) 54. (4) 84. (3)
25. (2) 55. (3) 85. (1)
26. (3) 56. (2) 86. (4)
27. (4) 57. (3) 87. (3)
28. (4) 58. (3) 88. (4)
29. (2) 59. (1) 89. (4)
30. (1) 60. (3) 90. (3)

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)

PART - A (PHYSICS)
1. Answer (1) 4. Answer (2)

3mg
T
T m
2 m/s2 2 kg
mg 2mg
20 2 (T = 0)
3 kg 2 m/s 2mg
30 m
a=2 m/s2 kx = mg mg
T = 24 N kx = mg
In 2 seconds, block of 3 kg mass will move down by m
4 m and block of mass 2 kg will move up by 4 m. mg
On 2 kg block On 3 kg block On system When string is cut, spring force will not change
immediately.
Wmg = 80 J Wmg = 120 J Wmg = 40 J
So, just after cutting the string.
WT = 96 J WT = 96 J WT = 0
B (m )
Wnet = 16 J Wnet = 24 J a = 2g
Pulley is ideal (massless), so net force on it is 2mg
zero. 5. Answer (2)
2. Answer (4) 10 m/s
2 kg 30
Work done by kinetic friction on a system is always
negative.
3. Answer (2) 40 m
a = g sin N
m
v = 25 m/s
mg sin mg cos Using work-energy theorem,
mg
Wmg + Wair-resistance = K

1
N = mg cos 800 J + Wair-resistance = 2[625 100]
2
a = g sin (down the incline) Wair-resistance = 275 J
g sin cos 6. Answer (1)
At t = 5 s,
v v
2 kg 3 kg F = 10 N
g sin g sin2
A 20/3 m B
So, (mg N cos = mg sin2) w.r.t. A,
N sin 20/3 m
N
2 kg 3 kg
m

mg a = 10 m/s2
3
(u = 0)

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Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

1 2 10. Answer (1)

s at
2 F/2
( ) m
20 1 10 2 F F
t 2m
3 2 3
t=2s
S
7. Answer (1) Force acting on each block is in the ratio of
4 m/s2 masses. No slipping tendency. So, no frictional force
will act.
( = 0.4) 2 kg f=8N
2T 11. Answer (2)
f=8N 3 kg

T 8 m/s2 ac (centripetal)
anet
T M
mg at (tangential)
At the time of slipping, friction would be maximum. a net is resultant of centripetal and tangential
So, 2T = 5 4 = 20 acceleration.
T = 10 N 12. Answer (2)
Now, mg T = M 8 At origin,
M 2 = 10 U=0
M = 5 kg K=0
8. Answer (3) So, total mechanical energy = zero.
By conservation of mechanical energy, speed of At x = 1, U = 3 and K + U = 0
block at highest point of track is same.
k=3J
In first case at highest point,
13. Answer (2)
mv 2
N1 mg ac
1
In second case, m
3m
mv 2
N2 mg
2
1 < 2 N1 > N2 F

9. Answer (2) F
acommon =
4m
f
FBD of m w.r.t. 3m,
f
N = ma
N 150 N
5 kg fmax = ma fP = ma m N
50 For no slipping,
mg
N = 150 N fmax mg

fL = N ma mg

= 60 N a 2g
fL > weight equilibrium amin = 2g
So, frictional force would be 50 N. Fmin = 8mg

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)

14. Answer (3) 17. Answer (4)

TA = ? x3 5 2
U x 6x 5
4 m, 4 kg 3 2
A
2 kg 18 N dU
F ( x 2 5 x 6) 0
3m dx

18 x = 2, 3
a 3 m/s 2
6
a Positions of equilibrium
T T
3 kg 3 kg 18 N dU
x2 5x 6
dx
3 m/s2 d 2U
2x 5
3 kg T dx 2
d 2U
So, T = 9 N 1;
x2
dx 2 x 2
15. Answer (1) Position of unstable equilibrium
When spring is in natural length normal reaction is d 2U
50 N. 1;
x2
dx 2 x 3
Position of stable equilibrium
18. Answer (2)
N T = 20 y 20
N
5 kg t=1
5 kg s 40
50 uy = 30 m/
50 50
10 N
kx = 20
mean position 37
2 kg 2 kg x
vmax (t = 0) ux = 40
20
At t = 1 s,
When 2 kg will have maximum velocity, i.e., at
mean position. F 10( j )

