Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
27 OCTOBER 2016
15.00-15.15 T-SET14-O148 T-CRE06-O81 I-PM07-O55 I-PSC08-O42 I-BFT08-O133 T-PM03-P61 I-ESH04-P114
15.15-15.30 T-SET15-O166 T-CRE07-O82 I-PM08-O71 I-BFT07-O126 T-IA03-P98 I-CRE01-P25
15.45-16.00 T-SPT02-O99 T-CRE08-O79 I-PM09-O115 I-PSC09-O57 I-BEB01-O118 T-ESH13-P158 I-CRE03-P37
16.00-16.15 T-SPT03-O169 T-CRE11-O111 I-PM10-O119 I-PSC11-O154 I-BEB02-O67 T-ESH14-P159 I-CRE04-P39
16.15-16.30 T-IA01-O50 T-CRE12-O122 I-PM11-O129 I-PSC12-O160 I-ESH01-O34 T-ESH15-P170 I-CRE09-P103
16.30-16.45 T-IA02-O17 T-CRE13-O32 I-PM14-O162 I-PSC13-O165 I-ESH02-O47 T-CRE09-P104 I-CRE10-P116
16.45-17.00 T-IA04-O69 T-CRE14-O152 I-PM15-O172 I-PSC14-O168 T-BFT03-P100 I-CRE15-P138
17.00-17.15 T-PSC06-O157 T-CRE17-O177 I-PM16-O173 I-PSC15-O51 T-BFT05-P176 I-BFT06-P108
10.45-11.00 T-ESH01-O15 T-PM02-O60 T-BFT01-O26 I-SET01-O19 I-CRE11-O121 T-BEB01-P45
11.00-11.15 T-ESH02-O56 T-PM04-O109 T-BFT02-O92 I-SET02-O18 I-CRE02-O31
11.15-11.30 T-ESH03-O73 T-PM05-O124 T-BFT04-O150 I-SET03-O21 I-CRE05-O40 ITIChE & TIChE Program
11.30-11.45 T-ESH04-O102 T-PM08-O153 T-PPT01-O96 I-SET04-O14 I-CRE06-O23 BEB Biomedical Engineering and Biomaterials
28 OCTOBER 2016
11.45-12.00 T-ESH05-O105 T-PM09-O161 I-SET05-O35 I-CRE07-O59 BFT Biochemical Engineering & Food Technology
13.00-13.15 T-ESH06-O107 T-SET01-O16 T-PSC01-O90 I-SET06-O36 I-CRE08-O91 CRE Catalyst and Reaction Engineering
13.15-13.30 T-ESH07-O127 T-SET05-O75 T-PSC02-O93 I-SET07-O63 I-CRE12-O125 ESH Environmental, Safety, Health & Risk Management
13.30-13.45 T-ESH09-O130 T-SET16-O175 T-PSC03-O101 I-SET08-O66 I-CRE13-O131 IA Innovation in Chemical Engineering & Applied
13.45-14.00 T-ESH10-O132 T-SET08-P88 T-PSC04-O155 I-SET09-O76 I-CRE14-O137 Chemistry for Industrial Development
14.00-14.15 T-ESH11-O80 T-PSC05-O156 I-SET10-O94 I-CRE16-O140 PM Polymers and Materials
14.15-14.30 T-ESH12-O151 I-SET11-O95 I-CRE17-O48 PPT Petroleum & Petrochemical Technology
14.30-14.45 I-SET12-O134 I-CRE18-O171 PSC Process Design, Simulation and Control
SET Sustainable Energy Technology
SPT Separation and Purification Technology
The 26th National Thai Institute of Chemical Engineering and
Applied Science Conference (TIChE2016)
The 6th International Thai Institute of Chemical Engineering and
Applied Science Conference (ITIChE2016)
ABSTRACTS
by
In collaboration with
On behalf of King Mongkuts University of Technology North Bangkok, it is an honor and my great
pleasure to warmly welcome all guests and participants to the 26th National Thai Chemical Engineering
and Applied Chemistry Conference (TIChE2016) in conjunction with the 6th TIChE International
Conference (ITIChE2016) at Thailand Science Park Convention Center, Pathumthani, Thailand, from
October 26-28, 2016.
As we are moving into the next industrial revolution i.e. INDUSTRY 4.0, it is definitely a challenge to
the chemical engineering community to integrate into smart production systems with Internet of
Things-IoT. The conference theme this year, Innovative Technology toward Sustainable
Development, has been arranged to align well with the current situation beside the chemical
engineering fundamentals and principles. Furthermore, green and sustainability always have been the
focuses of the industrial development for last few decades, and so interestingly covered in
TIChE/ITIChE2016 as well.
Last but not least, I would like to express my appreciation to the Thai Institute of Chemical Engineering
and Applied Chemistry (TIChE) for believing in us to co-host this year conference, and to admire the
Department of Chemical Engineering, Faculty of Engineering, Chemical Process Engineering
Technology Division, Faculty of Engineering and Technology, Chemical and Process Engineering
Division, The Sirindhorn International Thai-German Graduate School of Engineering, for their great
efforts and really Make-It-Success. I have a strong believe that this year conference will contribute
significantly to the modern engineering and science communities as a whole
11.45 T-PM09-O161
12.00 Lunch break
ORAL PRESENTATION SESSION 3
28 October 2016 : TIME: 10.45-12.00
Room 403 TIChE:
(1) Biochemical Engineering & Food Technology
(2) Petroleum & Petrochemical Technology
Chairpersons: Kittiphoom Suppalakpanya
: Benjamaporn Wonganu
Time Code Presenter Title
13.00 T-SET01-O16
Saccharomyces cerevisiae SG
13.15 T-SET05-O75
13.30 T-SET16-O175 Seri Chitriprot
13.45 T-SET08-P88 Sakdipat Wiengket
Ni-Mo
Co-Mo
14.00
14.15
14.30
14.30
At the United Nations Climate Change Conference 2015 in Paris the members agreed
on reducing their carbon output "as soon as possible" and to do their best to keep
global warming "to well below 2 degrees C". The goal of global warming beneath 2C
can just be reached if between 2000 and 2050 the cumulative carbon emission is
limited to 1.000 Gt CO2. At the moment the annual CO2 emission amounts 36 Gt CO2.
With this capacity limit and production rate CO2 emission may be switched off in
2027.
To reach the goal of 2C earth warming the Paris agreement further comprises to exit
the use of fossil fuels [1]. The phase-out of fossil fuels entails that new technologies
must be developed, process intensification has to be applied in all fields of industrial
production and state of the art technologies have to be re-boarded with new
technologies. Main obstacle of the bio-refinery is the economic feasibility, which can
be addressed either by a fair valuation basis or/and by new technologies and
processes. Fair valuation basis is a political topic. Research has to address technical
topics. New technologies and processes have to suffice economic and ecological
aspects.
As early as in the late 19th century, research activities on usage of waste from the
pulp and paper industry are reported [2], [3]. In the 1920s and 1930s first industrial
size plants were built for the production of furfural and for the recovery of lignin;
lignin was then used as dispersing agent. US patent 2.050.400, dating back to the year
1930, claims a method for the recovery of heat and chemicals from waste products
from industrial processes such as alcohol [4]. In 1940 already P. von Walden [Zitat]
addressed a still fashionable topic: How long the national economy can tolerate to
classify lignin as wastage? In conclusion the pulp and paper industry has been the
focus and lead in industrial biorefinery for centuries. Referring to the Paris Agreement
several technologies and products, covering a span from low molecular weight
constituents such as ethanol, carboxylic acids or furfural to product blends like
turpentine and tall oil may seemingly just need reevaluation of the market potential,
arising the question, wether there is any need for future research activities?
Membrane separations is an established technology in processing effluents from
bioprocesses [5], targeting isolation of dissolved macromolecular constituents. New
technologies for intensified carboxylic acid isolation have become subject of intensive
investigation. Investigation of hydrogenation and hydrodeoxygenation of black liquor
is under way. Finally, reactive separations may offer new approaches in the isolation
and processing of biobased products to contribute innovative technologies toward
sustainable development.
[1] C. McGlade and P. Ekins, The geographical distribution of fossil fuels unused
when limiting global warming to 2 C, Nature, vol. 517, no. 7533, pp. 187190, 2015.
[2] B. Kamm, P. Gruber, and M. Kamm, BiorefineriesIndustrial Processes and
Products, Ullmans Encycl. Ind. Chem., vol. 5, pp. 659688, 2007.
[3] N. A. Engineering, The Ecology of Industry: Sectors and Linkages. Deanna
Richards, Greg Pearsonq, 1998.
[4] C. L. Wagner, Method for Recovery of heat and chemicals from waste
products, 2,050,400, 1930.
[5] L. Y. Jiang and J. M. Zhu, Separation technologies for current and future
biorefineries status and potential of membrane-based separation, vol. 2, no.
December, pp. 673690, 2013.
Carbon dioxide hydrogenation for
energy storage and chemical feedstock production
Professor Dr.-Ing Stefan Ernst
E-Mail : ernst@chemie.uni-kl.de
Kaiserslautern University of Technology
Carbon dioxide hydrogenation for energy storage and chemical feedstock production
Depending on the cheap availability of hydrogen, carbon dioxide can be selectively
hydrogenated to methane, methanol or liquid hydrocarbons as a means for energy
storage but also as a means for chemical feedstock production (e.g., methanol can
be further converted to short chain olefins (MTO or MTP process) or to aromatics
(MTA process).
This keynote would give a short overview over the different routes and will highlight
our own results on the selective hydrogen of carbon dioxide to methane over various
metals supported on mixed alumina-titania supports.
PLENARY SPEAKERS
Industry 4.0: Role of Thai University for Engineering Education
Assoc. Prof. Dr. Prasert Pavasant
- Acting Vice President for Administration, Vidyasirimedhi
Institute of Science and Technology
- Director Research and Researchers for Industries
Program
I-BEB01-O118
Abstract:
This research investigated effect of cross - linking agents, citric acid and tannic acid,
on the properties of hydroxyapatite/ chitosan/ collagen composites synthesized by
precipitation method. The experiments were done at different ratios of
hydroxyapatite / chitosan/ collagen composites. The result showed that with
increasing chitosan content in the composites, Vickers hardness value were
increased. Hydroxyapatite/ chitosan/collagen composite at the ratio of 70/15/15
was chosen to add cross - linking agents at 5, 10, and 20% by weight of the
composites. As a result, Vickers hardness values were increased with an increase in
the amount of citric acid but Vickers hardness values of tannic acid were not
increased clearly. However, it was found that the citric acid gave greater Vickers
hardness value than that of the tannic acid at 20% by weight of the composites.
I-BEB02-O67
Abstract:
This research investigated effect of cross - linking agents, citric acid and tannic acid,
on the properties of hydroxyapatite/ chitosan/ collagen composites synthesized by
precipitation method. The experiments were done at different ratios of
hydroxyapatite / chitosan/ collagen composites. The result showed that with
increasing chitosan content in the composites, Vickers hardness value were
increased. Hydroxyapatite/ chitosan/collagen composite at the ratio of 70/15/ 15
was chosen to add cross - linking agents at 5, 10, and 20% by weight of the
composites. As a result, Vickers hardness values were increased with an increase in
the amount of citric acid but Vickers hardness values of tannic acid were not
increased clearly. However, it was found that the citric acid gave greater Vickers
hardness value than that of the tannic acid at 20% by weight of the composites.
