Name: Class :

SMK KERATONG

UJIAN PENILAIAN TAHAP 1

FORM 5

2012

CHEMISTRY

1 HOUR

(40 MARKS)

SECTION A

1. The following equation represents the reaction between calcium carbonate and hydrochloric acid
Persamaan berikut mewakili tindak balas antara kalsium karbonat dan asid hidroklorik

CaCO3 (s) + 2HCl(aq) CaCl2(s) + H2O(l) + CO2(g)

Which of the following factors cannot increase the rate of this reaction
Antara faktor berikut, yang manakah tidak boleh meningkatkan kadar tindak balas ini?
A Decrease the size of calcium carbonate
Mengurangkan saiz kalsium karbonat
B Increase the temperature of the mixture
Meningkatkan suhu campuran
C Increase the concentration of hydrochloric acid
Meningkatkan kepekatan asid hidroklorik
D Increase the volume of hydrochloric acid
Meningkatkan isipadu asid hidroklorik

2. Which of the following changes can increase the amount of product formed in a chemical reaction?
Antara perubahan berikut, yang manakah dapat meningkatkan jumlah hasil dalam suatu tindakbalas
kimia?
A Increase the concentration of the reactant
Meningkatkan kepekatan bahan tindak balas
B Reduce the mass of catalyst
Mengurangkan jisim mangkin
C Increase the size of a solid reactant
Meningkatkan saiz bahan tindakbalas
D Decrease the volume of reactant
Mengurangkan isipadu larutan bahan tindakbalas

3. Effective collision is the collision where

Perlanggaran berkesan ialah perlanggaran yang
A its energy is less than the activation energy and with correct orientation
tenaganya kurang daripada tenaga pengaktifan dan dalam orientasi yang betul.
B has a low energy
mempunyai tenaga yang rendah
C its energy is equal to the activation energy
tenaganya sama dengan dengan tenaga pengaktifan
D its energy is greater than the activation energy with the correct orientation
tenaganya lebih besar daripada tenaga pengaktifan dan dalam orientasi yang betul
4. The following equation shows the reaction between excess zinc powder and dilute hydrochloric acid:
Persamaan berikut menunjukkan tindak balas antara serbuk zink berlebihan dengan asid hidroklorik cair:

Zn + 2HCl ZnCl2 + H2

Which of the following graphs represents the volume of hydrogen gas (V) released against time (t)?
Antara graf berikut yang manakah mewakili isipadu gas hidrogen (V) yang dibebaskan melawan masa
(t)?
A

D
5. Diagram shows the set-up of apparatus used to study the rate of reaction of marble chips and nitric acid.
Rajah menunjukkan susunan radas yang digunakan untuk mengkaji kadar tindak balas antara ketulan
marmar dengan asid nitric

The rate of reaction in this experiment can be increased by

Kadar tindak balas bagi eksperimen ini boleh ditingkatkan dengan

A using the smaller sizes of marble chips

menggunakan saiz ketulan marmar yang lebih kecil
B using a larger conical flask.
menggunakan kelalang kon yang lebih besar
C adding water to the nitric acid.
menambahkan air ke dalam asid nitrik
D decreasing the temperature of the nitric acid
merendahkan suhu asid nitrik

6. Excess zinc granules are added to 50 cm3 of 0.1 mol dm-3 hydrochloric acid. The hydrogen gas evolved is
collected at 30 second intervals. The results are tabulated in Table below.
Butiran zink yang berlebihan ditambahkan kepada 50 cm3 asid hiroklorik 0.1 mol dm-3. Keputusan
dicatatkan di dalam jadual di bawah.

Time /s 0 30 60 90 120 150

Masa/s
Total volume of H2 /cm3 0 11 18 22 24 24
Jumlah isipadu H2 /cm3
What information can you obtain from the results of this experiment?
Apakah maklumat yang boleh diperolehi daripada keputusan eksperimen ini?
I No hydrogen gas is released after 120 seconds
Tiada gas hidrogen dibebaskan selepas 120 saat
II The average rate of reaction is 0.16 cm3 s-1
Purata kadar tindak balas ialah 0.16 cm3 s-1
III The total volume of hydrogen gas collected is 99 cm3
Jumlah isipadu gas yang terkumpul ialah 99 cm3
IV The rate of hydrogen gas released decreases with time
Kadar pembebasan gas berkurang dengan masa

A IV only
B I and IV
C I, II and IV
D I, III and IV
7. The time taken for the reaction between lumps of marble with sulphuric acid can be shorten by
Masa yang diambil untuk tindak balas antara ketulan marmar dengan asid sulfurik boleh dipendekkan
dengan
A adding distilled water
menambahkan air suling
B adding concentrated of sulphuric acid
menambahkan asid sulfurik pekat
C Using the bigger size of marbles
menggunakan saiz marmar yang lebih besar
D keeping the mixture of the reaction in refrigerator
meletakkan campuran tindak balas di dalam peti sejuk

8. The following information shows the effect of concentration on the rate of reaction.
Kenyataan berikut menunjukkan kesan kepekatan terhadap kadar tindak balas

When the concentration of sodium thiosulphate, Na2S2O3 solution increases, the time taken for the
mark X to disappear from sight becomes shorter.