T + N = 50 v 40i 20 j
N = 50 T
P F v 200 J/s
= 30 N
19. Answer (3)
and when spring is maximum elongated,
KE = 2t2
T = 40 N
1
mv 2 2t 2 (m = 1 kg)
So, N = 10 N 2
16. Answer (3) v = 2t

1 2 at = 2 m/s2
mgh mgs kx
2 max v 2 16
ac 2 m/s2
1 t 2 R 8
200 100 2
(100) xmax
2 Power delivered by centripetal force is zero.

xmax 2 m (F v 0)

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Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

Power delivered by tangential force at t = 2 s 23. Answer (3)

= (mat)v v

1 sin
=24=8W 1
f
20. Answer (1) 1 cos

F (N)
10

As shown in figure, unit vector in the direction of

friction is sin i cos j .
t (s)
4 24. Answer (1)
T
Area under F-t graph,

20 P 5 kg

20 Pf Pi 10 = kx 37 37
kx = 10

2v = 20 50
k = 100 N/m
v = 10 m/s
Compression x = 0.1 m
1 kx = 10 N
Wnet = 2 100 0
2 In equilibrium,
= 100 J T + 20 cos 37 = 50
T = 34 N
Wnet 100
Pav 25 W 25. Answer (2)
t 4
21. Answer (3)
10 kg F = 35 N
p2 fk = 30 N ( s = 0.4,
k
2m k = 0.3)
p 2mk As block starts sliding, friction would be kinetic.
5
1 So, acceleration a 0.5 m/s2 .
loge p (loge 2m loge k ) 10
2 26. Answer (3)
1 Explanation : In absence of pushing force, block
Y (constant x ) cannot move with constant velocity as frictional force
2
will retard it.
1
So, slope = A net force is always required to change state of a
2 body.
22. Answer (1) 27. Answer (4)
Impulse = Change in momentum Frictional force will not be directed towards the
centre because one component of friction will
I = m(3u (u)) provide tangential acceleration.
I = 4mu Centripetal force is always required to revolve in a circle.
28. Answer (4)
1
W = K = m(9u2 u2) KE depends upon frame of reference, so for different
2
observers it may be different.
W = 4mu2 29. Answer (2)
W = Iu 30. Answer (1)

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)

PART - B (CHEMISTRY)
31. Answer (1) nO RT
2
Volume of O2 =
Second ionisation potential of O is higher than that P
of F and N because of its stable electronic
configuration. 2 0.0821 310
=
32 1
32. Answer (4)
= 1.59 L
Cs+ ion is least hydrated in aqueous medium due to
its lowest charge density among alkali metal ions. nCO RT
2
Volume of CO2 =
33. Answer (2) P

Electronic configuration of X (atomic number = 34) is 8 0.0821 310

=
1s22s22p63s23p63d104s24p4 44 1
Group number = 10 + number of valence electrons = 4.62 L
= 10 + 6 = 16
38. Answer (4)
Period number = principal quantum number of the
outermost shell = 4 Ionisation potential of an element is high if its atomic
size is small and/or it has stable electronic
34. Answer (2) configuration.
As the size of halogen atom increases, bond angle 39. Answer (2)
of PX3 increases.
The maximum difference in ionisation potential
35. Answer (2)
values occurs between IE3 and IE4. Therefore, the
element belongs to group 13 whose general
O
electronic configuration is ns2np1.
Structure of SO42 ion is S .