I-BFT01-O33
Abstract:
Cassava starch were liquefied by alphaamylase and saccharified by gluco-amylase
before fermentation for bioethanol production. Response surface methodology was
used to optimize the effects of percentage of starch, liquefaction temperature and
liquefaction time on sugar (dextrin, maltose and glucose) concentrations. Maximum
glucose content was 186.43 g/l when cassava starch (30%w/v) was liquefied by
alpha-amylase at 80C for 90min and saccharified by gluco-amylase at 60C for
60min. Saccharomyces cerevisiae TISTR 5606 (S. cerevisiae) and Zymomonas
mobilis TISTR 405 (Z. mobilis) were studied in batch mode to prove ethanol
efficiency and the performance of microorganism. The growth curve was determined
in bioreactor. The culture was inoculated at 30 1C and agitated at 70rpm with a
Rushton turbine in a 2 liter-working volume bafed tank. The culture medium was
made up of soluble cassava starch, diammonium phosphate, urea and magnesium
sulfate. The batch mode results showed that the log phase was approximately 16h.
The growth curves of Z. mobilis showed good agreement with the growth curve of
S. cerevisiae but the number of viable cells/mL was slightly lower. Maximum
ethanol concentration of 75.78g/l and ethanol yield of 37.89% (g/g dry starch) with
a fermentation efficiency of 74.30% were observed when using the mixed culture of
S. cerevisiae and Z. mobilis for 72h of fermentation.
I-BFT02-O41
Abstract:
Co-fermentation can simplify the process of ethanol production from cassava starch by
using microorganisms including fungi (Aspergillus niger, Rhizopus oligosporus, Trichoderma
reesei), yeast (Saccharomyces cerevisiae) and bacteria (Zymomonas mobilis). The cassava
starch solution was controlled pH to 5 by acetate buffer. Saccharification of cassava starch
(5%w/v) by fungi was firstly investigated amount of total reducing sugar concentration. The
result showed that single culture of R. oligosporus gave the highest yield of 0.37g TRS/g dry
starch. Next, ethanol production from cassava starch (30 %w/v) that was liquefied with
alpha-amylase and saccharified with glucoamylase was achieved highest yield of 0.08 g
ethanol/g dry starch by using co-culture of R. oligosporus and S. cerevisiae for 2days.
Additionally, cassava starch was liquefied with alpha-amylase and inoculated fungi for 7days
in order to investigate glucose content during this period. The results showed that amount
of glucose from single culture of A. niger, R. oligosporus and T. reesei was continuously
increasing in 7 days and the highest yield achieved by R. oligosporus at 7days was 0.24 g
glucose/g dry starch. Finally, cassava starch was liquefied with alpha-amylase, inoculated
fungi for 7 days and then inoculated S. cerevisiae or Z. mobilis for 2days. The result showed
that co-culture of R. oligosporus and S. cerevisiae can produce 50.9 g/l (corresponding to
the highest yield of 0.17 g ethanol/g dry starch).
I-BFT03-O46
Abstract:
This research was studied on ethanol fermentation from cassava starch. The effect
of enzymatic liquefaction and saccharification was studied by various enzyme
combinations and pH and measured total reducing sugar. The total enzyme content
of -amylase and glucoamylase were 0.5, 0.6, 0.7, 0.8 and 0.9 mg per g cassava
starch. pHs were controlled at 4.0, 5.0 and 6.0. The results showed that the
optimal the total enzyme content of -amylase and glucoamylase were 0.8 mg per
g cassava starch and pH was 5.0. Gelatinized starch (10%w/v) was liquefied by -
amylase and saccharified by glucoamylase before fermentation using single culture
of S.cerevisiae (TISTR 5606) and single culture of Z. mobilis (TISTR 405) and mixed
culture of these microorganisms. The result shows that batch fermentation of
cassava starch using single culture of S.cerevisiae gave the highest ethanol
concentration of 31 g/l and 61 % efficiency for 36 hours.
I-BFT04-O87
Abstract:
This research aimed to find suitable conditions and to compare the effect of
experimental parameters of quaternization reaction of chitosan and cyclodextrin
grafted with chitosan (CD-g-CS). CD-g-CS has potential applications in many fields.
However, the applications of the CD-g-CS is limited because of its poor water
solubility. Quaternized cyclodextrin grafted with chitosan (QCD-g-CS) was
synthesized for improving the solubility. The quaternized chitosan (QCS) and the
QCD-g-CS were prepared by reacting chitosan or the CD-g-CS with glycidyltrimethyl
ammonium chloride (GTMAC). The effects of mole ratio, reaction time, and reaction
temperature on degree of quaternization (DQ) were investigated. The results
indicated that the conditions that suitable for this reaction is at the mole ratio of 7,
the reaction time of 5 hrs, and the temperature of 50 C. For the synthesis of QCD-
g-CS, the trend of the DQ at various mole ratio similar the trend of the DQ of the
QCS.
I-BFT05-O106
Abstract:
The objectives of this work were to evaluate the moisture sorption isotherms model
for prediction equilibrium moisture content (EMC) and to investigate some
thermodynamics properties of chicken meat. To determine the EMC value for the
chicken meat, the experiments were carried out among surrounding temperature
ranging from 50-65C correlating to relative humidity of 10-90%. And the exact
moisture content values in each equilibrium state condition were curve fitted by six
commonly EMC models. The criteria for the best fitting model was the highest
coefficient of determination (R2) and the lowest mean relative error (RMSE) value.
The result showed that the simulated EMC values using the modified Oswin model
were the best fitting model with the exact values. Finally, the thermodynamic
properties in terms of enthalpy and entropy of heat sorption for chicken meat were
evaluated by following the Clausius-Clapeyron equation. The results were stated
that the enthalpy and entropy of heat sorption was negative exponential function
of moisture content.
I-BFT06-P108
Abstract:
Conversion of lignocellulosic biomass to sugars as raw materials for biorefinery
process is considered as a rate-limiting step. To improve the efficiency,
pretreatment is suggested to modify biomass to be more susceptible for hydrolysis
reaction. Here, we aimed to study the application of ionic liquid (IL), EMIM-Ac, for
pretreatment and its potential for recyclability. First, the optimum operational
condition for EMIM-Ac pretreatment was determined, based on Response Surface
Methodology (RSM), to be 71.83 min of duration time, 128.4oC of reaction
temperature, and 5% w/w loading mass ratio. To observe the potential of
recyclability of EMIM-Ac, different types of anti-solvents, including methanol, water,
and acetone were tested as anti-solvent to precipitate cellulose from the mixture.
After 5 cycles of IL recovery using methanol, more than 80% of sugars were still
obtained compared to the first round of pretreatment suggesting the high possibility
of recyclability of EMIM-Ac.
I-BFT07-O126
Abstract:
Beta glucan is widely distributed in cell wall of microorganism. The first part to
extract beta glucan is digestion of the cell and the last, purification part.
Conventional digestion method is autolysis, with long treatment time and high
energy consumption. The advanced techniques, subcritical water (SCW) and high
electric field pulse (HELP), was proposed in this paper. The results of this study
have indicated that SCW at 160 C with time of 60 min resulted in highest beta
glucan (222.46 mg/g of dry yeast cell) followed by HELP treatment (97.68 mg/g) and
was distinct higher than conventional autolysis method (46.33 mg/g).
I-BFT08-O133
Abstract:
Chitosan is a biopolymer with rich remarkable properties that are appropiate for
biomedical applications. Several previous studies showed that chitosan has been
used as adsorbent materials. In this work the adsorption of calcium by chitosan
together with the effects of chitosan particle sizes and degree of deacetylation
(%DD) were investigated. The adsorption isotherm parameters were evaluated with
Langmuir and Freundlich models in order to characterise the experimental isotherm.
The experimental experiments reveal that chitosan performed good adsorption
capability and correlated with the particle sizes and degree of deacetylation.
Smaller paticle sizes and higher degree of deacetylation result in the increase of
adsorption. Coefficient of determination or R squred (R2) shows that Freundlich
model fitted well with the experimental data.
I-BFT09-O143
Abstract:
High Electric Field Pulses (HELP) is a non-thermal cell disintegration method for
extraction of intracellular compounds. The aim of this study is to investigate the
effect of HELP process parameters on cell disintegration of plant cell materials. And
also evaluated the prediction model for sugar cane HELP treatment using Response
Surface Methodology (RSM). The rests of this study showed that at 9 kV/cm and 60
pulses up to 70% cell disintegration of sugar cane was observed. Similarly, cell
disintegration of coconut meat using HELP at 4 kV/cm, 60 pulses was achieved.
Comparison between heat and HELP cell disintegration clearly indicated that it is
possible to disintegrated plant cell with similar or higher disintegration degree at
very shorter time (about 1 min) compare to thermal method (15 min). In addition,
the energy consumption for HELP treated sample was distinct lower (3 kJ/kg)
compare to thermal treatment (200 kJ/kg).
Keywords: High Electric Field Pulses (HELP), cell disintegration, energy consumption, non-
thermal process, sugar cane, coconut meat
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-BFT10-P167
Abstract:
Polyhydroxybutyrate (PHB) is a biodegradable polymer synthesized and
accumulated in a variety of microorganisms where it is stored as carbon and energy
sources. The PHB production cost is more expensive than the petrochemical
polymer due to the cost of substrates. In this study, the different sources of
sugarcane molasses, the by-product of sugar industries, were used as a low cost
carbon source in order to reduce PHB production cost. The culture achieved the
maximum PHB production 21.36% PHB content after 24 h shaking at 150 rpm and
37C in a PYM medium containing 10 g/L molasses, 1.5 g/L yeast extract 2.5 g/L and
peptone. The extracted PHB was identified by 1H NMR, which showed properties
similar to those of standard PHB. This study indicated that using the molasses as an
inexpensive carbon source can be contributed to reduce the high PHB production
cost.
I-CRE01-P25
Abstract:
This work focused on synthesizing Ce/ La0. 25Sr0. 75Co0. 5Mn0. 5O3 ( Ce/ LSCM)
composites for application as a material in fuel cell typed reactor at high
temperature between 700-900C. The Ce/LSCM was investigated for their potential
use in an oxidative coupling of methane ( OCM) reaction. The Ce/ LSCM was
characterized using XRD and BET. The catalytic activity of catalysts for OCM reaction
was studied in fixed bed reactor. The experiments were performed using co-feeds of
methane, oxygen and nitrogen inert gas molar ratio of 4:1:3 at various temperatures
(700-900oC). The results show that the methane conversion increases with increasing
operating temperature, and that operating temperature significantly influences the
reaction selectivities. The optimum temperatures appear at 800oC, where the C2
hydrocarbon selectivity was 55.3% . Increasing the operating temperature from 700
to 850oC, the conversion of methane was rapidly increased, from 10.3% to 15.2%
with increasing C2 hydrocarbon selectivity.
I-CRE02-O31
Abstract:
Multi-metallic RuO2-CuO-NaCl-TeO2-MnOx/SiO2 catalysts were investigated for the
epoxidation of propylene to propylene oxide (PO) using O2 under atmospheric
pressure. The metallic weight ratio, the total metal loading on SiO2 support,
calcination time, and calcination temperature were optimized for PO formation rate.
RuO2 and CuO were determined to exhibit a critical bifunctional role for PO
synthesis. These active sites were assisted by MnOx and TeO2 to increase PO
formation rate and by NaCl to reduce CO2 formation. With using the Box-Behnken
design, a maximized PO formation rate of 1507 gPO h-1 kgcat-1 was obtained by varying
O2/propylene feed volume ratio, (O2+propylene)/Helium volume ratio, total feed
gas flow rate, and reaction temperature.
I-CRE03-P37
Abstract:
This research developed tungsten oxide to use as a photocatalyst under the visible
region. It aimed to improve WO3 by doping Fe at 1 mol % , doping Mo at 1 mol %
and co-doping Fe/Mo at 1:1% 1:2% 1:3% 2:1% 2:2% 3:1% by mol. The synthesized
WO3 by flame spray pyrolysis was compared with the modified WO3 at different Fe
and Mo doping levels. The main objective is to find out the appropriate doping
level of Fe and Mo on WO3 for photocatalytic degradation of methylene blue. From
the results, a synergistic effect appears after co-doping of Fe and Mo on WO3, leads
to significant improvement in photocatalytic activity. Among different prepared
compositions, the most superb WO3 that achieves the highest degradation of
methylene blue is 2:1% Fe/Mo co-doped WO3.
