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~ .':tESTCong0:?;2140l0 ~ ~
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. l ' /. :. . . "'
FORMTPioo7i73 ...
. . MA Y/JliNE2007 .
. :: ;. : ;~- ..- .. ' .
NS CAREFULLy \
1. In addition to this test booklet, you should
. .
2. Each item in this test has four suggested ~nc:Uh"I"C!]ettered (A), (B), (c), q)). Read_.; e'ath item:you~re~.:
about to answer and decide which choice is
3. On your answer sheet, find the numberwh orresponds ~o yo.ur iterri arid s~age the space having
the same letter as the answer you have ch . Look ~it:ih{~~TR)~;f~~~~~~ow.
Sample Item
......
The best answer to this item is "a 'tO a*", so ~tnc~-uvf~rspace (C) has been black~ned.
....3-
_ ...........__.
.....
R!i.--
. ,~., . ;,;;~~~~~~::~~\dL ~',~;;;:.; . .
The rate equation for a reactio~l" -is~given-bj:~;~:.:;: '"3",.:":-: ~:/(li~::iitt~-equation for the reaction between
r. ~
1.
: . i '~. . - .-- .
(A) .. .. t ...
Rate
-: : ; .:_' t_ : .."! :. ~:~-: . :-."' :
Concentration
......
. .; .: -:- :'.. - .
(B)
~
.
.: .. : . . .: ~
Concentration
(C)
Rate
.....
Concentration
_,.... /
(D)
Rate
Concentration
GOONIO+HENEXTPAG~
I!
.:OJ._.,.._ --
.& -~ ::~a
.......... .:.. '
-3-
No. of
molecules (D)
with a
particu~ar
0/
energy 0
. :.}-:Yield:
No. of
molecules
with a
particular
energy
.. .
~ ':
(C)
No. of
molecules
with a
particular
energy
_lQn~t~c en_ergy
(D) Tt
"i
No. of _
~olecules
I with a
particular
energy
Kinetic energy
GOONTOTHENEXTPAGE
022 120 l 0/C 2007
--------
..
~
.....
.w ]_a:- Z;a;;# i -
' .
- 4- ...
~ ref~rs to the follo~i_ng _information.' -~. ;. , ... ..: ... :, . -~ . .: :-.. : ..
. . . .. . .... ; ,;.:.'.: :t~,;':>:~_:;;t ....~.;:: : .. :. ; .."
The standard electro~
.
e_potenti~ls ofchl~ti e, dich~om.~tC? ~:nd:it9.~.(III) iP~~-;;t.~~ a~ fol!6~~: .
. . . .~ . . .. ... - . . .. - .
: i
.: :-:
~ 1.36V.
+0.77V .
. ; _.,. .. :_: :. ~
i: -. : .
(A)
-
i ..... - ..
.
::. ... :;
(B) 2Fe ~(~q) + 2~~-~~q) ~ C1 2(g) + 2
3
. :' :
. ; ._.
- ' .'
.. :.:-
GOO~IOTHENEXTPAG E ~~-'":'
-: --- __:. . . ..:. . :. -=-=====~.i54!F~g:..;;.!:j:
~.:;:~2J2010/C2007
-: : --:i- . : . . -- -- .
h..,,
.. - 5-
8. Whic~ of the foi.Jo~iqg_.il~di~ator~ would _:.Whiph ~~:n.~~H9.n. wjll_ giye a . v.~J~.~ for t.he
.: ~
produce a sharp. colour change in tile titration hyd~~ge~-f~O.~.o?c~~~-{~HoP~.(~~)in an acidic
of a stro~g acid against a ~t~~~g base? .: buffer so1~tion? .
. -
9. Which of the following is: true about a buffer (A) At a given temperature, K, is the
s61uti6n? -~ maximum amount of ionfc solid
; . :. . : :4issplved in a.$aturat~4 solution .
I. (A) Normally c~msis;ts of :;t weak aciq .(B) .Ute.K;p of.an:ionic solid indicates the
l . and. its corresponding salt relative concentration .of ions that
. . fo!Jrl :a .pr~cipit~te i~ a .saturated
i
.i (B) Alters' the pH of a. sol.1:1tion to the
i desired pH~ :~oltition. ':
.1 (C) Does not. change in pH on addition (C) As _te_Jilp~rature changes~ the K,P of
!;
~fla.rge amouf!ts of aci4. or alkali . : : a_n(ip!JiC sol_i~ re~a~ns th.e same.