O O 40. Answer (1)
O
1.6 1019 92 10 12
cal 4.42 D; obs 1.98 D
Bond order of S O bond is 1.5. 3.33 10 30
36. Answer (2)
1.98 100
Percentage of ionic character = = 44.8%
3O2 (g) 2O3 (g) 4.42

Vol. (L) 1.8 0 41. Answer (2)

2 More electronegative elements occupy the axial

1.8 x x position in trigonal bipyramid structure. Therefore, F
3
and Cl occupy axial positions.
2
Volume of the mixture = 1.8 x x 1.6 42. Answer (1)
3
x = 0.6 4.2
Number of moles of N2 in container 'A' = = 0.15
28
2
Volume of O3 = 0.6 0.4 L Let number of moles of N2 in container 'B' be x.
3
0.4 Partial pressure of N2 in container 'A' and 'B' must
Mole fraction of O3 = 0.25
1.6 be equal.
37. Answer (3) xRT2
(0.15 x)RT2 x 0.12
0.1 L blood has 0.02 g O2 and 0.08 g CO2 4
10 L blood has 2 g O2 and 8 g CO2 Mass of N2 in container 'B' = 3.36 g

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Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

Entire mass of I2 sublimes in container 'A' and is 0.75 V = (n1 + n2)R 300
collected in container 'B'.
8.25 V = (2n1 + 3n2)R 1200
Total mass of N2 and I2 in container 'B'
8.25 (2n1 3n2 )n n2 3
= 3.36 + 1.27 = 4.63 g
0.75 n1 n2 n1 1
43. Answer (2)
3 100
3RT1 M Percentage of N2H4 in the mixture = = 75%
E1, Total KE of N2 = 4
2 28
49. Answer (3)
3RT2 M
E2, Total KE of Ar = The hybridisation state of Cl in ClO3 is sp3. The
2 40
P-atom of PO43 also has sp3 hybridisation.
E1 T1 40 5 T1 7
50. Answer (2)
E2 T2 28 1 T2 2
44. Answer (4) Electronic configurations of the given species are

2NO O2 2NO2 2 p 2
C2 : 1s 2 * 1s 2 2s 2 * 2s 2
x

Moles 3 0.75 2 p 2
y
3 1.50 0 1.50 Diamagnetic (Bond order = 2)
= 1.50
Initial moles = 3 + 0.75 = 3.75 2 p2
NO : 1s 2 *1s 2 2s 2 *2s 2 2 pz2 x
*2 px
1
Final moles = 1.50 + 1.50 = 3.00 2 p2
y
nRT Paramagnetic (Bond order = 2.5)
Change in pressure =
V
0.75 0.082 300 2 p2 *2 p1
x x
= O2 : 1s 2 *1s 2 2s 2 *2s 2 2 pz2
9 2 p2 *2 p1
y y
= 2.05 atm Paramagnetic (Bond order = 2)
45. Answer (4)
Elements of 4d and 5d transition series belonging to 2 p 2
N2 : 1s * 1s 2s * 2s
2 2 2 x2
2 pz
2
the same group from 4th group onwards have nearly 2 p2
y
same atomic radii due to lanthanoid contraction.
Diamagnetic (Bond order = 3)
46. Answer (3)
NO+ becomes diamagnetic and has bond order = 3.0.
Electronic configuration of Al is 1s22s22p63s23px1
51. Answer (1)
Shielding constant () for the outermost electron
= 0.35 2 + 0.85 8 + 1 2 = 9.5 720 0.25 0.6
Number of moles of N2 =
Zeff = Z = 13 9.5 = 3.5 760 R 300 760 R
47. Answer (1) 776 0.30 0.8
Number of moles of O2 =
Fact 760 R 291 760 R
48. Answer (3) 0.6 0.8
Total number of moles of N2 and O2 =
Let the number of moles of NH3 and N2H4 be n1 and 760 R
n2 respectively.
1.4
=
2NH3 N2 3H2 760 R
N2H4 N2 2H2 1.4 R 310
Pressure of N2 and O2 = atm = 868 torr
Total number of moles after complete decomposition 760R 0.5
= 2n1 + 3n2 Total pressure = 868 + 42 = 910 torr

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)