I-CRE04-P39
Abstract:
This research focused on titanium dioxide as a based photocatalyst and developed
its band gap energy into the visible range for the photo-activation. It aimed to
improve photocatalytic performance of TiO2 by varying doping level of Fe/Pt from
0.25% to 0.75% by weight. The synthesized and modified TiO2 were compared with
the commercial TiO2 to prove the effectiveness of flame spray pyrolysis. The
photocatalytic efficiency of different doped metal was compared to find out the
most suitable level of Fe and Pt. From the results, Fe doped TiO2 enhances the
photocatalytic activity by narrowing the band gap energy when compared with the
pure synthesized TiO2. Pt-doped TiO2 is beneficial to reduce the recombination of
photogenerated electrons and holes but it does not enhance the narrow of band
gap and surface area. The optimum composition is at 0.75%Fe/0.5%Pt doped TiO2
which has the highest photoactivity for furfural degradation.
I-CRE05-O40
Abstract:
In this research, the effect of prepartion conditions (chemical ratio and calcination
tempature) of precipitated CaO and MgO catalysts on their properties and
transesterification activities as percentage of methyl ester content (% FAME) was
investigated. The CaO catalysts were calcined at 700 or 800 C while those of MgO
catalysts were at 410 and 510 C. The catalysts were characterized using SEM, N2-
adsorption, Hammett-indicator and XRD and tested for their activities on biodiesel
production from palm olein and methanol using a reaction condition of 65oC, 2 h,
12:1 methanol-to-oil molar ratio, and 5 wt% catalyst amount. The best preparation
conditions for CaO catalyst were 1:3 Ca2+ :Na+ molar ratio and 700 C calcination
temperature while those of MgO were 1:1 Mg2+ :Na+ and 410C. At these conditions,
the highest values of % FAME of 98.14% and 42.98% could be obtained with the
CaO and MgO catalysts, respectively.
I-CRE06-O23
Abstract:
Solid acid catalysts have recently been recently studied in starch hydrolysis as solid
catalysts could be recycled, easy to separate and low cost, therefore they play an
important role in glucose production for biorefinery process. In this work, different
methods namely sulfonation and Cl- dipping were used to synthesize solid acid
catalyst when amorphous carbon was a support. Synthesized catalysts were then
used to hydrolyze cassava starch and cassava mash. Hydrothermal hydrolysis of
cassava starch and cassava mash gave high sugar yield that were 111.10% total
reducing sugar (TRS) and 42.18% glucose yields from CC-SO3H catalyst and 87.11%
TRS and 37.35% glucose yields from HA-L-SO3H catalyst at 140 C for 3h. Moreover,
byproducts such as levulinic and formic acids were produced at low concentration.
Keywords: cassava mash and cassava starch, carbonaceous solid acid catalyst,
liquefaction, saccharification
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-CRE07-O59
Abstract:
This research was to study photodegradation of Reactive red 120 (RR120) dye using
synthesized sphere-TiO2 under UV illumination. Comparison the performance
between the synthesized sphere-TiO2 and the commercial TiO2 was also mentioned.
The synthesized sphere-TiO2 were prepared by hydrolysis precipitation method. The
synthesized sphere-TiO2 and the commercial TiO2 were characterized by means of
X-ray diffraction (XRD) for determining the crystallize structure and N2
adsorption/desorption for evaluating the specific surface area. The morphology of
both TiO2 photocatalysts was analyzed by Field Emission Scanning Electron
Microscope (FESEM). The factors studied here were illumination time, types of
photocatalyst and its dosage. The XRD patterns revealed that the structure of both
catalysts was anatase phase. From N2 adsorption/desorption, it evaluated that the
synthesized sphere-TiO2 had higher specific surface area than the commercial TiO2
about 9.5-folders. The FESEM revealed that the shape of commercial TiO2 was non-
spherical with smooth surface but the synthesized one was not. The complete
photodegradation was achieved when using 0.10 g of photocatalyst under UV
illumination within the first 30 minutes for the synthesized sphere-TiO2 and within
120 minutes for the commercial TiO2.
I-CRE08-O91
Abstract:
The nano-bio hybrid materials with the features of both material types are the
potential alternative for improving the activity of photocatalysts. In this research,
the unique chlorophyll and Mg co-modified P25 was synthesized as a visible light
reactive photocatalyst by using a simple incipient wetness impregnation method.
The synthesized catalysts were tested for photocatalytic degradation of Rhodamine
B (RhB) under visible light and the effect of co-modified chlorophyll and magnesium
were investigated. It was found that the activities of catalysts were in the order of:
P25 < Mg/P25 < Chl/P25 < Chl-Mg/P25. The addition of chlorophyll and
chlorophyll-Mg in the catalyst could promote the photocatalytic efficiency for
approximately 1.9 and 2.3 times of P25, respectively. This remarkable photocatalytic
activity could be attributed to the enhancement in visible light adsorption, the
additional electrons from chlorophyll, and the synergistic effect between modifiers
and P25 catalyst.
I-CRE09-P103
Abstract:
A series of Mg and Al mixed oxides, derived from Mg and Al layered double
hydroxides (MgAl LDHs) were used as solid base catalysts for synthesis of , -
unsaturated branched carbonyl compounds via aldol condensation of furfural with
2-butanone. The MgAl LDH precursors with different Mg/Al atomic ratios were
prepared via co-precipitation and urea methods, and were then calcined at 500 C
to obtain the corresponding mixed oxides. The physicochemical properties of the
MgAl LDHs and mixed oxides were characterized by using various techniques. The
aldol condensation reaction was performed batch wise in a stainless-steel autoclave
at 80 C for 8 h, and the reaction products were analyzed for their composition
using a gas chromatography (GC). The MgAl mixed oxide with the Mg/Al ratio of 3,
prepared by co-precipitation, was the suitable catalyst, giving a high furfural
conversion and a high selectivity to the desired carbonyl compound product.
I-CRE10-P116
Abstract:
This research aims to develop nickel oxide for electrochemical-related applications. The
addition of surfactants as structure directing agent for nickel oxide synthesis is the subject
of investigation. In this work, nickel oxide was prepared by 2 methods: precipitation with the
addition of cationic gemini-surfactant (butanediyl-1,4-bis(dimethyl dodecyl ammonium
bromide)) mixed with anionic surfactant (sodium dodecyl sulfate,SDS) and modification of
preparation method by urea hydrolysis with hydrothermal treatment. The results showed
that by addition of surfactant Gemini:SDS = 0.04:8.2 molar provides greater porous
morphology and uniform particle size.
I-CRE11-O121
Abstract:
The pyrolysis reaction of poly( ethylene terephthalate) or PET bottle waste was
conducted comparatively in two cases: without catalyst and with MgO-ZSM-23
zeolite catalyst. The pyrolysis of PET was successfully decomposed to the product
of liquid/ wax, char, and gas ( major product). Applying MgO-ZSM-23 catalyst, the
product shows pronounced higher yield of gas (72.5 vs. 58.7 wt.%) and less yield of
char solid (8 vs. 17.6 wt.% ). The gas product shows less yield of CO2 (75 vs. 98
wt.% ) but gives higher hydrocarbon gas fractions of C1-C5 (25 vs. 2.1 wt.% ). In
liquid/ wax products, the catalytic pyrolysis shifted the product spectrum from
higher molecular weight, e. g. , biphenyl, terphenyl to benzene derivatives,
predominantly in benzoic acid.
I-CRE12-O125
Abstract:
Benzene oxidation and NO reduction with NH3 were performed on TiO2 (anatase)
catalyst. The catalyst was treated with sulfuric acid having concentration in the
range 0-1.0 M. Catalysts were characterized by using X-ray powder diffractometer
(XRD), Nitrogen Physisorption, pyridine adsorption and NH3temperature
programmed desorption (NH3-TPD). The results indicate that treatment with sulfuric
acid can improve NO reduction activity and conversion of benzene to CO 2 of TiO2
catalyst
I-CRE13-O131
Abstract:
This research aims to study the effect of sulfuric acid treatment on the catalytic
performance of V2O5-WO3/TiO2 for the simultaneous removal of NO, CO2 and
benzene. The catalysts are prepared wet impregnation method. Catalysts were
characterized by using ICP technique (ICP-OES Perkin Elmer Optima 7000DV), X-ray
powder diffractometer (XRD), single point BET surface area measurement, pyridine
adsorption and NH3temperature programmed desorption (NH3-TPD). The base V2O5-
WO3/TiO2 catalyst is the catalyst for the selective catalytic reduction (SCR) of
nitrogen oxide by NH3. The reaction is carried out in the reaction temperature range
120 - 450 C. It is found that V2O5-WO3/TiO2 treated with 0.2M H2SO4 has the highest
catalytic activity for benzene oxidation and nitrogen oxide reduction.
I-CRE14-O137
Abstract:
The effect of silica content on flame spray-made silica-modified titania supported
cobalt catalysts for Fischer-Tropsch synthesis (FTS) was investigated. The catalysts
were prepared by two steps as the supports were first prepared by flame spray
pyrolysis (FSP) and then 10 wt.% of Co were loaded on FSP-made silica-titania
supports using incipient wetness impregnation method. The catalysts were
characterized by X-ray diffraction (XRD), N2 physisorption, H2-chemisorption and
temperature programmed reduction in H2 (H2-TPR). The results presented the
promotional effect of silica on physical properties and metal-support interaction,
resulting in higher reducibility and Co active sites. The catalytic test in FTS showed
that selectivity toward C5+ products was significantly improved by reducing
formation of methane over silica-titania supported cobalt catalysts. The highest
selectivity to C5+ products was obtained at 50 wt.% silica loading.
I-CRE15-P138
Abstract:
In this study, the photocatalytic activity for degradation of methylene blue (MB) dye has
been investigated using suspension of different TiO2 nanoparticles including Degussa P25
TiO2, nitrogen-doped P25, flame spray pyrolysis (FSP)-derived TiO2 and 1 mol% Si- and 1
mol% Fe-modified FSP-TiO2 under UV and visible light sources. Compared to P25 TiO2, all
the FSP-synthesized TiO2 and modified TiO2 exhibited lower band gap energy similar to the
N-doped P25. However, under UV light irradiation P25 showed the highest photocatalytic
activity while the FSP-1 mol%Si-TiO2 and N-doped P25 exhibited comparable activity for MB
decomposition under visible light. It is suggested that not only the lower band gap energy
but also the increase of BET surface area of the modified catalysts was important for
improving the catalyst activity especially under visible light irradiation.
I-CRE16-O140
Abstract:
The A- and Z-type microchannel reactors for Steam Methane Reforming coupled
with Methane Combustion were designed and evaluated for its performance by
computational and modeling approaches. The kinetics of SMR and MC were
adopted from literatures [1, 2]. In the models, Ni/MgAl2O3 catalyst layers were
applied on the bottom of each channel. The influence of inlet/outlet patterns i.e.
effective entrance/exit lengths and orientation angles on flow and temperature
distributions and methane conversions were investigated. The maximum methane
conversion achieved by the A- and Z-type microchannel reactors were 87.6% and
72.9%, respectively.
