El sistema 1-clorobutano(1)/clorobenceno ( 2) se comporta como solucin ideal el cual

satisface la ley de Raoult

a) Prepare el diagrama Pxy para esta mezcla a 100C

A B C
1) 1-clorobutano 13.96 2826.26 224.1
2) clorobenceno 13.9626 3295.12 217.55

Presin de saturacion a t= 100.00 C

P1,sat= 188.61
P2,sat= 36.09

La presin total resulta:

x1 P Y1
0 36.0859436445 0
0.1 51.338073505 0.3673827812
0.2 66.5902033656 0.5664714409
0.3 81.8423332262 0.6913558112
0.4 97.0944630867 0.7770051402
0.5 112.346592947 0.8393990298
0.6 127.598722808 0.8868767873
0.7 142.850852668 0.9242161815
0.8 158.102982529 0.9543513436
0.9 173.35511239 0.9791838019
1 188.60724225 1
b) Prepare un diagrama t Vs XY a P=101.33 Kpa
1-clorobutano clorobenceno
T= 78.45 C 135.08734039
P= 101.33 KPa 101.33 KPa
Funcin Objetivo 0.00 KPa 0.00 KPa

Delta T= 1
T P1,sat P2, sat x1,sat Y1,sat
78.45 C 101.329999801 16.949717259 1 1.0000000004
79.45 C 104.496917992 17.597105623 0.96355668 0.9936712028
80.45 C 107.741036273 18.264625347 0.92834943 0.9870850597
81.45 C 111.063640194 18.95274574 0.89432694 0.9802349288
82.45 C 114.466024123 19.66194274 0.86144031 0.9731140562
83.45 C 117.949491113 20.39269892 0.82964291 0.9657155746
84.45 C 121.515352772 21.145503487 0.79889028 0.9580325038
85.45 C 125.164929129 21.920852281 0.76913999 0.9500577491
86.45 C 128.899548497 22.719247778 0.74035157 0.941784101
87.45 C 132.72054734 23.541199087 0.7124864 0.933204235
88.45 C 136.629270132 24.387221942 0.68550761 0.9243107101
89.45 C 140.62706922 25.257838702 0.65937998 0.9150959692
 90.45 C 144.715304683 26.153578339 0.6340699 0.9055523379
91.45 C 148.89534419 27.074976436 0.60954523 0.895672024
92.45 C 153.168562859 28.022575169 0.58577527 0.8854471172
93.45 C 157.536343113 28.996923306 0.56273069 0.8748695887
94.45 C 162.000074534 29.998576185 0.54038344 0.86393129
95.45 C 166.561153721 31.028095708 0.51870669 0.8526239534
96.45 C 171.220984138 32.086050319 0.4976748 0.8409391908
97.45 C 175.980975975 33.173014992 0.4772632 0.8288684933
98.45 C 180.842545991 34.289571211 0.45744843 0.8164032314
99.45 C 185.807117371 35.436306953 0.43820801 0.8035346538
100.45 C 190.876119578 36.613816664 0.4195204 0.7902538875
101.45 C 196.050988197 37.822701238 0.40136501 0.7765519373
102.45 C 201.333164789 39.063567996 0.38372211 0.7624196854
103.45 C 206.724096738 40.337030657 0.36657278 0.7478478911
104.45 C 212.225237101 41.643709319 0.34989891 0.7328271903
105.45 C 217.838044456 42.984230423 0.33368314 0.7173480956
106.45 C 223.563982746 44.359226733 0.31790882 0.7014009955
107.45 C 229.404521131 45.7693373 0.30256001 0.6849761548
108.45 C 235.361133831 47.215207434 0.28762139 0.6680637134
109.45 C 241.435299975 48.697488674 0.27307829 0.650653687
110.45 C 247.62850345 50.216838748 0.25891662 0.6327359664
111.45 C 253.942232739 51.773921547 0.24512288 0.6143003173
112.45 C 260.377980775 53.369407083 0.23168409 0.5953363802
113.45 C 266.937244786 55.003971455 0.2185878 0.5758336703
114.45 C 273.621526136 56.67829681 0.20582206 0.5557815771
115.45 C 280.432330179 58.393071307 0.19337539 0.5351693648
116.45 C 287.371166095 60.14898907 0.18123676 0.5139861716
117.45 C 294.439546748 61.946750156 0.16939557 0.4922210096
118.45 C 301.638988522 63.787060506 0.15784164 0.4698627655
119.45 C 308.971011172 65.670631903 0.1465652 0.4469001995
120.45 C 316.437137672 67.598181931 0.13555682 0.4233219461
121.45 C 324.03889406 69.570433924 0.12480748 0.3991165133
122.45 C 331.777809284 71.588116927 0.11430846 0.3742722834
123.45 C 339.655415051 73.651965642 0.10405141 0.3487775125
124.45 C 347.673245675 75.762720383 0.09402828 0.3226203303
125.45 C 355.832837926 77.921127028 0.08423133 0.2957887409
126.45 C 364.135730876 80.127936966 0.0746531 0.2682706222
127.45 C 372.583465749 82.383907049 0.06528643 0.2400537261
128.45 C 381.177585771 84.689799537 0.0561244 0.2111256788
129.45 C 389.919636023 87.04638205 0.04716038 0.1814739807
130.45 C 398.811163283 89.454427509 0.03838796 0.1510860065
131.45 C 407.853715888 91.914714087 0.02980096 0.1199490056
132.45 C 417.048843577 94.42802515 0.02139346 0.0880501018
133.45 C 426.398097348 96.995149203 0.01315972 0.055376294
134.45 C 435.903029308 99.616879834 0.00509423 0.0219144559
135.09 C 442.09091763 101.3300003 -8.910E-010 0
solucin ideal el cual

180

160

140

120

100
P
P
80 P

60

40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1,Y1

T Vs XY
140.00 C

135.00 C

130.00 C

125.00 C

120.00 C
 130.00 C

125.00 C

120.00 C

115.00 C

110.00 C

T,C 105.00 C

100.00 C

95.00 C

90.00 C

85.00 C

80.00 C

75.00 C

70.00 C
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1,Y1
 P Vs X1
P Vs Y1

7 0.8 0.9 1
 v

T Vs X1
T Vs Y1

0.7 0.8 0.9 1

P= 101.33 Kpa