Which of the following statement best concludes about the information above?
Manakah antara yang berikut merupakan kesimpulan terbaik tentang kenyataan di atas?
A The concentration is directly proportional to the time taken
Kepekatan berkadar terus dengan masa
B The rate of reaction is directly proportional to the time taken
Kadar tindak balas berkadar terus dengan masa
C The rate of reaction is directly proportional to the concentration
Kadar tindak balas berkadar terus dengan kepekatan
D The rate of reaction is inversely proportional to the concentration
Kadar tindak balas berkadar songsang dengan kepekatan

9. Diagram 4 shows the graph of volume of carbon dioxide gas against time when 5 g of marble chips is
added to 50 cm3 of 0.2 mol dm-3 hydrochloric acid.
Rajah 4 menunjukkan graf isipadu gas karbon dioksida melawan masa apabila 5g ketulan marmar
dimasukkan ke dalam 50 cm3 asid hidroklorik 0.2 mol dm-3.
Volume of CO2 gas / cm3
Isipadu gas CO2 / cm3

Time / s
0 t1 t2 t3 t4 Masa / s
 At what time the rate of reaction the highest?
Pada masa manakah kadar tindak balas paling tinggi?
A t1
B t2
C t3
D t4

10. Diagram 15 shows curve W obtained from the decomposition of 20 cm3 of 0.40 mol dm-3 hydrogen
peroxide solution, H2O2, using 0.2 g of manganese (IV) oxide as catalyst at a temperature of 30 0C.
Rajah 15 menunjukkan lengkung W terbentuk daripada penguraian 20 cm3 larutan hidrogen peroksida
0.40 mol dm-3, di mangkinkan oleh mangan(IV) oksida pada suhu 300C.

Volume of oxygen /cm3

Isipadu oksigen /cm3

Time /minutes
Masa/minit

Which of the following experiments will produce curve X?

Antara eksperimen berikut yang manakah akan menghasilkan lengkung X?

Volume of H2O2 /cm3 Concentration of H2O2/ mol dm-3 Temperature /0C

Isipadu H2O2 /cm3 Kepekatan H2O2 /mol dm-3 Suhu / 0C
A 10 0.60 30

B 15 0.20 30

C 20 0.60 40

D 30 0.30 40

11. Which of the molecular formula is saturated hydrocarbon ?

Manakah formula molekul bagi hidrokarbon tepu?
A C3H6
B C4H10
C CH3OH
D C5H10

12. Hexene is classified as an unsaturated hydrocarbon because

 Heksena dikelaskan sebagai hidrokarbon tidak tepu kerana
A it contains only carbon and hydrogen .
ia mengandungi karbon dan hidrogen sahaja.
B it is a liquid at room temperature.
ia adalah cecair pada suhu bilik.
C it is less dense than water.
ia kurang tumpat daripada air
D it has a double bond between carbon atoms.
ia mempunyai ikatan ganda dua di antara atom karbon

13. Diagram shows the structural formula of a compound.

Rajah menunjukkan formula struktur bagi suatu sebatian.

Name the compound using IUPAC

nomenclature
Namakan sebatian tersebut menggunakan penamaan IUPAC.
A 2,4-dimethylhexane
2,4 dimetilhekasana
B 3,5-dimethylhexane
3,5-dimetilheksana
C 1,1,3-trimethylpentane
1,1,3-trimetilpentana
D 3,5,5-trimethylpentane

14. Which chemical formulae represent saturated hydrocarbon?

Formula kimia yang manakah mewakili hidrokarbon tepu?
I CH3CH(CH3)CH3
II CH3CH2CH2CH3
III CH2CHCH2CH3
IV CH3CHCHCH3
A I and II
B I and III
C II and III
D II and IV

15. Which of the following pairs of compounds are in the same homologous series?
Manakah antara pasangan sebatian berikut berada dalam siri homolog yang sama?
Compound 1 Compound 2
Sebatian 1 Sebatian 2
A C2H4 C4H8
B C2H6 C6H6
C C3H6 CH3CH2CH2OH
D C2H5OH C2H5COOH

16. The molecular formula of an organic compound is C4H10.

 Formula molekul sebatian organik adalah C4H10.
Which of the following is the isomer for the above molecular formula?
Antara yang berikut, yang manakah isomer bagi formula molekul di atas?
A CH2= CH-CH2-CH3

B CH3-CH=CH-CH3

C CH3-CH- CH3
|
CH3

D CH3-CH2- CH2
|
CH3

17 The following equation represents the reaction between propene and bromine.
Persamaan berikut mewakili tindak balas antara propena dan bromin.