I-CRE17-O48
Abstract:
Major challenge of using metal based microcrochannel reactor is catalyst active phase
deposition onto the metal surface. Washcoating method is one of the effective procedure
for depositing supported catalyst onto the substrate surface. In order to control quality of
the catalytic washcoated layer, stability of catalyst slurry, amount of catalyst solution and
number of coatings were focused. The catalyst slurry used in this work contained 20wt% of
10%Ru/Al2O3, 5wt% of polyvinyl alcohol, 1% of acetic acid and water. The suitable pH of
catalyst solution was in a range of 2 4. For the single layer coating, the good adherance of
catalytic layer was observed. The highest %weight loss was 0.007% at pH value of 8. From
the effect of catalyst slurry volume, 0.1 ml and 0.2 ml gave relatively low catlyst loading
difference of before and after adhesion test. The average thickness of 0.2 ml single layer
washcoating was 121.73m. For multilayer washcoating, the results clearly showed that the
obtained washcoated layer can be used to apply onto the metallic substrate not only
single layer but also multilayer. The double layer washcoating gave the highest catalyst
loading per unit area for every volume of catalyst slurry. The 0.2 ml gave relatively good
adherence and uniform washcoating layer in multilayer coating process.
I-CRE18-O171
Abstract:
The objective of this work is to study the performance of 30%Co/MgO (30CMC) and 30%Co-
1%Mn/MgO (30CMMC) catalyst-coated plates. The catalyst samples were prepared by sol-
gel method and deposited onto a stainless steel plate (coating area of 6.9 mm x 60.0 mm)
by spray coating. The Fisher-Tropsch Synthesis were demonstrated on catalyst-coated
plates in a multichannel reactor. The effects of syngas flow rate (similar CO to H2 ratio),
coating thickness and Mn promoter on FTS performance were carried out. Operating with
low feed flow rate enhance the stable of activity as well as C5+ selectivity. Increasing the
thickness of catalyst layer results into the improvement of selectivity toward long chain
hydrocarbons with the decline in FTS activity due to the porosity of catalytic layer. The
electronic effect of Mn promoter developes CO chemisorption which diminishes the CH4
formation. The addition of Mn reinforce a selective toward gasoline production.
I-ESH01-O34
Abstract:
This work focused on the preparation of activated carbon from wood dust by physical activation with CO2. The
preparation process consisted of carbonization of sample under the flow of N2 at 400oC and 1 hr followed by
activating the derived chars with CO2 at 800oC for 1 hr. The porous properties of the resultant activated carbon
was characterized based on the analysis of N2 adsorption isotherms at -196oC. The results showed that the
activated carbon was dominated with micropore structure (77%) with the surface area of 357 m2/g and average
pore width of 2.1 nm. The prepared activated carbon was then used as adsorbent for color removal of
biological treated wastewater. It was found that the percentage of color removal increased with the increasing
of amount of adsorbent. The adsorption reaches equilibrium at 12 and 4 hr for the using of activated carbons of
1 and 1.5 g with the maximum percentage of 90% and 93%, respectively. This was higher than the target value
of the company at 58%. The removal of color by using commercial activated carbon reach equilibrium at 24
and 16 hr for the using of carbons 1 and 1.5 g with the percentage of 75% and 100%, respectively. The
percentage removal of color for prepared activated carbon is higher than commercial activated carbon at all
adsorption times for using sample of 1 g. However, for the case of using sample of 1.5 g, the percentage color
removal for prepared carbon is higher than commercial activated carbon for the adsorption time less than 14 hr
after that the results showed reverse trend. Therefore, the prepared activated carbon had higher efficiency for
color removal of wastewater than commercial activated carbon in the meaning of shorter equilibrium time and
%removal. This mean that wood dust, that is the waste, can be the potential raw material for produced
activated carbon for using as adsorbent to remove color from wastewater.
I-ESH02-O47
Abstract:
Formaldehyde is the most active aldehyde with a disinfection ability, killing bacteria
and stopping bacteria from growing. It has been banned internationally from food
and food-related products due to high toxicity that lead to dizziness, vomiting and,
in extreme cases, death. In this work, the sensor was fabricated relying on catalytic
activity of nickel nanoparticles immobilized on graphene support (Ni-graphene
composite), and was operated in an amperometric mode of an electrochemistry
work station. Our best sensor showed good responses to 1-60 ppm of formaldehyde
in pH 13 alkali solution with a sensitivity of ~0.09 ppm-1 with good rate of
reproducibility. No significant interferences were observed from testing the sensor
against benzoic acid (preservative), sodium hydrosulfite (bleach) and sodium tetra
borate (food additive) at tested concentrations.
I-ESH03-P86
Abstract:
The adsorption of methylene blue dye from water onto longkong waste peel has
been investigated under various experiment conditions. Batch experiments were
conducted to determine the effect of pH, initial dye concentration, contact time,
adsorbent dose and temperature. The equilibrium time was found to be 205
minutes at the optimum pH of 7. The capacity of adsorption was improved with
increasing of initial dye concentration and temperature. In contrast, as the mass of
adsorbent increased, a decrease in the adsorption capacity was obtained. For
isotherm study, the adsorption data of longkong peel was best fitted to Freundlich
model. The kinetics of adsorption followed the pseudo second order model.
Thermodynamic parameters such as, enthalpy, entropy and free energy changes
were evaluated. The adsorption process was exothermic and spontaneous.
I-ESH04-P114
Abstract:
In this research, the removal of methylene blue dye (MB) from aqueous solution with
sugarcane leaves as an adsorbent was investigated using a batch adsorption experiment.
The experiments have been devided into two parts. The objective of the first part is to find
out the effect of pretreatment with chemicals (NaOH and KOH) and enzymes (pectinase
and cellulase) on the adsorption capacity of the sugarcane leaves. It was found that the
sugarcane leaves pretreated firstly with NaOH and then sequenthly pretreated with
cellulase (SL-NaOH/Cellulase) showed the maximum adsorption capacity. In the second
part, the adsorption bahaviors of SL-NaOH/cellulase was determined and compared to the
unpretreated sugarcane leaves (SL-untreated). The results showed that SL-NaOH/cellulase
had a greater percentage of dye removal than SL-untreated. However, both of the samples
reached equilibrium in 5 hours. For the study on adsorption isotherm, it was found that
Langmuir isotherm model was the best data fitting for both SC-NaOH/Cellulase and SL-
untreated with maximum sorption capacity of 1.387 and 2.985 mg/g respectively. For the
study of the kinetic model, it was found that the experimental data were fitted very well
with the pseudo-second-order. The thermodynamic study revealed that both adsorbents
showed negative values of enthalpy (H), and negative values of Gibbs free energy (G)
changes indicating an exothermic and spontaneous biosorption.
I-IA01-P97
Abstract:
In the present study, we developed a new sol-gel approach to synthesize amine-
functionalized hexagonal mesoporous silica (HMS-NH2) in the presence of
dodecylamine as a neutral templating agent. The functionalization was performed
via direct co-condensation method using 3-aminopropyltri-methoxysilane (APS) as
an amino-functional group precursor. The APS loading amount was varied in a range
of 015 mol%. The resultant materials were characterized for their physicochemical
properties using various techniques. The HMS-NH2 materials obtained not only had
highly ordered hexagonal structure, but also very high concentration of amino-
propyl group (0.16 mmol g-1).
I-PM01-O27
Abstract:
The nano titanium dioxide impregnated alginate (TiO2-ALG) beads has been
prepared and used for the removal of methyl orange (MO). Nano-TiO2 was
entrapped in Ca-alginate matrix bead under the effects of nano-TiO2 and
glutaraldehyde crosslinker contents. The TiO2/ALG beads were then characterized
by BET, SEM, TG and texture analysis. Moreover, the MO removal efficiency of TiO2-
ALG beads via adsorption-photocatalytic degradation process under UVC radiation
was investigated. The results showed that nano-TiO2 content, irradiation time and
pH affect the adsorption-photocatalytic degradation efficiency of the TiO2-ALG
beads. The maximum %MO removal was found for 30%wt TiO2-ALG beads at pH =
3 and 180 minutes irradiation time. The TiO2-ALG beads can be reused in which the
MO removal efficiency decreased about 54% after reuse for seven times.
I-PM02-O28
Abstract:
This research aims to develop biosorbent materials from agricultural wastes, i.e.
coffee ground (CG), sawdust (SD) and sugarcane bagasse (SB). These wastes were
modified by graft copolymerization with acrylonitrile monomer and used as Cr(VI)
adsorbents. After copolymerization, the acrylonitrile/cellulose copolymers were
characterized by FTIR and SEM. The FTIR results indicated the cyano group in all
absorbent structures after grafted successfully. Furthermore, the effects of contact
time, pH and amount of absorbent to Cr(VI) removal potential of copolymers were
investigated.
I-PM03-O29
Abstract:
Formation of oxides on AISI 1045 and AISI 304 at 673 K for 168 hours and 720 hours
in air was studied. The oxide formed on AISI 1045 surface was magnetite with
different sizes of oxide particles because of the different exposure times.
Thicknesses of the oxide film formed on AISI 1045 for 168 hours and 720 hours were
found to be 2.98 m and 4.33 m, respectively. The oxide formed on AISI 304
surface was not observed for 168 hours but it was found as iron oxide and
chromium oxide for 720 hours. The thickness of the oxide film formed on AISI 304
was not determined from the weight gain measurement due to the irregular
characteristic of oxide formed.
I-PM04-O30
Abstract:
The objective of this study was to synthesis nanosilica from sugarcane bagasse ash
(SBA). Sugarcane bagasse ash was burnt at 800 C for 4 h. Silica content which
obtained after heat treatment at 800 C for 4 h was 76.8% . SBA was purified by
alkaline extraction method with 4 M NaOH. Percent yield of silica extracted by 4 M
NaOH was 35.25. Subsequently, the purified silica from SBA was used to production
of nanosilica by precipitation method. The precipitation was done by refluxing silica
from SBA in boiling 2.5 M NaOH by continuous stirring for 3 h. Then, nanosilica was
precipitated by added 2. 5 M H2SO4 with flow rate of 1, 2, and 3 ml/ min,
respectively. TEM results showed that the addition of 2.5 M H2SO4 with flow rate of
2 ml/min provided agglomerate particles with dimension of 5-20 nm. The specific
surface area was found to be 544.3 m2/g.
I-PM05-P44
Abstract:
Fire-retardant paper was prepared by mixing of montmorillonite (MTM),
carboxymethyl cellulose (CMC) and cellulose fibres (CF) isolated from oil palm
trunk biomass by alkaline treatment. The mixtures of dispersed CMC, MTM and CF
with various ratios were stirred for 24 h, then casted and dried to form paper. The
samples were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray
diffractometer (XRD), scanning electron microscope (SEM) and thermogravimetric
analyzer (TGA). Their mechanical and fire retardance properties were also evaluated.
The CMC50:MTM50:CF12 paper showed the best of flame-retardant testing with
maximum tensile testing at 24.7 MPa and Youngs Modulus at 13.7 MPa.
I-PM06-O49
Abstract:
The aim of this paper was to investigate the influences of adding milled glass fiber
on the mechanical properties and shrinkage behavior of polypropylene (PP) as a
feedstock material for fused deposition modeling (FDM) technique. Due to
semicrystalline structure of PP, it negatively affects the dimensional stability. PP
with different milled glass fiber content (0, 10, 20 and 30 wt%) were studied in
order to decrease shrinkage. Dogbone-shaped specimens were fabricated by FDM
3D printer for tensile test and square boxes were printed for evaluating shrinkage
behavior. Furthermore, fracture surfaces of printed tensile samples were analyzed
via scanning electron microscopy (SEM) to support the tensile results. The findings
indicated that milled glass fiber enhanced the tensile modulus and elongation at
break, and reduced shrinkage behavior. Finally, PP may become an alternative
choice as a material for FDM technique.