52. Answer (2) 54. Answer (4)

Intramolecular H-bond is present in all the given
PV 800 1
Z ; 1.90 options.
nRT nR 330
H
200 V H O O O H
1.10 Cl O
nR 570 N O
Cl C CH O C
On solving, O
Cl O
H O H
1.10 200 V 330
55. Answer (3)
1.90 800 570
Bond angle of NF3 is lower than that of NH3 because
V=4L F is more electronegative than N, whereas N is
more electronegative than H. PH3 has lower bond
53. Answer (1)
angle than PF3 due to back bonding in PF3.
Methoxy group at the p-position is electron releasing
56. Answer (2)
group due to +R effect and hence enhances the
dipole moment of nitrobenzene to a large extent. 57. Answer (3)
Methyl group releases electron density due to +I 58. Answer (3)
and hyperconjugation. Cl and NO2 are electron with
drawing groups and hence decrease the dipole 59. Answer (1)
moment. 60. Answer (3)

PART - C (MATHEMATICS)
61. Answer (4) 63. Answer (2)
A B = {b, d} Number of relation from A to B is
A B = {a, b, c, d, e, f} 2mn = 255 = 225
Elements b and d are must in set C, elements a, c, A = {2, 1, 0, 1, 2}, n(A) = 5
e and f may or may not be present.
B = {1, 0, 1, 2, 3}, n(B) = 5
Total number of set C possible is 24.
62. Answer (2) 64. Answer (2)

cos[ 4]x = cos(97x) A

cos[ 4]x = cos(98x) R

sin[ 3]x = sin(31x)
sin[ 3]x = sin(30x) S Q
3 B C
Now, cos (97) 0 P
2
Let a be the length of each side of equilateral
3 1
cos 98 1 ABC. Then, r be the radius of the incircle = AP
2 3
(the altitude, median and the angle bisector of angle
3 A).
sin 31 1
2
2
1 2 a a
3 r a
sin 30 0 3 4 2 3
2

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Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014
2
Area of square 2r b c
= Similarly, tan B, tan C
Area of equilateral triangle 3 2 Y Z
a
4 a b c
2 = tan A + tan B + tan C
a x y z
2
43 = tan A tan B tan C
=
3 2
a abc
4 =
4 1 xyz
=
3 6 67. Deleted
2 68. Deleted
=
3 3 69. Answer (1)
65. Answer (3)
A
A
3
2 E
Q b
R c
2 B
3
B D C
B C
2 P 3
ADE = B
1 2 3
Area of ARQ = sin A c b From ABD,
2 5 5
AD = c sin B
6
= BD = c cos B
25
Similarly, area of BRP = Area of CPQ 1 2
Area of ABD = c sin B cos B
6 2
= 2
25 c
= sin 2B
6 4
Area of PQR = 3
25 AE = AD sin B AE = c sin B sin B
Area of PQR 18 7
1 ED = c sin B cos B
Area of ABC 25 25
66. Answer (1) 1 2 2
Area of ADE = c sin B sin 2B
A 4

1 2 2
Area of BDE = c cos B sin 2B
cF
X Eb 4
B
70. Answer (3)
H Let be the smallest angle, then 2 is largest. So,
D from the triangle
B C
a sin sin 2
In a ACF,
a 1 a1
AF = b cos A
a1
In AHF, 2 cos
a 1
b cos A 2 2 2 2
sin B (a 1) a (a 1) a 4a
X Also, cos = =
2a(a 1) 2(a 1)a
X = 2R cos A
a a 1 a 4
So, tan A a5
X a 1 a 1

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)
71. Answer (1) 74. Answer (1)
r r2 = r3 r1
A B A B


s s b s c sa
AB A B
b c a
A B
s(s b) (s c )(s a)

(s a)(s c ) a c
(A B) (A B)
s(s b ) b
75. Answer (4) A
B ac
2 3 4
tan Arc(AB) = 3
2 b
Arc(AC) = 4 B C
B
But, , Arc(BC) = 5
2 6 4 5
3 4 5
r 3 ; ;
B 1 1 ac r r r
tan
2
, 1 = 1
2 3 3 b Now, 3 + 4 + 5 = 2r

