Torres Boker Cesar 2IM47 Termodinmica del Equilibrio

Qumico

Uso de la temperatura para

determinar la constante de
equilibrio
Con base en el problema hecho en clase, determine la
K y con ello determine las nuevas fracciones y el
avance de reaccin
Compuesto Alimentacin Moles en Fraccin en el
[mol] equilibrio [mol] equilibrio
N2 1
1 =0.98095 1
2 2
=0.19770
5
H2 4 3 3
4 =3.94286 4
2 2
=0.79463
5
NH3 - =3.94286E-2
=0.00795
5
TOTAL - 5=4.96191 1

K ( 5 )
K=K yK P n = R
=1.2188E-03 K
3 3 1

2(
200 4 2 1
2 ) ( ) 2

^ N H
K= 3
3

( ^ H ) ( ^ N ) 2
2
2
2

^
P
dP BP BPc ( B 0+ B1i )RT ci
ln i= ( Z i1 ) , Z =1+ , 0 '
=B + B B=
0
P i RT RTc P ci

0.422 1 0.172
B 0i =0.083 1.6
, Bi =0.139
T ri T r i4.2

P P
BP dP B BP P BP
ln ^ i= 1+
0
(
RT
1 =
P 0 RT
dP= =
RT 0 RT ) ( ) ( )

Tarea 3
Torres Boker Cesar 2IM47 Termodinmica del Equilibrio
Qumico

Para NH3
=0.253,Tc=405.7 K , Pc=112.8
111.324914 atm

T 505.2222 K P 200 atm

Tr= = =1.24531, Pr = = =1,79654
Tc 405.7 K Pc 111.324914 atm

c m3 atm

B=
( B0 + B1i )RT ci
=
( 0.083
0.422
1.245311.6
+ (
0.253 0.139
0.172
1.245314.2 ))
82.06
mol K
405.7 K
=58.681
P ci 111.324914 atm

3
cm
58.68193 200 atm
^ BP =
ln =
mol ^
=0.283087322766 =0.75345
RT c m3 atm
8 2.06 505.2222 K
mol K

Para H2
=0.216,Tc=33.19 K , Pc=13.13 12.95829899 atm

T 505.2222 K P 200 atm

Tr= = =15.22212 , Pr= = =15.43412
Tc 33.19 K Pc 12.95829899 atm

c m3 atm

B=
( B0 + B1i )RT ci
=
( 0.083
0.422
15.222121.6
0.216 (
0.139
0.172
15.222124.2
8 ))
2.06
mol K
33.19 K
=9.997
P ci 12.95829899 atm

c m3
9.9970862103 200 atm
^ BP =
ln =
mol ^
=0.04823 =1. 04941
3
RT c m atm
8 2.06 505.2222 K
mol K

Para N2
=0.038,Tc=126.2 K , Pc=34 33.555382atm

T 505.2222 K P 200 atm

Tr= = =4.00335, Pr= = =5.96029572842
Tc 126.2 K Pc 33.555382atm

c m3 atm

B=
( B0 + B1i )RT ci
=
( 0.083
0.422
4.003351.6
+0.038(0.139
0.172
4.00335 4.2 ))
8 2.06
mol K
126.2 K
=13.0864
P ci 33.555382 atm

Tarea 3
Torres Boker Cesar 2IM47 Termodinmica del Equilibrio
Qumico
3
cm
13.0864431781 200 atm
^ BP mol ^
ln = = =6.31302750005 E2 =1. 06517
RT c m3 atm
82.06 505.2222 K
mol K

Volviendo al problema original

^ N H 0 . 75345
K= 3
3

1
= 3 1
=0. 67909
( ^ H ) ( ^ N )
2
2
2
2 2
( 1. 04941 ) ( 1. 06517 ) 2

0.67909 ( 5 ) 10010.98095
K=1.2188 E03 K =8.27675 e4= =3.8093 9 e2 X N =
3 3 1 2
1
2 (
200 4 2 1 ) ( )
2
2

Tarea 3