I-PM07-O55
Abstract:
Graphene is a 2-dimensional nanostructure with outstanding electrical, chemical,
and mechanical properties. Its ability to react/interact with gas molecule and
become more or less electrical conductive created basic principal for graphene-
based gas sensor. In this research, chemically exfoliated graphene was synthesized,
and further composited with polyaniline (PANI) conductive polymer. The composite
was fabricated to a chemiresistive sensor and was demonstrated in detecting
selected volatile organic compounds (VOCs) - water, ethanol, and benzene. The
sensor sensitivity was determined as 0.2289, 0.0806 and 0.0295 ppm-1 for water,
ethanol and benzene, respectively. The sensing mechanism relies on PANI acting as
a VOCs capturing nodes, altering conductivity of graphene.
I-PM08-O71
2vanida.c@psu.ac.th
Abstract:
Hydrogel was prepared by free radical polymerization with grafting of 2-acrylamido-
2-methyl-1-propanesulfonic acid (AMPS) onto natural rubber (NR) backbone, using
potassium persulfate (KPS) initiator and N,N-methylenebisacrylamide (MBA) cross-
linker. The polymerization reaction was carried out at 40-60C for 20 minutes. The
swelling capacity of hydrogel was investigated with regard to the effects of
monomer concentration, cross-linker concentration, and initiator concentration. The
chemical structures in the hydrogel were confirmed by FTIR spectroscopy The
results showed that the swelling capacity increased with the quantities of AMPS,
MBA, and KPS, and with reaction temperature.
I-PM09-O115
Abstract:
Coating is one of versatile methods that can protect metal surface from corrosive
environment. Various types of anti-corrosion coating have been studied. Composite
coating that contains dispersed particles has shown promising protection efficiency
for metal such as carbon steel and stainless steel. In this work, we report the
preparation of anti-corrosion coating for 316L stainless steel using titania-
mesoporous silica nanocomposites (MSN@TiO2) as an anti-corrosion filler. Corrosion
resistance behavior of coated steels in 3.5 wt.% NaCl solution (pH 3-11) were
measured using a potentiodynamic technique. It was found that at all pHs, stainless
steel coated with MSN@TiO2/epoxy-silane provide the lowest pitting current density
comparing to bare stainless steel and stainless steel coated with pure epoxy-silane.
.
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-PM10-O119
Abstract:
Effects of polyol molecular weights (1000, 2000, and 3000 daltons or PU1K, PU2K
and PU3K) on thermally reversible light scattering (TRLS) behaviors of BA-a: PU
polymer alloys are investigated. The experimental results revealed that TRLS of BA-
a:PU alloys tends to occur at a wider range of alloy compositions with an increase
of the polyol molecular weights. That is the TRLS phenomenon of BA-a:PU1K was
observed at 10 to 20wt% of PU1K while BA-a:PU3K was found at 20 to 50 wt% of
the PU. The fully opaque state was observed at room temperature whereas the
transparent state was achieved when the specimen was heated above 170C.
Moreover, the results reveals that Tg values of all BA:PU alloys increase with
increasing PU fraction from 0 to 50 percent by weight in the alloy networks. The
TRLS materials based on BA-a:PU alloys find potential use in thermal sensor or
shutter etc.
I-PM11-O129
Abstract:
Phase separation behaviors of polymer blends between 3,3,4,4-
biphenyltetracarboxylic dianhydride/4,4-diaminodiphenyl ether (s-BPDA/ODA)
polyimide (PI) and polysulfone (PSF) have been investigated. All blend films with
400-micron thickness were prepared by a solution casting method. The effects of
PSF mass fraction (varied from 0 to 100 wt%) on thermal and mechanical properties
of the blends were eamined by a dynamic mechanical analyzer (DMA) and a
universal testing machine (UTM). From the results, the tensile modulus of the
blends was observed to increase with increasing PSF contents in a linear manner.
Furthermore, glass transition temperature of PI/PSF blends indicated that the blends
were partially miscible in nature due to the appearance of two Tgs that shift
towards each other. The optical micrographs reveal the phase separation of the
blends being dependent on the blend compositions.
I-PM12-P139
Thailand
napida.h@chula.ac.th
Abstract:
Dye-sensitized solar cell (DSSC) is consisted of transparent electrode,
semiconductors, coordination compounds, inorganic salts and metallic catalysts.
However, transparent electrodes made from the conductive glass have some
inherent problems such as brittleness, heavy weight, and high cost. To solve these
drawbacks of glass electrode, polymer was expected to substitue. Poly(methyl
methacrylate) (PMMA) was selected to replace the conductive glass since it has
excellent optical transparency, low cost and light weight. Thus, this work aimed to
develop a conductive PMMA sheet used as a counter electrode by deposition of
poly(3,4-ethylenedioxythiophene) (PEDOT) (electrical conductivity = 36 S.cm-1) via
spin coating technique to increase electrical conductivity of PMMA surface. The
modified PMMA sheet was assembled with other components to form the DSSC.
The efficiency to convert solar light as electricity was also reported.
I-PM13-P141
Thailand,
napida.h@chula.ac.th
Abstract:
Graft copolymerization of poly(butyl acrylate (BA)-co-2,2,2-trifluoroethyl
methacrylate (3FMA)) onto natural rubber (NR) was prepared in the latex stage
initiated by potassium persulfate (K2SO4). The effects of BA/3FMA wt ratio, initiator
concentration and reaction temperature on the monomer conversion, grafting
properties detected by soxhlet extraction and water contact angle were
investigated. From the initial study, it was observed that the maximum content of
graft NR (GNR) at 70.7 wt% was achieved when the graft copolymerization was
performed by using 1.5 phr K2SO4 at 60 C for 8 h. At this condition, the chemical
structure of graft product was characterized by using attenuated total reflectance
Fourier transform infrared spectroscopy (ATR-FTIR). The decomposition temperature
was evaluated by using thermogravimetric analysis (TGA). The morphology of graft
product was also observed by using transmission electron microscope (TEM).
Moreover, it was found that the contact angle of the graft product film was 101,
which was higher than that of NR film as 1.25 times.
I-PM14-O162
Abstract:
Graphene was synthesized through chemical cleavage followed by reduction process and
through liquid-phase exfoliation methods. The characteristics of synthesized graphene were
investigated by Raman spectroscopy, FTIR, SEM, XRD and UV-Visible spectrophotometry. It
was found that graphene oxide (GO) synthesized by modified Hummers had carboxylic acid,
hydroxyl, and ether groups confirming that graphite was successfully oxidized. The result
also showed that graphene oxide consisted of 12 layers and the layer distance was in the
range of 0.67-0.72 nm. In liquid-phase exfoliation method, graphene sheets were
synthesized by mixing graphite with naphthalene and N-methyl-2-pyrrolidone (NMP)
followed by sonication. The results indicated that the inter layer spacing of graphite was
expanded from 0.3356 to 0.3364 nm or 0.23%. The highest graphene concentration was up
to 3.26 mg/ml and the yield was 54.34% at 120 minute of sonication time. Therefore, the
sonication time was directly proportional to graphene concentration in NMP.
I-PM15-O172
Abstract:
Nanofibers of polylactide (PLA)/poly(vinylpyrrolidone) (PVP) blends loaded with TiO2
particles have been prepared by an electrospinning technique. TiO2 particles are
formed by sol-gel mechanisms from titanium (IV) isopropoxide (TTIP) precursor.
Effect of TiO2 formation rate on properties of the fibers are examined by adding
isopropyl alcohol (IPPA) to slow down the TiO2 precipitation process. The use of
IPPA produces fiber mats consisting of slightly bigger and smoother filaments, but
smaller-sized embedded TiO2 particles. Both materials show a distinct UV absorption
characteristic of TiO2 at max 300 nm, which can be applied in many catalytic
applications. Degradation behaviors of the materials in phosphate buffer solutions
have also been investigated.
I-PM16-O173
Abstract:
This research was to study the mechanical properties of the rubber compound
mixed with modified silica via admicellar polymerization. The formula compounds
of rubber inner tube were selected for mixing with silica as a reinforcement. The
properties of the rubber compounds were compared with commercial inner tube
using carbon black as a reinforcement. The results showed that the mechanical
properties of the rubber compounds using modified silica were better than those of
all rubber compounds using unmodified silica and carbon black, especially flexibility
that was much higher than that of carbon black reinforcement rubber.
I-PSC01-O53
Abstract:
This article aims to estimate properties of the Poly-Lactic Acid (PLA) synthesized by
direct condensation polymerization process in laboratory scale using artificial neural
network (ANN). Firstly, samples of PLA were synthesized at various conditions
(reactant amount, pressure, temperature and reaction time). The samples were
further analysed for thermal property: melting temperature (Tm). Then a neural
network for properties estimation (Tm) was developed using of those analysed data.
The obtained neural network was tested and validated by comparing with another
set of analysed data. The simulation results showed that the neural network model
could predict the properties of samples in accuracy over 80% .
I-PSC02-O65
Abstract:
This research investigated the influences of cooling water flowrate and surface
tension on a foam formation at the sealed well of thermal power plant. The
volume fraction of the entrained air, which was related as the main cause of foam
formation on the water surface around the sealed well, was simulated using the
Computational fluid dynamics (CFD) with the commercial code ANSYS Fluent. The
volume of fluid ( VOF) and the k-epsilon models were employed to analyze the
volume fractions of air in water and the turbulence flow, respectively. The results
from the CFD showed that when the water flowrates were increased from 15,000 to
28,000 m3/ h, the average air volume fractions would be increased from 0.057 to
0.074. In contrast, the surface tension showed no effect on the foam formation in
this study.
Keywords: cooling water flowrate, cooling water surface tension, foam formation,
Sealed well, CFD
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-PSC03-O84
Abstract:
Polymerization reaction has been considered as a highly nonlinear process due to
the presence of the parameteric uncertainties, resulting in high level of difficulty in
control. The human experience based method, namely fuzzy logic control, is an
alternative approach in which the process is controlled, according to the rules
implemented by the experienced operators. In this paper, the developed robust
fuzzy controller was applied to guarantee the stability of the polypropylene
polymerization process in the presence of the uncertainties in kinetic constants for
propagation rate and heat of reaction. The results showed that the mass of polymer
and the reactor temperature can be regulated to setpoints despite uncertainties.
I-PSC04-O113
Abstract:
Computation fluid dynamic (CFD) modeling has been applied in this study to modify
downdraft gasifier in order to improve the efficiency for energy generation. The
gasifier was simulated as porous bed. The RNG k- model was used to solve the
turbulent gas flow. The mass transfer was solved using Eddy Dissipation Concept
approach. The energy equation was used to solve the temperature distribution in
the reactor. The results of this research will be used to develop the design and
operation guidelines of biomass downdraft gasifiers for community empowerment.
I-PSC05-O117
Abstract:
In a cassava starch production process, the improvement in the design and
operation of a hydrocyclone network was focused on to reduce starch loss and also
to reduce starch impurities such as sulfur and fine pulp in the product. A simulation
model was firstly created and then tuned with actual plant data by adjusting a set
of empirical parameters in a hydrocyclone model. Several modification approaches
were then investigated. A substantial amount of starch loss saving worth 21.43
million Baht/year could be obtained by combining all considered approaches.
Finally, to decrease the starch impurities, an additional hydrocyclone stage was
applied in addition to the modification approaches. The pulp content in the starch
slurry could be reduced from 586 to 223 ppm by weight. The benefit in terms of
starch recovery was 21.53 million Baht/year in the last modification scheme.
I-PSC07-O144
Abstract:
This project aims to develop alternative energy generation for producing renewable sources and is
suitable for agricultural sector in Thailand. The framework focuses on electricity production (small-
scale applications of 10-15 kW) using syngas as fuel from biomass gasification process intakes an
internal combustion (IC) engine. Conceptually, the methodology uses ASPEN Plus simulator as tool
for analytical modeling and thermodynamic conditions to perform concept design studies of syngas
production and system configuration. In particular, the lack of the solid library modeling is
compensated by FORTRAN codes nested within the ASPEN Plus input file to calculate mass and
energy balances for predicting the syngas performances i.e., volumetric flowrate, syngas composition,
lower heating valve (LHV), syngas yield, power output and cold gas efficiency (CGE), respectively,
which all of them lead to optimize by adjusting better the model sensitivity over uncertainty
conditions.