b < 3a 3c < 3b 6 1
r
r 6
b + 3c < 3a < 3b + 3c
ABC = OAC + OAB + OBC
72. Answer (2)
1 2 3 4 5
r sin sin sin
2
f(2) = 2(2) + 3 = 1 =
r r r
f(3) = 3 + 2 = 1
1 36 2 5
= sin sin sin
f(6) = 6 + 2 = 4 2 2 2 3 6
f(| f(6) |) = f(4) = 4 2 = 2
18 3 1
= 2
1
f(5) = 5 + 2 = 3 2 2
f(f(3)) = f(3) = 3 + 2 = 1 9 3(1 3 )
= 2
f(2) = 0
f(0) = 3 76. Answer (4)
f(f(0)) = f(3) = 3 2 = 1 2 sin x
2
f(f(f(0))) = f(1) = 2(1) + 3 = 5 1

/2
X
f(f(f(f(0)))) = f(5) = 3 1
2

2
A = f(2) + f(3) = 2
B = f(| f(6) |) = 2
C = f(f(5)) + f(2) = 1 7/6
11/6
D = f(f(f(f(0)))) = 3 /2 5/6 2
X
1
73. Answer (3) 2

Only option (3) satisfy the condition of a function.

Range = {2, 1, 0, 1}

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Test - 2 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

77. Answer (2) 81. Answer (2)

r1, r2, r3 are in H.P. A
a, b, c are in A.P.
c = 16 a S
2A
s(s a)(s b )(s c ) 24
P1 Q1
a = 6, 10 B C
D
a = 10 (largest side) P1Q1
sin 2 A
78. Answer (3) SD
D60 = {1, 2, 3, 5, 6, 10, 12, 15, 30, 60} So, we have
f(2, 15, 30) = (2 + 15)(15 + 30) P1Q1 P2Q2 P3Q3
= sin 2A + sin 2B + sin 2C
SD SE SF
60
= (30) 30
15 = 4 sin A sin B sin C

= (30)(4 + 30) 2
= 2
= (30)(60) R
= GCD(30, 60) 82. Answer (2)
A
= 30 A A
DI = r cosec x cosec /6
79. Answer (4) 2 2
D x
Given, = 2r 2x
2f(x 3) + f(2 x) = x 2 ...(i) r + x = 2(r x) I r
Put, x 3 = t in (i)
r 1
2f(t) + f(t 1) = (t + 3)2 ...(ii) 3x r x B C
3 3
Now, put t 1 = u 83. Answer (1)
2f(1 u) + f(u) = (u + 2)2 ...(iii)
[sin{3x 2}] = [sin(fractional part)]
i.e., 2f(1 t) + f(t) = (2 t)2 ...(iv)
= [fractional value]
Solving (ii) and (iv) for f(t), we have
=0
2
t 16t 14
f (t ) 84. Answer (3)
3 3 3
80. Answer (2) The given function can be graphically, represented
as
A y = |x|

y=3
4
/4
B C
D
y = 1 |x|

(BD DC ) cot = DC cot B BD cot C
4 3
Range is , .
2 = | cot B cot C | 4

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All India Aakash Test Series for JEE (Main)-2014 Test - 2 (Paper-I) (Answers & Hints)

85. Answer (1) 3x 5 1

b 6
Slope AG = (0, b) x
2a 3
x2
3b 0, b
2a 2 G
So, tan 30 = 7
2
30 A x N and x
b 2
1 2 (a, 0)
a a, 0 x {4, 5, 6, ......}
2
where, a2 + b2 =9 88. Answer (4)
5 8

1

3ab
2 2 2 sin B
3 2(a b )
3
2 2
1 a b 9 16
ab 3 sin B
2 3 3 3 3 15
86. Answer (4) sin B > 1
Maximum value of is when a = b = c. Not possible
89. Answer (4)
3 2
a
4 R A A and R is not a relation in A.
3a 90. Answer (3)
and s =
2
A B
3 2s 2 s
2
8 6 4

4 3 3 3 4
2 1
87. Answer (3)
25 10
For 3x5Cx+2 to defined
C
3x 5 x + 2
n(A B C) = 35
2x 7
Statement 2 is false.
7
x n(A B C) = 60 (4 + 1 + 10)
2
= 60 (15)
x+2N
= 45
xN

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