Propene + Br2 X
Propena + Br2 X

What is the IUPAC name of compound X?

Apakah nama IUPAC bagi sebatian X?
A Tetrabromopropane
Tetrabromopropana
B 1-bromopropane
1-bromopopana
C 1,1-dibromopropane
1,1-dibromopropana
D 1,2-dibromopropane
1,2-dibromopropana

18 Which properties of propane and propene are the same ?

Sifat-sifat manakah sama bagi propana dan propena?

A Soluble in water
Larut dalam air
B Decolourise brown colour of bromine water
Menyahwarnakan warna perang air bromin
C Burn completely in air to produce carbon dioxide and water
Terbakar dengan lengkap dalam udara menghasilkan karbon dioksida dan air
D Decolourise purple colour of acidified potassium manganate (VII) solution
Menyahwarnakan warna ungu larutan kalium manganat (VII)berasid
19 Part of the structure of polymer is shown below .
Struktur sebahagian daripada suatu polimer ditunjukkan di bawah

H CH3 H H H CH3

~~~~C C C C C C ~~~~

H H H CH3 H H

Which of the following is the monomer of the polymer?

Di antara berikut yang manakah monomer bagi polimer tersebut?

A H H H

C = C C H

H H
B H H

C = C H

H
C H H H H

C = C C C H

H H H

D H H H H H

C = C C C CH

H H H H

20. Butene can be transformed to butane by the process of

Butena boleh ditukarkan kepada butana melalui proses
A Fermentation
Penapaian
B Oxidation
Pengoksidaan
C Dehydration
Pendehidratan
D Hydrogenation
Penghidrogenan
 SECTION B

1. A group of students carried out two experiments to investigate one factor that affects the rate of a
reaction
Sekumpulan pelajar menjalankan dua eksperimen untuk mengkaji satu faktor yang mempengaruhi
kadar suatu tindak balas.

Experiment 1 : Excess granulated of metal zinc is added to 25cm3 of 0.2 moldm-3 hydrochloric acid
Eksperimen 1 : Ketulan logam zink berlebihan ditambah kepada 25cm3 asid hidroklorik 0.2moldm-3

Experiment 2 : Excess powder of metal zinc is added to 25cm3 of 0.2 moldm-3 hydrochloric acid
Eksperimen 2 : Serbuk logam zink berlebihan ditambah kepada 25cm3 asid hidroklorik 0. 2 moldm-3

(a) (i) Write the chemical equation for this reaction

Tuliskan persamaan kimia bagi tindak balas ini

..
(2 marks)
(ii)Calculate the maximum volume of hydrogen gas released at room condition.
[Molar volume of gas at room condition : 24dm3mol-1]
Hitungkan isipadu maksima gas hidrogen yang terbebas pada keadaan bilik.
[Isipadu molar gas pada keadaan bilik : 24dm3mol-1]

(3 marks)
 (b) Diagram shows the results of experiment 1.
Rajah menunjukkan keputusan eksperimen 1.

Volume/cm3

Time/s

(i) Sketch the curve for experiment 2 on diagram above.

Lakarkan lengkung bagi eksperimen 2 pada rajah di atas.
(2 marks)

(ii)What is the factor that affects the rate of reaction in this experiment
Apakah faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini

..
(1 mark)
(iii)Compare the rate of reaction between experiment 1 and experiment 2
Give a reason.
Bandingkan kadar tindak balas antara eksperimen 1 dan eksperimen 2.
Berikan alasan.

.
(2 marks)

2 Table shows molecular formulae of 4 carbon compounds.

Jadual menunjukkan formula molekul bagi 4 sebatian karbon.

Compound Molecular Formula

Sebatian Formula molekul
A C4H8
B C4H10

(a) Write the general formula of the homologous series of compound B.

Tuliskan formula umum bagi siri homolog sebatian B.

..
[1 mark]

(b) State the functional group of compound A and compound B

 Nyatakan kumpulan berfungsi bagi sebatian A dan sebatian B.

Compound A : ..
Sebatian A

Compound B : ..
Sebatian B

[2 marks]

(c) Compound B shows isomerism. Draw the structural formula of all isomers of compound B.
Sebatian B menunjukkan isomerisme. Lukiskan formula struktur bagi semua isomer sebatian B.

[2 marks]

(e) Compound A burns in excess oxygen to produce carbon dioxide and water.
Sebatian A dibakar dalam oksigen berlebihan menghasilkan karbon dioksida dan air.

(i) Write a balanced chemical equation for the reaction.

Tuliskan persamaan kimia seimbang bagi tindak balas tersebut

................................................................................................................................................
[2 marks]
(f) Compare these two hydrocarbons.
Bezakan kedua-dua hidrokarbon ini.

[3 marks]