I-PSC08-O42
Science and Technology Research Institute, King Mongkut's University of Technology North Bangkok,
Bangkok, Thailand
jermkwan.n@gmail.com
Abstract:
Design equations for a catalytic microchannel reactor for Fischer-Tropsch synthesis were
proposed and verified in this study. Design equations were created in term of dimensionless
group with assumption of a two-dimensional catalytic microchannel reactor to obtain an
optimal dimension of channel; height and length for a single straight flow channel with a
crossection of square or rectangular. Length of a flow channel can be divided into three
regions by particular controlled regimes consisting of kinetic, external diffusion and fluid
flow rate. The dimension of channel were optimized by the Intersection of Asymptotes
Method responding to maximum reaction rate. After that, dimension of channels from
design equation were simulated by Computational Fluid Dynamics method via COMSOL
Multiphysics 3.5a to compare reaction rate between the two methods. The difference of
results from design equations compared with simulation were about 25-50%.
I-PSC09-O57
Technology Research Institute, King Mongkut's University of Technology North Bangkok, Thailand
chaiwat.r@eng.kmutnb.ac.th
Abstract:
This paper proposes optimization method in order to find the optimal operating parameters
on reactive distillation column (RD column) via esterification of acetic acid with methanol
to produce methyl acetate using Aspen Batch Distillation. The set-up reactive distillation
model was adopted from an in-house made RD column, which comprised of seven stages
including reboiler and condenser, five possible feed stages, where solid catalyst for the
reaction was contained. In this work, effect of temperature of heater at reboiler, feed stage
and reflux rate on yield of methyl acetate and purity of total distillated product were
studied. Case studies were designed by design of experiment and consequently simulation
results was optimized by using Response Surface Methodology (RSM) to determine optimal
condition. The result indicated that the optimum temperature of heater at reboiler, feed
stage and reflux rate were 141.87 C, Stage4 and 332.48 moleshour-1, respectively, giving
maximum yield and purity of methyl acetate at 57.50 mole% and 80.46 wt.%, respectively
I-PSC10-O72
wanthana.chw@gmail.com
Abstract:
Heat removal is a crutial issue for Fischer Tropsch synthesis operation owing to its
highly exothermic characteristic. In this work the concept of microchannel and heat
exchanger integration into a single module was studied. The microreactor/heat
exchanger simulation model composed of 3 reaction channels and 3 cooling
channels. The effect of cooling stream direction on FT reaction performance was
focused. The simulation results showed that co current direction presented higher
temperature difference, especially for inlet position although conversion of reactant
were relatively closed compare to counter current case. The CO conversion of co
current and counter current were relatively closed of 10.71% and 10.65%
respectively.
I-PSC11-O154
Abstract:
Gas-solid phase polymerization of propylene in a fluidized bed reactor is
commercially used for polypropylene production. Polypropylene physical properties
are certainly controlled by polymer molecular weight and polydispersity index (PDI)
which depend on kinetic rate of polymerization. Due to many complex reactions
such as site activation, initiation, propagation, chain transfers, site transformation,
and deactivation, a method of moment is used in order to predict molecular weight
of polypropylene. This work presents a well-mixed flow model as a simplified
representation of a fluidized bed reactor with hydrodynamic correlation and
method of moment. This model is capable of predicting polymer production rate,
reactor temperature, particle size, molecular weight and PDI. In addition, the
hydrogen concentration effect on polymer molecular weight can be predicted. This
model also predicts volume fraction of solid phase and particle diameter change as
a function of time. This model is useful for both interpretation of laboratory data
and for scale-up of industrial scale reactor.
I-PSC12-O160
Abstract:
The discrete elemement method for solid phase coupled with Eulerain model for
gas phase is applied in the silicon production by silane chemical vapor deposition in
a spouted bed to investigate local phase movements, and mass and heat transfer
in the system. The simulation provides the distribution of phase, temperature,
concentration in the bed. In addition, the particle size distribution due to surface
deposition on the silicon seed particle and scavenging of the fines formed in the gas
phase. Futhermore, the particle size distribution shows a broad distribution due to
non uniform deposition reaction on the solid particles.
I-PSC13-O165
rungrote.k@eng.kmutnb.ac.th
Abstract:
The Henrys Law constant is the required parameter for gas-liquid reactions to
determine the reaction rate constants. It is very difficult to practically estimate the
Henrys Law constant using experiment of the systems containing ozone and
unsaturated fatty acids. In this study, the simulation technique using Aspen Plus and
Polymath software was presented to evaluate the Henrys Law constant of such
systems. The results showed that the Henrys Law constants obtained from the
simulation is slightly different from the experiment for binary and multi-fluid system.
The simulation method is, therefore, an alternative technique for determination of
the Henrys Law constant.
I-PSC14-O168
Abstract:
Velocity and temperature profiles of cryogenic air in an individual quick freezer (IQF)
for industrial food processing were simulated using Computational Fluid Dynamic
(CFD) modeling. In addition, the motion of fragments broken off from the products
was investigated. The results were used to guide the modification of the IQF so as
to mitigate the cleaning problem due to the fragments, blown and trapped in
different locations. RNG k- model, radiative energy equation, and discrete phase
model were used to predict the velocity, temperature, and product fragment
trajectories respectively. Good agreement with the experimental results was found.
Keywords: Individual Quick Freezer, Turbulent multiphase flow, Frozen food processing,
CFD modeling
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-PSC15-O51
ekaroek.ph@skru.ac.th
Abstract:
The aim of this research is to simulate the silica-natural rubber latex mixing in a
stirred tank by using computational fluid dynamics. The computational fluid
dynamics (CFD) were applied in the micro-silica dispersion and natural rubber mixing
using the stirred tank. The volume fraction of silica phase in NR latex phase at
various mixing times were predicted and compared with the experimental results.
The result was shown that, the silica will be dispersed well after the mixing time
was more than 40 seconds. The mixing time prediction from CFD was compared
with the experiment and a good agreement was found.
I-SET01-O19
3Sun Genesis Industry, Teparak road Km24, Bangsaothong, Samutprakarn, 10540, Thailand
suphang.chu@mahidol.ac.th
Abstract:
This research was aimed to manage and utilize 3 contaminated macro algae from shrimp
farming, Caulerpa lentillifera, Caulerpa racemosa, and Acanthophora spicifera as an
alternative oil feedstock for biodiesel production. Oil extraction was performed and
biodiesel production was conducted in further to get the maximum yield. The optimization
of condition, such as the molar ratio of oil to methanol, effect of reaction time, reaction
temperature, and percentage of catalyst were carried out. The results were discovered that
the average amount of oil from these macro algae were approximately 3.3% from dried
basis. The optimum condition for biodiesel production with these 3 macro algae was nearly
the same. The reaction was complete within 8 hours and the achievement of biodiesel
yield was 55.58% from Caulerpa lentillifera with the suitable condition of oil to methanol
molar ratio 1:15 using 1 % of KOH at 60 oC. Caulerpa racemosa sp. can be produced 58.36%
of biodiesel from the condition of oil to methanol ratio 1:15 with 1.5 % of KOH at 60 oC. As
well, the optimum condition for biodiesel production from Acanthophora spicifera was
using 1:12 of oil to methanol ratio with 1 % of KOH and obtained 49.29% of biodiesel.
Keywords: biodiesel, greenhouse gas, oil feedstock, macro algae, shrimp farming
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-SET02-O18
suphang.chu@mahidol.ac.th
Abstract:
The aim of this research was to find the suitable conditions for bio-ethanol
production from Ceratophyllum demersum L., an abundant aquatic plant. The
parameters affected to alcohol production were evaluated. Percentage of solid, the
amount of yeast, pH value and temperature were carried on. The results
elucidated that the condition to produce the maximum bio-ethanol from
Ceratophyllum demersum L. were applied with 10% (w/v) of solid, 10% (w/v) of
yeast, controlled pH= 6 at 30 degree Celsius. The highest rate of bio-ethanol
production was reached 2.92 g ethanol/L within 24 hrs. By the way, the Carbon
Footprint for ethanol production was able to calculate only from 2 boundary steps
of life cycle analysis which were the boundary step of raw material acquisition and
of manufacturing process. Consequently, the carbon footprint for ethanol
production from Ceratophyllum demersum L. was 77.8780 kg CO2 equivalent.
I-SET03-O21
2National Metal and Materials Technology Center (MTEC), National Science and Technology
Development Agency
3PTT Research & Technology Institute, PTT Public Company Limited
pattaraporn.kim@mahidol.ac.th
Abstract:
The CuO/ZnO catalysts are synthesized using co-precipitation method with varied
precipitation temperature (25-80C), pH value (5-10) and technique (conventional
precipitation and ultrasonic assisted precipitation), which affect the catalyst
properties and activity. Crystallite size, specific surface area and surface acidity are
investigated for catalyst characterization. Methanol is directly synthesized from CO2
and H2 through an alcohol-assisted method with ethanol as a medium. The results
shows that the catalyst precipitated at 60 C and pH 8 with the use of ultrasonic
exhibited the maximum %yield of methanol at 33% and 81% selectivity.
I-SET04-O14
Abstract:
Potential of biomass feedstocks from four primary food crops as a co-firing fuel for
Mae Moh power plant has been investigated using publicly available database. It
can be concluded that no single type of biomasses can meet the electricity
capacity of Mae Moh power plant. Besides, this study also found that biomass
which has the most potential to generate electricity is rice straw (316 MW) while the
most potential biomass redisue is sugar cane leaves and tops (175 MW).
I-SET05-O35
Abstract:
Catalytic and non catalytic pyrolysis of plastic packaging wastes were conducted in
fixed-bed reactor. Four types of plastics were used in this study: polypropylene (PP),
polystyrene (PS), low density polyethylene (LDPE) and high density polyethylene
(HDPE). The effect of pyrolysis temperature (400550oC), pyrolysis time (414 min),
types of catalyst (zeolite and kaoline), and catalyst content (catalyst/plastic weight
ratio 0.050.20) on oils yield and their properties were investigated. It was observed
that pyrolysis temperature did not affect the oil products yield while heating value
of oil products slightly increase with increasing pyrolysis temperature. When
pyrolysis time increased, oil products yield also increased. Use of zeolite and
kaoline increased the yield and heating value of oil products. However, catalyst
content also did not affect the yield and heating value of products. The heating
value and viscosity of obtained oils were comparable to commercial fuels like
diesel and gasohol 91. FTIR results showed that oils from PS had compositions in
accordance with gasohol 91 while oils from PP, LDPE and HDPE had compositions in
accordance with diesel.
I-SET06-O36
pattaraporn.kim@mahidol.ac.th
Abstract:
This research project is conducted for the purpose of syngas production from CO2
and H2O using a solid oxide electrolysis cell (SOEC). BaCeO3- (BC), Ba0.6Sr0.4CeO3-
(BSC), Ba0.6Sr0.4Ce0.9Y0.1O3- (BSCY), and Ba0.6Ce0.9Zr0.4O3- (BCZ) are synthesized using
solid state reaction method. BC, BSC, and BSCY are calcined at 1100oC for 2h and
BCZ is calcined at 1300oC for 12h. Its shown 100% perovskite. The proton
conductivity is tested (400-800oC) and it is found that the conductivity increase with
temperature. The activity toward the reverse water gas shift reaction is also tested
(400-800oC) and it is found that CO yield of BCZ higher than BSCY, BSC, and BC,
respectively at 550-800oC. Electrolyte composite with Cu are also tested toward
RWGS. Addition of 40%wt. Cu significantly increases catalytic activity as the reaction
temperature for synthesis syngas decreases to lower 400oC and CO yield of Cu/BSCY
higher than Cu/BCZ, Cu/BSC, and Cu/BC, respectively.