'
(D) Can a~t as a cataJyst in d.~eaction
- . . ......
. (D) . T.h~ K,P value of an ionic soli~ can
. - . . . . . . . ~.
'.. :.1:?<1 obtained before s~turation point
~ ~ :;-'iS achieVed.
~ 10. Wh~~h of the following does NOT describe a
:~ .prop~rty of the buffering ~ction of mixture a
l
1 of ammonium chlorid_e and aqueo~. s J~.- .. :The sia~dar~' :electrode potent.ial for the
ammonia? -
.. ~~~~ti~n ~n~~ :~ :2~-. t Sn 2
+ is E 6 = +0 .15V.
(A) Ammoni~ molecules are basic.
Chloride iops re~ct with hydrogen ';__ . -: B~~e.d .on tP:is infonnation ONLY, which of
(B) ...
..
ions.
- -
(C)
tons. I. .Tin'is a strong reducing agent.
II.-- Tin produces many stable compounds
(D) Ammonium chloride djssocates
in the +2 state.
C<?mple~~ly in ~ater..
III. Sn.4+ can oQ:itiize Cu 2+.
IV. The E 8 Sn 4+/Sn2+ is generated using
a standard hydrogen e_lectrode.
III. MnO-
.4
~ Mn 2++
+ sfi+ +: se- -t- 4H 0
2
.:.. .
. .
:
+ 1.52
....
~
(D) .. ~ ~ : . .. . -.. ~ .
.,:~
Na Mg AI Si P S Cl
i
-7 -.
Items 18 and 19 refer to _tht?. follow ng 2~ ... -.,\WJ!qnpf)b~ foJlow.ing q~jd.e& of~leme.nts in
oxidation states. : . ~- Oro~p t.Vi$ ~h~ .LEASTi~_i
.
q~c in_characte
. .
r?
. . . . . . ..
Match each underlined .~lement with ts . 24. Whi~h qf _.th~ ."foljo_wing grap.hs MOST
.oxidation .state. E~d{h~id~tion .state may be .. . -. :.- ~~curat~.ly ~.r~-~r.~~e_ntS)he treiJd ~n~;vo latil ity
.. .
. used once;-.nor~ tha~~on~e or n~t at.aH. : . _ .of. chl9ri~e;:b. roniine. ~~d. iocline?~:.
. "' . . .
I <::
18. ...-. .. ~A).
19 .
.I
j 20. Which of the following oxides has a_ s.im _le
molecular structure?
:I
Atomic number
l
(A) Na 2 0 . ..
(B) Si02
(C) Al2 0 3
{B)
(D) S03
JI
21.. Which of the following -~tatemehts al;> t. - ..
I
Group II elements are corre,ct? .' : .
:j
I
.J I. Atomic r;1~iu_s inre~ses down t e
]
group. Atomic nu~ber
.:!.,
ll. Ionic radius de.creases down t e
group. . . ::_:_. . .
l
:t
III. Io~isation energy' de<;re-ases 4o ::{C).
;
the group.
i IV. Sulp~ate solu~jlityincr~~ down
.~
!
. grotiii ' ~-, . . :
(A) I and III only
{B) U _and UI only
{C) I and IV only
. (D) 'Il and IV only. Atomic number ..
(D)
22. The metallic chara~ter of Group TV elemen s
increases down the gro"up ~ecause t;.O
.5 .0
til-
~:3
(A) they are all reducing agents ....
~
(.)-
c 0
(B) their melting points are high
- :>
(C) the +2 oxidation state becomes mo
stable
(D) atomic radius increases for eac Atomic number
successive element
GO QN TO Tl-IFNF_X .T.PA n-.:;
= =: ...
--------------------------------"------
..
J
25. The precipitate.fomied when iodide ions react .: , .:~Itemi'l9refeisto tlie:tabhi~which.-showS. the
,vith AgNO/!tci) is ; .. ~ ......., . opservations:made }fl:;.ih:e.:qfi~)li~iive-'.analysis.
J (A) soluble in dilute-nqueousammonia
of two cations, X and Y, \.\Sing dilute NaOH
(aq) and Na2C03 (aq). : .~-:
J
!
i
(B)
(C)
(D)
yellow silver ioelide
cream silver hydroxide
soluble in nitric acid
.:: .