Keywords: Solid oxide electrolysis cell, reverse water gas shift, proton conductivity,
strontium doped barium cerate, syngas
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
I-SET07-O63
2pattaraporn.kim@mahidol.ac.th
Abstract:
This study aims at providing an alternative approach to CO2 utilization, molecularly
reforming CO2 into liquid fuel such as ethanol or methanol. The technique relies on
photocatalytic conversion, utilizing catalytic activities of titanium dioxide (TiO2)
nanoparticles and charge transportation of graphene support, in liquid phase and at
room temperature. Graphene oxide (GO) was synthesized, following a modified
Hummers method, and further composited the GO with titanium dioxide (TiO2)
nanoparticles through a sol-gel method. After that, thermal was used for reduction
of GO functional groupsto obtain reduced graphene oxide (rGO). Photocatalyst was
characterized using TEM, BET surface analysis, FTIR spectra and XRD. Our best result
showed that the TiO2/rGO composite with 20 wt. % TiO2 loading converted water-
dissolved CO2 into ethanol, yielding 28.62 mol ethanol per gram composite. Good
performance of the TiO2/rGO composite was attributed to low band gap energy (2.9
eV) and high surface area (106.5 m2/g) of the material.
I-SET08-O66
Abstract:
This study aims at showing catalytic activity of a potent fuel cell anode candidate,
Pd-rGO composite. The palladium (Pd) nanoparticles were chemically synthesized
and immobilized on reduced graphene oxide (rGO), following a sol-gel method with
potassium bromide (KBr) as soft template. The obtained Pd nanoparticles were in
spherical (nanoparticles) and cubical geometry (nanocubes) with a particle size
ranging from 10 to 50 nm, providing "edges" that expose the active Pd atoms for
catalysis purpose. Catalytic performances of the PdrGO composite were tuned and
tested over electrochemical oxidation of ethanol in a liquid phase electrochemical
cell, and catalytic oxidation of hydrogen in a gas phase proton exchanging
membrane fuel cell. Best results obtained from PdrGO composite with 10% wt Pd
loading per gram of graphene oxide and 0.01 M KBr concentration exhibited current
density of 25.73 mA/cm2 for ethanol and 4.09 A/cm2 for hydrogen.
I-SET09-O76
Abstract:
Hydrothermal liquefaction (HTL) is a promising process to convert biomass into
liquid fuels, so called biocrude. The objective of this work was to investigate an
effect of demineralization using nitric acid on the liquefaction of sugarcane leaves.
Besides, the biocrude production from that process was comprehensively explored
in various ratios of co-solvent (ethanol/water). The experiments were conducted in
a 250 mL autoclave reactor at a temperature range of 300-350C and reaction time
of 60 minutes. The results indicated that the demineralization obviously reduced
ash content in sugarcane leaves and gave a higher biocrude yield from HTL using
pure ethanol. The characteristic of biocrude was also evaluated in terms of
elemental composition, water content, and the total acid number (TAN).
I-SET10-O94
Abstract:
In this study, the torrefaction of highly moist sawdust pellets (with the initial
moisture content of 40 wt.%) using microwave irradiation, with or without the
addition of biomass char, was investigated. It was found that the torrefied sample
with the addition of the char of corncob (biomass char) had lower amounts of
moisture and volatile matter than did the torrefied sample without the addition of
corncob char. The amounts of moisture and volatile matter of the torrefied sample
decreased with time. An increase in the microwave power led to a decrease in the
amounts of moisture and volatile matter. It was also found, from the combustion
test runs, that the torrefied sample possessed a higher rate constant (k) and a lower
activation energy (Ea) than did the raw sample.
I-SET11-O95
Abstract:
The purpose of this research was to study the effects of microwave absorbers on
the torrefaction of highly moist municipal solid waste pellets. The effect of the type
of agricultural residue used as the microwave absorbers (char from agricultural
residue), microwave power, and torrefaction time on the torrefaction of MSW-pellet
samples was investigated. It was found that the addition of char from bagasse
yielded the lowest remaining mass and the highest temperature of the torrefied
sample. The increases in the torrefaction time and the microwave power resulted in
lower amounts of remaining moisture and volatile matter. The amounts of ash and
fixed carbon were found to be relatively constant at their initial values. The addition
of the microwave absorbers led to an increase in carbon content, but a decrease in
the amount of oxygen, of the torrefied sample, when compared to the sample
without the addition of the microwave absorber.
I-SET12-O134
Abstract:
This research studied the effects of Fe2O3 addition to CaSO4 oxygen carrier which is
the worthwhile material in terms of combustion and thermal stability. The result
revealed that 20 wt.% Fe2O3/CaSO4 gave the best result in terms of methane
conversion, thermal stability and regenerability. For the CLC of coal, the reaction
temperature is optimal at 950oC. The reduction reaction was rapidly completed
within 60 min. SEM and XRD were used to analyze the solid composition and
morphology of spent oxygen carrier. It was found that 20 wt.% Fe2O3/CaSO4 could
be used in CLC process both gaseous and solid fuels.
Keywords: Calcium sulfate oxygen carrier, Fluidized bed reactor, chemical looping
combustion, coal
Biomedical Engineering & Biomaterials
(T-BEB)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-BEB01-P45
*
, , , ,
10140
panchan.sri@kmutt.ac.th
:
scaffold
scaffold
simulated body fluid (SBF)
scaffold
: , , , ,
T-BFT01-O26
*, ,
. . . 80240
kittiphoom.s@rmutsv.ac.th
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-BFT02-O92
Cellic Ctec2
.. ,*, , .. , .
50
fengjrc@gmail.com
:
(Oil Palm Empty Fruit
Bunches) Cellic Ctec2
54.74, 21.73
16.17
10, 15 20 60
15 14.28
3.41
5, 7, 10 15
Cellic Ctec2 20 FPU/g substrate
140 5 5
10
85.79
60.29 12.51
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-BFT03-P100
, , *, .
. .
thirawat.m@en.rmutt.ac.th
:
30
500 200 30
68.55%
67.26% 4.08% 4.11% 3.16% 2.59%
4.23% 4.18% 0.34% 0.29%
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-BFT04-O150
.. *, Prof. Dr. M.N. Eshtiaghi
nuttawan.yos@mahidol.ac.th
:
(Saccharomyces cerevisiae)
220.
1:92 110 330 .
5 ,4 15
314 182.8 .
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-BFT05-P176
Abstract:
Shelf life study is a crucial step of product development since it indicates safety,
acceptable sensory characteristics with proclaimed nutritional values when the product is
kept in the recommended condition. This study was aimed to study the sensory properties,
physical properties the correlation between sensory properties and physical properties of
mochi ice cream as it was kept in different conditions (-5oC, -10oC and -20oC). Descriptive
analysis was performed by 8 trained-panelists and evaluated using intensity score between
0-15. Texture profile analysis (TPA) was performed by using texture analyzer. The results
from both measurements were performed ANOVA, t-test and Dunnetts test (=0.05) and
Principal Component Analysis (PCA) were performed to compare the stored samples with
the control as well as indicate the correlation between sensory attributes and physical
characteristics. There were 13 developed lexicon attributes. The longer of storage caused
lower intensity of softness and gumminess from mochi phase. From texture analyzer that
showed significantly decreased from control. From these results, both measurements can
be applied for mochi ice cream development.
Keywords: shelf life, mochi ice cream, sensory analysis, physical measurement,
Texture
Catalyst & Reaction Engineering
(T-CRE)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE01-O24
-
*
, ..
140 10530
vissanu.meeyoo@gmail.com
:
15%
Ni/Ce0.75Zr0.25O2
650 850
6 9
(W/F)
650 6 9
(W/F)
(W/F)
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE02-O70
Er(OTf)3
*
, .
kptanawa@gmail.com
:
15%
(Er(OTf)3)
- 150 200 0
45 Er(OTf)3 0.1:1 1:1
200
5
190
30 Er(OTf)3 0.5:1
54.29
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE03-O74
:
(TMA) MgCl2
adduct (-OH group)
TMA OH
Ti
MgCl2 /EtOH 1:6 TMA 3
(MgCl2 /EtOH/TMA) 1:6:6 1:6:6.3 1:6:6.6 MgCl2 /EtOH/TMA
1:6:6.3 6.9 kg PE/mmol cat.h
( SEM)
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE04-O68
*
, .
10520
kptanawa@gmail.com
:
190
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE05-O58
1 1,* 2
, ,
1
10330
2
bunjerd.J@chula.ac.th
MMAO 3
(XRD) SiO2-syn
1,081 m2/g (activity)
70oC 400gPE/gZrh
SiO2 -com 98 gPE/gZr h SiO2 -syn 77 gPE/gZrh
52 gPE/gZrh
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE06-O81
*
,
254 10330
bunjerd.j@chula.ac.th
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE07-O82
1,* 2 1
1
254 . 10330
2
. ()
71 2 13170
Atthawut1308@gmail.com
(Titanocene) MAO
10% 3, 3.25, 3.5 3.75
1081m2/g
(SEM)
0.1-0.5 MAO 3.75
2.96 kg PE/mmol cat.h
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE08-O79
*
,
10330
aname_i@hotmail.com
270
2 80
10
82.83
79
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE09-P104
2
1,2* 1,2
,
1
--
2
10900
waleepornd@gmail.com
(Ni/BPS) (AC)
(CB) (NT) 10Ni(CB)
/BPS 17.5
13.0
: ,, , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE11-O111
*
,
10330
suphot.P@Chula.ac.th
(Impregnation method) 2, 4 6
(NH3-TPD)
(CO2-TPD)
(Binding energy O 1s)
(XPS)
(X-Ray Diffraction)
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE12-O122
V2O5-MoO3/TiO2
NO
*
,
10330
A.Yasadayan@gmail.com
:
(NO)
(Selective catalytic reduction ; SCR) V2O5-MoO3/TiO2
0.2 0.5 M
0.2 M CO2
: ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE13-O32
1 1,* 2
, .. , ..
1
,
140 10530
2
vissanu.meeyoo@gmail.com
1 2
Ni-P-B
hexamethyleneimine (HMI)
: , , -
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE14-O152
, , , ,
*
.
169 . . .
. 20131
soipatta@buu.ac.th
-
CuO/ZnO/Al2O3 CaO, ZrO2 ,
Zeolite type-A HZSM-5 2:1
250 C
(GC) (%CO2 conversion)
(%Selectivity)
CuO/ZnO/Al2O3 HZSM5
,
HZSM-5
C2 C3
: , / / ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-CRE17-O177
--/
1 2* 3*
, .. , ..
1
pinyapat_pengbubpha@hotmail.com
2
wipoo.sr@kmitl.ac.th
3
kkkunlan@kmitl.ac.th
-- ABS (TiO2)
TiO2 0.5
: , ,
Environmental, Safety, Health &
Risk Management
(T-ESH)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH01-O15
*, , ,
anurak.p@eng.kmutnb.ac.th
50x50x50
100 15
800-1,200 3
Flat Disc-6- Blade Turbine, 45 Pitched-4- Blade Turbine 45 Flat Disc-
6- Blade Turbine 45Flat Disc-6-
Blade Turbine 800
(SAED) 1.334 kgO2/kWh
: , ,
(SAE), (KLa)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH02-O56
Fe/TiO2
, .. *
pornsawan.as@kmitl.ac.th
:
Fe/TiO2 Box-Behnken
Minitab 95
(X1)
Fe/ TiO2 (X2) (X3) (X4)
= 38.7 + 0.2666 X1 + 194.2X2 - 0.1120X3 + 1.313X4 - 0.000475X1X1 181.3
X2X2 200 X1 = 140 X2 = 0.53
X3 = 250 X4 = 1
5
99.6 (TOC)
62
: , , , Fe/TiO2
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH03-O73
, , .. *
pornsawan.as@kmitl.ac.th
H2O2
pH pH 5.7
H2O2
H2O2 100 mg/L 53%
10,000 mg/L 92.55%
10 mg/L 35% 1,000
mg/L 92% H2O2
10,000 mg/L 100 mg/L pH 5.7 92.55%
: , , Fe/NaA, H2O2
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH04-O102
*,
panuwat_tak@hotmail.com
:
Pilot Scale
2/3
1/3 (6 12 )
0.3-1.5 m3/h
1.59 m SAED
1.2 1.5 m3/h
95% ( = 0.05)
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH05-O105
*,
naphatcha.wg@gmail.com
0.55 0.5
0.25
70 90 ./
4.2 /
(G)
20%, 35%, 50% 65% (0.55
) 35% 390 -1
79.5% 50% (G=326 -1), 65%
(G=286 -1) 20% (G=516 -1) 78.6%,
76.9% 73.4%
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH06-O107
,
patcharin.w@eng.kmutnb.ac.th
NaY
: NaY, , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH07-O127
,
umpuch_ck@yahoo.com
:
(Polyethylene glycol, PEG) 20000 g/mol 2.5:2.5
SEM (BSA)
100% 0.5 13 10
psi
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH09-0130
, *
supatpong.mj@gmail.com
:
(HL4040FN, GE water
and process technology) 0.01 0.005
10 7
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH10-O132
, *
varong.p@chula.ac.th
:
30
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH11-O80
*, . .
w.tungthirawanich@gmail.com
:
2 (4 6 )
(Pilot Scale)
1.8-2.4 m3/h 0.4 m
6 SAED 4
1.8, 2.1 2.4 m3/h
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH12-O151
1,2, 2, 2, 2,*
1
2
lekw@eng.buu.ac.th
:
PHAST
Version 7.11
(1.5 )
30,000 ppm 15 (Short-
term Exposure Limit : STEL)
> 106.92 127.75
5,000 ppm 8 (Permissible exposure
limit : PEL)
> 189.75 237.06
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH13-P158
(II)
*,
12000
wanvimon@rsu.ac.th
:
(II)
600C 2 1 M NaCl 600 C 2
/
/
(Cu2+) 5-6
180
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH14-P159
*, ,
panida.s@rsu.ac.th
3 M 1:15 50oC 8
2.618
(XRD)
100 %
63.66
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-ESH15-P170
*, ,
sangnuan.s@eng.kmutnb.ac.th
:
(H2O2)
(COD)
Granular 1:9
2 1
40:30 mL 90 2
(COD) 100 mg/l, 24.5 S.U. 2
30:10 mL
60 8 COD 333.3 mg/l,
3.95 S.U.
: , , , Granular
Innovation in Chemical Engineering &
Applied Chemistry for Industrial Development
(T-IA)
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
T-IA01-O50
Abstract:
The world is overwhelmed with the so-called innovations. The problem is that
most innovations end up as only patents or small-scale production because they fail
to be scaled up or commercialized on a large scale. Forbes reported that a staggering
95% of the active 2 million patents fail to be commercialized, and an incredible
amount of research money is being wasted down the drain around the world. This
paper analyzes why innovations in chemical engineering fail to be commercialized,
and suggests ways to increase the chance of successful scale-up and
commercialization. The approach includes the big picture of scale-up work flow and
also the detailed picture of equipment design and scale-up methodology. We also
provide examples of successful scale-up of innovations in chemical engineering, as
well as our findings and lessons-learned from the scale-up process. An approach to
scale up some common types of equipment or reactor are also discussed.
T-IA02-O17
*, .
t_craziness@hotmail.com1
:
50 oC
16.7% w/v 0.1
3.25 20 53%
: , , ,
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
T-IA03-P98
, , *, .
. .
thirawat.m@en.rmutt.ac.th
3 0.5, 20, 70
35%
100 50 48
11.5
70 57
: , , ,
The 6th TIChE International Conference 2016
Innovative Technology toward Sustainable Development
Bangkok, Thailand, October 26-28, 2016
T-IA04-O69
*,
fengsks@ku.ac.th
:
35 45
(CMC)
CMC
3
CMC
CMC 1.28 1.50
47.84 29.18 CMC
USP37
: ,
Polymers & Materials
(T-PM)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM01-P38
304
*
, , ,
, 123
40002
chaikr@kku.ac.th, c.kruehong@gmail.com
304 650
1:1:2
400 20
304
15
FE-
SEM TEM 3
: , , , 304
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM02-O60
*
, ,
surat.ar@kmitl.ac.th
:
0-80%
-
(Sintering)
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM03-P61
-
*
,
joongjai.p@chula.ac.th
:
(Amberlyst 31)
-
Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS)
exchange capacity activity selectivity
: -, , , Amberlyst 31
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM04-O109
(-)
*
,
jintana09530055.por@gmail.com
:
(-)
:, , , (-)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM05-O124
1 1 2,* 2 3
, , , ,
1
2
3
sutasineene@kku.ac.th
:
(Scanning Electron Microscope; SEM)
0.8 A
(compact)
210 5
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM06-O146
1,* 1,2
,
1
()
2
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM07-O147
1,* 1,2 1
, ,
1
()
2
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM08-O153
1,* 1 1 2
, , ,
1
2
tienchai.ton@mahidol.ac.th
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PM09-O161
1* 2
,
1,2
*kanokporn_anan@hotmail.com
:
(Polylactic Acid : PLA)
45 m 0
1 3 5 % wt. 20 rpm
190 C Compression molding 180 C 1 bar
PLA
PLA
: , , , ,
Petroleum & Petrochemical Technology
(T-PPT)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-PPT01-O96
1 1,* 2
, ,
1
10330
2
114 . .
. . 12120
*ppattara@chula.ac.th
:
(DBT) 4,6-
(4,6-DMDBT)
3
> >
Cu Ni
Cu-Y ~ Ni-Y > Ni/AC
~ Cu/AC
: , ,
Process Design, Simulation & Control
(T-PSC)
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC01-O90
*
,
.
sarawut_j@rmutt.ac.th
3 ,
3.65%
45.6%
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC02-O93
90
*
, ,
10520
cfdgroup_santi@hotmail.com
90
1.5
FLUENT
90
Renormalization group k-epsilon
: , 90 ,
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC03-O101
90
*
, ,
10520
cfdgroup_santi@hotmail.com
90
4 3
(17.05, 34.1, 51.15 /), (90, 180, 270 ),
(1D, 1.5D, 2D) D , (,
, ) (Orthogonal
Array)
: , , 90 ,
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC04-O155
*
, , ,
30000
atichat@sut.ac.th
:
(CO2)
(Monte Carlo)
10 60 283 K 4500 kPa
(SiO4)
CO2
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC05-O156
*
, , ,
30000
atichat_w@hotmail.com
:
(Selectivity)
(Grand Canonical Monte Carlo, GCMC)
293.15K 318.15K
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
PSC06-O157
(Gas Turbine)
, .. *
18 99 . . . 12120
cattalee@engr.tu.ac.th
:
(Gas Turbine)
292 MW (Compressor)
Aspen Hysys version 8.6
34 ,
49% Base case 3
1. (Base case) 2. (Fogging Spray
Cooling) 3. (Electrical Chiller) Fogging Spray
Electrical Chiller 6.85 12.73
T-SET01-O16
Saccharomyces cerevisiae
SG
*
. , , ,
, , ,
pongsri.s@en.rmutt.ac.th
:
Saccharomyces cerevisiae SG
24 20 40
31C 40C
40 2,000 mL 5% v/v
15 % w/v
40 pH 5 72
31C
T-SET02-O22
*
. , ,
93210
ruamporn6798@gmail.com
:
pH 3 5
56.9 38.1
5 15
120 70
BOD5 COD
95 pH pH
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET03-O62
1 1 1 1,2,* 1,2
, , , , ,
1
1
2
sutasineene@kku.ac.th
:
250 350C
99
15%Cr/DM 91.7
12
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET04-O64
* *
, ,
Global R&D Co. Ltd.
rungrote.globalrd@gmail.com
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET05-O75
RT-P3
SG
*
. , . , . , , ,
, ,
pongsri.s@en.rmutt.ac.th
:
RT-P3
5 (LM) (OR:RB)
7.2x107
cell/mL, 150 g 5, 25, 45 g 5
400, 450, 550 mL 242C 7
9.10 g/L OR:RB:LM 150:25:450 6
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET06-P77
*
, .
10330
nuttapol.p@chula.ac.th
:
Ni0.85Se
Poly(Ethylene oxide), 5% acetamide NaI/I2
4.0 %
DSSC 30 x 30
T-SET08-P88
Ni-Mo
Co-Mo
1 1,* 2
, ,
1
10330
2
114 . .
. . 12120
*ppattara@chula.ac.th
:
Ni-Mo
Co-Mo Ni-
Mo Co-Mo
C14, C15 C16
- 0.2 320 70
60
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET10-O120
*
, .
10330
*
nuttapol.p@chula.ac.th
(dye-sensitized solar cell, DSSC)
(photoconversion efficiency; PCE)
: , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET11-P135
- Core-shell:
1, 2 1, 2 1, 2,*
, ,
1
- 10900
2
10900
fengmtc@ku.ac.th
:
- Core-shell
27.7 mT
(N-S) 20.2%
240C 1.7
T-SET12-P136
MCM-41
1, 2 1, 2 1, 2, *
, ,
1
- 10900
2
10900
fengmtc@ku.ac.th
:
Fe-
Cu/MCM-41
15.69
: , , , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET13-O145
* 1,*
, ,
12000
sirikul@rsu.ac.th
:
2
0.2 m3 15 55
(mixed solar dryer) (flat plate
collector) 80x120 cm2 8 cm
0.3 cm 15
(natural convection or
passive system) 2,000 g 73.66
5 29-30 2559 09.0017.00 .
58.06C 39.73C
552.32 g 569.74 g
72.38 71.51
1.28 2.15
3.07x10-5 s-
1
61
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET14-O148
12000
wannee.e@rsu.ac.th
:
0.565 m2 2 45o
0.011m2
.06 m2
30
%
: ,,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET15-O166
. - . 12110
yanyong_s@en.rmutt.ac.th
:
( Tube
Furnace) 10 C/min
100 cm/ 3min
350 C
500 m 4 g 1.30
5.76%
28.82 48.25
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SET16-O175
1,* 2
.. ,
2
serij@mitrphol.com
:
(Zero Breakdown Technique)
(Root Cause Failure Analysis : RCFA)
(Fish bone
diagram) 98.43 2.65
28,371,420.00
: , ,
Separation & Purification Technology
(T-SPT)
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SPT01-P78
Ocimum citriodourum Vis.
1,*, 2, 1
1 10330
2 10330
somkiat.n@chula.ac.th
:
( )
(SCCO2)
GC-MS
4.04 SCCO2 (350
70 ) 1.50 0.29
: , ,
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SPT02-O99
, *
10330
khantong.S@chula.ac.th
:
Over flow
1 0.04650.0003 0.05790.0009
/ 40 o
1 0.04020.0007 /
22-23% 14-15% 2
1000 /
:
26
Innovative Technology toward Sustainable Development
26-28 2559
T-SPT03-O169
Box-Behnken Design (BBD)
1,2, 1,2 1,*
1 40002
40002
kumsaen@gmail.com
(Mn2+)
(MnO2)
(0.05 )
(5 10 15 ) pH (3 4
5) (5 10 15 )
Box-Behnken Design (BBD)
2.194 100% 15
pH 4 20
T-SPT06-P77
, . *
10330
nuttapol.p@chula.ac.th
:
Ni0.85Se
Poly(Ethylene oxide), 5% acetamide NaI/I2
4.0 %
30 x 30
: , ,