Cation NaOH(aq)
(B) [ArJ I
. 3d
t t I t l I t
3d-
* I t -1- 1 t:.
. .- .
4s
I. ffi]
4s
= (tf: . :::N!Ao~--~_.,fr'X~5tf~ :
.:<I?J ..~ .. s~~q/~J~f(~gi.:'... .
(C) [Ar] I ti I t-1- l'tt I t-t,lti.l [LJ
3d ~: . 4s
(D) [ArJ I t~ -I t t I t~:l t-1- 1-t I ;[ill
. r~.J .. ..-! .f~.~- :_., .. : l. \
28_, --Which of the fo~lowipg species CANNOT act (A) compl.~~~i<?Jl.of. jmpurit~~s such as
as a ligand for transition metal complexes of
.sodium.siiic~i~ : ,
(B) prote~iJ~g. :th'e'_-:g~~phite .~r:t9de from
Cr1+? o 2- .. io~s . " - ~
(C) providing'_ a lower melting.:p-oint
(A) H 20
(B) NH 3 ...:..: -~!i~~~~: . i : .. . . . .
. gent?r,atj.n_g AP~ . ic;m~. that are
(C) NH.~
dl~ch~rged at the anode
(D) c1-
~ = i ~ - . =;;.._,-
___;.;;-..-:;;;;:::.
/
,. -9 -
. Tp; w_l!at \IS~ .c~.n..Jh~~ .:P~9-G.l!9.t~Jrpm JJ:lJ~ 3_3., Apply~ngJ..e_.~hat~li~r;s RDQ~ipl~ to the Haber
.. fractionl;ll d_i$t~lla~i~n qf c~~-~ C?i.J .1?-~ .put?. . . .
, . , r I 1 ~:---: :: , ! .-, ,o t 0 ,I . ,, .. , ...... ) . , , 0 P!PG.~-~s:pre9j~ts th.a;~.~-~igg ~r~s~~~e and low
t~mper,~tuJ~;::ar_~J.id.~aLL . H.Q.wever, a
. l. : ~a~~~g ~&?.ftflg ',i .. teinperat_ureof 400 to 500~ is used. Why- is .
II. lxfak~pg ~~~~J~.s ._ 1~UQ a .~Jg~_ t~r;nperan~r~:employ~d?
Pn).~~_cing-~v~r&i.
:~~:~:h-~teii~r's~rinciple does not
III.
.....
. . .. ... .. . .. ~ (A) ;
(A) nr~nly :.. :. _.>:-- .
I ~~d ll .only:.'.... .
.. >....:; 'i. ~ = . :. f:tpplyJq:Ul~ :4t~u~trial manufacture
.,(J?). ... ._ = : . : . 1- .- qf aqm.t~:m~-~.-.:
. ...
- ..
.. \: '.l' :. . .
Cathode Anode
35. Which ofthe following is NOT a cpmmerciaJ 37. Dis~ol~e~ _Q~yg~n in :~at~r is importan t to
methodof~lcqhol P~C?Q~~~jo n? ._.: . aquatic iife .. Wh~ch of the following fact?rs
.: ..
. . .
conct?ntrati~n of oxygen in
decrease the
-(A) . -~nai-~o~i~-~~~p~~~tion_ .:- ~: ~ .. ::
(B) Aerq~i-~ ~~~P!r~~~9~ . . .
is
(C) Hydration I. .; .:. . : Dec~y ;of o'~g~~ic materia
(D) Fermenta tion . II. Turbulep<;e. of the. water
.~i1f ~~_-' _pl);tps~tpesi~-: _
- .. IV.:.. . J{espiratiqn,
......_
. - 10.:
- 11 -
.... ".
I 44. Which of ~he fo11owing represent . 45. Which of the following is NOT involved in.
greenhouse effect causedby- g~~e~ su as the formation of photochemic al smog?
C02 in the atmosphere~ .
(A) Su1phurdioxide
(A) Promotion ~f photpdi~spci (.B). Ozone
reactions . (C) Oxygen
(B) Absorption of infrared radiation . .(D) Nitrogendiox ide
(C) Free radic~l fonitation . . .
I
I
I ---
I
i
I
I.
!!
-
-~ ..........
::
wti .
=*~
-..;.
~
.. :. ~
022120 l 0/C 2007
_
- l_. ~-
__:__;====::::::::i~~=-~ .
~.........__
:: ~-
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